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Start-up of a new CO2capture unit in a pulp millMay 2019
Richard Surprenant, ing.SVP Process Engineering and CTO
FORWARD LOOKING STATEMENTS
All statements in this presentation that are other than statements of historical facts are forward-looking statements which contain our current expectations about our future results. Forward-looking statements involve numerous risks and uncertainties. We have attempted to identify any forward-looking statements by using words such as “anticipates”, “believes”, “could”, “expects”, “intends”, “may”, “should” and other similar expressions. Although we believe that the expectations reflected in all of our forward-looking statements are reasonable, we can give no assurance that such expectations will prove to be correct. A number of factors may affect our future results and may cause thoseresults to differ materially from those indicated in any forward-looking statements made by us or on our behalf. Such factors include our early stage of technology development; our need for capital to finance necessary research and product development; our ability to attract and retain key employees and strategic partners; our ability to achieve and maintain profitability; fluctuations in the trading price and volume of our stock; competition from other providers of similar products and services; and other unanticipated futureevents and conditions. For further information concerning risks and uncertainties that may affect our future results, please review the disclosures as may be contained from time to time in our filings with SEDAR. Other than as required by applicable securities laws, we undertake no obligation to publicly update or revise any of our forward-looking statements, whether as a result of changed circumstances, new information, future events, or for any other reason occurring after the date of this presentation. This presentation does not constitute an offer to sell or solicitation of an offer to buy securities in any jurisdiction.
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CO2 SOLUTIONS INC. – BACKGROUND INFORMATION
Publicly traded on TSX-V (CST-V)
• 92 patents granted and pending (as of September 30, 2018)
Proprietary CO2 capture and separation technologies based on the use of the
carbonic anhydrase (CA) enzyme
• Lowest opex among known technologies
• Standard equipment configurations
• Environmentally friendly process
• Demonstrated at large scale
• Commercial stage (TRL 8)
• Output of high purity CO2
Value Proposition Leadership in Carbon Capture & Utilization through Valorisation
Carbone Québec project• CO2 capture from post-combustion
industrial flue gas streams produced by any fuel source
• CO2 separation from biogas, native gas or process gas
Applications
• Head office and labs in Quebec City (QC)
• 25 employees, including 6 PhD’s
Canadian Company
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𝑪𝑶𝟐 + 𝑯𝟐𝑶𝑪𝑨𝑯𝑪𝑶𝟑
− +𝑯+
Active metallic
site
CARBONIC ANHYDRASE – Nature’s Perfect Catalyst
Molecular Weight ~30,000
Dissolved in solution / free flowing
Thermostable and process stable
Resistant to high pH (9.5-10.5)
Originating from extreme environments (P, T, Salinity)
Directionally evolved for industrial conditions
Proprietary to CO2 Solutions
Produced by third party enzyme manufacturing contractors
pH
Catalyses CO2 hydration reactions
4
𝐻𝐶𝑂3− + 𝐻+
𝐶𝑂2 (aqueous)
𝐶𝑂2 (gas)
𝐾2𝐶𝑂3+𝐻𝐶𝑂3− + 𝐻+↔ 2 KHCO3
Gas/Liquid interface
Carbonic Anhydrase
Carbonate Bicarbonate
CHEMICAL SYSTEM REACTIONS
WATERDemineralized
CATALYST< 1 g / litre
POTASSIUM CARBONATECommodity Chemical
One of the fastest catalystsin nature:
kcat = ~106S
-1
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CO 2
Reclaimer
Absorber
Stripper
L-R Heat Xger
Flue gas
Exhaust gas
Blower
Trimmer
Water wash tower
Water washdrum
Exhaust cooler
Reboiler
CO2
Wastes
Conditionning
Intercooler
Wash
Wash return
Activated carbon
NaOH
The market needs a lower-cost environmentally friendly solution
TYPICAL AMINE CAPTURE PROCESS
Amine technologies fall short on:
▪ Toxic, volatile and expensive solvent▪ High parasitic load / heat quality▪ Significant corrosion rates▪ Sensitive to oxidation and contaminants
Equipment in BLUE is not required in the
CO2 Solutions enzymatic process.
NOx / SOxpolisher
Polishedflue gas
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Absorber
Stripper
L-R Heat Xger
Flue gas
Exhaust gas
Blower
Trimmer
Reboiler
CO2
Wash
Wash return
Conditionning
ENZYMATIC CAPTURE PROCESS
CAPEX and OPEX advantages
Reduced environmental footprint
NO TOXIC WASTE
STANDARD GAS TREATMENT EQUIPMENT
LOW-COST “COMMODITY” CARBONATE SOLVENT
LOW-GRADE HEAT FOR REGENERATION ENERGY
BEST-IN-CLASSPROPRIETARY ENZYME
NO TOXIC AEROSOLS
PURE CO2
NO FLUE GAS POLISHING REQUIRED
FERTILIZER PRODUCED FROM PERIODIC SOLVENT BLEED
DEMONSTRATED AT LARGE SCALE – TRL 8
ENVIRONMENTAL PROPERTIES CONFIRMED IN 3RD PARTY LIFE
CYCLE ANALYSIS
LOW-COST MATERIALS
NO WATERWASH
NO INTERCOOLERS
NO RECLAIMER
NO FILTER
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8
Technical differentiatorsCSI vs. amines
Heat medium at reboiler
Steam (parasitic
load)
Hot water @ 85°C (residual
heat)
Tolerance to SOx/NOx
contaminants
Scrub below10 ppm
No scrubbingrequired
Choice of materials
High-grade stainless steel
to control corrosion / toxic risks
Low-grade allowable (SS-304), carbonsteel and C-
PVC
Environmentalfootprint
Side reactionsgenerate
toxic wastesand aerosols
Stable solvent and non-toxicCSI
Amines
CAPTURE TECHNOLOGY DEMONSTRATED
Operated a demo plant for 2,500 hours in 2015 and
3,000 hours at Parachem since August 2017
CO2 produced is at 99.95%+ purity
No solution degradation observed
No solution makeup required
No toxic waste products generated▪ Spent solution sent to the
municipal sewer
3rd party validation of plant performance and simulator benchmark (Tetra Tech Inc.)
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< 39$ < 28$
10
30 tpd project, Can$10.0 M- Commissioned in Q1
2019
<20140.5 tpd
2014-20151 tpd
201510 tpd
In advanced discussions for commercial projects
up to 300 tpd
201710 + 10 tpd
201930 tpd
COMMERCIAL PROGRESS – CAPTURE & UTILIZATION
2016: first commercial agreement signed
tpd = metric tonnes CO2
captured per day 10
Scope of St-Félicien project
Lime kiln
Venturi
(environmental compliance)
Stack
Blower
Venturi
(for CO2 capture)
Quench column
Absorber
StripperCompressor
(2 stage)
Condenser
Pipeline
Greenhouse
Dryer
Separator
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CO2 captured and sent to the greenhousereplaces CO2 generated from natural gas
(fossil fuel)
An extra venturi cleaning step removesparticulates before the capture unit as hot lime (cement) would create maintenance
issues. However, there are no SOx nor NOx treatment required.
Latest Commercial Project – 30 tpdSERRES TOUNDRASaint-Félicien, QC
• Capture up to 30 tpd CO2 from Resolute Forest Products’ (RFP) pulp mill lime kiln
• Utilize mill’s low-grade / waste heat for process
• Reduce CO2 output from mill / share carbon credits
• Supply CO2 to neighboring Serres Toundra greenhouse complex
Full CO2 value chain enabled by CO2 Solutions’ technology
Full CO2 value chain enabled by CO2 Solutions’ technology
In Operation March 2019
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All equipment are « standard » issues
i.e. pumps, plate/frame exchangers, packed columns, compressors, venturi systems, etc.
EQUIPMENT & CONSTRUCTION STRATEGY
TRANSPORTABLEBUILDING ERECTEDAROUND MODULE BASE
CIVIL PRE-WORK + PIPERACK
ALTERNATIVE MATERIALS
(CPVC, SS304)
COLUMN ABSORBER
MODULAR CONSTRUCTION
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SITE PREPARATION BEFORE MODULES ARE BOLTED IN
GAS CONDITIONING EQUIPMENT(QUENCH + VENTURI)
STRIPPER FOUNDATION
MODULE ANCHORS
GROUNDING
PIPERACK
ABSORBER FOUNDATION
CO2 PIPELINE
SUMP
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RAISING THE COLUMNS – A GOOD DAY AT THE OFFICE
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INTERMEDIATE RESULT
ABSORBER
VARIABLE THROAT VENTURY
STRIPPER
QUENCH TOWER
LIME KILN
GREENHOUSE
CAPTURE UNIT AND UTILITY
PIPERACKTOWER HEIGHT: 7.6 MPACKING HEIGHT: 3.7 MDIAMETER: 1.07 M VENTURY HEIGHT: 6.7 M
VENTURY DIAMETER: 1.07 MVENTURY-QUENCH
CONNECTION LENGHT: 1.37 M
TOWER HEIGHT: 39.39 MPACKING HEIGHT: 25.0 MDIAMETER: 1.13 M
TOWER HEIGHT: 30.3 MPACKING HEIGHT: 18.9 M
DIAMETER: 2.05 M
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CLOSING THE BUILDING AND WORKING ON THE GUTS OF THE UNIT
17
COMMISIONNING AND START-UP
18
LESSONS LEARNT
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If you see those in the hotel parking lot, ask yourselfif it’s the right season to start-up your unit!
FINAL RESULT
ADDITION SYSTEM
PROCESS EQUIPMENT ON MODULES
Shop fabricatedfor reduced construction costs, better qualitycontrol, better safetyand easy transport
On unit slab, self contained with unit sump
ELECTRICAL ROOM
In separate containerized buildingPLC and Motor Drives wired in-situ
HUMAN MACHINE INTERFACE (HMI)
Data historian through PI (PFR)Remotely accessible (internet)
MAIN PROCESS BUILDING
Prefab steel40’ X 52’ X 34’ Picture not shown
VACUUM PUMP / COMPRESSOR
2-stage reciprocalSpecial grease/oil free pistons for
food grade (greenhouse)Separate shelter/housing
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CURRENT STATUS
In operationMarch 2019
Performance audit report
completed
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RESULTS FROM THE PERFORMANCE AUDIT
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• 100% of the thermal energy required for carbon capture comes from residualsources from the pulp mill – at no cost!
• Thermal energy required is 2.4 GJ/tCO2
• Combined thermal and electrical energycost for the project is less than 5€ per tonne of CO2
• CO2 quality meets the stringentgreenhouse specifications
PROJECT PEER RECOGNITION
• 2019 Innovation Project Award by the Ordre Des Ingénieurs du Québec in Chaudière-Appalaches-Québec region
• One of three Finalist for Provincial Innovation Project of the year (provincial award night May 29th 2019)
ST-F
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Creating the New Carbon Economy
Contact:Richard Surprenant, Senior VP, Process engineering and [email protected]
www.co2solutions.com
Ticker: TSX-V (CST)24