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Good Afternoon!
COURSE DESCRIPTION
ENS 130 is a college level course in general chemistry designed primarily for students who have had previous chemistry training in high school. This course is designed for students to gain a better understanding of the world of matter and energy. Students will study: measurement, metrics, reactions, atomic structure, the periodic table, chemical bonding, states of matter, solutions, equilibrium, gases, oxidation-reduction, and acid-base chemistry. Most topics on this course require calculation; therefore, a solid math background is helpful. Through extensive lab writing students will examine laboratory investigations using the scientific method.
REQUIRED MATERIALS
Periodic Table Scientific calculator with exponents
and logarithms (NOT graphing/programmable)
Lab Gown ( for laboratory experiments)
Notes
Course OutlineIntroduction to Chemistry
Everyday Chemistry Measurements Significant Figures Scientific Notation Factor Label Method or Dimensional
Analysis Conversion of units Matter
Continuation…
Structure of Matter A. Atomic theory and atomic structure 1. Evidence for the atomic theory 2. Atomic masses 3. Atomic number and mass numbers; isotopes
4. Electron energy levels; atomic spectra, quantum numbers, atomic orbitals 5. Periodic Table History, Periodic Relationship Among Elements
B. Chemical Bonding 1. Binding forces a. Types: ionic, covalent and metallic
b. Intermolecular Attractions Hydrogen bonding, van der Waals (including London dispersion forces) c. Polarity of bonds, electronegativities2. Molecular models
a. Lewis structures b. Valence bond: hybridization of orbitals, resonance, sigma and pi bonds c. VSEPR Theory 3. Geometry of molecules and ions; structural isomerism of simple organic molecules and coordination complexes; dipole moments of molecules; relation of properties to structure
Science Systematized body of knowledge From the Latin word “scientia”
meaning knowledge Greek word “scire” meaning to
know Combination of processes and
products
Technology From the Greek word
“technologia” “techno” meaning art and skill and “logia” meaning study of
Applied science
Chemistry Branch of science that deals with
the study of matter, its composition, properties and changes it undergo.
Considered core or central science.
Who am I? I determine the structure, composition,
and nature of substances by examining and identifying their various elements or compounds.
ANALYTICAL CHEMIST
I study the chemistry of the vast number of carbon compounds that make up all living things.
ORGANIC CHEMIST
I study compounds consisting mainly of elements other than carbon, such as those in electronic components
INORGANIC CHEMIST
I develop a fundamental understanding at the molecular and atomic level of how materials behave and how chemical reactions occur, knowledge that is relevant in nearly every area of chemistry.
PHYSICAL CHEMIST
I am identifying substances' chemical and physical properties in biological systems that is of great importance
BIOCHEMIST
SCIENCE PROCESS SKILLS: BASIC AND INTEGRATED
Observing Communicating Classifying Measuring Inferring Predicting
Making a model Defining operationally Investigating *Asking a question *Collecting data *Reporting data *Comparing results *Making a conclusion
OBSERVING Using one or more of
the senses Extending the power
of the senses by using equipment/gadgets
Gathering information: objects and/or events
Comparing and contrasting
Looking for similarities and differences
COMMUNICATING Giving or
exchanging information
Describing: object, action, event
* Words: oral or written * Graphic
symbols
COMMUNICATING:Graphic Symbols
Drawings Diagrams Maps Tables Charts Graphs
COMMUNICATING:Graphic Symbols
COMMUNICATING:Graphic Symbols
CLASSIFYING Observing
similarities and differences
Sorting according to a predetermined set of properties or schemes
Labeling the common characteristics
Classifying Animals:Dichotomous Key
MEASURING
Comparing objects to arbitrary units that are standardized
Comparing objects to arbitrary units that are not standardized
*Estimating– Approximately calculating a quantity or value based on judgment
MEASURING INSTRUMENTS
Length
Mass and weight
Volume
Temperature
Ruler, tape measure, meter stick
Equal-arm balance, weighing scale
Measuring cups and spoons, graduated cylinder, beaker, dropper
Thermometer
Using the Equal-Arm Balance
See if the pointer points to the zero mark. If not, adjust it to its initial zero reading.
Protect the platforms with paper/plastic containers.
After using, wipe the platforms with a clean tissue paper.
MEASURING INSTRUMENTS:Weighing Scales
ESTIMATING Dali (cm), dangkal (cm), dipa (m) Estimate: drops in 1 cc or mL Estimate: heaviness/mass of solids
by *using hands *improvised balance *non-standard masses
INFERRING Developing
ideas based on observations
PREDICTING Forming an
idea of an expected result, based on inferences
Observing,Inferring, or Predicting?
The bean’s seed coat is broken.
The seed is sprouting.
If the seed would have enough water, air, warmth, and nutrients, it would grow into a healthy bean plant.
Observing, Inferring, or Predicting?
There is a bee on a flower.
A bee is pollinating a flower.
The flower will be fertilized.
Observing, Inferring, or Predicting?
DEFINING OPERATIONALLY
Stating specific information about an object or phenomena based on experiences with it
Telling what you do and what happens
Describing what will be observed or measured
MAKING MODELS Developing a
physical or mental representation to explain an idea, object, or event
INVESTIGATING Asking a question Hypothesizing Designing
investigation Collecting data Reporting data Comparing results Making conclusion
SCIENCE IS INQUIRY Fair test
Observe
Look for a pattern
Make things
Make models
Control and experimental
Unfolding of events; do tests
E.g.: Where are snail habitats in the school campus?
Process: e.g., make soap
Physical, abstract; working or not
ASKING QUESTIONS
INVESTIGATING: DESIGNING AN INVESTIGATION
Identifying variables Controlling variables *Manipulating one factor that
may affect the outcome of an event while other factors are held constant Setting up an experiment
INVESTIGATING:COLLECTING DATA
Keeping a record notebook Making a tabulation
INVESTIGATING:REPORTING DATA
Making a graph *Converting numerical
quantities into a diagram that shows the relationships among the
quantities
INVESTIGATING:COMPARING RESULTS
Reviewing literature *Books *Science Magazines *Internet
INVESTIGATING:MAKING CONCLUSIONS
Writing the investigation Answering the question raised
SYSTEMS OF MEASUREMENT
A system of measurement is a set of units which can be used to specify anything which can be measured and were historically important, regulated and defined because of trade and internal commerce.
ENGLISH SYSTEM OF MEASUREMENTThe English system of measurement
grew out of the creative way that people measured for themselves. Familiar objects and parts of the body were used as measuring devices. For example, people measured shorter distances on the ground with their feet.
ENGLISH SYSTEM OF MEASUREMENT They measured longer distances by their
paces (a "mile" was a thousand paces). They measured capacities with common household items such as cups, pails, and baskets. The word gallon comes from an old name for a pail. Unfortunately, these creative measuring devices allowed for different measurements to be obtained when different people measured the same items. Eventually, a standard was set so that all measurements represented the same amount for everyone.
ENGLISH SYSTEM OF MEASUREMENT
Length:12 inches (in) = 1 foot
(ft)3 feet = 1 yard (yd) 5280 feet = 1 mile
(mi)
Capacity:3 teaspoons (tsp) = 1
tablespoon (tbsp) 16 tbsp = 1 cup (c)8 ounces (oz) = 1 c
2 c = 1 pint (pt)2 pt = 1 quart (qt)
4 qt = 1 gallon (gal)
Weight:16 ounces (oz) = 1
pound (lb)2000 lb = 1 ton
METRIC SYSTEM OF MEASUREMENT
The metric system is an international decimalized system of measurement that was originally based on the mètre des archives and the kilogramme des archives introduced by France in 1799.
METRIC SYSTEM OF MEASUREMENTFrom its beginning, the main feature of
the metric system was the standard set of inter-related base units and a standard set of prefixes in powers of ten. These base units are used to derive larger and smaller units and replaced a huge number of unstandardized units of measure that existed previously. While the system was first developed for commercial use, its coherent set of units made it particularly suitable for scientific and engineering purposes.
METRIC SYSTEM OF MEASUREMENT
Length:1 kilometer (km) = 1000 meters (m)1 centimeter (cm) = .01 meter (m)
1 millimeter (mm) = .001 meter (m)
Capacity:1 milliliter = .001 liter (l)
Weight:1 kilogram (kg) = 1000 grams (g)1 milligram (mg) = .001 gram (g)
Kilo means thousand (1000)Hecto means hundred (100)
Deca means ten (10)Deci means one-tenth (1/10)
Centi means one-hundredth (1/100)Milli means one-thousandth (1/1000)
SI BASE UNITS
SI BASE UNITSThe SI unit system consists of seven
base units, with a number of other units derived from those foundations. Below are the base SI units, along with their precise definitions, showing why it took so long to define some of them.•meter (m) - The base unit of length; determined by the length of the path traveled by light in a vacuum during a time interval of 1/299,792,458 of a second.•kilogram (kg) - The base unit of mass; equal to the mass of the international prototype of the kilogram (commissioned by the CGPM in 1889).
SI BASE UNITS• second (s) - The base unit of time; duration
of 9,192,631,770 periods of the radiation corresponding to the transition between the two hyperfine levels of the ground state in the cesium 133 atom.
• ampere (A) - The base unit of electrical current; constant current which, if maintained in two straight parallel conductors of infinite length, of negligible circuit cross-section, and placed 1 meter apart in vacuum, would produce between those conductors a force equal to 2 x 10-7 newtons per meter of length.
SI BASE UNITS OF MEASUREMENT
QUANTITY UNIT SYMBOL
LENGTH METER m
MASS KILOGRAM kg
TIME SECONDS s
TEMPERATURE KELVIN K
AMOUNT OF SUBSTANCE MOLE mol
ELECTRIC CURRENT AMPERE A
LUMINOUS INTENSITY CANDELA cd
SI DERIVED UNITSFrom these base units, many
other units are derived. For example, the SI unit for velocity is m / s (meter per second), using the base unit of length and the base unit of time to determine the length traveled over a given period of time.
SCIENTIFIC NOTATION
Very large or very small numbers can be written in scientific notation. This has the format Nx10n, with N as the whole number coefficient with a value from 1 to 9 and n is the exponent of 10 and is either a positive or a negative integer.
SIGNIFICANT FIGURESIn a measurement, all digits that we are sure of plus the one that is uncertain are called significant figures. In determining the number of significant figures, the following rules should be followed:o All nonzero digits are significant.Examples1.39 = 3 significant figures234.98 = 5 significant figures
o Zeroes between nonzero digits are significant.Examples:309.2 = 4 significant digits600.5 = 4 significant digits430.056 = 6 significant digitso Zeros before the first nonzero digit are
nonsignificant. These are called leading zeros.Examples:0.234 = 3 significant digits0.0056 = 2 significant digits0.000405 = 3 significant digits
o Zeros after the nonzero digit may or may not be significant. These are called trailing zeros.a. If there is a decimal point in the number, all trailing zeros are significant.
Examples:341.20 00 = 7 significant digits0.30 = 2 significant digits0.000609 = 3 significant digitsgits
b. If there is no decimal point in the number, the trailing zeros are NOT significant.Examples:400 = 1 significant digit324000 = 3 significant digitsoExact numbers are considered to have an infinite number of significant figures. These are numbers that we obtain be counting or multipliers in numbers that are part of a formula.Examples:
The number 2 in the formula for calculating the area of a circle, 2(pi)r(squared), is an exact number.
Significant Figure Rules for Addition and Subtraction
For addition and subtraction, the accuracy with which you quote an answer does not depend directly on the number of S.F. in the input numbers as above. Instead, it is determined by the position of the least significant digit in any of the input numbers. Here are some examples.
2.34 + 0.18 = 2.52 2.34 + 2.8 = 5.1
2.341234 - 2.0 = 0.3
In multiplication and division, the number of S.F. in the answer is the same as the number of S.F. in
the input number that has the fewest. For example, consider Person 3's measurement of
the wood. If you wanted to know the area of the wood you would use the formula
Area = Length x Width = (11.63 cm) x (5.74 cm)
The input number with the smallest number of S.F. is the width measurement, which has 3. So, the
answer must also have 3 S.F.:
Area = 66.8 cm2
UNIT CONVERSIONUnit Conversion is very important since not all measurements are expressed in the same units. Conversion of units is the conversion between different units of measurement for the same quantity, typically through multiplicative conversion factors.