Stewart International Airport PFC Sampling Report - November … · 2017-01-30 · Project: Stewart International Airport (PFAS) Report Number: 280-88381-1 This case narrative is

ANALYTICAL REPORT

Job Number: 280-88381-1

Job Description: Stewart International Airport (PFAS)

For:HDR Inc

1 International Blvd, 10th FloorMahwah, NJ 07495

Attention: Ms. Melissa LaMacchia

_____________________________________________

Approved for release.Shalini WilliamsProject Management Assistant II9/30/2016 9:33 AM

Designee forSapna Nayyar, Project Manager I

777 New Durham Road, Edison, NJ, [email protected]

09/30/2016

TestAmerica Laboratories, Inc.

TestAmerica Denver 4955 Yarrow Street, Arvada, CO 80002

Tel (303) 736-0100 Fax (303) 431-7171 www.testamericainc.com

09/30/2016Page 1 of 495

mailto:[email protected]://www.testamericainc.comhttp://

Table of ContentsCover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Report Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

LCMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

Method PFC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32Method PFC QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33Method PFC Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205

Method PFC ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205Method PFC CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 299

Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 380Method PFC Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 380Method PFC LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 399Method PFC MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 445

Method PFC Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 483Method PFC Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 487

09/30/2016Page 2 of 495

Table of ContentsShipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 491

Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 492

Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 495

09/30/2016Page 3 of 495

CASE NARRATIVE

Client: HDR Inc

Project: Stewart International Airport (PFAS)

Report Number: 280-88381-1

This case narrative is in the form of an exception report, where only the anomalies related to this report, method specific performance and/or QA/QC issues are discussed. If there are no issues to report, this narrative will include a statement that documents that there are no relevant data issues.

It should be noted that samples with elevated Reporting Limits (RLs) as a result of a dilution may not be able to satisfy customer reporting limits in some cases. Such increases in the RLs are unavoidable but acceptable consequence of sample dilution that enables quantification of target analytes or interferences which exceed the calibration range of the instrument.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPTThe samples were received on 09/17/2016; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 16.6 C.

The following samples was received at the laboratory outside the required temperature criteria: PFC-MW-4 (280-88381-1), CB2K (280-88381-2), CB9A (280-88381-3), W6 (280-88381-4), ANG-CB-EB-091516 (280-88381-5), D27 (280-88381-6), D15-A (280-88381-7), ANG-MW-EB-091516 (280-88381-8), ANG-CB-FB-091516 (280-88381-9), STM-UP (280-88381-10), CB (280-88381-11), CB (280-88381-11[MS]), CB (280-88381-11[MSD]), C17 (280-88381-12), D8 (280-88381-13), CB-DUP (280-88381-14), PFC-MW-2 (280-88381-15), MW-DUP (280-88381-16), PFC-MW-3 (280-88381-17), PFC-MW-3 (280-88381-17[MS]), PFC-MW-3 (280-88381-17[MSD]), CB-FB-0914-16 (280-88381-18), CB-EB-091416 (280-88381-19), ANG-CB-EB-091616 (280-88381-20) and ANG-FB-091616 (280-88381-21). The client was contacted regarding this issue, and the laboratory was instructed to proceed with/cancel analysis.

Cooler received with not enough ice and ice melted, out of temp at 16.6°C.

The container label for the following sample(s) did not match the information listed on the Chain-of-Custody (COC): D8, SAMPLE 13 The container labels list DB-8, while the COC lists D8.

Note: All samples which require thermal preservation are considered acceptable if the arrival temperature is within 2C of the required temperature or method specified range. For samples with a specified temperature of 4C, samples with a temperature ranging from just above freezing temperature of water to 6C shall be acceptable. Samples that are hand delivered immediately following collection may not meet these criteria, however they will be deemed acceptable according to NELAC standards, if there is evidence that the chilling process has begun, such as arrival on ice, etc.

PERFLUORINATED HYDROCARBONS (PFC)Samples PFC-MW-4 (280-88381-1), CB2K (280-88381-2), CB9A (280-88381-3), W6 (280-88381-4), ANG-CB-EB-091516 (280-88381-5), D27 (280-88381-6), D15-A (280-88381-7), ANG-MW-EB-091516 (280-88381-8), ANG-CB-FB-091516 (280-88381-9), STM-UP (280-88381-10), CB (280-88381-11), C17 (280-88381-12), D8 (280-88381-13), CB-DUP (280-88381-14), PFC-MW-2 (280-88381-15), MW-DUP (280-88381-16), PFC-MW-3 (280-88381-17), CB-FB-0914-16 (280-88381-18), CB-EB-091416 (280-88381-19), ANG-CB-EB-091616 (280-88381-20) and ANG-FB-091616 (280-88381-21) were analyzed for Perfluorinated Hydrocarbons (PFC) in accordance with DV-LC-0012. The samples were prepared on 09/27/2016 and analyzed on 09/28/2016 and 09/29/2016.

13C4 PFBA (ISTD) retention times for the following samples were outside the acceptance criteria of +/-0.5 minutes from the mid-point of the initial calibration: MW-DUP (280-88381-16), PFC-MW-3 (280-88381-17), PFC-MW-3 (280-88381-17[MS]), PFC-MW-3 (280-88381-17[MSD]), CB-FB-0914-16 (280-88381-18), CB-EB-091416 (280-88381-19), ANG-CB-EB-091616 (280-88381-20), ANG-FB-091616 (280-88381-21), (LCS 280-343904/2-A), (LCSD 280-343904/3-A) and (MB 280-343904/1-A).

This particular IS is associated with PFBA which was selected based on retention time of 13C4 PFBA. The CCV's are just in control, while the samples and batch QC are just over the limits of being 0.5minutes.

PFC preparation batch 280-343904 and analytical batch 280-344279

MW-DUP (280-88381-16), PFC-MW-3 (280-88381-17), PFC-MW-3 (280-88381-17[MS]), PFC-MW-3 (280-88381-17[MSD]), CB-FB-0914-16 (280-88381-18), CB-EB-091416 (280-88381-19), ANG-CB-EB-091616 (280-88381-20), ANG-FB-091616 (280-88381-21), (LCS 280-343904/2-A), (LCSD 280-343904/3-A) and (MB 280-343904/1-A)

09/30/2016Page 4 of 495

Internal standard responses were outside of acceptance limits for the following samples: MW-DUP (280-88381-16), PFC-MW-3 (280-88381-17), PFC-MW-3 (280-88381-17[MS]) and PFC-MW-3 (280-88381-17[MSD]). The sample(s) shows evidence of matrix interference.


The samples failed for internal standards, the method blank and LCS were in control..

Internal standard responses were outside of acceptance limits for the following sample: D27 (280-88381-6). The sample(s) shows evidence of matrix interference.


The sample failed for % recovery for several internal standards, the method blank and LCS were in control.

The surrogate recovery for the blank associated with preparation batch 280-343884 and analytical batch 280-344280 was outside the upper control limits for 13C8 PFOS at 131% (limits 45-130). All sample surrogates were in control, therefore, the data has been reported with narrative.

Internal standard responses were outside of acceptance limits for the following samples: PFC-MW-4 (280-88381-1), CB2K (280-88381-2), CB9A (280-88381-3), W6 (280-88381-4), D27 (280-88381-6), D15-A (280-88381-7), ANG-CB-FB-091516 (280-88381-9), STM-UP (280-88381-10), CB (280-88381-11[MS]), CB (280-88381-11[MSD]), C17 (280-88381-12), D8 (280-88381-13), CB-DUP (280-88381-14) and PFC-MW-2 (280-88381-15). The samples show evidence of matrix interference. Failing internal standards are not associated with the clients requested target analytes. Report with narrative.

3C4 PFBA (ISTD) retention times for the following samples were outside the acceptance criteria of +/-0.5 minutes from the mid-point of the initial calibration: CB9A (280-88381-3), ANG-CB-FB-091516 (280-88381-9), STM-UP (280-88381-10) and (LCS 280-343884/2-A). This IS is associated with compound PFBA which is not on the client's requested target analyte list. Report with narrative.

13C8 PFOS failed the surrogate recovery criteria high for MB 280-343884/1-A. Refer to the QC report for details.

Sample D27 (280-88381-6)[4X] required dilution prior to analysis. The reporting limits have been adjusted accordingly.

A deviation from the Standard Operating Procedure (SOP) occurred. Details are as follows: The PFC LCS was not verified at time of extraction.

A deviation from the Standard Operating Procedure (SOP) occurred. The PFC LCS was not verified at time of extraction.

No other difficulties were encountered during the PFC analysis.

All other quality control parameters were within the acceptance limits.

09/30/2016Page 5 of 495

Sample SummaryTestAmerica Job ID: 280-88381-1Client: HDR Inc

Project/Site: Stewart International Airport (PFAS)

Lab Sample ID Client Sample ID ReceivedCollectedMatrix

280-88381-1 PFC-MW-4 Water 09/15/16 12:40 09/17/16 08:45

280-88381-2 CB2K Water 09/15/16 13:40 09/17/16 08:45

280-88381-3 CB9A Water 09/15/16 14:05 09/17/16 08:45

280-88381-4 W6 Water 09/15/16 14:35 09/17/16 08:45

280-88381-5 ANG-CB-EB-091516 Water 09/15/16 14:45 09/17/16 08:45

280-88381-6 D27 Water 09/15/16 15:15 09/17/16 08:45

280-88381-7 D15-A Water 09/15/16 16:00 09/17/16 08:45

280-88381-8 ANG-MW-EB-091516 Water 09/15/16 13:00 09/17/16 08:45

280-88381-9 ANG-CB-FB-091516 Water 09/15/16 16:10 09/17/16 08:45

280-88381-10 STM-UP Water 09/15/16 13:50 09/17/16 08:45

280-88381-11 CB Water 09/14/16 08:57 09/17/16 08:45

280-88381-12 C17 Water 09/14/16 08:30 09/17/16 08:45

280-88381-13 D8 Water 09/14/16 09:30 09/17/16 08:45

280-88381-14 CB-DUP Water 09/14/16 10:00 09/17/16 08:45

280-88381-15 PFC-MW-2 Water 09/14/16 12:05 09/17/16 08:45

280-88381-16 MW-DUP Water 09/14/16 12:30 09/17/16 08:45

280-88381-17 PFC-MW-3 Water 09/14/16 16:25 09/17/16 08:45

280-88381-18 CB-FB-0914-16 Water 09/14/16 16:50 09/17/16 08:45

280-88381-19 CB-EB-091416 Water 09/14/16 16:55 09/17/16 08:45

280-88381-20 ANG-CB-EB-091616 Water 09/16/16 15:40 09/17/16 08:45

280-88381-21 ANG-FB-091616 Water 09/16/16 15:50 09/17/16 08:45

TestAmerica Denver

09/30/2016Page 6 of 495

Detection SummaryTestAmerica Job ID: 280-88381-1Client: HDR Inc


Client Sample ID: PFC-MW-4 Lab Sample ID: 280-88381-1

No Detections.

Client Sample ID: CB2K Lab Sample ID: 280-88381-2

Perfluorobutane Sulfonate (PFBS)

RL

0.018 ug/L

MDL

0.0075

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J0.0091 DV-LC-0012

Perfluoroheptanoic acid (PFHpA) 0.027 ug/L0.012 Total/NA10.51 DV-LC-0012

Perfluorohexane Sulfonate (PFHxS) 0.027 ug/L0.0063 Total/NA10.064 DV-LC-0012

Perfluorononanoic acid (PFNA) 0.036 ug/L0.016 Total/NA10.052 DV-LC-0012

Perfluorooctanesulfonic acid (PFOS) 0.027 ug/L0.012 Total/NA10.071 DV-LC-0012

Perfluorooctanoic acid (PFOA) 0.018 ug/L0.0089 Total/NA10.52 DV-LC-0012

Client Sample ID: CB9A Lab Sample ID: 280-88381-3

Perfluoroheptanoic acid (PFHpA)

RL

0.029 ug/L

MDL

0.013


Total/NA10.19 DV-LC-0012


Perfluorononanoic acid (PFNA) 0.039 ug/L0.017 Total/NA10.031 J DV-LC-0012



Client Sample ID: W6 Lab Sample ID: 280-88381-4


RL

0.028 ug/L

MDL

0.012



Perfluorohexane Sulfonate (PFHxS) 0.028 ug/L0.0065 Total/NA10.020 J DV-LC-0012

Perfluorooctanesulfonic acid (PFOS) 0.028 ug/L0.012 Total/NA10.017 J DV-LC-0012


Client Sample ID: ANG-CB-EB-091516 Lab Sample ID: 280-88381-5

No Detections.

Client Sample ID: D27 Lab Sample ID: 280-88381-6


RL

0.018 ug/L

MDL

0.0072







Perfluorooctanesulfonic acid (PFOS) -

DL

0.11 ug/L0.047 Total/NA43.61 D DV-LC-0012

Client Sample ID: D15-A Lab Sample ID: 280-88381-7


RL

0.028 ug/L

MDL

0.012







TestAmerica Denver

This Detection Summary does not include radiochemical test results.

09/30/2016Page 7 of 495



Client Sample ID: ANG-MW-EB-091516 Lab Sample ID: 280-88381-8

No Detections.

Client Sample ID: ANG-CB-FB-091516 Lab Sample ID: 280-88381-9

No Detections.

Client Sample ID: STM-UP Lab Sample ID: 280-88381-10


RL

0.018 ug/L

MDL

0.0075







Client Sample ID: CB Lab Sample ID: 280-88381-11


RL

0.019 ug/L

MDL

0.0077





Perfluorooctanoic acid (PFOA) 0.019 ug/L0.0091 Total/NA10.013 J DV-LC-0012

Client Sample ID: C17 Lab Sample ID: 280-88381-12


RL

0.020 ug/L

MDL

0.0081







Client Sample ID: D8 Lab Sample ID: 280-88381-13


RL

0.017 ug/L

MDL

0.0072








Client Sample ID: CB-DUP Lab Sample ID: 280-88381-14


RL

0.017 ug/L

MDL

0.0070








TestAmerica Denver


09/30/2016Page 8 of 495




No Detections.

Client Sample ID: MW-DUP Lab Sample ID: 280-88381-16

No Detections.



RL

0.019 ug/L

MDL

0.0080





Perfluorooctanesulfonic acid (PFOS) 0.029 ug/L0.013 Total/NA10.021 J DV-LC-0012


Client Sample ID: CB-FB-0914-16 Lab Sample ID: 280-88381-18

No Detections.

Client Sample ID: CB-EB-091416 Lab Sample ID: 280-88381-19

No Detections.

Client Sample ID: ANG-CB-EB-091616 Lab Sample ID: 280-88381-20

No Detections.

Client Sample ID: ANG-FB-091616 Lab Sample ID: 280-88381-21

No Detections.

TestAmerica Denver


09/30/2016Page 9 of 495

Method SummaryTestAmerica Job ID: 280-88381-1Client: HDR Inc


Method Method Description LaboratoryProtocol

TAL-DENDV-LC-0012 Perfluorinated Hydrocarbons TAL DEN

Protocol References:

TAL-DEN = TestAmerica Laboratories, Denver, Facility Standard Operating Procedure.

Laboratory References:

TAL DEN = TestAmerica Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL (303)736-0100

TestAmerica Denver

09/30/2016Page 10 of 495

Client Sample ResultsTestAmerica Job ID: 280-88381-1Client: HDR Inc


Lab Sample ID: 280-88381-1Client Sample ID: PFC-MW-4Matrix: WaterDate Collected: 09/15/16 12:40

Date Received: 09/17/16 08:45

Method: DV-LC-0012 - Perfluorinated HydrocarbonsRL MDL

Perfluorobutane Sulfonate (PFBS) 0.0077 U 0.019 0.0077 ug/L 09/27/16 10:45 09/29/16 00:46 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.028 0.012 ug/L 09/27/16 10:45 09/29/16 00:46 1Perfluoroheptanoic acid (PFHpA) 0.012 U

0.028 0.0065 ug/L 09/27/16 10:45 09/29/16 00:46 1Perfluorohexane Sulfonate (PFHxS) 0.0065 U

0.037 0.016 ug/L 09/27/16 10:45 09/29/16 00:46 1Perfluorononanoic acid (PFNA) 0.016 U

0.028 0.012 ug/L 09/27/16 10:45 09/29/16 00:46 1Perfluorooctanesulfonic acid (PFOS) 0.012 U

0.019 0.0091 ug/L 09/27/16 10:45 09/29/16 00:46 1Perfluorooctanoic acid (PFOA) 0.0091 U

13C8 PFOA 109 60 - 155 09/27/16 10:45 09/29/16 00:46 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

13C8 PFOS 121 09/27/16 10:45 09/29/16 00:46 145 - 130

Lab Sample ID: 280-88381-2Client Sample ID: CB2KMatrix: WaterDate Collected: 09/15/16 13:40



Perfluorobutane Sulfonate (PFBS) 0.0091 J 0.018 0.0075 ug/L 09/27/16 10:45 09/29/16 00:58 1


0.027 0.012 ug/L 09/27/16 10:45 09/29/16 00:58 1Perfluoroheptanoic acid (PFHpA) 0.51

0.027 0.0063 ug/L 09/27/16 10:45 09/29/16 00:58 1Perfluorohexane Sulfonate (PFHxS)

0.064

0.036 0.016 ug/L 09/27/16 10:45 09/29/16 00:58 1Perfluorononanoic acid (PFNA) 0.052

0.027 0.012 ug/L 09/27/16 10:45 09/29/16 00:58 1Perfluorooctanesulfonic acid (PFOS)

0.071

0.018 0.0089 ug/L 09/27/16 10:45 09/29/16 00:58 1Perfluorooctanoic acid (PFOA) 0.52

13C8 PFOA 113 60 - 155 09/27/16 10:45 09/29/16 00:58 1


13C8 PFOS 124 09/27/16 10:45 09/29/16 00:58 145 - 130

Lab Sample ID: 280-88381-3Client Sample ID: CB9AMatrix: WaterDate Collected: 09/15/16 14:05







0.054

0.039 0.017 ug/L 09/27/16 10:45 09/29/16 01:10 1Perfluorononanoic acid (PFNA) 0.031 J


0.23


13C8 PFOA 115 60 - 155 09/27/16 10:45 09/29/16 01:10 1


13C8 PFOS 113 09/27/16 10:45 09/29/16 01:10 145 - 130

TestAmerica Denver

09/30/2016Page 11 of 495



Lab Sample ID: 280-88381-4Client Sample ID: W6Matrix: WaterDate Collected: 09/15/16 14:35





0.028 0.012 ug/L 09/27/16 10:45 09/29/16 01:22 1Perfluoroheptanoic acid (PFHpA) 0.014 J


0.020 J



0.017 J


13C8 PFOA 109 60 - 155 09/27/16 10:45 09/29/16 01:22 1


13C8 PFOS 109 09/27/16 10:45 09/29/16 01:22 145 - 130

Lab Sample ID: 280-88381-5Client Sample ID: ANG-CB-EB-091516Matrix: WaterDate Collected: 09/15/16 14:45










13C8 PFOA 108 60 - 155 09/27/16 10:45 09/29/16 01:35 1


13C8 PFOS 113 09/27/16 10:45 09/29/16 01:35 145 - 130

Lab Sample ID: 280-88381-6Client Sample ID: D27Matrix: WaterDate Collected: 09/15/16 15:15



Perfluorobutane Sulfonate (PFBS) 0.15 0.018 0.0072 ug/L 09/27/16 10:45 09/29/16 01:47 1




1.22



13C8 PFOA 112 60 - 155 09/27/16 10:45 09/29/16 01:47 1


13C8 PFOS 122 09/27/16 10:45 09/29/16 01:47 145 - 130

Method: DV-LC-0012 - Perfluorinated Hydrocarbons - DLRL MDL

Perfluorooctanesulfonic acid (PFOS)

3.61 D 0.11 0.047 ug/L 09/27/16 10:45 09/29/16 14:05 4


TestAmerica Denver

09/30/2016Page 12 of 495





13C8 PFOA 108 D 60 - 155 09/27/16 10:45 09/29/16 14:05 4


13C8 PFOS 102 D 09/27/16 10:45 09/29/16 14:05 445 - 130

Lab Sample ID: 280-88381-7Client Sample ID: D15-AMatrix: WaterDate Collected: 09/15/16 16:00







0.051



0.037


13C8 PFOA 115 60 - 155 09/27/16 10:45 09/29/16 01:59 1


13C8 PFOS 111 09/27/16 10:45 09/29/16 01:59 145 - 130

Lab Sample ID: 280-88381-8Client Sample ID: ANG-MW-EB-091516Matrix: WaterDate Collected: 09/15/16 13:00










13C8 PFOA 113 60 - 155 09/27/16 10:45 09/29/16 02:24 1


13C8 PFOS 117 09/27/16 10:45 09/29/16 02:24 145 - 130

Lab Sample ID: 280-88381-9Client Sample ID: ANG-CB-FB-091516Matrix: WaterDate Collected: 09/15/16 16:10










TestAmerica Denver

09/30/2016Page 13 of 495



Lab Sample ID: 280-88381-9Client Sample ID: ANG-CB-FB-091516Matrix: WaterDate Collected: 09/15/16 16:10


13C8 PFOA 114 60 - 155 09/27/16 10:45 09/29/16 02:36 1


13C8 PFOS 115 09/27/16 10:45 09/29/16 02:36 145 - 130

Lab Sample ID: 280-88381-10Client Sample ID: STM-UPMatrix: WaterDate Collected: 09/15/16 13:50







0.14



0.22


13C8 PFOA 116 60 - 155 09/27/16 10:45 09/29/16 02:49 1


13C8 PFOS 114 09/27/16 10:45 09/29/16 02:49 145 - 130

Lab Sample ID: 280-88381-11Client Sample ID: CBMatrix: WaterDate Collected: 09/14/16 08:57



Perfluorobutane Sulfonate (PFBS) 0.0084 J 0.019 0.0077 ug/L 09/27/16 10:45 09/29/16 03:01 1




0.029



0.055

0.019 0.0091 ug/L 09/27/16 10:45 09/29/16 03:01 1Perfluorooctanoic acid (PFOA) 0.013 J

13C8 PFOA 114 60 - 155 09/27/16 10:45 09/29/16 03:01 1


13C8 PFOS 117 09/27/16 10:45 09/29/16 03:01 145 - 130

Lab Sample ID: 280-88381-12Client Sample ID: C17Matrix: WaterDate Collected: 09/14/16 08:30







0.16


TestAmerica Denver

09/30/2016Page 14 of 495



Lab Sample ID: 280-88381-12Client Sample ID: C17Matrix: WaterDate Collected: 09/14/16 08:30


Method: DV-LC-0012 - Perfluorinated Hydrocarbons (Continued)RL MDL

Perfluorooctanesulfonic acid (PFOS)

0.46 0.029 0.013 ug/L 09/27/16 10:45 09/29/16 03:38 1



13C8 PFOA 113 60 - 155 09/27/16 10:45 09/29/16 03:38 1


13C8 PFOS 126 09/27/16 10:45 09/29/16 03:38 145 - 130








0.33



0.74


13C8 PFOA 115 60 - 155 09/27/16 10:45 09/29/16 03:50 1


13C8 PFOS 120 09/27/16 10:45 09/29/16 03:50 145 - 130

Lab Sample ID: 280-88381-14Client Sample ID: CB-DUPMatrix: WaterDate Collected: 09/14/16 10:00







0.30



0.98


13C8 PFOA 115 60 - 155 09/27/16 10:45 09/29/16 04:03 1


13C8 PFOS 123 09/27/16 10:45 09/29/16 04:03 145 - 130

TestAmerica Denver

09/30/2016Page 15 of 495













13C8 PFOA 111 60 - 155 09/27/16 10:45 09/29/16 04:15 1


13C8 PFOS 123 09/27/16 10:45 09/29/16 04:15 145 - 130

Lab Sample ID: 280-88381-16Client Sample ID: MW-DUPMatrix: WaterDate Collected: 09/14/16 12:30










13C8 PFOA 104 60 - 155 09/27/16 10:55 09/28/16 20:39 1


13C8 PFOS 120 09/27/16 10:55 09/28/16 20:39 145 - 130








0.15



0.021 J


13C8 PFOA 112 60 - 155 09/27/16 10:55 09/28/16 20:51 1


13C8 PFOS 118 09/27/16 10:55 09/28/16 20:51 145 - 130

TestAmerica Denver

09/30/2016Page 16 of 495



Lab Sample ID: 280-88381-18Client Sample ID: CB-FB-0914-16Matrix: WaterDate Collected: 09/14/16 16:50










13C8 PFOA 111 60 - 155 09/27/16 10:55 09/28/16 21:28 1


13C8 PFOS 114 09/27/16 10:55 09/28/16 21:28 145 - 130

Lab Sample ID: 280-88381-19Client Sample ID: CB-EB-091416Matrix: WaterDate Collected: 09/14/16 16:55










13C8 PFOA 110 60 - 155 09/27/16 10:55 09/28/16 21:41 1


13C8 PFOS 113 09/27/16 10:55 09/28/16 21:41 145 - 130

Lab Sample ID: 280-88381-20Client Sample ID: ANG-CB-EB-091616Matrix: WaterDate Collected: 09/16/16 15:40










13C8 PFOA 112 60 - 155 09/27/16 10:55 09/28/16 22:05 1


13C8 PFOS 118 09/27/16 10:55 09/28/16 22:05 145 - 130

TestAmerica Denver

09/30/2016Page 17 of 495



Lab Sample ID: 280-88381-21Client Sample ID: ANG-FB-091616Matrix: WaterDate Collected: 09/16/16 15:50










13C8 PFOA 115 60 - 155 09/27/16 10:55 09/28/16 22:18 1


13C8 PFOS 117 09/27/16 10:55 09/28/16 22:18 145 - 130

TestAmerica Denver

09/30/2016Page 18 of 495

Surrogate SummaryTestAmerica Job ID: 280-88381-1Client: HDR Inc


Method: DV-LC-0012 - Perfluorinated HydrocarbonsPrep Type: Total/NAMatrix: Water

Lab Sample ID Client Sample ID (60-155) (45-130)

13C8 PFOA13C8 PFOS

109 121280-88381-1

Percent Surrogate Recovery (Acceptance Limits)

PFC-MW-4

113 124280-88381-2 CB2K

115 113280-88381-3 CB9A

109 109280-88381-4 W6

108 113280-88381-5 ANG-CB-EB-091516

112 122280-88381-6 D27

108 D 102 D280-88381-6 - DL D27

115 111280-88381-7 D15-A

113 117280-88381-8 ANG-MW-EB-091516

114 115280-88381-9 ANG-CB-FB-091516

116 114280-88381-10 STM-UP

114 117280-88381-11 CB

113 115280-88381-11 MS CB

113 128280-88381-11 MSD CB

113 126280-88381-12 C17

115 120280-88381-13 D8

115 123280-88381-14 CB-DUP

111 123280-88381-15 PFC-MW-2

104 120280-88381-16 MW-DUP

112 118280-88381-17 PFC-MW-3

113 122280-88381-17 MS PFC-MW-3

113 122280-88381-17 MSD PFC-MW-3

111 114280-88381-18 CB-FB-0914-16

110 113280-88381-19 CB-EB-091416

112 118280-88381-20 ANG-CB-EB-091616

115 117280-88381-21 ANG-FB-091616

107 105DLCK 280-343000/14 Lab Control Sample

114 118LCS 280-343884/2-A Lab Control Sample

111 128LCS 280-343904/2-A Lab Control Sample

109 124LCSD 280-343884/3-A Lab Control Sample Dup

110 120LCSD 280-343904/3-A Lab Control Sample Dup

112 131 XMB 280-343884/1-A Method Blank

113 118MB 280-343904/1-A Method Blank

Surrogate Legend

13C8 PFOA = 13C8 PFOA

13C8 PFOS = 13C8 PFOS

TestAmerica Denver

09/30/2016Page 19 of 495

QC Sample ResultsTestAmerica Job ID: 280-88381-1Client: HDR Inc


Method: DV-LC-0012 - Perfluorinated Hydrocarbons

Client Sample ID: Lab Control SampleLab Sample ID: DLCK 280-343000/14Matrix: Water Prep Type: Total/NAAnalysis Batch: 343000

Perfluorobutane Sulfonate

(PFBS)

0.443 0.398 ug/L 90 70 - 130

Analyte

DLCK DLCK

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

Perfluoroheptanoic acid (PFHpA) 0.500 0.490 ug/L 98 70 - 130

Perfluorohexane Sulfonate

(PFHxS)

0.473 0.502 ug/L 106 70 - 130

Perfluorononanoic acid (PFNA) 0.500 0.513 ug/L 103 70 - 130

Perfluorooctanesulfonic acid

(PFOS)

0.478 0.539 ug/L 113 70 - 130

Perfluorooctanoic acid (PFOA) 0.500 0.465 ug/L 93 70 - 130

13C8 PFOA 60 - 155

Surrogate

107

DLCK DLCK

Qualifier Limits%Recovery

10513C8 PFOS 45 - 130

Client Sample ID: Method BlankLab Sample ID: MB 280-343884/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 344280 Prep Batch: 343884

RL MDL


MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

0.013 U 0.0130.030 ug/L 09/27/16 10:45 09/29/16 00:08 1Perfluoroheptanoic acid (PFHpA)

0.0070 U 0.00700.030 ug/L 09/27/16 10:45 09/29/16 00:08 1Perfluorohexane Sulfonate (PFHxS)

0.017 U 0.0170.040 ug/L 09/27/16 10:45 09/29/16 00:08 1Perfluorononanoic acid (PFNA)

0.013 U 0.0130.030 ug/L 09/27/16 10:45 09/29/16 00:08 1Perfluorooctanesulfonic acid (PFOS)

0.0098 U 0.00980.020 ug/L 09/27/16 10:45 09/29/16 00:08 1Perfluorooctanoic acid (PFOA)

13C8 PFOA 112 60 - 155 09/29/16 00:08 1

MB MB

Surrogate

09/27/16 10:45

Dil FacPrepared AnalyzedQualifier Limits%Recovery

131 X 09/27/16 10:45 09/29/16 00:08 113C8 PFOS 45 - 130

Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-343884/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 344280 Prep Batch: 343884


(PFBS)

0.177 0.138 ug/L 78 70 - 134

Analyte

LCS LCS


Spike

Added

%Rec.

Limits



(PFHxS)

0.189 0.169 ug/L 89 70 - 132



(PFOS)

0.191 0.167 ug/L 87 70 - 130


13C8 PFOA 60 - 155

Surrogate

114

LCS LCS


11813C8 PFOS 45 - 130

TestAmerica Denver

09/30/2016Page 20 of 495



Method: DV-LC-0012 - Perfluorinated Hydrocarbons (Continued)

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-343884/3-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 344280 Prep Batch: 343884


(PFBS)

0.177 0.153 ug/L 86 70 - 134 10 30

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Perfluoroheptanoic acid (PFHpA) 0.200 0.169 ug/L 84 70 - 135 2 30


(PFHxS)

0.189 0.176 ug/L 93 70 - 132 4 30

Perfluorononanoic acid (PFNA) 0.200 0.171 ug/L 85 69 - 143 2 30


(PFOS)

0.191 0.167 ug/L 87 70 - 130 0 20

Perfluorooctanoic acid (PFOA) 0.200 0.189 ug/L 94 70 - 130 2 20

13C8 PFOA 60 - 155

Surrogate

109

LCSD LCSD


12413C8 PFOS 45 - 130

Client Sample ID: CBLab Sample ID: 280-88381-11 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 344280 Prep Batch: 343884


(PFBS)

0.0084 J 0.153 0.142 ug/L 87 70 - 134

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Perfluoroheptanoic acid (PFHpA) 0.012 U 0.173 0.166 ug/L 96 70 - 135


(PFHxS)

0.029 0.164 0.187 ug/L 97 70 - 132

Perfluorononanoic acid (PFNA) 0.016 U 0.173 0.159 ug/L 92 69 - 143


(PFOS)

0.055 0.166 0.189 ug/L 81 70 - 130

Perfluorooctanoic acid (PFOA) 0.013 J 0.173 0.182 ug/L 98 70 - 130

13C8 PFOA 60 - 155

Surrogate

113

MS MS


11513C8 PFOS 45 - 130

Client Sample ID: CBLab Sample ID: 280-88381-11 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 344280 Prep Batch: 343884


(PFBS)

0.0084 J 0.144 0.129 ug/L 84 70 - 134 10 30

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Perfluoroheptanoic acid (PFHpA) 0.012 U 0.162 0.156 ug/L 96 70 - 135 7 30


(PFHxS)

0.029 0.154 0.175 ug/L 95 70 - 132 7 30

Perfluorononanoic acid (PFNA) 0.016 U 0.162 0.149 ug/L 92 69 - 143 7 30


(PFOS)

0.055 0.155 0.191 ug/L 87 70 - 130 1 30

Perfluorooctanoic acid (PFOA) 0.013 J 0.162 0.176 ug/L 100 70 - 130 3 30

TestAmerica Denver

09/30/2016Page 21 of 495




Client Sample ID: CBLab Sample ID: 280-88381-11 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 344280 Prep Batch: 343884

13C8 PFOA 60 - 155

Surrogate

113

MSD MSD


12813C8 PFOS 45 - 130

Client Sample ID: Method BlankLab Sample ID: MB 280-343904/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 344279 Prep Batch: 343904

RL MDL


MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

0.013 U 0.0130.030 ug/L 09/27/16 10:55 09/28/16 20:02 1Perfluoroheptanoic acid (PFHpA)

0.0070 U 0.00700.030 ug/L 09/27/16 10:55 09/28/16 20:02 1Perfluorohexane Sulfonate (PFHxS)

0.017 U 0.0170.040 ug/L 09/27/16 10:55 09/28/16 20:02 1Perfluorononanoic acid (PFNA)

0.013 U 0.0130.030 ug/L 09/27/16 10:55 09/28/16 20:02 1Perfluorooctanesulfonic acid (PFOS)

0.0098 U 0.00980.020 ug/L 09/27/16 10:55 09/28/16 20:02 1Perfluorooctanoic acid (PFOA)

13C8 PFOA 113 60 - 155 09/28/16 20:02 1

MB MB

Surrogate

09/27/16 10:55

Dil FacPrepared AnalyzedQualifier Limits%Recovery

118 09/27/16 10:55 09/28/16 20:02 113C8 PFOS 45 - 130

Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-343904/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 344279 Prep Batch: 343904


(PFBS)

0.177 0.160 ug/L 90 70 - 134

Analyte

LCS LCS


Spike

Added

%Rec.

Limits



(PFHxS)

0.189 0.180 ug/L 95 70 - 132



(PFOS)

0.191 0.178 ug/L 93 70 - 130


13C8 PFOA 60 - 155

Surrogate

111

LCS LCS


12813C8 PFOS 45 - 130



(PFBS)

0.177 0.166 ug/L 94 70 - 134 4 30

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Perfluoroheptanoic acid (PFHpA) 0.200 0.179 ug/L 89 70 - 135 2 30


(PFHxS)

0.189 0.191 ug/L 101 70 - 132 6 30

Perfluorononanoic acid (PFNA) 0.200 0.181 ug/L 91 69 - 143 1 30

TestAmerica Denver

09/30/2016Page 22 of 495






(PFOS)

0.191 0.170 ug/L 89 70 - 130 4 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD

Perfluorooctanoic acid (PFOA) 0.200 0.199 ug/L 99 70 - 130 2 20

13C8 PFOA 60 - 155

Surrogate

110

LCSD LCSD


12013C8 PFOS 45 - 130

Client Sample ID: PFC-MW-3Lab Sample ID: 280-88381-17 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 344279 Prep Batch: 343904


(PFBS)

0.10 0.170 0.279 ug/L 102 70 - 134

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Perfluoroheptanoic acid (PFHpA) 0.060 0.192 0.219 ug/L 83 70 - 135


(PFHxS)

0.15 0.181 0.331 ug/L 101 70 - 132

Perfluorononanoic acid (PFNA) 0.017 U 0.192 0.177 ug/L 92 69 - 143


(PFOS)

0.021 J 0.183 0.200 ug/L 98 70 - 130

Perfluorooctanoic acid (PFOA) 0.037 0.192 0.225 ug/L 98 70 - 130

13C8 PFOA 60 - 155

Surrogate

113

MS MS


12213C8 PFOS 45 - 130

Client Sample ID: PFC-MW-3Lab Sample ID: 280-88381-17 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 344279 Prep Batch: 343904


(PFBS)

0.10 0.166 0.276 ug/L 103 70 - 134 1 30

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Perfluoroheptanoic acid (PFHpA) 0.060 0.188 0.234 ug/L 93 70 - 135 7 30


(PFHxS)

0.15 0.178 0.330 ug/L 102 70 - 132 0 30

Perfluorononanoic acid (PFNA) 0.017 U 0.188 0.169 ug/L 90 69 - 143 4 30


(PFOS)

0.021 J 0.180 0.181 ug/L 89 70 - 130 10 30

Perfluorooctanoic acid (PFOA) 0.037 0.188 0.231 ug/L 103 70 - 130 3 30

13C8 PFOA 60 - 155

Surrogate

113

MSD MSD


12213C8 PFOS 45 - 130

TestAmerica Denver

09/30/2016Page 23 of 495

Definitions/GlossaryTestAmerica Job ID: 280-88381-1Client: HDR Inc


Qualifiers

LCMS

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

D Sample results are obtained from a dilution; the surrogate or matrix spike recoveries reported are calculated from diluted samples.

X Surrogate is outside control limits

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Denver

09/30/2016Page 24 of 495

QC Association SummaryTestAmerica Job ID: 280-88381-1Client: HDR Inc


LCMS

Analysis Batch: 343000

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Water DV-LC-0012DLCK 280-343000/14 Lab Control Sample Total/NA

Prep Batch: 343884


Water 3535280-88381-1 PFC-MW-4 Total/NA

Water 3535280-88381-2 CB2K Total/NA

Water 3535280-88381-3 CB9A Total/NA

Water 3535280-88381-4 W6 Total/NA

Water 3535280-88381-5 ANG-CB-EB-091516 Total/NA

Water 3535280-88381-6 D27 Total/NA

Water 3535280-88381-6 - DL D27 Total/NA

Water 3535280-88381-7 D15-A Total/NA

Water 3535280-88381-8 ANG-MW-EB-091516 Total/NA

Water 3535280-88381-9 ANG-CB-FB-091516 Total/NA

Water 3535280-88381-10 STM-UP Total/NA

Water 3535280-88381-11 CB Total/NA

Water 3535280-88381-12 C17 Total/NA

Water 3535280-88381-13 D8 Total/NA

Water 3535280-88381-14 CB-DUP Total/NA


Water 3535MB 280-343884/1-A Method Blank Total/NA

Water 3535LCS 280-343884/2-A Lab Control Sample Total/NA

Water 3535LCSD 280-343884/3-A Lab Control Sample Dup Total/NA

Water 3535280-88381-11 MS CB Total/NA

Water 3535280-88381-11 MSD CB Total/NA

Prep Batch: 343904


Water 3535280-88381-16 MW-DUP Total/NA


Water 3535280-88381-18 CB-FB-0914-16 Total/NA

Water 3535280-88381-19 CB-EB-091416 Total/NA

Water 3535280-88381-20 ANG-CB-EB-091616 Total/NA

Water 3535280-88381-21 ANG-FB-091616 Total/NA

Water 3535MB 280-343904/1-A Method Blank Total/NA

Water 3535LCS 280-343904/2-A Lab Control Sample Total/NA

Water 3535LCSD 280-343904/3-A Lab Control Sample Dup Total/NA

Water 3535280-88381-17 MS PFC-MW-3 Total/NA

Water 3535280-88381-17 MSD PFC-MW-3 Total/NA



Water DV-LC-0012 343904280-88381-16 MW-DUP Total/NA

Water DV-LC-0012 343904280-88381-17 PFC-MW-3 Total/NA

Water DV-LC-0012 343904280-88381-18 CB-FB-0914-16 Total/NA

Water DV-LC-0012 343904280-88381-19 CB-EB-091416 Total/NA

Water DV-LC-0012 343904280-88381-20 ANG-CB-EB-091616 Total/NA

Water DV-LC-0012 343904280-88381-21 ANG-FB-091616 Total/NA

Water DV-LC-0012 343904MB 280-343904/1-A Method Blank Total/NA

Water DV-LC-0012 343904LCS 280-343904/2-A Lab Control Sample Total/NA

Water DV-LC-0012 343904LCSD 280-343904/3-A Lab Control Sample Dup Total/NA

TestAmerica Denver

09/30/2016Page 25 of 495

QC Association SummaryTestAmerica Job ID: 280-88381-1Client: HDR Inc


LCMS (Continued)

Analysis Batch: 344279 (Continued)


Water DV-LC-0012 343904280-88381-17 MS PFC-MW-3 Total/NA

Water DV-LC-0012 343904280-88381-17 MSD PFC-MW-3 Total/NA




Water DV-LC-0012 343884280-88381-2 CB2K Total/NA

Water DV-LC-0012 343884280-88381-3 CB9A Total/NA

Water DV-LC-0012 343884280-88381-4 W6 Total/NA

Water DV-LC-0012 343884280-88381-5 ANG-CB-EB-091516 Total/NA

Water DV-LC-0012 343884280-88381-6 D27 Total/NA

Water DV-LC-0012 343884280-88381-7 D15-A Total/NA

Water DV-LC-0012 343884280-88381-8 ANG-MW-EB-091516 Total/NA

Water DV-LC-0012 343884280-88381-9 ANG-CB-FB-091516 Total/NA

Water DV-LC-0012 343884280-88381-10 STM-UP Total/NA

Water DV-LC-0012 343884280-88381-11 CB Total/NA

Water DV-LC-0012 343884280-88381-12 C17 Total/NA

Water DV-LC-0012 343884280-88381-13 D8 Total/NA

Water DV-LC-0012 343884280-88381-14 CB-DUP Total/NA


Water DV-LC-0012 343884MB 280-343884/1-A Method Blank Total/NA

Water DV-LC-0012 343884LCS 280-343884/2-A Lab Control Sample Total/NA

Water DV-LC-0012 343884LCSD 280-343884/3-A Lab Control Sample Dup Total/NA

Water DV-LC-0012 343884280-88381-11 MS CB Total/NA

Water DV-LC-0012 343884280-88381-11 MSD CB Total/NA



Water DV-LC-0012 343884280-88381-6 - DL D27 Total/NA

TestAmerica Denver

09/30/2016Page 26 of 495

Lab ChronicleClient: HDR Inc TestAmerica Job ID: 280-88381-1Project/Site: Stewart International Airport (PFAS)

Client Sample ID: PFC-MW-4 Lab Sample ID: 280-88381-1Matrix: WaterDate Collected: 09/15/16 12:40


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 267.8 mL 5 mL

Analysis DV-LC-0012 1 344280 09/29/16 00:46 HKF TAL DENTotal/NA

Client Sample ID: CB2K Lab Sample ID: 280-88381-2Matrix: WaterDate Collected: 09/15/16 13:40


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: CB9A Lab Sample ID: 280-88381-3Matrix: WaterDate Collected: 09/15/16 14:05


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: W6 Lab Sample ID: 280-88381-4Matrix: WaterDate Collected: 09/15/16 14:35


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: ANG-CB-EB-091516 Lab Sample ID: 280-88381-5Matrix: WaterDate Collected: 09/15/16 14:45


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 293 mL 5 mL


Client Sample ID: D27 Lab Sample ID: 280-88381-6Matrix: WaterDate Collected: 09/15/16 15:15


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



TestAmerica Denver

09/30/2016Page 27 of 495




Prep 3535 ACF09/27/16 10:45DL TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil


Analysis DV-LC-0012 DL 4 344348 09/29/16 14:05 HKF TAL DENTotal/NA

Client Sample ID: D15-A Lab Sample ID: 280-88381-7Matrix: WaterDate Collected: 09/15/16 16:00


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: ANG-MW-EB-091516 Lab Sample ID: 280-88381-8Matrix: WaterDate Collected: 09/15/16 13:00


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: ANG-CB-FB-091516 Lab Sample ID: 280-88381-9Matrix: WaterDate Collected: 09/15/16 16:10


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: STM-UP Lab Sample ID: 280-88381-10Matrix: WaterDate Collected: 09/15/16 13:50


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: CB Lab Sample ID: 280-88381-11Matrix: WaterDate Collected: 09/14/16 08:57


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



TestAmerica Denver

09/30/2016Page 28 of 495


Client Sample ID: C17 Lab Sample ID: 280-88381-12Matrix: WaterDate Collected: 09/14/16 08:30


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil





Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: CB-DUP Lab Sample ID: 280-88381-14Matrix: WaterDate Collected: 09/14/16 10:00


Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil





Prep 3535 ACF09/27/16 10:45 TAL DEN343884

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: MW-DUP Lab Sample ID: 280-88381-16Matrix: WaterDate Collected: 09/14/16 12:30


Prep 3535 ACF09/27/16 10:55 TAL DEN343904

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil





Prep 3535 ACF09/27/16 10:55 TAL DEN343904

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



TestAmerica Denver

09/30/2016Page 29 of 495


Client Sample ID: CB-FB-0914-16 Lab Sample ID: 280-88381-18Matrix: WaterDate Collected: 09/14/16 16:50


Prep 3535 ACF09/27/16 10:55 TAL DEN343904

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: CB-EB-091416 Lab Sample ID: 280-88381-19Matrix: WaterDate Collected: 09/14/16 16:55


Prep 3535 ACF09/27/16 10:55 TAL DEN343904

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: ANG-CB-EB-091616 Lab Sample ID: 280-88381-20Matrix: WaterDate Collected: 09/16/16 15:40


Prep 3535 ACF09/27/16 10:55 TAL DEN343904

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Client Sample ID: ANG-FB-091616 Lab Sample ID: 280-88381-21Matrix: WaterDate Collected: 09/16/16 15:50


Prep 3535 ACF09/27/16 10:55 TAL DEN343904

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



Laboratory References:

TAL DEN = TestAmerica Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL (303)736-0100

TestAmerica Denver

09/30/2016Page 30 of 495

Certification SummaryClient: HDR Inc TestAmerica Job ID: 280-88381-1Project/Site: Stewart International Airport (PFAS)

Laboratory: TestAmerica DenverUnless otherwise noted, all analytes for this laboratory were covered under each certification below.

Authority Program EPA Region Certification ID Expiration Date

New York 119642NELAP 04-01-17

Analysis Method Prep Method Matrix Analyte

The following analytes are included in this report, but certification is not offered by the governing authority:

DV-LC-0012 3535 Water Perfluorobutane Sulfonate (PFBS)

DV-LC-0012 3535 Water Perfluoroheptanoic acid (PFHpA)

DV-LC-0012 3535 Water Perfluorohexane Sulfonate (PFHxS)

DV-LC-0012 3535 Water Perfluorononanoic acid (PFNA)

DV-LC-0012 3535 Water Perfluorooctanesulfonic acid (PFOS)

DV-LC-0012 3535 Water Perfluorooctanoic acid (PFOA)

Oregon NELAP 10 4025 01-09-17

Analysis Method Prep Method Matrix Analyte

Laboratory: TestAmerica SacramentoThe certifications listed below are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

Oregon 404010NELAP 01-29-17

TestAmerica Denver

09/30/2016Page 31 of 495

Method PFCPerfluronated Hydrocarbons (LC/MS)

by Method PFC

09/30/2016Page 32 of 495

FORM IILCMS SURROGATE RECOVERY

Lab Name: Job No.: 280-88381-1

SDG No.:

Matrix: Water Level: Low

TestAmerica Denver

GC Column (1): Gemini-NX ID:

#Lab Sample IDClient Sample ID #PFOA PFOS

280-88381-1PFC-MW-4 109 121

280-88381-2CB2K 113 124

280-88381-3CB9A 115 113

280-88381-4W6 109 109

280-88381-5ANG-CB-EB-091516 108 113

280-88381-6D27 112 122

280-88381-6 DLD27 DL 108 D 102 D

280-88381-7D15-A 115 111

280-88381-8ANG-MW-EB-091516 113 117

280-88381-9ANG-CB-FB-091516 114 115

280-88381-10STM-UP 116 114

280-88381-11CB 114 117

280-88381-12C17 113 126

280-88381-13D8 115 120

280-88381-14CB-DUP 115 123

280-88381-15PFC-MW-2 111 123

280-88381-16MW-DUP 104 120

280-88381-17PFC-MW-3 112 118

280-88381-18CB-FB-0914-16 111 114

280-88381-19CB-EB-091416 110 113

280-88381-20ANG-CB-EB-091616 112 118

280-88381-21ANG-FB-091616 115 117

MB 280-343884/1-A

112 131 X

MB 280-343904/1-A

113 118

LCS 280-343884/2-A

114 118

LCS 280-343904/2-A

111 128

LCSD 280-343884/3-A

109 124

LCSD 280-343904/3-A

110 120

280-88381-11 MSCB MS 113 115

280-88381-17 MSPFC-MW-3 MS 113 122

280-88381-11 MSDCB MSD 113 128

280-88381-17 MSDPFC-MW-3 MSD 113 122

QC LIMITSPFOA = 13C8 PFOA 60-155PFOS = 13C8 PFOS 45-130

FORM II DV-LC-0012

# Column to be used to flag recovery values

09/30/2016Page 33 of 495

FORM IILCMS SURROGATE RECOVERY

Lab Name: Job No.: 280-88381-1

SDG No.:

Matrix: Water Level: Low

TestAmerica Denver

GC Column (1): Gemini-NX ID:

#Lab Sample IDClient Sample ID #PFOA PFOS

DLCK 280-343000/14

107 105

QC LIMITSPFOA = 13C8 PFOA 60-155PFOS = 13C8 PFOS 45-130

FORM II DV-LC-0012

# Column to be used to flag recovery values

09/30/2016Page 34 of 495

LCMS LAB CONTROL SAMPLE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1

Lab File ID: PC516I028102.dWater

Lab ID: LCS 280-343884/2-A Client ID:

TestAmerica Denver

REC %REC

QCLIMITSCONCENTRATION

(ug/L)

SPIKEADDED(ug/L)

#LCS LCS

COMPOUNDPerfluorobutane Sulfonate (PFBS)

0.177 0.138 70-13478


0.200 0.172 70-13586

Perfluorohexane Sulfonate (PFHxS)

0.189 0.169 70-13289

Perfluorononanoic acid (PFNA) 0.200 0.168 69-14384Perfluorooctanesulfonic acid (PFOS)

0.191 0.167 70-13087

Perfluorooctanoic acid (PFOA) 0.200 0.192 70-13096

FORM III DV-LC-0012

# Column to be used to flag recovery and RPD values

09/30/2016Page 35 of 495

LCMS LAB CONTROL SAMPLE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: LCS 280-343904/2-A Client ID:

TestAmerica Denver

REC %REC


(ug/L)

SPIKEADDED(ug/L)

#LCS LCS


0.177 0.160 70-13490


0.200 0.175 70-13588


0.189 0.180 70-13295


0.191 0.178 70-13093


FORM III DV-LC-0012


09/30/2016Page 36 of 495

LCMS LAB CONTROL SAMPLE DUPLICATE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: LCSD 280-343884/3-A Client ID:

TestAmerica Denver

COMPOUND

SPIKEADDED CONCENTRATION %

REC%RPD

QC LIMITS

RPD REC (ug/L) (ug/L)#

LCSD LCSD

0.177 0.153 30 70-134Perfluorobutane Sulfonate (PFBS)

1086

0.200 0.169 30 70-135Perfluoroheptanoic acid (PFHpA)

284

0.189 0.176 30 70-132Perfluorohexane Sulfonate (PFHxS)

493

0.200 0.171 30 69-143Perfluorononanoic acid (PFNA) 2850.191 0.167 20 70-130Perfluorooctanesulfonic acid

(PFOS)087

0.200 0.189 20 70-130Perfluorooctanoic acid (PFOA) 294

FORM III DV-LC-0012


09/30/2016Page 37 of 495

LCMS LAB CONTROL SAMPLE DUPLICATE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: LCSD 280-343904/3-A Client ID:

TestAmerica Denver

COMPOUND


REC%RPD

QC LIMITS


LCSD LCSD


494


289


6101


(PFOS)489


FORM III DV-LC-0012


09/30/2016Page 38 of 495

LCMS MATRIX SPIKE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: 280-88381-11 MS Client ID: CB MS

TestAmerica Denver

LIMITSCOMPOUND

CONCENTRATION %REC

QC

REC

SAMPLECONCENTRATION

SPIKEADDED(ug/L) (ug/L) (ug/L)

#MS MS

0.153 0.142 70-134Perfluorobutane Sulfonate (PFBS)

870.0084 J

0.173 0.166 70-135Perfluoroheptanoic acid (PFHpA)

960.012 U

0.164 0.187 70-132Perfluorohexane Sulfonate (PFHxS)

970.029

0.173 0.159 69-143Perfluorononanoic acid (PFNA) 920.016 U0.166 0.189 70-130Perfluorooctanesulfonic acid

(PFOS)810.055

0.173 0.182 70-130Perfluorooctanoic acid (PFOA) 980.013 J

FORM III DV-LC-0012


09/30/2016Page 39 of 495

LCMS MATRIX SPIKE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: 280-88381-17 MS Client ID: PFC-MW-3 MS

TestAmerica Denver

LIMITSCOMPOUND

CONCENTRATION %REC

QC

REC

SAMPLECONCENTRATION

SPIKEADDED(ug/L) (ug/L) (ug/L)

#MS MS

0.170 0.279 70-134Perfluorobutane Sulfonate (PFBS)

1020.10

0.192 0.219 70-135Perfluoroheptanoic acid (PFHpA)

830.060

0.181 0.331 70-132Perfluorohexane Sulfonate (PFHxS)

1010.15

0.192 0.177 69-143Perfluorononanoic acid (PFNA) 920.017 U0.183 0.200 70-130Perfluorooctanesulfonic acid

(PFOS)980.021 J

0.192 0.225 70-130Perfluorooctanoic acid (PFOA) 980.037

FORM III DV-LC-0012


09/30/2016Page 40 of 495

LCMS MATRIX SPIKE DUPLICATE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: 280-88381-11 MSD Client ID: CB MSD

TestAmerica Denver

COMPOUND


REC%RPD

QC LIMITS


MSD MSD


1084


796


795


(PFOS)187


FORM III DV-LC-0012


09/30/2016Page 41 of 495

LCMS MATRIX SPIKE DUPLICATE RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: 280-88381-17 MSD Client ID: PFC-MW-3 MSD

TestAmerica Denver

COMPOUND


REC%RPD

QC LIMITS


MSD MSD


1103


793


0102


(PFOS)1089


FORM III DV-LC-0012


09/30/2016Page 42 of 495

LCMS DETECTION LIMIT CHECK STANDARD RECOVERYFORM III

Job No.:Lab Name:

SDG No.:

Level:Matrix: Low

280-88381-1


Lab ID: DLCK 280-343000/14 Client ID:

TestAmerica Denver

REC %REC


(ug/L)

SPIKEADDED(ug/L)

#DLCK DLCK


0.443 0.398 70-13090


0.500 0.490 70-13098


0.473 0.502 70-130106


0.478 0.539 70-130113


FORM III DV-LC-0012


09/30/2016Page 43 of 495

FORM IVLCMS METHOD BLANK SUMMARY

Lab Name:

SDG No.:

Job No.: 280-88381-1TestAmerica Denver

Instrument ID:

Level:(Low/Med)

Date Extracted:

Date Analyzed: 09/29/2016 00:08

09/27/2016 10:45

Low

LC_LCMS5

Lab File ID: PC516I028101.d Lab Sample ID: MB 280-343884/1-A

Matrix: Water

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:

LAB SAMPLE IDLAB

FILE ID DATE ANALYZEDCLIENT SAMPLE ID 09/29/2016 00:21PC516I02810

2.dLCS 280-343884/2-A

09/29/2016 00:33PC516I028103.d

LCSD 280-343884/3-A

09/29/2016 00:46PC516I028104.d

280-88381-1PFC-MW-4

09/29/2016 00:58PC516I028105.d

280-88381-2CB2K

09/29/2016 01:10PC516I028106.d

280-88381-3CB9A

09/29/2016 01:22PC516I028107.d

280-88381-4W6

09/29/2016 01:35PC516I028108.d

280-88381-5ANG-CB-EB-091516

09/29/2016 01:47PC