106
Remedial Planning Activities _ at Selected Uncontrolled ^^vomlT^nngry Hazardous Substance Disposal \-^ \ ARCS Sites in Region I . /^j^'Ji/^ c^m iK-SS-; Environmental Protection Agency Region I ^ ^ ARCS Work Assignment No. 12-1JZZ Pownal Tannery Pownal, VT VTD069910354 TDD# 9209-27-ATX Site Inspection Prioritization Final Report December 1993 SDMS DocID 18574 TAMS Consultants, Inc. TRC PEl Associates. Inc Jordan Commumcalion Companies, Inc. U$"j •-

SITE INSPECTION PRIORITIZATION, FINAL REPORT. · 2020. 12. 1. · 1.0 introduction 1 2.0 site description ; 3.0 operational ant) regulatory history ant> waste ch.aracteristics f 4.0

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  • Remedial Planning Activities _ at Selected Uncontrolled ^^vomlT^nngry Hazardous Substance Disposal \-^ \ ARCS Sites in Region I . /^j^'Ji/^

    c^m

    iK-SS-;

    Environmental Protection Agency Region I

    ^ ^ ARCS Work Assignment No. 12-1JZZ

    Pownal Tannery Pownal, VT VTD069910354 TDD# 9209-27-ATX

    Site Inspection Prioritization Final Report

    December 1993

    SDMS DocID 1 8 5 7 4

    TAMS Consultants, Inc. TRC PEl Associates. Inc Jordan Commumcalion Companies, Inc.

    U $ " j •

  • SITE [NSPECTION PRJORJTIZATIQN

    POWNAL TANNERY

    POWNAL, VERMONT

    VTD069910354

    FINAL REPORT

    Prepared for

    U.S. ENVIRONMENTAL PROTECTION AGENCY

    Region I

    90 Canal Street

    Boston. Massachusetts 02203-2211

    Work .Assignment: 12-1 JZZ

    EPA Region: 1

    Contract No.: 68-W9-0033 (ARCS)

    TRCC Document No.: L93-1261

    TRCC Project No.: 1-636-013-0-1J03

    TDD No.: 9209-27-ATX

    TRCC Work Assignment Manager: Diane Stallings

    TRCC Task Manager: Joseph Schmidl

    Telephone No.: (508) 970-5600

    EPA Work Assignment Manager: Sharon Hayes

    Telephone No.: (617)573-5709

    Date Prepared: December 17. 1993

    TRC COMPANIES. INC.

    Boon Mills South

    Foot of John Street

    Lov>ell. Massachusetts 01852-1124

    (508) 970-5600

  • DISCLAIMER

    This report is intended for use solely by the U.S. Environmental Protection .Ager.cy for the specific purposes described in the contractual documents between TRC EnvLronmenial Corporation and the U.S. Environmental Protection Agency. All professional serMces performed and reports generated by TRC have been prepared for the U.S. Environmental Protection Agency purposes as described in the contract. TTie information, statements and conclusions contained in the report have been prepared in accordance with the work statement and contract terms and conditions. The repon may be subject to differing interpretations and/or may be misinterpreted by third persons or entities who were not involved in the investigative or consultation process. TRC Environmental Corporation therefore, expressly disclaims any liability to persons other than the U.S. Environmental Protection Agency who may use or rely upon this report in any way or for any purpose.

    L93-1261.Lxt

  • TABLE OF CONTENTS

    Section Page

    1.0 INTRODUCTION 1

    2.0 SITE DESCRIPTION ;

    3.0 OPERATIONAL ANT) REGULATORY HISTORY ANT> WASTE

    CH.ARACTERISTICS f

    4.0 WASTE/SOURCE SAMPLING 1!

    5.0 GROUND WATER PATHWAY U

    6.0 SURFACE WATER PATHV^'AY 1 >

    7.0 SOIL EXPOSURE PATHWAY 2:

    8.0 AIR PATHWAY : •

    9.0 SUMMARY ; ^

    10.0 REFERENCES Z"

    Appendices j Pact-

    A Ground Water and Dnnking Water Sample Analytical Results •X '.

    B Ground Water. Drinking Water and Surface Water Sample Analytical Results . B ; C Drinking Vv'ater Sample Analytical Results. January 19. 1991 C-; D Drinking Water Sample .A.nalytical Results. April 10, 1992 D ; E Lagoon Sludge. Soil, and Drum Sample Analytical Results E : F Lagoon Sludge and Sediment Sample Analytical Results F-:

    L9?- i :6 i .Lxt i i i

  • TABLE OF CONTENTS (CONTI.NX'ED)

    TABLES

    Number Page

    1 Source Evaluation for Pownal Tannery 7 2 Hazardous Waste Quantity for Pownal Tannery 8 3 Summary of Source Samples Collected by EPA Removal Program from

    April 28-29, 1993 11 4 Sample Summar>': Pownal Tannery Source Samples Collected by TRCC on

    June 9, 1993 13 5 Summar\' of Analytical Results: Source Sample Analysis for Pownal Tanner>' . . . 14 6 Public Ground Water Supply Sources Within Four Miles of Pownal Tannery . . . . 1~ 7 Estimated Drinking Water Populations Served by Ground Water Sources

    Within Four Miles of Pownal Tannery 17 8 Water Bodies Within the Surface Water Segment of the Pownal Tannery

    Propert)^ Zd 9 Sample Summar>': Pownal Tannery Samples Collected by TRCC on June 9.

    1993 : i 10 Summary of Anal> tical Results: Sediment Sample Analysis for Pownal

    Tannery 22

    11 Estimated Population Within Four Miles of Pownal Tannery 23

    FIGURES

    Number Page

    1 Location Map 3 2 Site Sketch 4

    L93-1261.L\t iv

  • 1.0 INTRODUCTION

    TRC Companies, Inc. (TRCC) v.as requested by the Region 1 U.S. Environmental Protection

    Agency (EPA) Waste Management Division to perform a Site Inspection Prioritizadon of die

    Pownal Tannery property in Pownal. Vermont. Tasks were conducted in accordance with the

    TDD No. 9209-27-ATX, the Site Inspection Prioridzation scope of work, and technical

    specificanons provided by EPA under Work Assignment No. 12-1 JZZ, which was issued to

    TRCC on December 25. 1992. A Screening Site Inspection (SSI) of the property was

    prepared by NUS/FIT on December 20, 1989 (1). On the basis of information provided in

    the SSI report, the Pownal Tanner\ Site Inspection Prioritization (SIP) was initiated.

    The following tasks were performed in order to complete the SEP.

    TRCC conducted a file search at the Vermont Agency of Natural Resources (VT AN'R) in order to update information pertaining to the Pownal Tannery propeny and \ icin:;_\.

    TRCC conducted site reconnaissance at the property on May 3, 1993 in order to document cunent site conditions and identify sample locations.

    S TRCC conducted en\u-onmental sampling at the property on June 9. 1993.

    This package follows the guidelines developed under the Comprehensive Environmental

    Response, Compensation, and Liability Act of 1980 (CERCLA). as amended, commonly

    referred to as Superfund. Ho>Ae\er. these documents do not necessarily fulfill the *

    requirements of other EPA regulations such as those under die Resource Conservation and

    Recovery Act (RCRA) or other Federal. State, or local regulations. Site Inspection

    Prioritizations are intended to provide a preliminary screening of sites to facilitate EPA's

    assignment of site priorities. They arc limited efforts and arc not intended to supersede more

    detailed investigations.

    193-1261.1X1

  • 2.0 SITE DESCRIPTION

    The Pownal Tannery site is located in Pownal, Bennington County, Vermont at 42' 4"" 49.S'

    north latitude and 73° 15' 56.7' west longitude (2) (Figure 1). The Pov,nal Tannery property

    is located in the Village of Nonh Pownal, between the Hoosic River and State Route 346

    (Figure 2). TTie propeny was the site of a cow and sheep hide tanning operation from circa

    1937 until 1988, and is currently inactive (3, 4). The owner of record for the propeny is the

    Pownal Tanning Company, which is now bankrupt (4).

    Three potential source areas have been identified at the Pownal Tannery propeny; the

    lagoons, the landfill, and the former tannery building. Five lagoons are located at the

    nonhern end of the propert>. Lagoon #1 was closed in place in 1983 by covering with si.\ to

    18 inches of clay cover material (3). The surface of Lagoon #1 subsequently sank, forming a

    depression on die top of the cover, and the depression is currently filled with water, in which

    wedand vegetation lives (3. 4). An undocumented amount of sludge was removed from

    Lagoon #2 and disposed of m the landfill (I), Lagoon #2 is currcnUy full of water (4).

    Lagoons #3A and #3B were capped in place with 12 inches of clay circa 1982^3).

    Containers of fuel oil, sawdust, rags, lignosulfonate filler, finishing materials (including

    associated solvents), burned wood. soot, and chromium III crystals were discovered in

    Lagoons #3A and #3B in 1984, and were removed (3). Lagoon #4 is uncovered and mostly

    without water. Gray-green sediment is exposed on the bottom of the lagoon (4). Lagoon #5

    is currently filled with water. Currentiy, leachate collected from the leachate collection

    system beneath the landfill is disposed of in Lagoon #5. An outflow channel exists which

    periodically allows water from Lagoon #5 to discharge to the Hoosic River (4).

    TRCC personnel noted in 1993 that a breach in the bcrm at the nonhern end of Lagoon # 4

    allows surface water to discharge to the Hoosic River during periods of high water in the

    lagoon. EPA personnel onsite during the Spring of 1993 observed the discharge to the

    Hoosic River at this breach (4i. .Also, ground water seeps were noted on the outside of the

    nonhern berm which contains Lagoon #2, The water flowing from these seeps had collected

    L93-1261.LXI 2

  • LAGOONS

    Wal«f Suppty Wed ^ (scr««n«d inltrval unknown)

    BASE MAP IS A PORTION OF THE FOLLOWING USGS 7.5' SERIES QUADRANGLES:

    POWNAL, VT, 1954; NORTH POWNAL, VT-NY, 1957, PHOTOREVISED 1980

    0 1000 2000 3000

    QUADFIANGLE LOCATOR SCALE-feet

    LOCATION MAP TC Companies, Inc POWNAL TANNERY

    POWNAL, VERMONT Figure 1.

  • 0 t Trees Clanfier Building • «« . . — ̂

    ^ ̂ Seep/lnterminent Stream'Direcoon of Fiow Ji

    ^ Grass Press Building

    •"0

    Sediment Sample Locanon

    Monitoring Well (screened in ovefburae".

    ^ ];

    ^ •̂

    _ Bridge

    I I

    ^ ̂

    Railroad Trac»ii

    Steanv Direcnon ot Flow -M/ A » ! i '

    O'

    Drinking Water Well (screened interval unKpown) —X—

    „ i i .. Fenw

    _ _ - ' — — 1 Slope (ticks indicate downhill) C ] A a * -

    " " M X Fence Gate

    SITE SKETCH TIC POWNAL TANNERY POWNAL, VERMONT Figure 2.

  • in a small pond in the cornfield immediately adjacent to Lagoon ~1 (4). Finally, a pipe

    protruding from the berm separating Lagoon #1 from Lagoon #5 v. as noted to be discharging

    water to Lagoon #5 (4).

    A landfill, constructed in 1982 to dispose of sludge collected in the lagoon, is located at the

    southern end of die property (1, 4, 53). The landfill is approximately 54,100 square feet in

    size (53). The landfill is equipped with a hypalon liner and a leachate collection system (1,

    53), The landfill consists of three cells, two of which are capped v.ith local material and

    vegetated. The third cell is not complete, and the uncapped portion forms a depression where

    wedand vegetation grows (4. 53). Leachate generated by the landfill is collected by the liner

    and directed to a 6000-gallon steel underground storage tank (53). The leachate is collected

    periodically and trucked to Lagoon #5. where it is discharged (4. 53). VT ANR personnel

    suspect that the leachate collection system leaks and began investigating the system during

    Fall 1993 (53. 55).

    TRCC personnel observed that ground water seeps exist at several points along the base of

    the slope bcDAcen the landfill and the wetlands along the Hoosic River (4). In addition, three

    of the five ground water monitoring wells were identified in the vicinity of the landfill.

    Two large buildings, 169.915 and 16.902 square feet in size, are located in the center

    propeny, in proximity to the bridge crossing the Hoosic River. (4: 5) (Figure 2). The larger

    building, the former tannery, was built in approximately 1880 and was used as a woolen mill

    until circa 1937. The other building was a warehouse. The former tannery building has a

    brick foundation and wooden walls aboveground. The building is four stories tall, including

    .the basement (4). The former tannery building is in poor condition, with broken windows,

    missing doors, and a leaking roof which allow precipitation to infiltrate the building (4).

    Water migrates through the building from top to bottom, and collects in a trench which runs

    the length of the former tannery building (4). The trench apparently discharges to the Hoosic

    River at both the nonhern and southern ends of the building (6). A ground water spring was

    noted in the cobblestone fioor of the basement, which indicates that the floor of the basement

    is not impermeable to water (4).

    L93-1261.L\t 5

  • Following the bankruptcy of the Pownal Tanning Company, approximately' 12.830 pounds of

    hazardous materials were abandoned within the former tannery building ("). The materials

    were stored throughout the building in containers of various sizes. TRCC obser\ed the

    containers during site reconnaissance on June 9, 1993, as they were being collected in a

    central area at the nonh end of the former tannery building. Because of the infdtiation of

    water through the building, the containers were subject to releases of hazardous substances to

    the Hoosic River. During TRCC field activities, EPA Emergency Planning and Response

    Branch personnel were directing OHM personnel in the removal of hazardous materials from

    the former tannery building during a rime-critical removal action. Containers of hazardous

    materials were collected, categorized, grouped according to compatibilit\. and shipped offsite

    for disposal on May 20 and June 24, 1993 (7).

    3.0 QPERATIONAL AND REGLL.ATORY HISTORY AND WASTE CHARACTERISTICS

    Previous investigations have summarized the operational and regulatory history of the

    property through 1988 (1). Since 1989, the Vermont Attorney General's Office has begun

    preparation for litigation against two companies, John Flynn & Sons, Inc. and Pownal

    Tanning Company. Both corporations are bankrupt, have no assets, and their chaners have

    been revoked (8).

    Table 1 presents all identified structures or areas on the Pownal Tanner)' propert)' which are

    potential sources of contamination, the containment factors associated with each source, and

    the relative location of each source. Table 2 summarizes the types and amounts of hazardous

    materials used, stored, and/or disposed of on the propeny.

    The following summarizes activiues at the propeny since the completion of the SSI in 1989.

    • Vermont Agenc\ of National Resources (VT AMI) personnel collected samples of water from Lagoons #4 and #5, ground water monitoring wells L-9 and L10. and two residential drinking water wells on (Dctober 11. 1990 (11). All samples except for the residential wells were analyzed for the following: volatile organic compounds (VOCs) by EPA Method 8240. semi-volatile

    L93-1261.L\i 6

  • TABLE 1. SOURCE EVALUATION FOR POV -̂NAL TAN-NERY

    Spatial

    Potential Source Area Containment Factors ; Location

    Lagoons Divided by berms constructed of sandy Northern end of material, which are breached to the the propert\-. Hoosic River; no liners; Lagoons #1, #3A, and #3B closed and capped.

    LandfiU H>'palon liner and functioning leachate Southern end of collection system; monitoring wells which the propertv. have not been sampled; no run-on/runoff control: incomplete landfill cap. 11

    1

    Former Tannery Incomplete protection from precipitation. Center of the Building due to deterioration of roof and walls: propeny.

    ground water spring in basement, which adjacent to the

    tlows via trenches to the Hoosic River; nonh bank of

    hazardous materials inside the building are the Hoosic

    mostlv uncontained. and are in contact Ri\er

    uith the fiow-through of precipitation and

    ground water.

    (4:8)

    organic compounds (SVOCs) by EPA Method 8270. and dissolved chromium and lead. The t̂*. o drinking water samples w ere analyzed for VOCS by EP.A Method 8240 onl> No compounds were detected above detection limits (12)' Complete analytical results are included in Appendix B.

    VT A.NR personnel collected samples of drinking water from three residential drinking water v^ells on January 10, 1991. Samples were analyzed for VOCs by EPA Method 8240. No compounds were detected above detecnon limits (13). Complete analytical results are included in Appendix C.

    VT ANR personnel collected samples of drinking water from at least two residential drinking water wells on April 10, 1992. Samples were analyzed for VOCs by EP.A .Method 8240. No compounds were detected above detection limits (14; 15). Complete analytical results are included in Appendix D.

    EPA Removal Program personnel collected seven samples of lagoon sludge, two samples from the former tanner>' "screen house", and one sample each from the sludge pit. clanfier. and a pentachlorophenol drum in the vicinity of the lagoons on .April 28 and 29. 1993. Samples were collected from Lagoons

    L93-1261.UM

    http:L93-1261.UM

  • TABLE 2. HAZARDOUS WASTE QUA.NTITY FOR POWNAL TA.N-N'ERY

    Substance

    Tannery Sludge

    Tannery Discharge Water

    Ammonium hydroxide

    Ammonium persuJfaie

    Asbestos

    Cyanide sail

    Ethanoi

    Hydrochloric acid

    Hydrogen peroxide

    Magnesium persulfaie

    Methyl ethyl ketone

    Mercuric sulfate

    Mercury iodide

    Quantity or

    Volume/Area

    unknown

    250.000 to 300.000 gallons per month (penod of discharge rate uncertain)

    unknown

    20C>'| pounds

    ISC"' pounds

    15 pounds

    unkno'A n

    unknov^n

    unknoy.n

    unknown

    ut\knov».n

    unknown

    15 pound*;

    Years ofUse Storage

    1930-sio present

    1930's to 1988

    unknown to 1988

    unknown to 1988

    unknown to 199?

    unknown to 1988

    unknown to 1988

    unknown to 1988

    unknown to 1988

    unknown to 1988

    uf\known to 1988

    unknown to 1988

    unknown to 1988

    i Years of Disposal

    1930"s to 1988

    1930's to 1988

    1988 to 1993

    1988 to 1993

    Not disposed of onsite

    1988 to 1993

    1988 to 1993

    1988 to 1993

    1988 to 1993

    1988 to 1993

    1988 to 199?

    1988 to 1993

    1988 to 1993

    Source Area

    direct outfaU to Hoosic Rjver. 1930-s to 1963: Lagoons. 1963 to present;' Landfdl. 1982 to present

    direct outfaU to Hoosic Rjver. 1930's to 1963; Lagoons, 1963 to present i

    1

    containers. Former i Tannery Building i

    containers. Former ' Tanner. Building

    used as insulation. Former Tannery Building j

    containers. Former Tannery Building

    containers. Former Tannery Building

    containers. Former Tannery Building

    containers. Former Tannerv- Building

    containers. Former 1 Tannery Building

    containers. Former Tannery Building

    containers. Former Tanner\' Building

    containers. Former Tannery Building

    L93-I261.txt

  • T.ABLE 2. (CONTINUED)

    Substance

    Mineral spirits

    Muriatic acid

    Nitric acid

    Petroleum distillates

    Phenol

    Phosphoric acid. solution

    Potassium nitrate

    Silver nitrate

    Sodium azide

    Sodium hydroxide, solid and liquid

    Sodium h>'pochlorite

    Sodium peroxide

    Sulfide compounds, liquid and solid

    Sulfuric acid

    Toluene

    1.1,1tnchloroethane. solubon and bquid

    QuaDtit\ or Years of \olume'Area Use/Storage

    1 unknown unknown to 1988

    unknown unknown to 1 1988

    unknown unknown to 1988

    650 pounds unknown to 1988

    unknown unknown to 1988

    150 pounds unknown to 1988

    400 pounds unknown to 1988

    unknc^n unknown to 1988

    unkno'An unknown to 1988

    1410 p îunds unknown to 1988

    1550 pounds unknown to 1988

    unknown unknown to 1988

    1300 pounds unknown to 1988

    unknown unknown to 1988

    unkno^^n unknown to 1988

    2150pkiunds unknown to 1988

    Years of Disposal

    1988 to 19^ '̂

    1988 to 1993

    1988 to 199?

    1988 to 1993

    1988 10 199?

    1988 to 199?

    1988 to 199?

    1988 to 199?

    1988 to 1993

    1988 to 1993

    1988 to 199?

    1988 to 1993

    1988 to 1993

    1988 to 1993

    1988 to 1993

    1988 to 199?

    Source Area

    conuiners. Former Tannery Building

    coniainers. FormerTannery BuiJdin ̂

    1

    j| j

    coniainers. Former Tannery BuJJing

    coniajners. Former Tanner. Buildink.

    coniainers. Former Tanner. Budding

    containers. Former Tannery Building

    containers. Former Tannerv Budding

    containers. Former Tannen' Budding

    containers. Former Tannerv' Budding

    containers. Former Tannen Budding

    containers. Former Tannery Budding

    containers. Former Tannery Budding

    containers. Former Tanner. Building

    containers. Former Tannery Budding

    containers. Former Tannery Budding

    containers. FormerTannery Budding

    il

    L93-126I.txt

  • TABLE 2. (CONTIN'UED)

    Quantity or Years of Years of Substance Volume Area Use'Storage Disposal Source Area

    Waste baneries. 50 pound> unknown to 1988 to 199? containers. Former filled widi acid 1988 Tanner. Budding

    Xylenes unknown unknown to 1988 to 1993 containers. Former 1988 Tannery Budding

    (4; 7; g; 9^

    #2. #4, and #5. Two trip blank samples, a matrix spike/macrix spike duplicate sample, and duplicate samples were collected for quality control. Samples were analyzed for Target Compound List (TCL) VOCs by EPA Method 824(i. SVOCs by EP.A .Method 8270, pesticides and polychlorinated biphenyls (PCBs). dioxins and furans. and Target Analyte List (TAL) Metals (16). Complete analytical results are included in Appendix E. A location map fc: the sediment samples collected from the lagoons is also included (17; 18; Ivi

    On May 24. 1993, a memorandum was complied by VT ANR. DEC. Solid Waste Division personnel which outlined the construction, history, and current status of the landfill. Included in this memorandum were a number of options for closure of the three landfill cells and treatments of the vicinit}' of the landfill (53).

    On .August 9, 1993. VT ANR. Department of Environmental Conservation. Hazardous Matenals Management Division personnel drafted a memorandurr, summarizing proposed uork to be completed at the Pownal Tannery Lagoons site. Funding for the work wiU be provided from the settlement of a lawsui: against the owners of the property and an escrow account set up by the ouners for closure and maintenance of the landfill. Tasks included in the proposal include:

    removal of 14 transformers from the property;

    cleanup and removal of #6 fuel oil located in the former tannery

    building;

    repair of three monitoring wells (L-1. L-2 and L-15);

    one round of ground water sampling:

    collection of surface water and sludge from Lagoon #5;

    a ground uater fiow/transpon study, which would include the

    insullaticn of two additional deep overburden wells, slug tests to

    determine aquifer characteristics, ground water sampling, and ground

    water modelling;

    investigation of a possible breach of the leachate collection system and

    repair of the breach (54).

    L93-126I.LM 10

    http:L93-126I.LM

  • Reponedly. this work began in September 1993 with the repair of monitoring wells, removal of #6 fuel oil and investigation of the landfill liner (55).

    4.0 WASTE/SOURCE SAMPLING

    The EP.A Removal Program collected seven samples of lagoon sludge from the three

    unfenced lagoons on April 28 and 29, 1993 (16). EPA Removal Program personnel also • • . ^ '

    collected four sludge samples from the clarifier screen house basement pit. These samples

    were analyzed through the Contract Laboratory Program for TCL VOCs; SVOCs which

    include base/neutral acid extractables and PCBs and pesticides; dioxins; furans; and TAL

    Metals and cyanide (16). Complete analytical results for these samples are included in

    Appendix E.

    Table 3 summarizes the analytical results of EPA's field activities. The validation repons for

    the organic data fraction did not include sample quantitation limits (SQLs), therefore organic

    compounds detected were compared uith contract required quantitatioti limits (CRQLs). Due

    to the nature of the lagoon samples, a background sample was not available for reference

    comparison. Therefore, all compounds and elements present in the lagoon samples were

    compared to CRQLs or CRDLs. as appropriate.

    TABLE 3. SUMM.ARY OF SOLT^CE SAMPLES

    Collected by EPA Removal Program from April 28-29, 199?

    Substance Concentration Location |

    MATRIX: Sludge

    mediylene chloride 92 J pg/Kg L5A

    2-butanone 730 J pg/Kg L5A

    phenanthrene 430 J pg/Kg L4A

    fluoranthene 750 pg/Kg L4A

    pyrene 460 pg/Kg L4A

    benzo(a)andiracene 330 J pg/Kg lAA

    chrysene 330 J ug/Kg L4A

    bis(2-ethylhexyl)phthalate 840 J pc/Kg L5A

    di-n-ocr>iphdialate 87 J p ^ g L5A

    benzo(k)nuoranthene 360 J pg/Kg L4A

    heptachlor 8.1 J pg/Kg L5A

    heptachlor epoxide 66 J pg/Kg L5A

    L93-126I.L\[ 11

  • TABLE 3. (CONTINUED)

    Substance Concentration Location

    endrin 7.8 J ti2./Ke L:B endrin aldehyde 4.5 I Mg.'Kg L4B Aroclor-1266 97 PS/Kg L4A chromium 10200 mg/Kg L5A cobalt 23.4 mg^g L5A

    ! lead 367 .F mg/Kg L5A 1,2,3.6,7,8-hexachlorinated dibenzo dioxin 1.85 ppb L5A 1.2.3.4.6.7,8-hepiachlorinated dibenzo dioxin 22.14 ppb L5A octachlorinated dibenzo dioxin 156.88 ppb L5A 1 1.2,3.4.6.7,8-heptachlorinated dibenzofuran 2.60 ppb L5A 1 octachlorinated dibenzofuran 7.59 ppb L5A

    MATRIX:-SOHr ^ U i ̂ (

  • TRCC personnel collected two sediment samples (SD-03-C'3 and SD-03-04) from different

    locations in the vicinity of the lagoons at the propeny on June 9, 1993, The samples were

    analyzed for-TCL VOCs and SVOCs. which include base-neutral/acid extractables (BN.Abi;

    pesticides and PCBs; and TAL inorganics, including cyanide, under Routine .Analytical

    Services (RAS) Case Number 20136. A description of the sample locations collected by

    TRCC personnel is presented in Table 4; the locations of these samples are depicted on

    Figure 2.

    TABLE 4. SAMPLE SUMMARY: POWNAL TAN-NERY

    Source Samples Collected by 1 RCC on June 9, 1993

    Sample Traffic

    Location No. Report No. Time Remarks Sample Location

    1 SD-G3-03 AFH27, 12:05 grab 0'-3 ' Sediment sample collected MADA2^ from Lagoon #5 outfall

    channel to the Hoosic River,

    SD-03-04 AFH28 14:12 grab 0 '-3 ' Sediment sample collected ' MADA27 from a seep located between

    Lagoons #1 and #5.

    RB-03-10 AFH34 13:30 grab 0'-2' Equipment rinsate blank MADA33 sample collected for quality

    control.

    Table 5 summarizes compounds and elements detected in source samples collected by TRCC

    Listing of a compound or clement is based upon its detection at a concentration which is at

    least three times greater than the concentration of the same compound or clement in a

    reference sample. If the compound or clement was not detected in a reference sample, the

    sample quantitation limit (SQL) or sample detection limit (SDL) is used as a reference value;

    the compound or clement is listed on the table if its concentration is greater than or equal to

    the SQL/SDL. Complete analytical results for samples collected by TRCC arc contained in

    Appendix F.

    L93-1261.txi 13

  • TABLE 5. SUM.M.ARY OF ANALYTICAL RESULTS; SOURCE SAMPLE

    ANALYSIS FOR POWNAL TANNERY

    Sample Location Compound/' Reference

    No. Element Concentration Concentration Comments

    , SD-03-03 benzo(b)fluoranthene 790 pg/Kg 630 ugXg 1,3 X SQL benzo(k)fluoranthene 790 pg/Kg 6?ri Mg.Kg 1? xSQL Aroclor-1254 170 J pg/Kg 6? ugKg 2.7 X SQL

    SD-03-04 chromium 659 mg/Kg 2,0 mgKg 330 X SDL

    (17. 18, 19) fig/lcg = micrograms per kilogrxTi mgylcg = milligrams per kilogra-Tis SQL = Sample Quantitation Limit SDL = Sample Detection Limi;

    5.0 GROUND WATER PATHWAY

    Native soils at die property have been removed or modified by construction activities (4),

    Soils are mapped as Copake and Hartwell well-drained soils, indicating that surface water

    tends to percolate into the soil instead of ponding on the surface (20).

    Overburden material at the property' is mapped as recent alluvium and fluvial gravel and is

    composed of stratified drift underiain locally by glacial till (21). Soil borings completed in

    the vicinity of the lagoons indicate that overburden is comprised of silt, silty sand, and fine

    sand which overlie coarse sand and gravel, which overlie grey clay, deposited in honzontalK

    discontinuous layers by glaciofluvial processes (22), The landfill is located on a glaciofluvial

    terrace where five to ten feet of coarse sand and gravel overlie fine sand and silt. Before

    construction of the landfill, fill was added to assure that ten feet of material separate the top

    of the water tabic from the bottom of the landfill (53). No subsurface data is available in the

    vicinity of the former tannery building. Overburden deposits beneath the property are up to

    40 feet thick (22. 53).

    L93-1261.1X1 14

  • The depth to ground water beneath the lagoons is less than 10 feet (22), Based on ground

    water elevations recorded during previous ground water sampling rounds (data from

    overburden wells exclusively), the direction of ground water flov. in o\erburden is westv\ard

    toward the Hoosic River. A steep hydraulic gradient is noted in the vicinity of monitonng

    wells L-7 and L-8 (23). Water level elevations in the five overburden monitoring wells in the

    vicinity of the landfill indicate that ground water flow is from west to east, touard the Hoosic

    River (53). No ground water elevation data is available for wells completed in bedrock in the

    vicinity of the property.

    Bedrock in the vicinity of the propeny is mapped as the Cambrian St. Catherine Formation,

    composed of purple to gray-green variegated slate and phyllite. with minor quartzite (24),

    The depth to bedrock beneath the property is unknown, but bedrock outcrops occur along the

    south bank of the Hoosic River opposite the former tannery building and the lagoons (4),

    Parts of the following towns are located within four radial miles of the potential source areas

    at the propeny: Bennington, VT (population 15,230), Hoosic, NT (population 6629),

    Petersburg. NT (population 1461). Pownal VT (population 3485), and Williamstown. M.A

    (population 8220) (25; 26: 27; 28: 29; 30; 31). The parts of Bennington. VT, Hoosick, NY,

    Petersburg, NT, and Williamstov.n, MA which are located widiin four radial miles of the

    property have no public water supplies, and all residents rely upon private drinking water

    weUs (25; 26: 27; 32).

    The Town of Pownal, VT has seven small public water supplies located within four radial

    miles of the property (33). Two of these supplies, the Pownal Tannery Water Company and

    the Pownal Water Company, obtain 100 percent of their supply from surface water sources

    which are not located along the downstream surface water pathway from the propeny. TTie

    remaining five supplies rely 100 percent on ground water sources for drinking water; one

    supply has two ground water sources in approximately the same location. Interim Wellhead

    protection areas (3000-foot radiusi apply to all four public drinking water wells (34).

    L93-1261.txt 15

  • The population using ground water was estimated as follows. Distance rings were measured from

    th; outer edge of the three potential source areas, which are separated by approximately 1.3 miles:

    this leads to non-circular distance rings. Population within each distance ring was estimated by

    conducting housecounts, using the best information available for each toun, and multiplying the

    number of houses per ring by the 1990 U.S. Census persons per household value for each town (8;

    25; 26; 27; 32). Then, persons relying on non-ground water sources of water in each ring were

    subtracted from the population apportioned to the ring. The remainder of the population was

    concluded to rely on a combination of public and private ground water sources for drinking water

    (32). The population using public ground water was identified from available Vermont Division of

    Water Quality records; the remainder of the population apportioned to each ring was presumed to

    relv on private drinking water sources located in the same distance ring as each home (32; 33).

    Table 6 summarizes the public ground water supply sources located within four radial miles of the

    property, and Table 7 summarizes the estimated drinking water population served by ground water

    supplies located within four radial miles of the property.

    Private drinking water wells in the vicinity of source areas on the propeny are completed in ei[her

    overburden or bedrock; due to the age of many of these wells, limited information regarding the

    completion interval of private drinking water weUs is available (8. 53). Review of available well

    completion records indicate that 14 of 18 North Pownal wells recorded since 1966 are completed

    in bedrock, with the remainder completed in overburden (55). These 18 wells are the only wells

    of approximately 100 private drinking water wells located within 0.5 miles of the property for

    which drilling records exist (25; 26; 27; 28; 29; 32; 33; 55).

    Extensive ground water sampling has been conducted at the propeny since 1986, Based on the

    results of these investigations, the Screening Site Inspection determined that a release of hazardous

    substances to ground water beneath the propeny has occurred from the lagoons

    (1). Ground water sampling dau collected since 1989 supports previous conclusions regarding

    ground water releases from the lagoons. A drinking water sample collected from a nearby

    residence on May 4, 1988 indicated the presence of dioxin at 34 picograms per liter (parts per

    trillion) (56). However, this result could not be duplicated during subsequent sampling. Private

    wells in the vicinity of the lagoons have been shown to be uncontaminated by sampling conducted

    from 1989 to 1992 (12.13.14.15). Due to the availability of data from previous investigations, no

    ground water samples were collected by TRCC.

    L9--1261,txi 16

    http:12.13.14.15

  • TABLE 6. PUBLIC GROUND WATER SUPPLY SOURCES \MTHIN FOUR MILES OF POWNAL TANNERY .

    Distance/ Direction Location Estimated

    from Property Source Name of Source Population Served Source Type

    1.7 miles Pownal Elementary' Pownal 380 Bedrock well East School

    2.05 miles Alia Gardens Estates Pownal 135 Bedrock Well Southeast

    2.3 miles Lampman Water Pownal 87 Spnng East System

    2.7 miles Evergreen Mobile Pownal 26 Bedrock w,ell Southeast Home Park

    2.8 miles Royal Pine Villa Pownal 10(J Bedrock well Southeast 1

    3.4 miles Barter's Pond Trailer Pownal 75 Bedrock well East Park. WeU =1

    1

    3.4 miles Barber's Pond Trailer Pownal 75 Overburden v-ili East Park. WeU <

    (28; 29; 32; 33)

    TABLE 7. ESTIMATED DRINKING WATER POPLT.ATIONS SERVED BY GROUNT) WA lER SOURCES WITHIN FOUR MILES OF POWNAL TANTsTRY

    Total Estimated j Radial Distance Estimated Population Estimated Population Population Served b\ j

    From Pownal Tannery Ser\ed bv Private Served by Public Ground Wafer Source> (miles) Wells Wells Within the Rin}!

    0.(X)-0.25 169 0 169 : {

    0.25-0.50 273 0 273

    0.50-1.00 219 0 219

    1.00-2.00 376 380 756

    2.00-3.00 662 348 1010

    3.00-4.00 1011 150 1161

    TOTAL 2710 878 3588

    (2.^; 26; 27; 28; 29: 32: 3?i

    L93-1261.LXI 17

    file:///MTHINhttp:3.00-4.00http:2.00-3.00http:1.00-2.00http:0.50-1.00http:0.25-0.50http:0.(X)-0.25

  • No ground water elevation data is available for bedrock in the vicinity of the lagoons and no

    ground water elevation data is available for the vicinity of the landfill and the former tanner)'

    building. Because of the lack of information regarding ground water flou direction and the

    actual completed interval of most private drinking water wells, no conclusions may be made

    regarding the possibility of private drinking water wells located downgradient of these source

    areas.

    6.0 SURFACE WATER PATHWAY

    The three potential source areas on the property are located adjacent to the Hoosic River, over

    a stream distance of approximately 1.5 miles (Figure 1). Each potential source area has

    different containment characteristics to surface water. Tlie lagoons were designed to release

    effluent water to the Hoosic River from a channel located at the southwestern comer of

    Lagoon #5. Lagoon #5 periodically releases water to the Hoosic River (4). A breach has

    developed at the northwest corner of Lagoon #4. which also periodically releases water to th,e

    river. Parts of the lagoon system are located belov^ the 100-year flood elevation (35).

    The landfill does not have a run-oa'runoff collection system, and the cap is incomplete.

    Surface water has ponded within cell #3 at the landfill, and wetland vegetation {Typha. spp..

    Phragmites, spp.) has developed in the pond (4). In addition, precipitation enters the landfill

    since the cap is incomplete and contacts the sludge disposed of in the landfill, creating

    leachate. VT ANR personnel suspect that die leachate collection system beneath the landfill

    leaks, and may be discharging leachate to the subsurface (53. 55). Leachate and/or ground

    water beneath the landfill comes to the surface in seeps noted along the slope downhill of the

    landfill (4). Surface water runoff from the landfill combines with ground water seeps at the

    base of the slope below the landfill, and flows through wetlands located adjacent to the

    Hoosic River for approximatelv 350 feet to discharge to the Hoosic River (4).

    Tlie sources of water within the former tannery building include both precipitation which

    infiltrates the building through the roof walls and windows and a ground water spring which

    is located in the basement of the building (4). This water comes in contact with poorly

    L93-1261.L\i 18

  • a

    contained hazardous materials stored in the former tannery building. The former tannery

    building has trenches constructed in the basement which collect this water and discharge it

    into the Hoosic River at the northern and southern ends of the building (4),

    The Hoosic River is a moderate to large stream and has a mean annual flov. rate of greater

    than 463 cubic feet per second (cfs) at the probable points of entry of surface v-ater to the

    river (36). The farthest downstream probable point of entr>' to surface water is located

    immediately downstream of the breach in the berm enclosing Lagoon #4 (4j. From this point.

    the Hoosic River flows fifteen miles downstream (northwestward) to a point approximately

    1.3 miles downstream of the confluence of the Hoosic and Walloomsac Rivers in Hoosick.

    New York (37; 38; 39). At 4.75 miles downstream, the Linle Hoosic River joins the Hoosic

    River; the mean annual flou rate at this point is greater than 557.5 cfs (37, 4C)i At 1 3 î

    miles downstream, the Walloomsac River joins the Hoosic River; the mean annual flou rate

    at this point is greater than 775.5 cfs (37; 39). Approximately 1.1 miles downstream of the

    15-mile downstream point on the Hoosic River, at Eagle Bridge, New York, the mean annu.::

    flow rate of the Hoosic River is 948 cfs (37; 39; 40). No surface water intakes for dnnkini:'

    water are located within fifteen downstream miles of the potential source areas at the

    property.

    The Hoosic River is identified as Class C by VT ANR. According to VT ANR. Class C

    Waters are "suitable for recreational boating, irrigation of crops not used for consumption

    without cooking, habitat for v\ildlife and for common food and game fishes indigenous to thr

    region, and such industrial uses as are consistent with other ' C uses" (41).

    The Hoosic River is a cold-uater fisherv' for brook trout and brown trout along its length (41.

    42; 43). Recurrent fish kills have been noted in both the Vermont and New York reaches oi

    the river (42; 43). During TRCC reconnaissance, adolescents were observed fishing in die

    Hoosic River from the bank opposite the former tannery building (4). In addition, the

    Vermont reach of the Hoosic River is used for recreational boating (41).

    No sensitive environments (w ith the exception of wedands) or endangered/threatened species

    are located along the Vermont or New York reaches of the Hoosic River (44; 45). At least

    L93-1261.LXI 19

  • 5.8 miles of frontage to wedands occurs along the Hoosic River within fifteen doun>iream

    miles from the most downstream probable point of entry (46; 47; 48; 49), In addition, the

    probable point of entry to surface water runoff from the landfill is located in paJusLnne.

    unconsolidated-bottom. permanently flooded wedands adjacent to the Hoosic River (37: 46;

    47: 48; 49). The mean annual flow rate of these wedands is likely to be less than 10 cubic

    feet per second (50). Surface water flow duough these wedands is approximately 350 feet,

    yielding approximately 700 feet (0.13 miles) of wetiond frontage to these v-etiands (4).

    Table 8 summarizes the flowrates and sensitive environments located along the 15-mile

    downstream surface water drainage from the property.

    TABLE 8. WATER BODIES WFTHIN THE SURFACE WATER SEG.ME.NT OF THE POWNAL T.\NNTRY PROPERTY

    Surface Length of Flow Lenpth of W ater Body Descriptor Reach Characteristics Wetlands

    Unnamed su-eam Minimal stream 350 feet < 10 cfs 0.13 miles

    Hoosic River Moderate to large 15 miles >463 cfs to su-Mm

  • TABLE 9. SAMPLE SUMMARY: POWNAL TANN'ERY

    Samples Collected by IRCC on June 9, 1993

    Traffic

    Sample Report

    Location No. No. Time Remarks Sample Location

    SD-03-01 AFH25/ 11:50 grab 0'-2' Sediment sample collected from MADA24 wedands downstream of the

    outfall from Lagoon #5.

    SD-03-O: AFH26/ 11:50 grab 0'-2' Duplicate of sample SD-03-01 MADA25 coUected for qualit>' control.

    SD-03-05 AFH29/ 13:40 grab 0 '-3 ' Sediment sample collected from MADA28 the Hoosic River upstream of

    the point of entry for surface water draining the landfill.

    SD-03-06 AFH30/ 14:30 grab 0 '-3 ' Sediment sample collected 300 MADA29 feet into wedands downstream

    of the landfill.

    SD-03-07 AFH31/ 12;27 grab 0'-2' Sediment sample collected MADA30 upstream of the outfall to the

    Hoosic River from Lagoon #5.

    SD-03-08 AFH32/ 14:40 grab 0 ' -3 ' Sediment sample collected at a MADA31 ground water seep downgradient

    of the landfill.

    RB-03-10 AFH34/ 13:30 grab Equipment rinsate blank sample M.\DA33 collected for quality control. '

    — - Not Applicable

    entry to surface water from the propert>'. Sample SD-03-08 was sediment collected at a seep

    at the base of the slope beneath the landfill, and therefore has no applicable upstream

    location. No hazardous substances were detected in sample SD-03-08 at concentrations above

    applicable background concentrations.

    Table 10 summarizes compounds and elements detected in sediment samples collected by

    TRCC. Listing of a compound or element is based upon its detection at a concentration

    L93-1261.LXI 21

  • TABLE 10. SUMMARY OF ANALYTICAL RESULTS: SEDLMENT SAMPLE

    ANALYSIS FOR POWNAL TANNERY

    Sample Reference Location No. Element Concentration Concentration Comments

    SD-03-01 copper 99.6 mg/Kg 13.5 mg/Kg 7,4 X SDL

    SD-03-02 copper 67.8 mg/Kg 13.5 mg/Kg 5.0 X SDL (Dup. of SD- mercurv- 2.40 mg/Kg - 7.80 mg/Kg -7.80http:SD-mercurv-2.40

  • 8.0 AIR PATHWAY

    The closest resident to the potential source areas on the property is located at 200 West Main

    Street, approximately 260 feet (0.05) miles northeast of the soudiem end of the former

    tannery building (4; 8). Approximately 3591 persons live within four radial miles of the

    property (32). Table 11 summarizes the estimated population located within four radial miles

    of potential source areas on the propeny. The population was estimated using the same

    method as for ground water users, as explained in Section 5.0.

    TABLE 11. ESTIMATED POPUL.ATION WITHIN FOUR MILES OF POWNAL

    TANN'ERY

    Radial Distance from Pownal Tannery

    (miles 1 Estimated Population

    0.00-0.25 260

    0.25-0.50 273'"

    0.50-1.00 219

    Q 1.00-2.00 523

    2.00-3.C(> 1155

    3.00-4.00 1161

    TOTAL 3591

    (25; 26; 27; 28; 29: 32)

    Approximately 452 acres of wetlands are located within four radial miles of the property (46;

    47; 48; 51).

    9.0 SUMMARY

    The Pownal Tannery propeny was used as a leadier tannery (Pownal Tanning Company) from

    circa 1937 to 1988. The eftluent \^aste water produced by the facility was discharged directly

    to the Hoosic River from cu-ca 193" until 1963. Beginning in 1963. effluent waste water was

    L93-I261.txt 2^

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  • treated in a lagoon system on the propeny before release to die Hoosic Rj\er. Sludge which

    accumulated during waste water treatment was disposed of in lagoons (currently capped j and

    in an onsite landfill. When the facility closed in 1988, approximatel) 12.h3(i pounds of

    hazardous materials were abandoned within die former tannery building.

    Analytical data indicate that hazardous substances have been released to ground water in die

    vicinity of the lagoons, surface water in the Hoosic River, and that hazardous substances are

    present in surface soils on the property. These hazardous substances include volatile organic

    compounds, semi-volatile organic compounds, polychlorinated biphenyls (PCBs), dioxins and

    furans, and heavy metals.

    Ground water is used for drinking water by approximately 3588 persons within four rad:.:;

    miles of the property. The Hoosic River is a cold-water trout fishery, and has at least 5 >

    miles of frontage to wedands downstream of the property. TRCC sampling results indicate

    that sediments in wedands downstream of the property are contaminated w ith copper and

    merciary, which are at least partially attributable to operations at the Pownal Tanning

    Company. Approximately 752 persons live within one mile of the propertv' and

    approximately 3591 p#sons live v-ithin four miles of the propeny. Appro.ximately 452 acres

    of wedands are located within four radial miles of the property.

    L93-I261.ut 24

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  • 10.0 REFERENCES

    1. Final Screening Sire Inspection Report. Pownal Tannery, Pownal. Vermont. NL'S/FIT TDD No, Fl-8904-07. December 20, 1989.

    2. Project Note by Joseph Schmidl (TRCC) RE: Latitude/Longitude Calculations. Pownal Tannery. March 29, 1993.

    3. Subsurface Hazardous Waste Site Investigations at Pownal Tanning, by SP, Inc. January 1988.

    4. Field Logbook. Pownal Tannery. Site Inspection Prioritization. TDD No. 9209-27ATX.

    5. Propert)' Appraisal Information, Pownal Tanning Company, provided by Doris Lillie (Town of Pownal Lister). November 10. 1992.

    6. ARCS Contact Report between Joseph Schmidl (TRCC) and Lisa Danek (EPA. Emergency Services Division. Onscene Coordinator. Pownal Tanner)'). RE: Emergency Removal - Pownal Tanner). August 23. 1993.

    7. North Carolina Hazardous U asie Manifest No. 96339 for Waste Shipped from Pownal Tannery site by US EPA Region 1 Laboratory (ID No. VTD002074839) to Laidlav^ Environmental Ser\ices (ID No. NCD000648451). June 24. 1993; Massachusetts Hazardous Waste Manifest Nos. 78250. 78251, 78253, 75254, 78255, 78252, 78253. 78254, 78255. 782^6. 78261. 78262. 78263, 78264, 78265, 75266, for Waste Shipped from Pownal Tannery site by US EPA Region I Laboratory (JD No. VTD002074839) to Laidlaw Environmental Services (ID No. MAD000604447). June 24, 1993; New Jersey Hazardous Waste Manifest Nos. 93001, 93002 for Waste Shipped from Pownal Tannery site by US EPA Region I Laboratory (ID No. VTD002074839) to Laidlaw Environmental Services (ID No. NJD002200046). May 20. 1993.

    8. Letter from Winslow Ladue (Assistant Director. Water Supply Division, Vermont Department of Environmental Conservation) to Edith Goldman (Assistant Regional Counsel, EPA Region I), RE: WSID 5497 - Pownal Tannery. January 29, 1993.

    9. Project Note by Joseph Schnrudl (TRCC), RE: Area Measurements - Lagoons. August 25, 1993.

    10. Analytical Results for Water Samples Collected on July 19. 1989 by Environmental Consulting Laboratory. Inc. Personnel. Aquatec Project Number 88159. August 7, 1989.

    11. Office Memorandum: Summary of Sampling at Pownal Tanning Site on October 11, 1990, by Vermont Agency of Natural Resources personnel. October 23. 1990.

    L93-126I.LM

    http:L93-126I.LM

  • 12. Office Memorandum: Summary of Results from October 11. 1990 sampling visit, by

    Vermont Agency of Natural Resources personnel. January- 2.

    13. Office Memorandum: Summary of Results from January 10, 1991 sampling visit, by

    Vermont Agency of Natural Resources personnel.. January 30.

    14. Letter from Brian Woods (Hydrogeologist, Hazardous Materials Management Division, Department of Environmental Conservation, Vermont Agency of Natural Resources), to Nancy Lubeck (Homeowner), RE: Analytical Results from April 10, 1992 sampling. April 28, 1992.

    15. Letter from Brian Woods (Hydrogeologist, Hazardous Materials Management Division, Department of Environmental Conservation, Vermont Agency of Natural Resources), to Nancy Lubeck (Homeowner), RE: Analytical Results from April 10, 1992 sampling. April 28, 1992.

    16. Organic Traffic Report & Chain of Custody Records (Nos. 0348008, 0348009). Inorganic Traffic Report &. Chain of Custody Records (Nos. 0348701, 0348702) for Contract Laboratory Program Case Number 19831 and Special Analytical Service Packing List/Chain of Custody (Nos. S030901, S030902) for Contract Laboratory Program Case Number 7845A-01, for samples collected from the Pownal Tannery site by EPA/ESD. AprU 30. 1993.

    17. Organic data validation package for contract Laboratory Program Case No. 19831, Pownal Tannery site, by Lockheed Engineering & Sciences Company. July 2, 1993.

    a 18. Inorganic data validation package for contract Laboratory Program Case No. 19831.

    Pownal Tannery site, by Lockheed Environmental Systems & Technologies Co. July 9. 1993.

    19. Dioxin/Fiu-an data validation package for contract Laboratory Program Case No. 7845A-01. Pov\nal Tannery site, by Lockheed Environmental Systems & Technologies Co. July 14, 1993.

    20. Soil Survey Field Sheet, Bennington County, Vermont. U.S. Department of Agriculture, Soil Conservation Service, with attached Soil Interpretations Records Nos. VTOOll and NT0096. undated.

    21. Surficial Geological Map of Vermont, edited by Charles C. Doll, State Geologist, Vermont Geological Suney. 1970.

    22. Hydrogeological Site Assessment. Pownal Tanning Lagoon Site, North Pownal, Vermont, by Saunders Associates. Inc. February 14, 1988.

    24. Bedrock Geological Map of Vermont, edited by Charles C. Doll, State Geologist. Vermont Geological Survey. 1961.

    L93-l26l.Lxt 26

  • 25. 1990 Census of Population and Housing, Vermont. Summary Population &. Housing Characteristics. U.S. Department of Commerce. Office of the Census, Document No. 1990-CPH-47. July 1991.

    26. J990 Census of Population and Housing. Massachusetts. Summan. Population & Housing Characteristics. U.S. Department of Commerce, Office of the Census. Document No. 1990-CPH-23. August 1991.

    27. 1990 Census of Population and Housing, New York. Summary Population & Housing Characteristics. U.S. Department of Commerce, Office of the Census, Document No. 1990-CPH-34. August 1991.

    28. North Pownal Quadrangle, VT-NT. U.S. Geological Survey 7.5 Minute Series Topographic Map. 1954. photorevised 1980.

    29. Pownal Quadrangle. VT. U.S. Geological Survey 7.5 Minute Series Topographic Map. 1954.

    30. Williamstown Quadrangle. VT, U.S. Geological Survey 7.5 Minute Series Topographic Map. 1954.

    31. Beriin Quadrangle, NY-MASS-VT, U,S. Geological Survey 7,5 Minute Series Topographic Map. 1985.

    32. Project Note by Joseph Schmidl (TRCC) RE: Site Inspection Prioritization Distance Ring Calculations. Pownal Tannery. TX)D No.: 9104-03-ATS. Februar)' 1993.

    33. Printout of Water System Database (Public Water Supplies). Vermont Department of Environmental Conservation, Division of Water Supply, dated December 1992.

    34. .ARCS Contact Report by Joseph Schmidl (TRCC) with Tim Raymond (Assistant Regional Manager. Region FV. Water Supply Division, Vermont Agency of Natural Resources), RE; Wellhead Protection in Vermont. February 22, 1993.

    35. Flood Boundary and Floodway Map, Pownal, Bennington County, Vermont. National Flood Insurance Program, Federal Insurance Administration, Department of Housing and Urban Development, Community-Panel Number 500016 0005 C. April 1. 1980.

    36. Telecon Note by Joseph Schmidl (NUS/FIT) with Jeff Cueto (Principal Hydrologist. Division of Water Quality. Vermont Agency of Natural Resources), RE: Hoosic River Flow Rate. June 21. 1991.

    37. Project Note by Joseph Schmidl (TRCC), RE: Measurements of the 15-mile Surface Water Pathway from the Pownal Tannery. August 16, 1993.

    L93-1261.L\; 27

  • 38. Hoosic Falls. N̂Y Quadrangle. U.S. Geological Survey 7.5 Minute Series Topographic Map. 1944, photorevised 1̂ 980.

    39. Eagle Bridge, NY Quadrangle. U.S. Geological Survey 7.5 Muiute Series Topographic Map. 1944, photorevised 1980.

    40. ARCS Contact Report between Joseph Schmidl (TRCC) and Lloyd Wagner (U.S.

    Geological Survey, NY), RE: Row Rates along Pownal Tanner)' SWP. August 18,

    1993.

    41. Vermont Rivers Study, Vermont Agency of Environmental Conservation, with the assistance of the National Park Service, Mid-Atlantic Regional Office. February 1986.

    42. Letter from David R. Galium (District Fisheries Biologist, Department of Fish and Wildlife, Vermont Agency of Nauiral Resources) to Joseph Schmidl (TRCC), RE: Fishery information. March 9, 1993.

    43. A Fisheries Management Plan for the New York Section of the Hoosic River, by Norman D. McBride, Senior Aquatic Biologist, Region 4 Fisheries Office, New York Department of Fish and Wildlife. Watershed File #1794. June 1989.

    44. Letter from Everett Marshall (VT Nattiral Heritage Program) to Joseph Schmidl (TRCC), RE: Sensitive Environments. 1993.

    45. Letter from Burell Buffington (NT Natural Heritage Program) to Joseph Schmidl (TRCC>, RE: Sensitive Environments. Inarch 1, 1993.

    46. National Wetlands Inventory Map. North Pownal. VT Quadrangle. U.S. Department of the Interior. March 1986.

    47. National Wetlands Inventory Map. Pownal, VT Quadrangle. U.S. Department of the Interior. April 1977.

    48. National Wetlands Inventory Map. Williamstown, MA Quadrangle. U.S. Department of the Interior. April.

    49. Project Note by Joseph Schmidl (TRCC) RE: Wetlands Frontage to the 15-mile Surface Water Padiway Pownal Tannery. TDD No.: 9104-03-ATS. August 16, 1993.

    50. Project Note by Joseph Schmidl (TRCC), RE: Area Measurements - Watershed in vicinity of landfill. September 9. 1993.

    51. Project Note by Joseph Schmidl (TRCC) RE: Wedands Area within Four Radial Miles of Pownal Tannery. TDD No.: 9104-03-ATS. September 16. 1993.

    L93-1261.ut 28

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  • 52. Industrial Wastes. Summary of EPA Directive Documents. Black and Veach, Section 13, pp. 1-13. 1980.

    53. Memorandum to Edward Leonard (Director) from James Suruilo (Technical Assistance Section, Solid Waste Management Division, Department of Envu-onmental Conservation, Vermont Agency of Natural Resources), RE: Pownal Tannery Landfill. May 24. 1993.

    54. Memorandum to Chuck Clarke (Secretary, ANR) from Brian Woods et al. (Site Management Section, Hazardous Materials Management Division. Department of Environmental Conservation, Vermont Agency of Natural Resources). RE: Pownal Tannery - Proposed Activity (Site #77-0066). August 9, 1993.

    54. Memorandum to Jim Surwilo (SWD) et al, from Brian Woods (Site Management Section. Hazardous Materials Management Division, Department of Environmcnul Conservation, Vermont Agency of Natural Resources). RE; Pownal Tannery. September 23. 1993.

    55. Basic Well Data. Vermont Agency of Natural Resources, Department of Environmental Conservation, Division of Water Supply. Well Records compiled from July 26. 1966 through 1991.

    56. Anahiical results for samples analyzed for polychlorinated dioxins and furans (isomer specific) collected at the Pownal Tannery. Samples collected by Aquatec, Inc. personnel on May 4 and 5, 1988 and analyzed by Enseco, Inc. (Aquatec Project No 88057). July 5, 1988. j

    L93-1261.L\t 29

  • APPENDIX A

    GROUND WATER AND DRINKING WATER SAMPLE ANALYTICAL RESULTS

    Samples Collected by VT ANR Personnel on July 19, 1989.

    S

    L93-1261.txt A-l

  • m 08 m^

    \ W ^ ^ ^ ^ ̂ 'NO. ENVIRONMENTAL SERVICES

    7 5 ^ ^ R E E N MOUNTAIN DRIVE, SOUTH BURLINGTON,' VERMONT 05403, TELEPHONE (802) 658-1074

    7 August 1989

    Ms. Diane Conrad

    State of Vermont

    Department of Environmental Conservation

    Agency of Natural Resources

    103 South Main Street

    Waterbury, Vermont 05676

    Re: Aquatec Project No. 88159. ETR No. 17811

    Dear Ms. Conrad:

    Enclosed are results of GC/MS analyses performed on water

    samples received at Aquatec on 20 July 1989.

    Sincerely, /

    Richard T. Gomez/^)

    Chemist

    RTG/jg

    Enclosure

    Hydrographic Studies and Analyses * Water Quality Studies • Analytical Laboratories

    Ecological Studies * ComputerSimulations • Industrial Waste Surveys

  • /

    . / / aquatec

    ENVmONklENTAL SERVICES

    75 Cre«n Mountain [>ive. So. Burlington, VT .i;W3

    TEL. 802/653-1074

    A N A L Y T I C A L R E P O R T

    Dace: 4 August: 1989

    Aquatec Lab No.: 100570

    ETR No.: 17811, Project 88159

    Received On: 20 July 1989

    Sample Identification: Vermont Department of Envirorunencal Conser-zation,

    sample labeled Trip Blank, 7/19/89.

    Volatile Organic Compounds in ug/1

    EPA Method 524.2

    benzene

    bromobenzene

    bromochloromethane'

    broraodichloromethane

    bromoforra

    bromomethane

    n-bucvlbenzene

    sec-but:vlbenzene

    terc-butvl^nzene

    li.uboti LBLrachlorlde

    chloroberjzene

    chloroethane

    chloroform

    chloromethane

    2-chlorotoluene

    4-chlorotoluene

    dlbroraochloromethane

    1 2-dibromo-3-chloroorooane

    1.2-dlbromoethane

    dibroraomethane

    1,,2-dichlorobenzene

    1 J-dichlorobenzene

    1A-dichlorohenzene

    dichlorodlfluoromethane

    1,1-dtchloroethane

    1.2-dlchloroethane

    1,1-dichloroechene

    cls-1.2-dichloroethene

    trans -1.2-dlchloroechene

    1.2-dlchloroprooane

  • aquatec

    ENVIRONMENTAL SERVICES

    75 Cretn Mountjin I>ive, So. Burlinfjion. VT nS4n3 TEL. 802/658-1(774

    A N A L Y T I C A L R E P O R T

    Date: 4 August 1989

    Aquatec Lab No.: 100571

    ETR No.: 17811, Project 88159

    Received On: 20 July 1989

    Sample Identification: Vermont Department of Environmental Conservation, water

    sample labeled Lubeck, 7/19/89 at 1200 hours.

    Volatile Organic Compounds in ug/1

    EPA Method 524.2

    benzene bromobenzene bromochloromethane bromodichloromethane broraoform bromomethane n-butvlbenzene sec-butvlbenzene tert-butvlbenzene g carbon tetrachloride

    chlorobenzene

    chloroethane

    chloroform

    chloromethane

    2-chlorotoluene

    4.chlorotoluene

    dtbromochloromethane

    1. 2-dibromo-3-chloroDrooane

    1.2-dibroracethane

    dibroraomethane

    1.2-dichlorobenzene

    1.3-dichlorobenzene

    1.4-dichlorobenzene

    dichlorodlfluoromethane

    1.1-dlchloroethane

    1.2-dichloroethane

    1.1-dtchloroethene

    cis-1.2-dichloroethene

    tran3-1.2-dtchloroethene

    l,2-

  • y

    aquatec

    ENVIRONMENTAL SERVICES

    75 Cre«n Mountain t>rive. So. Burlington. VT 054O3

    TEL. 802/658-1074

    A N A L Y T I C A L R E P O R T

    Date: 4 August 1989

    Aquatec Lab No.: 100572

    ETR No.: 17811, Project 88159

    Received On: 20 July 1989

    Sample Identification: Vermont Department of Envirorunental Conservation, water

    sample labeled L-9, 7/19/89 at 1300 hours.

    ' > ^ < ? ° d'.

  • /

    aquatec

    ENVIRONMENTAL SERVICES

    75 Creen Mountain Drtve, So. Burlington, VT 054O3

    TEL. 802/658-1074

    A N A L Y T I C A L R E P O R T

    Date: 4 August 1989

    Aquatec Lab No.: 100573

    ETR No.: 17811, Project 88159

    Received On: 20 July 1989

    Sample Identification: Vermont Department of Environmental Conservation, water

    sample labeled Tudor, 7/19/89 at 1215 hours.

    Volatile Organic Compounds in ug/1

    EPA Method 524.2

    benzene

    bromobenzene

    bromochlorome thane'

    bromodichloromethane

    bromoform

    bromomethane

    rn-butvlbenzene

    sec-butvlbenzene

    tert-butvlbenzene

    carbon tetrachloride

    chlorobenzene

    chloroethane

    chloroform

    chloromethane

    2-chlorotoluene

    4-chlorotoluene

    dibromochloromethane

    1.2-dibromo-3-chloroorooane

    1.2-dibromoethane

    dibroraomethane

    1.2-dichlorobenzene

    1.3-dichlorobenzene

    1.4-dichlorobenzene

    dichlorodlfluoromethane

    1.1-dlchloroethane

    1.2-dichloroethane

    l.l-dlchloroethene

    cls-1.2rdichloroechene

    trans -1.2-dichloroethene

    l,2-dlchloroDrc)Dflne

  • APPENDIX B

    GROUND WATER, DRINKING WATER AND SURFACE WATER SAMPLE

    ANALYTICAL RESULTS

    Samples Collected by VT ANR Personnel on October 11, 1990

    L93-963.txt B-1

  • State of Vermont

    AGENCY OF NATURAL RESOURCES

    103 South Main Street

    Deoanment of Pish and Wildlife Waterbury', Vermont 0S676 Deoariment of Forests, Parks and Recreation Department of Environmental Conservation S:a:e Geologist Department of Environmental Conservation NaTural Resources Conservation Council

    OFFICE MEMORANDUM

    TO: Pownal Tannery Site file

    FROM: Steven L. Winters, ,^*erdous Materials Specialist, Sites

    Management Section,-;;̂ -̂!,.̂ ^

    DATE: Jar.uary 2, 1991

    SUBJECT: Summary of results from October 11, 1990, sar.pling

    visit.

    The analytical laboratory results for water samples collected

    at the Pownal Tannery site, Pownal, Vermont, on October 11, 1990,

    are summarized in Table 1:

    T.iBLZ 1: RESULTS SUMMARY

    Method 8 240 Crfd) 1

    Pbldl Method 8270

    Sampling Point:

    MW-L9 RND^

  • Memo to Pownal Tannery site file page 2

    Copies of the original laboratory reports are attached.

    attachments

    cc: Kerry A. Diskin, NUS Corporation

    Don Smith, EPA

    SLW/slw/M2-365-0923P0WT AN

  • 6 0 i.i.'^V'

    DEPT- O f ENVIRONHENTAL CONSERVATION LAB MA.\A3£ r.£.>ir SYSTEM PAGE I

    FINAL LAB REPORT

    DATE 1 1 / 2 6 / 9 0

    .AB 10 579'V5 REPORT TO S/WJNTERS DUE DATE 1 1 / 1 2 / 9 0

    JOURCE LOCATION MW-L9 COLLECTION DATE 1 0 / 1 1 / 9 0

    'ROGRAM 022-HA2AROOUS HASTE (STATE) AMa i f cM i^ATER SAMPLE )t

    SUBMITTED BY S/«INTERS PHONE 2-^4-8702 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL YES

    iAMPLE NOTES:

    EST .JOE TEST NAME RESULT

    UNIT OF MEASURE

    KEMA;

  • . V '^H 1990

    , ^ ^ DEPT, OF ENVIRONMENTAL CONSERVATION LAB MANAGEMENT SYSTEM PAGE 1

    FINAL LAB i^EPORT

    DATE 1 1 / 2 6 / 9 0

    AB ID 57946 REPORT TO S/WINTERS DUE DATE 1 1 / 1 2 / 9 0

    OURCE LOCATION MW-LIO C O L L E Z T I O N DATE 1 0 / 1 1 / 9 0

    ROGRAM 022-HA2AROOUS WASTE iSTAJE} AMBIENT *AT£R SAMPLE r

    UBMITTEO BY S/WIAn"£RS PHONE 2 4 4 - 8 7 0 2 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL Y£ S

    AHPi.E NOTES:

    £ST

    ODE TEST NAME R L S U L T

    UNIT OF MEASURE

    REMARKS CCDE

    PRCCESS C A T :

    24W METHOD 8 2 4 0 TESTS, HATER 0 NCNE Z 1 0 / 2 5 / s

    CR CHROMIUM DSSSOIWED < 10 UG/L I Z / Z 2 / .

    P . ̂ LEAD DISSOLVED < 10 UG/L l C / 2 < . / .

    27W METHOD 8 2 7 0 , WATER c NONE z L l / l t 3 / l

  • 1

    I ( uuV Zb 1 : , .

    DEPT. OF EWIRONMENTAL CONSERVATION LAB MANAGEMENT SYSTEM PAGE

    ' ^ ̂ F INAL LAB i?EPORT

    DATE 1 1 / 2 6 / 9 0

    AB ID 57947 REPORT TO S/.WINTERS DUE DATE 1 1 / 1 2 / S O

    OURCE LOCATICN Ml, -L20 CCLLECri'ON DATE 1 0 / 1 1 / 9 0

    'ROGRAM 022-HA2AROOUS HASTE (STATE) AMBIENT J^ATER SAMPLE Y

    iLBMITTEO BY S/HINTERS PHONE 2 4 4 - 8 7 0 2 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL VE S

    .AMPLE NOTES:

    EST -ODE TEST NAME RESULT

    UNIT OF MEASURE

    REMARKS CODE

    PROCESS DATE

    t24H METHOD 8240 TESTS, WATER 0 NCNE 2 10/25/93

    )CR CHROMIJM DISSOLVED < 10 UG/L lC/23/9:

    )PB LEAD DISSOLVED < 0 UG/L 10/24/93

    ; 2 7 ^ H E T H 0 D 8 2 7 0 , HATER c NCrjE Z 11/16/90

  • 'NOV I'S' igg-

    DEPT. OF ENVIRONMENTAL CONSERVATICN LAb M A N A G E H L N T SYSTEM PAGE

    FINAL LAB REPORT

    DATE l i / 2 f c / 9 j

    .AB ID 57948 REPORT TO S/HlNTEKS OuE DATE 1 1 / 1 2 / 9 0

    SOURCE LOCATION LAGOON 5 CCLLECTION DATE 1 0 7 1 1 / 9 0

    =»ROGRAM 022-mZARDOUS HASTE (STATEi AMBIENT WATER SAMPLE Y

    SUBMITTED BY S/WINTERS PHONE 2 4 4 - 8 7 3 2 SUBMIT DATE 1 0 / 1 2 / 9 C LEGAL YES

    iAMPLE NOTES:

    TEST

    :oDE TEST NAME SULT

    J M T [iC ••' L -Si.'-; E

    REMARKS CODE

    PROCESS DATE

    324W

    DCR

    METHOD 8240 TESTS,

    CHROMIUM DISSOLVED

    HATER 0

    15

    NCNE

    UG/L

    2 10/25/90

    10/23/90

    3Pf LEAD DISSOLVED - UG/L 10/24/90

    327W METHOD 8 2 7 0 , HATER C NCNE 2 11/16/90

  • I DEPT. OF ENVIRONMENTAL CONSERVATION LAB MANAGEMENT SYSTEM PAGE

    " " ^ FINAL LAB REPORT

    DATE 1 1 / 2 6 / 9 0

    AB ID 57949 REPORT TO S/HINTERS OUE DATE 1 1 / 1 2 / 9 0

    OURCE LOCATION LAGGON 4 . CCLLECTION DATE 1 0 / 1 1 / 9 0

    RDGRAM 022-HAZAROOUS WASTE ( S T A T E J AMBIENT »,AT£R SA^JJLE Y

    UBMITTED BY S/HINTERS PHONE 2 4 4 - 8 7 0 2 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL YES

    AMPLE NOTES:

    EST UNIT OF REf-ARKS PROCESS RESULT .MEASURE CODE DATE

    ODE TEST NAME

    24H METHOD 8240 TESTS, HATER C NCNE 10/25/̂ 3̂

    CR CHROMIUM DISSOLVED < 10 UG/L lO/23/SO

    P^ LEAD DISSOLVED < 10 UG/L 10/2

  • NOV 0 5 13;

    S*^ DEPT. OF ENVIRONMENTAL CONSERVATION LAB MANAGEMENT SYSTEM PAGE

    F INAL LAB i^EPORT

    DATE 1 0 / 3 1 / 9 0

    LAB ID 57951 REPORT TO S/HINTERS DUE DATE 1 1 / 1 2 / 9 0

    SOURCE LOCATION LUBECK COLLECTION DATE 1 0 / 1 1 / 9 0

    PROGRAM 022-HA2ARDOUS WASTE iSTATEJ AMBIENT HATER SAMPLE

    SUBHITTED BY S/HJNTERS PHONE 2 4 4 - 8 7 0 2 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL

    SAMPLE NOTES:

    Y

    YES

    TEST UNIT OF REMARKS PROCESS CODE TEST NAME RESULT MEASURE CODE DATE

    324H METHOD 8 2 4 0 TESTS, WATER 0 NONE 10/26/90

  • NOV 0 5 .:.

    DEPr . OF ENVIRONMENTAL CONSERVATION LAB MANAGEMENT SYSTEM PAGE I

    ^ " ^ FINAL LAB REPORT

    DATE 1 0 / 3 1 / 9 0

    AB ID 57952 REPORT TO S/HlNTERS DUE DATE 1 1 / 1 2 / 9 0

    OURCE LOCATION TUDOR COLLECTION DATE 1 0 / 1 1 / 9 0

    ROGRAM 022-HA.ZARDOU$ WASTE (STATE) AMBIENT HATER SAMPLE Y

    UBMITIED BY S/HINTERS PHONE 2 4 4 - 8 7 0 2 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL YES

    AMPLE NOTES:

    EST UNIT OF REMARKS PROCESS ODE TEST NAME RESULT .-MEASURE CODE DATE

    24H METHOD 8240 TESTS, HATER NCNE lC/2 5/9:

  • l

    NOV G5 m

    ^ ^ ^ DEPT. OF ENVIRONMENTAL CONSERVATION LAB MANAGEMENT SYSTEM PAGE

    FINAL LAB REPOi^T

    DATE 1 0 / 3 1 / 9 0

    -AB ID 57950 REPORT TC S/WINTERS DUE DATE 1 1 / 1 2 / 9 0

    iOURCE LOCATION TRIP BLANK COLLECTION DATE 1 0 / 1 1 / 9 0

    'ROGRAM 022-HAZAROOUS HASTE (STATEJ AMBIENT HATER SAMPLE Y

    SUBMITTED BY S/WINTERS PHONE 2 4 4 - 8 7 0 2 SUBMIT DATE 1 0 / 1 2 / 9 0 LEGAL YES

    •AMPLE NOTES:

    'EST UNIT OF REMARKS PROCESS :00E TEST NAME RESULT MEASURE CODE DATE

    J24W METHOD 8240 TESTS, HATER 0 NONE 2 1 0 / 2 6 / 9 0

  • State of Vermont

    AGENCY OF NATURAL RESOURCES 103 South Main Street

    D e o a r t m e n t o< F ish and Wi l d l i f e

    DeoarTment o* Fores is , ParKi and Recrea t ion Waterbury, Vermont 05676

    OeoarTment o< E n v i r o n m e n i a l Conse rva t i on

    State Geolog is t Department of Environmental Conservation Natu ra l Resources Conserva t ion Counc r l January 30, 1991

    Mr. and Mrs. Lubeck

    P.O. Office Box 51

    North Pownal, Vermont 05260

    SUBJECT: Laboratory results for drinking water sample collected

    January 10, 1991.

    Dear Mr. and Mrs. Lubeck:

    I am writing to notify you of the results of the laboratory

    test for volatile organic chemicals performed on the well-water

    sample collected from your kitchen rap by me on January 10, 1991.

    The test was conducted by the Vermont Department of Environmental

    Conservation (DEC) Laboratory, and the results are attached to

    this letter.

    The results indicate that all volatile organic chemicals

    tested for were below the detection limits indicated on the

    attached data sheet. On the basis of the DEC laboratory analysis

    of your sample, your drinking water should be free of volatile

    organic chemicals and safe to drink.

    If you have any questions regarding these results, please

    call me in Waterbury at 244-8702.

    Sine

    Steven L. Winters

    Hazardous Materials Specialist

    Sites Management Section

    attachment: Vermont DEC laboratory data sheet for volatile

    organics in sample 59291

    cc: Pownal Tannery site file (w/attach.)

    Kerry A. Diskin, NUS Corporation (w/attach.)

    Don Smith, EPA (w/out attach.)

    SLW/slw/L2-029-1321POWTAN, January 29, 1991

    Regional Offices Bi're.'Essex Jc; P ;:?forc rj So'inqfield'St Johrshur

  • APPENDIX C

    DRINKING WATER SAMPLE ANALYTICAL RESULTS

    Samples Collected by VT ANR Personnel on January 10, 199L

    k

    L93-963.txt C-1

  • ?, Fi ! -^ i C ^ a ^ ^ ' '̂ p 134139

    State of Vermont

    2̂,75-̂ T,J t̂ —AGENCY OF NATURAL RESOURCES

    103 South Main Street

    D e p a r t m e n t o f F ish j n c W i l d l i f e Waterburv, Vermont 05676 D e o a r t r r e n t o f Forests. ParKs and Recrea t ion /-^^fl'? D e p a r t m e n t of Env i r onmen ta l Conse rva t i on

    State Geo log is t Department of Environmental Conservation Na tu ra l i=esources Conservat ion C o u n c i l

    OFFICE MEMORANDU!^ !LE COPY TO: Pownal Tannerv site file

    FROM: ^^teve.n L. Winters, Hazardous Materials Specialist:, Sites

    Management Section

    DATE: January 30, 1991

    SUBJECT: Summary of results from January 10, 1991, sampling

    visit,.

    The analytical laboratory results were below analytical

    detection limits for DEC Method 824W performed on the tap-water

    samples collected at the Lubeck and the 3 residences, North

    Pownal, Vermont, on January 10, 1991.

    A copy of Chain-cf-Custody Record and the DEC Laboratory data

    reports for these samples are attached.

    cc: Kerry A. Diskin, NUS Corporation

    Don Smith, EPA

    SLW/slw/M2-030-0950PCWTAN, January 31, 1991

    [ 3 r /*« * • - . , • r

    ' • -3 - 7 1991

    ciiLNlrC

    Reconal Off ice; • Barre/Essex JctVPitrsfo-d, N Sor rg-,eld/St. JohrsSur',

  • M i l I .STATE o r KfOll l

    DrPAiiTMi;ii i, or I . - H V I I I O N I / AL r.oiisi K V A I IOM ( (CHAIN OF CUSTO.;)' nCCOlU) I'AC.

    i i ( ) . i i ; c r " i i A M i : / i i i i i ' \ i i i ' u : 1 AllOllAIOIlY ^^AMi'iritisyr'i'siTjiuirirrer^

    ..iiii|)Tes s e a l e d Sea ls b roken & remaJe^ fo r Samples so (Tied oli (iL c o l l e c t i o n a d d i U o n o f p r e s e r v a t i v e \̂ DESCRIPTION AND NUMUCK OF CONTAlNLi^S rece lp iaL lahoraLory

    ' ^ o r U "m i V\"nT _b̂

    - ^ s Y~or~N" InTHaTs" S A M P L T

    LOCATIOH C O L L C t T I O J l

    _DATC_| TTRr GRAB ^ ,.\

    'S^l ^ REMAIIKS

    U/> '^ ll:'"'^-, M ^ 7 Lhl^^^-l ^^i.\.t) ^ / lu j

    ; 'S'usii-u I'lt^'ll yi^

  • j Hi . 1 SJ

    DEPT- OF ENV IRCNMENTAL CuNSEkVflT IL.M LA^s MANAGfcMtiM SYSTEM PAJE 1

    FINAL LAc SEPOxT

    DATE 0 1 / 2 3 / 9 1

    AB ID 59291 R E P C K T TO S/Wl.NTERS OLE DATE J 2 / 1 1 / 9 1

    3URCE LOCATION LUBECK c C L L t C T I C N oAlfc G l / l U / 9 1

    ROGRAM 0 2 2 - H A Z A R O U U S kJASTE ISTATE) AMbicNT WATER SAMPLE Y

    UBMITTEO BY S/WINTERS PHUNE 2 ' t 4 - a 7 0 2 SUBMIT DATE 0 1 / 1 1 / 9 1 LEGAL VES

    iMPLE NOTES:

    EST UiMl T OF REMARKS PROCESS IDE TEST .NAME KcSUL T / . i « i b R t CuDE DATE

    'AU METHOD d 24U TESTS, >,ATER 0 NCNE 0 1 / 1 7 / 9 1

  • D E P T . CF EiNVIRGiSHfcNr AL Co. \S£R V M T I C N L A b MANAGEMENT SYSTEM PAGE

    FINAL LA6 REPCKT

    DATE ui/23/91

    \S ID 59293 REPORT TC S / i s I \ T E K S DUE DATE 0 2 / 1 1 / 9 1

    lURCE LOCATION -iSCEVlCH COLLECTION CAIE 0 1 / 1 0 / 9 1

    ;QGRA,M 0 2 2 - H A Z A R D G U S WASTE (STATE) AMBIENT WATER SAMPLE Y

    IBMITTED 3Y S/WINT£RS PHONE 2 ^ A - d 7 0 2 SUBMIT DATE 0 1 / 1 1 / 9 1 LEGAL YE

    • MPLE NOTES:

    ST U N I T J F REMARKS PROCESS OE TEST NAME RESULT KEA^UKE C G D c DATE

    4W METHOD 6 2 ^ 0 T E S T S , -ATER C NCNE 0 1 / 1 7 / 9 1

  • TC'

    . DEPT. :-:MVIROtn-IENTAL CCNSERVATIO;; L.-.EOP.iTOF,Y DATA SHEET FOR VOLa.TILI CP.G?.^1CS - HATER

    SPJ-IPLE NUTIBER: 59291 WJ;»iYST: P""^ RUII: 01-17-91 DILUTION £ % ^ : Lubeck DATE COLLECTED: 01-ie-91

    -.pprox

    VW07 Vinyl chloride

    W 08 Chloromethane

    VW09 Bromomethane

    VW10 Chloroethane

    VWll Trichlorofluorcmethane

    VW12 Acetone

    VW13 1,1-Dichloroethene

    VW14 Carbon disulfide

    V,-/15 Methyl-ene chloride

    VW16 Methyl-t-Butylether (MTBE)

    VW17 1,2-Dichloroethene

    W IS 1, l-Dichloroethane

    VW19 Vinyl acetate VW20 2-Butanone V\'/21 Chloroform VW22 1,1,1-TrichlorGethane

    VW_^ Cairbon tetrachloride

    VWzf^ Benzene

    v;'/25 1,2-Dichloroe thane

    V^-,'2G Trichloroethene

    VW27 1,2-Dichloropropane

    VW28 Bromodichloroniethane

    VW29 4-Methyl-2-pentanone

    V5'f30 cis-1,3-Dichlorcprcpene

    VW31 Toluene

    VW32 trans-l,3-Dichloroprcpene

    W/33 1,1,2-Trichloroethane

    VW34 2-Hexanone

    VW35 Tetrachloroethene

    VW36 Dibromochloromethane

    VW37 Chlorobenzene

    VW38 Ethylbenzene

    VW39 Xylenes

    W/40 Styrene

    VW41 Bromoform

    VW42 1,1,2,2,-Tetrachloroethane

    TVH Total Volatile Hydrocarbons

    SRL CCD:

    FACTOR:

    Lmate De t5-tion Limit

    ua/1

    10

    10

    10

    10

    10

    50

    2

    2

    10

    50

    20

    2

    2

    2

    100

    Detected at.

    ug/l

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND ND ND ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    I.TI

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    REMI^IIS.

    SURROGATE RECOVERIES... ,

    1,2-Dichloroethane - D4: 120*4 D8-Toluene: 4-BroraoFluorobenzene: llSi;

    :nD\VW01

  • • 1 :

    VT. Dci.. ENVIRONIIENTAL CONSERVATION Li.BCR.2TC?.-,

    DATA SHEET FOR VOLATILE ORGANICS - HATER

    SAl-S'LE NLTEER: 5S311 A-MALYST: SRL REM;^_°.K5 CCDE DATE Rhl l : 01-11-91 DILUTION FACTOR: 1 ITE: T3

    ^ii^.TE COLLECTED: 1-10-91

    Approximate Detection Lim:

    ua/1

    VW07 Vinyl chloride 10 vwea Chlorome thaPie 10 VW09 Bromomethane 10 VW10 Chloroethane 10

    v;vii Trlchlorofluoromethane 10

    VW12 Acetone 50

    VW13 1,1-Dichloroethene 2

    VW14 Carbon disulfide 2

    WIS Met.hylene chloride 2

    VW16 Methyl-t-Butylether (MTBE) 10

    VW17 1,2-Dichloroethene 2

    v;7ia. 1,1-Dichloroethane 2

    VT'/ig Vinyl acetate 50

    VW20 2-Butanone 50

    V1V21 Chloroform 2

    V;/22 1,1,l-Trichloroethane

    V̂ >r23 Carbon tetrachloride 2

    Benzene 2

    v ^ 1,2-Dichloroethane 2 V^;26 Trichloroethene

    VW27 1,2-Dichloropropane

    v;^2a Bromodichloromethane

    VW29 4-Methyl-2-pentanone :0

    cis-1,3-Dichloropropene wna 2

    VW31 Toluene

    W/32 trans-1,3-Dichloropropene

    VW33 1,1,2-Trichloroethane

    VW34 2-Hexanone 20

    2

    VW36 Dibromochloromethane 2

    VW37 Chlorobenzene 2

    VW38 Ethylbenzene 2

    VW35 Tetrachloroethene

    VW39 Xylenes

    VW40 Styrene 2

    VW41 Bromofonn 2

    VW42 1,1,2,2,-Tetrachloroethane 2

    TVH Total Volatile Hydrocarbons 100

    ;=rted a:

    uq/1

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    NP

    ND

    ND

    ND

    J ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    R T ""JCS.

    SURROGATE RECOVERIES

    1,2-Dichloroethane - D4: 96% D8-Toluene: 94% 4-BromoFluorober.zene: 84\

    GD\VH01

    http://Li.BCR.2TChttp:REM;^_�.K5

  • 134727 FVLt GOn State of Vermont

    AGENCY OF NATLT^AL RESOURCES 103 South MaiQ Street

    Ceoa i - tmem of F-.tr anc W i i c : i f « Waterburv, Vermont 05676 Ceoar-menT 0*- Por»5:5 Pari

  • VT. 11.1 J. u,. -ROi^ENT.--L CONi l.^ vTION LABOR"' OPY ZATA SHEET FOR VOIA.TILE C.^GANICS - WATE.

    SAJ-IPLE NUISBER: 59293 W^ALYST: SRL REMARKS CODE 824'..' DAT UN: 0 1 - 1 1 - 9 1 DILUTION FACTOR: 1 S I T J S T ' Ascev i ch DATE COLLECTED: 01 -10 •91

    Approximate Detection Limit Detected a

    ua/1 ucr/1

    v;'/07 Vinyl chloride 10 ND

    VW08 Chloromethane 10 ND

    VW09 Bromome tha.ie 10 ND

    VW10 Chloroethane 10 ND

    VWll Trichlorofluoromet-hane 10 ND

    VW12 Acetone 50 ND

    VW13 1,1-Dichloroethene 2 ND

    VW14 Carbon disulfide 2 ND

    V\fl5 Methylene chloride 2 ND

    VW16 Methyl-t-Butylether (MTBE) 10 ND

    VW17 1,2-^ichloroethene 2 ND

    VWlS 1,1-Dichloroethane 2 ND

    VVI19 Vinyl acetate 50 ND

    VW20 2-Butanone 50 ND

    VW21 Chloroform 2 ND

    VW22 1,1,l-Trichloroethane 2 ND

    W & 3 Carbon tetrachloride 2 m V\'/24 Benzene 2 ND VW25 1,2-Dichloroethane 2 ND VW26 Trichloroethene 2 ND

    .-•-.— . * r-\.-^UT, • \rr\ V H ^ / X , >U- l -

  • 134728

    PT T I L L U U i

    State of Vermont

    AGENCY OF NATURAL RESOURCES

    D e o a r t m e n t of Pisn and w i i e i i f e

    O e o a r t m e n t o i Forests. ?ar»s ana Recrea t ion

    D e o a r t m e n t of Env i r onmen ta l Conserva t ion

    1

    icij],Jl %rst^vf icor̂ f̂ ^ 103 South Main Street

    Waterbury, Vermont 05676

    State Geolog is t

    N a t u r a l Resources Conser^ar ion C o u n c i l Fi-f(fdM> Department of Environmental Conservation

    January 30, 1991

    Mr. and Mrs. Lubeck

    P.O. Office Box 51

    Norcn Pownal, Vermont 05260

    SUBJECT: Laboratory results for drinking water sample collected

    January 10, 1991.

    Dear Mr. and Mrs. Lubeck:

    I am writing to noti fy you of the results of the laboratory

    test for volatile organi c chemicals performed on the well-water

    sample collected from yo ur kitchen tap by me on January 10, 1991'.

    The test was conducted b y the Vermont Department of Environmental

    Conservation (DEC) Labor atory, and the results are attached to

    this letter.

    The results indicate that all volatile organic chemicals

    tested for were below th e detection limits indicated on the

    attached data sheet. On the basis of the DEC laboratory analysis

    of your sample, your dri nking water should be free of volatile

    organic chemicals and sa fe to drink.

    If you have any questions regarding these results, please

    call me in Waterbury at 244-8702.

    Sincgs^ly,

    Steven L. Winters

    Hazardous Materials Specialist

    Sites Management Section

    attachment: Vermont DEC laboratory data sheet for volatile

    organics in sample 59291

    cc: Pownal Tannery site file (w/attach.)

    Kerry A. Diskin, NUS Corporation (w/attach.)

    Don Smith, EPA (w/out attach.)

    SLW/slw/L2-029-1321?OWTAN', January 29, 1991

    P.'q'.ci': 0:'-'C»s • Bar-e Essex Jc: .'P:;:s*ord/N Springfield'St. Jo^n^bur

    http:P.'q'.ci

  • JAU 2 ^ ;;.! VT. c :p ' i . nNVi.RONii!:::;:.-!. coNsr lyr.noN LP.20RATORV

    •DATA SHEET FOR V:--.!'!;.'! Oi.GA.-^ICS - WATER

    SAI-IPLE NUl-EER: 59291

    DAT'': RUN: 01-17-91

    S ^ ^ : Lubeck

    DAlE COLLECTED: 01-10-91

    :r.ed at.

    ua/1

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    ND

    V;V07

    V;V08

    VW09

    VW10

    VWll

    VW12

    V1V13

    VW14

    VWIS

    VW16

    VW17

    V̂ 'flS

    V^V19VW20VW21

    VW22

    VW

    VW25

    VW26

    VW27

    VW28

    VW29

    W20

    Vlf31

    VW32

    VW33

    VW34

    VW35

    VW36

    VW37

    VW3a

    VW39

    VW40

    VW41

    VW42

    TVH

    Vinyl chloride

    Chloromethane

    Bromomethane

    Chloroethane

    Trichlorofluoromethane

    Acetone

    1,1-Dichloroethene

    Carbon disulfide

    Methylene chloride

    Methyl-t-Butylether (MTBE)

    1,2-Dichloroethene

    1,1-Dichloroethane

    Vinyl acetate 2-Butanone

    Chloroform

    1,1,l-Trichloroethane

    Carbon tetrachloride

    Benzene

    1,2-Dichloroethane

    Trichloroethene

    1,2-Dichloropropane .

    Bromodichloromethane

    4-Methyl-2-pentanone

    cis-1,3-Dichloropropene

    Toluene

    trans-1,3-Dichloropropene

    1,1,2-Trichloroethane

    2-Hexanone

    Tetrachloroethene

    Dibromochloromethane

    Chlorobenzene

    Ethylbenzene

    Xylenes

    Styrene

    Bromoform

    1,1,2,2,-Tetrachloroethane

    Total Volatile Hydrocarbons

    W-IALYST: SF.l REIUKP.KS CODE DILUTION FACTOR: 1

    Approxima-e Defection Limit L ~ : uc/1 10 10 10 10

    10

    50

    2

    1

    2 10

    2

    2

    2

    2

    2

    2

    -1

    2 2

    20

    2

    2

    2

    2

    20

    2

    2

    2

    2

    2

    2

    2

    2

    100

    Bsai^/cs.

    SURROGATE RECOVERIES 1,2-Dichlaroethane - 04: 120** D8-Toluene: 4-BromoFluorobenzene: 116%

    3D\VW01

    http:REIUKP.KS

  • ^ i c o C C

    State of Vermont

    AGENCY OF NATURAL RESOURCES Department of Environmental Conser\ation

    D e p a r i m e n : of Fish ana Wi i c i i f e Hazardous M a t e r i a l s Management D i v i s i o n

    D e o a r i m e n t o t roresTS, Parks and flecreai'on 103 Sou th Main S t r e e t Deoannnen i of E n v i r c n m e n r a l Conserva r ion

    State Geo log is t W a t e r b u r y , VT 05671-0404 Na tu ra l Pesou'Cfts Conse'^vaTion C o u n c i l

    A p r i l 2 8 , 1992

    Mrs, Nancy Lubeck

    Box 51

    N. Pownal, VT 05260

    Dear Mrs. Lubeck:

    Enclosed are the analytical results of the water sample taken from your tap on

    April 10, 1992. On the left is the list of chemicals that the sample was

    analyzed for. The ce.iter column identifies the minimum amount of chemical that

    can be detected, in parts per billion (ug/1). The column on the right identifi.es

    the amount of each chemical detected, in parts per billion. The "ND" listed j.n

    this column stands for "not detected", and means that none of these chemicals

    were in the sample in detectable amounts. Your drinking water is safe to'drink

    according to Vermont drinking water standards.

    0 The Hazardous Materials Management Division will continue to monitor remediation

    efforts at the former Pownal Tannery. We appreciate your cooperation in this

    matter. If you have any questions regarding the sampling, cr other concerns

    regarding the Pownal Tannery^ please feel free to call me at 244-8702. Thank : y ^

    you.

    Brian Woods, Hydrogeologist

    Sites Management Section

    http://identifi.es

  • DEPARTMENT OF ENVIRONMENTAL CONSERVATION LABORATORY m 2 m2 DATA SHEET METHOD 8240 GC/MS FOR VOLATILE ORGANICS - WATER

    ^̂ âmple Number: 68445

    Date Run: 4/16/92

    Site: Lubeck

    Date Collected: 4/ 10'92

    Analyst: SRL

    Dilution Factor:

    Approximate Detection Limit

    VW07

    VW08

    VW09

    W/10

    VWll

    v\n2 \nn3 VW14

    VWIS

    VW16

    W/17

    v;vi8

    VW19

    V;V20

    ' " • f Z l

    VW22

    VW23

    VW24

    VW25

    Vl'tie

    VW27

    V;̂ 28

    V1729

    VW30

    VW31

    VW32

    VW33

    V(V34

    VW35

    VW36

    VW37

    W738

    VW39

    VW40

    V\̂ 41

    VW42

    ^ ,H

    Vinyl chloride

    Chloromel:hane

    Bromomethane

    Chloroethane

    Trlchlorofluoromethane

    Acetone

    1,1-Dichloroethene

    Carbon disulfide

    Methylene chloride

    Methyl-t-Butylether (MTBE)

    1,2-Dichloroethene

    1,1-Dichloroethane

    Vinyl acetate

    2-Butanone

    Chloroform

    1,1,l-Trichloroethane

    CcU±on tetrachloride

    Benzene

    1,2-Dichloroethane

    Trichloroethene

    1,2-Dichloropropane

    Bromodichloromethane

    4-Hethyl-2-pentanone

    cis-1,3-Dich