Sodium Hypochlorite SDS - Apr 2016...Safety Data Sheet Sodium Hypochlorite Mountain Cleaning Products Issue Date: April 2016 Valid to: April 2021 Page 2 of 8 P273 Avoid release to

SafetyDataSheet

SodiumHypochloriteMountainCleaningProducts

IssueDate:April2016Validto:April2021

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SECTION1:IDENTIFICATIONOFPRODUCTANDCOMPANY

TradeName: SodiumHypochloriteSynonyms: Bleach,Chlorine

ChemicalFormula: NACASNumber: NAProductUses: Sanitising,disinfectingandbleachingagent

Supplier/Manufacturer: MountainCleaningProducts

Address: 7/7/SnowSt,SouthLismore,NSW2480Telephone: 0266228733

Fax: 0266228744Email: [email protected]

Website: www.mountaincleaning.com.auEmergencyTelephone: 131126(PoisonsInformationCentre)

SECTION2:HAZARD(S)IDENTIFICATION

GHSClassification: Corrosivetometals(Category1).Skincorrosion(Sub-category1C).Eyedamage(Category1).

LABELLINGELEMENTS:

SignalWord: DangerPictogram(s):

Corrosive

HazardStatements(s): H290Maybecorrosivetometals.H314Causessevereskinburnsandeyedamage.AUH031Contactwithacidliberatestoxicgas.

PrecautionaryStatement(s):

PreventionP234Keeponlyinoriginalcontainer.P260Donotbreathefumes/gas/mist/vapours/spray.P264Washhandsthoroughlyafterhandling.

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P273Avoidreleasetotheenvironment(unlessintendeduse).P280Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.ResponseP301+P330+P331IFSWALLOWED:Rinsemouth.DoNOTinducevomiting.P303+P361+P353IFONSKIN(orhair):Immediatelytakeoffallcontaminatedclothing.Rinseskinwithwater/shower.P363washcontaminatedclothingbeforereuse.P304+P340IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.P310ImmediatelycallaPOISONCENTRE(131126)ordoctor.P321Specifictreatment,seeFirstAidMeasuresonthisSafetyDataSheet.P390:AbsorbspillagetopreventmaterialdamageP391:Collectspillage.

Storage: P405Storelockedup.P406:Storeincorrosiveresistantcontainer.

Disposal: P501Disposeofcontents/containertoanapprovedwastedisposalplant.

SECTION3:COMPOSITIONANDINFORMATIONONINGREDIENTSIngredients CASNo.s Percentage(w/w) ClassificationWater 7732-18-5 >60% Sodiumhypochlorite 7681-52-9 10-13% H314+H400Sodiumhydroxide 1310-73-2 <1% H314SECTION4:FIRSTAIDMEASURES

FirstAidFacilities: Normalwashroomfacilities.Safetyshowerandemergencyeyewash.

EyeContact: Immediatelyirrigatewithcopiousquantitiesofwaterforatleast20minutes.Eyelidstobeheldopen.Seekmedicaladvice

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(e.g.ophthalmologist)ifthereareongoingsymptoms.SkinContact: Removecontaminatedclothing.Immediatelywash

contaminatedskinwithplentyofsoapandwater.Seekmedicaladviceifirritation,burningorrednessoccursandpersists.

Inhalation: Removevictimtofreshairawayfromexposure-avoidbecomingacasualty.Removecontaminatedclothingandloosenremainingclothing.Allowpatienttoassumemostcomfortableposition,keepwarmandatrest.Ifbreathinglabouredandpatientcyanotic(blue),ensureairwaysareclearandhavequalifiedpersongiveoxygenthroughafacemask.Ifbreathinghasstoppedapplyartificialrespirationatonce.Seekimmediatemedicaladvice.

Ingestion: DoNOTinducevomiting.DoNOTattempttogiveanythingbymouthtoanunconsciousperson.Rinsemouththoroughlywithwater.Givewatertodrink.Ifvomitingoccurs,givefurtherwatertoachieveeffectivedilution.Seekmedicaladvice.

AdvicetoDoctor: Nospecificantidote.Treatsymptomatically.Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressofthepatient.PoisonsInformationCentreineachAustralianStatecapitalcityorinChristchurch,NewZealandcanprovideadditionalassistanceforscheduledpoisons.

ScheduledPoisons: PoisonsInformationCentreineachAustralianStatecapitalcitycanprovideadditionalassistanceforscheduledpoisons.PhoneAustralia131126.

SECTION5:FIREFIGHTINGMEASURESFireandExplosionHazard: Non-flammable.Mayevolvetoxicgas(chlorine)whenheatedto

decomposition.ExtinguishingMedia: Ifmaterialisinvolvedinafireusefinewaterspray,oruse

normalfoamordryagent(carbondioxide,drychemicalpowder).

FireFighting: Keepcontainersexposedtoextremeheatcoolwithfinewaterspray.Firefighterstowearself-containedbreathingapparatusifriskofexposuretoproductsofcombustionordecomposition.

FlashPoint: None.HazchemCode: 2X

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SECTION6:ACCIDENTALRELEASEMEASURES

MinorSpills: Donotnormallyrequirespecialclean-upmeasures.Sweepupresiduesandrinseareawithwater.

MajorSpills: Forexampletransportaccidentorbulkspill.Clearareaofunprotectedpersonnel.Workupwindorincreaseventilation.Preventspillagefromenteringdrainsorwatercourses.Wearappropriateprotectiveequipment(seesection8)topreventskinandeyecontaminationandinhalationoffumes.Containspillage,thencover/absorbspillintodry,inertmaterial(e.g.sand,earthorvermiculite),collectandplaceintosuitablecontainers,appropriatelylabeled,fordisposalbyanapprovedagentaccordingtolocalconditions.Spillageareamayremainslippery.Flushspillareawithwater.Ifcontaminationofsewersorwaterwayshasoccurredadvisethelocalemergencyservices.Intheeventofalargespillagenotifythelocalenvironmentprotectionauthorityoremergencyservices.

PPE: PersonalprotectiveequipmentadviceiscontainedinSection8ofthisdocument.

SECTION7:HANDLINGANDSTORAGE

Handling: Avoidskinandeyecontactandavoidbreathinginvapours.Keepoutofreachofchildren.Alwayswashhandswithwaterafterhandling.

Storage: Storeinacool,dry,placewithgoodventilationandoutofdirectsunlight.Avoidstoringinaluminiumandalloycontainers.Storeawayfromincompatiblematerials(seeSection10).Keepcontainersclosedatalltimeswhennotinuse.

SECTION8:EXPOSURECONTROLSANDPERSONALPROTECTIONOCCUPATIONALEXPOSURELIMITS:Noneestablishedforthisproduct.Ingredient TWA STEL NotesSodiumhypochlorite 1ppm-3mg/m3 Notset Sodiumhydroxide 2mg/m3

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PersonalProtection: Overalls,chemicalgogglesorfaceshield,gloves(LONG).

Possiblyapronandrubberboots. EngineeringControls: Ensureventilationisadequate.Whereaninhalationriskexists,

mechanicalextractionventilationisrecommendedtomaintainvapourlevelsbelowrecommendedexposurestandard.

EyeandFaceProtection: Chemicalgogglesorfaceshield.HandandSkinProtection: WearimperviousPVCorrubbergloves(long)todispense.

Wearcoveralls.Whenusinglargequantitiesorwhereheavycontaminationislikely,wearrubberbootsandaPVCapron.

InhalationProtection: WhereaninhalationriskexistswearaTypeB(inorganicvapoursandgasses)respiratorthatmeetsAS/NZS1715andAS/NZS1716.

SECTION9:PHYSICALANDCHEMICALPROPERTIES

Appearance: Clearpaleyellowliquid

Odour: Chlorine VapourPressure: NotavailableOdourThreshold: Notavailable VapourDensity: Notavailable

pH: 12.5-13.5neat RelativeDensity(Water=1):

1.17-1.2@25°C

Melting/FreezingPoint:

Notavailable WaterSolubility: Soluble

BoilingPoint: 100°Capprox. PartitionCoefficientn-Octanol/Water

Notavailable

FlashPoint: Notrelevant Auto-ignitionTemperature

Notavailable

EvaporationRate: Notavailable DecompositionTemperature

Notavailable

Flammability: Notflammable Viscosity NonviscousUpper/LowerFlammability:

Notrelevant

SECTION10:STABILITYANDREACTIVITY

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Reactivity: Mayevolvechlorinegaswhenheatedtodecomposition.ChemicalStability: Stableunderrecommendedconditionsofstorage.

PossibilityofHazardousReactions:

Hazardouspolymerisationwillnotoccur.Reactsexothermicallywithacids.Reactswithammonia,aminesandammoniumsaltstoproducechloramines.Decomposesonheatingtoproducechlorinegas.

ConditionstoAvoid: Avoidcontactwithfoodstuffs;exposuretoheat,ignitionsourcesandopenflame;andexposuretodirectsunlight.Avoidcontactwithacidsandmixingwithotherchemicals.

IncompatibleMaterials: Acids,metals,metalsalts,organicmaterials(e.g.peroxides),reducingagents(e.g.amines),EDTA.

SECTION11:TOXICOLOGICALINFORMATION

Inhaled: Breathinginmistsoraerosolsmayproducerespiratoryirritation,coughing,nauseaandheadache.Delayed(upto48hours)fluidbuildupinlungsmayoccur.

SkinContact: Mayresultinirritation,redness,pain,rash,dermatitisandpossibleburns.

EyeContact: Corrosivetoeyes.Contactcancauseirritation;redness,cornealburnsandcanpossiblyresultinpermanentinjury.

Ingestion: Swallowingcanresultinnausea,vomiting,diarrhoea,abdominalpainandchemicalburnstothegastrointestinaltract.

AcuteToxicity: NoLD50dataavailableforthisproduct.Formainactiveconstituent,sodiumhypochlorite:OralLD50(mice)-5800mg/kgOralTDLo(woman)-1gm/kgIntravenousTDLo(man)-45mg/kg

Chronic: Noinformationavailable.SECTION12:ECOLOGICALINFORMATION

Ecotoxicity: Acuteaquatictoxicity(Category1).Verytoxictoaquaticlife.Avoidcontaminatingwaterways.LC50(fish)-0.07-5.9mg/l–48h.

Persistenceand Biodegradabletosaltandoxygen.

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Degradability:Bioaccumulative

Potential:Noneknown.

MobilityinSoil: Mayleachtogroundwaterwithresultanttoxicitytoaquaticorganisms.

OtherAdverseAffects: Noneknown.SECTION13:DISPOSALCONSIDERATIONS

DisposalMethods: RefertoWasteManagementAuthority.Disposeofmaterialthroughalicensedwastecontractor.Decontaminationanddestructionofcontainersshouldbeconsidered.

SECTION14:TRANSPORTINFORMATIONADGCodeClassification: DangerousGoods.

UNNo.: 1791ProperShippingName: HYPOCHLORITESOLUTIONTransportHazardClass: 8–Corrosive

PackingGroup: IIIHazchemCode: 2X

EnvironmentalHazardsforTransport:

Harmfultoaquaticlife.

SECTION15:REGULATORYINFORMATIONSUSMP(PoisonSchedule): S5CautionSECTION16:OTHERINFORMATION

Abbreviations: ADG–AustralianCodefortheTransportofDangerousGoodsby

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RoadandRail.CASNo.-ChemicalAbstractServiceNumberusedtouniquelyidentifychemicalcompounds.GHS-GloballyHarmonisedSystem.IARC-InternationalAgencyforResearchonCancer.LD50-LethalDose,50%/medianLethalDose.Mg/m3-Milligramspercubicmetre.PPM–Partspermillion.STEL–ShortTermExposureLimit.STOT-RE–SpecificTargetOrganToxicity(repeatedexposure).STOT–SE-SpecificTargetOrganToxicity(singleexposure).SUSMP–StandardfortheUniformSchedulingofMedicinesandPoisons.TWA/OEL–TimeWeightedAverageorOccupationalExposurelimit.

RevisionHistory: Rev1.0InitialSDSforGHScompliance.PreparedBy: MountainCleaningProductsRegulatoryService.

ENDOFSDS

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Sodium Hypochlorite SDS - Apr 2016...Safety Data Sheet Sodium Hypochlorite Mountain Cleaning Products Issue Date: April 2016 Valid to: April 2021 Page 2 of 8 P273 Avoid release to