SOUTHWEST LABORATORY OF OKLAHOMA, INC · SOUTHWEST LABORATORY OF OKLAHOMA, INC 1700 W. Albany . Suite "C" . ... # Column to be used to -flag recovery and RPD values with an asterisk

SOUTHWEST LABORATORY OF OKLAHOMA, INC1700 W. Albany . Suite "C" . Broken Avow, Oklahoma 74012 . 918-251-2858

CLIENT: URS CONSULTANTS, INC. . REPORTS 323Sb570 DELAWARE AVE.BUFFALO, NY 14202 DATEi 08-22-90ATTN: PETER FAIRBANKS

LABORATORY BLANK

SAMPLE MATRIX i SOILSAMPLE IDs METHOD BLANK

DETECTIONCOMPOUND LIMIT (»Q/Ka)

TPH 10.0

TPH MATRIX SPIKE/MATRIX SPIKE DUPLICATE

> SAMPLE MATRIX I SOILSWLO # 3238.19/3238.20 (MS/MSD)PROJECT: DELAWARE SAND & GRAVELSAMPLE IDs UR-29 (MS/MSD)

SPIKE CONC. SAMPLE CONC. 1(•g/Kg) <«g/Kg)*

TPH 667 20

MSD CONC. MSD PERCENT(•g/Kg) RECOVERY

SAMPLE AMOUNTS 30SDILUTION FACTORS 1

AMOUNT FOUND(Md/Ka)

ND

RECOVERY DATA

MS CONC. HS PERCENT(*g/Kg)S RECOVERY

610 887.

RECOVERY PERCENTDIFFERENCE

TPH 59O 83V. 37.

DILUTION FACTOR NOT APPLIED TO THESE CONCENTRATIONS

0004 0

3B _.SOIL VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lao Name: 314L-TULSA_______________ Contract: URS_______

t.gib Code: SWQK CaCT No.: UR5 9AS No.: _______ .§DB No.:

aoike - EPA Sample Ho.: UR-76_______ ; Leve !.:,<_! ow/incd) LQIO

COMPOUND

1 . 1-DicnloroetheneFricnloro^theneBenzeneToluene . ..Chlorobenzene

SPIKEADDED(ug/Kg)

59.559.559.559.559.5

SAMPLECONCENTRATION

( ug/Kg)

00000

MSCONCENTRATION

(ug/Kg)

52.448 . 334. 056.252 . 7 :

MS«//.

REC tt

83SI9194

. 89j

QCLIMITSREC.

59-17262-13766-1-3-259-ir°6O- t 33

COMPOUND

1 . l-DichloroetheneTrichloroetheneBenzeneTolueneChlorobenzen©

SPIKEADDED< ug/Kg)

59.559.559.559.559.5

MSDCONCENTRATION

(ug/Kg)

55. 749.355.757.755.0

MSDV/•

REC #

9483949792

V/•

.,RP& **__"7/_ *7»

-3— 7^-3

QC L3RPD

2224212121

HITS *REC . '

KTQ_ 1 7 - 1vj" 1 / *. »

62-137-16&-142!59-139!60-133!

;

F* Column to bm u ed to -^laa recovery and RPD values with an asterisk

* Values out»id« o-f QC limits

HFD: _2 out o-f _3. outside limitsSpit e Recoveryi _0. out o-f 10 outside limits

COMMENTSi —

lSr00043lFORM III VOA-2 " .1- - l'B7 R

101557

3DSOIL SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: SWL-TUL5A_______' Contract; URS_______

Lab Code: SWOK Case -No.: URS SAS No. s m_____ SDB No.:

Matri;: Spike - EPA Sample No.: UR-36______'__ Level s (low/med) LOW

COMPOUND

Phenol2-Chloroohenol1 ,4-Dichlorobenrene ___N-NitrosQ-di— n-prop. ( 1 )1 . 2?4-Trichlorobenzene_4-Chloro-3-methy 1 phenolAcenaphthene4-NitroDhenol2 . 4-Dinitrotoluene ____Pen tac hi or o phenolPvrene

SPIKEADDED(ug/Kg)

1 59001590O794079407940 •15900794015900 .794O"159007940

SAMPLECONCENTRATION

(ug/Kg )

0Oo000 -0o000

MSCONCENTRATION

(ug/Kg)

969O10200521050306340131004910122006260158007010

MS/•

REC #

61646663SO8262777999S3

QCLIMITSREC .

26- 9025-10228 10441 12633 10726 10331-13711-11423- 3917-10935-142

COMPOUND

Phenol2-Chloroohenol1 „ 4-DichlorobenzeneN-Nitroso-di-n-prop". ( 1 )1 ,254-Trichlorobenzene_4-Ch 1 oro-3-me thy 1 pheno 1Acenaohthene4-NitroDhenol2-« 4-Din it ro toluenePefitachlorophenolPvrene

SPIKEADDED(ug/Kg)

159001590079407940 -7940159007940159007940

1 59007940

MSDCONCENTRATION

(ug/Kg)

102001140059005736'580O1270.05570116OO6190665O3340

MSD7.REC #

647274T1"*/ J^_

73SO70737342105

7.RPD *

-5— 12-11-1392

-1251

SI *-18

!DC LIMITS !RPD

35502733*L '

331950474736

REC . !s-— * s— ~ '26- 90!25-102!23 104!41 126!33 107!26 103!31-137!11-114!28- 89!17-109!35-142!

<1) N-Nitroso—di—n-propylamine

# Column to be used to -flag recovery and RPD values with an asterisk* Values outside of QC limits

RPD: _1_ out. o-f 11_ outside limitsSpike Recovery: 0 out of 22 outside Jimits

COMMENTS: UR-36 URSINSTrF SWL#3238.23. . ._

FORM III 3V-2 1/B7 Rev.

ARiOlSSS

3FSOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Names SWL-TULSA______________ Contract: UR§_______

Lab Code: 5MQK Case No.: URS SAS No.: ______ SDG No.

Matrix Spike - EPA Sample No.; * UR-36______ Level:(low/med) LOW

COMPOUND

gamma-BHC < Lindane ) ___HeotitchlarAldrinDieldrinEndrin4. 4 '-DOT

SPIKEADDED< ug/Kg )

oo • o63.363.3158158158

SAMPLECONCENTRATION

(ug/Kg)

000000

MSCONCENTRATION

< ug/Kg)

TT Ti-O • •-"

49.034.879.611667.2

MS7.

REC ft

37 *7755507343•

QC !LIMITS!REC. !

_______ i46-127!35-130!34-132!31-134!42-139!23-134!

ii

COMPOUND, EsssssBmscsssEsxssasa

gamma-BHC ( Lindan« ) ,Heptachlor ________

1 Aldrin

Endrin4,4* -DOT

SPIKEADDED{ug/Kg)sssacxsaea

63.363.363.3158158158

MSDCONCENTRATION

<ug/Kg)

l~>ae c;4.ta) • hJ

50.040.085.612379.2

MSD7.

RECS3K3K

40796354780

7.RPD ftESS-SEZK

-8-3-14-8-7-15

QC LIMITSRPD

503143384550

REC

46-12735-13034-1331-13442-13923-134

# Column to ba used to -flag recovery and RPD values with an asterisk

* Values outside o-f QC limits

RPD: _C| out o-f _& outside limitsSpike Recoveryi _2. out of 12 outside limits

COMMENTS:

FORM III PEST-2 — - -- Q/S7 Rt

5-00048

A R I D 1559"""

U.S. EPA - CLPERA SAMPLE NO,

6 " ________DUPLICATES

Lab Name: SOUTHWEST LAB OF OK Contract: 6S-D9-OOS9MU3823D

Lab Code: SWQK Case No.: 32381 SAS No.: SD(3 No.: MUT301

Matrix (water/sail): SOIL Level (low/med): LOW

7. Solids -for Sample: 45.1 "C Solids -for Duplicate: 35.0

Concentration Units (ug/L or mg/kg dry weight): MG/KG

J! Analyte1! Aluminum! Antimony! ArsenicI Barium '! Beryl lium! Cadmium! Calcium! ChromiumJCobalt1 Copper! I ronILead[Magnesium(Manganese! MercuryINickel! Potassium1 Seleniumi Silveri Sodium! Thai 1 ium! Vanadium! ZincI Cyanider

ControlLimit

88.7

_._

11.1

<•?

•?*? *?<£•&. •

11

Sample (S) C!I

29029.75301 !14. 0809 IB!2.6341 IB:94.09371 11.201418!1 . 3304 1 U I

502. 4249 IBS28.7104! 11 •— • • S5-_>S * c> i28.5291! J

26665. 498O! 120 . 6475 ! J983. 1386! Bt490 . 5392 I !

.1774IUI16.1720IBI

767.01141BJ1 .3304(Ui2.4168!&:

186. 6486! B!1. 33041 U!54.6419! !56.2147J !-i . 97-io i U i

i ii i

:Duplicate CD) C!

ii20961 -363OI !

1 1 . 5299 ! U 12-2173IU!9O.4920! I1 . 0426 1 B 11 . 4644 ! B !

522.9091 IB!24.40551 !1 T i A ; * R •i •-• • 1 O ._J i O i

28 . 4973 I i25277.86801 1

20.1986! !900,254718!515.7161! 1

. 1 7O6 i U !10. 9229! B!

540 . 0680 I B 11.3304 I U!1 • B6ji>-' t B i

162.74941U!1 , 3304 ! U !

48 . 7696 ! !64.4316! !3 . 8229 ! U !

i ii «

:y.RPD :

1

'— ' —--••-.•>

200 . 0 !200 . 0 .'

3.9114.2:

200 . o :4.0;16.2!5.11. 1 !

5.3:*•> ^ is.s:5.0:i38.7!34.7:

;

25.9:20 o . o :

;11 .4:13.6:

LI

*

rn;~

r

Pp

PPPPPPPPFPF'CVPPFPPpPPC

FORM VI - IN"V88

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY

' ab Names SOUTHWEST LAB OF OK Contract: 6S-D9-QOB9MU38

Lab Code: SWOK Case No.: "32381 SAS No.: SDE No.: MU3S01

Matrix: SOIL Level (low/med): LOW

/I Solids -for Sample: 45.1

Concentration Units (ug/L or mg/kg dry weight); MG/KG

i {Control1 ! LimitI Analyte ! 7.R

I Aluminum !J Antimony 175-1251 Arsenic I 75-125! Barium 175-125JB@ryllium!75-125! Cadmium 175-125! Calcium !! Chromium ! 75-125! Cobalt J 75-125! Copper ! 75-125ilron !(Lead 175-125agnesium!

.. langanese! 75-125I Mercury 175-125{Nickel 175-125! Potassium 11 Selenium 175-125! Silver 175-125(Sodium !i Thallium !75-125S Vanadium 175-125IZinc 175-125! Cyanide 175-125i i

Spiked SampleResult <SSR) C

!43.2981117.7206!969.9728!22.1600!30.8983!

!113.0438!223.9765 !143.3277!

!30 . 3947 !

ii690.9433!1.0440!

224.1379!t•

2 . 5366 !23.655O!

ri

21.7738!- 271.3027!

273.3179!41.8784!

i

SampleResult CSR) C

j14.0809IB2.6341 IB94.0937!1.2014JB1 .3304 I U

;28.7104!13. 8538 IB28.5291!

I20.6475!

!490 . 5392 !

-1774JU16.1720IB

j1.3304JU2.416810

;1.3304IU54.6419!56.2147!3 . 9736 ! U

!

_Spike

Added (SA)

219.5317.74878. 1421.9521.95

37.81219.53109.77

8.87'219.53

.92"? 1 O E?"T-Si 1 7 . -J.J-

4.4421.95

'22.17219.53219.5343.14

7.R

13.385 . 099.795.5140. S

96.095.7104.6

109.9

91.3113.594.7

57. 196.8

98. 298.798.997.1

Q!M

INftNIPIFIP!P

NIPINRIPIPIP!NRIFINRIPICVIPINR

NIFIPINRIFIPIP1CI

Comments

FORM V (Part 1) - IN

ARIOT56/

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700 W. Albany . Suite "C" . Broken Arrow, Oklahoma 74012 . 91&2S2-285B

CLIENT: URS CONSULTANTS, INC. REPORT: 323Sc570 DELAWARE AVE.BUFFALO, NY 14202 DATE: 08-22-90ATTNl PETER FAIRBANKS

LABORATORY BLANK

SAMPLE MATRIX* SOILSAMPLE ID i METHOD BLANK

DETECTIONCOMPOUND LIMIT (»q/Kg)

TPH 10.0

. TPH MATRIX SPIKE/MATRIX SPIKE DUPLICATE

* SAMPLE MATRIX I SOILSWLO # 3238.24/3238.23 (MS/MSD)PROJECT! DELAWARE SAND & GRAVELSAMPLE ID: UR-36 (MS/MSD)

SPIKE CONC. SAMPLE CONC. 1(•g/Kg) (wg/Kg)*

TPH 667 0

MSD CONC. MSD PERCENT(•g/Kg) RECOVERY

SAMPLE AMOUNTS . 30GDILUTION FACTOR: 1

AMOUNT FOUND(flip/Kg)

ND

RECOVERY DATA

IS CONC. MS PERCENT(•g/Kg)* RECOVERY

6OO 90%

RECOVERY PERCENTDIFFERENCE

TPH 600 907. 0%

DILUTION FACTOR NOT APPLIED TO THESE CONCENTRATIONS

A R I O I 5 6 2

3BSOIL VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lmb Name: SML-TULSA_______________ Contract: URS_______^ .

t Cedes Sl*JQ> Case No.: URS SAS No.: ______ SDG No.:

triv. inU a - EPA Sample No.: UR-44_______ Level : Clow/njed > LOW

COMPOUND

1 , l-l'ichloroethsn©^richloroethene

3 I '.'©no .......• \*~i i DroDenzene

SPIKEADDED(ug/Kg )

56.856. S« i. OwJO . OÂ Q

56. 3

SAMPLECONCENTRATION

< ug/Kg';

00

' i.15C!

MSCONCENTRATION

(ug/Kg)

54 . 752". 3R4, O

63-3_._ .__ 6i.i

M5

REC #

9~6~921001O9103 .

" L'lCLI ni r=PEC .

59- I Z6J1-17766— I -^2c;o i "rs^JT L -• ~bU-I _-

COMPOUND

1 „ l-Dicnloro^theneTrichloroethgng&«n=en«TolueneCMcrobenzEin©

SPIKEADDED(ug/Kg)

56. S56.856.856. B56.8

MSDCONCENTRATION

< ug/Kg)

51.5-49.554.560 . 957.6

MSD

REC #

918796105101

RPD #

5, £447

iQC LIMITS !RPD ! REC. i

22 i 59— 1 72 !24 ! 62-137!21 166-1^2:~? i ; "=;ij_ i —c '.i. A 1 •— > J J. •—• t •

^ i ' fa ( ') —• i ~ ™ '; :

0 Column to bm used to -flag rgcov^ry and RPD values with an asterisk

* Values outmide o-f QC limits

o-f _ 5 outside limitsRecov^rvs _ Q_ o'u"t o-f 10 outside limits

COMMENTS:

6 000487FORM III VOA-2 — - 1/37 Re^

3DSOIL SEMIVQLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

_ab Names SWL-TULSA Contract: URS

_ab Code: SWQK Case No.: URS 3AS No.:""

latrix Spike - EPA Sample

COMPOUND

Phenol _2-Chloraphenol1 , 4-Dichlorobensene . .N-Nitraso— di-n-prap. ( 1 )1 ,2,.4-Trichlaraben2ene_4-Chl or o— 3— methyl phenolAcenaphthene4— Nitrophenol2 , 4-D in itro toluene ____PeritachlorophenolPvrene

SDG No. :

No.: UR-44 Level: ( low/med) 'LOW

SPIKEADDED( ug/Kg )

1 52001 5200"... 7580758075301520O7530152007530152007580

SAMPLECONCENTRATION

< ug/Kg >

00000 'o00 •

— - 000

.

MSCONCENTRATION

<ug/Kg )

37'2010000"5220434056201=06004540

"1 12005260115006400

MS

REC $

57666957747O6074697634

QCLIMITSREC.

26- vO25-10228 10441 12633 10726 1 0331-13711-11428- 3917-10935-142

>

COMPOUND

P hen a 12-Chlorophenol1 , 4-Dichlorobenzene ___N-Ni troso-di-n-prop . ( 1 )

4-Ch 1 oro-3-methy 1 pheno 1Acenaphthene4 -Nitro phenol2 «4-Din itro toluenePentachlorophenolPvrene

-

SPIKEADDED(ug/Kg)

1520015200758075307580

1 52007580152007580152007580

MSDCONCENTRATION

( ug/Kg )

1 020010200504044005630

1 1 i" 604970

1 25005720

1 22007030

MSD•/REC #

6757

58747366"8275SO93

• /

RPD *

-16

4

0-4-10-10— s-5-10

QC LRPD

T="

502733

1950474736

IMITSREC.

26- 90

2B 10441 12638 10726 10331-13711-11428- 3917-10935-142

(1) N-Nitroso-di-n-propylamine

# Column to be used to -flag recovery and RPD values with an asterisk* Values outside o-f QC limits

RPD: _0 out o-f 11 outside limitsSpike Recovery: _0 gut o-f 22 outside 1 imits

COMMENTS: UR-44 URSINST:F SWL#3238,09

FORM 111 SV-2 ^ . 1/87 ReveroobTso


Lab Name: SHL-TULSA_______________ Contract: URS3_______

Lab Codes 5MQK Case No.: URS SAS No-s ______ SDG No.:

Matrix Spike - EPA Sample No • ; UR-44______ Level:(low/m@d) LOW

COMPOUND

gamma-BHC (Lindane) ___HeptachlorAldrinDieldrinEndrin4,4'-DDT

•

SPIKEADDED<ug/Kg>

60. 460.460.4151151151

SAMPLECONCENTRATION

(ug/Kg )

000000

MSCONCENTRATION

(ug/Kg )

46.368.245.0124137125

MSV.REC #

7711374829183

QCLIMITSREC.

46-12735-13(334-1323 1 - 1 3442-1392T--134

COMPOUND

aamrna-BHC (Lindane)HeotachlorAldrinDieldrinEndrin ~~~4,4'-DDT

SPIKEADDED< ug/Kg)

60.460.460.4151151151

MSDCONCENTRATION

< ug/Kg)

42.865.547.9129140137

MSD.//.REC #

7110879859391

•/.RPD #

85-7-4_jL.

-9

QC L]RPD

50314338

' 4550

ii[MI rs REC m

- — — -^46-12735-13074-13231-1 -.442-13923-134

# Column to be used to -flag rgcov^ry and RPD values with an asterisk


RPD: _G! out 0<f _6. outmid© limitsSpike Recovery: _g. out o-f 12 outside limits

COMMENTS:

FORM III PEST-2 S/87

SRIOJ565* " •

U.S. EPA - CLPEPA SAMPLE NO.

6 ______DUPLICATES

Lab Name: SOUTHWEST LAB OF OK Contract: 68-D9-0089MU3809D

Lab Code: SWOK Case No.: 32381 SAS No.: SDG No.: MU3801

Matrix (water/soil): SOIL Level <low/med): LOW

7. Solids -for Sample: 88.7 7. Solids -for Duplicate: 87.8


i1 Analyteir Aluminum! Antimony! Arsenic! Barium! Beryl lium! Cadmium! Calcium! Chromium! CobaltI CapperI IronI LeadI MagnesiumI ManganeseI Mercury1 Nickel1 Potassium1 SeleniumISilverI-Sodium! Thai liumI VanadiumIZincI Cyanidei•

ControlLimit

45.1

.7

.1

11.3

1.9-

iiSample (S) CI*•

7780.9541 I I5.8625IUI5.63701 UI58 . 8247 ! J

. 4359 I B I

. 67641 U!410.7929IBJ1 1 . 9042 1 14.2115IB!3.6077IU!

11807.4200! !74.01351 I320 . 3267 ! B 1199.6961! I

.42641 !5. 05281 B!

321.7134IBI.6764JUI. 6O84 ! B !

82.7508IU!. 6764 I U J

20.83011 !25.07291 11.S604IU!

i i

«iDuplicate CD) CIii

10990.8290! J5.7475IU!1.1053JU!

75.66171 I. 4886 ! B 1.6632IUI

321.4701 IB!13.5648! !4.1887:B!3.5369IU:

12364.98101 I71.7886! 1348.1100IB!195.8722! 1

.26491 I8.4617IBI

366.8301 !B!. 66- ji, i U i. 7053 ! B J

S1.12S3IUJ. 6632 I U !

21.9900! I30.62891 I2.os7s:u:

i ii i

.•/.RPD

34.2

25.011.4

24.413.0

.5

4.63.18.31.9

46.750.413.1

14.8

5.419.9

1

Q!Mi

*!PIPIFIPIPIPIPIP!PIPIP:FIPIP

* ICVIP;pIFIPIPIFIPIP1Ci

FORM VI - IN7/88

0-0004UO

flRI01566

u.5. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY

/ ' *b Name: SOUTHWEST LAB OF OK Contract: 6S-D9-0089MU3809S


Matrix: SOIL - - Level Clow/med): LOW

"/. Solids -for Sample: S3.7


I {Control! ! LimitI Analyte I */.R! !{Aluminum !{Antimony 175-125! Arsenic 175-125! Barium 175-1251 Bery 1 1 i urn I 75- 1 251 Cadmium I 75-125{Calcium I! Chromium ! 75-125! Cobalt .'75-125i Copper 175-125I Ironi Lead Iagnesium!

. Manganese ! 75-125! Mercury !75-i251 Nickel ! 75-125! Potassium!.' Se 1 en i urn 1 75- 1 25(Silver 175-125I Sodium I\ Thai lium 175-125! Vanadium 175-125I Zinc 175-1251 Cyanide ! 75- 125I !

Spiked SampleResult (SSR)

116.37022 . 0829

471.548910.S79214.2190

56 . 0626106.066553.0721

47.0158

313.0247.2523

110.5212

2.051611.1689

.6697127.6149126.439714.7471

C

B

U

SampleResult CSRJ C

ii5.S625JU5 . 6370 I U58.8247!

. 4359 ! B

.6764IUi

11.9042!4.2115JB.3.6077,'U

ii74.0135!

i199.6961 !

.4264!er r'le-'jp ' Q-J . V.J«£.O i O

»t.6764 I U. 6084 I B

».6764IU

20.3301 125.0729!1.8604JU

ii

SpikeAdded <SA)

111 .628.93

446.4911.1611.16

44.651 1 1 . 6255.81

4.46

1 1 1 . 62.54

1 1 1 . 62

2.23,11.16

11.16i 1 1 . 621 1 1 . 6218.18

"

•/.R

104.7TT -r*^w • -J>

92.493.6127.4

98.991.395.1

-605.3

101 .5-32.294.5

92 . 094.6

0 . 095.790.881.1

.

itQ!M

ii;NRIP

NIFIP!P

NIPINRIPIPIPINRIF!NRI F*

NICVIPINRIFIPINR

NIFIPIP:cj

Comments:


£-000491

A R J O I 5 6 7

U.S. EPA - CLP

7LABORATORY CONTROL SAMPLE

Lab Name: SOUTHWEST LAB OF OK Contract: 68-D9-0089


Solid LCS Source: EPA0287

Aqueous LCS Source: EPA-LV

i

I Analyteti! Aluminum! AntimonyI ArsenicI Barium! Beryl liumI Cadmium! Calcium! Chromium! Cobalt! Copper

-on. _ead! Magnesium1 ManganeseI Mercuryi NickelI Potassium1 SeleniumISilverI Sodium1 Thai lium1 VanadiumIZincI Cyanideit

Aqueous (ug/L>True Found

201O.O!1010.0!47.4!

1960. O!483.01.502 . 0 !

48700.0!510.01502.01515.0!2040 . 0 !4500.0!24600.0!504 . 0 !

i480 . 0 1

49OOO . 0 I52.6!500 . 0 !

49600 . 0 I97.01488.0!

31OO.OIitii

2039.997.44.

1969.479.506.

47777 .507.484.513.1944.4605.24119.

487.

490.47463 .

50.470.

49154.84.496.2880.

70!16!46!4O!52!55!OO!50!13!52130150!OO!31 !

i•44!00!06!8*-i i*L i

OO!75!69!30!

itti

•/.R

101.598.793.8100.599.3100.998.199.596.499.795.3102.398.096.7

102.296.995.294.299.187.4101.892.9

True

325.0!• 211.0!917.0!

4.8!19.4!45.41

196200.0!99.61

.144.O!6910.0122430.0!236.01

118100.0!208 . 0 !12.7!60.9!5O.O!TO *•* I•_>T • -t iO"» *"> i4U. . JL. t

50.0!39.0!65.8!187.0!5.6!

i

Solid (mg/kg)Found C

304.169.799.4.18.45.

220818.86.

l<j>*i> •7133.18995.227.

132763.214.14.52.69.08 .16.

r>Tr**_•_'-;. •

•1'C* .

59.167.5.

j 1••? i*? i6IB8!Bii4!•j' io *5 111t7 '/ 1718!1 !o;u8!6!7IB4!4!1 !9!!

OT>cf

12763501635

16630079124600617770188

10O400177S

-4901915024511384

11

Limits 7.R I-ii

.0

.0

.0

.0

.5

.7

.0* ».0.0.0.0.0.0.5

*—>.0.1.5.0.6.7.0.3

424.0294 . 01199. 040 .0T*'"? T55.1

2256OO.O120.0162.07820.027080 . 0285.0

1 299OO . 0239 . 017.072.6

1000.059.429.0

1000.O53.579.9236,06.9

93.6!SO . 2 J37. 2!95. SI96.91

1 00 . 9 1112.5!86.6193.01103.2!84.7!96.3!112.41103 .2 !116.5!85.6!0 .0 I ••''99 . 0 !74. 3 IV465 . 4 (/85.6!90.3 !89.4!105.4!

ii

FORM VII - IN7/8B

£-000492

fl R I 0 1 5 6 8

r

U.S. ERA - CLP


Lab Names SOUTHWEST LAB OF OK Contract: 6S-D9-0089

Lab Codes SWQK Case No.: 32381 SAS No.: " SDG No.: MU3801

Solid LCS Source: EPA02S7

Aqueous LCS Sources

*•i«! Analyte!! Aluminum! Antimony! Arsenic1 BariumI Beryllium1 Cadmium! Calciumt Chromium! Cobalt! Copper'on

.-•ad(MagnesiumI Manganese! MercurySNickelI PotassiumI SeleniumISilver) SodiumI Thai lium1 Vanadium!Zinc\ Cyanidei

AquecTrue

.

.

DUS <ug/LFound

- -

- .-

7.R__

SolidTrue Found C

f^^ l~\ ' "T/"iQ Q '-w .'j . yj i -_tijo . a >211 .01 163.1 I917.01 955.8!

4.8! 4. SIB19.4! 17.8!45.41 46.3!

196200. 01215861. 3!99.6! 83.7!144.0! 128.2!6910.0! 7481.2!22430.0! 18648.3!236.0! 229.2!

118100.0! 134970.3!208.0! 207.5112.7! 11.7!60.9! 51 .4150.0! 69.0IU39 . 2 I 37 . 4 I^*n "J 1 4 • •-* 1*i. - . 4. 1 i O . —— t

50.01 222.9 IB39.0! 42.6!65.8! 59.3!187.01 164.7!

5 A ' ^ c") *. O i *J . V it i

mg/kg )Limits

225.0! 424.0127.0! 294.0635.0!' 1199.00 . 0 I 40 . 0

1 1_ C" 1 T^ T*1 O . hJ t -i-J- . •-*

w*o . / i 3«J . X166800.01225600.0

79.2! 120.0124.0! 162.06006.0! 7820.017770.0! 27080.0188.0! 285.0

1OO400.0! 129900.0177.0! 239.0

8.5! 17.0::49.2! _ 72.6

0.0! 1000.019.11 59.4

:-15.5l 29.00.0! 1 000 . 024 . 6 ! 53 . 551.7! 79.9133.0! 236.0

4.3! 6.9ii

i

•/.R

95 . 077.3

104.2100.091.8102.011O.O84.089.0108.383. '97. |114. J|99.892.184.40.0

95.473.0

4-45.8109.290. 138. 189.3

FORM VII - IN7/88

0-OCU49

A R i O I 5 6 9

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700 W. Albany . Suite "C" . Broken Arrow, Oklahoma 74012 . 918-251-2858

CLIENT: URS CONSULTANTS, INC. " REPORT: 3238a570 DELAWARE AVE.BUFFALO, NY 14202 DATEs 08-22-90,ATTN: PETER FAIRBANKS

LABORATORY BLANK

SAMPLE MATRIX* SOIL SAMPLE AMOUNT? 30GSAMPLE IDs METHOD BLANK DILUTION FACTORS 1

DETECTION AMOUNT FOUNDCOMPOUND_______________LIMIT (ma/Ka)____________

TPH 10.0 ND

TPH MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY__

SAMPLE MATRIXJ SOILSWLO # 3238-10/3238.12 (MS/MSD)PROJECT! DELAWARE SAND * GRAVELSAMPLE IDs UR-44 (MS/MSD)

SPIKE CONC. SAMPLE CONC. MS CONC. MS PERCENT<»g/Kg) (mg/Kg» («g/Kg)« RECOVERY

TPH 667 22 S9O 857.

MSD CONC. MSD PERCENT RECOVERY PERCENT(ing/Kg) RECOVERY DIFFERENCE

TPH 610 98'/. -3V.

* ^ DILUTION FACTOR NOT APPLIED TO THESE CONCENTRATIONS

A R I O I 5 7 0


Name! SWL-TULSA_______________ Contract: URS_______

Lab Code: BVJQK Case No.: URS SAS No.: ______ „ SDG No.:

Matri,; Spike - EPA Sample No. : 'BC-6-1______ Level :< low/med) LOW

COMPOUND

1 » i-Dichlorogthgne ____

EenzsngToluene •_...Chlorabgnzfme

SPIKE !ADDED(ug/Kg) !

54.4 !54.4 !54.4 !54.4 !54.4 !

!

SAMPLECONCENTRATION

(ug/Kg )

O00O0

MSCONCENTRATION

(ug/Kg)

= 42.639-247.551.848.6

MS

REC

• 7B72879539

! CfC !SLIMITS!

# ! REC . !. ... ' .... _ 1 - *

159-172!162-137!!66-142!159-139!160-133!"i i

COMPOUND

1. l-Dichloraeth«n» ____Trichlora^theneBenc^n©Tolu«naChloro benzene

SPIKEADDED(ug/Kg)

54-454.454.454.454.4

MSDCONCENTRATION

<Lig/Kg>

46.239.648.752.148.3

MSDmi

REC *

asT-T

909689

~

•f/.RPD #

-9. -1

-1O

QC L:RPD

f *"/

74

21*. u.^1

:MITS REC.^

59-17262-13766-1^259-13960- 1 33

S Column to b^ used to -flag recovery and RPD values with an asterisk


RPD: _0 out o-f _5. outside limits "3piK» Recov*rys _0 out of 10 outside limits

COMMENTSi SC-c-1 - URSINSTsI SWL#367S.30 5

FORM Til VOA-2 -- - 1/37 Re

6-000495

3DSOIL SEMTVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

» Lab Name: 5WL-TUL5A______________ Contract:

Lab Code: SMOK Case No.: URS SAS No.: ______ SDG No.:

Ma .;; Spike - EPA Sample No.: BC-6-1______ Level:(low/med> LOW

COMPOUND

Phenol - _2-Chlorophenol1 ,4-Dichlorobenzene ___N-Nitroso-di-n-prop. ( i )1 , 2,4-Trichlorabenzene_4-Ch loro-3-methyl phenolAcenaphthene4-NitroDhenol2, 4-Din itro toluene ____F'entachlorophenolPvrene

SPIKEADDED(ug/Kg)

1450O145007250725072501 45007250145007250145OO7250

SAMPLECONCENTRATION

(ug/Kg)

O00000000o0

MSCONCENTRATION

(ug/Kg)

543051502960244O 2850594O281053402890369O3030

MS

REC #

37364134 *39413937402542

QC !LIMITS!REC. !

26- 90!25-102!28 104!41 126!38 107!26 103!31-137!11-114!28- 89117-109!35-142!

It

COMPOUND

Phenol_______2-Chlorophenol.1,4-Dichloroben2@ne___N-Nitroso-di-n-prop.<1)1.2,,4-Trichlorobenzene_4--Ch loro-3-methyl phenolAcenaphthene____4-Nitrophenol________2,4-Dinitrotoluene____Pentachlorophenol_____Pvrene ___________....

SPIKEADDED< ug/Kg)

1450014500725072507250145007250145OO7250145007250

MSD ! MSDCONCENTRATION! 7.

< ug/Kg) ! REC

35

2Q *5* *#-

sMisa

RPD

6OS-252S.

8

10

QC LIMITSRPD

50273823331950474736

REC

26- 9025-10228 10441 12638 10726 10331-13711-11428- 8917-10935-142

tl> N-Nitroso-di-n-propylamine

# Column to be used to -flag recovery and RPD values with an asterisk# Values outside o-f QC limits

RPD: _ 0 out of 11 outside limits .Soike Recovery: «3. v out o-f 22 outside limits

COMMENTS: BC-6-1 ._ URSI NST : F SWL#3678 . 30

\\

FORM III SV-2 , 1/37 Rev.

0-00049C

A R I O I 5 7 2

3FSOIL PESTICIDE "MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Names SWL-TULS.fi______________ Contract: URS_____

Lab Code: SfrJQK Case No.: URS SAS No,: ______ SDG No.:

Matrix Spike - EPA Sample No.: BC-6-1_____ Level:(low/med> LQW__

COMPOUND

gamma-BHC ( Lindane ) ___HeotachlorAldrinDieldrinEndrin4,4'-DDT

SPIKEADDED(ug/Kg>

5.78s, "7Q

5.7814.514.514.5

SAMPLECONCENTRATION

(ug/Kg)

0O0Oo0

MSCONCENTRATION

< ug/Kg)

3.496OQ

4. • / wl

20.317.67.70

MS7.REC #

6O12148140 *121S3

DC !LIMITS!REC . I

46-127!35-130!34-132131-134!42-139!23-134!

!

COMPOUND

gamma-BHC (Lindane),Heptachlor________Aldrin___________Dieldrin__________Endrin____________4,4'-DDT__________

SPIKEADDED(ug/Kg)

IBIS se rn.sc am at

5.785.785.7814.514.514.5

MSDCONCENTRATION

(ug/Kg)

4.O48.124.469.3518.99.75

MSD7.REC #sar«aea>s

7014O *776413O67

7.RPD #33JB3ES3B

-15-15-46 *75 *-7

QC LIMITSRPD

503143384550

REC.

46-1235-13034-13231-13442-13923-134

ft Column to be used to -flag recovery and RPD values with an asterisk


RPD: _i out of _6 outside limitsSpike Recovery: _2 out of 12 outside limits

COMMENTS:

FORM III PEST-2 B/87 Rev.

0-00049

ARIOI573

AffiRICA* ANALYTICAL t TECHKICAL SERVICESMtTRtt SPIKE EVALUATION FORK

UfiS

SAMPLE IB BC-6-1HS

H£T MT. 10.0

atount aiount itountno in spl. added detected I TARGET

added ppt ppt ppt recovery recovery lints2378 TCDF 2.5 0 250 298.5 119 60 - 140 IHPC8F 10 0 1000 1513.0 151t 60 - 140 X,

25 0 2500 3859.0 154* ' 60 - 140 I

2378 TCSa 2.5 0 250 424.6 170* 60 - 140 IPCBO 10 0 1000 1596.3 1601 60 - 140 Xmm 10 o 1000 1502.3 isot 60 - 140 z

DUPLICATE SAMPLE EVALUATION

SAWLE ID BC-i-lMS 8C-6-1HSD

»a JIT. to.o 10.0aiount amount RPDin spl. in spl.ppt ppt

2378 7CBF 298.5 313.8 5.0HPCDF 1513.0 1390.0 8.5OCDF 3B59.0 3732.0 3.3

2378 TCDD 424.6 385.7 9.6PCDD 1SH.3 1507.7 5.7HICDD 1502.3 1520.8 1.2

AHE8ICAH AWU.YTICAL i TECHNICAL SERVICES

HATfUX SPIKE EVALUATION FORH

URS

SAMPLE ID BC-6-1HSD

«£T HT. 10.0

aiout itount amountng in spl. iddefl detected Z TARGET

added ppt ppt ppt rttovtry recovery liiits2378 TCDF 2.5 0 250 313.8 126 60 - 140 IHPC0F 10 0 10W 1390.0 139 60 - 140 Z

25 0 2500 3732.0 149* 60 - 140 Z

2371 TCD0 2.5 0 250 385.7 1541 60 - 140 ZPCM 10 0 1000 1507.7 151* 60 - 140 ZHICD0 10 0 1000 1520.8 152* 60 - 140 Z


SAHPtE IS IC-6-1HS IC-6-1HSS

»T. 10.0 10.0

await tflIB spl. in spl.ppt ppt

237i TCDF 291.5 313.S 5.01513.0 1390.0 8.53859.0 3732.0 3.3

2371 TCDD 424.6 385.7 9.6PCDD 1596.3 1507.7 5.7HXCDD 1502.3 1520.fi 1.2

U.S. EFA ---CLPEPA SAMPLE NO.

6 _____ ___DUPLICATES

Lao Name: SOUTHWEST LAB OF OK Contract: 63-D9-OO39 ___________

l_ab Code: SWOK Case Mo.: 367S1 SAS No.: SDG No.: MU7B01

Matrix (water/soi1>: SOIL Level (low/med): LOto

y. Sclids tor Sample: 88.4 7. Solids -for Duplicate: 33.4

Concentration Units lug/L or mg/kg dry weight): MG/KG

i1 Anaiytei

; Al u/ni nunt1 Antimonyi Arseni c! Bar i um! Beryl I ium1 Cadmium; Calcium1 Chromium! Cobalt! Copper! IronJLead1 Magnesium! Manganesei Mercury-INicksl'! Potassi um! Sel'eni um! Si 1 veri Sodi umI Thai 1 ium! VanadiumIZinc! Cyanide!

ControlLimi't

2-i 2

5.6

.7

,

.

11.24.5

Sample CS> C

95 1O. 9846;1 1 . 4336 ! B1. 1200 I L1

24. 8567 IB. 5283 ! B. 6720 ! U

146. 6689 JB10.897912.8044IB3.5841IU

16912.3700!4.7489!

219. 6590! B82.3636!

t6. 2663 IB

173. 4436 IB. 4430 ! U1.0961 !3

112.352713. 6720 HJ

19.3959!10. 19O4!2. 1833JU

!

Duplicate CD) C

4450. 3073 I13.332OIB1. 1312JU9. 1307! 3. 333S ! B.67971U

91. 2007 IB8. 06 OS!1 . 3875 J B3.9051 i

13433.1690!- 2-36431106. 1221 IB21.7678!

15. 1405JB

i 23. 5063 i 32.2624!U. 9024 ! B

1 OO.3359 IB". 67S71U9. 2842 IB5.1448!1. 1312JU

1 • !

y.RPD/ jll . u'

1 -li * •'-*

92. 145. i

46.629. 967.6200.022. 967.069. 7116.4

1 9. 7~ r*i *•»

19.410.3

70.565. S

I

Q

*

#

'•*•**

*

*

M

PPFPPPPPPPc-

FF'PNRPp.FPP—PPC

FORM VI - IN7/88

U.S. EPA - CLP

5A EPA 3AMF,_SPIKE SAMPLE RECOVERY"" "

) 1 MU7830SLab Names SOUTHWEST LAB OF OK- Contract: 68-D9-5089 ! __Ji£r4:J______ !

Lmb Code: SWOK Cam© No.: 36781 SAS No.: " SDG Mo.: MU7801

Matrix: SOIL Level Clcw/med): UDW

% Solids -for Sample: 92.5

Concentration Units Cug/L or mg/kg dry weight): MG/KG

! ; Control1 ! Limitt Anmlyte ,' XRI :* Aluminum !I Antimony (75-125f Arsenic : 75-125i Bar ium ! 75-1 25JBeryllium!75-i25J Cadmium t 75-125i Calcium ;! Chromium 175-125! Cobalt ,'75-125

.! Copper 175-125). Iron !ÎLead ! 75-125

1 Magnesium!! Manganese ! 75-125{Mercury ! 75-1 25! Nickel ! 75-1251 Potassium I(Selenium '75-125{Silver 175-125'Sodium !! Thai lium ! 75-125< Vanadium I 75-125IZinc J75-125ICyanid® 175-1251 !1 4

Spiked SampleRMuIt (SSR) C

ii39. 7263 J5^3571 1

507.0297112.223O!15.5794!

ii57.32971123. 3475 i69.65231

11O. 46191

it181.4773!

.094O1U126,3848!

i1 . 0425 1 BSATTT- I. O <«••_> . i

i1

1 1 . 6628 1133.5733!132.4586!19.7477!

!

SampieResult CSR) C

>9. 9595 IB1-2131 !B

27- 1645SB.4011 ;B. 6422 ! U

ii1 1 . 5487 !2.3619IB3.42521U

i•5.59171

ii55.5301 1. 1029 !U

5.67121Bii

- 4232 ] U1 . 3207 1 B

ii. 6422 ! U

IS. 5623!13.9876!1 . 8575 ! U

ii

SpikeAdded (SA)

. 103.113.56

432.431 0.3110.81

:; 43.24108. 1154.05

4.28

108. 1 11 . 00

108.11

2. 141O.E1

10.701 OQ . 1 1108. 1118.02

1 11 < <1 !r i <

7.R ! Q I M ,i I

J ! NR !27.5!N,'P :D4.~;N!F !1 1 1 . O ! ! P !109. 4 ; IP !144. i ;N;P ;

J 1 NR !105.9! JP !111.9! i g128. 9!N, •

! ihP113.3! IF

i INR116.5! IP

O.OINICV112. 1 : IP

i ; NR43. 7;NJFi?.6 -NIP

: ; NR109,01 IF106!. 4: IP1O9. 61 IP109. /a, 1C

i ii i t

Comments:

FORM V (Part 1)- - IN

fir-00050*R!0!577

U.S. EPA - CLPEPA SAMPLE NO,

6DUPLICATES 1

! MU7830DLab Name: SOUTHWEST LAB OF OK Contract: 63-D9-O089 i _JJC^-j_____

Lab Code: SWOK .Case No.: 367B1 SAS No.: SDB No.: MU7BO1

Matrix (water/soil): SOIL Level <iaw/med): LOW

% Solids for Sample: 92.5 X Solids for Duplicate: 92.5


i AnalyteiI Aluminum1 Ant i manyJ Arsenic! Bar i umi Beryl 1 i um1 Cadmium! Cal ciumJ Chrcjmium! Cobal t1 Copper! Iron!Lead; Magnesium! ManganeseS Mercury! Nickel: Potassium: Selenium! Si 1 ver! Sodium! Thai 1 iumJ Vanadiumi ZincI Cyanide

ControlLimit

5.4

1O.74.3

Sample (S) C

1O61 1.4480!9. 9595 IB1.2181IB

27. 1645 IB-4O11 IB' . 6422 I U

185.432OIB1 1 . 5487 !2.3619!B3.4252JU

15599. 1060!5.5917!

2S4.09O3JB55.53011. 1029IU5.67121B

245. 6526 IB. 4282 ! U

1 . 3207 ! B131. 0220 !B

. 6422 1 U18.5623!13.9876!1 . 8575 ! J

Duplicate <D) C

9397. 7990 !3.5511 IB1.3124 IB25. 8074 IB.363213. 6436 ! U

187. 3804 IB11.2833! •3. 0387 IB6.80661

15665.0010!6.6422!

333. 1207 IB60.3643!. 1029 JU

7. 3242 IB250. 5 1 79 IB

. 4324 ! U1. 1359 iB

112. 9765,! B. 6486 J U

16.6006!14.0658!1 . 3900 ! U

7.RPD

12. 115.27.55. 19.9

1.0''3 "

25.1200 . 0

.417.215.99. 2

25.42 . 0

15.014. S

11.2.6

i

irIP

IP

IFfPIPIPIPIPIP

*!PIPIFIPIP;CVIPIPt ;""

IP

IP

! PIP1C

FORM VI --IN7/83

6-00050A R 1 0 I 5 7 8


Lab N«m»: SWL-TULSA_______________ Contract: URS______: "

Lab Codg: SVJOK Case No.: URS SAS No.: ______ SDG No.:

Matrix Spike - EPA Sample No.: BC-6-~______ Leveli(low/med) MED

{COMPOUND

1 . 1-Dichloro^th^ne ____Trichloro^th^neBenzene'Tolusng

! CHlorobenzenî _..=

SPIKEADDED< ug/Kg)

67906790679067906790

SAMPLECONCENTRATION

( ug/Kg )

000o0

MSCONCENTRATION

(ug/Rg)

3440556060 1 060505950

MS

REC #

51 *823999SB

QCLIMITSREC.

59-17262-13766-14259-1 7?6O-133

COMPOUND

1 , l-Dichloroeth©ng ____Trichloro^th^neBenzeneTolueneChlorobgnzene

SPIKEADDED(ug/Kg)

67906770679067906790

MSDCONCENTRATION

(ug/Kg >

36505300626066006820

MSDV.REC #

54 *859297100

•//.RPD #

-6-4

_C3

-13

QC LIRPD

•T"?

24212121

iiEMITS '

REC. t

59-1726^__ 4 T"^^1—— 1 _' /

66-14259-13960-133

t* Column to bm used to flag recovery and RPD values with an asterisk

* Value* outmide o-f QC limit*

P.PDi _ 0 out o-f _ 5 outside limits ; :Spike RacDvervs. _ 2. OLJt o-f 1O outside limits

COMMENTS i

FORM III VOA-2 1/S7 Res

503DO05-^

A R I O I 5 7 9

3BSOIL VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVER/

Lab Name: SWL-TULSA_______________ Contract: URS_______

Lab Code: SUiOK Case No.: URS 3AS No.: ___^_ SDG No.:

Matrix Spike - EPA Sample No.: .BC-7—2_______, Level :(Iqw/med > LOW

COMPOUND

1 . 1-Dichloroethene ____TrichloroetheneBenzeneTolueneChlorobensene

SPIKEADDED< ug/Kg)

oo • w63.5od . kj63. 568.5

SAMPLECONCENTRATION

(ug/Kg)

60011.0 -9.73

M9CONCENTRATION

(ug/Kg)

e;o -7J 7 . i

~ e; cr•-t , . J

60.862.1 .61 .5

MS.//f

REC *

877789-re;

76

DCLIMITSREC.

59-17262-13266-14259-1 _.960- 1 .. »i

COMPOUND

1 , 1-Dichlordethene .__.TrichloroetheneBenzeneToluene?Chlorc-benzene .

SPIKEADDED(ug/Kg)

68.56S.563.563.563.5

MSDCONCENTRATION

< ug/Kg)

er^ f, i%J/ . T

52.961. 160.759.2

MSDf,

REC S

85773973-~n-,/ -i

•/fm

RPD tt

»•>00o>1=]

DC L .RPD

*?*24^* 1*. 12121

iMITSREC.

5=9-1 "262-13766-14259-13?60-1 ."

# Column to. be used to -flag recovery and RPD values with an asterisk

* Vslues outside o-f QC 1 imits

RPD: _0 out of _5 outside 1imitsSpike Recovery: _0, out of 10 outside limits ;

COMMENTS: 3C-7-2-- - -^ URSINST:I 3

FORM IIT"VOA-2-. .. . .. 1/B7 =e

000304

01580


Lab Name: SWL-TUL5A______________ Contracts URS_______

Lab Codei SMOK Case No.: URS SAS No.: ______ SDG Nol:"\

Ma. *x Spike - EFA Sample No.: BC-6-4______ Levels<low/med) LOW

COMPOUND

Phenol2-Chlorophenol1 ,,4-Dichlarobenzene ___N-Nitroso-di-n-prop.~( 1 )1 j,254-Trichlarobenzene_4-Chloro-3-methy 1 phenolAcenaphthene4-NitroDhenol2?4-Dinitrotoluene^ ___PentachloroohenolPyrene _ _ __

SPIKEADDED(ug/Kg)

7240724036203.620362072403620724036207240-p. t ~\s\

SAMPLECONCENTRATION

(ug/Kg)

00000O0000

MSCONCENTRATION

< ug/Kg)

565052102360199O250057902460608027708220*?QOf"i

MS•/Sm

REC #

7872655569SO'688477114 *_ ,

DC !LIMITS!REC. !

26- 90!25-102!28 104!41 126!38 107!26 103!31-137!11-114!28- 89!17-109!_^ e , , ,

t*

1 COMPOUNDJ MC3atSKXSE»^£3ES

! Phenol___2-Chlorophenol________154-DichlQrobenzen©___N-Nitroso-di-n-prop.(1)1?254-Trichlorobenz»ne_4-Chloro-3-methylphenolAcenaphthene_________4-Nitrophenol______- _._2«4-DinitrotoluenePentachlorophenol_____Pyrene___. _____._ -

SPIKEADDED(ug/Kg)£»« 35s=za:

7240724036203620362072403620724036207240362O

MSD J MSDCONCENTRATION! %

(ug/Kg) J REC #

3o 5393

84

i U1

RPD #

1*4.13-6-

QC LIMITSRPD

50273823331950474736

REC.

26- 9025-10:2S 104!41 126!39 107!26 103131-137!11-114128- 89!17-109!35-142!


# Column to be u*»d to -flag recovery and RPD valuem with an asterisk* Value* outside o-f QC limits -

: QHs out o-f 11 outside limitsSpike Recovery: \ S* out o-f 22 outside limits

COMMENTS : BC-6-4 URSINSTsF SWL83678.33

FORM III SV-2 - 1/87 Re

flR-l-ai58

3DSOIL SEHIVQLATILE MATRIX SPlKE/MAfRIX SPIKE DUPLICATE RECOVERY

Lab Name: SWL-TULSA______________ Contract: URS_______

Lab Code: SWOK Case No.: URS SAS No.: ______ SDB No.:

Ma. ,x Spike - EPA Sample No.: BC-7-2______ Level:<low/med) LOW

COMPOUND

Phenol2-Chloroohenol1 ,4-DichIorobenzeneN-Nitroso-di-n-prop. ( 1 )1 ,2,4-Trichlorobenzene_4-Ch 1 oro-3— me thy 1 pheno 1Acenaohthene4-Nitroohenol2. 4-Din itro toluenePentachlorcohenolPvrene

SPIKEADDED(ug/Kg)

912091204560456045609120456091 2O456091204560

SAMPLECONCENTRATION

(ug/Kg)

880000000

. 0000

MS ! MSCONCENTRATION! 7.

(ug/Kg) ! REC *

IfTo-ros* me*Tl3o 7SG£ ! 5 34-UH&3TO6 !C»tW"3*40«4£ W-953if3o3-&aO. H5&A

*)H*lo TS kO ! ZS4."31 GO -TO 1-6 s Sa.es.^ fD~l 1 flJ l l Ifcfi V 7?^ — itU

Sio " jj o rw 7t

QC !LIMITS!REC. !

26- 90!25-102!28 104!41 126!38 107!26 103!31-137!11-114!28- 89!17-109!35-142!

COMPOUND

Phenol2-Chlorophenol1 ,4-DichlorabenzerieN-Nitroso-di-n-prop. ( 1 )1 ,2,4-Trichloroben2ene_4-Ch loro-3-methyl phenolAcenaphthene4-Nitrophenol2 ? 4-Din itro toluene ____PentachloroDhenolPyrene

SPIKEADDED(ug/Kg )

18300 "18300914091409140183009140183009140183009140

MSDCONCENTRATION

(ug/Kg)

117001020060705240588O111005890111006 ISO130006720

MSD !X ! 7.REC #! RPD $

59 Pfe-fe> -*56 !3 4S*66 ! 3 MS.57 IMS* *64 !lUS561 JÎ-SS *•64 !M*3i *61 ffl«t 34-68 ! )4 S*-71 !3S«S-*74 ! 1 -4.

ii

DC L]RPD

3550273823

195O474736

[MITSREC,

26- 9025-10228 10441 12638 10726 10331-13711-11428- 8917-10935-142


# Column to be used to -flag recovery and RPD values with an asterisk* Values outside of QC limits

RpD: Q "S out of 11 outside limit'sSpike Recovery: o » out of 22 outside limits

COMMENTS: BC-7-2 URSINST:F SWL83678.25

J/ .1

FORM III SV-2 1/87 Rev.

0000506

flRIOl582

3FSOIL PESTICIDE' MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Names SWL-TULSA______________ Contract: URS______

Lab Code: SUJQK Case No.: URS SAS No.: ______ SDG No.:

Matrix Spike - EPA Sample No.: BC-6-4_____ Level i (low/med) LOW

COMPOUND

aamma-BHC (Lindane)HeotachlorAldrin

' DieldrinEndrin _ _4. A * — nnT~T * T MM 1

SPIKEADDED(ug/Kg)

5.785.785.78

14.514.514. =;.Jk T • J "

SAMPLECONCENTRATION

(ug/Kg)

00OO0-u

MSCONCENTRATION

(ug/Kg)

6.4610.81.823.794.747.50

MS ! QC !7. [LIMITS!

REC #! REC. IrSSSSSX J 3KM353 ———— j

112 J46-127!187 *! 35-1 30!31 *!34-132!26 *!31-134!33 * 142-139!&*^ t TT i T A iU*. i 2si 1 -?4 i

1 11 1

{:{ COMPOUND

g »mma-BHC ( Lindane ) ___HeptachlorAldrin

t DieldrinI Endrini 4,4'-DDTii

SPIKEADDED(ug/Kg)

SEKS3»atat3KK

5.785.785.7814.514.514.5

MSDCONCENTRATION

(ug/Kg)SBXEa^SCKESKaraB

7.6810.11.715.544.756.8O

MSD'/.

REC *s»ssa

133 *175 *30 #3833 *47

'/.RPD #

azaaeixats

-1773

-38010

•

QC L]RPD

503143384550

iEMITS {

REC. '».*» A46-12.135-13034-13231-13442-13923-134

# Column to be used to flag recovery and RPD values with an asterisk

* Values outgide of QC limits

RPD: _0 out of _^ outside limitsSpike Recovery: _B out of _12. outside limits

COMMENTS:

FORM III PEST-2 :- 3/87 Rev

£00050

fl-R-1'01583 -


Lab Names SWL-TULSA______________ Contract: URS _____

Lab Code: 3WQK Case No.: URS SAS No.: ______ SDG No.:

Matrix Spike - EPA Sample No.: BC-7-2_____ Level:<low/med) LOW

COMPOUND

aamma-BHC (Lindane)HeDtachlorAldrinDieldrinEndrin4.4'-DDT

-

SPIKEADDED(ug/Kg)

7.197.197. 1918.018.018.0

SAMPLECONCENTRATION

(ug/Kg)

O00O00

MSCONCENTRATION

(ug/Kg)

9.074.69A- m J-±

7.439.4213 . 4

MS7.REC #

1266531 *4152

. 74

QCLIMITSREC.

46-12735-13034-13231-13442-13923-134

~

COMPOUND

qamma-BHC ( Lindane )HeptachlorAldrinDieldrinEndrin4.4' -DOT

SPIKEADDED(ug/Kg )

7.197.197. 1918 1018.018. 0

MSDCONCENTRATION

(ug/Kg )

2.066.954 . 3713.916.620 . 7

MSD

REC 3

29 *97617792115

XRPD #

125 *-4O *-65 *-61 *-56 *-43

QC LRPD

503143384550

EMITSREC.

46-12735-13034-13231-13442-13923-134


* Values outside of QC limits

RPD: _5 out of _6 outside limitsSpike Recovery: _2 out of 12 outside limits

COMMENTS;

FORM III PEST-2 B/87 Rev.

0TQ0050S

IS AMERICAN AKALYTICAl fc TECHNICAL SERVICES

MAIRII SPIKE EVALUATION FORK

URS

S&HPLE ID BC-6-4HS

K£T HT. 10.0

atotmt «ount Mountng in spi. idderf detected Z TARGET

added ppt ppt ppt recovery recovery liiits2371 TCDF 2.5 0 250 285.3 114 iO - 140 IHPCDF 10 0 1000 t4ii.fr 144$ 40 - 140 1OCBF 25 0 2500 34B9.0 1481 40 - 140 I

2378 TCDD 2.5 0 250 379.9 1321 40 • 140 IPCDD 10 0 1000 1334.4 133 40 - 140 1HXCDS 10 0 1000 1424.5 142* 40 - 140 I


SAMPLE ID BC-4-4HS BC-4-4HSD

KT «T. 10.0 10.0

atount iiount RPDin spl. in spl.ppfc ppt

2378 TCDF 285.3 313.4 9.5HPCDF 1441.0 1099.0 28.3OCDF 3489.0 3415.0 2.0

2378 TCDD 379.9 287.7 27.4PCDD 1334.4 1144.0 13.5HICDQ 1424.5 1493.7 17.3

\ tl u I

ISO AMERICAN AHAUTIML 4 TECHNICAL SERVICESHATRU SPIKE EVALUATION FORM

URS

5AHPLE ID BC-4-4HSD

«ET *T. ' 10.0

iiount aiount uountnq in spl. added detected Z TfiRSET

added ppt ppt ppt recovery recovery 1nits237B TCDF :.5 0 250 313.4 125 60 - 140 XHPCDF 10 0 1000 1099.0 110 60 - 140 I(OF 25 0 2500 3415.0 1451 40 - 140 I

2378 TCDD 2.5 0 - 250 287.7 115 40 • 140 ZPCDD 10 0 1000 1144.0 117 40 - 140 ZH2CDD 10 0 1000 • 1493.7 i49t 40 - 140 Z

DUPLICATE SAHPLE EVALUATION

SAHPLE ID BC-4-4HS BC-4-4HSD

MET »T. 10.0 10.0

itount iiount RPDin spl. in spl.ppt ppt

2378 TCDF 285.3 313.4 9.5HPCDF 1441.0 1099.0 28.3QCDF 3489.0 3415.0 2.0

2373 TCDD 379.9 287.7 27.4PCDD 1334.4 1144.0 13.5HKCDD 1424.5. 1493.7 17.3

flR 101 5.8.6

MS AMERICAN ANALYTICAL I TECHNICAL SERVICES

HATJtII SPIKE EVALUATION FORK

URS

SAKPLE ID BC-7-2«S

MET XT. 10.0

KT. 10.0 10.0

iiount iicunt Mountn§ in spl. added detected Z TARGET

iddtd ppt ppt ppt recovery recovery liiits2371 TCDF 2.5 0 250 233.4 113 40 - 140 ZHPCDF 10 0 1000 1115.0 112 40 - 140 ZOCDF 25 0 2500 3129.0 125 40 • 140 Z

2378 TCDO 2.5 0 250 343.3 137 40 - 140 ZPCDD 10 0 1000 1155.8 114 40 - 140 ZHXCDQ ID 0 1000 1485.4 149t 40 - 140 Z


SAKPIE ID BC-7-2K3 BC-7-2RSB

atount uount RPDin spl. in spl.ppt ppt

2373 TCDF 283.4 312 9.5HPCDF 1115.0 1125.0 .9OC3F 3129.0 370B.O ' 14.9

2379 TCDD 343.3 341.3 5.1PCD0 1155.B 1190.8 3.0HXCDD 1495.4 1852.4 9.4

00031 iAR.LOLI.587

-SB .AMERICAN ANALYTICAL 4 TECHNICAL SERVICES

HATRIX SPIKE EVALUATION FORM

URS

SAHPLE ID BC-7-2HSD

WET NT. 10.0

iiount atount atountng in spl. idded detected Z TARGET

idfled ppt ppt ppt recovery recovery Huts2378 TCDF 2,5 0 250 312 125 40 - 140 ZHPCDF 10 0 1000 1125.0 • U3 40 - 140 ZOCDF 25 0 2500 3708.0 1481 40 - 140 Z

2378 TCDO 2.5 0 250 341.3 145t 40 - 140 ZPCDD !0 fr 1000 1190,8 119 40 - 140 ZHXCDO 10 0 1000 1852.4 ISSt 40 - 140 Z


SAHPLE ID 8C-7-2HS BC-7-2HSD

NET NT. 10.0 10.0

iiount atount RPIin spl. in spi.ppt ppt

2378 TCDF 283.4 312 9.5HPCDF 1U5.0 1125.0 .9QCDF 3129.0 3708.0 14.9

2378 TCDD 343.3 341.3 5.1PCDD 1155.8 1190.8 3.0H1CDO 1485.4 1852.4 9.4

U.S. EPA - CLPEPA SAMPLE

6 ::DUPLICATES

MU7S32DLab Name: SOUTHWEST LAB OF OK Contract: 68-D9-O039 _fiL'-il-l___.

Lab Code: 3WQK Case No.: 36761 SAS No.: 5DS No.: MU7801

Matrix (water/soil): SOIL Level (low/med): LOW

*/. Solids far Sample: 92.1 % Solids for Duplicate: 92.1


i) Analyte

! Aluminum! Antimony! Arseni c} BariumJ B©ryl 1 i umt Cadmium1 Calcium1 ChromiumJ CobaltI Copper! Iron! Lead! MagnesiumEMangangss! MercurySNickel; PotassiumJ Selenium! Si 1 v©ri SodiumI Thallium! VanadiumIZinc[Cyanideti

ControlLimit

2.2

•

1'O.S4.3

-

Sample (S) C!

4646. 4307! ,5.5901 !U!l . 2234 ! B !16.7191 IB!.4229JB!. 645O ! U !

156.3603IB!/ • 0000 * i3.5501 IB;3.4401 !U!

13728.9170! f3.6469! !

135- 9334! 91177.9587! !

. 1150JU!4. 3087! Bi

217.9754JB!. 430O ! U 1.9391 !B!

137.0512JB!. 6450 ! U I

12. 4945 J !10.1195! i1 .98S61U!

iDuplicate <D> C!

4363.8708! !12.8291 IB!1.6178JB!14.9548JB!. 4689 { B !.6515IU!

109.4148!B!13.6247! !5.7253IB!4.9418JB!

18229.4650! i4. 2150 f I

1 19. 8473! B!243.76O5J !

. 1085 !U!5. 1274 !B!

165.7213IBJ. 4799 ! B J

1.2397IB!94. 3032! B!.6515!U!

14.9479: !12.6690! !1 . 7289 ! U !

6.3200 . 027.811.11O.3

T^ T

53.446.9

200. 028.214.512.6-"^1.2

i. 427. 2

200. 027. 637.0

17.922.4

•

1

0!«!PI o( ~

!F!PIP!P!P j

*!P i!P;p

*!P!FiP

*!P!CV;P;P1 i ~!PIPIFfPIP:c

FORM VI - IN7/SS

.,,,,,_ 8-00051nR i u i 088

U.

5A EFASPIKE SAMPLE RECOVERY

! MU73Lab Nams: SOUTHWEST LAB OF OK' Contract: 68-D9-0089 \ fiC-W-

Lab Code: SWOK Case No.: 367S1 SAS No.: SDG No.: r-;U73<.-l

Matrix-: SOIL " .. ^ "~ _ Level flow/med > : ":_3W

% Solids tor Samolez" 91.5

Concentration Units (ug/L or mg/kg dry weight): MS/KC3

! Analyte

! Al umi HLim1 Antimony; Arsenic: Ban U.T;-: Beryl 1 ium! Cadmium; Cal ci um! Chromi um! Cobalti Capper< Iron.' Lsad! Magnesium! Manganese' Msrcurv! Nickeli Potassiumi Seleniumi Si 1 ver: SodiumI Thai 1 1 um: Vanadi umi 2 i n c •! Cyani ciei

ControlLimit7.R

75-12575-125~7ef— 1 •"!"=;/ j i -—•-./75-12575-125

75-12575-12575-125

75-125

75-12575-125

75-12375-125".

75-12575-12575-12575-125

So iked SampleResult CSSR)

79.33316. 9727

497.715812.O99015.8869

55.2387127. 110665.7576

Q T' TTt?

579.8893. 084O

123.7382

1 . 25258.9202

1 1 . 9257128.6896126.319320.8341

C

U

~~

Samp 1 eResult (SR) C

;12. 4853 IB1 . 3727 ! B

23. 4055 iB.3941 IE. 6557 i U

•6.6758!6. 9369 IB3.4973JU

!o * - 1 Q V *

t487.5951 i

. 0993 \ U4. 7480 IB__.... ._. i.4372 ! U

1. 1603 IB— - . ,

. 6557 I U11. 1026!9.6251 I2.0239IU

I

Spike :Added <SA) !

1 i109., 298.74

437., it10.9310. 93

• 43.72109 ,,2954.64

4 37

109. 291 , OO

1 09 „ 29

2. 191 0 ., 93

1 0 „ 93109- 291 09 „ 2921,. 60

1 1 •

:'.R • Q : M :

I INR!5 i . 6 . N ! P :s4. : :M;F j-.03.5; ,P ;;07. 1 . IP I145. 4:N!P !

. ; NR :111.2! IP !i i 0 . o : IP !120. 7 ' .: P !

. I NR !i 1J-. 3 IF !

. I NR !>O. *5 I IP I0. 'JiNlCV!

Iv8. "' IP !INR!

57. C NIF J71 .». M:P ;

. I NR I1 'I 9 . 1 - : F . !I 07. ,T. !P iJLV6.3 P i56.'.;; :c Ii• i

Ji• '

Lommenrs:


0-00051.1ARi01590

U.S. EPA - CLPEPA SAMPLE N

6 ____ „__* DUPLICATES

MU7S33DLab Name: SOUTHWEST LAB OF OK Contract: 68-D9-OO89 _C£i&T.iL___.

Lab Code: 5WOK Case No.: 36781 SAS No.: " SDG No.: MU78O1


7. Solids -for Sample: 91.5 */. Solids for Duplica-e: 91.5

Concentration Units Cug/L or mg/kg dry weight): MG/KBiI Analytei*i Aluminum[Antimony1 ArsenicI Barium! Beryl 1 ium! CadmiumI Calcium! ChromiumI CobaltI Capper! IronILead1 MagnesiumI ManganeseI têrcuryINickelI Potaseiumf Sal gniumI Si 1 ver! SodiumJ Thall ium! VanadiumIZincI Cyanidei

ControlLimit

2. 2

.7

•

10.94.4

11Sample (S) CI

!4346.6061! !

12. 4853! E!1 . 3727 I B !

23. 4055 JB!.3941 IB!. 6557 ! U i

100. 0753 IB!6. 6758 J I6. 9369! B!3. 4973! U!

14542.368O! !3.2109! I

187.9976iBI437.59511 !

. O993 I U I4-748OJB;

267. 3667 IB I. 4372 ! U !

1. 1603! B I94.2277EB!

. 6557 I U I11. 1026! I9.6251! !T> «*\*?T1Q Ml1-i. Vjiwv » U »

i it i

ii

Duplicate "£D> C!i

3745.9021 : !12.49321BIl.O9~29!U!

21. 8287 IB!. 3987 ! B I. 6557 I U I

99.3719IB!7.1878! 16.O304IB!3.7858IBI

13133.4110! I2.7060! !

179.5024IBI419. 15561 i

. O993 I U !3.3285131

248. 3855 IB!. 43721 U I

1. 1126 IB!8O.2186IU!

. 6557 I U I10. 30051 E I9.1568! I2.0543IU!

< t

XRPD

14. S. 1

20O.O7,01.2

_. 77.414.0200.010.217. 14.615. 1~r,~\ "35.27.5

4 r>2OO . 0

7.55.0

I Ii r

QittiiIPIP!FIPIP-IPIPIPIPIPIPIFIPIPicv!P!P.IFIPIPIF!PIP1Cii

FORM VI - IN7/88

U.S. "EPA - CLP

5A EPA SAMSPIKE SAMPLE RECOVERY

- . --- --- - - I - MU7S25SLab Name: SOUTHWEST LAB OF OK Contract: 63-D9-0089 I

Lab Code: SWOK Case No.: 36781 SAS No.: SDG NO.: MU7801

Matrix: SOIL - .. Level (lcw/msd> : LOW

'•i Sol ids -for Sampl e: 75.6 :

Concentration Units tug/L cr mg/kg dry weight): MG/KS

111t

! Anal yteiii Al uminumI Anti manyI Arsenici Bari urn! Beryl 1 ium! Cadmium! Cal ci um! Chromi um

kl Cobaltml Copper\\ Irony I Lead! Magnesium1 ManganeseI MercuryINickel; Potassium\ SeleniumI Silver! Sodi um! Thai lium! Vanadium; ZYhcI Cyani de• _

ControlLimity.R _

75-12575-12575-12575-12575-125

75-12575-12575-125

75-125

75-12575-12575-125

75-12575-125

75-12575-12575-12575-125

3pi ked SampleResult <SSR>

43.81347.9601

646.335615.161013. 1264

76.37.21151.82248 1 . 6300

18.9193

485. 1221. 1017

168.9687

.523911.2276

14.3852184.719O165. 596626.3896

C

U

U

Samp 1 eResult (SR) C

i•16.O99B!i . 322S ! U87.4473;

,9122 IB. 7937 i U

i19.4224!S . 6730 ! B7.4502!

ii15.50261

t315. 1506;

. 1150IU20.07161

i.5291 iU

i . 5722 ; Bi

. 7937 I U37.5476; _O1™^ TT^T * I^ *i. . •_'•_' •_> i i2. 3963 I U

i

So i keAdded <SA)

130. 9710.48

tJ-£C- . OC5

13. 10i T ^ t~\i •-» . - V

52.39130.9765.43

5.24•130.97

1.00130.97

2.6213. 10

13. 10130.97130.9725. 15

7.R

:? 1 •"?7 is . 0

1 06 . 7108.8138. 4

1 08 . 7109.3113.4

65.2

129.30 . 0

113.7

0 . 073, 7

. 109. G112.4109.41 04 . 9

I1

Q!MiiINR

N ! Pr- cr; PI P

NIPINRIPI F'IPINR

NIF!NR

NIFNICV;pINR

NIFN I P

; NR; p

IPp

f c ;1 . .

Commentsj

FORM V (Fart 1 ? -^ IN

ARID,592

U.S. EPA - CLPEPA SAMPLE N

6, DUPLICATES !

i MU7E25DLab Names SOUTHWEST LAB OF OK Contract: 68-D9-OOS9 I 6t->2,

Lab Code: 3WOK Came No.: 36781 SAS No.: SDG Nc.: MU7SO1

Matrix (water/soil): SOIL Level Clow/med): LOW

7. Solids -for Samole: 75.6 7. Solids for Duplicate: 75.6

Concentration Units £ug/L or mg/kg dry weight): MG/KG

J

! ! Control! Analyte ! Limiti *i i1 Aluminum I; Antimony I 15.9I Arsenic i(Barium ! 52.9I Beryl lium! 1.31 Cadmium !I Calcium II Chromium J.'Cobalt ! 13.2! Copper I 6.6ilron I! Lead I! Magnesium!I Manganese I.Mercury :INickel I 10.6; Potassium II Sel en ium :! Si 1 ver'.Sodium iI Thai lium !! Vanadium 1 13.2JZinc ! 5.3! Cyan id© !' I< *

Sampl© (S) C

25121.3620!16.0998!1 . 3228 ! U87.4473!

-9122SB. 7937 ! U

400. 4679 !B19.4224!8. 6730 IB7.4502!

20344. 1900!15.5026!

671. 7352 IB315. 1506!

. 1150IU20.0716!468. 6218 IB

.5291 IU1 . 5722 ! B

227. 1672 IB. 7937 I U

37.5476!22.3331J2. 3963 I U

i

Duplicate (D> C

31856.3160!18.5799!2.36771997.2592!1 . 3274 I1.2191IB

463. 1079 !B26.3699!13.4489!10.6197!

31775.5910:14.8545!

317. 4666 IB451.673S!

. 1017IU3G.2025!515.0419IE

.5291 IU2.4201 IB

157.7153IB. 7937 ! U

56.6599!31.6140!2. 5052 I U

ir

•/.RPD

23.614.3

20O. 010.637. 1200.014.530.343.235. 143.94. 319.635. <b12.240 . 39.4

42.536. 1

40. 634.4

1 11

QIMi

*!P;PIFIFIPIP!P

*!PIPIP

*!PIFIP

# ! PICVf P! P'IF!PIPiF

*!P*!P1C(

FORM VI - IN7/as

0-000517A R I OT5W ~ ~ ~"

U.S. EPA - CLPEPA SAMPLE NO.

6 _______DUPLICATES ! " ~!

! MU7326D ;Lab Name: SOUTHWEST LAB OF OK . Contract: 63-D9-0089 ! .JL -Jtl____:

i_ab Code: SWOK Case No.: 36761 SAS No.: 5-DG No.: MU7S01

Matrix- (water/soi 1 ; : SOIL Level (low/med) : LOW

'/ Solids -for Sample: 79.B 7. Solids tor Duplicate: 79.6

Concentration Units (ug/L cr mg/kg dry weight): MG/KG

11

! Analyte

: Al umi numi Antimony! ArsenicI BariumI Beryl 1 ium! Cadmiumi CalciumI Chromiumi CobaltI CopperI IronI LeadI Magnesi um! ManganeseI MercuryI Nickel! PotassiumI SeleniumI Si 1 veri Sod i umI Th a i 1 i um! Vanadium! Zinc! Cyan! deii

ControlLi mi t

14". 9

49.6

6.2

"

9.9

12.45.0

Sample <S) C

20O1 9 . 240O !' 22. 3234 i

1 . 2407 ! U78.8315:. 7320 ! B. 7444 ! U

382. 1595!B25.9492!9.0070137.8232!

26644.6380!12.0O44!

953. 01 00 IB228.56521

. 10891019.9041 I

523.3804! B4.9629IU2.055913

166.7619IB.7444 I U

35.3649!24.4604!2.4O06IU

>

Duplicate (D) C

: 23014- 5900!20. 9739!2.4417!B66.3145!

. 9493 I B

. 7444 I U415. 2675 IB21.8126!12. 1154 IB7.79O3!

30717.7240!13.0946!

798. 4257 IB400.960O!

. 0963 I U14.0933!

569. 4953 !B. 4963 ! U

2.30OOIB152.6615SB

. 7444 ! U33.7432!26. 1872!2. 1606 iU

!

•/.RPD13.9a. 4

200 . o.17.225.8

83• •— '17.329.4. 4

14.28.717.754.846.234. 23 . 3

11.2a. (39. 16. 3

r

!Q

!i!!!i!I!iiiiii

!*!!1iiiir

it

i!I

M

PPFPPPPPPpPFPPCVPPFPF'crPPr*

FORM VI - IN7/88

£-000513

U.S. EPA - CLP


Lab Name: SOUTHWEST LAB OF OK Contract: 68-09-0089

Lab Coae: SWOK Case No.: 367E1 5AS Ho.: = DG Mo

Soli a LCS Source: EPAO237

Aqueous uCS Source:

1

Anai viz©

AluminumAnri.TionvArmsnicBariumBervi liumCadmium

1 Calcium•J Chromi um^/CobaltJCoopsrI Iron!Le*dJ MagnesiumJ Manganesei MercurvlNick»l! PotassiumI SeleniumS SilverI Sod iumI Thai 1 iumI Vanadiumi ZincI Cyanidei

Aqueous (ug/L)True Found "CR

t.

!

~

Solid (mg/kg >True Found C Limits */.R

325.0! 270.3!211.0! 207.7!917.0! 659.2!

4R * î "? f R. O ' *J. •— • I O

19.4! 19.2! .45.4! 48.2!

196200.01 197950.0!99.6! 103. 1!144.0! 137.3!6910.0! 7138. O!22430.01 19675.5!

236. Oi 240.7!118100.0! 12241O.O!

208.0! 211.7!12.71 12.5!60.9! 50. B!50. 0! 69.0 JUTO *? ' - T7 jL t•_> v . *i. i •_• / . C i

22.2! 20. 6 i50.0; ' 73. 4! U39.0! 29.6!65.8! 64.7!

187. 0! 151.0!5.61 5.71

i •

225 . 0127.0635 . 00. 0

16.535.7

166800.079.2

124.06OO6. 017770.0

188. 01.0O4OO . 0

177.03.5

49.20. 019. 115.50 . 0

24.651.7

1 33 . 04.3

424. ! : 83.2r94.v! 93.41199.0. 71.940. O: i 10.422.71 99.053. 1 ; 106.2

22560O.O! 100.9120.01 IQT^

16- v: 7aro. v ic H27030.-.'! So2S5.O: 102.0

1Z9900. :•: 103.639. :-: 101.5:7. :-; 93.472. h. F53.4

' ''.'OO. '"' ' 0* C59.*. '"5.9Z9.OI ?2.8

iooo. . . o.o-* 'j- . -re- a_l^._.- / _J • 7

"o. 9 ; 98. 3Zo. .•: SO. 7o . ° : 1 0 1 . S

FORM VII - IN 7/es

flRIO!595

U.S. EPA .- CLP


Lab Name: SOUTHWEST LAB OF OK Contract: S8-D9-OOS9

Lab Code: 5WOK .___. Case No.: 367S1 3AS No.: SDG No.: MU7301

Solid LCS Source: EPA02S7

Aqueous LCS Source:

1

i AnalytetJ Aluminum! AntimonvI Arseni c! Bari umI Beryl 1 ium! Cadmium! Calcium

V ChromiumJ Cobalt

! Copper! IronI Lead! MagnesiumI Manganese! Mercury! NickelI Potassium! Seleni um! Si 1 ver! Sodium! Thai! ium! Vanadi umiZincICyani dei

Aqueous Cug/L)True Found XR

'

Solid (mg/kg)True Found C Limits 7.R

5.6 5.9

:

4.3 =>.9 105.4

FORM VII - IN7/BS

#0005 0

t nP. ID1594>

SOUTHWEST LABORATORY OF OKLAHOMA, INC.7700 W. Albanv . Suitf "C" . Broken Arrow. Oklahoma 74012 . 918-251-2858 . FAX: 918-251-2599

ANALYTICAL REPORT

URS CONSULTANTS, INC. REPORT: 3678-1570 Delaware AvenueBuffalo, New York 14202

REPORT DATE: 10/05/90

SAMPLE NO.: 3678.01 - 3678.39DATE RECEIVED: 09/08/90

fl&ZQC

DESCRIPTION PARAMETER RESULTS

MATRIX SPIKE BC-7-2 ' TOTAL SULFIDE ' 44% RECOVERYMATRIX SPIKE BC-6-4 TOTAL SULFIDE 43% RECOVERSMATRIX SPIKE BC-6-1 TOTAL SULFIDE 64% RECOVERY

DUPLICATE BC-6-4 TOTAL SULFIDE 5.2% RPDDUPLICATE BC-6-4 TOTAL SULFIDE 31% RPDDUPLICATE BC-6-1 TOTAL SULFIDE 9.6% RPD

A R I O I 5 9 7 frT)C052i

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700W.Albanv . Suite "C" . Broken Arrow, Oklahoma 74012 , 918-251-2858 , FAX: 918-251-2599

ANALXT1CAL..PEPQET

"RS CONSULTANTS, INC." REPORT; .3677-1570 Delaware AvenueBuffalo, New York 14202


SAMPLE NO.: 3677.01-- 3677.04DATE RECEIVED: 09/08/90

QA/QC

OKCRIEXIQH PARAMETER RESULTS

TCLP BLANK 09/13/90 ARSENIC -:0.05 mg/LTCLP BLANK 09/13/90 BARIUM <0 .02 mg/LTCLP BLANK 09/13/90 CADMIUM <0.005 mg/LTCLP BLANK 09/13/90 CHROMIUM <0 . 005 mg/LTCLP BLANK 09/13/90 ' LEAD <0.05 mg/LTCLF BLANK 09/13/90 MERCURY <0.0002 mg/LTCLP BLANK 09/13/90 SILVER <0.01 mg/LTCLP BLANK 09/13/90- SELENIUM : <0-05 mg/L .

BLANK SPIKE - 09/16/90 MERCURY _ . 106% RECOVERY

MATRIX SPIKE DC-1 REACTIVE SULFIDE 117% RECOVERYMATRIX SPIKE DC-1 REACTIVE CYANIDE 0% RECOVERY

0-DC05f l R i n i 5 9 8

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700 W. Albany . Suite "C . Broken Arrow, Oklahoma 74012 . 918-251-2858

CLIENT: URS CONSULTANTS, INC. REPORT: 3677*570 DELAWARE AVENUEBUFFALO, NY 14202 DATE: 10-02-90ATTNs PETER FAIRBANKS

SAMPLE MATRIX! E.P. TOX EXTRACTION FLUIDSWLQ * E.P. TOX METHOD BLANKDATE EXTRACTEDJ 09-12-90DATE ANALYZED! 09-16-90METHOD REFERENCES SWB46-8150, EPA METHODOLOGYSAMPLE IDs E.P. TQX BLANK

RESULTS REPORTED IN mg/1 OR Parts Per Million

E.P. TOX DET.HERBICIDES___________LIMIT___________RESULTS

2,4-D 1.0 ND2,4,5-TP (SILVEX) 0.1 . ND

QA/QC SURROGATE RECOVERY

2,4,5-T 741/.

ND « NOT DETECTED ABOVE QUANTITATION LIMITJ » ESTIMATED VALUEl CONCENTRATION BELOW LIMIT OF QUANTITATIQNB m ANALYTE DETECTED IN BLANK AS WELL AS SAMPLE* - SURROGATE RECOVERY OUTSIDE OF QC LIMITS

A R I O I 5 9 9 0-00052J


CLIENT: URS CONSULTANTS, INC. " REPORT s 3677b570 DELAWARE AVENUEBUFFALO, NY 14202 DATE: 10-02-90ATTN: PETER FAIRBANKS

SAMPLE MATRIX: WATER .SWLO * METHOD BLANKDATE EXTRACTED: 09-12-90DATE ANALYZED: 09-16-90METHOD REFERENCE: SW846-8150, EPA METHODOLOGYSAMPLE ID: METHOD BLANK

RESULTS REPORTED IN mg/1 OR Parts Per Million

E.P. TOX DET.HERBICIDES___________LIMIT _________RESULTS

294-D 1.0 ND2,4,5-TP (SILVEX) 0.1 ND


2,4,5-T 797.

ND « NOT DETECTED ABOVE DUANTITATION LIMITJ = ESTIMATED VALUE: CONCENTRATION BELOW LIMIT OF QUANTITATIONB « ANALYTE DETECTED IN BLANK AS WELL AS SAMPLE* = SURROGATE RECOVERY OUTSIDE OF QC LIMITS

f l R I O l S O O#000521


CLIENT: URS CONSULTANTS, INC. REPORT: 3677c

DATE: 10-03-90

SAMPLE MATRIX: SOIL, E-P. TOX EXTRACTIONSWLO # 3677.02/3677.03 (MS/MSD)DATE EXTRACTED! 09-12-90DATE ANALYZEDs 09-16-90PROJECT: DELAWARE SAND & SRAVELSAMPLE IDi DC-1 (MS/MSD)

HERBICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS

MSSPIKE ADDED AMT. FOUND AMT. FOUND PERCENT

(ug/1) SMP. (ug/1) MS (ug/1) RECOVERY

2,4-D 97 0 68 70'/.2,4,5-TP (SILVEX) 25 0 20 SI'/.

MSDAMT. FOUND PERCENT RECOVERY PERCENTMSD (ug/1 ) RECOVERY DIFFERENCE

2, 4-D 6B.5 71% 0.6%2,4.,5-TP (SILVEX) 17.8 71"/. 12. 5"/.

AR I 01601 #'000520

SOUTHWEST LABORATORY OF OKLAHOMA, INC1700 W. Albany . Suite "C" . Broken Arrow, Oklahoma 74012 . 918-251-2858

CLIENT: URS CONSULTANTS, INC. REPORT: 3677d570 DELAWARE AVENUEBUFFALO, NY 14202 DATE: 10-03-90ATTN: PETER FAIRBANKS

SAMPLE MATRIXs E.P. TOX EXTRACTION FLUIDSWLO # E.P. TQX BLANKDATE EXTRACTED? 09-12-90DATE ANALYZED : 09-17-90PROJECT: DELAWARE SAND & GRAVELMETHOD REFERENCES SW846-8080., EPA METHODOLOGYSAMPLE ID: E.P. TOX BLANK

RESULTS REPORTED IN mg/L OR Parts Per Million (PPM)

PESTICIDES/PCB'S DETECTION LIMIT ; RESULTS

GAMMA-BHC 0.040 NDHEPTACHLOR 0.0008 NDENDRIN 0.002 NDHEPTACHLOR EPOXIDE 0.0008 NDTECH CHLORDANE ' O.OO3 NDMETHOXYCHLOR 1.0 NDTOXAPHENE 0.050 ND

QA/QC SURROGATE RECOVERIES

DIBUTYLCHLORENDATE ( 24-154) 857.

ND « NOT DETECTED ABOVE QUANTITATION LIMITJ « ESTIMATED VALUE: CONCENTRATION BELOW LIMIT OF QUANTITATIONB « ANALYTE DETECTED IN BLANK AS WELL AS SAMPLE* « SURROGATE RECOVERY OUTSIDE OF QC LIMITS


CLIENT: URS CONSULTANTS, INC. ' REPORT: 3677©570 DELAWARE AVENUEBUFFALO, NY 14202 DATE: 10-03-90ATTN: PETER FAIRBANKS

SAMPLE MATRIX: WATERSWLO # METHOD BLANKDATE EXTRACTED: 09-12-90DATE ANALYZED J 09-17-90PROJECT: DELAWARE SAND «t GRAVELMETHOD REFERENCES SW846-8080, EPA METHODOLOGYSAMPLE ID: METHOD BLANK

RESULTS REPORTED IN mg/L OR Parts P«r Million (PPM)

PESTICIDES/PCB'S DETECTION LIMIT RESULTS

GAMMA-BHC 0.040 NDHEPTACHLOR 0.0008 NDENDRIN 0.002 NDHEPTACHLOR EPOXIDE 0.0008 NDTECH CHLORDANE 0.003 NDMETHOXYCHLOR 1.0 NDTOXAPHENE 0.050 ND


DIBUTYLCHLORENDATE (24-154) 66'/.

ND - NOT DETECTED ABOVE QUANTITATION LIMITJ - ESTIMATED VALUE: CONCENTRATION BELOW LIMIT OF QUANTITATIONB - ANALYTE DETECTED IN BLANK AS WELL AS SAMPLE* - SURROGATE RECOVERY OUTSIDE OF QC LIMITS

ARIUTBUT #"000527


CLIENT: URS CONSULTANTS, INC. REPORT: 3677f570 DELAWARE AVENUEBUFFALO, NY 14202 DATE: 10-03-90ATTN: PETER FAIRBANKS

SAMPLE MATRIX: SOIL, E.P. TOX EXTRACTIONSWLO # 3677.02/3677.03 (MS/MSD)DATE EXTRACTED: 09-08-90DATE ANALYZED: 09-17-90PROJECT: DELAWARE SAND & GRAVELSAMPLE IDs DC-1 (MS/MSD)

PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS

MSSPIKE ADDED AMT. FOUND (SAMPLE) AMT. FOUND (MS) PERCENT(ug/L) (ug/L) (ug/L) RECOVERY

GAMMA-BHC 1.00 0 0.60 607.HEPTACHLOR i. 00 0 0.66 667.ALDRIN 1.00 0 0.66 66'/.DIELDRIN 2.50 0 1,47 597.ENDRIN 2.50 0 1.70 717.4,4'-DDT 2.50 0 1.69 687.

MSD RELATIVEAMT. FOUND (MSD) PERCENT PERCENT

(ug/L) RECOVERY DIFFERENCE

GAMMA-BHC . 63 637. 4«97.HEPTACHLOR .72 727. 8.7%ALDRIN .70 707. 5,97.DIELDRIN 1.56 627. 5,97.ENDRIN 1.83 737. 2,87.4,4'-DOT 1.88 757. 10.67.

f l R I O I G O U . . /H>005:


CLIENT: URS CONSULTANTS, INC. , REPORT: 3676c570 DELAWARE AVENUE .BUFFALO, NEW YORK 14202 DATES 09-19-90ATTNi PETER FAIRBANKS

SAMPLE MATRIX: WATERStfLO * METHOD BLANKDATE ANALYZED i 09-12-90METHOD REFERENCES SW846-S240, EPA METHODOLOGYSAMPLE ID: METHOD BLANK

RESULTS REPORTED IN ug/L OR Parti P«r Billion (PPB)

TOLP DET.VOLATILEi LIMIT RESULTS

BENZENE 5 NDCARBON TETRA CHLORIDE 5 NDCHLOROBEMZENE 5 NDCHLOROFORM 5 ND1,2-DICHLOROETHANE 5 ND:fl-DICHLOROETHESE 5 NDTETRACHLOROETHENE 5 KIDTRICHLOROETHENE 5 NDVINYL CHLORIDE 10 NDhETHYL ETHYL KETONE 10 ND

OA/QC SURROGATE RECOVERIES

TOLUENE-d9(S8-110) 965: BROMOFLUOROBENZENE(86-115) 98« l,2-DICHLOROETHANE-d4(76-H4) 94*

NOT DETECTED ABOVE QUANTITATION LIMITESTIMATED VALUEl CONCENTRATION BELOW LIMIT OF QUANTITATIONANALYTE DETECTED IN BLANK AS WELL AS SAMPLESURROGATE RECOVERY OUTSIDE OF QC LIMITS

A R I O I 6 0 5

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700 W. Albany . Saute "C" . Broken Arrow, Oklahoma 74012 . 918-251-2&58

.***

CLIENTS URS CONSULTANTS, INC. . REPORTi 3676d570 DELAWARE AVENUEBUFFALO, NEW YORK 14202 DATEs 09-19-90ATTNi PETER FAIRBANKS

SAMPLE MATRIX s WATERSWLO » METHOD BLANKDATE EXTRACTED* 09-11-90DATE ANALYZED I 09-18-90SAMPLE IDs METHOD BLANK

DET. METHODPARAMETER ______________ LIMIT UMIT _____ RESULTS REFERENCE

TCLP SEHI-VOLATILES

0-CRESOL . 10 ug/L ND SW 8270M-CRESOL 10 ug/L ND SW 8270P-CRESOL 10 ug/L ND SW 8270TOTAL CRESOL'S** 10 ug/L ND SW 82701,4-DICHLORQBENZENE 10 ug/L ND SW 82702,4-DINITROTOLUENE 10 ug/L ND 8W 8270HEXACHLOROBENZENE 10 ug/L ND 8W 8270NITROBENZENE 10 ug/L ND SW 8270PENTACHLQROPHENOL 10 ug/L ND SW 82702,4,5-TRICHLOROPHENQL 10 ug/L ND " SW 827<>2,4,6-TRICHLORPHENOL 10 ug/L ND SW 8270HEXACHLOROBUTADIENE 10 ug/L ND SW 8270HEXACHLORDETHANE 10 ug/L ND SW 8270PYRIDINE 10 ug/L ND SW 8270

OA/QC SURROGATE RECOVERIES

NITROBEMZENE-d5(33-114) 48* 2-FLUQROBIPHENYL(43-116) 54* TERPHENYL-d:i4 (33-141) 58'PHENOL-d5 (10-94) 36fc 2-FLUOROPHENOL (21-100) 42« 2,4, 6-TRIBR(3MQPHENOL< 10-123) 52'

D = SURROGATES DILUTED OUT** = COMBINATIONS OF 0, M, AND P CRESOLSND = NOT DETECTED ABOVE QUANTITATIQN LIMITJ » ESTIMATED VALUEi CONCENTRATION BELOW LIMIT OF QUANTITATIONB s ANAtYTE DETECTED IN BLANK AS WELL AS SAMPLE« - SURROGATE RECOVERY OUTSIDE OF QC LIMITSSW = EPA METHODOLOGY HKSW846% THIRD EDITION

A R i O ! 6 0 6


CLIENT: URS CONSULTANTS, INC. REPORT: 3676b570 DELAWARE AVENUEBUFFALO, NEW YORK 14202 DATE: 09-19-90ATTNi PETER FAIRBANKS

SAMPLE MATRIX: WATERSWLO # METHOD BLANKDATE EXTRACTED: 09-11-90DATE ANALYZED s 09-13-90METHOD REFERENCES SW846-80BO. EPA METHDDOL08YSAMPLE IDi METHOD BLANK

RESULTS REPORTED IN ug/L OR Part* P.r Billion (PPB)

PESTICIDES/PCB'S DETECTION LIMIT RESULTS

BAMMA-BHC 0.04O NI?HEPTACHLOR 0.OOOS NDENDRIN 0.001 NDHEPTACHLOR EPOXIDE O.OOOS NDTECH CHLORDANE 0.003 NDMETHOXYCHLOR . 1.0 NDTOXAPHENE O.050 ND


DIBUTYLCHLORENDATE < 24-154) 79'/.

I * SURROGATE NOT QUANTITATIBLE DUE TO MATRIX INTERFERENCEND » NOT DETECTED ABOVE QUANTITATION LIMITJ - ESTIMATED VALUE: CONCENTRATION BELOW LIMIT OF QUANTITATIONB - ANALYTE DETECTED IN BLANK AS WELL AS SAMPLE* » SURROGATE RECOVERY OUTSIDE OF QC LIMITS

#00053

M/0/607

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700 W, Albany . Suite "C" . Broken Arrow, Oklahoma 74012 . 918-251-2858

CLIENT: URS CONSULTANTS. INC. REPORT: 3676*570 DELAWARE AVENUEBUFFALO, NEW YORK 14202 DATE: 09-19-90ATTNi PETER FAIRBANKS

SAMPLE MATRIX: WATERSWLO # METHOD BLANKDATE EXTRACTED: 09-11-9ODATE ANALYZED: 09-13-90METHOD REFERENCE: SWB46-S150, EPA METHODOLOGYSAMPLE ID: METHOD BLANK

RESULTS REPORTED IN mg/L OR Parts Per Million

TCLP DET.HERBICIDES____________LIMIT____________RESULTS

2,4-D 1.0 ND2f4,5-TP (SILVEX) 0.1 ND


2,4,5-T 697.

ND - NOT DETECTED ABOVE QUANTITATION LIMITJ » ESTIMATED VALUE: CONCENTRATION BELOW LIMIT OF QUANTITATIONB = ANALYTE DETECTED IN BLANK AS WELL AS SAMPLE» = SURROSATE RECOVERY OUTSIDE OF QC LIMITSI = NOT QUANTITATIVE DUE TO MATRIX INTERFERENCE

6-000332

f l R I O I 6 0 8


ANALYTICAL REPORT

URS CONSULTANTS, INC. REPORT: 3S7S-1570 Delaware Avenu©Buffalo, New York 14202


SWLQ IDENTIFICATION

SAMPLE NO.: 3676.01DATE RECEIVED: 09/08/90

QA/QC

DESCRIPTION PARAMETER RESULTS

METHOD BLANK 09/13/90 " ARSENIC <0.0"5 mg/LMETHOD BLANK O9/19/90 BARIUM <0.02 mg/LMETHOD BLANK 09/19/90 CADMIUM <0.005 mg/LMETHOD BLANK 09/19/90 CHROMIUM <O.OOS mg/LMETHOD BLANK 09/19/9O LEAD <O.05 mg/LMETHOD BLANK 09/19/90 MERCURY <0.0002 mg/LMETHOD BLANK 09/19/90 SELENIUM <0.05 mg/LMETHOD BLANK 09/19/90 SILVER <0.01 mg/L

#1)00333

A R I O J 6 0 9

SOIL VOLATILE LABORATORYCONTROL SPIKE RECOVERY

In*. ID:

client Code: _JLLE=L__ Episode #:Matrix Spikc-LCS No.: J?2dl li___. Level (low/med):

COMPOUND

1,1-DichloroetheneTrichlorocthcncBenzeneTolueneChlorobenzene

SPIKEADDED(ug/Kg)

H?

V

•

//

MSCONCENTRATION

(«g/Kg)

'M«51«5D5B61

MS%

REC*3fe

{02t 001(30IOA

QCLIMITSREC.

59-17262-13766-14259-13960-133

#CoIumn to be used to flag recovery and RPD values with an asterisk

•Values outside of QC limits

Spike Recovery! 0 mit of 6_____outside limits

Comments:

A R I O I 6 I O 0nj0053'i


lost. ID:

Tah Matnf ___________ Ol r rinA* Fpiwlr *•

Matrix Spike- LCS No.:_2Illii£L!____ Lcrel Oow/meeD:

COMPOUND

1 , 1-DichlorocthcneTrichloroetheneBenzeneTolueneChlorobenzene

SPIKEADDED(ug/Kg)

W

i,

r

//

MSCONCENTRATION

(ug/Kg)

4fciw<5DLta

£ b

MS%

REC*

3k3$loow(00

QCLIMITSREC.

59-17262-13766-14259-13960-133

#Column to be used to flag recovery and RPD values with an asterisk


Spike Recovery:____ out of _2______outside limits

Comments:

f l R I O I G


last, ID:-

/ i C ^ . c? TztteLab Name:_________________ m^r rviH ( A. rv > Ffrfgnrfg »• JJ •=» / —

f"— / w c c : - -Spike-rrs M<V- - ~ " — Level Oow/mccD:

COMPOUND

IJ-DichloroctfacncTrichloroetheneBenzeneTolueneChlorobcnzene

SPIKEADDED(ug/Kg)

^ f^—.

\V

MSCONCENTRATION

(us/Kg)

A3-//*<?w5H-

MS%

REC#

l<5^^c<:\%'S}OS

QCUMTTSREC

59-17262-13766-14259-13960-133

#Column to be used to flag recovery and RPD values with an asterisk


Spike Recovery:____ out of >___outside limits

Comments:

$-000530AR1Q1G12._______

50IL VOLATILE riATRIx -=pn -E/nATRI X SPIKE DUPLICATE RECOVERY

l_aD Name: SUJL - TULSA ____________ Contract: URS ____ '

Coae: SldQK Case No.: URS 3 AS No.: ______ . SDG No.:

Matrix Spike - .EPA Sample No.: TBC-i _______ Level : < low/med ) MED

COMPOUND '

1 . 1-DichloroetheneTrichloroetheneBgnreneTolueneChlorooenrene

—

l- -SPIKEADDED(ug/Kg)

79107910791079107910 .

SAMPLECONCENTRATION

(ug/Kg)

000

SI 60706

MSCONCENTRATION

(ug/Kg )—- ———— g! —— — »S — S = — —

41706930741030600saoo

MS : QC! LIMITS

REC #i REC.

62 ! 59- 172S3 162-13:794 ; 66-142234 *!D9-139102 160-133

ii

COMPOUND

1 , 1-Dichloroethene ____TrichloroetheneBenzeneTolueneChlorodenzene

SPIKEADDED(ug/Kg )

791079 1O791079107910

MSDCONCENTRATION

(ug/Kg)

5250699O766O304009020

MSD'/.

REC #

66S39728 1 *105

i"/. !

RPD #!SSSSESX J :

-6 !o :-3 :i :

—3 !1

QC LIMITSRPD ! REC A

_«.__ —— rrrew t -™— »™ —— - H

22 159-17224 ;62-13721 i 66-14221 =59-13921 160-133

;

Column to be used to tlag r^cov^ry and RPD values with an asterisk

Values outside o-f QC limits

out of _ 5. outside 1 imitsSpike R^coveryi _ ^. out o-f 10 outside limits

COMMENTS: TBC-1 ' URSINST : C „ 4B/ 1 OML/50UL

FORM III VOA-2 1/S7 Rev

^000537

=iD name: .5WL-r:JL5A

ac Ciae: swQfeSftr i/ase No.s

; COMPOUND_ . . . .. 1 , i-Dicr-loroetnene _.'- Tr-icr.rc-roethene; Benzene- " ~~-"rToluene : " -

\ ChiorQ&enzene'

; COMPOUND

1 - i , l-Dicriioraetnene_ ___S Trichloroetnene: Ben 2 en e: Toluene: Chlorocenzene"

\ SPIKE

; <ug/Ka }• —— _ —i •?!=;•>,-.i / J •-".-: 530; -7530! -753O V:1 7*3c-

! SPIKE; ADDED! j; ug/Kg ;

! 7530

I 7530; 7530! 7530. .;

; slftMP LEi CCNCE?-n*RATION

. ™ — . - ....._

- ;! ;'v62osr

"i -' i3±i"t>Wi ""'"~" " " 3i 3S : ,-.';i '.> "

; CONCENTRATION: ( ug/Kg /

i 5.7203220

: 21100: 605000

"4OO1

! CCîC

,;

j _ ;_I ~''?2

i ri

! MSDi .•'.! REC

; 76! 1 091 65; -soI 1S1i

rISENTRATTCr:ua/Ka ;

7290

2 1 4OOi . oSo.-

# i RPD ff

i ' 24 *; _7

* ; 6- * 1 __~Vj;-'j *

•?• !. *.'

,

' PI 3 ' '.:'_*i \ Llr:;T3"^

; '"•' / . D T — 1 _;; i t*i "• -, ~' — ; ~"~

: 69. '66- 14"'• - - - » » . =•» _ •< — -— .i . . Mi- -* > w;1?"" i. ._. Tr A r* -«"!t so-i". - - • -

i ii iQC i-lhXTS

! *PD ! REC. '

! 22 159-172!; 24 "62-137': ^1 ?66-l42;

>-. * - =• « _ -, ^ •— . •_A *J T — i ._ T •

21 ' 6C1-- .3;;

3 Column tio De used to -flag recovery and PPD /alues with ^n asterisk

« values outside o-f QC limits

5 outside . iSoike Recbvej : '_5 out o-f 10 outside limits

ICMMENTS: "TC-1 URSINST:C,4S/10ML/5UL F

FORM IlI"VQA-2 ~ - ' 1/S7 e>

A R I O I 6 I U

SOIL 5EMI VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECCvER f

NAm*i SUJL - TyLSA ____________ Contract: URS _______

Code: SldQK Case No,.: URS2 3AS No. i _____ SDG No.:

- EPA Sample No.: TBC-1 _______ Level :< low/med ) i-QUJ

COMPOUND

Phenol _.. ._ _Z-Chloroongnol1 , 4-Dichlorob^nzgn^N-Nitroso-di-n-prop. ( 1 )1,2, 4-TrichloroDens@ng_•i-Chloro-3— methyl phanolAcsnaohth^ng4-NitroDhgnoi2.4-Dinitrotolu^n^P*nt£iChloroDhenoiPvr«n»

'SPIKE •ADDED(ug/Kg )

1690016900S430843084 30

1 69008430169008430169008430

SAMPLECONCENTRATION

< ug/Kg )

2980000O0-000

. 00

MSCONCENTRATION

(ug'/Kg )

1080014800683049706030_9330632062004760

1 32005180

MS JC•; .LIMITS;

REC *; EC.

46 26- *?038 '5-10231 23 1 :-459 ,41 12671 7-3 10756 ; Z6 103— tr "**_!• ""7. j . . i _ /

." 11-114^6 ' -V3- 39-3 I--K.^Jl 73-142 "

; '

.

COMPOUND

Phenol2-ChlaroDh©nol1 ,4-Dichlorobsnzen*N-Nitroso-di-n-prop. < 1 )1 ,2.4-Trichlorobenzene4-Ch loro-3-methyl phenolAcgn^pnthen©4-NitroDhenolC, 4-Din itro toluenePen t AC n 1 orooheno 1Pyren©

SPIKE 1 MSDADDED ! CONCENTRATION< ug/Kg) ! (ug/Kg)

16900 ! 923016900 i 139008430 ! 63603430 ! 43308430 J 565016900 I 943O3430 J 6030169OO ! 122008430 ! 4380169OO ! 127008430 ! 5020

i

MSDy.

REC S

378275s-"?U-i6756-? t/ .£.7*7

527560

7.RPD #

/-j*-j— »/s

1 3—04

-64 *74T*

:QC LIMITSRPD fiEC.

75 16- ^50 '25-10-27 23 10473 41 11623 .73 10777 : 26 1071^ 71-17750 11-11447 IS- -8947 17- 10°76 35 - 1 4^j

'

\ 1 )• N-Nitromo-di-n—

4 Column to be us»d to -flag recovery and RPD values with an»" VA!U*S outside o-f DC limits

out o-f 1 1 outside limitsP»cov«ry: _ 0 out o-f 22 outside limits

COMMENTS : TBC- 1 URSINSTsF SWL#5037.01

FORM III SV-2 - 1/B" R-

ft-000539


Lab Name: SWL - TULSA_____;_______ Contract:

Lab Code: SWOtC?' Case No7: .URS SAS No.: ______ SDQ No.:

Matrix Spike - EPA Sample No.: TTC-1_____• Level:<low/med> MED

COMPOUND

Phenol2-Chlorophenol1 .4-DichlorobBnzch»N-Nitroso-di— n-prbp. < 1 )

4-^Nitrophenol2,4-Dinitrotoluene ____Pen tac h 1 orooheno 1Pvrene

SPIKEADDED< ug/Kg)

4820OO48200024100024100024100082000

48200024100048200O241000

SAMPLECONCENTRATION

< ug/Kg)

403OO000o w

• = o ,o0

3080

MSCONCENTRATION

(ug/Kg)

289OOO22700013100O12BOOO140000

_„ 253000.~ 148000 f-

29200O13600051SOOO3140O

MS

REC #

524754s'Z

535261615610333 *

QCLIMITS!REC. ;

26- 90!25-102!29 104!41 126!33 107!26 103!31-137!11-114!29- 39 t17-109!35-142!

i

itiCOMPOUND - - !

ssassssssaeaesssssaisssaaEaKssassa {Phenol !2-Chloroohenol !1 54-Dichlorob*n2»n» ___ !N-Nitroso-di-n-prop. ( i ) i1 .2,4~Trichlarob»nz»n«_i4-Chloro-3-m«thylph«nol !Acenaohthen* - 14-NitroDhenol i2.4-Dinitrotolu«n» ____ !Pentachloroohenol ' •Pvrene !

•

SPIKEADDED< ug/Kg)

3sa:*»3sss5s

4820004S20OO2410002410OO2410004820002410004820002410OO482000241000

MSDCONCENTRATION

< ug/Kg)==ssss:acesae33asaB

24600018900010400O1070001160002390OO132OOO90SOO13200047000082400

MSD%REC #S=KSVS3

4339434448SO5519359833 *

RPD #

1919231919410105 *2100

QC LIMITSRPD

33SO2738

195047476

REC.

26- 9O!25-102!28 104!41 126138 107!26 103!T * _ i -r 1 >*>i — lo/ i11-1.14!28- 89!17-109!35-142!

(1) N-Nitro»dTdi-n-propylamin«

# Column to bit used to -flag recovery and RPD values with an asterisk* Values outside of QC limits

RPD: _i_ out o-f 11 outside limitsSpike Recovery: _£ out of 22 outside limits

COMMENTS: TIC-1 URS 1G SOILS ,

FORM III SV-2 1/87 Rev,

1 0 1 6 1 6


Lab Name: SML-TULSA______________ Contract: URS_______

Lab Code: 3VJQK Case No.: URS2 SAS No.: ______ SDG No.:

Matrix Spike - EPA Sample Nc.: TBC-1______ Level:(low/med) LOW

COMPOUND

gamma-BHC < Lindane ) ___HeotachlorAldrinDieldrinEndrin _ _ _ _ _4.4' -DDT

SPIKEADDED< ug/Kg)

67.467.467.4163168169

SAMPLECONCENTRATION

(ug/Kg)

00O000

MSCONCENTRATION

(ug/Kg)

59.30

53.1237206131

.

MSV.

REC ft

390 *79141 *123103

QCLIMITSREC.

46-12735-13034-13231-13442-13923-134

~"

COMPOUND

gamma-BHC ( Lindane ) ___HeotachlorAldrinDieldrinEnarin4.4' -DDT

SPIKEADDED< ug/Kg)

67.467.467.4169169163

MSDCONCENTRATION

< ug/Kg )

47.9043.2161160193

MSD

REC #

710 *649695115

/•RPD #

0213326-6

QC LJRPD

503143394550

tMRE^j

46-12735-13034-13231-134

." r23-134

# Column to be used to flag recovery and RPD value* with an asterisk


RPD: _ 2 out of _ & outside limitsSpike Recovery: _ out of 12 outside limits

COMMENTS:

FORM III PEST-2 — 8/87 F

6-000541

A R I O I 6 1 7 - - . — — -

3FSOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE IMPLICATE RECOVERY

Lab Name: SHfr-TULSA____________ Contract: UHS_____

Lab Code; SWLQ Case No.; opg SAS No.; _____ SDG No.;

Matrix Spike,- EPA Sample No.: TTC-1______ Level: (low/med) M££~

COMPOUND

gamma-BHC (Lindane) ___Heptaehlor .,... ,AldrinBiftldrinEndrin • . .._ -4.4--DDT

SPIKEADDED(ug/Kg)

241024102410602060206020

SAMPLECONCENTRATION

(ug/Kg)

0000

5810

MSCONCENTRATION

(ug/Kg)

208021102110559063006940

MS%REC

86888893

' 95115

! QC! LIMITS

*! REC..— i ___.—«,_146-12'!35-13(134-13^! 31-13<I42-13S123-13*i

COMPODND

gamma- BHC (Lindane ) ___fiftDtachlorAldrinDieldrinEndrin4. 4 '-DDT

SPIKEADDED(ug/Kg)

241024102410602060206020

MSDCONCENTRATION

(ug/Kg)

365016903440774086507540

MSD%REC *

152 *70143 *129134125

%RPD #

-55 *23-48 *-32-34— A

QC LIMITSRPD ! REC.

50 ! 46- 12731 135-13C43 134-13238 131-13*45 142-13$50 123-13*i

t* Column to be used to flag recovery and RPD values with an asterisk


RPD: _2. out of 6 outside limitsSpike Recovery: _2. out of 12 outside limits

COMMENTS:

FORM III PEST-2 8/87 Rev.

6 00054

01618

ItS SOUTHWEST LABORATORY OF QKLAHOM

MATRIX SPIKE EVALUATION FQRH

URS

SASPLE ID T8C-1HS

. NET MT. 10,0

iiount itount iiountno in sol. added detected Z TARSET

added ppt ppt ppt recovery recovery huts2378 TCDF 2.5 'o 250 299.5 120 60 - 140 ZHPCDF 10 • 0 1000 900.0 90 60 - 140 ZQCDF 25 0 , 2500 2863.0 115 60 - ;40 X

2378 TCDS 2.5 0 250 219.4 98 60 - 140 IPCDD 10 0 1000 1109.4 Hi 60 - 140 IH)(CDD 10 0 1000 368.9 37 60 - 140 I


SAHPLE ID TBC-IHS TBC-1HSD

MET »T. 10.0 10.0

uouftt aaount RPGin sol. in spl.ppt pot

2378 TCDF 299.5 293.5 2.0HPCDF 900.0 748.0 18.4OCDF 2863,0 2950.0 3.0

2378 TCDD 219.4 195.1 11,7PCDD 1109.4 954.1 15.1HICDD 868.9 865.8 . .4

I O I 6 I 9

1SD SOUTHKEST LABORATORY OF 3KLAHDRA

HATRIX SPIKE EVALUATION FORA

SAMPLE ID TBC-1HSD

MET NT. 10.0

aiount aiotint uountno in sol. added detected Z TARSET

added ppt ppt pot recovery recovery lmt?237S TCDF 2.5 0 250 293.5 117 60 - 140 ZKPCDF 10 0 1000 748.0 75 60 - 140 ZEOF 25 0 2500 2950.0 118 60 - 140 Z

2378 TCDD 2.5 0 250 * 195.1 78 60-1402PCDD 10 0 1000 954.1 95 60 - 140 ZHXCDB 10 0 1000 865.8 87 60 - 140 X


SA«PIE ID TBC-1HS TBC-1HSD

KET HT. 10,0 10.0

uount atount RPDin sol. in spl.SDt ppt

2371 TCDF 299.5 293.5 2.0HPCDF 900.0 743.0 18.4QCDF 2863.0 2950.0 3,0

2371 TCDD 219.4 195.1 11.7PCDD 1109'.4 954.1 15.1HICDD 868.9 365.8 .4

f l R I O I 6 2 0

"ftTRH SPIKE EVALJATION ?•£*

SAHPLE !3 r"-l*S

S£T ST.*

IQad sec

2"S "DF 2.5H&CDF 10DCDF 25-.--Q *«*r_ - s. . ; 0 . wJt- , .-v

:C3D ID-XC3B :)

SAMPLE ID

KET «7. '

•;7Tq Trnciij.' C . w-yr

HPCDFI-C3F

"fa rrrvn.» j g ; wuvirnri• tf>'W

HXCD0

aaount:a sol.crt5U^

v -.A

TTC-1HS

10.0

aiountin sol.cot

''SI 'A3i.it220.02937.0

it! iiwi .0

1074.5352.4

:C.O

diOUHt alCURt

533EC :etecteg '; , "ARSETDot sot .rscoverv rscoverv :is;:=2^0 231.: - 112 aO - MO Iim -320.0 ' 32 iO - 140 I2500 2997.0 119 aO - MO Z

250 - MJ.i *i 60 - 140 Z1 00 1074,5 ^ -107 60 - !40 X

.. :000 5:2.4 85 oO - i40 I


TTC-iHSD

10. C

aiount RPDin sol.;ot291.3 3.6903. 0 9.63233.0 8.1

207.4 31.11077.3 .3725.2 16.0

flRIO!62l «2r 000545

TRH SPIKE SVAUJATIW «3RK

x!

2"8 TC3FMPCDFJC3F

::?s -CUD5C9D"tCDD

SAMPLE ID

HET Iff.

2378 "CD?H^CDF-

&h /a ! wrfU

"33HSCDD

-r.

taount"0 ;T SDI.

,GGec :ct" e, 0«4kl kC

10 S25 •)

2.5 v:o o:» :

TTC-1MS

10.0

tflountin sol.OBt2S1.I820.0C07 A

151.61074.5852.4

4 V r v

i.icunt ssoun:idaifl :§t§ctsa A *^R8£Toat art 'icoverv "sccvtrv ;?;:i250 :?.:.'• 117 B0 - 140 S:ooo • ==> .c *?o "• BO -T40 :sroo :; s.o :30 so - ;40 "250 . 207. 33 sO - 1*0 ".ICOO 1C77.8 108 iO - ;iO Z)300 -5.: -3 iO--S40S;

DUPLICATE SAtfLS EVALUATIDN

TTMHSD:o.o

aacunt RPDin ssl.sot291.3 3.i303.0 5.63233.0 9.1

207.4 3M1077.8 ,372s. 2 lfe.0

6T000546SR10J622

U.S. EPA - CLP

5A , EPA SAMPLE NO.SPIKE SAMPLE RECOVERY _____________

Lab Name: SOUTHWEST LAB OF OK" Contract: 63-09-0089MDTBCI:

•_aD Code: SWOK Case No.: 50371 SAS No.: SDG No.: MDTBCI

Matrix: SOIL - _ ...Level ( low/med >': LOW

% Solids for~"Samp"le: SO.4


Analvte

AluminumAn timonyArsenicBarium3ervl liumCadmiumCalciumChromiumCobaltCoooerI ranLeadMagnesiumManganeseMercuryNickel'PotassiumSeleniumSilverSodium "Thai 1 iumVanadiumZinc 'Cyanide

ControlLimit7.R

75-12575-12575-125"7= — 1 /~>c:/ —j i *.»j75-125

75-12575-12575-125

75-125

75-125-7C1 __ •( O="/ U~liU~7 — i '?'=;/ *J 1 .i-wJ

75-12575-125

-75-12575-12575-12575-125

Spiked SampleResult (3SR)

10.43163.2773

577.783514.511612.4942

34 . 4445143.013579 . 6400

12.5112

579.1353.5258

152.4353

1 .951513.6120

14.9552169.3467161.057321.3735

C

B

SampleResult (SR)

•.!'' • / •.!• 1 •->

* -2.010977.47331 .1617.4975

27.33658.6703

1 4 . 4230

7.9739

338.9954.lies

13.7647

.4975

.7463

.497537.665829.24222.3919

C

UsBU

B

U

Uuu

u

SpikeAdded < 3A >

124.339.95

497.5112.4412.44

49.75124.3362.19

4.98

" 124.38.57

124.33

2.4912.44

12.44124.33124.32T-t T~?.-i. . •«• /

1 1i 1i 1

:.R :.Q ; M< ii *! INR

3.4INIP33.01 NIF100. a! !P107.31 IPiOO.4! IP

; INR113.8; JPlos.o: IP104.9! iP

I INR91 .1 ; :F

! INR152.9!N!P9 .2! ICV

111.51 IP: !NR

9.4! IF109.41 IP

; INR120.2; IF106.3: IP106.UI IP95.61 1C

Comments:


01623 6-OOOQ47

U.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY __________

MDTBCIALab Name: SOUTHWEST LAB OF 0(C Contract: 6S-D9-0089

Lab Code: SWOK Came No.: 50371 SAS No.: SDG No.: MDTBCI


Concentration Units: uq/L

ittiS Analyt©i•1 Aluminum! Antimonv! ArsanicI BariumI B»rvl liumJ Cadmium.CalciumI ChromiumI CobaltI CopperI IronIL@ad\ Magnesium! ManganeseI MercurvI Nickel'! PotassiumI SeleniumISilvgr! SodiumI Thai lium! VanadiumI Zinc 'I Cyanide1

ControlLimit;<R

Spiked SampleResult <SSR)

991.97

~~

4636.58

"

CSample

Result CSR)'

15.00

1 kjo- i • 76

C

u

SpikeAdded (3A)

1 20 . 0---

.3100.0

_

••'.R

326.6

99. 1

~"

ii

Q!Mii,'NRIP:NRINRINRINR!NR!NR:Mmiiw:NR:NR;pINRINRINRfNRINRINRINRINRINRINR

_! __

Comments:


#-000545

U.S. EPA - CLPEPA SAMPLE NO,

6 . . ___________._DUPLICATES ! . .

i MDTBC1Di_ab. Names SOUTHWEST LAB OF OK Contract: 63-D9-0039 ! ___________

Lab Code: SWOK Case No.: 50371 SAS No.: SDG No.: MDTBCI

Matrix (water/soil): SOIL .. Level (low/med): LOW

!•: Solids -for'"Samples " SO.4 . % Solids for Duplicate: ~?7.3


11

i Analyte

: Aluminum! AntimonyArsen ic

i Barium! Beryl II um"! Cadmiumi Calcium! Chromium{Cobalt1 Copper1 I ran! Lead; Magnesium1 ManganeseI Mercurv ~; Nickel; PotassiumI SeleniumI Silver; Sad ium1 Thai 1 ium' Vanadiumi Zinc .": Cvanide „•i

ControlLimit

.- 49. S

-

6.2

1 0 . 0

-

12.45.0

_

_Sample (S) C

22303 . 3330 !3 . 73 1 3 ! U2.Q10.9.J.B

77 , 4733 I .1 * 1&17 1 B.4975IU

739 . 4037 ! B27.3365!8. 6703 I B14.42301

26597.318017.97391

952. 1577 IB333. 9954 J

.U85IU13.76471

303. 5476 IB.4975IU.7463 I U

600. 0479 IB. 4975 I U

37 .6653 I" Q •"!> /I *"? *"? '

... 2.._3919.UJii

Duplicate (D)

13903.3100o . / •_;• j. 31.2514

..61 .6182. 9704.4975

569.435326.31503 . 370713. 6934

19337.43207 . 0522

923.3140391 .3016

.lias10.4364

651.2190.4975.7463

519.6455.4975

30.772024 . 4657

•-i -r Q O T.._.. - * '-•.«•*•'

C

u8

BUB

B

B

U

BUUBU

u

;y.RPD !

46 . 4 {I

46.6 i'"*•'•> Q (jl-ji. m O 1

17.9!I

32.415.61•-' . sJ 1

cr ^ ii_J > - i31-. 4 IL /% '

. •"? =; i« . vJ 1

,711

27 .5 !20.91

I! .

14.41t

20 . 1 1" J. / . ci i

|

I

Q

*

*

M

PPFPPPPPPPPFPPCVP 'PFpPFPPC

FORM VI - IN7/83

flR!Oi625 6-000543

U.S. EPA - CLP


AD Name: SDUTHW£ST LAB OF OK Contract: 6S-D9-O039

ab Code: SWQK Case No.: 50371 SAS No.: SDG No.: MDTBCI

olid LCS Source: EPA0287

us LCS Source: EPA-LV

ii! Anftlvt*iI riiuminum; Antimonv{ Arm^nir; BariumIServlliumi CadmiumI Calcium! ChromiumICobalt{Cooper1 Iran!L«aI Magnemium! Manaanesel rcurvJfJickBii PotaamiumJ Seleniumi SilverI SodiumJ Thai lium ;I Vanadiumi ZincJ CvanidB)i i

i AquecTrue

>

r

"L.

i

!

Dus Cug/LFound

=

---- —

-

)KR True

325 . 0211.0917.04.8

. 19.445.4

196200.099.6

144.06910.022430 . 0236 . 0

113100.0208 . 0

12.760 „ 950 . 039.222 . 250 . 039.065.31S7._05.6

SalicFound

234.2161.5706 . 43. 6

21.943.5

179570.3112.6155.16381.3

13661 .7217.7

1 1 1 730 . 0T"»O OjL.ji.V . O

12.369. 167.524,823.377.545.063.3

190.45.3

JC

B

B

B

\ mg/kg)J. Limits

225.0! 424.0: 127.0! "94.0635 . 0 I 1 1 99 . 00 . 0 i 40 . 0

14, <=: » o*? Tl a . o i — i • o— —35.71 55.1166800.01225600.0

79.21 120.0124.01 162.06006 . 0 I 7320 . 017770.0! 27080.0

138.01 235.01 00400 . 0 I 1 29900 . 0

: 177.0! 239.03er i i ~* A. wJ 1 J. / . '.J

: 49.2; 72.60 .01 1 000 . O

19.1! 59.4.15.51 29.00 . 0 I 1 000 ; 0

r-i /\ f i c"~ cr^l^.Oi i '_•»•_!

51.71 79.9133.0! 236.0

4.3! 6.9ii

•/.R

37.76.77.i75.'

112.'95. <91 :Aiov99T33.:92.:94. c

no.;96.'

113..135.'63. "

107.-155.-115.-104.*101 .£1 03 . <:

FORM VII - IN7/SS

1RIOJ626

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY ___

Lab Name: SOUTHWEST LAB OF OK Contract: 68-D9-0089MDTTC1S

Lab Code: SWOK Case No.: 50131 SAS No.: SDG No.: MDTTC1


% Solids for Sample: 71.6


! i Control! ! Limit! Analyte ! %Ri i1 __..._LJ. ,-IIL-T —— --.--- ——— 1 __________________

! Aluminum [{Antimony ! 75-125! Arsenic [75-125! Barium 175-125JBeryllium} 75-125! Cadmium ! 75-125! Calcium !! Chromium ! 75-125! Cobalt 175-1251 Copper . !klron • ,'jLead [75-125! Magnesium !! Manganese!! Mercury ! 75-125! Nickel !{Potassium!! Selenium 175-125[Silver ! 75-125! Sodium I! Thallium 175-125i Vanadium 175-125{Zinc 175-125! Cyanide ! 75-125i i• >

Spiked SampleResult (SSR) C

|12.83911B5.7765!

708.4941!16.9762!-17.1288!

!108.8243!171.6450!116.5039!i325.3140!

]1042.4277!

1.0265!425.5360!i

1.6844J14.7436!i16.4302!205.4687!343.4626!24.0788!t... — - i _

SampleResult (SR) C

i4.1899IU2.8827!

227.5388!1.2288IB1.7559!i60.3654!14.7497!365.8036!i141.1011Ji745.8838,'

.2095}2124.6472Ji

.5587JU

.838QIUi

.5587JU51.7159!151.4737J2.63521Ui---—..——..- ———— _ i —

iSpike

Added (SA) !i- —— „ _,,riL.,— ti139. 66 i.11.17!558.66,'13.97!13.97!

!55.87!139.66!69.83!i139.66!i139.66!

.70!139.66!i

2.79!13.97!i13.97!139.66!139.66!26.15!. i

-._.. ... • .. i • - — .——— 1

t 1t 11 1

%R 1 Q JMi r——— _ — _. i _ i —! !NR

9.2!N!P25.9INJF8.6 . 1 ! |P112.7! IP110.0! jP

! INR86.7! |P

112.3J |P-357.0J |P

I INR131.9!N|P

1 INR212.3! IP116.7! {CV

-1216.6! IP! INR

60. 4! N|F105.5} IP! ;NR117.6! IF110.1! |P137.5INIP92.11 |Ct i_ _. i _ i - —

Comments:


A R I O I 6 2 7

U.S. EPA - CLP

EPA SAMPLE NO.

Lab Name: SOUTHW2ST LAB OF OK Contract: 68-D9-0089MDTTC1A



Concentration Units: ug/L1111! Analyte

! Aluminum! Antimonyi Arsenic1 Barium{BerylliumI Cadmium! Calciumj Chromium! Cobalt1 CopperIronjLeadI Magnesium! Manganese' Mercury! Nickel{Potassium{Selenium{Silver! Sodium! Thallium! Vanadium{ZincI Cyanide

ControlLimitXR

______ ___


1069.36

1439.72

1577.04.--•- . ___ ———— ———— 1_;_L_——— • ——————

C

—

SampleResult (SR)

15.00

505.14

542.28

C

U

SpikeAdded (SA)

120.0 '

'

1000.0

"

1100.0

XB

891.1

93.5

1

94.1

i ii ti iQ!M !

1 l

INR!IP 1INR!INR!INR!INR!INR!INR!|NR!1 W Jl;Ht p ^w

INR!INR!!NR!INR!INR!INR!INR!INR!INR!INR!jP !1 I! !

Comments:


f l R i O I 6 2 8

U.S. EPA - CLPEPA SAMPLE NO

6 __________DUPLICATES

Lab Name: SOUTHWEST LAB OF OK Contract: 68-D9-0089MDTTC1D

Lab Code: 3WOK Case No.: 50131 SAS No.: SDG No.: MDTTC1


% Solids for Sample: 71.6 % Solids for Duplicate: 71.6

Concentration Units (ug/L or mg/kg dry weight): MG/KG11! Analyteii Aluminum{ Antimony[Arsenic! Barium{Beryllium\ CadmiumI Calcium} Chromium! Cobalt; Copper| Ironi LeadI Magn.es ium! Manganese! Mercury! Nickel! Potassium! Selenium| Silver! Sodium[Thallium; Vanadium|Zinc} Cyanide(

ControlLimit

2.855.91.41.4

1396.6

14.0

.1

.

14.0

~-Sample (S) C

21129.3282!4.1899JU2.8827}

227.538811.2288IB1.7559!

1958.2286!B0.3654!14.7497!365.8036!

38626.6257!141.1011!801.1008IB745.8838{

.2095!2124.6472!425.6128JB

.5587{U

.8380JU611.8179JB

.5587|U51.7159!151.4737!

2..6352JUi- — - - — t ___

Duplicate (D) C

26439.0299!4.1899IU2.8827!

137.7546!1.7028!2.0792!

426.5426JB40.9722!14,7700!70.8662!

46676.2151!100.5415!888.6482IB784.3788!

.4260,'367.2465!508.9126IB

.558710

.8380|U1095.2859JB

.5587IU65.0117!148.4193!2.6057!Ui>

i%RPD 1i

22.3! i0.0!49.2!32.3!16.9!

128.5138.31

.1!135.1!

18.9!33.6!10.4!5.0}68.1!141.0!17.8! it\56.6! t22.812.0! iiti

i

QIMi

*|PIPIF

*|PIP!P*;p*{PIP

*|PIP

*|PIPIP

*|CV*!PIPIFIP.1 Pi ±IFIPIP1C1i

FORM VI - IN7/88

&-QC0553A R I O I 6 2 9

U.S. EPA - CLP





Aqueous LCS Source: EPA-LV

111I! Analyteii — -•-! AluminumI Antimonyj ArsenicI Barium{Beryllium! Cadmium{Calcium' ChromiumCobalt{ Copper1 Iron,' Lead{Magnesium! Manganese! Mercury! Nickel; Potassium! Selenium{Silver! SodiumI Thai lium{ Vanadium{Zinc! Cyanidei•

AquecTrue

.... ........ ._ . .....

3US ( Ug/LFound

- ——— ... ————— ——-•_..!_-

)

XBSolid (

True Found C

325.0! 284. 2\211.0! 161.5!917.0! 706.4!4.8! 3.6IB

19.4! 21.9!45,4! 43.5!

196200.01179570.3!99.6! 112.6!144.0{ 155.1!

6910.01 6881.3!22430.0! 18661.7,'236.0! 214.2!

118100.0ll29159.il208.0) 229.8!12.7! 12.3!60.9J 69.1!50.0! 67. SIB39.2! 24.8!22.2! 23.8!50.0J 77.5JB39.0! 45.0!65.8! 68.8!187.0! 190.4!5.6! 5.9!i i—————— . i — - ———— i _

mg/kg)Limits %R

225.0! 424.0! 87.4127.0,' 294.0! 76.5635.0; 1199.0! 77.00.0! 40.0! 75.0

16.5! 22.31112.9.35. 7{ 55.11 95.8

166800.0[225600.0! 91.5;79.2) 120.0!113. |124.01 162. 01107. 06006.0! 7820.0! 99.5117770. 0! 27080.0! 83.2!188.0! 285.0! 90.8!

100400 . 0 J 129900 . 0 ! 109 . 4 J177.0! 239.0I110.5!

8.5J 17.0! 96.9!49.2! 72.61113.50.0! 1000.0[135.0

19.1! 59.4! 63.3.15.5! 29.01107.2!0.0! 1000.0!155.0!24.6! 53.5J115.4!51.71 79.91104.6!138.0! 236.01101.8!4.3! 6.9J105.4J

i i t_______ i ——————— i ———— i

FORM VII - IN7/88

flR!OI630 6-000554

U.S. EPA - CLP





Aqueous LCS Source: EPA-LV ._..__..

1I1t! Analyte

{ Aluminum{ Antimony! Arsenic! Barium! Beryl lium! Cadmium[ Calcium< Chromium| Cobaltt Copper! Iron[Lead{Magnesium[Manganese[ Mercury{NickelJ Potassium! Selenium[SilverJ Sodium[Thallium{ Vanadium[Zinc{ Cyanide

Aqueous ( ug/L )True Found XR

Solid (mg/kg). True Found C Limits XR

12.7 14.2

"

8.5 17.0

1

111.8

FORM VII - IN7/88

flRI0163

U.S. EPA - CLP

LABORATORY CONTROL SAMPLE ; ..

Lab Name: SOUTHWEST LAB OF OK Contract: 68-D9-OOB9

Lab f>.'fr: ^HHf Case No.: 5014.1 SAS No.: . ?DG No. : MBR114

Solid LCS Source: EPAQ2S7 :

LCS Source: EPA-LV

1111

I AluminumI An Lxmonv! Arsenic! Barium! P r* r v 1 1 1 1 "n

! r^ 3 c > um

! C^b-- 1 t! CODDPr! Iron! Lead1 Mnpn^'sium! flHnn-^nea^r-I Mercurv•Hi cl- *»1! Potassium! SeleniumI Sll vpr! Sod i u m! Th^ 1 1 iumj Van^d a umI ZincM%«md«

£nueou5 (ug/L )T""?1 Found ";R

"

.._

— -_.

. __.

-

Sal id ''mciYkg )True Found C - Limits %P>

325 . 0211.0917.04.3

.19.445.4

196200.099.6

1 44 . 06910.022430.0236.0

1 13100.0208 . 012.760 . 950 . 039.222.250 . 039 . 065.8187.05.6

234.2161 .5706.43.6

21 .943.5

179570.3112.6155.1

6881 .318661 .7217.7

1 1 1 780 . 0229.8

1 *? T.!.*.••_'

69.167.524.823.877.545 . 066.3

1 O . 45.8

rs

B

B

225 . 0127.0635.0

'!> . 016.5

• 35.7166SOO.O

• 79.21 24 . 06006.017770.0188.0

1O0400 .O1 77 . 08.549.20 . 019. 115-50 - 024.65.1 .7138.0

: : 4.3

424.0294 . 01199. 040 . 022.355. 1

225600 . 0120.0,162.0

782O . 027080 . 0235 . 0

129900 . 0239.017.072.6

1 000 . 05.9.429.0

1 000 . 053.579.9236 . 06."

87.'76.77. t75. (112. r95. E91 .:

10 199S3.:92.:94.*

1 1.0 . f96. c113.'135.63.107.155.'115.1 04 . .1 0 1 . £•103.*

FORM VII - IN7/88

flfi(OI632

SOUTHWEST LABORATORY OF OKLAHOMA, INC.1700 W. Albany • Suite "C" • Broken Arrow, Oklahoma 74012 • 918-251-2858 • FAX: 918-251-2599

./JR r_..-:3" J CATjT" . _ _. ..._.__. __ . _ ._. .. REPORT: ?0 L 4 67.70 DEi_ AWARE ...AVENUE I •"BUFFALO. NEW YORK 14202. ' . ... " _" . =/:;-_: " "'DATE: "" 07-1..1-91AfrN: PETER FAIRBANKS

9AMPLE MATRIX: SOILSWLO t 50.14.02 . •••PROJECTS 35214; DELAWARE SAND & GRAVELCLIENT ID: TBR-1 (24') (MS/MSD*

TPH MATRIX SPIKE/MATRIX SPIKEJDUPLIGATE RECOVERY DATfl

SPIKE CONC. SAMPLE CONC. MS CONC. MS PERCENT(mg/kg) (mg/kg)* (mg/kg)* RECOVERY

657 16 610 8 "'1

MSD CONC. MSD PERCENT RECOVERY PERCENT(mg/kg)* RECOVERY DIFFERENCE

~H 616 907. -17.

* = DILUTION FACTOR NOT APPLIED TO THESE CONCENTRATIONS

A R J O I 6 3 3

WATER VOLATILE LABORATORYCONTROL SPIKE RECOVERY

Inst. ID:

Lab Name: fti""' " UiPfMTrf/ffMm\«nt Code: (A- £-- Episode #: $ '*? 5 *

Matrix Spikc-LCS No.: ff / -

COMPOUND

1 , l-DichlorocthcncTrichiorocthcneBenzeneTuolcneChlorobcnzcne

SPIKEADDED(ug/1)

5 O~ri//V

MSCONCENTRATION

Cug/0

<-f>^M>^^^

MS%

REC#

q^qsqA9A^

QCLIMITSREC.

61-14571-12076-12776-12575-130



Spike Recovery: f~**\____out of ^ S___outside limits

Comments:

U.S.. EPft -- CLP

r*& EPA BAHPi.t. MO-SF'I KG SAMPLE RECOVERY

i JlfttVfft^Sl.ab Mama: snUTHWE&'I LAS UP-' OK * Contracts 6BHD9-OO09 !„„„„„„._.._

Lab Docior &WOK U<*s>e? Ho.. ;;- 437 &JL SAB No. s SDG No. s HR!:-TKv:

MA Kr i x s WATER Lcsvel. (lowXfn-a-d > s LOW

''•» Sol Lei is "ror Sample:: O.O

c^n fcra t\3 un Units C'-tg/L or mg/kg dry weight) r LiCi/'L.

1

1

An a 3 y te»

AluminumAn •{• imonyi^rseiii c:BariumBe?ryl liumC&dmiumO*il ci i.tfl'iChr ttmiuriiCobaltHopperPi ronLoadl1&gne«F.j urnriang«Ane&9Mercury'NickelPol-ass ium<^r-"i i»r» i umSx 1 v&-rSodiumThai 1 i urnV*n«id:i.UT(!£ :t j*i t.Oy&jiicie.... ...... ...._. „,.-.. _..

I Control iLimi 1 ! Spited Sampler"i'R { ©"sul 'I*. C EiGi*? i

75-175 i " 5789, 122675-125 I 152.404775—1*25 ! 75- 525O.•'"S""!! ! K3&6 1> VJVxM"? "i -- 1 S? * ' 49 S"L "i775-125 ..I 65^2a?S

:75-125 J 7!39.87"5l7S-125 ! 572*869475-125 J 256.1931

I 2537 65. 560075-125 i SA.7500

iI 9154-3419

,/ ..1 •* i, X™ s.' i i»C3*TW\.'

"/?- j 2'5 ! 8 J.8 . 5306ii

75-125 ! .10.. 43.5O7 A- 125 ! 55.04O1

;

75-125 ! 48.3OOO7S-J.25 ! 491.0294;' is ~- i :•? 5 ; 323 .. 34 4 175-125 ! 146. 81 55-«.--..,_„..„.„._ ' __ __. _ ._.,_..„ _ , _ ,„. ..

c:

B

..

SampleResult CSJ-O" C.

•1707. 4604 J30.0000JUÔ»t:125O-t

93V.. 879 ;1 "-\ 1 T:i ' TW

4. 3 1 3.0 !»J

B9.Bio:M'8S.1 - 7B4S !17.742VJB

279022.3100!53.2000!

!9366. 1973 ;

,4OOO!U33 O- 6917.: J

I1 « 429EnO * B

*1 X IOj*''i '. —— _ — .._ t_

1O*0000|U2.0OOOIU

333,9921 !16.7000JU

t...., .„ —....-— .._*_.-*.,*,...-.„-.-..- * ....

r i

Spike ! [A eld rod i S A i l ";R ;Q

J:OOC-..OO[ f.u4.:l ;NMO « 00 ; -~0 , l:t J N4O,00! J 11 -li!

ôOo .. 0 .3 ; y... :;•> ;">0 ., 00 ! ^7«O :

; ;• Oo,.0o; 10O-G j••OO.. 00 I r»'H-0 !50 ..00! -;ili.4!

1OOO .. 00 ! •-i'.'C.o ."'•' ;20.00J 167.3 IN

i >300.00; -42.4!

1..00! 84.0!SOO-OO ! V7. 6 !

; i.l.O ,. OH.) J 91 .. 'J. ;e.O,30; 84 -2 !

i i

50 H 00 ! v6.6 <riOO,,OO ; S' .X!;5OO „ 0^ ! 9 ,'>.*? ;10O..OO-; :f'4<:..BiH

1 1 <... . ....™-.. ._». ._....— .™ 1 — .— — — — ™ ' ~

1.

-.-.,. *r 1O i

1

r :p :P'.' »p iHft ;P :*'' !< ' it:- i> tJIT '

NR !P ;

cv;p :NR ;F 1P !NR :t:' ;P !K !."• '

i.___ !

FORM V <PA:-t 1) - -IW

A R 1 0 1 6 3

u .. s - fc:i -A - CLI"'

sf EPA SANPLfc' rKJPOST DIGEST SPIKE SAMPLE RECOVERY "

L*b Maine s SOUTHWEST L( B OF OK , Con*.r*ft.s 6R -09-0039 I ..,.____ _

I <*b Code: :5WPK UAK» No.;: S^M SA'J Mo. a ' BOG HO-S WRWi Ri'

Mwvtr i x i WATER ! ,c*vel (luw/rnrwci ; u uQto

Con cc-nt ration Uni Ira* ucj/L

I Control! ; Lind t; wi'iuilxte J 5sR< i*...,,«,». „. •-* . ' __ „_ __.--....»-__

1 Aluminum !; Antimony ;! Arêri^ c Ii £i,\rium I: jtorylJ ium I, i^ j is l--Mt.ini LUlui r» . *i • (t win it I* it U rt 1 t

! Chromium .*! Cobalt I"opper ;T IT*!**? *< J, J (7* 1 i

! L©AOI MAgn&snuin!illAnqamece*I Mercury •1 hid ckfe*! ;! Pataa.g.ium!!St»l*nium iI Bi Ivoi- 1I cj .J 'i 2 «U U (L U i< i )

, Thc.iJ.1 i um {! VAn^diutn ;1 7.1 nc II Cyanide. i• .

ISpiked SAmplf*- ; S Ann pieR«-BU 1 1 ( SSR 5 C: ; i ie*"u 1 i C SR )

.-•-i— u vH — i-irt . «.i«~-«_.» ,« ' ...«...<-». - - .—— ,«— .

13801*. 00 ; '"' ; """"' " 47077 50J5O.oo ;u; '.rto.oo

1 11 Ii i1 11 1t 1f 11 1l r,' ',1 11 .1 «> 11 i1 1i rf 1I 11 tr 11 11 rI t1f1 1t f( 1

1 1« 1! 1

I1 I1 tI 1t 11 11 11 11 11

1f1 Sprite

C i Haded ifSAjii

„ .. L „ . _„ „..„ . . isf™.™. „„ , _ „.

1 ' 9400 „ 5u; i 2-0-0• ;

;>•iii•iir

i'

14

rti

l

t1 \lt

1t;!t1

1 1 t1I I! C

-. 1-' I (4 \ M; r

«. ™. .. _>.- -«« ™ i „, ' „__.9c>.7'| IF'o „ o ; ; p

; ;NP: : NR; INR1 ' Mf-1i rir*i t t r"11 4 f*H l

: : NR: ;NP. ; Nr|: IMf-1; ! NP:; INK:. ; NR; i NR• : NR; ; NR; ; Mr--

— ; INR1 ' Wf-'1 1 ~1 *

! 1 NR•: INR! I NR; : NR' 1

(Pvtrt 2} - IN

A R I O I 6 3 6

EPA SAflP'LE NO,

'i .ICATFB """ """ •"•"••""" ™

Lab Names SOUTHWEST LAB OF OK Contracts 6.S-D9-OOB9 „...„...„__.„.

L*n Codes SWOK " Case No-s 4&7t*l . iSAS N-j. . s , SDG Hi-.,,.: HRS

Matrix <«rf twr/soi 1) s WriTER " "Level < low/med 1 c I. > JUt

"•; Sol set** •for' 'SAinples" O*O r» ?JoIid«» for 3>upl i Crvl'e:; O

Con can t r & t i an Un i is*, c y.g .••' L o r rnq / l<g d r v ue i g h t )i:; t .JO ' L.

1

Aluminum ;Antimony !Aris-fcTj.i. c iBarium IBer v.ll ium [Cadmium fCa 1 c i u in ,Chromium ICobal t ICopper IT ran ' " 'Lead 1Htfonesium \

Mercury !Nickel Ir-'atciss ium i$«£ Ionium !feilver ;Sodium !Thai l_i urn IUanadiiifli I7inc !CyoTKi-de? i-.... ........ ..— ,™~- .. _ -. :

Control•Limit

—

1O,620O.O

SOOO.O

t-0 . 0

3OOOTO

3000 , O

1O.O5000-0

„ —... — ., — . — . —.— .

i! Sample

! 47O7; 30

. 30: 939' 1I *

1 4! 20193! WV1; fciv-! 17I :WOi;:2! 33< i i *-• 't jr ,L j. x_ .L *-i

it; 330; 49c-41 •«r -*.T "i 3! 135*471 'i r-1 .L *.-r ••••», .v.I 3331 i i4r •'• *t3i

i(S) ' C:

i-4AO4! !.OOOOIU!,&£50! !-(3796; ;.:s:i 3S!n;«31 !.0 1 & !-ISiO; ;.0103! I.78 i:i| ;„ 74 W ! H |. 3100J I,2000; 1(U' 0 ' '

" 1 7 3 ;' '-4000IUJ.6912! IB P^TijJO ! &«29so; B;. 40i!s l :.c-oôi ;. ooooiu :,oooo;ui*9tt2i * ;.7000 ', U !__ _ -= _ ^__. .1 ___ i

Duplicate

4 '364.30 *29.938.

1 -4 -

19736.88.;JQ -11,

274C21..48..

11O93-922 J ,

H

328-?iO7 f^ «

1.'! '"•''

13400.10..*'; •

34 .U16.

_ — „_.„.. ««..._....

31' l'i!OOOO ! UIS 50!1153!3124 IB7491 IB2 530!5SAA !49 &i !S7:l6 IB12OO;•?$tOv !S' AO '5830 I4OOO ! U4?79I6753 IOuOO ! iJ5840 I2 WO !oooo : uOOOO ! U3194 17000 I U

r_......-*_. t ....

' • ; !i . 1

1 1 I

! J .. 11. 1 1:': ; : p

; 5-31 ; ;Fi t f i i 1 1i .. i : •: ; Pi Q '3 " ' ' C-i 7 « , i i | r

! .<•; « r> [ t , P; .U4; ! IF! ;.:..:.s; : IP"; 4'L.%;> ; ; ;ri 1 ., H ! . i i'1'

& - "^ ' ' ' FI *l - i. I ! ', f'1'

! ! I CV• , , j .,-v

1 « . . ' ; i l 1

, .<L .. .J. , ) ( r

! 200.01 ! IF1 .:>.. ••;; ; :Pi -I I i ' ' ILi, ! « • . . , i Ii i i i:.~i ! i i 'i ' > ' ( . . •i i , i r, ..) K O i i i r*

i • • ' r1 1 1 ' *-•i 1 1 •! ,„. ,_._=;„...-, • i „ ' ——

-IN

bflR!OI637

L'.S.. EPA - CLP

7LABORATORY CONTROL «

L.«-*ta Names ÔUTHWEST LrtF* OF OK f;ar» I r«»rt s *8 »»9;-C/O8y

L«tb COCI»K SUJDK CA*e Ho,:: 4H751 OrV'i Nows ' SDG Ho

:;o1-irt I.H? Source;* ^

Aqueous. LCS Sources &.PA-LV

I Aq u ff ou » { ug / L > } Bo lid ( rrtcj / ky )! True ' Found W' ! f' ue Found C _ .--Limits

201O.O;An td rnony j l o to . O I 1033 . W \ 1O2- 3Arênl r : 47.4; 'J4-1?! 9o-^Barium ! 196O-6J 1929-121 98.4H&ry t 1 A..UH : 483. O ! 4Ft6 - .ii ; 1 00 - 8CAcJmium I Mfi.O; 403.65"; 9O.4{Calcium :4870O.O;4SG4R 59; 10O-SChromium I 310.01 526. 8?! 103. S

t I UO2-0; 4B».53 I ..7!' I 51S.OJ 504.24! 97.9

I X ran j £040 . O ! 1896 „ -Vt J 93 - C97-5! 99.O3; 3O1.6

^ -oOO » O I 2AOO3 . 33 ! 1O5 - 7W4 . o : 3O1 .951 99. 6

48O- 0 ! MO. 47 ! 104.. 5

: Se:i w ium ; TO. & ;• si.90: 99„ *JSJIvor ; 5OG-0! 486.931 97.4;Godium ;47600,0 JR0291.00 1101 * 4

I 97,O! 94.201 97.1

310O.O!

flRIOI638

VI L - TM7/se

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

WSTOMER NAME:

SAMPLE SOURCE:

SAMPLE TYPE:

DATE RECEIVED:

ANALYST:

SAMPLEEHRT NO.

313323135331374

3133531335313353134131356

K13561356o135631377313773137731377

,313803138031338313383135931359

313473134731368313683138931389

113656134431386

NO.

URS CONSULTANTS

Delaware Sand & Grave)

Quality Control

01-29-91

M. Copper & P. Ward

CUSTOMER NO.

AS-BK1AS-BK8AS-BK15

AS-BK2AS-BK2AS-BK2AS-BK4AS-BK9AS-BK9AS-BK9AS-BK9AS-BK16AS-BK16AS-BK16AS-BK16

AS-BK17AS-BK17AS-BK3AS-BK3AS-BK10AS-BK10

AS-BK6AS-BK6AS-BK13AS-BK13AS-BK20AS-BK20

AS-BK12AS-BK5AS-BK19

(Blank)(Spike)(Spike)

(Blank)(Blank)(Blank)(Blank)(Spike)(Spike)(Spike)(Spike)(Spike)(Spike)(Spike)(Spike)

(Blank)(Blank)(Spike)(Spike)(Spike)(Spike)

(Blank)(Blank)(Spike)(Spike)(Spike)(Spike)

(Blank)(Spike)(Spike)

(Prolect #35214)

PROJECT NO.: 12583

DATE ANALYZED:

LAB NOTEBOOK NO.:

ANALYSIS &METHOD

NIOSH Method 10031,2-DteWoroethane1 ,2-Dlchloroethane1 ,2-Dlchioroethane

NIOSH Method 1501Benzene

Ethyi benzeneTotal XyieneTolueneBenzene

Ethyi benzeneTotal XyieneTolueneBenzene

Ethyi benzeneTotal XyteneToluene

NtOSH Method 1300Methyl Ethyi Ketone

Methyl Isobutyi KetoneMethyl Ethyl Ketone

Methyl Isobutyt KetoneMethyl Ethyl Ketone

Methyl Isobutyl Ketone

NIOSH Method 5020Bis(2-Ethyl Hexyi)Phthalate

Di-N-Butyl PhthalateBls(2-Ethyi Hexyl)Phtnalate

DI-N-Butyf PhthafateBls(2-Ethyf Hexyl)Phthalate

Di-N-Butyi Phthalate

NIOSH Method 5503PCSPCBPCB

01-31/02-07-91

160. Pg.' 50

RESULTS(ug/FBter)

• '

< 2090.1% Spike Recovery91% Spike Recovery

< 15< 15< 22< 15

88% Spike Recovery88.1% Spike Recovery82.1% Spike Recovery90.3% Spike Recovery85.8% Spike Recovery84,3% Spike Recovery81 .6% Spike Recovery92.6% Spike Recovery

< 15< 15

93.9% Spike Recovery108.51% Spike Recovery91.77% Spike Recovery101.17% Spike Recovery

<20< 20

104.9% Spike Recovery98.8% Spike Recovery93.2% Spike Recovery93.2% Spike Recovery

<0.0596.9% Spike Recovery105.1% Spike Recovery

Ol639 J-0005GJ

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY .________

1 tI AS-BK7S I

Lab Name; ENVIR._HEALTH_RESEARCH_TE Contract: .URS_____ I___________I

Lab Code: WS8__ Case No.: 35214 SAS No. s 12583. SDG No.:

Matrix (soil/water): WATER Level (low/nmd):

Concentration Unit* (ug/L or mg/kg dry weight): US/L_

I i i1 1 Control 11 i Limit i1 Analyte 1 XR 11 1 1(Aluminum I i(Antimony 1 I1 Arsenic 175-125 J1 Barium 1 iIBerylliuml I1 Cadmium 175-125 1ICalcium 1 i1 Chromium 175-125 1i Cobalt 1 i1 Copper __ 1 75-125 J _1 Iron i 1ILead 175-125 1IMaanesiuml I1 Manganese t I1 Mercury i I1 Nickel 175-125 11 Pot ass ium 1 11 Selenium 175-125 1I Silver 1 11 Sodium 1 i1 Thai lium 1 i(Vanadium I 1IZinc 175-125 1(Cyanide 1 11 Tin 1 •

11

Spiked Sample 1Result (5SR) CI

11 11 1

332.0000 t 1i 11 1

920.7000 I I1 1

____ 924. 1888 J 1955.1000 1 1

_____ 1166. 0000 J I1 I

940.7000 1 11 1f 1i t

909.6800 1 tt 1

831.6080 1 11 11 1f il l

923.9000 1 I1 1

965.00 1 i

I 1 11 i

Sample 1 Spike 1Result <SR) ClAdded (SA) 1 *R

i iI 11 1

10- 1450IUI1 1i 1

1.8320IUII 1

____ 37. 6000I J_6.8300IUI

____ 98. 90001 J.1 1

16.0000IUI1 1t 11 1

12.0000IUI1 1

22.0270IUI1 I1 11 1f 1

22.7000I i1 1

20.0 IU 1

11

1800.01 83.211

1888.01 92.11

__ 1888. 0 1 __ 86. 61

__ 1888.8I_186.71

10dC.CH 94.1i11

1000.01 91.01

1000.0! 83.21111

__ 1888.81 __ 90.11

1000.0 I 97.0

I It I1 1

01 Ml1 tJNRIJNR!

IP 1.INRI~INR1

IP 1INRIJPJ

INRIJPJJNRIIP 1JNRIJNRiJNRI"iP 1INRIIP 1INRI

JNRI

"INRI.IP iJNRI

1 1

Comments:

FORH V (PflRT 1) - IN

A R I O I 6 l * 0

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY ___________

I II ASBK21S i

Lab Names ENVIR._HEALTH_RESEARCH_TE Contract: URS_____ I___________I

Lab Code: W88__ Case No. : 35214 SAS No. : 12583. SDG No.: 000000

Matrix (soil/water): WATER Level (low/med): ___

Concentration Units (ug/L or mg/kg dry weight): US/L_

1 1 1! 1 Control!i 1 Limit 1I Analyte i %R 1i I I(Aluminum 1 t1 Antimony 1 11 Arsenic I75-1£5 1(Barium I 11 Bervl i ium 1 1(Cadmium 175-125 11 Calcium 1 i1 Chromium J 75-125 J .1 Cobalt 1 l"(Copper 175-125 11 Iron 1 1i Lead ____ 1 75-125 J .IMaanesiuml t1 Manganese) 11 Mercury 1 1i Nickel __ 1 75-125 J.(Potassium! 1ISeleniumJ 75-125 J.1 Silver 1 1(Sodium 1 11 Thai lium t i(Vanadium 1 1I Zinc 175-125 1(Cyanide 1 I| Tin 1 |

11

Spiked Sample 1Result (SSR) CI

1t 11 1

804.6000 1 11 11 1

943.9000 1 11 1

____ 962.4000J 1986.2000 t 11149.0800 i 1

1 1975.4000 1 t

1 t1 11 1

____ 937.9000 1 11 I

____ 831.2888JJ1 11 11 1t 1

971.5088 1 11 I

858.70 | |

1 11

Sample 1 Spike 1Result <SR) CI Added (SA)

11 11 1

10. 1458IUI1 11 1

1.8320IUI1 1

____ 37. 6000I J_6.8300IUI98.98801 1

1 i____ 16.0080IUL

1 11 1t 1

____ 12.0000IU1_1 1

22.8270IUI1 1t 11 11 i

22.7000I 11 1

20.0 |U |

___1000. 0

1008.8

__ 1808.8

1800.0

___ 1000.0

__ 1888. 0

__ 1000.0

1 1 i1 1 11 t 1

*R IQI MlI 1 t1 INRI1 INRI

88.51 IP ii INRI1 INRI

94.4IJP 11 INRI

__ 92. 51 JPJ1 INRI

105.01 IP 11 INRI

__ 97. 51 JPJINRIINRIINRI

93.8 IP iINRI

__ 83.1 JPJINRIINRIINRiINRI

1888.81 94.9 IP 11 INRI

1000.0 | 86.0 | | i

Comments:

FORM V (PART 1) - IN 7/87f t R ! O I 6 l * l £-00056;;

3FSOiL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: Environmental Health Research & Testing, Inc.

Customer Name: URS CONSULTANTS

Project No.: 12728_______ Method No.: EPA 8080

Customer Sample No.: TC8-1/1200/45_____ EHRTNo.: 32205

COMPOUNDgamma-BHC (Lindane)HeptachkxAJdrinDieldrinEndrin4,4'-DDT

SPIKE ADDED(uo/ko)505050505050

SAMPLE CONC.(UQ/kfl)000000

MS CONC.(ua/ka)56.5563.3463.5459.1659.6459.82

MS%REC*111.6126.8127.09118.56119.29120.6

QC LIMITSREC.46-12735-13034-13231-13442-13923-134

COMPOUNDQtmma-BHC (Undine)HftptachtorAldrinDMdnnEndrin4,4'-DDT

SPIKE ADDED(ua/ka)505050505050

MSD CONC.(ua/ka)51.1758.8958.4953.4454.0155.04

MSD%REC*101.3116.8116.9107.09108

110.97

%RPD*9.997.288.2810.29.918.32

QCURPD503143384550

MITSREC.46-12735-13034-13231-13442-13923-134

# Column io be used to flag recovery and RPD values with an asterick


RPD: _____Q_____ out of 6 outside limitsSpike Recovery:_____0____ out of 12 outside limits

COMMENTS: ...-:


Lab Name: Environmental Health Research & Testing, Inc.

Customer Name: URS CONSULTANTS ___

Project No.: 12728________ Method No.: EPA 8080

Customer Sample No.: TBC-1/1800/45_____ EHRTNo.: 32211

COMPOUNDqamma-BHC (Lindane)HeptachlorAldrinDieldrinEndrin4,4'-DDT

SPIKE ADDED(ug/kg)505050505050

SAMPLE CONC.(ua/ka)000000

MS CONC.(ua/ka)52.9364.1362.1755.5456.7959.15

MS%REC*105.76128.28124.34111.3113.58119.25

QC LIMITSREC.46-12735-13034-13231-13442-13923-134

COMPOUNDaamma-BHC (Lindane)HeptachlorAldrinDieldrinEndrin4,4'-DDT

SPIKE ADDED(ua/ka)505050505050

MSD CONC.(ua/ka)48.0157,1455.0348.5949.7354.38

MSD%REC*91.97114.39110.0797.3799.46109.63

%RPD*9.7511.512.213.313.38.4

QCURPD503143384550

MITSREC.46-12735-13034-13231-13442-13923-134

# Column to be used to flag recovery and RPD values with an asterick


RPD: _____0____fc out of 6 outside limitsSpike Recovery: 0____m out of 12 outside limits

COMMENTS:

p , A-00056YPage 1 <V

A R I O I 6 I 4 3

-U.S. EPA - CLP

5B EPA SAMPLE NC .POST DIGEST SPIKE SAMPLE RECOVERY .———————————__

Lab Name: ENVIR. HEALTH RESEARCH TF. Contract: ras______ I___BC215

Lab Code: uaa Case No.: 3-740 SAS No.: 12728 SDG No.: QQOOOO

Matrix (soil/water): SOIL Level (low/med): ___

Concentration Units: ug/L

1 I I| | Control Ij j Limit I Spiked Sample1 Analyte | %R ] Result (SSR)! 1 i1 Aluminum 1 1] Antimony 1 1I Arsenic | 1 49.301 Barium j 11 Beryllium I 11 Cadmium I fI Calcium j |I Chromium 1 !I Cobalt 1 iI Copper i 1i Iron ] I1 Lead 1 |1 Magnesium! 11 Manganese! [1 Mercury I II Nickel I 1j Potassium! j(Selenium 1 j(Silver | 1j Sodium I i1 Thallium i 11 Vanadium I IIZinc 1 11 Cyanide | j1 1 1

CSample

Result (SR)

6.90

CSpike

Added (SA)

500.0

%R

84 _ a

...

..

Q

[

M

Comments :(AS) DILUTION VALUE; SAMPT.F HTTTTTFT^ 1:10 THEN SPTVFTI —— TOTAL HETAT.S ANALYSTS

32203

^ 6-OC05GSFORM \ 0 I 6**l 7/87

U.S. EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ,—————_______

1 TBC230Lab Name: ENVIR, HEALTH RESEARCH TF Contract: ITRS_____ I____

Lab Code: us a Case No.: 3-740 • SAS No.: 12728 SDG No.: 000000

Matrix (soil/water)r SOIL Level (low/raed): _____


11i1 Analytei} Aluminum| Antimony1 Arsenic1 Barium(Beryllium1 Cadmium1 CalciumI Chromium1 Cobalt1 CopperI IronI Lead1 MagnesiumI Manganese1 Mercury1 NickelI Potassium| Selenium1 SilverI SodiumI Thai lium1 VanadiumIZinc1 Cyanide1

Control :Limit%R

.


50.10

CSample

Result (SR)

8.6

CSpike

Added (SA)

50.0

%R

83.0

i

Q

111

M |1i11111ij11111i11I111I!11'

Comments:(AS) DILUTION VALUE: SAMPLE DILUTED 1:10 THEN SPIKED. TOTAL METALS ANALYSIS.

TBOI/12QQ/30__32204 ________________

0-000560FORM V pA- 01 61*5 7/S

-U.S. EPA - CLP

5B EPA SAMPLE NO.jrwoi u.i.V9£**3 x &r«Lric* 0/uifj t* *\**ww » A^^V* . • — - — — —— ™ — _ ——

I TBC245Lab Name: ENVIR. HEALTH RFSFARCH TF Contract: TJRS 1

Lab Code: Case No.: ;

Matrix (soil/water) : SOIL

J-74Q SAS No.:12728 SDG No. : 000000

Level (low/med) :


1 1 !j 1 Control i| | Limit | Spiked Sample| Analyte 1 %R 1 Result (SSR) Ct I 11 Aluminum 1 11 Antimony I !I Arsenic ! i 50.401 Barium ! i1 Beryllium! !} cadmium 1 I1 Calcium | 11 Chromium ! 11 Cobalt I I(Copper I 1llron i tI Lead I 1j Magnesium! 1(Manganese! I1 Mercury 1 1! Nickel [ |I Potassium! * 1I Selenium I 1(Silver j 1( Sodium 1 j(Thallium 1 I(Vanadium 1 1IZinc 1 11 Cyanide 1 11 i 1

—

—

SampleResult (SR)

2.20

C

u"

"«

~

-

SpikeAdded (SA)

50.0

%K

101

i11

Q! MIi

.1iiitiitiiiiiii!i11

1i11

Comments :(AS) DILUTION VALUE: SAMPLE DILUTED 1:10 THEN SPIKED. TOTAL METALS ANALYSIS.

TRr i n ?nn/Aswns

6-0005YOFORM V 7/87

.U.S. EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ,————————__

I TBC515Lab Names ENVIR. HEALTH RESEARCH TF Contract: URS_____ I_____Lab Code: yaa Case No.: 3-740 SAS No.: 12728 SOG No,: OOQOOQ

Matrix (soil/water) : SOIL Level (low/med) : ___


1111 Analytei(Aluminum| Antimony1 Arsenicj BariumJBerylirum1 Cadmium| Calcium1 Chromium1 Cobalt1 Copper(Iron!Le*d{Magnesium1 Manganesei MercuryI Nickel1 Potassium( SeleniumI Silverj Sodium(Thallium(vanadiumIZinc1 CyanideI

ControlLimit%R


5(5.30

c

m

SampleResult (SR)

2.9

CSpike

Added (SA)

SfKO

iii

%R IQi11

Q^.a 1I1I11!1i1!i 'I!1i11Ii1

._!i

M

Comments:(AS) DILUTION VALUE: "SAMPLE DILUTEE 1-20 THEM SPTEFTi.——TOTAL MFTAT.q ANATY<!Tq

32206

fr-00 (J5 7 iFORM V (PART 2 7/87

ARI016U7

,U.S. EPA - CLP

SB EPA SAMPLE NO.

1 TBC530 !Lab Name: EKVIR. HEALTH RESEARCH TT? Contract: TTRS 1 l

Lab Code: y Case No.:

Matrix (soil/water) : §gx^

5-740 SAS No. :12728 SDG No. : 000000

Level (low/med) :


1 1 i| | Control 1| | Limit | Spiked Sample| Analyte | %R | Result (SSR) C1 1 i1 Aluminum f i1 Antimony I I1 Arsenic 1 1 51.70j Barium 1 11 Beryllium 1 11 Cadmium [ II Calcium i I(Chromium I !1 Cobalt 1 I1 Copper | Illron 1 1I Lead I 11 Magnesium] 1(Manganese! i1 Mercury 1 • 11 Nickel I ij Potassium! I1 Selenium 1 I(Silver ! I1 Sodium 1 I(Thallium 1 Ij Vanadium ! !(Zinc | I( Cyanide 1 11 t 1

—

-

SampleResult (SR)

6.9

C

*

-

—

"

"

—

\Spike

Added (SA)

so.o

%R

89.6

Q

~

-

-

1I1

M i

t|111'it\\11|IiiiililIliii

Comments :fAS> DILUTION VALUE;. SAMPLE DILUTED 1:10 THEK SPIKED. TOTAL METALS. ANALYSTS ——

T-ar i /i srtn/^n32207

0-000572FORM V (PART 2) fl R | Q j 6 1*8

. U.S. EPA - CLP

5B ' EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ,———————______

I TBC545Lab Name: EXVIR. HEALTH RESEARCH TF. contract: URS_____ 1_____

Lab Code: uaa Case No.: 3-740 SAS No.: 12728 SDG No.: QOQQQO

Matrix (soil/water) : SOIL Level (low/med) : _____


i111 Analyte1| Aluminumj Antimonyt Arsenic1 Barium(Beryllium1 Cadmium| Calcium1 ChromiumI Cobalt1 Copper1 IronILead(Magnesium{ ManganeseI Mercury(Nickelj Potassium! Selenium(SilverI Sodium[Thallium(VanadiumIZinc( Cyanide1

1ControlLimit*R

.'Spiked SampleResult (SSR)

48.00

.

cSanpl*

Result (SR)

4.90

1_.c

SpikeAdded (SA)

sn n

%R

a*, 7

.

Q

„

M

Comments :/^ nTTTTTTAM VAT.TTFt ——— QAMPT_g HTT TTTPH 1.10 THFM gPTVFD ——— TOTAT, MFTAT S flNflT

TBC-1/15QO/45•322DT

000573FORKV (PART 2) - A R I 0 i 6 U 9

- CLP :

5B EPA SfiMPLE NC.POST DIGEST SPIKE SflMPLE RECOVERY ____

I TBC31'N*m«: £N\;lR._HEflLTH_RESEflRCHjTE Contract: URS_____ i ._-... _

Lab Cxie: iJSe__ JC*w No.: 3-748 SnS No.: 1£7£8_ SDG. No. : -3000130

fla'Sri- iBc:I.**are»-! : SGIL_ Level (loW

Concentration Units: ug/L ug/L

i : i i i i; 1 Control! i 1 I

i Limit t Spiked Sample E Sample 1 Spike 1lfln*lyte I *R i Result (SSR) CI Result CSR) Clftdded <SA) It i l 1 1 1IRluwimiia i f I 1 I I 1Iflntuoony I I f 1 I I 1iflrsenic i 1 47. £13 1 1 £.£& IUI 50.911 Barium I I I I i t 1iBerylliural I 1 ! I I 1ICadroium 1 1 i 1 I I iICalciurn 1 1 1 i _ i I 11 Chromium I I I I 1 i 1ICobalt I I 1 1 I I iICoDoer 1 1 I I I I 11 Iron 1 1 I I I f 1ILead I I I I I I 1IMaonesium! 1 I I I I 1IM-naaneiel ! I I I I 1i Mercury I I t f I t 1INicksl 1 i I I I I I1 Pot ass i urn 1 1 i 1 11 1

i Selenium ! ! 1 i I I I1 Silver 1 I ' l l I I 11 S o d i u m I 1 I I I I IIThalliura I I I I I I I1 Vanadium 1 ! 11 1 1 1iZinc 1 1 I I . I I 11 Cyanide 1 1 I I I I 1i 1 1 I I f 1 1

1 1 i1 1 , !1 I 1

%R IQI Ml1 ! 11 I N R I1 i NR 1

94. H| IF 11 J N R I1 INR!! INRI1 I N R l1 INRI1 INRI1 I N R I1 INRI1 I N R I1 INR!i I NRI1 INR!1 I N R Ii INRI1 I N R I! INRI

1 I N R I1 INRI

1 INRI1 I N R II 1 1i 1 1

Comment s:<flS> DILUTIQN_VflLUEs_Sft«PLE DILUTED_1: i0_THEN_SPIKEDTBC-l/1800/15

TOTflL METflLS ftNflLYSIS

FORM V CPflRT £) - IN 7/87

ARIOI65[£OG0574

- U.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY .——————————__

~ +. TBC830Lab Name: ENVIR. HEALTH RKSFA'srH TE Contract: TRR_____ i______

Lab Code: waft Case No.: 3-740 SAS No.: 12728 SDG No.: 000000

Matrix (soil/water): grm Level (low/med): ___


i ^ 11 " 1i1 Analyte1| Aluminum| Antimony1 Arsenic1 Barium(Beryllium1 Cadmiumj Calciumj Chromium1 Cobalt1 Copper1 IronILe.d1 Magnesium| Manganese1 Mercury1 Nickel1 Potassium| Selenium[Silver1 Sodium1 Thai liumj VanadiumIZinc1 Cyanidet

ControlLimit%R

•


51.10

9.60

19.2 .

-J

C

i -•*"»: --, . - • .33?«Us.

SampleResult (SR)

a in

9.60

2.14 -

~3*w=i

C

B

«.

'•-'Spike

Added (SA)

50.0

?n.n

20.0

'

%R

fiS.60

104.5

96.0

Q M

i

Comments:m*m- .l HV4- -l.i-.LJ ,1 1-1 - _i tJ i «i. -..i-t |f||-i||r ............... ... - —————— •

T-RC } 1

322101800/3Q —————— - ———————————————————————————————————————— • ——————

6-000575FORM V (PART : fiR j 0 | 65 I 7/8?

U.S. EPA - CLP

5fl EPA SAMPLE NO..SPIKE SAMPLE RECOVERY

Lab NAM«I ENVIR. HEALTH RESEARCH IE C

_ab Code: U88 __ Caie No.: 3-740

Matrix (soil/water): SOIL_

Concentration Units (ug/L or

I I I t1 IControll 11 1 Limit I Spiked Sample i! Analyte 1 *R t Result (SSR) CI Ril i t 1( Aluminum 1 1 1 1 '(Antimony I I 1 11 Arsenic 175-125 1 39.9612 I 1! Bar ium 175-125 1 87.3327 1 1IBervlliutwl l 1 1 ....1 Cadmium 175-125 ! 45,8390 1 1(Calcium 1 1 I Ii Chromium 175-125 I 44.3938 I 11 Cobalt 1 1 I I1 Copper I I I Illron 1 1 . 1 1(Lead 175-125 1 49.2726 1 1IMaanssiuml 1 1 1IManqanese! t I 11 Mercury 175-125 1 1.2233 I 1(Nickel 1 . i 1 1(Potassium! 1 1 11 Selenium t 1 I I1 Silver (75-1S5 1 43.5596 1 1i Sodium 1 1 I I[Thallium 1 1 I I

i : i1 TSC845S i

ontract: URS I 1

SAS No. : 12728_ SDG No. : 000000

Level (low/med): ___

mg/kg dry weight): MG/KG

i 1 1 i !1 • 1 i l l

Sample 1 Spike 1 I I I>sult (SR) C [Added (SO) I %R IQI Ml

1 i i l lI I I I INRII I 1 1 I NRI

0.5432IBI 48.5! 81.31 IF 134.64601 1 43.51 108.61 IP I

1 1 1 1 I NRI0.4850IUI 48.51 94.51 IP t

I I 1 1 INRI3.88941 1 48.51 83.51 IP 1

I I i I I N RfI I 1 1 INRII I 1 i INRI

0.52381 1 48.51 100.51 IF 1( I 1 I INRII I I 1 (NR1

0.0244IUI 1.21 100.81 ICVI1 1 1 1 I NRII t 1 ! INR!I I i ( 1 ) i INRI

0.4850IU1 48. 5 1 89. SI IP !I I f I I NRI( I I I I N R

(Vanadium I I I I I t I I INRIIZinc 1 1 1 1(Cyanide 1 1 1 I1 1 1 I I

I I I I I N RI t I I I N RI I I i I

Comments:TBC-1/ 1803/453E211TOTAL METALS ANALYSIS

1. Sample was spiked, digested and analyzed. 5 times to determine aSpike Recovery because of the matrix problem the spikes were not reproducible:(1) W\ (2) 50% (3) 68% (M 61% (5) 61%

FORM V (PART 1) - TW _ 7/87

A R I D

U.S. EPfi - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ___ ______

1 TBC845Lab va e: ENVIR. _HEfiLTH_RESEflRCH_TE Contract: URS_____ I________

Lad C:.Je: U68__ Case No.: 3-743 3AS No.: l£7£fl_ SDG No.: 000000

Matrix s-:: I/water* s SOIL Level (leu


i l l . ! t ii _ iControll 1 i ^ 11 1 Limit 1 Spiked Sample 1 Sample I Spike 11 A*alytr~ 1 " ?-R 1 Result TSSR) CI Result <SR) C Ifldded tSfl) 1] ^ ../ - r r —*t;"!". "^ " ""' •" -* -*-r- -•—'-{ ----- -**>*. _»«,•=-..=£ .,.- . * • -,i {-_-Iftluminum ! ! "' ' •" - ~~t--| —— -- -,---—— j { j(Antimony 1 ' 1 I f I I 11 Arsenic ! . _ . 1 I I I I 1

1 B a r i u m I I 1 ! 1 1 1IBervlliuml 1 I I I f 1(Cadmium 1 1 t 1 I I I[Calcium I 1 I f " " f 1 1

l Chromium ( I I I I t 1f Cobalt I I I I ( 1 (ICoDoer I I 1 1 ! I 11 Iron 1 1 I t I I 1ILead I I 1 1 ( t 1IMaanesiuml 1 1 1 I I !

1 Manganese i 1 I I f 1 11 Mercury I I I I I t !INickel I I 1 1 I I 1IPotassiuml 1 i 1 I t !! Selenium 1 1 £0.70 f 1 £.14 lUt £0.®ll Silver I 1 ( i I I 1

i Sod ium i 1 1 I 11 I(Thallium i 1 t 1 I f 1

1 Vanadium I I I I f 1 ' 1iZinc I I t 1 1 1 1(Cyanide 1 1 1 i I I t

i 1 :' 1 ! i

1 !%R IQI I"U

I I 11 INR!1 I N R i1 I N R I

1 I N R It INR!1 [NRI1 INRI1 INRII IMP'

t INPit INRIi I N R I1 I NRI

1 I N R I1 I NRt1 INRI1 I N R l

103.51 IP i1 INPI1 INR!1 I N R i

1 I N R i! I N R It 1 . i

Comments:TBC-i/1300/4532211TOTAL METftLS ANALYSIS

FORM V (PART £)

B R I O I 6 5 3

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY _^___ ___

I TBC845SLsb Mam*: ENVIR._HEALTH_RESEARCH-TE Contract: URS_____ i________

C:-dts U88__ Came No. : 3-740 SAS No. : 1£728_ SDG No. : 000000

Matrix is:.-. 1'water i : WATER Level (low/med) : __^

Concentration" Units (ug/L or mg/kg dry weight): US/L_

I 1 1 i 1 1...I 1 Control I i 1 L1 1 Limit i Spiked Sample t Sample t Spike 1lAnalyte 1 *R 1 Result (SSR) CI Result (SR) CtAdded (SA) tI t ! 1 I I

*R

(Aluminum 1 1 I I - I I 1(Antimony 1 I •1 Arsenic *175-125 1i Bar ium (75-125 11 Beryllium! 1ICadauum 175-125 11 Calcium 1 11 Chromium 175-125 I1 Cobalt 1 IICoDoer I (I Iron I !ILead 175-125 IIMaanesiuml tIManaanesel !t Mercury 175-125 11 Nickel 1 1I Potassium! !1 Selenium »l 75-125 (1 Silver (75-125 Ii Sod i ura l 1! Thai Hum 1 1(Vanadium 1 11 Zinc 1 I1 Cyanide 1 1

1 168.3000 i 1805.9000 1 t

. . i t497,5000 1 1

1 1463.8000 1 i

f i.i tl i

508.5000 i 11 t

1 14.6800 1 !

I 11 t

17.2000 1 1485.9000 1 t

1 I1 1

i t1 11 1

1 I£5.30001 1

310.00001 11 t

5.00001U!1 1

6.5000fUi1 1t 11 1

11.6000IUI1 11 1

0. 10001 Ul1 t1 1

2. 1420IU15.0000(UI

1 1f 11 11 11 1

1.50.01

500. 0 11

500. 0 11

500. 0 i1t1

500. 0 11

i5.01

11

20.01500.01

i1t11

36.099.2

99.5

92.8

101.7

93.6

86.097.2

i

1

11 1 1 1 1 I I t

NRII INRIIJFJ1 JPJI JNRII JPJI JNRl1 JPJI JNRIi I N R I

INRIIPJI N R I

I JNRIIJCVI[JNRII JNRI

i "IF ii JPJI J.NRII JNRII JNRII JNRII JNRI1 I i

Comments:TBC-1/1800/4532211_____~TCLP METALS ANALYSIS

FORM V (PART 1) - IN 7/87

(3-000573

- U.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY .———————.————

Lab Name: ENVTK. HFAT.TW pygpAoru TF Contract: URS______ I TTC215

Lab Code: W88 Case No.: 3-740 SAS No.: 12728 SDG No.: QQQQQQ

Matrix (soil/water) : SOIL Level (low/med): _____

1 - -11 " "1I Analyte11 Aluminumj Antimony1 Arsenic1 BariumI Beryllium1 Cadmiumj Calciumj Chromium1 Cobalt1 Copper.llronILeadt Magnesium1 Manganese! Mercury1 Nickelf Potassium| SeleniumI SilverI Sodium| Thalliumj VanadiumI ZincI Cyanidei

k-ControlLimit%R


52.70

34.20

_17,40

~

c

—— --.___,-„._

~" SampleResult (SR)

4.0

12.5

9 1 L

CSpike

Added (SA)

so.o

20.0

20.0

%R

25.4

108.5

87.0

Q

W

i

M

Comments:

URS# TTC-1/1 200/1 S

SAMPT.B nTLlTTED 1 - i n THEN SPTITim ———————

FHRT# 3?194

FORMV A R 1 0 I 6 S- i5 7/87ft-00057'

U.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY __._

\ TTC215 ILab Namt: ENVIR.J€flLTH_RESEftRCH_TE Contract: URS_____ I___________I

Lab Code: W88__ Casm No.: 3-740 SflS No.: 127£8_ SDG_No. : 0001300

Matrix dci1/water)E WATER Level (low/med): ___


i t t 11 1 Control! 11 I Limit 1 Spiked Sample 11 Analyte t *R 1 Recult (SSR) Ci) t I 1I Aluminum I I I I1 Antimony I 1 1 11 Arsenic 1 1 48. 40 1 11 Barium I t I f1 Beryllium! t I 11 Cadmium I f 1 1(Calcium l i I f1 Chromium I t 1 11 Cobalt 1 i 1 1ICopoer I I 1 !1 Iron 1 i I IILtad I t I IiMannesiuml I t 11 Manganese! 1 t 11 Mercury ! 1 f t(Nickel t 1 I IIPotasiiuml t 11 Selenium 1 I l*r. !•% 1 1ISilver 1 II S o d i u m 1 1 i l

1 t 1 1 11 1 i l l

Sample 1 Spike 1 1 1 1Result (SR) Clfldded (SA) I %R IQI Ml

1 1 I I II I 1 1 INRI1 1 i i INRI

£.£0 iUl 50.01 36. SI IF 11 1 t ! INR!i 1 t 1 INRI

1 ! 1 i INRIt i 1 1 INR!I I I i INRI1 1 1 1 INRII I i i iNRI1 ! 1 1 INRI! 1 t 1 INRII t t 1 INRI

I 1 1 ^1: I f • INP.1 1 ! 1 iNRI1 i i 1 INRI

:' ••+ IUi £0.01 S&.5! IF I. 1 1 ! INRI

I 1 ! ; INR.

hall i u m 1 ( I I I IVanadium 1 1 1 I | 1 IN R iin-- i . - - i 1 i INRIICya- •» t 1 I ' 1 I I ?

Comments:TTC-i/l£00/15

TCLP fr -.^ flNfiL

FORM V (PART £) - TN 7/87

A R I D 1656 0-000500

5B EPA SAMPLiE3QST DISE5T SPIKE SAMPLE RECOVERY

__ " £PS No.: l£?28_ SDG No.:

_ -..-•-..- Level (low/med) :

C or cent rat i on Lr. 115: u g .' L ug / L

: ! i ; 1 1'• ! Control ! I i . 1

i 1 Limit 1 SpiUed Sample 1 Sample 1 Spiê !'Qr-.slyte- i %R i Result (SSR) CI Result (SR) CIAdded (Sfi) 1

• i ' I 1 1 1Iftlaminum 1 i i 1 i 1 f

l Antimony i 1 1 ! I I i1 Arsenic i 1 49.50 1 i £.20 IU! 50.0!

1 B a r i u m I I 1 - 1 1 1 1IBe^vlliuml 1 1 i I I 1! Cadmium 1 1 1 1 t 1 11 Calcium 1 1 I I - I I t

1 Chromium 1 1 I I I I 1ICoQalt I I I I . 1 1 t

1 Copper I I t 1 I I 1llron t i 1 1 I I fILead 1 1 I I I I 1IMannesiuml S I t 1 1 1IMarqanesel 1 I I I I 1I Mercury t I I t I I IINickel 1 I 1 1 1 1 11 Potassium! t I I I I i

1 Selenium I t I t I I 1ISilver t M 1 1 1 i 1 .

l Sodium I I I I 1 i I1 Thai lium 1 1 I t I I i

1 Vanadium I t 1 1 I I 1IZinc 1 1 I t I I 1

i !i ! li 1 1

*R IQl Mli i E"INRI

I INRi99.01 IF 1

I INRI1 INR!1 INRI

____ ! JNRIi "INR'I1 INRI1 INR!1 INRI

1 INRI1 INRI

i I N R I1 I N R I

i I NRI1 INRI

1 I N R i1 INRII INRI1 i N R I1 INRI1 INRI

1 Cyanide I 1 I I I I t 1 1 1! I I I 1 1 f f i l l

Comment s 3(AS) DILUTION VALUE :_D I LUTED Is 10 THE_SPIKED.TTC-1/1200/30_____________________________32195_______TOTAL .METALS_ANALYSIS.

FORM V (PART £) - IN 7/87.

A R I O I 6 5 7 fe'°C05Si

JJ.S. EPA - CLP

SB EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ,—————————____

Lab Name: ENVIR. HEALTH RESEARCH TE Contract: ims_____ 1 TTC245

Lab Code: uaa Case No.: 3-740 SAS.No.: 12728 SDG No,: QOQOOO

Matrix (soil/water): SOIL Level (low/med):


1 i 1j j Control 1| j Limit I Spiked Sample| Analyte | %R 1 Result (SSE)1 ! I1 Aluminum I Ii Antimony i 11 Arsenic 1 I ^ 7ni Barium 1 i1 Beryllium! 11 Cadmium 1 jI Calcium I 11 Chromium 1 !1 Cobalt i 11 CctePer 1 1llron I I1 Lead I 1I Magnesium 1 1(Manganese! iI Mercury i • 1(Nickel I 11 Potassium I Ij Selenium 1 1tsilver 1 1j Sodium 1 1(Thallium 1 11 Vanadium t 1IZinc i 11 cyanide i 11 ! I

CSample

Result (SR)

6.2

CSpike

Added (SA)

50.0

*R

.

95.0

Q

i!1

M li1iii[

i1I1I1iii111i!111!

Comments:(AS) DILUTION VALUE: SAMPLE DILUTED 1:10 THEN SPIKED. TOTAL MP,T*T-fi AWAT.YSTS

"""TTC-I/ 1200/4532196 ___________________________

FORM V (PART 2)-lflR|0|658

*U,S. EPA - CLP

5B EPA .SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ,_———————————

Lab Name: ENVIR. HEALTH RESEARCH TR Contract: jmo_____ j FTC515

Lab Code: was Case No,: 3-740 SAS No.: 12728 SDG No.: OQQQOO

Matrix (soil/water) : SOTT. Level (low/med) : ___


11i1 Analyte1| Aluminum| Antimony1 Arsenic1 Bariumj Beryllium1 Cadmiumj Calcium| Chromium1 Cobalt1 CcpperllronI Lead1 Magnesium(ManganeseI MercuryI Nickel(Potassium1 Seleniumt Silver1 Sodiumj Thai liumI Vanadium"IZinc1 Cyanide1

ControlLimit*R

...


53.70

CSample

Result (SR)

2.7

CSpike

Added (SA)

50.0

%R

102.0

.

Q

,

M

Comments:

rrr-i /T-.AQ/I32197

L5 —— . ———————————————————————————————————————————————————

FORM V (PART 2 A R i 0 I 6 5 9 7/8?

*U.S. EPA - CLP

SB EPA SAMPLE NO.

I TTC530Lab Name: ESVIR, HEALTH RESEARCH TE Contract: URS 1.

Lab Code: y^8 Case No.:

Matrix (soil/water) : SOIL

3-740 SAS No. :12728 SDG No. : 000000

Level (low/med) :


1 1 11 j Control i1 j Limit j Spiked Sample| Analyte [ %R 1 Result (SSR)1 t 1(Aluminum 1 i(Antimony I i1 Arsenic 1 i svon1 Barium [ 1I Beryllium! II Cadmium j |I Calcium j j1 Chromium ! !1 Cobalt 1 (1 Copper I |llron I 1! Lead ( ij Magnesium! j1 Manganese 1 )(Mercury 1 1(Nickel I (1 Potassium] * i(Selenium 1 1ISilver I !1 Sodium ! I(Thallium 1 i(Vanadium 1 iI Zinc I (1 Cyanide I I1 1 I

Comments :fAS> DTLUTTON 'V&T.TTF? gAMPT.f *nTf ; yf _L —————————————————————————————— _..

C

~

—

—

_

_

SampleResult (SR)

5.0

C

*~

~

•CT-, 1:10 THEN SPIKED.

SpikeAdded (SA)

50.0

%R

97.8

Q

"

1

1M |

11i

THTAT METALS ANALYSTS

TTC-1/1500/3032198

&OOQ584FORM V (PART 2) - I«A R I 0 I 6 6 0 7/87

U. 5. EPS .- CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ___________

i TTC545Lab Name: ENVIR* _HEftLTH_RE5E3RCH_7E Contract": URS_____ ! ________

Cods: wS3__ Case No. : 2-7- 3 SfiS No. : 127£8_ SDG No. :

'-i-^ = : i '; •<*. airs:'; :-.uCI-_ . " " :/. "".._" .Level (low/med):

C:<r,ceritration Units: ug/L ug/L

1 1 1 1 I II (Control ! t • f i! i Limit 1 Spiked Sample t Sample 1 Spike 1lAnaiyts ! %R \ Result CSSR) CI Result CSR) ClAdded (SA) I

1 ' ! 1 ! 1 1: Aluminum i f i - 1 I I Iiflyitimoriv 1 i ' I I 1 1 ii flr-sentc I i 51.30 1 1 2.20 tUi 50.131

1 Barium I t 1 i t 1 1IBervlliuwl i I I i t i

i Cadmium 1 1 1 1 1 1 1! Calcium i t I t I I 1(Chromium ( 1 I I I I 1i Cobalt I I ' I I I i 1ICoooer I . I I I I t Iilron I I I I I I 1(Lead 1 1 I I I I !IMaanesiumi I t 1 t i 1'Manpanesel 1 I I I I ti Mercury 1 1 1 1 1 1 tINickel 1 1 I I 1 1 !! P o t a s s ium! ! 1 1 I f t(Selenium i t I I ' 1 1 ti Silver 1 1 I I t i 1

1 Sodium 1 i I I 1 , 1 1i Thai lium I t t 1 f ! 1

1 Vanadium I f I t 1 i t(Zinc I I t 1 I f 1IC/anide I I 1 1 I I i

1 i i1 ! '\ { \

%R IQI Mi1 ! 11 INR;t iNR!

103.6! IF f1 I N R Ii I N R II INRIi INRI1 INRI1 INR!

1 I N R I1 I N R It INRI! INRI

i INRI1 INRI

i I N R Ii INRI

1 INRI1 INRI

1 I N R I1 I N R I1 INRIE INRI

i 1 11 ( 1 E l i t 1 1 1 1

Comments:(flS) DILUTIDN_VfiLUE:_SAMPLEjnLUTED 1:10_THEN_SPIKED.TTC-1/1500/45_________________________________32199 ___ _________TOTAL METALS ANALYSIS

FORM V (PORT £) - IN 7/87

A R I O I 6 6 1

.U.S. EPA - CLP

5B . EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ..——————______

Lab Name: EXVIR. HEALTH RESEARCH TE Contract: I-RS_____ |_TTC815

Lab Code: ua a Case No.: 3-740 SAS No.: 12728 SDG No.: OQQQQQ

Matrix (soil/water): SOTL Level (low/med): _____


I I I1 i Control ]I j Limit I Spiked Sample| Analyte 1 %R | Result (SSR)1 1 11 Aluminum 1 |1 Antimony 1 iI Arsenic I | 53.4t Barium I iI Beryllium I 1j Cadmium j II Calcium j f1 Chromium I i! Cobalt i |I Copper I |1 Iron I [ILe*d | I1 Magnesium! |1 Manganese] |1 Mercury I 1i Nickel i 1I Potassium! 1I Selenium | 1ISilver i Ij Sodium 1 ![Thallium 1 |I Vanadium j 1(Zinc I i(Cyanide I |.1 1 I

CSample

Result (SR)

7.1

. .

CSpike

Added (SA)

50.0

11i*R 1Q

i1I

92.6 IiI1111i!11111ii1!1i111

I

M |1

!1IAJt

1

Comments:(AS) DILUTION VALUE: SAMPLE DILUTED 1:10 THEN SPIKED. TOTAL METALS ANALYSIS.

TTC-J/180Q/1532200 ____________________

6-OOOSSi,FORM V (PART 2 A R [ Q I 6 6 2

' U.S, EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY ,-—————.———————

TTC630Lab Name: ENVIR...HEALTH RESEARCH TF Contract: URQ_____ i,______

Lab Code: _jas Case No.: 3-740 SAS No.: 12728 SDG No.: 000.000.

Matrix (soil/water): SOIL - -- - Level (low/med): _____


Ii!i Analyte1| Aluminum| Antimony1 ArsenicI Barium(Beryllium1 Cadmium1 Calcium1 ChromiumI Cobalti CcpperilronILeadj Magnesium| Manganese1 Mercuryi Nickelj Potassium| SeleniumISilverj Sodium[Thalliumj VanadiumIZinc1 Cyanide1

ControlLimit%R


b4.50

,

CSample

Result (SR)

iQ.n

CSpike

Added (SA)

50.0

1 11 !1 1

%R IQi M1 I1 11 1

85.8 I 11 !! 1i 11 1! i1 1i 11 11 11 !

. i ii ! '! !1 !1 1 '1 1 :i i1 11 11 11 11 ._ I

Comments:

TT01/ 1800/10 ———————————————32201

s O 005 3. VFORMV (PART 2) AR 101663 ""* '

, U.S. EPA - CLP

SB ' EPA SAMPLE KC.

~ _ ! TTC845ALab Name: ESVIR. HEALTH RESEARCH TF Contract: URS 1

Lab Code: ysf. Case No.: 3-740 SAS No.: 12728 SDG No.: 000000

Matrix (soil/water) : SOIL Level (low/med) :


t 1 1j | Control.!| | Limit 1 Spiked Sample| Analyte I %R 1 Result (SSR)1 ! 11 Aluminum 1 i1 Antimony 1 11 Arsenic 1 | 67.?n1 Barium 1 I1 Beryllium I 11 Cadmium { 1I Calcium j \I Chromium i 11 Cobalt I I1 Copper I II Iron I I]Le*d j i 45.9i Magnesium! j(Manganese! I1 Mercury I . |I Nickel [ I! Potassium! j(Selenium I 1 19.40ISilver i |1 Sodium | 1! Thallium I I1 Vanadium j I(Zinc i 1I Cyanide 1 1I 1 i

C

*••

SampleResult (SR) C

23.4

24.fi

2.14

-

~

—

-

-

SpikeAdded (SA)

50.0

20.0

20,0

%R

8 8. .6

106.5

97.0

1 1! 1I |

Ql M I1!

.1 11

.111 |1 J1jii11 I! 1! !1 11 1

.1J! !

1i 11 Lt I1 1

t

Comments :(AS.) DILUTED VALUE: SAMPLE DILUTES 1:4 THEN' SPIKES-' THTAT METALS AMLIS1S. —————(PB) DILUTED VALUE; SAMPLE DILUTED. I;4Q THEN SPIKEP- ————————— —

URS* rrc-1/1800/45 EHRTff 32202

•0^00583FORM V (PART 2) -Afl 101664 7'''s '

U.S. EPA - CLP

5B EPA SAMPLE NO.

~ *. *. ! TTC845Lab Name: EXVIR. HEALTH RESEARCH TE Contract: URS 1 iLab Code: waa

Matrix (soil/water)

Case No.: 3-740 SAS No.:

: SOIL

12728 SDG No. : OOOODO

Level (low/med) :


11iI Analyte1(Aluminum| Antimony1 Arsenic| Barium| Beryl liumI CadmiumI Calcium1 Chromium! CobaltI Cc/pperI Iron(Lead| Magnesium1 Manganese! MercuryI Nickel| Potassiumj Seleniumj Silver1 Sodium(Thallium(vanadium1 Zinc( cyanide1

ControlLimit%R

Spiked SampleResult (SSR) C

66,30

SampleResult (SR)

21.7

C

"

"

-

SpikeAdded (SA)

50.0

*R

89.2

Q M

1!111

Comments :(AS) DILUTION VALUE: SAMPLE DILUTED 1:4 THEN SPIKED. TOTAT. MFTAT c ANALYSTS.

XTC-l/IROn/AS32202 B - • -

FORM V (PART 2) T ft R ] Q | fi 6 S /&?

U.3. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY ___ .

I TTC845SLib N«MII EN'vIR. J-iEALTHJ-JESEARCHJFE Contract: URS_____ I_________

Lub Cede i MSB__ .___.. Case No. : 3-740 SAS No.: 1£728_ SDG No.:

Matrix ;i.:il/&*aterj t WATER Level (low/med):

Concentration Units (ug/L or rng/kg dry weight): U6/L_

I l l 1 1 11 1 Control 1 _ L 1 . . 1 .1 t Limit l Spiked Sample 1 Sample 1 Spike 1lAnalytg 1 *R 1 Result (SSR) CI Result <SR) ClAdded (SA) 1I I I 1 I fI Aluminum 1 !1 Antimony I 11 Arsenic * 175-125 11 Barium 175-125 1IBervlliuml 11 Cadmium 175-125 1iCalcium i 11 Chromium 175-125 1ICobalt I 11 Cooper 1 11 Iron I lILead 175-125 1IMaanesiuml 1

1 Manganese! Ii Mercury 175-125 1INickel i 1(Potassium) 1J Sel em um*I 75-125 1i Silver 175-125 11 Sod i um t 11 Thai Hum l I1 Vanadium 1 IIZinc 1 11 Cyanide t I1 I I

1 11 1

43.4000 1 1617.3000 t 1

1 1439.3000 1 1

1 1 •455.0000 1 1

' 1 11 11 I

502.4000 1 11 I

1 14.9100 1 1

1 i1 1

17.0000 1 1449.8000 1 1

1 11 I

1 11 1

I 11 1

1 11 1

4. 60001 Bl123.2000IBI

1 15. 00001 Ul

1 16. 50001 Ul

1 t1 11 1

13.00001 11 11 1

0. 10001UI1 i1 1

2. 1420IUI5. 00001111

1 11 11 11 11 11 I

11

50.01500. 0 1

1500.01

1500. 0 1

I11

500. 0 11

15.01

11

20.01500.01

1111

11

*R

87.93.

97.

91.

97.

98.

85.90.

1 1 11 1 i1 1 I101 Ml

1 1 E1 INRI1 INRI

61 IF 181 IP f

t I N RI91 IP 1

t INRI01 IP 1

i INRI1 INRI1 INRI

91 IP 1f INRI

1 I N RI2! ICV!

1 I N R I1 INRI

01 IF 101 IP 1

1 INRI1 INRI1 INRI1 iNRI

f INRI1 1 I

Comments:TTC-1/1800/4532E02TCLP METALS ANALYSIS

^

FORM V (PART 1) - IN 7/87

flRJO!666 A,

STAGE 1

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