Short Fiber Composite Theory

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    CONTINUOUS FIBER COMPOSITE STRENGTH

    Composite stress is given by the simple rule of mixtures:

    1 (1 )f f fV V m = +

    for strains before onset of matrix cracking.

    Two Cases

    Case 1: Fiber has a higher strain to failure, and

    Case 2: Matrix has the higher strain to failure

    In the figure above (Hull, D. and Clyne, T. W. 1996.An Introduction to Composite

    Materials.Cambridge Univ. Press):

    1 (1 )u f fmu f mV V u = + u 1 (1 )u f fu f mf V V = +

    ' ' muf

    fu fmu mu

    V f

    = =

    + ' '

    mu mfu

    f

    fu mfu m

    V fu

    = =

    +

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    SHORT FIBER COMPOSITES

    Cost effective manufacturing often drives the use of discontinuous or short reinforcing

    elements in composites. These materials differ from continuous reinforced composites

    because the fibers do not extend throughout the entire material. Therefore, load is not

    directly applied to each reinforcing element.

    Stress Transfer

    The most commonly quoted theory of stress transfer in discontinuous element composites

    is the shear-lag analysis.1 Classically, this element is considered as a discontinuous

    cylindrical fiber embedded in a continuous matrix.

    Differences in longitudinal strain in the matrix and adjacent fiber (matrix >> fiber) will

    result in shear stresses at the interface. Tensile load is transferred to the fibers by a

    shearing mechanism between fibers and matrix. The stresses acting on this body are:

    c

    dz

    f

    + d

    Ignoring stress transfer at the fiber end cross sections and interaction between

    neighboring fibers, we can calculate normal stress distribution by a simple equilibrium

    analysis. Consider the force equilibrium on the infinitesimal length, dz:

    ( ) ( ) ( )( ) r r dz r f f2 22+ = + d f

    1Agarwal, B.D. and L.J. Broutman. 1990. Analysis and Performance of Fiber Composites; 2ndedition.

    John Wiley and Sons, Inc. NY, NY. 449 pp.

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    Reducing this relation, we find that the change in fiber stress with length is:

    d

    dz r

    f

    =2

    This relation implies that the change in fiber stress is proportional to the shear stress atthe interface between the fiber and matrix. The fiber stress at any point along the fiber is

    obtained by integrating this equation with respect to z.

    f fo

    z

    rdz= +

    2

    0

    The stress at the fiber end, fo, is often negligible and can be neglected in theformulation:

    fz

    rdz= 2

    0

    This formulation requires knowledge for the shear stresses along the fiber length.

    Although these are seldom known, one frequently used assumption is that the matrix

    material is perfectly rigid and perfectly plastic. In this case, the shear stress would

    develop instantly at the end of the fiber, reaching a maximum of the yield stress (y). Thenormal stresses in the fiber can then be given as:

    f

    yz

    r=

    2

    The maximum normal stress in the fiber will occur a mid-length (z = l/2):

    f

    yl

    r

    max =

    Assuming continuity of strains between the fiber, matrix, and composite (i.e. f= m=c), the maximum fiber stress can be given as:

    ff

    c

    cEE

    max =

    Because the normal stress in the fiber changes along the fiber length, we can assume that

    a minimum fiber length (lt) exists to transfer the maximum fiber stress. This minimum

    fiber length can be calculated by combining the previous two equations and rearranging:

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    ( )ld

    E Et f

    y

    f c

    y

    = =

    max /

    2 2

    c

    If we consider that the maximum fiber stress can be equated to that required to fail the

    fiber (fu), then we can imagine that extremely short fibers will never develop enoughstress to fail. This concept leads to the theory that a critical fiber length (lc)exists foreffective reinforcement:

    l

    d

    c fu

    y

    =

    2

    Semi-Empirical Equations

    Halpin-Tsai Equations

    Halpin and Tsai2 performed a more exact micro-mechanics analysis on unidirectional

    composites with short fibers. For simplicity, approximate equations were produced that

    afford a more precise prediction of properties.

    The basic form of the relations is given as:

    fi

    fii

    m

    i

    E

    E

    +=

    1

    1

    where:

    ( ) imf

    mf

    iEE

    EE

    +

    =

    /

    1/

    iindicates the two principal material directions; longitudinal (L) or transverse (T) to the

    fiber direction

    The reinforcement shape parameter, idepends on the direction of loading and the fillershape:

    2,2 == TLx

    L where: x equals the fiber diameter or platelet thickness

    For random filler orientation the modulus is approximated as3:

    8

    5

    8

    3 TLr

    EEE += OR

    48

    TLr

    EEG +=

    2Halpin, J.C. and S.W. Tsai. 1969. Effects of Environmental Factors on Composite Materials. AFML-

    TR 67-423.3Agarwal, BD and JL Broutman. 1990. Analysis and Performance of Fiber Composites. John Wiley and

    Sons, NY, NY. 449pp.

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    Discontinuous Fiber Composite Strength

    Assuming (1) an aligned short fiber composite with (2) the load placed parallel to the

    fiber direction, the overall stress in the composite can be calculated as:

    mmffc +=

    And peak stress at the center of fiber = max2

    f

    l

    d

    = because force acting on half a fiber is:

    x

    F3

    Assuming a linear stress variation in the fiber

    2

    1

    2

    2

    3

    / 4

    [ ]

    f

    f f

    F D

    F d DF Ddx

    =

    = +=

    / 4

    D

    For equilibrium, F1+ F3= F2and by integration and simplification, we get

    4 ( / 2 ) /f

    l x =

    Note, x is measured from the mid-length of the fiber and is assumed to be a constant.

    In solving these equations, recall that the normal stress in a fiber changes along the

    discontinuous fiber length.

    dx

    F1 F2

    0

    l/2

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    fu

    The average fiber stress,f , is determined by taking the area under the stress-fiber

    length graph and dividing by the fiber length.

    Now consider the following three cases:

    Length Governing Equation Notes

    l < ltmmffc +=

    max

    21 Triangular stress over lt

    l > lt ( ) mmfftc ll +=

    max

    21 l >> lt

    mmffc += max 121 llt

    Considering both the ultimate fiber stress (fu) and matrix stress (mu) we can computethe composite material strength (cu)

    Length Governing Equation Notes

    l < lc ( ) mmufyc dl += Matrix failure or fiber pull-out

    l > lt ( ) mmffutc ll += 21 m= mat fu

    l >> lt mmffuc += 121 llt

    llc/2

    lc

    l

    2clD

    2 clD

    2 lD

    fu

    fu

    f

    f

    f

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    Interphase Volume

    For composites with engineered filler-matrix interfaces, a third phase must be

    is often

    )

    where fis the filler volume fraction in the fiber-interphase

    complex.

    simplification assumes:

    ==

    Using this assumption, the effective fiber volume fraction can be solved by fitting the

    of

    considered.4 The material interphase has properties higher than the matrix and

    included in the fiber volume fraction. Therefore, an effective fiber volume fraction (feff

    and fiber modulus (Efeff

    ) is substituted in the equations above for and E respectively.These terms can be computed as:f f

    if

    eff

    f +=

    iiff

    eff

    f EEE += '

    A common

    eff

    ffi EEE

    modified Halpin-Tsai equations to the reinforced composite modulus at varying levelsfand solving for i

    4Jancar, J. 1999. Engineered Interfaces in Polypropylene Composites. In:Handbook of Polypropylene

    and Polypropylene Composites, HG Karian ed. Marcel Dekker, NY, NY. 559pp.

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    Equations Relating to Weight and Volume Fractions

    y Definition

    B

    nVolume Fractiocmmcff VVandVV ==

    Weight Fractioncmmcff WWandWW ==

    Invoking the definition of density:

    f

    c

    ffff VW

    ccc

    fVW

    === and m

    c

    m

    cc

    mm

    c

    m

    mV

    V

    W

    W

    ===

    y identity:B

    m 1=+=+ fmf

    ssuming that the material is void free:

    voking the definition of density:

    A

    mfcmfcVVVandWWW +=+=

    In

    mmffcc VVV +=

    ividing each side by the composites volume leads to:D

    mmffc +=

    r using similar paths for weight fraction:o

    m

    mf

    fc

    +=1

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