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staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 1: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 2: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 3: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 4: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 5: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 6: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 7: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Vapor Pressure of SolutionsA non­volatile SOLUTE lowers the vapor pressure of the solution.

The molecules of the solvent must overcome the force of both the other solvent molecules and the solute molecules. 

Page 8: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 9: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 10: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Freezing point depressionReason 1:  As the water tries to freeze, the other molecules get in the way.  Reason 2:  By adding these other substances, you’ve added disorder to the mixture.  Nature tends to favor disorder (entropy).  When water tries to freeze, it has to get organized, which will be more difficult because it’s mixed with all of these other molecules.

Page 11: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 12: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Osmotic Pressure (π)Osmosis is the selective passage of solvent molecules through a porous membrane from a dilute solution to a more concentrated one.

A semipermeable membrane allows the passage of solvent molecules but blocks the passage of solute molecules.

Osmotic pressure (π) is the pressure required to stop osmosis.

dilute moreconcentrated

Page 13: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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Page 14: staff.bbhcsd.orgstaff.bbhcsd.org/smithbeth/AP chem ch 11 2014.pdf · Freezing point depression ... • Useful for determining molar mass. Example ... 3.07 2.53 5.24 3.56 0.512 Freezing

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