STRUCTURAL EPOXY ADHESIVE A Safety Data Sheetmedia.hiscoinc.com/Volume2/d110001/medias/docus/224/MG Chem… · SAI Global File #004008 Burlington, Ontario, Canada STRUCTURAL EPOXY

Quality System Certified to ISO 9001:2008

SAI Global File #004008

Burlington, Ontario, Canada

STRUCTURAL EPOXY ADHESIVE 9200-PART A

Page 1 of 15

Date: 23 February 2016 / Ver. 1.00

Safety Data Sheet Section 1: Identification

Product Identifier and Other Means of Identification

Product Name: Structural Epoxy Adhesive

SDS Code: 9200–Part A

Related Part # 9200-25ML, 9200-50ML

Recommended Use and Restriction on Use

Use: Epoxy adhesive resin for use with hardeners

Uses Advised Against: Not for use as a spray coating

Details of Manufacturer or Importer

Manufacturer

MG Chemicals MG Chemicals (Head Office)

1210 Corporate Drive 9347-193 Street

Burlington, Ontario L7L 5R6 Surrey, British Columbia V4N 4E7

CANADA CANADA

+1-800-340-0772 +1-905-331-1396

FAX +1-800-340-0773 FAX +1-905-331-2682

E-MAIL [email protected] E-MAIL [email protected]

WEB www.mgchemicals.com

E-MAIL (Competent Person): [email protected]

Emergency Phone Number

For hazardous material incidents ONLY—leaks, spills, fires, exposures or accidents USA or CANADA: Call CHEMTREC : +1-800-424-9300

For emergencies involving dangerous goods; Collect 24/7 CANADA: Call CANUTEC : +1-613-996-6666 or *666 on cellular phones

mailto:[email protected]


http://www.mgchemicals.com/






Page 2 of 15


Section 2: Hazard(s) Identification

Classification of Hazardous Chemical

GHS Categories

Criteria Category Signal

Word

Pictograms

Sensitization Skin sensitizer 1 Warning Exclamation

Eye Irritation 2 Warning Exclamation

Skin Irritation 2 Warning Exclamation

Environmental Hazard Chronic Aqua. Tox. 2 none Environment

Note: The degree of severity is ranked within each hazard class from

1 (Highest Severity) to up to 5 (Lowest Severity), which is opposite to HMIS and NFPA

conventions. Severity category rankings do not allow comparisons between classes.

Label Elements

Signal Word WARNING

Pictograms Hazard Statements

H319: Causes serious eye irritation

H315: Causes skin irritation

H317: May cause an allergic skin reaction

H411: Toxic to aquatic life with long lasting effects

Prevention Precautionary Statements

P102 Keep out of reach of children.

P261 Avoid breathing fumes/mist/vapors.

P280 Wear protective gloves/eye protection/face protection.

P272 Contaminated work clothing should not be allowed out of the workplace.

P264 Wash hands thoroughly after handling.

P273 Avoid release to the environment.

Section continued on the next page





Page 3 of 15


Continued…

Response Precautionary Statements

P305 + P351 +

P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/attention.

P302 + P352 IF ON SKIN: Wash with plenty of water.

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P362 + P364 Take off contaminated clothing and wash it before reuse.

P391 Collect spillage.

Storage Precautionary Statements

none none

Disposal Precautionary Statements

P501 Dispose of contents/container in accordance to

local/regional/international regulations.

Hazards Not Otherwise Classified

Other Criteria Hazard Statements/Precautionary

Statement

Signal

Word

Pictograms

None None None None

Section 3: Composition/Information on Ingredients

CAS # Chemical Name %(weight)

28064-14-4 phenol, polymer with formaldehyde, glycidyl ether 46%

25068-38-6 bisphenol-A epoxy resin (reaction product) a) 32%

14807-96-6 talc (non-asbestos fiber) 17%

60506-81-2 dipentaerythritol pentaacrylate 2%

a) Average molecular weight of ≤700





Page 4 of 15


Section 4: First-Aid Measures

Exposure Condition GHS Code/Symptoms/Precautionary Statements

IF IN EYES P305 + P351 + P338, P337 + P313

Immediate Symptoms redness, irritation, pain

Response Rinse cautiously with water for at least 15 minutes. Remove


If eye irritation persists: Get medical advice/attention.

IF ON SKIN P302 + P352, P333 + P313, P362 + P364

Immediate or Delayed

Symptoms

redness, irritation, dry skin, allergic contact dermatitis

Response Wash with plenty of water.

If skin irritation or rash occurs: Get medical advice/attention.

Take off contaminated clothing and wash it before reuse.

IF INHALED P304 + P340

Immediate Symptoms cough, irritation of the respiratory track

Response Remove person to fresh air and keep comfortable for

breathing.

IF SWALLOWED P301 + P330, P331

Immediate Symptoms abdominal discomfort, nausea, vomitting

Response Rinse mouth. Do NOT induce vomiting.





Page 5 of 15


Section 5: Fire-Fighting Measures

Extinguishing Media In case of fire: Use dry chemical, carbon dioxide, chemical

foam, or water spray to extinguish.

Specific Hazards Not flammable or combustible, but burns if involved in a fire.

Produces irritating smoke of unknown toxicity in fires.

Prevent fire-fighting wash from entering waterway or sewer

system.

Combustion Products Produces carbon oxides (CO,CO2) and toxic fumes.

Fire-Fighter Wear self-contained breathing apparatus and full fire-fighting

turn-out gear.

Section 6: Accidental Release Measures

Personal Protection See personal protection recommendations in Section 8.

Precautions for

Response

Avoid breathing the fumes/mist/vapors. Remove or keep away

all sources of extreme heat or open flames.

Environmental

Precautions

Avoid releasing to the environment. Prevent spill from entering

drains and waterways.

Containment Methods Contain with inert and non-flammable absorbent such as soil,

sand, or vermiculite.

Cleaning Methods Collect liquid in a sealable, chemical-resistant container.

Sprinkle inert absorbent compound onto spill, then sweep into

the container. Wash residue with a paper towel wetted with

alcohol, ethyl lactate, or another suitable organic solvent; and

place dirty towels in container. Use soap and water to remove

the last traces of residue.

Disposal Methods Dispose of spill waste according to Section 13.





Page 6 of 15


Section 7: Handling and Storage

Prevention Keep out of reach of children.

Avoid breathing fumes/mist/vapors or contact with skin or

eyes.

Avoid release to the environment.

Handling Wear protective gloves/clothing/eye protection.


Contaminated work clothing should not be allowed out of the

workplace.

Wash hands thoroughly after handling.

Collect spillage.

Storage Store in a well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Substances with Occupational Exposure Limit Values

Chemical Name Country Long Term

Exposure Limits

(PEL)

Short Term

Exposure Limits

(STEL)

talc ACGIH 2 mg/m3 Not established

(without asbestos U.S.A. OSHA PEL 20 mppcf a) Not established

fibers) Canada AB 2 mg/m3 Not established

Canada BC 2 mg/m3 Not established

Canada ON 2 mg/m3 Not established

Canada QC 3 mg/m3 Not established

Note: Ingredients are listed in descending weight contribution order (from greatest to

least). The ACGIH1, OSHA (Table Z-1), and Canadian provinces exposure limits were

consulted. Limits from by RTECS2 database and data from suppliers’ SDS were also

consulted. Short term exposure limits (STEL) are for 15 min and long term permissible

exposure limits (PEL) for 8 h.

a) Millions of particles per cubic foot air, based on impinge samples counted by light-field

technique.





Page 7 of 15


Engineering Controls

Ventilation Keep airborne concentrations below the occupational exposure

limits (OEL).

Personal Protective Equipment

Eye protection Wear appropriate protective eyeglasses or chemical safety

goggles.

Recommendation: Ensure that glasses have side shields for

lateral protection.

Skin Protection For likely contacts, use of protective butyl rubber or other

chemically resistant gloves.

For incidental contacts, use nitrile or other chemically resistant

gloves.

Respiratory Protection For over-exposures up to 10 x OEL of mist/vapors/spray, wear

respirator such as a half-mask respirator with organic vapor

cartridges.

Above 10 x OEL, use a positive-pressure, air-supplied

respirator or a self-contained breathing apparatus.

RECOMMENDATION: onsult your local safety supply store to

ensure that your respirator has a NIOSH (U.S.) approved filter

cartridges appropriate for the ingredients listed in Section 3.

The respirator should be fitted to the employee by a

professional. Ensure vapor cartridges are stored in sealed

plastic bags when not being used.

General Hygiene Considerations

Wash hands thoroughly with water and soap after handling.





Page 8 of 15


Section 9: Physical and Chemical Properties

Physical State

Liquid Lower Flammability

Limit

Not

available

Appearance

Light grey Upper Flammability

Limit

Not

available

Odor Mild Vapor Pressure

@20 °C

Not

available

Odor Threshold

Not

available

Vapor Density Not

available

pH Not

available

Specific Gravity

@25 °C

1.3

Freezing/Melting

Point

Not

available

Solubility in

Water

Negligible

Boiling Point a) ≥150 °C

[≥302 °F]

Partition

Coefficient

Not

available

Flash Point b) >113 °C

[>235 °F]

Auto-ignition

Temperature

Not

available

Evaporation

Rate

Not

available

Decomposition

Temperature

Not

available

Flammability

(solid, gas)

Not

available

Viscosity

@25 °C

>20.5 mm2/s

a) Component with the lowest value—bisphenol-A epoxy resin (reaction product)

b) Component with the lowest value—dipentaerythritol pentaacrylate

Section 10: Stability and Reactivity

Reactivity Reacts exothermically with amines.

Chemical

Stability

Chemically stable at normal temperatures and pressures

Conditions to

Avoid

Avoid ignition sources, open flames, and incompatible substances.

Incompatibilities Strong oxidizing agents, strong acids, strong bases, amines

Polymerization Will not occur

Decomposition Will not decompose under normal conditions. For thermal

decomposition, see combustion products in Section 5.





Page 9 of 15


Section 11: Toxicological Information

Routes of Exposure

Skin Contact, Eye Contact, Inhalation, and Ingestion

Symptoms Summary

Eyes May cause redness, irritation, or pain.

Skin May cause skin redness, irritation, dry skin, or allergic contact

dermatitis.

Inhalation May cause cough and irritation of the respiratory track.

Ingestion May cause abdominal discomfort, nausea, and vomiting.

Chronic Prolonged and repeated exposure may lead to skin sensitization.

Acute Toxicity (Lethal Exposure Concentrations)

Chemical Name LD50

oral

LD50

dermal

LC50

inhalation

phenol, polymer with

formaldehyde, glycidyl ether

4 000 mg/kg

Rabbit a)

Not

available

6 000 mg/kg

Rabbit a)

reaction products:

bisphenol-A-(epichlor-

hydrin) and epoxy resin b)

11 400 mg/kg

Rat

Not

established

Not

established

talc (non-asbestos fiber) Not

available

Not

available

Not

available

dipentaerythritol

pentaacrylate

Not

available

Not

available

Not

available

Note: Toxicity data from the RTECS2 and ECHA were consulted. The data from supplier

(M)SDS were also consulted.

a) Supplier MSDS

b) Referred to as bisphenol-A epoxy resin (reaction product)

Other Toxicological Effects

Skin corrosion/irritation Based on component data, the mixture is a skin irritant.

Serious eye

damage/irritation

Based on compenent data, the mixture causes serious

eye irritation.

Sensitization

(allergic reactions)

Based on component data, the mixture is a skin

sensitizer based on animal studies.






Page 10 of 15


Carcinogenicity

(risk of cancer)

Not classified or listed as a carcinogen by IARC, ACGIH,

CA Prop 65, or NTP.

Mutagenicity

(risk of heritable genetic

effects)

Based on available data,

the classification criteria are not met.

Reproductive Toxicity

(risk to sex functions)



Teratogenicity

(risk of fetus malformation)



STOT-single exposure Based on available data,


STOT-repeated exposure Based on available data,


Aspiration hazard Based on available data, the classification criteria are

not met. There is no category 1 components, and the

kinematic viscosity is >20.5 mm2/s at 40 °C.

Section 12: Ecological Information

Ecological classifications are based on the IMDG/GHS criteria in conjunction with

ecotoxicological data from our suppliers, the European Chemical Agency database

(http://echa.europa.eu), and other reliable sources.

In Europe, similar epoxy resin mixtures with CAS# 25068-38-6 and 28064-14-4 have an

average molecular weight of less than 700 are generally classified as chronic category 2

marine pollutant due to LC50 96 h of >1 mg/L but ≤10 mg/L.

Based on available data, talc and dipentaerythritol pentaacrylate are not classified as

environmental hazards according to GHS criteria.

Acute Ecotoxicity

Category 2

Toxic to aquatic life

Chronic Ecotoxicity

Category 2

Toxic to aquatic life with long lasting effects

Avoid release to the environment. Collect spillage.


http://echa.europa.eu/





Page 11 of 15


Biodegradability

Not available

Bioaccumulation

Not available

Section 13: Disposal Information

Dispose of contents in accordance with all local, regional, national, and international

regulations.

Section 14: Transport Information

Ground

Refer to TDG regulations (Canadian Transportation of Dangerous Goods regulations);

USA DOT 49 CFR (Parts 100 to 185) Regulations.

Sizes under 450 L FOR REFERENCE ONLY

NOT REGULATED in TDG UN number: UN3082

per Special Provisions 99 Shipping Name: ENVIRONMENTALLY

Sizes 5 L and under HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(silver particles <1 mm)

NOT REGULATED in 49 CFR Class: 9

per exception 171.4 (c)(2) Packing Group: III

Marine Pollutant: Yes

Special Provision 99 (2): These Regulations, except for Part 1 (Coming into Force,

Repeal, Interpretation, General Provisions and Special Cases) and Part 2 (Classification),

do not apply to the handling, offering for transport or transporting of less than 450 kg of

UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., or less than

450 L of UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., on a

road vehicle or a railway vehicle. The dangerous goods must be contained in one or more

small means of containment designed, constructed, filled, closed, secured and maintained

so that under normal conditions of transport, including handling, there will be no

accidental release of the dangerous goods that could endanger public safety.






Page 12 of 15


Air

Refer to ICAO-IATA regulations.

Sizes 5 L and under: Cat. No. 9200-25ML, 9200-50ML

NOT REGULATED

Not Restricted, as per Special

Provisions A197

Special Provision A197: These substances when transported in single or combination

packagings containing net quantity per single or inner packaging of less than 5 L or less

for liquids or having a net mass of 5 kg or less for solids, are not subject to any other

provisions of these Regulations provided the packagings meet the general provisions

5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.

Sea

Refer to IMDG regulations.

Sizes 5 L and under: Cat. No. 9200-25ML, 9200-50ML

NOT REGULATED

per 2.10.2.7

2.10.2.7: Marine pollutants packaged in single or combination packagings containing a

net quantity per single or inner packaging of 5 L or less for liquids or having a net mass

per single or inner packaging of 5 kg or less for solids are not subject to any other

provision of this Code relevant to marine pollutants provided the packagings meet the

general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8. In the case of marine

pollutants also meeting the criteria for inclusion in another hazard class, all provisions of

this Code relevant to any additional hazards continue to apply.





Page 13 of 15


Section 15: Regulatory Information

Canada

Domestic Substance List (DSL) / Non-Domestic Substance Lists (NDSL)

All hazardous ingredients are listed on the DSL.

Industry and Science Canada

MG Labels products intended for the workplace to conform to WHMIS labeling

regulations. Product identification, net quantity declaration, minimum printing type

size heights, and packaging of this product are in compliance.

USA

Other Classifications

HMIS® RATING NFPA® 704 CODES

HEALTH: * 2

FLAMMABILITY: 1

PHYSICAL HAZARD: 0

PERSONAL PROTECTION:

Approximate HMIS and NFPA Risk Ratings Legend:

0 (Low or none); 1 (Slight); 2 (Moderate); 3 (Serious); 4 (Severe)

CAA (Clean Air Act, USA)

This product does not contain any class 1 ozone depleting substances.


This product does not contain substances that are listed as hazardous air pollutants.

EPCRA (Emergency Planning and Right to Know Act, USA, 40 CFR 372.45)

This product does not contain substances which are subject to the reporting

requirements of section 313 Title III of the SARA of 1986 and 40 CFR part 372.


2 0

1





Page 14 of 15


TSCA (Toxic Substances Control Act of 1976, USA)

All substances are TSCA listed.

California Proposition 65 (Chemicals known to cause cancer or reproductive toxicity,

June 06, 2014 revision, USA).

This product does not contain any listed substances in California.

Europe

RoHS (Restriction of Hazardous Substances Directive)

This product does not contain any lead, cadmium, mercury, hexavalent chromium,

PBB’s, or PBDE’s, and complies with European RoHS regulations.

WEEE (Waste Electrical and Electronic Equipment Directive)

This product is not a piece of electrical or electronics equipment, and is therefore not

governed by this regulation.

Section 16: Other Information

SDS Prepared by Michel Hachey

Date of Review 23 February 2016

Supersedes Not applicable

Reason for Changes: New product classified in compliance with WHMIS 2015 and

HCS 2012.

Reference

1) ACGIH 2013 TLVs and BEIs: Based on the documentation of the threshold limit values for

chemical substances and physical agents & biological exposure indices, American

Conference of Governmental of Industrial Hygienist Cincinnati, OH (2013).

2) All toxicological data were checked against the RTECS (Registry of Toxic Effects of

Chemical Substances®)






Page 15 of 15


Abbreviations

ACGIH American Conference of Governmental Industrial Hygienists (USA)

EC50 Half maximal effective concentration

EL50 Half maximal effective loading

IARC International Agency for Research on Cancer

NOELR No observable effect loading ratio

NTP National Toxicology Program

GHS Globally Harmonized System of Classification of Labeling of Chemicals

LC50 Lethal Concentration 50%

LCLo Lowest published lethal concentration

LD50 Lethal Dose 50%

OEL Occupational Exposure Limit

PEL Permissible Exposure Limit

SDS Safety Data Sheet

STEL Short-Term Exposure Limit

TCLo Lowest published toxic concentration

TWA Time Weighted Average

VOC Volatile Organic Content

Technical Queries Contact us regarding any questions, improvement suggestions, or

problems with this product. Application notes, instructions, and FAQs

are located at www.mgchemicals.com.

Email: [email protected]

Mailing Addresses Manufacturing & Support Head Office

1210 Corporate Drive 9347–193rd Street

Burlington, Ontario, Canada Surrey, British Columbia, Canada

L7L 5R6 V4N 4E7

Disclaimer This material safety data sheet is provided as an information resource only.

M.G. Chemicals, Ltd. believes the information contained herein is accurate

and compiled from reliable sources. It is the responsibility of the user to

query and verify any information seeming suspect where doubt on the validity

may exist. The buyer assumes all responsibility of using and handling the

product in accordance with local, regional, national, and international

regulations.



Registered Quality System ISO 9001:2008

QMI File #004008


STRUCTURAL EPOXY ADHESIVE 9200-PART B

Page 1 of 16


Safety Data Sheet Section 1: Identification

Product Identifier and Other Means of Identification

Product Name: Structural Epoxy Adhesive

SDS Code: 9200–Part B

Related Part # 9200-25ML, 9200-50ML

Recommended Use and Restriction on Use

Use: Epoxy adhesive hardener for use with resins

Uses Advised Against: Not for use as a spray coating

Details of Manufacturer or Importer

Manufacturer

MG Chemicals MG Chemicals (Head Office)

1210 Corporate Drive 9347-193 Street

Burlington, Ontario L7L 5R6 Surrey, British Columbia V4N 4E7

CANADA CANADA

+1-800-340-0772 +1-905-331-1396

FAX +1-800-340-0773 FAX +1-905-331-2682

E-MAIL [email protected] E-MAIL [email protected]

WEB www.mgchemicals.com

E-MAIL (Competent Person): [email protected]

Emergency Phone Number

For hazardous material incidents ONLY—leaks, spills, fires, exposures or accidents USA or CANADA: Call CHEMTREC : +1-800-424-9300

For emergencies involving dangerous goods; Collect 24/7 CANADA: Call CANUTEC : +1-613-996-6666 or *666 on cellular phones






QMI File #004008



Page 2 of 16


Section 2: Hazard(s) Identification

Classification of Hazardous Chemical

GHS Categories

Criteria Category Signal

Word

Pictograms

Serious Eye Damage 1 Danger Corrosion

Skin Corrosion 1 Danger Corrosion

Sensitization Skin 1 Warning Exclamation

Environmental Hazard Chronic Aqua. Tox. 2 none Environment

Note: The degree of severity is ranked within each hazard class from

1 (Highest Severity) to up to 5 (Lowest Severity), which is opposite to HMIS and NFPA

conventions. Severity category rankings do not allow comparisons between classes.

Label Elements

Signal Word DANGER

Pictograms Hazard Statements

H314: Causes severe skin burns and eye damage

H317: May cause an allergic skin reaction

H411: Toxic to aquatic life with long lasting effects



QMI File #004008



Page 3 of 16


Continued…

Prevention Precautionary Statements

P102 Keep out of reach of children.

P260 Do not breathe fumes/mist/vapors.

P280 Wear protective gloves/protective clothing/eye protection/face

protection.

P264 Wash hands thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the

workplace.

P273 Avoid release to the environment.

Response Precautionary Statements

P310 For all routes of exposure: Immediately call a POISON

CENTER/doctor.

P305 + P351 +

P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove


P301 + P330 +

P352

IF ON SKIN (or hair): Take off immediately all contaminated clothing.

Wash with plenty of water [or shower].

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P301 + P330 +

P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for

breathing.

P391 Collect spillage.

Storage Precautionary Statements

P405 Store locked up.

Disposal Precautionary Statements

P501 Dispose of contents/container in accordance to

local/regional/international regulations.

Hazards Not Otherwise Classified

Other Criteria Hazard Statements/Precautionary

Statement

Signal

Word

Pictograms

None None None None


QMI File #004008



Page 4 of 16


Section 3: Composition/Information on Ingredients

CAS # Chemical Name %(weight)

68683-29-4 ATBN polymer 32%

7727-43-7 barium sulfate 30%

68410-23-1 fatty acids, C18-unsatd., dimers, reaction products

with polyethylenepolyamines

24%

68082-29-1 fatty acids, C18-unsatd., dimers, polymers with tall-oil

fatty acids and triethylenetetramine

7%

112-24-3 triethylenetetramine 3%

140-31-8 2-piperazin-1-ylethylamine (AEP) 2%

Section 4: First-Aid Measures

Exposure Condition GHS Code: Precautionary Statement

IF IN EYES P305 + P351 + P338, P310

Immediate Symptoms redness, severe irritation, pain, burns

Response Rinse cautiously with water for 30 minutes or more. Remove


Immediately call a POISON CENTER/doctor.

IF ON SKIN (or hair) P301 + P330 + P352, P310, P333 + P313, P363

Immediate or Delayed

Symptoms

redness, irritation, rash (allergic contact dermatitis), pain,

burns, blistering

Response Take off immediately all contaminated clothing. Wash with

plenty of water [shower]. Immediately call a POISON

CENTER/doctor.

If skin irritation or rash occurs: Get medical advice/attention.

Wash contaminated clothing before reuse.



QMI File #004008



Page 5 of 16


Continued…

IF SWALLOWED P301 + P330 + P331, P310

Immediate Symptoms irritation, abdominal pain, nausea, vomiting, burns to the

digestive tract

Response Rinse mouth. Do not induce vomiting.


IF INHALED P304 + P340, P310

Immediate Symptoms cough, irritation of the respiratory track, burning sensation

Delayed Symptoms asthma, difficulty breathing

Response Remove person to fresh air and keep comfortable for

breathing.


Advice to Physicians

In case of exposure to nitrogen oxides (NOx) combustion products or triethylenetetramine

vapors during a fire, the symptoms may be delayed. For significant exposures, the exposed

person should be kept under medical surveillance for 48 hours.

Section 5: Fire-Fighting Measures

Extinguishing Media In case of fire: Use dry chemical, carbon dioxide, chemical

foam, or water spray to extinguish.

Specific Hazards Not flammable or combustible, but burns if involved in a fire.

Produces irritating and toxic fumes in fires or in contact with

hot surfaces.

Inhalation of toxic smoke during fire may have delayed effects.

Exposed person may need to be put under surveillance for 48

h.

Toxic for aquatic environment: Prevent fire-fighting wash from

entering waterway or sewer system.

Combustion Products Produces carbon oxides (CO, CO2) and nitrogen oxides (NOx).

Fire-Fighter Wear self-contained breathing apparatus and full fire-fighting

turn-out gear.


QMI File #004008



Page 6 of 16


Section 6: Accidental Release Measures

Personal Protection Use personal protection recommended in Section 8.

Precautions for

Response

Do not breathe fumes/mist/vapors.

Environmental

Precautions

Avoid releasing to the environment. Prevent spill from entering

drains and waterways. Do not flush to sewer.

Containment Methods Contain with inert and non-flammable absorbent (such as soil,

sand, vermiculite).

Cleaning Methods Collect liquid in a sealable container. Sprinkle inert absorbent

compound onto spill, then sweep into the container. Wipe

residue with a paper towel wetted with a suitable organic

solvent such as alcohol or ethyl lactate, and place dirty towels

in container. Wash spill area with soap and water to remove

the last traces of residue.

Disposal Methods

Dispose spill waste according to Section 13.

Section 7: Handling and Storage

Prevention Keep out of reach of children.

Do not breathe fumes/mist/vapors.

Contaminated work clothing should not be allowed out of the

workplace.

Avoid release to the environment.

Handling Wear protective gloves/protective clothing/eye protection/face

protection.


Wash hands thoroughly after handling.

Collect spillage.

Storage Store locked up.


QMI File #004008



Page 7 of 16


Section 8: Exposure Controls/Personal Protection

Substances with Occupational Exposure Limit Values

Chemical Name Country or

Vendor

Long Term Exposure

Limits

(PEL)

Short Term

Exposure Limits

(STEL)

barium sulfate ACGIH 10 mg/m3 Not established

U.S.A. OSHA PEL 15 mg/m3 (Dust) Not established

Canada AB 10 mg/m3 Not established

Canada BC 10 mg/m3 (Dust) Not established

Canada ON 10 mg/m3 Not established

Canada QC 10 mg/m3 Not established

triethylenetetramine ACGIH Not established Not established

U.S.A. OSHA PEL Not established Not established

U.S.A (WEEL) 1 ppm Not established

Canada AB Not established Not established

Canada BC Not established Not established

Canada ON 0.5 mg/m3 (Skin) a) Not established

Canada QC Not established Not established

Note: Ingredients are listed in descending weight contribution order (from greatest to

least). The ACGIH1, OSHA (Table Z-1), and Canadian provinces exposure limits were

consulted. Limits from by RTECS2 database and data from suppliers’ SDS were also

consulted. Short term exposure limits (STEL) are for 15 min and long term permissible

exposure limits (PEL) for 8 h.

a) Skin—can be absorbed through the skin.

Engineering Controls

Ventilation Keep airborne concentrations below the occupational exposure

limits (OEL).

Personal Protective Equipment

Eye protection Wear appropriate protective eyeglasses or chemical safety

goggles.

RECOMMENDATION: Use safety glasses with lateral protection

(side shields).

Skin Protection For likely contacts, use of protective butyl rubber, neoprene,

or other chemically resistant gloves.

For incidental contacts, use nitrile or other chemically resistant

gloves.



QMI File #004008



Page 8 of 16


Respiratory Protection For over-exposures up to 10 x OEL of mist/vapors/spray, wear

respirator such as a half-mask respirator with organic vapor

cartridges.

Above 10 x OEL, use a positive-pressure, air-supplied

respirator or a self-contained breathing apparatus.

If the product is heated or worker has a known allergic

reaction, consider using a full mask with organic vapor

cartridge or with an independent air supply.

RECOMMENDATION: Consult your local safety supply store to

ensure your respirator has a NIOSH (U.S.) approved filter

cartridges appropriate for the ingredients listed in section 3 of

this SDS, and that the respirator is fitted to the employee by a

professional. Ensure vapor cartridges are stored in sealed

plastic bags when not being used.

General Hygiene Considerations

Wash hands thoroughly with water and soap after handling.

Section 9: Physical and Chemical Properties

Physical State

Liquid Lower

Flammability

Limit

Not

available

Appearance

Amber Upper

Flammability

Limit

Not

available

Odor Ammonia-like Vapor Pressure

@20 °C a)

<0.001 kPa

[<0.01 mmHg]

Odor Threshold

Not

available

Vapor Density Not

available

pH Not

available

Specific Gravity

@25 °C

1.18

Freezing/Melting

Point

Not

available

Solubility in

Water

Slightly

soluble

Boiling Point Not

available

Partition

Coefficient

Not

available

Flash Point a) >122 °C

[>252 °F]

Auto-ignition

Temperature

Not

available

Evaporation

Rate

Not

available

Decomposition

Temperature

Not

available

Flammability

(solid, gas)

Not

available

Viscosity

@25 °C

>20.5 mm2/s

a) Literature value for triethylenetetramine


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Section 10: Stability and Reactivity

Reactivity Reacts exothermically with ketones, halogenated hydrocarbons,

cyanides, nitriles, and epoxides. May attack metals such as

aluminum, zinc, copper, and their alloys.

Chemical

Stability

Chemically stable at normal temperatures and pressures

Conditions to

Avoid

Ignition sources, open flames, and incompatible substances

Incompatibilities Strong oxidizing agents, strong acids

Polymerization Will not occur

Decomposition Will not decompose under normal conditions. For thermal

decomposition, see combustion products in Section 5.

Section 11: Toxicological Information

Routes of Exposure

Eye Contact, Skin Contact, Inhalation, and Ingestion

Symptoms Summary

Eyes May causes redness, severe irritation, pain, or burns.

Skin May cause redness, serious skin irritation, allergic contact dermatitis,

and chemical burns. Triethylenetetramine can be absorbed through

skin leading to toxic effects.

When heated, hot triethylenetetramine vapors may also result in

itching of the face with skin redness (erythema) and swelling

(edema).

Inhalation May cause cough, irritation of the respiratory track, or burning

sensation.

Ingestion May cause irritation, abdominal pain, nausea, vomiting, burns to the

digestive tract (see inhalation symptoms).

Chronic Prolonged and repeated exposure to uncured epoxy hardener may

lead to skin sensitization.



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Acute Toxicity (Lethal Exposure Concentrations)

Chemical Name LD50

oral

LD50

dermal

LC50

inhalation

fatty acids, C18-unsatd., dimers, reaction

products with polyethylenepolyamines

>5 000

mg/kg a)

>5 000

mg/kg a)

Not

available

fatty acids, C18-unsatd., dimers, polymers

with tall-oil fatty acids and

triethylenetetramine

>5 000

mg/kg a)

>5 000

mg/kg a)

Not

available

triethylenetetramine 2 500 mg/kg

Rat

805 mg/kg

Rabbit

Not

available

2-piperazin-1-ylethylamine (AEP) 2 106 mg/kg

Rat

866 mg/kg

Rabbit

Not

available

Note: Toxicity data from the RTECS2 and ECHA were consulted. The data from supplier

(M)SDS were also consulted.

a) Supplier MSDS

Other Toxicological Effects

Skin corrosion/irritation Triethylenetetramine and 2-piperazin-1-ylethylamine

causes skin burns.

Serious eye

damage/irritation

Triethylenetetramine and 2-piperazin-1-ylethylamine

causes severe eye damage.

Respiratory and skin

sensitization (allergic reactions)

The epoxy hardener components may cause skin

sensitization according to animal studies.

Carcinogenicity

(risk of cancer)

None of the ingredients are classified or listed as a

carcinogen by IARC, ACGIH, CA Prop 65, or NTP.

Mutagenicity

(risk of heritable genetic effects)



Reproductive Toxicity

(risk to sex functions)



Teratogenicity

(risk of fetus malformation)



STOT-single exposure Based on available data,


STOT-repeated exposure Based on available data,


Aspiration hazard Based on available data, the classification criteria are

not met. There are no category 1 components, and

the kinematic viscosity is >20.5 mm2/s at 40 °C.


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Section 12: Ecological Information

Ecological classifications are based on the IMDG/GHS criteria in conjunction with

ecotoxicological data from our suppliers, the European Chemical Agency database

(http://echa.europa.eu), and other reliable sources.

The fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines

(CAS# 68410-23-1) and fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty acids

and triethylenetetramine (CAS# 68082-29-1) were classified as a chronic category 2

environmental toxicant (not readily biodegradable, LC50 range of 1—10 mg/L for fish;

EC0 bacterial >10 and ≤100 mg/L).

Literature values for the triethylenetetramine (CAS # 112-24-3) suggest an acute

category 3 aquatic toxicity (LC50, IC50, and EC50 values of >100 mg/L for fish and

between 10 and 100 mg/L for algae).

Acute Ecotoxicity

Category 2

Toxic to aquatic life

Chronic Ecotoxicity

Category 2

Toxic to aquatic life with long lasting effect

Avoid release to the environment. Collect spillage.

Biodegradability

Not readily biodegradable

Bioaccumulation

Not available

Other Effects

Not available

Section 13: Disposal Information

Dispose of contents in accordance with all local, regional, national, and international

regulations.

http://echa.europa.eu/


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Page 12 of 16


Section 14: Transport Information

Ground

Refer to TDG regulations (Canadian Transportation of Dangerous Goods regulations);

USA DOT 49 CFR (Parts 100 to 185) Regulations.

Sizes 1 L and under Sizes greater than 1 L

Limited Quantity

UN number: UN2735

Shipping Name: AMINES, LIQUID,

CORROSIVE, N.O.S. *

(containing triethylenetetramine,

dimer fatty acid (C18)poly amido

amine resin)

Class: 8

Packing Group: II


Air

Refer to ICAO-IATA Dangerous Goods Regulations.

Sizes 0.5 L and under Sizes greater than 0.5 L up to 1 L

Limited Quantity

UN number: UN2735


CORROSIVE, N.O.S. *



amine resin)

Class: 8

Packing Group: II




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Page 13 of 16


Sea

Refer to IMDG regulations.

Sizes 1 L and under Sizes greater than 1 L

Limited Quantity

UN number: UN2735


CORROSIVE, N.O.S. *



amine resin)

Class: 8

Packing Group: II


Note: Shipper must be appropriately trained and certified before involvement with

the transport of dangerous goods.

Section 15: Regulatory Information

Canada

Domestic Substance List (DSL)/Non-Domestic Substance Lists (NDSL)

All hazardous ingredients are listed on the DSL/NDSL.

Industry and Science Canada

MG Labels products intended for the workplace to conform to WHMIS labeling

regulations. Product identification, net quantity declaration, minimum printing type

size heights, and packaging of this product are in compliance.



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USA

Other Classifications

HMIS® RATING NFPA® 704 CODES

HEALTH: * 3

FLAMMABILITY: 1

PHYSICAL HAZARD: 0

PERSONAL PROTECTION:

Approximate HMIS and NFPA Risk Ratings Legend:

0 (Low or none); 1 (Slight); 2 (Moderate); 3 (Serious); 4 (Severe)

CAA (Clean Air Act, USA)



This product does not contain substances that are listed as hazardous air pollutants.

EPCRA (Emergency Planning and Right to Know Act, USA, 40 CFR 372.45

This product does not contain substances that are subject to the reporting

requirements of section 313 Title III of the SARA of 1986 and 40 CFR part 372.

TSCA (Toxic Substances Control Act of 1976, USA)

All substances are TSCA listed.

California Proposition 65 (Chemicals known to cause cancer or reproductive toxicity,

June 06, 2014 revision, USA).

This product does not contain any listed substances in California.

Europe

RoHS (Restriction of Hazardous Substances Directive)

This product does not contain any lead, cadmium, mercury, hexavalent chromium,

PBB’s, or PBDE’s, and complies with European RoHS regulations.

WEEE (Waste Electrical and Electronic Equipment Directive)

This product is not a piece of electrical or electronics equipment, and is therefore not

governed by this regulation.

3 0

1


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Page 15 of 16


Section 16: Other Information

SDS Prepared by Michel Hachey

Date of Revision 23 February 2016

Supersedes Not applicable

Reason for Changes: New product classified in compliance with WHMIS 2015 and

HCS 2012.

Reference

1) ACGIH 2013 TLVs and BEIs: Based on the documentation of the threshold limit values for

chemical substances and physical agents & biological exposure indices, American

Conference of Governmental of Industrial Hygienist Cincinnati, OH (2013).

2) All toxicological data were checked against the RTECS (Registry of Toxic Effects of

Chemical Substances®)

Abbreviations

ACGIH American Conference of Governmental Industrial Hygienists (USA)

EC50 Half maximal effective concentration

EL50 Half maximal effective loading

IARC International Agency for Research on Cancer

NOELR No observable effect loading ratio

NTP National Toxicology Program

GHS Globally Harmonized System of Classification of Labeling of Chemicals

LC50 Lethal Concentration 50%

LCLo Lowest published lethal concentration

LD50 Lethal Dose 50%

OEL Occupational Exposure Limit

PEL Permissible Exposure Limit

SDS Safety Data Sheet

STEL Short-Term Exposure Limit

TCLo Lowest published toxic concentration

TWA Time Weighted Average

VOC Volatile Organic Content



QMI File #004008



Page 16 of 16


Technical Queries Contact us regarding any questions, improvement suggestions, or

problems with this product. Application notes, instructions, and FAQs

are located at www.mgchemicals.com.

Email: [email protected]

Mailing Addresses Manufacturing & Support Head Office

1210 Corporate Drive 9347–193rd Street

Burlington, Ontario, Canada Surrey, British Columbia, Canada

L7L 5R6 V4N 4E7

Disclaimer This material safety data sheet is provided as an information resource only.

M.G. Chemicals, Ltd. believes the information contained herein is accurate

and compiled from reliable sources. It is the responsibility of the user to

query and verify any information seeming suspect where doubt on the validity

may exist. The buyer assumes all responsibility of using and handling the

product in accordance with local, regional, national, and international

regulations.



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