3
Nano B.S. Jorio a Instit 020 D b Instit 970, B c Depa Brazil d Depa 69011 e Depa Posta Figu scale oscale Map Archanjo a,1 o c , C.A. Ach tuto Nacional Duque de Caxi tuto de Física, Brazil. artamento de F l artamento de 1-970, Brazil artamento de E al 68505, Rio d ure S1 (com e analyses v Su pping of Ca 1* , D. L. Bap hete a,e de Metrologi ias, RJ, Brazil , PPGMicro, Física, ICEx, Ciências Agro Engenharia M de Janeiro, RJ mplementary via EDX spe uppleme arbon Oxid ptista b,1 , L. ia, Qualidade l. Universidade Universidade onômicas, Inst Metalúrgica e J 21945-970, B y to the Fig ectra, collec entary In dation in Bi A. Sena a , L e Tecnologia, e Federal do R e Federal de M tituto Naciona de Materiais, Brazil . 1a from th cted at 6 spo nformati iochar from L. G. Cançad , Av. Nossa Se Rio Grande do Minas Gerais, al de Pesquisa Universidade he main tex ots as indica ion m Ancient A do a,c , N.P.S enhora das Gr o Sul, Porto Al Belo Horizon as da Amazôn e Federal do R xt). Here we ated in the m Anthrosoils . Falcão d , A raças, 50, 252 legre, RS, 915 nte, MG 30123 nia, Manaus, A Rio de Janeiro e show the m micrograph. s A. 250- 501- 3-970, AM o, Cx. micro Electronic Supplementary Material (ESI) for Environmental Science: Processes & Impacts. This journal is © The Royal Society of Chemistry 2015

Supplemeentary Informati · zon. As exp Fig. 4 from on grains t ifferent pa ge. Here, a anic radic grains. Fu inent in th e main tex ion at the c rain is from ected carbo the mai

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Page 1: Supplemeentary Informati · zon. As exp Fig. 4 from on grains t ifferent pa ge. Here, a anic radic grains. Fu inent in th e main tex ion at the c rain is from ected carbo the mai

Nano B.S.

Jorio

aInstit

020 DbInstit

970, BcDepa

BrazildDepa

69011eDepa

Posta

Figuscale

oscale Map

Archanjoa,1

oc, C.A. Ach

tuto Nacional

Duque de Caxi

tuto de Física,

Brazil.

artamento de F

l

artamento de

1-970, Brazil

artamento de E

al 68505, Rio d

ure S1 (come analyses v

Su

pping of Ca

1*, D. L. Bap

hetea,e

de Metrologi

ias, RJ, Brazil

, PPGMicro,

Física, ICEx,

Ciências Agro

Engenharia M

de Janeiro, RJ

mplementaryvia EDX spe

uppleme

arbon Oxid

ptistab,1, L.

ia, Qualidade

l.

Universidade

Universidade

onômicas, Inst

Metalúrgica e

J 21945-970, B

y to the Figectra, collec

entary In

dation in Bi

A. Senaa, L

e Tecnologia,

e Federal do R

e Federal de M

tituto Naciona

de Materiais,

Brazil

. 1a from thcted at 6 spo

nformati

iochar from

L. G. Cançad

, Av. Nossa Se

Rio Grande do

Minas Gerais,

al de Pesquisa

Universidade

he main texots as indica

ion

m Ancient A

doa,c, N.P.S

enhora das Gr

o Sul, Porto Al

Belo Horizon

as da Amazôn

e Federal do R

xt). Here weated in the m

Anthrosoils

. Falcãod, A

raças, 50, 252

legre, RS, 915

nte, MG 30123

nia, Manaus, A

Rio de Janeiro

e show the mmicrograph.

s

A.

250-

501-

3-970,

AM

o, Cx.

micro  

Electronic Supplementary Material (ESI) for Environmental Science: Processes & Impacts.This journal is © The Royal Society of Chemistry 2015

Page 2: Supplemeentary Informati · zon. As exp Fig. 4 from on grains t ifferent pa ge. Here, a anic radic grains. Fu inent in th e main tex ion at the c rain is from ected carbo the mai

Figuscale

Figuscale

ure S2 (come analyses v

ure S3 (come analyses v

mplementaryvia EDX spe

mplementaryvia EDX spe

y to the Fig.ectra, collec

y to the Figectra, collec

. 1b from thcted at 4 spo

. 1c from thcted at 8 spo

he main texots as indica

he main texots as indica

xt). Here weated in the m

xt). Here weated in the m

e show the mmicrograph.

e show the mmicrograph.

micro  

micro  

Page 3: Supplemeentary Informati · zon. As exp Fig. 4 from on grains t ifferent pa ge. Here, a anic radic grains. Fu inent in th e main tex ion at the c rain is from ected carbo the mai

 

 

 

 

 

 

 

 

 

 

FiguscaleshowMartelem

 

 

 

 

 

 

 

 

 

Figuinforfigurtransbehacarbocarbograin

ure S4 (come analyses vwn in electrt.), a typical

ments. 

ure S5 (comrmation of tres show Esmission eleavior is oboxyl) are oonyl and cans.

mplementaryvia EDX spron microgl plant spec

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. 1e from thected in regcharcoal gzon. As exp

Fig. 4 frombon grains tdifferent paage. Here, aganic radic

grains. Fuminent in th

he main texgion at the cgrain is frompected carbo

m the maitaken from arts of theas discussedcals (aromaurthermorehe surface th

xt). Here wecenter of thm Ingá woon and oxyg

n text) ChSerra Baixgrain and

d in the maiatic, phenolthe signal han in the i

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hemical bonxa – TPISB. d the respein text, the l, carbonylintensity oinner part o

micro grain

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ective same

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