12
Summary of Notable Achievements (2005-2013) • Author or co-author on 29 publications: 26 peer reviewed+ I in print & 2 undergoing peer review, I book chapter; additionall3 miscellaneous publications (reports, etc.). • Received over $I,200,000 in grants: -$935,000 in competitive external funding (DOE & NSF); $3I4,000 in internal funding.(Provost Fund) for research projects. • Gave I9 invited talks; 11 invitations to speak at meetings, conferences and workshops; 8 at seminars and colloquia; gave 5 uninvited conference presentations. • Supervision (i.e., mentoring) of 2 postdoctoral associates (Drs. Hao Y an and Sonal Dey). • Helped "put MSU on the map" of DOE funded EFRC energy centers through participation in EFree center headquartered out of Washington, DC (since 2009). • Supervised I2 undergraduate students and 10 graduate students on thesis research projects; students routinely make presentations at MSU workshops/forums and regional and national meetings (see supplementary information). •Successfully led the establishment of the shared X-Ray Analysis Facility in CNAS (obtained by Provost Fund). • Successfully led an NSF-MRI acquisition of shared major instrumentation (Raman-PL spectroscopy) for faculty in CNAS & BMS. • Was awarded beam time at synchrotron (x-ray) facilities around the world (Advanced Photon Source, Argonne Nat' I Lab; CHESS, Cornell U.; ESRF, France) through on-going proposals for beam time; frequently take along I - 2 students per visit, for 2- 3 visits per year. • Originated cutting edge research on properties of nanophase (between atomic and microscopic scales) materials in extreme environments (e.g., under pressure-temperature-aqueous- radiation extremes) for energy applications. • Teaching evaluations scores range from 1.06 to 1.7; overall average= 1.35 • A "red-chili-pepper hotness" ranking on RateMyProfessor.com; current score 4.3/5. • Served on numerous university, college and department committees. •Refereed 2+ journal manuscripts per year; reviewed- I grant proposal peryear. • Participated in Dept. of Energy (OSR) review panel (2010); 2 days in Washington, DC+ review of multiple proposals prior to review panel workshop. • Participation in student fairs on annual basis. •Active participant in PAMS recruitment (e.g., provided PAMS tours to groups, students, etc.) • Worked with several local area high school students on their science-related projects. • Participated in MSU science-related summer programs for high school students. • Gave several public lectures on science-related topics. • Co-organizer of a session at international conference (Goldschmidt Conference) in Vancouver,' Canada, 2008. 3

Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

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Page 1: Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

Summary of Notable Achievements (2005-2013)

• Author or co-author on 29 publications: 26 peer reviewed+ I in print & 2 undergoing peer review, I book chapter; additionall3 miscellaneous publications (reports, etc.).

• Received over $I,200,000 in grants: -$935,000 in competitive external funding (DOE & NSF); $3I4,000 in internal funding.(Provost Fund) for research projects.

• Gave I9 invited talks; 11 invitations to speak at meetings, conferences and workshops; 8 at seminars and colloquia; gave 5 uninvited conference presentations.

• Supervision (i.e., mentoring) of 2 postdoctoral associates (Drs. Hao Y an and Sonal Dey).

• Helped "put MSU on the map" of DOE funded EFRC energy centers through participation in EFree center headquartered out of Washington, DC (since 2009).

• Supervised I2 undergraduate students and 10 graduate students on thesis research projects; students routinely make presentations at MSU workshops/forums and regional and national meetings (see supplementary information).

•Successfully led the establishment of the shared X-Ray Analysis Facility in CNAS (obtained by Provost Fund).

• Successfully led an NSF-MRI acquisition of shared major instrumentation (Raman-PL spectroscopy) for faculty in CNAS & BMS.

• Was awarded beam time at synchrotron (x-ray) facilities around the world (Advanced Photon Source, Argonne Nat' I Lab; CHESS, Cornell U.; ESRF, France) through on-going proposals for beam time; frequently take along I - 2 students per visit, for 2- 3 visits per year.

• Originated cutting edge research on properties of nanophase (between atomic and microscopic scales) materials in extreme environments (e.g., under pressure-temperature-aqueous­radiation extremes) for energy applications.

• Teaching evaluations scores range from 1.06 to 1.7; overall average= 1.35

• A "red-chili-pepper hotness" ranking on RateMyProfessor.com; current score 4.3/5.

• Served on numerous university, college and department committees.

•Refereed 2+ journal manuscripts per year; reviewed- I grant proposal peryear.

• Participated in Dept. of Energy (OSR) review panel (2010); 2 days in Washington, DC+ review of multiple proposals prior to review panel workshop.

• Participation in student fairs on annual basis.

•Active participant in PAMS recruitment (e.g., provided PAMS tours to groups, students, etc.)

• Worked with several local area high school students on their science-related projects.

• Participated in MSU science-related summer programs for high school students.

• Gave several public lectures on science-related topics.

• Co-organizer of a session at international conference (Goldschmidt Conference) in Vancouver,' Canada, 2008.

3

Page 2: Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

Education: 1982-1987 1980-1982 1978-1980

Employment: 2002-present 1997-2002 1994 (Jun.­Sep.) 1992-1997

1990-1991 1987-1990

Honors and Awards:

Robert A. Mayanovic Curriculum Vitae

Dept. of Physics, Astronomy and Materials Science Missouri State University

Purdue University, Graduate School: Ph.D. (1987); M.S. (1987) in Physics. Purdue University, Undergraduate School: Upper level Physics courses. Missouri State University, B.S. (1979) in Geology.

Professor, Dept. of Physics, Astron. & Mat. Sci., Missouri State University Associate Professor, Dept. of Physics, Astron. & Mat. Sci., Missouri State Univ. W.F. James Professor of Pure and Applied Science, St. Francis Xavier Univ., Nova Scotia, Canada. Assistant Professor (Tenured 1996), Dept. of Physics and Astronomy Missouri State University. Assistant Faculty Fellow, Physics Department, University of Notre Dame. Postdoctoral Research Associate, Physics Department, Univ. of Notre Dame

P AMS Department, MSU Research Award, 2008 PAMS Department, MSU Teaching Award, 2007 Who's Who in Science and Engineering, since 2004 MSU Foundation Research Award, 2001 Hawley Medal. 1999, Mineralogical Association of Canada. Faculty Award: Excellence in Research Award, 1997, College-Natural & Applied Science, MSU. Faculty Award: Excellence in Scholarship Award, 1995, College of Natural and Applied Science, MSU. 'w.F. James Chair Appointment, June-Sept., 1994, St. Francis Xavier Univ., Antigonish, Nova Scotia, Canada. Member Sigma Pi Sigma Honorary Society.

Funded Projects: Purchase of a New Scintag XDS2000 X-Ray Diffraction System (Co-investigator) NSF­Rill, $120,000 (1993-1994)

Purchase of UHV- Scanning Tunneling Microscope (Co-investigator) NSF- RUI, $115,465 (1993-1994)

X-Ray Spectroscopy on Zinc Complexes in Fluid Inclusions (Proj. Director) MSU Faculty Research Grant, $3,670 (1995-1996)

Structure of Iron Complexes in Fluid Inclusions at Elevated Temperatures (Proj. Director) MSU Summer Faculty Fellowship-1996 $4,000

Acquisition of Spectrophotometer for Undergraduate Advanced Physics Lab (Proj. Director) NSF- ILl, $28,052 (1996-1997)

An Applied Master's Degree Program in Materials Science (Co-Director) NSF, $346,000 (1997-1999)

Studies on the Zn and Fe Chlorocomplexes in Hydrothermal Fluids Using the Diamond Anvil Cell (Proj. Director) Research Corp., $20,300 (1999-2000)

A Study of the Structure and Speciation of Iron Chloride Hydrothermal Solutions (Proj. Director) MSU'Faculty Research Grant, $7,090 (2001-2002)

Structure Studies of Rare Earth and First-row Transition Metal Ions in Aqueous Solutions at Sub- & Supercritical Conditions (Proj Dir) Research Corp, $40,066 (2001-2003)

Acquisition of a Pulsed Deposition Facility for the Synthesis of Novel Electronic

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Page 3: Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

Materials, (Co-Director), NSF, $177,000 (2003-2004) X-Ray Spectroscopic Studies of the Structure of Rare Earth Element Aqueous Ion

Complexes under Hydrothermal Conditions, (Proj. Director), NSF, $117,500 (2004-2007)

X-Ray Characterization and Analysis Facility, (Proj. Director), Missouri State Futures Initiatives, $314,000 (2007-2010)

Energy Frontier Research in Extreme Enviromnents, (H. Mao-Director; Mayanovic PI MSU-Cornell group), DOE-EFRC, $425,000 (2009-2014).

MRI-Rill: Acquisition of a Micro-Raman-Photoluminescence Instrument for Materials­Related Research & Education, NSF-MRI, $392,000 (2011-2013)

Undergraduate 28 students from 1992 to present (list of student presentations in Supporting Materials).

Research Advising: Graduate Advising: 13 students from 1997 to present (list of student presentations in Supporting Materials).

Postdocs: Sumedha Jayanetti, 2000-2002. Presently: Professor, Physics Dept., Colombo U., Sri Lanka Hao Yan, 2010-2013. Presently: Research Scientist, HPSTAR Center, Shanghai, China Sonal Dey, (will start Jan. 2014)

Professional Interests Synchrotron x-ray studies of condensed matter; materials in supercritical fluids, high pressure-temperature studies, mineral physics.

Invited Talks:

Ultrasonic Studies of Bonding and Exchange Interactions in Zn,Mn1.,Se and Cd,Mn1_,Te. Solid State Seminar, Purdue University, W. Lafayette, IN, September, I987.

Attenuation of Ultrasound Due to Mn 2+ Spins in Zn,Mn1_,Se and Cd,Mn1.,Te at Low Temperatures. Solid State Seminar, University of Notre Dame, Notre Dame, IN, October, I987.

Polarization-Dependent Total-Reflection EXAFS Studies of Premelting at Cu/Al203 Interfaces. Solid State

Seminar, University of Notre Dame, Notre Dame, IN, April, 1991. Premelting at Interfaces: Polarization-Dependent Total-Reflection EXAFS Studies of the Cu/Al,03 System.

Department of Physics Colloquium, Louisiana State University, Baton Rouge, LA, April, 1991. Polarization-Dependent Total-Reflection EXAFS Studies of Premelting at Cu/Al20 3 Interfaces. Department of

Physics and Astronomy Colloquium, Missouri State University, November, 1991. X-Ray Absorption Fine Structure Studies of Premelting at Cui Al20 3 Interfacial Regions. Department of Geological

Sciences Seminar, Virginia Polytechnic institute and State Univ., Blacksburgh, VA, March, 1993. Structure Determination of Metal Complexes in Fluid Inclusions Using Synchrotron X-Ray Absorption

Spectroscopy. Department of Geology Seminar, St. Francis Xavier University, Antigonish, NS, August, 1994. Structure of Metal Complexes in Fluid Inclusions. National Synchrotron Light Source Seminar, Brookhaven

National Lob, Upton, NY, September, 1995. Physics Applications in Other Sciences: A Discussion of Differing Perspectives. Missouri Academy of Sciences

1997 Annual Meeting, Warrensburg, MO, April, 1997. How the Structure of the DNA Molecule Was Solved. Joint Spring Banquet of the Ozark Section ACS and Sigma XI,

Springfield, MO, May, 1997. X-ray Absorption Measurements of Transition Metal Complexes in Fluid Inclusions up to 500 °C. Geochemistry

Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring Under Hydrothermal Conditions in Fluid

Inclusions. American Chemical Society Symposium: Applications of Synchrotron X-Rays in Earth and Environmental Sciences, ACS Meeting, Las Vegas, NV, September, 1997.

Can Synchrotron X-Ray Absorption Measurements on Metal Ion Complexes in Fluid Inclusions Lead· to Observations on the Fundamental Properties of Supercritical Water? Department of Physics and Astronomy Colloqium, Missouri State University, Springfield, MO, October, 1997.

Structure Studies of Coordinated Metal Ions in Sub- and Supercritical Aqueous Solutions Department of Physics Solid State Seminar, University of Notre Dame, Notre Dame, IN, July, 1998.

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An XAFS Study of the Structure of Chlorozinc(II) Complexes in Aqueous Solutions from Ambient to Supercritical Conditions using a Novel Diamond Anvil Cell International Union of Crystallography- High Pressure Conference, Argonne National Laboratory, Argonne, /L, November, 1998.

XAFS Measurements on Zinc Halide Aqueous Solutions at up to Supercritical Conditions using the Diamond Anvil Cell Cornell High Energy Synchrotron Source Seminar, Cornell University, Ithaca, NY, May, 1999.

Evidence for dehydration of zinc halide complexes from XAFS measurements on zinc bromide and zinc chloride aqueous solutions at up to 500 'C and elevated pressures using a hydrothermal diamond anvil cell. William A. Bassett Symposium, American Geophysical Union Meeting, Washington, DC, May, 2000.

Solvation of Inorganic Metal Ion Complexes under Hydrothermal Conditions: Novel Results from X-Ray Absorption Analysis. American Chemical Society 2001 Meeting, San Diego, CA, April, 2001

Studies of Solvation of Inorganic Metal Ion Complexes under Hydrothermal Conditions Using XAFS Spectroscopy [Keynote Presentation], V.M. Goldschmidt Conference, Hot Springs, VA, May, 2001.

Getting Into Hot Water: Studies of Solvation of Ions in Hydrothermal Solutions. MSU Spring Research Showcase, 2001 University Foundation Award Lecture, Springfield, MO, April, 2002.

Structure of Metal Ion Complexes in Aqueous Solutions at High Temperatures and Pressures. Dept. of Physics, Astronomy & Material Science Colloquium, SMSU, Springfield, MO, May, 2002.

Studies of Solvated Complex Ions in Supercritical Solutions. Seminar for Wiley High School (Wiley, Texas) Science Visitation to MSU, Springfield, MO, June, 2004.

Growth of Metal Nanoparticles and Ion Association in Aqueous Solutions. Dept. of Physics, Astronomy & Material Science Colloquium, MSU, Springfield, MO, March, 2005.

Studies of Metal Nanoparticles, High-Temperature Aqueous Fluids and Silicate Melts Using Primarily Synchrotron X-Ray Spectroscopy. Chemistry Dept. Seminar, Missouri State U., Springfield, MO, March, 2006.

X-ray spectroscopic investigations ofNh partitioning from a silicate melt in contact with an aqueous fluid. Geological Association of Canada-Mineralogical Association of Canada Annual Meeting, Montreal, Canada, May, 2006.

Synchrotron X-ray spectroscopic investigations of an Nh-bearing silicate melt in contact with an aqueous fluid. American Geophysical Union Meeting, Baltimore, MD, May, 2006.

The structure of REE aqua and chloroaqua complexes in hydrothermal fluids. V.M. Goldschmidt Conference, Cologne, Germany, August, 2007.

High P-T x-ray spectroscopic studies of oxides, glasses and inorganic metal complexes in supercritical aqueous fluids. High Pressure Synchrotron Science Workshop, Argonne National Laboratory, May, 2009.

In situ analysis of materials in supercritical aqueous fluids. EFree Center Annual Meeting, Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC, September, 2009. ·

In situ high P-T x-ray spectroscopic studies of materials in supercritical aqueous fluids. Advanced Photon Source Users Science Seminar, Argonne National Laboratory, October, 2009.

Metal ion adsorption on Fe30 4 nanoparticles in supercritical aqueous fluids, EFree Highlight Presentation, Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC, July, 2010.

In situ investigations of materials and solutes in supercritical aqueous fluids. EFree Center Annual Meeting, Gepphysical Laboratory, Carnegie Institution of Washington, Washington, DC, September, 2010.

In situ XAS investigations of the adsorption of metal ions on metal oxide nanoparticles in aqueous fluids to 500 'C. The International Chemical Congress of the Pacific Basin Societies (PACIFICHEM), Honolulu, HI, December, 2010.

A kinetic study of synchrotron x-ray induced radiolysis effects on Fe2+ and Fe3

+ ions in aqueous fluids to supercritical conditions. Workshop: Dynamic Phenomena under Extremes, Austin, TX, January, 201 I.

Investigations of materials and solutes under extremes of temperature and pressure in aqueous fluids. Condensed Matter Seminar, Dept. of Physics and Astronomy, University of Missouri, Columbia, MO, Apri/6, 201 I.

The structural environment of Nb and Ta in aluminosilicate glasses and melts in aqueous fluids. EFree Center Annual Meeting, Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC, September, 201 I.

Reactivity offerrite nanoparticles with 3d metal ions in high-temperature aqueous fluids, EFree Highlight Presentation, Geophysical Laboratory, f:arnegie Institution of Washington, Washington, DC, January, 2012.

Investigations of materials for energy applications in aqueous fluids to supercritical conditions. EFree Center Annual Meeting, Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC, September, 2012.

6

Page 5: Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

Meeting our Future Energy Needs: Materials under Extreme Environments, College of Natural and Applied Science Public Lecture, Missouri State University, Springfield, MO, October, 2012.

In situ synchrotron investigations of the stability of mesoporous materials under extreme conditions. Study of Matter at Extreme Conditions (SMEC) 2013 Conference, Miami, Fir East Carribean, March 23-30, 2013.

Investigations of nanophase materials for energy applications under extreme conditions. 4'' Annual NanoFrontiers Symposium 2013, Columbia, MO, June 6-7, 2013.

Conference Presentations:

Ultrasonic Determination of Elastic Constants in Z11o.47M11o.53Se: Structural, Piezoelectric, and Magnetic Effects. American Physical Society, Las Vegas, NM, March 1986.

Bonding and Exchange in Zn,Mn1.,Se. 34th Midwest Solid State Conference, St. Louis, MO, October, 1986.

Ultrasonic Attenuation in a Diluted Magnetic Semiconductor: Zn,Mn1_,Se. American Physical Society, New York, NY, March 1987.

Ultrasonic Attenuation in Zn,Mn1.,Se and Cd,Mn1.,Te. 35th Midwest Solid State Conference, Notre Dame, IN, September, 1987.

EXAFS Study of Zn,Mn1.,S: Comparison of Local Structure of Zn,Mn1_,S and Zn,Mn1.,Se. American Physical Society, St. Louis, MO, March 1989.

EXAFS Study of Melting in Hg, American Physical Society, Anaheim, CA, March, 1990.

Glancing-Angle XAFS Studies of 'Premelting' at Cui AI,03 Interfacial Regions. American Physical Society, Cincinnati, OH, March, 1991.

Local Structure Surrounding Implanted As Ions in Polysulfone Films. Materials Research Society Fall Meeting, Boston, MA, November, 1993.

Micro-XAFS Investigations of Metal Complexes in Individual Fluid Inclusions. Synchrotron Radiation Instrumentation '94 Workshops, Stony Brook, NY, July, 1994.

Glancing Angle XAFS and X-Ray Reflectivity Study of Cu Thermal Vibration Amplitudes at the Cu-Al20 3 Interface. 8th International Conference on X-Ray Absorption Fine Structure, Berlin, Germany, August; 1994.

Development of Micro-XAFS: Applications to Studies of Single Fluid Inclusions. 8th International Conference on X-Ray Absorption Fine Structure, Berlin, Germany, August, 1994.

A Micro-XAFS Study of Zinc Chloride Complexing in Individual Fluid Inclusions at Elevated Temperatures. Synchrotron Radiation Instrumentation '95 Workshops, Brookhaven National Lab, NY, July, 1995 (in absentia).

Microbeam XAFS Investigations on Fluid Inclusions. Materials Research Society Spring Meeting, San Francisco, CA, April, 1996.

Investigations on Fe Lattice Strain Relaxation in the Al!Fe/ AI Trilayer. · Materials Research Society Spring Meeting, San Francisco, CA, April, 1996,

Micro beam XAFS Studies on Fluid Inclusions. Missouri Academy of Science 1996 Annual Meeting, Springfield MO, April, 1996,

Microbeam XAFS Studies on Fluid Inclusions at High Temperatures. 9th International Conference on X-Ray Absorption Fine Structure, Grenoble, France, August, 1996.

Micro-beam XAFS Studies on Fluid Inclusions Under Hydrothermal Conditions. 14th European Current Research on Fluid Inclusions Meeting, Nancy, France, July, 1997.

XAFS Measurements on Zinc Chloride Aqueous Solutions from Ambient to Supercritical Conditions using the Diamond Anvil Cell. lOth Inter. Conference on X-Ray Absorption Fine Structure, Chicago, IL, August, /998.

An XAFS study of the structure of chlorozinc(II) complexes in aqueous solutions from ambient to supercritical conditions using a novel diamond anvil cell. Workshop on Synchrotron, Neutron and Laboratqry Source Crystallography at High Pressure, Argonne National Lab, Argonne, IL, November, 1998.

XAFS Investigations of Aqueous Zinc Halide Solutions up to Supercritical Conditions. I 3th International Conference on Properties of Water and Steam, Toronto, Canada, September, 1999.

Comparison Between Yb3+ and Y3+ Ion Association with the Cl- Ion in Hydrothermal Solutions: Evidence From

XAFS Measurements on Rare Earth Aqueous Solutions at up to 500 oc and 270 MPa. American Geophysical Union Meeting, Washington, DC, May, 2002.

7

Page 6: Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

X-Ray Spectroscopic Investigations ofY3+ and the Lanthanide Ions La3+ and Yb3+ in Hydrothermal Solutions at up to 500 oc and 270 MPa. American Geophysical Union Meeting. Montreal, Canada, May, 2004.

The structure of Gd3+ aqua and chloro complexes under hydrothermal conditions. V.M. Goldschmidt Conference, Moscow, ID, May, 2005.

Use of the hydrothermal diamond-anvil cell for x-ray spectroscopic studies of metal ion complexes, hydrothermal leaching and element partitioning at elevated temperatures and pressures. Geological Society of America Annual Meeting, Salt Lake City, UT, October, 2005.

REB-chloride complexing in hydrothermal fluids with new data on lanthanum chloroaqua complexes. V.M. Goldschmidt Co1;rence, Vancouver 2008, BC, Canada, July, 2008.

In situ XAS study of Zn +and Ni2+ adsorption on Fe,04 nanoparticles in supercritical aqueous fluids, V.M. Goldschmidt Conference 20!0, Knoxville, TN, June, 20!0.

Experimental investigations of the structural environment of metal (Nh, Ta) ions in silicate glass-water systems to high P-T conditions, V.M. Goldschmidt Conference 20!2, Montreal, Canada, June, 20!2.

Publications : Book Chapters

A.J. Anderson and R.A. Mayanovic, Electron, nuclear and X-ray probe microanalysis of fluid inclusions. In Fluid Inclusions: Analysis and Interpretation, I. Samson, A. Anderson and D. Marshal, eds., Mineralogical Association of Canada Vol. 32 (2003) pp 323-351.

W.A. Bassett, I.-M. Chou, A.J. Anderson, and R.A. Mayanovic, Aqueous chemistry in the diamond anvil cell up to and beyond the critical point of water. In Chemistry at Extreme Conditions, M. R. Manaa, ed. (Elsevier, 2005) pp 223-240.

Publications in Journals: (student names in bold & underlined!

H. Yan, R.A. Mayanovic, J. Dernster and Alan J. Anderson. In situ monitoring of the adsorption of Co2+ on the · surface ofFe30 4 nanoparticles in high-temperature aqueous fluids, J. Supercrit. Fluids 81, 175-182 (2013).

D. Antonangeli, V. Dmitriev, Y. Filinchuk, M. Hanfland, M. Hazemann, M. Krisch, R. Mayanovic, M. Mezouar, G. Monaco, S. Pascarelli, R. RUffer, D. Testemale, R. Torchio, Science under extreme conditions of pressures and temperatures at the ESRF, Synchrotron Rad. News 26, 39-44 (2013)

R.A. Mayanovic, H. Yan, A.J. Anderson, G. Solferino, Investigation of the structural enviromnent of Ta in a silicate glass and water system under high P-T conditions; J. Non-Crystal. Solids 368, 71-78 (2013).

P.A. McCart, L. Farris, R.A. Mayanovic, H. Yan, Investigations of Ti02 minoparticles surface-doped with Eu in aqueous fluids to high P-T conditions, MRS Proceedings, 1582, http://dx.doi.org/l 0.1557/ op1.2013.ll41.

A.J. Anderson, H. Yan, R.A. Mayattovic, G. Solferino, C. Benmore, High energy X-ray diffraction of a silicate melt­H20 system under conditions of high pressure and temperature in a modified hydrothermal diamond anvil cell, High Pressure Res. (in print).

S. Men, A.J. Anderson, R.A. Mayanovic, In situ X-ray absorption spectroscopy study ofradiolysis-induced redox in chromium nitrate aqueous solutions under supercritical condition, 2014 Canada China Conference on Advanced Reactor Development Proceedings (submitted).

R.A. Mayanovic, H. Yan, A.D. Brandt, Z. Wang, M. Mandai, K. Landskron, W.A. Bassett, Mechanical and Hydrothermal Stability of Mesoporous Materials at Extreme Conditions, (submitted).

R.A. Mayanovic, A.J. Anderson, M. Luna, G. Solferino, H. Yan, Experimental investigations of the structural environment of metal (Nh, Ta) ions in silicate glass-water systems to high P-T conditions, Mineral. Mag. 76(6), 2081 (2012).

R.A. Mayanovic, H. Yan, A.J. Anderson, P.R. Meredith, W.A. Bassett, In situ x-ray absorption spectroscopic study of the adsorption ofNi2+ on Fe30 4 nanoparticles in supercritical aqueous fluids. J. Phys. Chern. C 116, 2218-2225 (2012)

H. Yan, R.A. Mayanovic, J. Dernster and Alan J. Anderson (20 12). In situ XANES Study of Co2+ Ion Adsorption on Fe304 Nanoparticles in Supercritical Aqueous Fluids. MRS Proceedings, 1383, mrsfll-1383-a0?-1 0 doi: I 0.1557/opl.2012.183

R.A. Mayanovic, H.A.N. Dharmagunawardllane, A.J. Anderson, S. Pascarelli, G. Aquilanti, Monitoring synchrotron x-ray-induced radiolysis effects on metal (Fe, W) ions in high temperature aqueous fluids, J. Synchrotron Rad. 19, 797-805 (2012).

8

Page 7: Summary of Notable Achievements (2005-2013) · Geochemistry Seminar, GeoForschungsZentrum, Potsdam, Germany, June, 1997. Bond Contraction in Iron(II) and Zinc Chloride Complexes Occurring

H. Yan, R.A. Mayanovic, A.J. Anderson, P.R. Meredith, An in situ x-ray spectroscopic study ofMo6+ speciation in

supercritical aqueous solutions. Nucl. Instr. Methods Phys. Res. A, 649, 207 (2011). P.R. Meredith, A.J. Anderson, R.A. Mayanovic, An in-situ investigation of the solubility of molybdenum trioxide in

oxygenated water at supercritical conditions. Proceedings of the 5th International Symposium on Supercritical Water -Cooled Reactors, Vancouver, Canada, 20 II , P04 7.

A.J. Anderson, R.A. Mayanovic, M.R. Frank, S. Pascarelli, Monitoring beam-induced radiolysis effects on transition metal complexes in hydrothermal fluids, Mineral. Mag. 75(3), 435 (2011).

A.J. Anderson, P.R. Meredith, W.A. Bassett, R.A. Mayanovic, C. Benmore, The design and application of a new Bassett-type diamond anvil cell for spectroscopic analysis of supercritical aqueous solutions, Proceedings of the CNS 2nd Canada-China Joint Workshop on SuperCritical Water-Cooled Reactors (SCWR), Toronto, Ontario, Canada, April 25-28 (2010) ISBN# 0-919784-98-4. 7pp.

H.A.N. Dharmagunawardhane, R.A. Mayanovic, A.J. Anderson, W.A. Bassett, S. Pascarelli, Rate kinetics of synchrotron radiation-induced radiolysis ofFe2

+ and Fe3+ ions in aqueous solutions to 500 °C. Geochim.

Cosmochim. Acta 74(12), A230 (2010). R.A. Mayanovic, A.J: Anderson, P.R. Meredith, W.A. Bassett, In situ XAS study of Zn2

+ and Ni2+ adsorption on

Fe30 4 nanoparticles in supercritical aqueous fluids. Geochim. Cosmochim. Acta 74(12), A681 (2010). R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and 1.-M. Chou, The structure and stability of aqueous rare-earth

elements in hydrothermal fluids: New results on neodymium(III) aqua and chloroaqua complexes in aqueous solutions to 500 oc and 520 MPa. Chern. Geol. 259, 30-38 (2009).

K. Mibe, I-M. Chou, A.J. Anderson, R.A. Mayanovic, and W.A. Bassett, The speciation and structure of aqueous zinc bromide solutions to 500 oc and 900 MPa. Chern. Geol. 259, 48-53 (2009).

K.N. Dalby, A.J. Anderson, AN. Mariano, R.A. Gordon, and R.A. Mayanovic, A micro-X-ray spectroscopic investigation of CL colors in albite from the Georgeville granite, Nova Scotia. Geochim. Cosmochim. Acta 73(13), A259 (2009).

K.N. Dalby, A.J. Anderson, T. Mariano,.R. Gordon, R.A. Mayanovic, and R. Wirth, Late stage Fe-enrichment in alkali feldspars from the Georgeville Granite: Insights from CL, XEOL and microprobe analysis, Lithos 114, . 86-94 (2009).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and 1.-M. Chou, Steric hindrance and the enhanced stability of light rare-earth elements in hydrothermal fluids, Am. Mineral. 94, 1487-1490 (2009).

I-M. Chou, W.A. Bassett, A.J. Anderson, R.A. Mayanovic, and L. Shang, Containment of fluid samples in the hydrothermal diamond-anvil cell without the use of metal gaskets: advantages for in situ analysis. Rev. Sci. Instr. 79,115103:1-4 (2008).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, REE-chloride complexing in hydrothermal fluids with new data on lanthanum chloroaqua complexes. Geochim. Cosmochim. Acta 72(12), A607 (2008).

K. Mibe, I-M. Chou, A.J. Anderson, R.A. Mayanovic, and W.A. Bassett, In-situ Raman spectroscopic investigation of the structure and speciation of aqueous zinc bromide solutions to 500 oc and 0.9 GPa. Geo. Cosmochim. Acta 72(12), A624 (2008).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and 1.-M. Chou, On the formation and structure of rare-earth element complexes in aqueous solutions under hydrothermal conditions with new data on gadolinium aqua and chloro complexes. Chern. Geol. 239, 266-283 (2007).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, The structure of REE aqua and chloroaqua complexes in hydrothermal fluids. Geochim. Cosmochim. Acta 71(15), A642 (2007).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I.-M. Chou, Spectroscopic studies ofEu!HN03 aqueous solutions at high temperatures and pressures and Nb-bearing silicate melt phases coexisting with hydrothermal fluids by improved mounting of a modified hydrothermal diamond anvil cell. Rev. Sci. Instr. 78, 053904:1-9 (2007).

A.J. Anderson, R.A. Mayanovic, W.A. Bassett, and I-M. Chou, X-Ray microspectroscopic analyses of mineral-fluid and melt-fluid interactions at extreme temperatures and pressures. Geochim. Cosmochim. Acta 69(10), A52 (2005).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, The structure of Gd3+ aqua and chloro complexes

under hydrothermal conditions. Geochim. Cosmochim. Acta 69(1 0), A662 (2005). R.A. Mayanovic, S. Jayanetti, A.J. Anderson, W.A. Bassett, and I.-M. Chou, Relaxation of the structure of simple

metal ion complexes in aqueous solutions at up to supercritical conditions. J. Chern. Phys. 118, 719-727 (2003).

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A.J. Anderson, S. Jayanetti, R.A. Mayanovic, W.A. Bassett, and I.-M. Chou, X-ray spectroscopic investigations of hydrothermal fluids in the diamond anvil cell: The hydration structure of aqueous La3+ up to 300 oc and 1600 bars. Am. Mineral. 87, 262-268 (2002).

R.A. Mayanovic, S. Jayanetti, A.J. Anderson, W.A. Bassett, & I-M. Chou, The structure of Yb3+ and Y3+ aquo ion

and chloro complexes in hydrothermal solutions. Geochim. Cosmochim. Acta 66, A496 (2002). R.A. Mayanovic, S. Jayanetti, A.J. Anderson, W.A. Bassett, and I.-M. Chou, The structure ofYb3

+ aquo ion and chloro complexes in aqueous solutions at up to 500 oc and 270 MPa. J. Phys. Chern. A 106, 6591-6599 (2002).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I.-M. Chou, Hydrogen bond breaking in aqueous .solutions near the critical point. Chern. Phys. Lett. 336,212-218 (2001).

S. Jayanetti, R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I.-M. Chou, Analysis of radiation-induced small Cu particle cluster formation in aqueous CuCI2• J. Chern. Phys. 115, 954-962 (200 I).

W.A. Bassett, A.J. Anderson, R.A. Mayanovic, and I.-M. Chou, Hydrothermal diamond anvil cell for XAFS studies of first-row transition elements in aqueous solutions up to supercritical conditions. Chern. Geol. 167, 3-10 (2000).

A.J. Anderson,R.A. Mayanovic, W.A. Bassett, and I.-M. Chou, XAFS investigations of aqueous zinc halide solutions up to supercritical conditions. in Steam, Water, and Hydrothermal Systems: Physics and Chemistry Meeting the Needs oflndustry, Eds. P.R. Tremaine eta!., (NRC Research Press, Ottawa, 2000) pp 599-606.

W.A. Bassett, A.J. Anderson, R.A. Mayanovic, and I.-M. Chou, Modified hydrothermal diamond anvil cells for XAFS analyses of elements with low energy absorption edges in aqueous solutions at sub- and supercritical conditions, Zeit. Krystal. 215,711-717 (2000).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I.-M. Chou, XAFS measurements on zinc chloride aqueous solutions from ambient to supercritical conditions using the diamond anvil cell. J. Synchr. Rad. 6, 195-197 (1999).

A.J. Anderson, R.A. Mayanovic, and S. Bajt, A Miero-XAFS study of aqueous chlorozinc complexing up to 430 oc in saline fluid inclusions from a high-level granitic pegmatite, Can. Mineral. 36, 511-524 (1998).

A.J. Anderson, R.A. Mayanovic, and I.M. Chou, Micro-beam XAFS measurements of zinc complexes in highly saline fluid inclusions to 400 'C before and after experimental re-equilibration at high hydrogen pressure. Goldschmidt Conf., France. Mineral. Mag. 62A, 55 (1998).

R.A. Mayanovic, A.J. Anderson, and S. Bajt, Microbeam XAFS studies on fluid inclusions at high temperatures. J. Phys. N France 7, C2-1029 (1997).

W.F. Pong, R.A. Mayanovic, Z.Q. Kao, H.H. Hsieh, J.Y. Pieh, Y.K. Chang, K.C. Kuo, P.K. Tseng, J.F. Lee, XAFS studies of diluted magnetic semiconductors Zn1_,M,S (M = Mn, Co). J. Phys. N France 7, C2-1147 (1997).

W.F. Pong, R.A. Mayanovic, Z.Q. Kao, H.H. Hsieh, J.Y. Pieh, Y.K. Chang, K.C. Kuo, P.K. Tseng, J.F. Lee Observations on the degree of p-d hybridization in Zn1_,Mn,Y (Y = S, Se) and Zn1_,Co,S alloys as studied by x-ray absorption spectroscopy, Phys. Rev. B 55, 7633 (1997).

C. J. Gutierrez, R. Selestino, R.A. Mayanovic, and G. Prinz, Evidence for loose spins in epitaxial Al/Fe/Al. J. Appl. Phys. 81, 5352 (1997).

B.A. Bunker, A.J. Kropf, K.M. Kemner, R.A. Mayanovic, and Q. Lu, XAFS and x-ray reflectivity studies of buried interfaces, Nucl. Inst. Meth. Phys. Res. B 133, 102 (1997).

R.A. Mayanovic and A.J. Anderson, Microcbeam XAFS studies on fluid inclusions under hydrothermal conditions. Proceedings of the 14th European Current Research on Fluid Inclusions (Nancy, France), M.C. Boiron and J. Pironon, Eds., pp 203-204 (1997).

A.J. Anderson, R.A. Mayanovic,_ I. Horn, S. Jackson, and R. Thomas, Element partitioning and ore-metal transport in a two-phase hydrothermal system: Evidence from fluid inclusions in pegmatites and associated polymetallic sulfide veins in the Saxonian Granulite Massif, Germany. Proceedings of the 14th European Current Research on Fluid Inclusions (Nancy, France), M.C. Boiron and J. Pironon, Eds., pp 4-5 (1997).

W.F. Pong, Y.K. Chang, R.A. Mayanovic, G.H. Ho, H.J. Lin, S.H. Ko, P.K. Tseng, C.T. Chen, A. Hiraya, M. Watanabe, Si K and Co L3 XANES study of thin-film CoSh, J. Electron Spectrosc. Relat. Phenom. 78, 107 (1996).

W.F. Pong, Y.K. Chang, R.A. Mayanovic, G.H. Ho, H.J. Lin, S.H. Ko, P.K. Tseng, C.T. Chen, A. Hiraya, M. Watanabe, X-Ray Absorption Spectroscopy ofCoSi2, Phys. Rev. B 53, 16510 (1996).

R.A. Mayanovic, A.J. Anderson, and S. Bajt, Microbeam XAFS investigations on fluid inclusions. Mat. Res. Soc. Symp. Proc. 437,201-206 (1996).

R.A. Mayanovic, C. J. Gutierrez, and G. Prinz, Investigations on Fe lattice strain relaxation in the Al/Fe/Al trilayer. Mat. Res. Soc. Symp. Proc. 437, 27-31 (1996).

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R.A. Mayanovic, Q. Lu, B.A. Bunker, A.J. Kropf, and J.R. Buscher!, Glancing angle XAFS and x-ray reflectivity study ofCu thermal vibration amplitudes at the Cu-Al20 3 interface, Physica B 208 & 209,405 (1995).

R.A. Mayanovic, A.J. Anderson, and S. Bajt, Development of micro-XAFS: Applications to studies of single fluid inclusions, Physica B 208 & 209, 239 (1995),

R.A. Mayanovic, and B.A. Bunker, Observation of anisotropy in Cu-Cu atom vibrational amplitudes due to thermal motion at a Cu-Al20 3 interface, Phys. Lett. A 202, 225 (1995).

A.J. Anderson, R.A. Mayanovic, and S. Bajt, Determination of the local structure and speciation of zinc complexes in individual fluid inclusions by Micro-XAFS, Can. Min. 33, 499 (1995).

W.F. Pong, R.A. Mayanovic, K.T. Wu, P.K. Tseng, B.A. Bunker, A. Hiraya, and M. Watanabe, Influence of transition metal type and content on local order properties of Zn1., Y ,S (Y = Mn, Fe, Co) alloys studied using XANES spectroscopy, Phys. Rev. B. SO, 7371 (1994).

R.A. Mayanovic, Y. Feng, K.W. Groh, Y. Wang, R.E. Giedd, and M.G. Moss, Local structure surrounding implanted As ions in polysulfone films, Mat. Res. Soc. Symp. Proc. 321, 113 (1994).

Z. Wang, R.A. Mayanovic, B.A. Bunker, and J.K. Furdyna, XAFS study of the ferroelectric phase transition in II­VI and IV-VI semiconductors,· Jpn. J. Appl. Phys. 32, 673 (1993).

W.F. Pong, R.A. Mayanovic, K.T. Wu, P.K. Tseng, B.A. Bunker, A. Hiraya, and M. Watanabe, X-ray absorption near edge structure (XANES) studies of diluted magnetic semiconductor (DMS) Zn1.,Y,S (Y= Mn, Fe, Co) systems, Jpn. J. Appl. Phys. 32, 722 (1993).

R.A. Mayanovic, Local order and bonding primarily using EXAFS and SEXAFS (Invited Review), Crit. Rev. Suif. Chern. 2, 63-90 (1993).

S. Gaarenstroom, R.A. Anderson, R.J. Baird, P.L. Coduti, M. Liehr, R.A. Mayanovic, G.C. Nelson, C.J. Powell, P.M.A. Sherwood, and M.J. Zaluzec, Interfacial microchemical characterization needs in surface processing, Crit. Rev. Surf. Chern. 3, 1-12 (1993).

z. Wang, B.A. Bunker, R.A. Mayanovic, U. Debska, J.K. Furdyna, and Q. Islam, EXAFS studies of the ferroelectric phase transitions induced by off-center ions in PbS,Te1., and Zn,Cd1.,Te alloys, Mod. Phys. Lett. B 6, 1413 (1992).

K.M, Kemner, Z. Wang, R.A. Mayanovic, and B.A. Bunker, A low temperature gas-glow total electron yield detector for EXAFS, Nucl. Instr. Meth. B 71, 345 (1992).

W.-F. Pong, R.A. Mayanovic, B.A. Bunker, J.K. Furdyna, and U. Debska, Extended x-ray absorption fine structure studies of Zn,Mn1.,Se alloy structure, Phys. Rev. B 41, 8440 (1990).

R.A. Mayanovic, W.-F. Pong, and B.A. Bunker, EXAFS studies ofHg,Cd1.,Te and Hg,Mn,_,Te bond lengths: bond relaxation and structural stability of ternary alloys, Phys. Rev. B 42, 11174 (1990).

W.-F. Pong, R.A. Mayanovic, and B.A. Bunker, Bond lengths in Hg,Cd1.,Te and II-VI diluted magnetic semiconductors, Physica B 158, 617 (1989).

R.A. Mayanovic, R.J. Sladek, and U. Debska, Elastic constants of Zn,Mn1.,Se: Tetrahedral bond weakening due to Mn 3d(t2)-Se 4p hybridization, Phys. Rev. B 38, 1311 (1988).

R.A. Mayanovic, R.J. Sladek, and U. Debska, Ultrasonic attenuation Due to Mn 2+ Spins in Zn,Mn1.,Se and Cd,Mn1.,Te at low temperatures, Phys. Rev. B 38,2787 (1988).

R.A. Mayanovic, R.J. Sladek, and U. Debska, Ultrasonic propagation-time measurements in Zn,Mn1.,Se down to low temperatures: Shear wave anomalies and the spin glass transition, Phys. Rev. B 38,5530 (1988).

R.A. Mayanovic, R.J. Sladek, and U. Debska, Bonding and exchange interactions in Zn,Mn1.,Se, Proceedings of the 18th International Conference on Physics of Semiconductors, Ed., 0. Engstrom, World Scientific, Singapore, 1755 (1987).

P. Maheswaranathan, R. Mayanovic, R.J. Sladek, and U. Debska, Elastic anomalies near the magnetic transition in Cd,Mn1.,Te, J. Magn. Magn. Mat 54-57, 1225 (1986).

R.A. Mayanovic, G.F. Giuliani, and J.J. Quinn, Plasmons in semiconducting superlattices with a complex unit cell, Phys. Rev. B 33, 8390 (1986).

Reports and Other Publications: (student names in bold & underlined!

L. Farris, H. Yan, P. McCart, R.A. Mayanovic, The vibrational and photoluminescence properties of Ti02

nanoparticles reacted with Eu3+ ions under hydrothermal conditions, Bul. Am. Phys. Soc. 58(1) (2013) http://meetings.aps.org/link/BAPS.2013.MAR.G20.3.

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, High P-T x-ray spectroscopic studies of oxides, glasses and inorganic metal complexes in aqueous fluids. High Pressure Synchrotron Science Workshop 2009 Abstract Book, p. 16 (2009), http:i/cdac.gl.ciw.edu/contenUview/26011/.

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K. Dalby, A.J. Anderson, R.A. Gordon, and R.A. Mayanovic, A multi-technique characterization of geological materials: A study of the Georgeville granite feldspar. Canadian Light Source II th Annual Users' Meeting, June 9-10, Saskatoon, Canada, Abstract #37 (2008).

K. Dalby, A.J. Anderson, R.A. Gordon, and R.A. Mayanovic, Interrogation of geologic materials using micro-scale synchrotron-based techniques: A study of the George ville granite feldspar. http://www.pnc.aps.anl.gov/ public/RAG/EGP-review/KND_forYNC20x40.pdf (2008).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, Rare earth element complexing with chloride in hydrothermal solutions: New data on Lanthanum chloroaqua complexes to 500 "C and 230 MPa, APS Scientific Advisory Committee Cross-cut Review of Atomic, Molecular, Optical, and Chemical Science, Argonne National Laboratory, IL, Nov. 2008.

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, Synchrotron X-Ray spectroscopic investigations of an Nb-bearing silicate melt in contact with an aqueous fluid. Eos Trans. AGU, 87(36) V43D-04 (2006).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, I-M. Chou, (2005) X-ray spectroscopic investigations ofNb partitioning from a silicate melt in contact with an aqueous fluid. (GAC/MAC Meeting 2006) GAC/MAC Abstracts, 31, 98 (2006).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, 1-M. Chou, and A.J. Layman, Use of the hydrothermal diamond­anvil cell for x-ray spectroscopic studies of metal ion complexes, hydrothermal leaching and element partitioning at elevated temperatures and pressures. (GSA Meeting 2005) GSA Abstracts with Programs, 37(7), 270 (2005).

J.M. Rinck, R.A. Mayanovic, A.J. Anderson, W.A. Bassett, 1-M. Chou, and A. Layman, The structure surrounding Nb in a hydrous Nb-bearing silicate melt at elevated temperatures and pressures, 16th Annual ANL Symposium for Undergraduates in Science, Mathematics and Engineering, http://www.dep.anl.gov/ p_undergradlugsymp/Final2005Master AbstractsForBook.htm (2005).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and 1-M. Chou, X-Ray Spectroscopic Investigations ofY3+ and the

Lanthanide Ions La3+ and Yb3+ in Hydrothermal Solutions at up to 500 "C and 270 MPa. Eos Trans. AGU, 85(17), VllB-05 (2004).

A.J. Anderson, W.A. Bassett, and I-M. Chou, R.A. Mayanovic, M. Newville, S. Sutton, Monitoring hydrothermal leaching of metamict zircon at elevated temperatures and pressures using synchrotron x-ray fluorescence. Eos Trans. AGU, 85(17), V21C-07 (2004).

R:A. Mayanovic, A.J. Anderson, W.A. Bassett, and I.M. Chou, X-Ray spectroscopic investigations of scandium chloride aqueous solutions using the hydrothermal diamond anvil cell. Advanced Photon Source Activity Report 2003, (Argonne National Laboratory, Argonne, IL; ANL-04/16, 2004).

A.J. Anderson, W.A. Bassett, and 1-M. Chou, R.A. Mayanovic, M. Newville, S. Sutton, In situ monitoring of hydrothermal leaching from metamict zircon by using synchrotron x-ray fluorescence. Advanced Photon Source Activity Report 2002, (Argonne National Laboratory, Argonne, IL; ANL-03/21, 2003).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and 1-M. Chou, XAFS investigations oflanthanide.chloride solutions at hydrothermal conditions. Advanced Photon Source Activity Report 2002, (Argonne National Laboratory, Argonne, IL; ANL-03/21, 2003).

A.J. Anderson, R.A. Mayanovic, S. Jayanetti, W.A. Bassett, and I.M. Chou, StructureofYb3+ aquo ion and chloro

complexes in aqueous solutions up to 500 "C and 270 MPa. Advanced Photon Source Activity Report 2001, (Argonne National Laboratory, Argonne, IL; ANL-02/06, 2002) pp 126-128.

W.A. Bassett, A.J. Anderson, 1.-M. Chou, R.A. Mayanovic, and S. Jayanetti, Element partitioning between fluids and between fluids and solids by XRF analyses in a hydrothermal diamond anvil cell modified for low­energy spectroscopy. Advanced Photon Source Activity Report 2001, (Argonne National Laboratory, Argonne, IL; ANL-02/06, 2002) pp 129-130.

R.A. Mayanovic, S. Jayanetti, A.J. Anderson, W.A. Bassett, and 1-M. Chou, Comparison between Yb3+ and Y3

+ ion association with the Cl- ion in hydrothermal solutions: Evidence from XAFS measurements on rare earth aqueous solutions at up to 500 "C and 270 MPa. Eos Trans, AGU, 83(19) M22A-12 (2002).

R.A. Mayanovic, S. Jayanetti, A.J. Anderson, W.A. Bassett and 1-M. Chou. Studies of solvation of inorganic metal ion complexes under hydrothermal conditions using XAFS spectroscopy. In Eleventh Annual V.M. Goldschmidt Conference, Abstract #3424. LPI Contribution No. I 088, Lunar and Planetary Institute, Houston (200 I).

W.A. Bassett, 1-M. Chou, R.A. Mayanovic, A.i. Anderson, S. Jayanetti, and R.S. Darling, The hydrothermal diamond-anvil cell. In Eleventh Annual V.M. Goldschmidt Conference, Abstract #3468. LPI Contribution No. I 088, Lunar and Planetary Institute, Houston (200 I).

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A.J. Anderson, S. Jayanetti, R.A. Mayanovic, W.A. Bassett, and 1-M. Chou, XAFS Investigations of light rare earth elements in hydrothermal solutions using a modified hydrothermal diamond anvil cell, Advanced Photon Source Activity Report 2000, (Argonne National Laboratory, Argonne, IL; ANL-01/03, 2001).

S. Jayanetti, R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I.M. Chou, Radiation-Induced Copper Particle Cluster Formation in Aqueous CuC]z: An XAFS Study, Advanced Photon Source Activity Report 2000, (Argonne National Laboratory, Argonne, IL; ANL-0 1103, 200 I).

W.A. Bassett, A.J. Anderson, R.A. Mayanovic, and 1.-M. Chou, XAFS analyses of solutions at subcritical and supercritical conditions in the hydrothermal diamond anvil cell. American Chemical Society 221" National Meeting. Geochemistry Abstract# 119 (200 I).

R.A. Mayanovic, S. Jayanetti, A.J. Anderson, W.A. Bassett and I-M. Chou, Solvation of inorganic metal ion complexes under hydrothermal conditions: Novel results from X-ray absorption analyses. American Chemical Society 221" National Meeting. Geochemistry Abstract# 120 (2001).

S. Jayanetti, R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, XAFS analysis of radiation-induced small Cu particle luster formation in aqueous CuCI2• American Chemical Society 221" National Meeting. Geochemistry Abstract # 121 (200 I).

J. Nichols, A.J. Anderson, R.A. Mayanovic, and S. Bajt, The Hawley Medal for 1999 to Alan J. Anderson, Robert A. Mayanovic and Sasa Bajt. Can. Mineral. 38, 255 (2000).

W.A. Bassett, A.J. Anderson, R.A. Mayanovic, and 1.-M. Chou, XAFS studies of first-row transition elements in aqueous solutions up to supercritical conditions using a special hydrothermal laser-drilled diamond anvil cell, CHESS Newsletter 2000. (Cornell University, Ithaca, NY 2000) pp27-29.

A.J. Anderson, R.A. Mayanovic, D. Jiang, M. Frank, and F. Candela, XAFS investigations of transition metal transport in two-phase (liquid + vapor) hydrothermal fluids, Advanced Photon Source Activity Report, (Argonne National Laboratory, Argonne, IL; ANL-00/5, 2000).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and.I-M. Chou, Evidence for dehydration of zinc halide complexes from XAFS measurements on zinc bromide and zinc chloride aqueous solutions at up to soo•c and elevated pressures using a hydrothermal diamond anvil cell. EOS Trans. AGU, 81, S37 (2000).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, and I-M. Chou, XAFS investigations of aqueous zinc halide solutions up to supercritical conditions. Final Program and Abstracts, 13th International Conference on the Properties of Water and Steam. Toronto, Canada, September 12-16, p.77 (1999).

R.A. Mayanovic, A.J. Anderson, W.A. Bassett, I-M. Chou, and G. Shea-McCarthy. First XAFS measurements on ferrous chloride hydrothermal solutions using a novel diamond anvil cell. National Synchrotron Light Source Activity Report 1998, (Brookhaven National Laboratory, Brookhaven, NY) pp. 2-57-59 (1999).

B.A. Bunker, Q. Lu, and R.A. Mayanovic, A.J. Kropf, R.J. Buscher!, Glancing angle XAFS studies of Cu thermal vibration amplitude at the Cu/Al20 3 interface. APS March Meeting, St. Jose, CA, Bull. Am. Phys. Soc. 40, s 18.09 (1995).

A.J. Anderson, R.A. Mayanovic, R.J. Bodnar, J.A. Mavrogenes, M.L. Rivers, S. Bajt, and S.R. Sutton, The first successful study of aqueous species in inclusion fluids using X-Ray absorption spectroscopy, Bull. Geog. Soc. Am. 25, A-316 ( 1993).

R.A. Mayanovic and B.A. Bunker, Glancing-Angle XAFS Studies of 'Premelting' at Cu/AI20 3 lnterfacial Regions. APS March Meeting, Cincinnati, OH, Bull. Am. Phys. Soc. 36 (1991).

R.A. Mayanovicand B.A. Bunker, EXAFS Study of Melting in Hg, APS March Meeting, Anaheim, CA, Bull. Am. Phys. Soc. 35 (1990).

R.A. Mayanovic and B.A. Bunker, EXAFS Study of Zn,Mn1_,S: Comparison of Local Structure of Zn,Mn1_,S and Zn,Mn1_,Se. APS March Meeting, St. Louis, MO, Bull. Am. Phys. Soc. 34 (1989).

R.A. Mayanovic, R. Sladek, and J.K. Furdyna, Bonding and Exchange in Zn,Mn1_,Se. 34th Midwest Solid State Conference, St. Louis, MO, Oct. 24-25, 1986, Appl. Phys. Comm. 7 (1987).

R.A. Mayanovic, R. Sladek, and J.K. Furdyna, Ultrasonic Attenuation in a Diluted Magnetic Semiconductor: Zn,Mn 1.,Se. APS March Meeting, New York, NY, Bull. Am. Phys. Soc. 32 (1987).

R.A. Mayanovic, R. Sladek, and J.K. Furdyna, Ultrasonic Attenuation in Zn,Mn1.,Se and Cd,Mn1.,Te. 35th Midwest Solid State Conference, Notre Dame, IN, Oct. 19-20 (1987).

R.A. Mayanovic, R. Sladek, and J.K. Furdyna, Ultrasonic Determination of Elastic Constants in Zllo.47M11o.53Se: . Structural, Piezoelectric, and Magnetic I;lffects. APS March Meeting, Las Vegas, NM, Bull. Am. Phys. Soc. 31 (1986).

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Research Matrix

1992- 2005 2006 2007 2008 2009 2010 2011 2012 2013 2004

Peer-reviewed articles: (Minimum of 1 peer reviewed 44 2 0 2 3 5 2 3 4 5# publication per year) Other major published works: (book chapter, etc.; 1 1 0 0 0 0 0 0 0 0 encouraged) Other publications (reports, etc.; encouraged) . 30 2 2 0 3 1 0 1 2 2

Peer-reviewed conference presentations: 27 2 2 1 1 1 2 1 1 2 (encouraged) Invited Presentations (Encouraged) 22 1 3 1 0 3 3 3 3 2

Grants Submitted: (Encouraged: submit 1 grant for 10+ 1 2 1 2 1 1 1 1 1 internal or extemal funding per year) Established program of research/ Impact on the Mayanovic is a participant in a DOE funded national energy center field: (Encouraged) (EFree); this has funded $425,000 during 2009-2014 making MSU

the only state-funded academic institution in Missouri to be included in the EFRC program. Discovered that certain periodic mesoporous silica have better mechanical-thermal strength at high pressures and temperatures than similar materials with random pores. We have discovered that mesoporous carbon has excellent stability in water at high temperatures-pressures. We have discovered methods to introduce dopants on the surface of nanoparticles in extreme hydrothermal environments, in order to modify their catalytic properties. We have made new discoveries on the structural modifications made on aluminosilicate glasses by dissolved water under extreme conditions.

.. • 2 add1t1onal manuscnpts under rev1ew

Mentoring students (2005-2013; Yearly subtotals not available) Member, Undergraduate Committee, 25 students Director, Undergraduate Committee: 12 students Member, Thesis Committee: 18 students

Related Awards (partial list) PAMS Department, MSU Research Award, 2008 MSU Foundation Research Award, 2001 Hawley Medal, 1999, Mineralogical Association of Canada.

Director Masters Research Project: 10 students

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