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    2003, Exide Industries Limited. All rights reeserved.

    Welcome

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    2003, Exide Industries Limited. All rights reeserved.

    Seminar On Stand! "atteries

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    Exide Industries

    Limited

    2003, All rights reeserved.Se#temer$, 20%&

    3

    Selection Of Batteries For GeneratingStation And Substation

    Application :

    Unit Battery

    Substation Battery

    PLCC

    24/26v C & Battery

    UPS Battery

    Battery !or "#$ set

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    '

    Battery Is Considered To Be TheHEARTOf The !o"er !lant

    Battery provi%es te ulti'ate an% !inal (C bac)*up !or operatin+ e'er+ency e,uip'ents -icpo-er te turbo +enerators .vi0 e'er+ency oilpu'ps etc01

    (C po-er !or operation o! all s-itc+earprotection relays in%icatin+ la'ps an% !acia

    Po-er !or e'er+ency li+tin+ -itin te+eneratin+ station buil%in+

    Uninterrupte% po-er !or controllin+ C &

    e,uip'ent an% associate% ups syste's Po-er !or vital co''unication e,uip'ent .plcc1

    essential !or resyncronisin+ te unit -it te +ri%or !or revivin+ te +ri% in te case o! a 'a3or +ri%

    !ailure

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    &

    #hat If The Battery Fails In AnE$ergency %

    Unit Battery

    e e'er+ency oil pu'p -ill not operate -ic

    coul% lea% to seiure o! te rotor bearin+s

    Loss o! un%re% o! crores o! rupees to-ar%s

    repairin+ te rotor an% +eneration revenue loss-ile te unit is out o! co''ission

    S-itc+ear associate% -it +enerator 'ay not trip

    -ic coul% lea% to +eneratin+ trans!or'er

    %a'a+e $ailure o! instru'entation an% control

    otal %ar)ness in te po-erouse

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    (

    #hat If The Battery Fails In AnE$ergency %

    Substation

    S-itc+ear an% relays -ill not operate causin+

    e5tensive %a'a+e to trans!or'ers an% po-er lines

    PLCC

    5tre'ely %i!!icult to resyncronise te unit -it te

    +ri%

    7a3or setbac) in te process o! revivin+ te +ri% in

    te event o! a re+ional +ri% !ailure

    ! te battery !ails -ile te unit is in operation it'ay beco'e essential to sut%o-n

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    )

    The Single &ost I$'ortant Feature OfBatteries For !o"er Sector A''lication Is

    8eliability

    8eliable stan%by po-er source

    (eliver po-er as an% -en calle% !or

    $ull capacity at any point o! ti'e in service li!e

    Pre%ictability

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    *

    #hat Is A Battery %

    A battery is an array o! si'ilar electricalstora+e cells

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    $

    #hat Is an Electrical Storage Cell %

    An electrical stora+e cell consists o! t-o %issi'ilar

    electro%es i''erse% in an electrolyte0

    t stores electrical ener+y in !or' o! ce'ical

    ener+y0

    9en te circuit is 'a%e bet-een its positive &

    ne+ative electro%es tere is a ce'ical reaction

    in te cell an% it %elivers electricity (irect

    Current .(0C1 trou+ te circuit0

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    %0

    Pri'ary Cell

    Litiiu' A''oniu' Silver

    5i%e Clori%e 5i%e

    Secon%ary Cell

    Al)aline Lea% Aci%

    Cells Cells

    ;i Ca% ;i$e

    SL or n%ustrial

    Auto'otive

    Stan%by 7otive Po-er

    "8LA $iat Paste% ubular Plant

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    %%

    #hat Is A (ead Acid Battery %

    Basic electroce'ical reaction participants :Positive lectro%e Pb2

    ;e+ative lectro%e Pb

    lectrolyte #2S4

    SOF

    T(

    EA)

    (EA)

    )IO*I)E

    H+S,- . E(ECTRO(/TE

    +

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    %2

    Ho" )oes A (ead Acid Battery #or0 %

    Car+e% (iscar+e%

    =ve *ve electrolyte =ve *ve

    Pbo2 = Pb = 2#2S4 PbS4 = PbS4 = 2#2

    Lea% Spon+y (ilute Lea% Lea% 9ater

    Pero5i%e Lea% SulpurAci% Sulpate Sulpate

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    %3

    Ty'es Of !lates

    A1 !ositi2e

    Plant< ype : Cast out o! >>0>>? pure Lea%

    as a !ine la'aellar structure

    $lat Paste% ype : @ri% ol%s te active 'aterial an%

    carries te current

    ubular ype : 8e% lea% .Pb41 an% @rey

    o5i%e .Pb1 'i5ture is !ille%

    in tubes an% spine o! lea%*

    alloy runs trou+ te centre o!

    entire tube len+t0 ube retails

    te active 'aterial !ir'ly an%spine carries te current

    B1 3egati2e

    $lat paste% type al-ays

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    Flat !asted !late . &or'hology

    # SUPP8 S8UCU8 S ;

    # $87 $ A 98*7S# L

    @8( CAS $ A SUABL LA(

    ALL

    # AC" 7A8AL S PAS(

    ; # @8( S8UCU8 $87

    US(

    A C#7CAL B;(;@ #L(S #

    AC" 7A8AL ; PLAC

    #8U@#U # S8"C L$

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    Features Of Auto$oti2e Flat !late

    @ri% : .Current Collector1 cast into a lattice

    structure

    Active 7aterial : Paste% on to te lattice

    Suite% $or :

    #i+ current %iscar+e

    Sort bac)up ti'e .Sallo-1 %iscar+e

    ;on*cyclic application

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    %(

    Tubular !late

    *

    (4G/

    T4BE

    CO3STR4CTIO3 OF T4B4(AR

    !OSITI5E !(ATE

    BOTTO& BAR/

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    Cross.Section Of Tubular !late

    SECTIO3 6 7//8 SECTIO3 6 7**8

    CO3STR4CTIO3 OF T4B4(AR !OSITI5E !(ATE 9contd1:

    RESI3 SHEATH

    S!I3E

    ACTI5E &ATERIA(

    T4BE

    BOTTO& BAR

    S!I3E 9(EA) A((O/:

    ACTI5E &ATERIA(9(EA) O*I)E:

    T4BERESI3 C4RE)9TER/(E3E GA43T(ET:

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    Tubular !ositi2e Structure

    # SUPP8 S8UCU8 S ;

    # $87 $ CAS 8(

    LC8(S CALL(S!I3ESD;( A # P B A BUS BA8

    ;("(UAL SP;S ;@UL$( ;

    A 7C8P8US PLU8UBULA8

    GA43T(ET

    A;;ULA8 SPAC B9; SP;

    A;( @AU;L $LL(9#ACTI5E &ATERIA( 9!bO+:1B7$ # @AU;L SAL( 9#

    A PLASC PLU@CALL(BOTTO&BAR

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    %$

    !lante !ositi2es 6 4ni;ue Structure

    !(A3TE HAS THE &OST 43I !4RE (EA)9#; ALL;@ L7;0

    (A&E((AR@8( C;S8UC;;#A;CS SU8$AC A8A

    LA8@LE

    $$C" SU8$AC A8A?+ TI&ES#A $ @78C SU8$AC

    A8A

    ; F8;AL A((; $ AC"

    7A8AL0 @8( SU8$AC

    C;"8( Pb2#8U@#

    C;8LL( C88S;

    8AC; (U8;@ PLAP8CSS;@

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    20

    !lante !ositi2e !late

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    2%

    !lante 3egati2e !late

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    SA3 Container

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    !lante @@@11 Salient Features

    Ecellent )ischarge !rofile

    5ery (o" &aintenance

    Fast Recharge and !ossibility Of High Rate Of

    Charging 3o (oss In Ca'acity Throughout its (ife S'an

    (ong (ife e'ectancy Of ?.+, /ears In FloatA''lication

    Trans'arent Container Easy 5isual &onitoring

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    2'

    !lante (o" &aintenance

    Lo- oppin+ 8e,uire'ent Acieve% rou+

    Anti'ony $ree Ultra Pure Lea%

    "ery lo- e,uilibriu' !loat current

    "ery lo- -ater loss Lo- oppin+ 8e,uire'ent

    Acieve% rou+ ;o Leacable 'purity

    ;o poisonin+ o! ne+ative

    ;e+li+ible rise in e,uilibriu' !loat current %urin+

    entire service li!e

    #u+e pool o! electrolyte

    5cellent ter'al 'ana+e'ent

    7a)es up !or lost -ater

    TO!!I3G 4! O3CE I3 ?+ 6 ?D &O3THS

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    2&

    !lante . 3o (oss In Ca'acity

    -ontinuous regeneration o active material

    /otal Leaddioxide content airl! constant

    throughout the lie s#an indicating a constant

    ca#acit! out#ut

    Lo1ering o internal resistance due to thinning

    O #arent material ma! ex#ect higher ca#acit!

    A##reciation as the cell ages

    /hus consideration o lie actor in ca#acit!

    ot necessar! as acce#ted ! IEEE '*& %$$)

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    2)

    !lante 6 Easy &onitoring

    /rans#arent SA ;S/

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    2$

    !lant Cells

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    &aintenance

    oppin+ up

    Car+in+

    Cec)in+ an% cleanin+ o! ter'inals

    n a lea% aci% battery car+in+ & cleanin+ /

    cec)in+ o! ter'inals cannot be avoi%e%

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    3%

    &aintenance

    TO!!I3G 4!

    9A8 LSS

    LC8LSS "AP8A;

    (8CL P8P8;AL

    A;7; C;; ;

    # PLA

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    (o" &aintenance

    #o- s t Acieve% K

    Lo- anti'ony alloy0

    Less lectrolysis * lo- -ater loss

    7icroporous vent plu+

    Bi++er Container -it 'ore electrolyte / i+ aci%

    ea% roo'

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    3'

    Cera$ic )o$e

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    #hat Is 5R(A %

    "alve re+ulate% lea% aci% battery )no-n to

    co''on users as

    Seale% 'aintenance !ree batteryM

    perates -it a sa!ety !or escape o! +asses

    unavoi%ably +enerate% %urin+ operation

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    3(

    S&F 5R(A Batteries

    ;o !ree electrolyte0 lectrolyte is )ept absorbe% in +lass

    'at separators

    nsu!!icient buoyancy !or o5y+en +as to travel up-ar% by

    ne+ative +ravitation

    5y+en travels oriontally & reaces ne+ative plate to

    react -it 'etallic lea%

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    3)

    5enting Arrange$ent Of A 5R(A Battery

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    #hy 5R(A %

    Seale% N Can be )ept in any orientation

    ;o toppin+ up re,uire% ever

    A ero e'ission pro%uct

    Battery co'es car+e%

    Co'pact

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    The Sealed &aintenance Free 75R(A8Battery

    Battery is %elivere% rea%y to use

    ;o toppin+*up re,uire% ever

    Oero e'ission un%er nor'al car+in+ con%itions Co'pact

    Lo- !oot*print

    asy to an%le

    I3HERE3TA)5A3TAGES

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    '0

    5ulnerabilities

    #i+ te'perature

    (eep %iscar+e

    Cyclin+

    Car+e sensitive

    8ecovery !ro' over %iscar+e

    er'al 8una-ay an% (ry out

    Unpre%ictability

    S l i C i i Of A B

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    Selection Criteria Of A Battery

    Pri'ary $actors

    Current loa%

    Bac)up ti'e

    7ini'u' volta+e re,uire'ents o! te syste'

    e lo-est e5cepte% operatin+ te'perature

    S l ti C it i Of A B tt

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    '2

    Selection Criteria Of A Battery

    Secon%ary $actors 5pecte% !re,uency o! %iscar+e

    (ept o! %iscar+e

    A'bient te'perature

    7eto% o! car+in+ constraint i! any

    Li'itation on space

    7aintenance li'itation

    $loor loa%in+

    T h i l C i

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    Technical Co$'arsion

    ;o'inal "olta+e

    ubular 2"

    "8LA 2"

    Plant

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    ''

    Technical Co$'arison

    8C#A8@

    ubular Capable o! ,uic) recar+e by boost

    car+in+ upto 20Hvpc an% J0G4 CGJ

    A'ps recar+e current

    "8LA Quic) recar+e li'ite% to !ast car+in+

    upto 204vpc an% GI*2J? o! li'it current

    Plant

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    Technical Co$'arison

    SUSCPBL #@# 7P8AU8

    ;(P ubular Satis!actory operations upto

    4/IJJC electrolytic te'perature

    "8LA Prolon+e% operation at i+a'bient te'perature curtail battery

    li!e severely0

    Plant< Satis!actory operations upto

    4/IJJ

    C electrolytic te'perature;i*C% Satis!actory operations upto

    4/IJJC electrolytic te'perature

    T h i l C i

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    Technical Co$'arison

    (iscar+e At $loat perations

    ubular Satis!actory

    "8LA Best

    Plant< Satis!actory

    ;i*C% ;i*C% %oes not +ive !ull

    capacity -en %iscar+e% a!ter

    re'ainin+ on !loat !or a lon+

    ti'e0 n or%er to obtain te%esire% capacityte capacity o!

    te battery nee%s to be

    increase% by I?

    T h i l C i

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    ')

    Technical Co$'arison

    7;8;@ SA $ C#A8@

    ubular Can be %one by 'easurin+ electrolyte

    speci!ic +ravity

    "8LA Cannot be %eter'ine% e5ternally acts asa blac) bo5

    Plant< ter tan 'easurin+ electrolytic speci!ic

    +ravity battery con%ition can be

    'onitore% visually trou+ te transparentcontainers

    ;*C( Cannot be %eter'ine% e5ternally acts as

    a blac) bo5

    T h i l C i

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    Technical Co$'arison

    A@;@

    ubular (e+ra%es +ra%ually %urin+ service li!e &!alls to about J? in *GJ years0 2I?capacity as to be increase% toco'pensate !or a+ein+

    "8LA (e+ra%es +ra%ually %urin+ service li!e &!alls to about J? in GJ*GI years0 2I?capacity as to be increase% toco'pensate !or a+ein+

    Plant< Plant< capacity %oes not %rop raterincreases in service li!e

    ;i*C% Capacity re'ains al'ost constant %urin+service li!e

    Technical Co$'arison

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    '$

    Technical Co$'arison

    8LABL

    ubular Quite reliable

    "8LA @enerally reliable o-ever prone to

    une5pecte% 'al!unctionin+Plant< 7ost reliable in !loat operations

    ;i*C% 8eliable %urin+ routine %uty cycles

    o-ever prone to une5pecte%

    'al!unctionin+ %urin+e'er+ency re,uire'ent

    Technical Co$'arison

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    &0

    Technical Co$'arison

    (ife E'ectancyubular GJ*G2 years

    "8LA *GJ years

    Plant< GI*2J years

    #(P ubular GJ*G2 years

    ;i*C% GI*2J years

    Internal Resistance;(P ubular #i+est

    "8LA Lo-est

    Plant< J*4J?lo-er tan

    e,uivalent #(P

    ubular Cells

    ;i*C% Lo-

    15

    10

    VRL

    5

    Internal

    Resistance

    L

    ifeExpectancy

    TUBULAR

    TUBULAR

    VRLA

    VRLA Plante

    Plante Ni-Cd

    Ni-Cd

    Technical Co$'arison

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    &%

    Technical Co$'arison

    oppin+ Up 8e,uire'ent ubular oppin+ up upto *4 ti'es in a year

    "8LA ;o toppin+ up re,uire%

    Plant< oppin+ up once in G2*G 'onts

    ;i*C% oppin+ up once a year0 5istin+

    electrolyte nee%s to be can+e% every

    H* years

    Auto* $ill Syste's 8e'oves e ;ee% !

    oppin+ Up 8outine 'aintenance is

    re,uire% !or all cate+ories

    o! batteriesNo.oftim

    es/year

    4

    3

    2

    1

    &yths Of 5R(A Batteries

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    &2

    &yths Of 5R(A Batteries

    7yt G "8LA batteries re,uire no 'aintenance Reality

    As per te Clause ;o0 I0H o! GG>*G>>6

    By te very nature o! te %esi+ns o! "8LA cells

    speci!ic +ravity rea%in+s an% -ater a%%itions arenot practical0 Conse,uently te batteries are o!ten

    re!erre% to as 'aintenance !ree0 #o-ever tis is

    true only -it respect to te electrolyte0 ter-ise

    "8LA battery 'aintenance is si'ilar to tat re,uire

    !or !loo%e% batteriesM0

    ere e5ists an stan%ar% . GG*G>>61

    -ic is %e%icate% !or 'aintenance an% testin+ o!

    "8LA batteries

    &yths Of 5R(A Batteries

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    &yths Of 5R(A Batteries

    7yt 2 "8LA batteries can be use% in tropicalcli'ate at i+ te'peratures -itout any a%verse

    e!!ects

    Reality

    As per Clause ;o0 B0 o! anne5ure B o! GG*G>>6

    As a +eneral rule continuous prolon+e% use at

    elevate% te'peratures -ill re%uce te batteries li!e

    by appro5i'ately one*al! !or every J

    C above 2IJ

    C tat "8LA Batteries operate0 is e!!ect can be

    'iti+ate% to so'e e5tent by te use o! te'perature

    co'pensate% car+es0 peration at elevate%

    te'peratures can also lea% to ter'al runa-ayM0

    &yths Of 5R(A Batteries

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    &yths Of 5R(A Batteries

    7yt "8LA batteries %o not ave te sa'e!ailure 'ecanis's as !loo%e%

    Reality As per Clause ;o0 I0 o! GG>*G>>6

    e !a'iliar !ailure 'ecanis's o! positive platecorrosion an% +ro-t active 'aterial !ailure postseal lea)a+e an% container / cover seal lea)a+eassociate% -it vente% cells are also present in"8LA cells0 #o-ever in "8LA cell te e!!ects o!

    lea)a+e at te post an% / or container cover sealsare 'ore si+ni!icant tan in vente% cells0

    "8LA cells are susceptible to t-o !ailure 'o%estat are nor'ally not associate% -it vente% cells0ese are %ryout an% ter'al runa-ayM

    #hy Then 5R(A %

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    &&

    #hy Then 5R(A %

    eleco''unications & UPS applications pro%uct

    attributes secon%ary re,uire'ent

    S'all $oot Print ;o 'issions

    ;o 7aintenance

    !o"er Stations

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    !o"er Stations

    !roduct Attributes Re;uired Reliability

    (eliver po-er as an% -en calle% !or an% !ull

    capacity at any point o! ti'e in service li!e

    !redictability #ealt

    'pen%in+ $ailure

    5pecte% i'e ! 8eplace'ent

    i'e este%

    Li!e

    A''lication

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    A''licationOur Reco$$endation

    3)! T4B4(AR

    Ideal for fre;uentCharge

    dischargecycling duties

    5R(A

    For relati2elyShort ti$e bac0u'

    "ith $oderatede'th of discharge

    !(A3TE

    Ideal for $eeting dutycycle in float o'eration

    !lant

    Ideal for $eeting dutycycle in float o'eration

    H)! T4B4(AR

    Ideal for fre;uentchargedischarge

    cycling duties

    3I.C)

    Can be used in highrate of discharge inabusi2e conditions

    The Trade.Off

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    The Trade.Off

    ere is no lea% aci% battery -it te bestpro%uct attributes in all te cate+ories o!

    attributes

    A tra%e*o!! as to be 'a%e !or eac

    application se+'ent consi%erin+ te

    re,uire'ents o! tat se+'ents

    Best battery !or

    po-er application *

    PLA;

    Best battery !or

    eleco' application

    * "8LA

    03 June2003

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    ?:E2

    003

    /han5