27
1 dgV 2dgV SOLUTIONS TO IRP FULL TEST-1 ONLINE (HELD ON 3 RD , 4 TH , 5 TH MAY 2018) PHYSICS (PAPER-1) SECTION 1: 1. A block is given some horizontal speed at point A of frictionless heavy track as shown in figure. Block breaks off the track at B and strikes horizontal track at point C. Height of point A is 15m and speeds at points A, B and C are in ratio 1:2:2. If height of B above ground is h and speed at C is u, then value of 2 u 2h is- (A) 8 m/s 2 (B) 20 m/s 2 (C) 8 m/s 2 (D) 8 m/s 2 Solution (B): A B C v :v :v ::1: 2:2 A B C KE :KE :KE ::1:2:4 A B KE mg 15 KE mgh A B 2KE KE A KE mg(15 h) A C KE mg15 KE A A KE 15mg 4KE A KE 5mg A C 4KE KE 20mg 2 1 mu 20mg 2 B KE 10mg mg.h =10mg h 10 2 2 u 20m/s 2h 2. Twelve rods of mass m and length are rigidly joined as edges (sides) of a cube. Moment of inertia of the cube about a face diagonal is- (A) 2 13 .m 5 (B) 2 23 .m 3 (C) 2 41 .m 5 (D) 2 31 .m 3 Solution (B): 2 2 2 2 2 mL 1 mL mL mL I 4 2 2 3 3 12 2 2 2 2 2 mL 1 4 4mL 3 2 2 23m 3 3. A conductor having cross section A = 1mm 2 is carrying I=1.0A current. The linear momentum of electrons in unit length of conductor is 9×10 -N . Value of N is- (A) 3.2×10 -17 N-s (B) 5.7×10 -19 N-s (C) 9.1×10 -25 N-s (D) 2.9×10 -27 N-s Solution (B): d I neAv p= n×volume× me×vd= n.(A.1) vd.m m p .I e 31 12 19 9.1 10 1 5.68 10 1.6 10 4. A spherical ball of density d is released at depth h in a non-viscous fluid of density 2d kept in a large tank. The ball returns to initial position after time- (A) 2h g (B) h 2. g (C) 2h 2. g (D) h 4. g Solution (C): While inside the fluid 2dgV dgV Vd a a g 2h t g The ball rises up height h in air up and comes down then returns to same depth. 5/2 total 2h h t 4 2 g g 5. A block pushed gently from the edge of a 15m high tower, immediately breaks into two pieces of equal mass. One piece reaches ground after one second, then time in second when other piece reaches ground is- (A) 2s (B) 3s (C) 4s (D) 5s Solution (B): 2 1 15 u1 10 1 2 u 10 m/s Other peace moves at 10 m/s upwards 2 1 15 10 t 10t 2 t 3 SECTION 2: 1. A charged particle of mass m carrying charge q is performing uniform circular motion at the center of a large ring of radius R carrying current I. Particle obeys Bohr's principle of angular momentum quantization. When the particle is in nth orbit- (A) its speed is proportional to n 1/3 (B) radius is proportional to n 1/2 (C) ratio of speed and radius is independent of n (D) time period is proportional to n 3/2 Solution (BC): BCentre 0 I 2R and nh mvr 2 A A

SOLUTIONS TO IRP FULL TEST-1 ONLINE (HELD ON 3RD, 4 , 5 MAY 2018) TH PHYSICS … Online... · 2018. 5. 17. · SOLUTIONS TO IRP FULL TEST-1 ONLINE (HELD ON 3RD, 4 TH, 5 MAY 2018)

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  • 1

    dgV

    2dgV

    While inside the fluid

    SOLUTIONS TO IRP FULL TEST-1 ONLINE (HELD ON 3RD, 4TH, 5TH MAY 2018) PHYSICS (PAPER-1)

    SECTION 1:

    1. A block is given some

    horizontal speed at point

    A of frictionless heavy

    track as shown in figure.

    Block breaks off the track at B and strikes horizontal track at point C.

    Height of point A is 15m and speeds at points

    A, B and C are in ratio 1:2:2. If height of B above ground is h and speed at C is u, then

    value of

    2u

    2his-

    (A) 8 m/s2 (B) 20 m/s2

    (C) 8 m/s2 (D) 8 m/s2

    Solution (B):

    A B Cv : v : v :: 1: 2 : 2

    A B CKE :KE :KE ::1: 2 : 4

    A BKE mg 15 KE mgh

    A B2KE KE AKE mg(15 h)

    A CKE mg15 KE

    A AKE 15mg 4KE AKE 5mg

    A C4KE KE 20mg 21 mu 20mg

    2

    BKE 10mg mg.h =10mg h 10

    2

    2u 20m/s2h

    2. Twelve rods of mass m and length are rigidly joined as edges (sides) of a cube.

    Moment of inertia of the cube about a face

    diagonal is-

    (A) 213

    .m5

    (B) 223

    .m3

    (C) 241

    .m5

    (D) 231

    .m3

    Solution (B):

    22 2 2 2mL 1 mL mL mL

    I 4 2 23 3 12 22

    222mL 1 4 4mL

    3 2

    223m

    3

    3. A conductor having cross section A = 1mm2 is

    carrying I=1.0A current. The linear

    momentum of electrons in unit length of

    conductor is 9×10-N. Value of N is- (A) 3.2×10-17 N-s (B) 5.7×10-19 N-s (C) 9.1×10-25 N-s (D) 2.9×10-27 N-s

    Solution (B):

    dI neAv

    p= n×volume× me×vd= n.(A.1) vd.m

    mp .I

    e

    3112

    19

    9.1 10 15.68 10

    1.6 10

    4. A spherical ball of density d is released at

    depth h in a non-viscous fluid of density 2d

    kept in a large tank. The ball returns to initial

    position after time-

    (A) 2h

    g (B)

    h2.

    g

    (C) 2h

    2.g

    (D) h

    4.g

    Solution (C): While inside the fluid

    2dgV dgV Vd a

    a g

    2ht

    g

    The ball rises up height h in air up and comes

    down then returns to same depth.

    5/2total

    2h ht 4 2

    g g

    5. A block pushed gently from the edge of a 15m

    high tower, immediately breaks into two pieces of equal mass. One piece reaches

    ground after one second, then time in second

    when other piece reaches ground is- (A) 2s (B) 3s

    (C) 4s (D) 5s

    Solution (B):

    2115 u 1 10 1

    2

    u 10m/s

    Other peace moves at 10 m/s upwards

    2115 10 t 10t2

    t 3

    SECTION 2:

    1. A charged particle of mass m carrying charge

    q is performing uniform circular motion at the

    center of a large ring of radius R carrying current I. Particle obeys Bohr's principle of

    angular momentum quantization. When the

    particle is in nth orbit- (A) its speed is proportional to n1/3

    (B) radius is proportional to n1/2

    (C) ratio of speed and radius is independent of n

    (D) time period is proportional to n3/2

    Solution (BC):

    BCentre 0I

    2R

    and

    nhmvr

    2

    A

    A

  • 2

    0I

    mv q.B.r q .r2R

    20r q I nh

    2R 2

    1/2r n

    mv

    rqB

    0

    0

    r 2mRn

    v qr I (independent of n)

    2. After absorbing a slow moving alpha particle a

    nucleus of mass number 87 breaks into two

    smaller nuclei. The product nuclei move away with speeds in ratio approximately 3:7. Then

    the correct statement is-

    (A) mass numbers are in ratio7:3

    (B) ratio of de Broglie wavelengths is 7:3 (C) atomic radii are in ratio 4:3

    (D) mass decreases in the process

    Solution (ACD): Since the alpha particle is slow moving, its

    linear momentum is neglected. 1 1 2 2m .v m .v

    1 1

    2 2

    m v 7

    m v 3

    11 1

    hand

    m v 2

    2 2

    h

    m v

    1

    2

    1

    11 3 33

    2 2

    m 7 64 4r

    r m 3 27 3 (C)

    (D) KE to both parts is result of nuclear

    energy released due to conversion of mass

    into energy.

    3. Three dielectric slabs P, Q and R are inserted between the metal

    plates of a capacitor. Area of

    plates is A and distance between

    them is d. Dielectric slab P has

    area of cross section A and thickness d/2 and dielectric constant K, slab Q and R have area

    A/2 and thickness d/2 each and dielectric

    constants 2K and 3K respectively. When

    capacitor is charged, electric fields at points

    A, B, C and D as shown in figure, are EA, EB,

    EC and ED respectively. The correct relationship is- (A) C AE E (B) A DE E

    (C) C BE E (D) D BE E

    Solution (ABC): Conceptual

    4. Electric field in a region is E (a.i b.j) N/C

    (a b) . There are four points A at (a, b), B at

    (b, -a), C at (-a, -b) and D at (-b, -a). Electric potential at these points are V1, V2, V3 and V4

    respectively, then- (A) V2

  • 3

    R

    d

    2 2

    GM G9Mx 2R

    x (8R x)

    21 GM.m G9Mmu2 R 7R

    GM.m G9M.m

    2R 6R

    21 GM.m 9 1 3 2GM.mmu 12 R 7 2 2 7

    4GMu

    7R

    2

    1 4GM GM.m G9M.mm.

    2 7R R 7R

    GM.m G9M.m 1mv

    7R R 2

    21 GM.m 1 2 9 62mv 9 1 GM.m2 R 7 7 7 7

    124GMv

    7

    7. Two students A and B conduct experiment to find the resistance of same wire. Voltmeter

    and ammeter readings by student A are

    (6.000.02) volt and (2.500.05) amp respectively. Corresponding values by student

    B are (6.000.05) volt and (2.50.02) amp respectively. (A) A measures potential diff. more precisely

    than B (B) B measures current more precisely than A

    (C) error in resistance is less in measurement

    by A

    (D) error in resistance is less in measurement

    by B

    Solution (ABD): V by A is more precise (A)

    I by B is more precise (B)

    Student A: r v I .02 .05

    .023r v I 6 2.5

    Student B: r v I .05 .02

    .0163r v I 6 2.5

    B has more precise resistance than A

    8. A particle is moving in x-y plane. At certain

    instant, the components of its velocity and

    acceleration are as follows Vx=3m/s, Vy=

    4m/s, ax= 2m/s2 and ay= 1m/s

    2.

    (A) angle between velocity and acceleration is

    1 2cos5

    (B) tangential acceleration is 2 m/s2

    (C) radial acceleration is 1 m/s2

    (D) The radius of curvature of trajectory at the

    instant is 20m

    Solution (ABC):

    Angle between ˆ ˆ ˆ ˆv 3i 4j & a 2i j is

    v.a 6 4 2cos

    v . a 5. 5 5

    1 2cos (A)5

    2radial

    v.aa 2m/s

    v (C)

    2 2 2tangential radiala a a 5 4 1m/s (B)

    SECTION 4: 1. There is uniform magnetic field of intensity B

    in an equilateral triangular region, directed

    vertically downwards. Magnetic field of same

    magnitude but directed vertically upwards

    exists outside the triangle. A charged particle of mass m carrying charge q horizontally

    enters the triangle perpendicular to one side

    at midpoint. If the side of triangular region is

    2mv

    q.B, the time period of particle is

    .mn.

    q.B

    ,

    value of n is?

    Solution (6):

    Particle makes 3 complete

    revolutions before coming back

    to same state.

    Time taken= 3T=6 m

    qB

    2. A point charge +q is placed at distance d from a center of a disc of radius R. Flux through

    the disc is o

    q

    3

    . Ratio R/d is 2n/2, value of

    n is-

    Solution (5):

    Rtan

    d

    0

    q 4

    3 3

    4 12 (1 cos ) cos

    3 3

    3/2R tan 8 2d n 3

    3. When a 4 resistance is connected in parallel with an ammeter, its range increases four

    times. If 2 resistance is also connected in parallel, how many times the range will

    increase compared to initial range? Solution (10):

    AI

  • 4

    AA

    nI

    B

    2 I2

    I

    3I

    4

    For the ammeter reading to be 1

    th4

    of the

    incoming current

    1I 3I

    23I 4 I 2 2I 6I

    6I 3I I 10I

    range of ammeter is increased to 10 fold.

    4. A body at temperature 40ºC is kept in a

    surrounding of constant temperature 20ºC. It

    is observed that its temperature falls to 35ºC

    in 10 minutes. Approximate time taken for the body to attain temperature of 30ºC is 4.X

    minutes, then value of x is-

    Solution (3):

    1 2

    2

    1

    2

    40-35 35-30=-k.t and =-k.t

    37.5 32.5

    t 37.5=

    t 32.5

    t 12minute

    5. Glycerin is filled in 25 mm wide space

    between two large plane horizontal surfaces.

    Calculate the force required to drag a very

    thin plate 0.75 m2 in area between the

    surfaces at a constant speed of 0.5m/s if it is

    at a distance of 10 mm from one surfaces and

    15 mm from other surface in horizontal

    position? Take coefficient of viscosity = 0.5

    N-s/m2. Find the value of X where X=

    20×force required to drag (in newton).

    Solution (625):

    F=dv

    Adr

    = 0.5×0.75. 3 30.5 0.5

    10 10 15 10

    = 0.5×0.75×0.5×103 .1 1

    10 15

    = 31.25 N

    AI4I

    A B

    4

    I1

    10mm

    15mm

    0.5m/s

    Fixed surface

  • 5

    5

    2NO

    2NO2 2NH NH

    O

    NH

    NH

    O

    + 2H N

    2NO

    2NO

    NO2

    NO2

    NH2

    NO2

    NH2

    F

    NO2

    NO2

    NH2

    NO2

    NO2NH2

    CHEMISTRY (PAPER-1)

    SECTION 1: 1. How many times does Cannizzaro reaction take place in the given conversion?

    H

    O

    H

    O

    H

    OH- OH

    OH

    OHHCOO

    -+

    (excess)

    (A) 0 (B) 1 (C) 2 (D) 3

    Solution (B):

    After undergoing two times aldol reaction further there is no -hydrogen so it undergoes one time cross cannizzaro reaction in which formaldehyde is oxidised to give formate ion and corresponding

    alcohol is formed.

    2. Predict the product(Y) of the following reaction:

    N-K

    +

    O

    O

    +

    NO2

    NO2

    F

    NH2NH

    2

    RefluxProduct(X) Product(Y)

    (A) (B) (C) (D)

    Solution (B):

    3. 3FeCl dissolved in ether and water forming respectively

    (A) 3 3

    2 2 6Et O Fe and Fe(H O)

    (B) 3

    2 3 2 6Et O FeC and Fe(H O)

    (C) 2 3 2 4 2Et O FeC and Fe(H O) C

    (D) 3 3

    2 2 66Et O Fe and Fe(H O)

    Solution (B):

    3 2 2 6 3FeCl CH O [Fe(H O) ]Cl

    N-K

    +

    O

    O

    +

    NO2

    NO2

    F

    NH2NH

    2

    RefluxProduct(X) Product(Y)

    N-K

    +

    O

    O

    +

    NO2

    NO2

    F

    NH2NH

    2

    RefluxProduct(X) Product(Y)

    2NO

    2NO2 2NH NH

    O

    NH

    NH

    O

    + 2H N

    2NO

    2NO

    3 2 3 2Co ordinatebond

    FeCl OEt FeCl OEt

  • 6 6

    OH

    and

    O

    Br Br

    H H

    and

    Br

    Br

    H

    H

    and

    4. An equilibrium mixture at 300K contains 2 4N O and 2NO at 0.28 and 1.1 atmosphere respectively. If

    the volume of container is doubled. Calculate the new equilibrium pressure of two gases (in atm)

    2 4N O 2NO

    (A) 0.095 0.64

    (B) 0.64 0.095

    (C) 0.17 0.32

    (D) 0.32 0.17

    Solution (A):

    5. Identify the incorrect statement.

    (A) Elemental silicon is known only in diamond structure and no form of silicon possess graphite

    structure.

    (B) BN has hexagonal and cubic arrangement.

    (C) Carbon can form d p bond.

    (D) Silicon exists in crystallite and amorphous forms. Solution (C):

    SECTION 2: 1. CORRECT statement is: (A) Ethanol and Ethanal can be distinguished by using aqueous sodium bisulphite solution.

    (B) Carbolic acid and Aspirin can be distinguished by using aqueous sodium bicarbonate solution.

    (C) Acetone and Acetyl acetone can be distinguished by using neutral FeCl3 solution.

    (D) 1.0 equivalents Acetyl acetone on reaction with excess of NaOI forms more than one equivalents of

    yellow precipitate. Solution (A,B,C):

    3 2 3

    O O|| ||

    CH C CH C CH NaOI

    3 3

    O||

    2CH C O CHI

    So, 1 equivalents of acetylacetone will give 1equivalent of 3CHI .

    2. Which of the following represents a pair of constitutional isomers?

    (A)

    (B) 3 2 2 3 3CH CH CH CH and CH CH CH CH

    (C)

    (D)

    Solution (B,C,D):

    Molecular formula in (A) is not same so not isomers, whereas in (B) (C) & (D) they have same molecular

    formula but different structural formula.

    3. Which of the following statement is/are true?

    (A) In a metal carbonyl c od larger compared to that of c od of free CO.

    (B) The pair of compounds 2 6 3Cr(H O) Cl and 2 3 3 2Cr(H O) Cl 3H O are hydrate isomers.

    (C) The „d‟ orbital of central metal atom/ion involved in 2dsp hybridisation is

    2dz .

    (D) The geometrical isomers of 3 3(Ma b ) complex are optically inactive.

    Solution (A,D):

    Metal carbonyls CO bond order is less than free carbonyls lesser the bond order greater c 0d

    3 3Ma b both the geometrical isomers have plane of symmetry

  • 7

    7

    optically inactive

    4. Correct statement about the structures of 2 24 2 7

    CrO &Cr O is/are

    (A) The structure of 24CrO

    is tetrahedral

    (B) 2

    2 7Cr O predominantly exist in acid medium and 24CrO

    predominantly exist in basic medium

    (C) 6Cr-O bonds are similar in 2

    2 7Cr O ion

    (D) Bridged Cr–O bond length is greater to terminal Cr–O bond length in 2

    2 7Cr O

    Solution (A,B,C,D):

    5. Identify the incorrect statements:

    (A) In the metallurgy of Al, purified Al2O

    3 is mixed with Na

    3AlF

    6 (or) CaF

    2 which lowers the melting

    point and conductivity

    (B) Alkali metals are extracted by the electrolytic reduction of their aqueous salt solutions (C) Leaching process is used in the concentration of red bauxite

    (D) The gases liberated at anode during electrolysis of Al2O

    3 + Na

    3AlF

    6 in Hall-Heroult process is

    2F gas

    Solution (A,B,D): Fact.

    6. In the decay process

    A B C D

    (A) A and B are isobars (B) A and D are isotopes

    (C) B,C and D are isobars (D) A and C are isotones Solution (B,C):

    7. If adsorption of a gas on a solid is limited to monolayer formation then which of the following

    statements are true?

    (A) At low pressures, x

    m varies proportionately with p

    (B) At moderate pressures x

    m varies less than proportionately with p

    (C) At high pressures, x

    m becomes independent of p

    (D) At high pressures, x

    m varies more than proportionately with p

    Solution (A,B,C):

    8. Select the correct statements

    (A) A NaCl type AB crystal lattice can be interpreted to be made up of two individual fcc type unit lattice

    of A and B fused together in such a manner that the corner of one unit lattice becomes the edge

    centre of the other. (B) In a FCC unit lattice the body centre is an octahedral void.

    (C) In a SC lattice there can be no octahedral void.

    (D) In a SC lattice the body centre is the octahedral void.

    Solution (A,B,C):

    O Cr O

    O

    O

    Cr Cr

    O

    O O

    O

    O

    O

    O

    , According to structure

  • 8 8

    3H C3CH

    ( )

    3H C

    * *

    4 isomer (2 enantiomeric pair)

    ( )

    2 3CH CH

    CH3

    C H3( )

    CH3CH3

    CH3

    CH3

    CH3

    CH3

    Cl

    + 3CCl C H

    O

    2 4H SO

    3CCl CH Cl

    Cl(DDT)

    SECTION 4: 1. How many of them will form atleast one enantiomeric pair during monochlorination ?

    (i) 2-methylbutane (ii) isobutane

    (iii) neopentane (iv) (Optically pure)

    (v) 2,2-di methyl butane (vi)

    (vii) (viii)

    Solution (6):

    (i)

    ( )

    3 2 3

    3

    H C CH CH CH|CH

    (ii) 3 3

    3

    H C CH CH|CH

    No enantiomeric pair

    (iii)

    3

    3 3

    3

    CH|

    H C CH CH|CH

    No enantiomeric pair (iv)

    (v)

    ( )3

    3 2 3

    3

    CH|

    H C C CH CH|CH

    (vi)

    (vii) (viii)

    2. Number of chlorine atoms present in a molecule of organic product of following reaction

    Solution (5):

    Cl2 4H SO

    3CCl C H

    O

    Chlorobenzene Trichloroacetaldehyde

    Cl2 4H SO

    3CCl C H

    O

    Chlorobenzene Trichloroacetaldehyde

  • 9

    9

    3. Among following the number of reactions with correct products is

    (i) HCl

    2 2 4SnCl I SnCl HI

    (ii) 3 3 4 2 4 2 2NaIO NaHSO NaHSO Na SO H O I

    (iii) 2 2 3 2FeBr Cl FeCl Br

    (iv) 2 2 4 2I N H HI N

    Solution (4): Factual

    4. Among 2 2 2 2 3Cu ,Mn ,Cd ,Zn ,Bi the number of cations which forms sulphide precipitate with

    4NH Cl and 4NH OH and 2H S is ____________

    Solution (5):

    Both cations of group- II and IV are precipitated

    5. A compound contains 28% N and 72% of a metal by weight 3 atoms of metal combine with two atoms of

    nitrogen. If atomic weight of metal is „M‟ find M

    ?6

    Solution (4):

    3 M 2 14 100 M 24

    M 244

    6 6

  • 10

    MATHEMATICS (PAPER-1) SECTION 1:

    1. If the value of the definite integral /6

    0

    1 sin xdx

    cos x

    2 ln A B C 1

    then A B C is (where A, B, C are different natural numbers)

    (A) 0 (B) 5 (C) 6 (D) 7

    Solution (B): /6

    0

    dxI

    x xcos sin

    2 2

    /6

    0

    x x2 ln sec tan

    2 4 2 4

    2 ln 2 3 2 1

    A 4,B 3,C 2

    2. If A is non-singular square matrix where TB A &

    2A B I . Such that 3A I KA

    then K is equal to

    (A) 0 (B) 1

    (C) 2 (D) 3 Solution (C):

    2

    TA A I …(i)

    Take transpose on both side: T 2A A I …(ii)

    From equation (i) & (ii):

    2

    2A I A I 4 2A A 2A O

    1 1 1 1 2A A A A 2A A 0

    3A I 2A K 2

    3. Number of values of x satisfying the equation

    7x 10 x is (A) 0 (B) 1

    (C) 2 (D) 3

    Solution (D):

    7x 10 x x

    3x

    x10

    4. Let ˆ ˆ ˆ ˆ ˆ ˆA 2i 3j 5k ,B i 3j 2k and

    ˆ ˆ ˆC i 5j k be the vertices of triangle ABC and the median through A is equally inclined

    to the positive directions of the axes then the

    value of 2 is equal to (A) 4 (B) 3 (C) 2 (D) 1

    Solution (A):

    Midpoint of 1/2 2

    BC D i 4j k2 2

    5 8AD i j k

    2 2

    As AD is equally inclined with axes.

    AD.i AD. j AD.k

    5 8

    12 2

    7, 10

    2 4

    5. If

    n1

    2 2 3r 1

    2r 1tan tan

    r r 1 r r 1 2r

    961 , then the sum of digits of n is equal to

    (A) 10 (B) 19 (C) 8 (D) 12

    Solution (A):

    1r 2 4 3

    2r 1T tan

    1 r r 2r

    1

    22

    2r 1tan

    1 r r

    1

    22

    2r 1tan

    1 r r 1

    221

    22

    r r 1tan

    1 r r 1

    21 2 1

    rT tan r tan r 1

    n1 2

    r n 0

    r 1

    T V V tan n

    n1 2

    r

    r 1

    tan T tantan n 361

    2n 316 n 19

    SECTION 2:

    1. Let

    2x 4x , 3 x 0

    f x sinx ,0 x2

    cos x 1 , x2

    , then:

    (A) x 2 is the point of global minima (B) x is the point of global maxima

    (C) f x is non-differentiable at x2

    (D) f x is discontinuous at x 0

  • 11

    Solution (ABC):

    From above figure clearly option (A), (B) and (C) are correct.

    2. Let f : a,b a,b (where a b and are real numbers) be a differentiable non-constant

    function for which f a b & f b a . Then

    (A) at least one c a,b such that f c c

    (B) 1 2 1 2c ,c a,b ,c c such that

    1 2f c .f c 1

    (C) c a,b such that f c 1

    (D) c a,b such that f c 1

    Solution (ABCD):

    Let g x f x x

    g x is continuous function

    g a b a 0

    g b a b 0

    g a g b 0

    g c 0 for some c a,b

    f x x for some c a,b

    Use LMVT on f x in a,c

    1

    f c f af c

    c a

    1c a,c

    1c b

    f cc a

    Use LMVT on f x in c,b

    2

    f b f cf c

    b c

    2c c,b

    2a c

    f cb c

    1 2f c f c 1

    1f c 1 , 2f c 1

    3. Contents of the two urns is as given in this

    table. A fair die is tossed. If the face 1, 2, 4 or

    5 comes, a marble is drawn from the urn A

    otherwise a marble is chosen from the urn B.

    Urn Red Marbles

    White marbles

    Blue marbles

    A 5 3 8

    B 3 5 0

    Let 1E : Denote the event that a red marble is

    chosen.

    2E : Denotes the events that a white marble is

    chosen

    3E : Denote the event that a blue is chosen.

    Then

    (A) Events 1 2 3E ,E & E are equiprobable.

    (B) 1 2 3P E ,P E ,P E are in AP. (C) If the marble drawn is red, the probability

    that it came from the urn A is 1

    2.

    (D) If the marble drawn is white, the probability that the face 5 appeared on the die

    is 3

    32.

    Solution (ABD):

    1A : urn A is selected 14 2

    P A6 3

    .

    2A : urn B is selected 22 1

    P A6 3

    1 1 1 1 2 1 2P E P A P E /A P A P E /A

    4 5 2 6 1

    6 16 6 16 3

    2 1 2 1 2 2 2P E P A P E /A P A P E /A

    4 3 2 10 1

    6 16 6 16 3

    3 1 3 1 2 3 2P E P A P E /A P A P E /A

    4 8 1

    6 16 3

    (C)

    1 1 1

    1 11

    20P E /A P A 20 596P A /E

    1P E 32 8

    3

    (D)

    2 1

    1 22

    P E P A1 1P A /E

    4 4P E

    121 396

    32 4 32

    96

    4. The line x 6 y 10 z 14

    5 3 8

    is the

    hypotenuse of an isosceles right angled

    triangle whose opposite vertex is 7,2,4 . Then which of the following is/are sides of the triangle?

    (A) x 7 y 2 z 4

    2 3 6

    (B) x 7 y 2 z 4

    3 6 2

    (C) x 5 y 5 z 2

    2 3 6

    (D) x 4 y 4 z 2

    3 6 2

    Solution (ABCD):

    Let M 5 6,3 10,8 14

    BM 5 13 i 3 12 j 8 18 k

  • 12

    BM. 5i 3j 8k 0 5

    2

    Coordinate of 13 5 12

    M , ,2 2 2

    and

    7BM AM CM

    2

    Let A 5 6,3 10,8 14

    25 15

    AM 5 i 3 j 8 20 k2 2

    7AM

    2

    2 2

    225 155 3 8 20

    2 2

    49

    2

    2 5 6 0 2,3

    A 4, 4,2 & C 9, 1,10 Lines in options A & C passes through points

    B & C lies in option B & D passes through

    point A & B.

    5. At a point P on the parabola 2y 4x , tangent

    and normal are drawn. Tangent intersects the

    x-axis at Q and normal intersects the curve at

    R such that chord PR subtends an angle of o90 at its vertex, then

    (A) PQ 2 6

    (B) PR 6 3

    (C) Area of PQR 18 2

    (D) PQ 3 2

    Solution (ABC):

    Let 2 21 1 2 2P t 2t & R t ,2t

    2 1 1 21

    2t t & t t 4

    t

    1t 2 , P 2, 2 2

    2t 2 2 , R 8, 4 2 Equation of tangent at P:

    21 1x yt t 0

    x 2y 2 0

    Coordinates of Q 2,0

    PQ 16 8 2 6

    PR 36 72 108 6 3

    1PQR 2 6 6 3 18 2

    2

    6. Identify the correct statements:

    (A) An ellipse passes through the point 4, 1

    and touches the line x 4y 10 0 . If its

    axes coincide with the coordinate axes,

    then its equation is 2 2x y

    180 5/4

    (B) In the expansion of

    203

    4

    14

    6

    , there

    are 19 irrational terms

    (C) The set S 1,2,3,..,12 is to be partitioned into three sets A, B, C of equal

    size such that A B C S ,

    A B B C A C . The number of

    ways to partition S is

    3

    12!

    4!

    (D) If the normal at 11

    cct ,

    t

    on 2xy c meets

    it again in the point 22

    cct ,

    t

    , then

    31 2t t 1

    Solution (ABC):

    (A) Let equation of ellipse 2 2

    2 2

    x y1

    a b

    Passes through 4, 1

    2 2

    16 11

    a b …(i)

    Touches the line 1 5

    y x4 2

    2225 a b

    4 16 …(ii)

    From (i) & (ii): 2a 80,20

    2 5b ,54

    Equation of ellipse 2 2x y

    180 5/4

    or 2 2x y

    120 5

    (B)

    r20 r420 3

    r r1

    T C 46

    For rational terms r 8,20

    Number of irrational terms

    21 2 19

    (C)

    3

    12! 3! 12!

    4! 4! 4! 3! 4!

    (D) 2c

    yx

    2

    2

    dy c

    dx x

  • 13

    Slope of normal at 21 11

    cct t

    t

    2 2 112 1

    c 1

    t tt

    ct ct

    1 2

    1

    t t

    31 2t t 1

    7. If x

    1

    ln tf x dt

    1 t

    , then

    (A)

    x

    1

    1 lntf dt

    x t 1 t

    (B)

    x

    1

    1 lntf dt

    x t 1 t

    (C) 1 1f e f8e

    (D) 21 1

    f x f lnxx 2

    Solution (BCD):

    x

    1

    ln tf x dt

    1 t

    1/x

    1

    1 lntf dt

    x 1 t

    , Put

    1t

    z ,

    2

    1dt dz

    z

    x

    21

    1ln

    1 1zf dz1 zx z

    z

    , when t 1,z 1

    1t ,z x

    x

    x x

    1 1

    lnz lntdz

    z 1 z 1 t

    x

    1

    1 lnt lntf x f dt

    x 1 t t 1 t

    x 2

    1

    ln xlntdt

    t 2

    1 1f e f8e

    8. If the cubic equation 3 2z az bz c 0 , a,

    b, c R , c 0 has a purely imaginary root then

    (A) c ab

    (B) b ac

    (C) number of purely imaginary root is 2

    (D) a bc

    Solution (AC):

    Let be purely imaginary root 3 2a b c 0 …(i)

    Take conjugate 3 2a b c 0

    3 2a b c 0 …(ii)

    (i) + (ii) 2c

    a

    cb

    a

    (i) – (ii) 2 b c ab

    Non real root occur in pair

    2 purely imaginary roots

    SECTION 4:

    1.

    n

    n

    1lim n e 1 a

    n

    and

    n 1

    n

    1lim n 1 e b

    n

    , then 2a 2b

    Solution (5):

    n 1 n

    n

    1 12a 2b 2 lim n 1 1

    n n

    n

    n

    1 12 lim n 1 1 1

    n n

    n

    n

    12 lim 1 2e

    n

    2a 2b 5 2. Let F : , be anti-derivative of the

    function 2

    f : ,3 3

    ,

    xf x ;

    sin x and

    2F F lnc

    3 3 2

    . Then c

    Solution (3):

    x

    x

    /3/3

    xf x dx

    sin x

    x

    /3

    xF x F

    3 sinx

    2 /3

    /3

    2 xf F dx

    3 3 sinx

    /2

    /3

    xnC

    2 sin x

    2 /3

    /3

    xnc dx

    2 sin x

    2 /3

    /3

    nc cosecx

    2 /3

    /3nc n cosecx cot x

  • 14

    2 /3

    /3

    xntan

    2

    1n 3 n

    3 2 n 3

    c 3

    3. Let a, b be arbitrary real numbers. Find the

    smallest natural number b for which the

    equation 2x 2 a b x a b 8 0 has

    unequal real roots for all x R Solution (5):

    For unequal real roots: D 0

    2

    4 a b 4 a b 8 0

    2 2a b 2ab a b 8 0

    2 2a 2b 1 a b b 8 0

    D 0 2 22b 1 4 b b 8 0

    8b 33 0 33

    b8

    as b N

    Smallest b 5 .

    4. If , are two distinct real roots of the

    equation 3ax x 1 a 0 , a 1,0 , none of which is equal to unity, then the value of

    3 2

    1 x1x

    1 a x x alim

    e 1 x 1

    is

    am n

    , where

    mn … m,n N Solution (1):

    3ax x 1 a 0

    2x 1 a x x 1 1 0

    2a x x 1 1 a x x

    3 2

    1 x1x

    1 a x x alim

    e 1 x 1

    , Put

    1x

    t

    3

    t 1t

    3

    1 a t atlim

    e 1 1 t1 t

    t t1

    t

    t

    a t 1 t tlim

    1 t t t 1

    a

    m 1,n 1 m n 1

    5. Through P 2,2 is drawn a chord of the

    ellipse 2 2x y

    125 16

    such that it intersects the

    ellipse at A and B. If maximum value of

    PA.PB is m then the value of m/2 is (where [.] is greatest integer function)

    Solution (7):

    Let A 2 rcos ,2 rsin lie on the ellipse.

    2 2

    2 rcos 2 rsin1

    25 16

    2 22cos sin r

    25 16

    4cos 4sin 236r 0

    25 16 400

    Roots PA & PB

    2 2 2

    236 236PA PB

    16cos 25sin 16 qsin

    max

    236PA PB m

    16

    m 236

    2 32

    m7

    2

  • 15

    PHYSICS (PAPER-2) SECTION 1:

    1. A metallic rod of length 1 m is rigidly clamped

    at its mid-point. Longitudinal stationary waves are set up in the rod in such a way that

    there are two nodes on either side of the

    midpoint. The amplitude of an antinode is

    2×106m. [Young‟s modulus = 2 × 1011 Nm

    2,

    density = 8000 Kg/m3). Origin is at O which

    is mid-point of the rod. P is a point on the rod

    such that OP=10 cm. Magnitude of maximum

    velocity of the point P is-

    (A) 20

    m/s (B)

    10

    m/s

    (C) 5

    m/s (D)

    4

    m/s

    Solution (A):

    V 5000 m/s, =0.4m

    4f 1.25 10 Hz

    Maximum Velocity = a. =20

    m/s

    because x= 10 cm is antinode

    2. Figure shows

    two, identical

    narrow slits S1

    and S2. A very

    small completely

    absorbing strip

    is placed at

    distance „y‟ from

    the point C. „C‟ is the point on the screen

    equidistant from S1 and S2. Assume

  • 16

    =5 3 2 2

    a(10 P 10 m 5 10).(50 10 )

    1 R

    T = 75

    RK.

    PARAGRAPH FOR NEXT TWO QUESTIONS:

    A rectangular block of area of cross section A, length L and

    density d is submerged and

    floating at the interface of two

    liquids. Densities of liquids are d1 and d2

    (d1

  • 17

    Electrons are accelerated through 5V, will

    reach the anode with maximum energy (5–+ 5) eV

    10 – = 8 eV

    = 2eV Current is less than saturation current

    because if slowest electron also reached the plate it would have 5eV energy at the anode,

    but there it is given that the minimum energy

    is 6eV.

    2. A sample of hydrogen atom gas contains 100 atoms. All the atoms are excited to the same

    nth excited state. The total energy released by

    all the atoms is 4800

    49Rch (where Rch = 13.6

    eV), as they come to the ground state through

    various types of transitions. (A) Maximum energy of the emitted photon

    may be 48

    49Rch

    (B) Initially atoms are in 6th excited state.

    (C) Initially atoms are in 7th excited state.

    (D) Maximum total number of photons that

    can be emitted by this sample is 100. Solution (AB):

    Maximum energy of one photon=

    4800Rch

    49

    100

    =48

    49Rch=Rch

    22

    1 1

    1 n

    Rch22

    1 1

    1 n

    =

    48

    49Rch

    n=7 n=6 there are 100 atoms, maximum number of

    photons that can be emitted=600.

    3. Radionuclide of 56Mn is being produced in a

    cyclotron at a constant rate P by bombarding

    a maganese target with deutrons. 56Mn has a

    half life of 2.5 h and the target contains large

    number of only the stable maganese isotope 55Mn. The reaction that produces 56Mn is:

    55Mn + 21H 56Mn + 11H . After being

    bombarded for a long time, the activity of the

    target due to 56Mn becomes constant equal to

    13.86×1010 s–1. (Use ln2 = 0.693; Avogadro No = 6 × 1023;

    atomic weight 56Mn = 56 gm/mole)

    (A) 56Mn nuclei are being produced in the

    cyclotron at rate 13.86×1010 nuclei/sec

    (B) After a long time, number of 56Mn nuclei present in the target, is 1.8×1015

    (C) maximum number of 56Mn nuclei depends

    on number of 55Mn nuclei

    (D) decay constant is 1.8 × 10–5 per second

    Solution (AB):

    In equilibrium - rate of production = rate of

    decay= 13.86 × 1010 nuclei/s

    P= N N=P

    =

    1/2Pt

    n2=1.8×1015

    4. A partition divides a

    container having

    insulated walls into

    two compartments

    and . The same gas fills the two compartments whose initial

    parameters are given. The partition is a

    conducting wall which can move freely

    without friction. Which of the following statements is/are correct, with reference to

    the final equilibrium position? (A) Pressure in the two compartments are

    equal

    (B) Volume of compartment is3V

    5

    (C) Volume of compartment is12V

    5

    (D) Final pressure is5P

    3

    Solution (ABCD):

    In the equilibrium position the net force on

    the partition will be zero. Hence pressure on

    both sides is same. Hence (A) is correct.

    Initially, PV=nRT

    n1=1 1

    1

    P V

    RT=

    PV

    RT & n2=

    (2P)(2V)

    RT=4

    PV

    RT

    n2 = 4n1

    1 1

    2 2

    V n

    V n =

    1

    4 V2=4V1

    V1+4V1=3V V1=3

    5V

    and V2=12

    5V

    13V

    P5

    =P V

    RT

    RT P1'=5PV

    3V=

    5

    3P

    5. Uniform rod AB is hinged at the end A in a

    horizontal position as shown in the figure. The other end is connected to a block through

    a massless string as shown. Pulley is smooth

    and massless. Masses of the block and the

    rod are same and equal to 'm'. Choose correct

    (A) acceleration of block is 3g

    8

    (B) tension in string is 5mg

    8

    (C) string force at A is zero

    (D) magnitude of initial acceleration of centre

    of mass of system is approx g

    10

  • 18

    Solution (AD):

    T( )–mg2

    =2m a

    3 and mg–T=ma

    a=3g

    8

    5mg

    T mg ma8

    rod block

    cmrod block

    am . m .a

    3g g2am m 32 10

    6. When some energy is given to an electron its

    de Broglie wavelength decreases from

    9 92 10 m to 0.5×10 m choose correct

    (A) momentum becomes four times of its

    initial value

    (B) energy becomes four times its initial value

    (C) energy required is 5.6 eV (D) final energy is 5.6 eV

    Solution (AC):

    1 2 11 2 1

    h h hp , p 4. 4p

    =h

    p=

    h

    2mE E=

    2

    2

    h

    2m

    E=2h

    2m.

    2 21 2

    1 1

    = 5.6 eV

    7. A 4kg block and a 2kg block are kept on a

    rough horizontal surface. Coefficient of static

    friction is s 0.4 and coefficient of kinetic

    friction is d 0.2 . Blocks are connected by

    massless spring of force constant K = 20 N/m.

    Spring is neither extended nor compressed

    initially. 4 kg block is given some speed towards 2kg block. 2kg block starts moving

    just before 4kg block comes to rest.

    (A) Maximum compression in spring is 0.4 m

    (B) Initial speed of 4kg block is 3

    2 m/s5

    (C) Finally spring is compressed by 0.2 m

    (D) Finally there is no compression or

    extension in spring

    Solution (ABD):

    When 2kg block starts motion

    2m g kx x 0.4m

    2 2 k 11 1

    4 v k.x m .g.x2 2

    2 21 1

    4.V 20 (0.4) 0.2 4 10 0.42 2

    3

    V 2 m/s5

    Finally- 2

    k 2

    1kx .m .g.x x 0.4m

    2

    8. There is a stream of neutrons with a kinetic

    energy of 0.0327eV. If the half life of

    neutrons is 700 seconds. Choose correct (A) Speed of neutrons is approx 2500 m/s (B) neutrons decay into proton, electron

    (C) neutrons decay into proton and electron

    and anti neutrino

    (D) nearly 0.0004% neutrons decay after

    travelling 10 m.

    Solution (ACD):

    19

    27

    2KE 2 0.0327 1.6 10V 2500m/s

    m 1.67 10

    1 1 00 1 1n H e E

    10m

    t 0.004s2500m/s

    dN dN

    .N .dtdt N

    Fraction decay dN ln2

    . t 0.004N 700

    0.0004%

  • 19

    19

    2 gN one mole

    1 atm

    2 gH one mole

    1 atm

    V L V L

    Temperature 298 K

    P 1 atm

    O CH3

    O2N

    O2N

    O CH3

    O

    CH3 NO2

    O

    NO2

    CH3

    isC,C42SOH

    H

    OHOH

    NO2CH3

    CHEMISTRY (PAPER-2)

    SECTION 1:

    1.

    (A) (B)

    (C) (D)

    Solution (C):

    2. Assume that 6 6 6 5 3C H andC H CH form an ideal solution then 0G, Hand S at 25 C for the

    addition of 1 mole of 6 6C H to an infinitely large sample of solution with with a mole fraction of 0.35 for

    6 6C H is

    (A) G H S 0 (B) H 0, G S 4582.57J

    (C) H 0, G 4582.57J, S 15.38 j/k

    (D) H 15.38J/k G 4582.57J, S 15.38J/k

    Solution (C):

    3.

    If we remove the wall in between the two container then change in entropy of mixing is:

    (A) 1 111.54 J mol K (B) 1 111.54 J mol K

    (C) 1 123.08 J mol K (D) 1 15.77 J mol K

    Solution (A):

    2

    1

    V2.303 nR log

    V

    4. 2 2BaC N A

    2 2CaC N B

    3CH2NO

    OH 2OH

    5

    4

    32 1

    H

    HO2O N

    +3CH

    H

    O2O N 3CH

  • 20 20

    O

    O

    O

    O

    CH3O

    O

    CH3

    O

    O

    CH3

    A and B are respectively

    (A) 2 2BaCN ,CaCN (B) 2 2Ba CN ,Ca CN

    (C) 22Ba CN ,CaCN (D) BaCN,CaCN Solution (C):

    2 2 2

    2 2 2

    BaC N Ba CN

    CaC N CaCN

    PARAGRAPH FOR NEXT TWO QUESTIONS

    In organic chemistry the functional groups plays major roll. Each functional group has it‟s own

    characteristic property. Few functional groups interact with specific reagents and sometimes the reactivity

    also depends on the structural connectivity of the functional groups in a molecule. Answer the following questions based on their conditions:

    5. The structure formula for “vitamin-C” shown below contains four different hydroxyl groups, in which,

    which hydroxy group that is most readily methylated with CH2N2

    (a)

    (b)

    OHCH

    2

    C

    OHH O

    O

    OH OH

    H

    (c) (d)

    (A) a (B) b (C) c (D) d

    Solution (C):

    Protonation of 2 2CH N takes place first, so more is the acidity of O H bond, faster will be

    protonation and faster will be the reaction.

    6. Predict the end product in the given reaction:

    CH3

    42.NaBH

    3. /H

    1. O3; H2O/H2O2

    (A) (B) (C) (D)

    Solution (A):

    22 3H C N N CH N3Ph OH Ph O Ph OCH

    3CH

    3 2 2 21. O H O/H OO

    O

    OH

    3CH

    42.NaBH

    OOH

    OH

    3CH

    3.H /

    Esterification

    3CH

    O

    O

  • 21 21

    H /NiH O 233heat heat

    A CH CHNC B

    3CH

    PARAGRAPH FOR NEXT TWO QUESTIONS

    Lead acid storage battery may be recharged after its usage. It consists of Pb anode with coating of spongy lead, Pb with a coating of

    2PbO , serves as cathode. 2 4H SO is used as an electrolytic solution.

    2

    4 4Pb SO PbSO 2e 0E 0.31 V

    2

    2 4 4 2PbO 4H SO 2e PbSO 2H O

    0E 1.70 V

    7. During discharge of battery, which of the following statements are TRUE?

    (P) At anode and cathode respectively 2Pb,PbO are involved in the redox reaction

    (Q) Density and concentration of 2 4H SO decreases during discharging process

    (R) It needs no salt bridge since the oxidizing and reducing agents in both discharge and recharge

    processes are solids.

    (S) Equivalent weight of 2 4H SO is 49 and that of 2H O is 18.

    (A) PQ (B) PS (C) PQR (D) PQS

    Solution (C):

    (P) At anode and cathode respectively 2Pb,PbO are involved in the redox reaction

    (Q) Density and concentration of 2 4H SO decreases during discharging process

    (R) It needs no salt bridge since the oxidizing and reducing agents in both discharge and recharge

    processes are solids.

    8. Two moles of 2 4H SO consumed during the discharge of lead storage battery. With this how many

    moles of gases will be liberated during the electrolysis of acidified water (A) 4 (B) 3 (C) 1.5 (D) 1

    Solution (C):

    SECTION 2: 1. Some statements are given about following compound

    3 2 3 2

    O||

    CH C CH CH (OCH )

    Identify correct statements

    (A) It gives yellow precipitate with 2I in aq NaOH Solution

    (B) It does‟t form silver mirror with Tollens reagent

    (C) One of Hydrolysis products of given compound gives red precipitate with Benedicts solution

    (D) Both, the given compound and its one of hydrolysis products gives positive test with 2, 4 – DNP

    Solution (A,B,C,D):

    2.

    Products „A‟ and „B‟ can be distinguished by (A and B are Nitrogen containing products)

    (A) the treatment of 3CHCl ,OH

    gives a foul smelling compound

    (B) the action of 2HNO A liberates 2N gas whilst B does not

    (C) the actions of 2 2CS ,HgCl . B gives odour of mustard oil whilst A doesn‟t

    (D) the treatment of p-toluene sulphonyl chloiride; „A‟ gives alkali soluble product Solution (A,B,D):

    H /NiH O 23

    3 2 3 3 3

    3 3 3

    CH CH NH CH CHNC CH CH NH CH| | |CH CH CH

    O

    2H /H O3 2 3 2 3 2Hydrolysis

    CH C CH CH(OCH ) CH C CH C H

    O O

  • 22 22

    Cl

    C

    N N

    CC

    NCl Cl

    O O

    O

    O

    OO

    S

    S S

    OO

    O

    O O

    O

    OO

    OO

    OO

    P

    P P

    3CH 3CH

    Si

    O O

    Si Si

    O

    3CH

    3CH

    3CH

    3CH

    3. Select compound which is / are isoelectronic

    (A) (B)

    (C) (D)

    Solution (A,B,C):

    (A,B,C) are isoelectronic 4. Which of the following reactions give the same nitrogen containing gaseous product?

    (A) Heating of 4 2NH NO (B) By passing 3NH over heated CuO

    (C) Heating of 3 2Ba(N ) (D) Cu cold and dilute 3HNO

    Solution (A,B,C):

    4 2 2 2NH NO N 2H O

    3 2 22NH 3Cuo N 3H O 3Cu

    3 2 3 2 23Ba(N ) Ba N 8N

    5. Which of the following statements are true

    (A) All crystalline solids are isotropic

    (B) 6SF molecule has no net dipole moment.

    (C) Amorphous solids are super cooled liquids with high viscosity.

    (D) In crystals, short range order exists

    Solution (B,C):

    6. Dry air is slowly passed through three solutions of different concentrations, 1 2 3c , c and c ; each

    containing (non volatile) NaCI as solute and water as solvent, as shown in the Fig. If the vessel 2 gains weight

    and the vessel 3 loses weight, then

    (A) 1 2c c (B) 1 2c c (C) 2 3c c (D) 2 3c c Solution (B, D):

    1 2c c , 2 3c c

    7. 0.1mol of 4MnO

    in acidic medium can oxidize:

    (A) 2 41

    mol of FeC O6

    (B) 20.5 mol of Fe

    (C) 2

    2 40.25 mol of C O

    (D) 2

    2 70.6 mol of Cr O

  • 23 23

    T

    S

    Solution (A,B,C):

    2 41

    mol of FeC O6

    , 20.5 mol of Fe , 22 40.25 mol of C O

    8. The Variation of solubility (S) of a salt s

    A B in water with temperature (T) is given by the

    following graph then the correct statements is/are (A) The solubility process is endothermic

    (B) The lattice energy of salt is less than the hydration energy of ions.

    (C ) Solubility decreases with increase of temperature.

    (D) The salt may be 4 sNH Cl

    Solution (B,C): Conceptual

  • 24

    MATHEMATICS (PAPER-2) SECTION 1:

    1. If 2 22 2 2

    2 21 0

    x 1 sin x xsin xdx dx

    x 2x 3 x 2x 3

    2 2

    21

    xsin x p2 dx

    qx 2x 3

    (p and q are relatively

    prime). Then p q is equal to

    (A) 0 (B) 1

    (C) 2 (D) 3

    Solution (D):

    2 22 2 22 2

    1 1

    x 1 sin x xsin xI 2 dx

    x 2x 3 x 2x 3

    2 2

    20

    xsin xdx

    x 2x 3

    2 22

    121

    x 2x 1 sin xI dx I

    x 2x 3

    2 2 22

    121 1

    sin xI sin x dx 2 I

    x 2x 3

    2

    1

    11 cos2 x dx 0

    2

    1 p

    2 q

    p q 3

    2. Three distinct points

    and are collinear and equation

    ,

    has roots u, v and

    w, then which of the following is true?

    (A)

    (B)

    (C)

    (D) cannot say anything

    Solution (B):

    2 3

    2 3

    2 3

    3u 2u 1

    3u 2v 1 0

    3w 2w 1

    u v v w w u uv vw uw 0

    uv vw uw 0 c

    0a c 0

    3. If a pair of variable straight lines

    (where is a real

    parameter) cut the ellipse at two

    points A and B, (where A, B and origin are

    non collinear), then the point of intersection of

    tangents at A and B, satisfies

    (A)

    (B)

    (C)

    (D)

    Solution (D):

    Let point of intersection of tangent at A & B is

    P h,k .

    Equation of chord of contact AB:

    hx 4ky 4 0 …(iii)

    22 2 hx 4kyx 4y 4 0

    4

    (homogenize equation (ii) with the help of (iii))

    2 2 2 2 2 24x 16y h x 16k y 8hkxy 0

    2 2 2 24 x 16 16k y 8hk xy 0 ..(iv) Comparing equation (i) & (iv):

    2 24 h 16 16k 8hk

    1 4

    2 24 4 14k 2 2x 4y

    4. If the eccentricity of

    is and e be the

    eccentricity of then is

    equal to

    (A) (B)

    (C) (D)

    Solution (A):

    2 2 1

    nb na 12

    2nb 1

    na 2

    2

    2na1 e 1nb

    23

    e2

    2 3 2 3P 3u ,2u ,Q 3v ,2v

    2 3R 3w ,2w3 2ax bx cx d 0

    a 0 & a,b,c,d,u,v,w R

    b 0

    c 0

    d 0

    2 2x 4y xy 0

    2 2x 4y 4

    2 2x 4y 8y 0

    2x y 2x y 0 2 2x 4y 4xy 0

    x 2y x 2y 0

    2 2

    2 2

    x y1

    na nb

    a b 0,a,b 1 1

    2

    22

    2b

    xy 1

    log a 2e

    3

    2

    1

    2

    2

    3

    5

    4

  • 25

    PARAGRAPH FOR NEXT TWO QUESTIONS:

    Let O be an interior point of such that

    . Points D and E are the

    midpoints of the sides AC and BC respectively.

    5.

    ar DOE

    ar ABC

    (A) (B)

    (C) (D) none of these

    Solution (D):

    6.

    ar ABC

    ar AOC

    (A) 2 (B) 3

    (C) 4 (D) 8

    Solution (B):

    SOLUTION FOR QUESTION NUMBER (5 & 6):

    Let O be the origin

    PV of a c

    D2

    , PV of

    b cE

    2

    , a 2b 3c

    1 1ABC a c b c a b b c c a2 2

    1

    2b 3c b b c c 2b 3c2

    3 b c

    1 a c b cDOE

    2 2 2

    1 2b 2c b c 1b c 0

    2 2 2 2

    1 1AOC a c 2b 3c c2 2

    b c

    ABC3

    AOC

    DOE0

    ABC

    PARAGRAPH FOR NEXT TWO QUESTIONS:

    Let be a sequence of

    numbers satisfying and

    .

    7.

    (A) (B)

    (C) (D)

    Solution (C):

    8.

    8

    ii 0

    1

    a

    (A) (B)

    (C) 100 (D) none of these

    Solution (A):

    SOLUTION FOR QUESTION NUMBER (7 & 8):

    n 1 0n

    18a 3 ,a 3

    6 a

    118

    a 3 19

    218 3

    a 37 7

    318 18 7

    a 3 33 45 5

    67

    418 3

    a 31 31

    65

    518 6 31 1

    a 3 36 3/31 63 21

    b 1 2S a a a ………. n 1a

    1 2 3 nT T T .....T

    n n

    3T

    2 1

    8 9 9 n

    i ni 0 n 1 n 1

    1 1 2 1 1013

    a T 3 3

    SECTION 2:

    1. Identify the correct statements:

    (A) If angle between the line

    x 1 y 1 z 2

    1 2 2

    and the plane

    2x y z 4 0 is such that 1

    sin3

    ,

    then the value of is 5

    3

    (B) A tetrahedron has vertices O 0,0,0 ,

    A 1,2,1 ,B 2,1,3 and C 1,1,2 , then angle between faces OAB and ABC will be

    1 19cos35

    (C) Number of divisors of 2 3 3 52 .3 .5 .7 of the

    form 4n 1,n N is 48

    ABC

    OA 2OB 3OC 0

    1

    3

    1

    6

    1

    9

    0 1 2 na ,a ,a ,......,a ,...

    n 1 n3 a 6 a 18

    0a 3

    5a

    1

    3

    1

    7

    1

    21

    1

    63

    1013

    3

    1010

    3

  • 26

    (D) If the graph of

    3 2f x 2x ax bx a,b N with the x-

    axis at three distinct points, then the

    minimum value of a b equals 4

    Solution (ABCD):

    (A) Angle between line and plane:

    2 2 2 1sin

    33 5

    4 5 5

    3

    (B) Normal to the face OAB

    1

    i j k

    n 1 2 1 5i j 3k

    2 1 3

    Normal to the face ABC

    2

    i j k

    n 1 1 2 i 5 j 3k

    2 1 1

    Angle between plane 1 2

    1 2

    n .n 19cos

    n n 35

    (C) Number of division 4 2 3 3 2 48

    (D) For 3 distinct roots 2a 8b 0

    Minimum value of a b 4

    2. A player tosses a coin. He sets one point for

    head and two points for tail. He plays till he

    gets sum of points equal to n. If np be the

    probability that his score becomes n, then

    (A) 31

    p2

    (B) n n 1 n 21 1

    p p p2 4

    (C) n n 1 n 21

    p p p2

    (D) 411

    p16

    Solution (CD):

    n n 1 n 21 1

    P P P2 2

    31 1 1 1 1

    P 22 2 2 2 2

    1 1 5

    8 2 8

    4 2

    41 1 1 1 1

    P 32 2 2 2 2

    1 1 3

    16 4 8

    1 4 6 11

    16 16

    3. Vectors a,b,c are three unit vectors and c is

    equally inclined to both a & b . Let

    2 2a b c b c a 4 x b 4xcos a ,

    then which of the following case be correct

    (a & b are non-collinear vectors, x 0 )

    (A) x 2 (B) 0

    (C) (D) x 4

    Solution (ABC):

    As c is equally inclined with a & b

    a.c b.c

    a.c b a.b c a.b c b.c a

    2 24 x b 4xcos a 2

    2

    a.c 4 x

    b.c 4x cos

    2 2x 2 4xsin

    x 2& x 0 sin 0

    4. In ABC with usual notations 2 2 2a 4 b 4c 4a 4bc then

    (A) Length of internal angle bisector of A is

    b Acos

    3 2

    (B) sinB

    2sinC

    (C) sinB 1

    sinC 2

    (D) Length of internal angle bisector of angle

    2b AA cos

    3 2

    Solution (AD): 2 2 2a 4a 4 b 4c 4bc 0

    2 2

    a 2 b 2c 0

    a 2,b 2c sinB

    2sinC

    Length of angle bisector of A

    A2bccos

    2

    b c

    2 Abcos

    3 2

    5. Let xe

    f xx

    then f x k has

    (A) 2 real solution when k e,

    (B) one real solution when k ,0

    (C) no real solution when k 0,e

    (D) 4 real solution when k 0,e Solution (ABC):

    xey

    x x R 0

    x

    x

    elim 0

    x ,

    x

    x

    elim

    x

    x x

    x 0 x 0

    e elim , lim

    x x

  • 27

    x

    2

    e x 1dy

    dx x

    6. Consider twice differentiable function f x

    such that f 1 3 , f 2 6 , f 3 9 then which of the following is/are true

    (A) f x 8 atleast one in 1,3

    (B) f x 3 atleast twice in 1,3

    (C) f x 0 atleast once in 1,3

    (D) f x 0 nowhere in 1,3 Solution (ABC):

    f x is continuous and f 1 3 , f 2 6 ,

    f 3 9

    f x must take all values between 3,9

    f x 8 for some x 1,3

    Let g x f x 3x

    g x is continuous and differentiable.

    g 1 g 2 g 3 0

    Rolles theorem holds in 1,2 and in 2,3

    1 2g c g c 0 where 1 2c 1,2 & c 2,3

    Now use Rolle‟s theorem on g x in 1 2c ,c

    g x 0 for atleast one 1 2x c ,c

    i.e., x 1,3

    7. If 2 2 2sin 2x cos 3y tan 4z sin2xcos3y

    cos3y tan4z tan4zsin2x 0 , where

    x,y,z 0,2

    then possible values of

    x y z is/are

    (A) 11

    12

    (B)

    7

    6

    (C) 5

    4

    (D)

    3

    2

    Solution (ABCD):

    2 2

    sin2x cos3y cos3y tan4z

    2

    tan4z sin2x 0

    sin2x cos3y 0,cos3y tan4z 0

    & tan4z sin2x 0

    sin2x cos3y tan4z 0

    2x n

    2m 1n kx ,y ,z

    2 6 4

    k m,n, I

    8. The value of 2

    2 2

    sec xdx

    a sec x btan x is

    (A) 11 b a

    sin tanx Cab a

    if b a 0

    (B) e1

    log tanx b ab a

    2 2cosec x btan x C

    if b a 0

    (C) 11 a b

    sin tanx Caa b

    if a b 0

    (D) e1

    log tanx a ba b

    2 2asec x btan x

    C if a b 0

    (where C is integration coust) Solution (AD):

    2

    2

    sec xI

    a a b tan x

    (i) if a b 0

    1

    n a b tanxa b

    2 2asec x b tan x

    (ii) if b a 0

    11 b aI sin tanxab a

    ************