Section VI 27 Nuclear Physics

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    Nuclear Physics 27. Nuclear Physics

    Content

    27.1 The nucleus 27.2 Isotopes

    27.3 Nuclear processes

    27.4 Mass excess and nuclear binding energy

    27.5 Radioactive decay

    Learning Outcomes

    (k) show an appreciation of the association between energy and mass asrepresented by E = mc2 and recall and solve problems using this relationship.

    (l) sketch the variation of binding energy per nucleon with nucleon number.

    (m) explain the relevance of binding energy per nucleon to nuclear fusion andto nuclear fission.

    (n) define the terms activity and decay constant and recall and solve problemsusing A = N.

    * (o) infer and sketch the exponential nature of radioactive decay and solveproblems using the relationship x = xoexp(t) where x could represent activity,number of un-decayed particles or received count rate.

    (p) define half-life.

    (q) solve problems using the relation = 0.693/t

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    Mass defect At the nuclear level, since the masses are very small, instead of measuring

    them in kilogram, we measure the masses of nuclei and nucleons in atomic

    mass unit One atomic mass unit (1 u) is defined as being equal to one-twelfth of the

    mass ofcarbon-12 atom. 1 u is equal to 1.66 x 10-27 kg

    Using this scale we have:

    proton mass mp = 1.007276 u

    neutron mass mn = 1.008665 u

    electron mass me = 0.000549 u

    e.g. the mass of a helium-4 nucleus which consists of 2 protons and 2

    neutrons should be (2 x 1.007276) + (2 x 1.008665) = 4.031882 u

    However the actual mass of a helium nucleus is 4.001508 u, less by0.030374 u

    This difference between the expected mass and the actual mass of a nucleus

    is called the mass defectof the nucleus(i.e. mass of the product < the sum ofmasses of reactants)

    Hence mass defect of a nucleus is the difference between the total mass ofthe separate nucleons and the combined mass of the nucleus

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    Example

    Calculate the mass defect for a carbon-14 nucleus. The measured mass is

    14.003240 u.

    Solution

    The carbon-14 nucleus contains 6 protons and 8 neutrons,

    Hence, total mass of separate nucleons is,(6 x 1.007276) + (8 x 1.008665) = 14.112967 u

    Given, combined mass is = 14.003240 u

    Therefore the difference is the mass defect = 0.109736 u

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    Mass-energy equivalence principle

    In 1905 Albert Einstein proposed that there is a equivalence between mass

    and energy, the relationship being

    E = mc2

    where c is the speed of light in metres per second , E is measured in joules

    and m in kilograms

    In the example of the helium nucleus earlier, since the mass defect is0.030374 u, converting u into kg and using the above Einsteins equation,the energy equivalent is 4.54 x 10-12 J

    This energy in Joules can be converted into eV which is a more convenient

    energy unit by dividing by 1.6 x 10-19 J giving 28.4 MeV

    1 u change in mass is the equivalent of 931 MeV The mass of object when it is at rest is called its rest mass

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    Binding energy

    Within the nucleus there are strong forces which bind the protons and

    neutrons together, and to separate all these nucleons requires energy i.e.work must be done, referred to as the binding energyof the nucleus(bindingmeans held together)(actually more appropriate to call it unbindingenergy)

    Stable nuclei which have little or no tendency to disintegrate, have largebinding energies whereas less stable nuclei have smaller binding energies

    Similarly, to join together protons and neutrons together to form a nucleus,

    this binding energy must be released.The binding energy is the equivalentof the mass defect

    Referring again to the helium example earlier, since the energy equivalent of

    the mass defect is 28.4 MeV which is the binding energy, 28.4 MeV of

    energy is required to separate to infinity the 2 protons and 2 neutrons ofthis nucleus

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    Example

    Calculate the binding energy in MeV of a carbon-14 nucleus with a mass defect

    of 0.109736 u.

    Solution

    Using the equivalence 1 u = 931 MeV,

    0.109736 u = 102 MeV

    Since the binding energy is the energy equivalent of the mass defect,the binding energy = 102 MeV

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    Stability of nuclei Within the nucleus of an atom the nucleons experience 2 major forces of attraction

    and repulsion

    The attractive forcewhich is called the strong nuclear forceacts like a glue to holdthe nucleons together and it is a short range force The repulsive forces are the electric forces between the positively charged protons

    (Coulombic force), which is a long range force The strong force is strong enough to overcome the Coulombic repulsion between

    protons otherwise the protons would fly apart

    Stability of a nucleus is determined by the equilibrium between these forces

    Stable nuclei have much larger attractive forces than repulsive forces Gravitational force of attraction also exist, but are negligible in comparison to the

    other 2 forces

    A stable nucleus is one which has a very low probability of decay

    Stable nuclides generally have approximately the same number of protons to theneutrons in the nucleus i.e. neutron-to-proton ratio is close to 1

    A useful measure of stability is the binding energy per nucleon which is defined asthe total energy needed to completely separate all the nucleons in a nucleusdivided by the number of nucleons in the nucleus

    The most stable nuclides are those with the highest binding energy per nucleon e.g.iron

    Typically very stable nuclides have binding energies per nucleon of about 8 MeV

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    Neutron vs proton number curve

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    Binding Energy/nucleon curve

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    Example

    The binding energy of a helium-4 nucleus is 28.4 MeV. Calculate the binding

    energy per nucleon

    Solution

    The helium-4 nucleus has 4 nucleons.

    The binding energy per nucleon is 28.4/4 = 7.1 MeV

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    Fusion and fission

    For a system to become stable, it tends to give out energy so that it has less

    energy content.

    e.g. chemical reaction : acid + base,

    mechanical : horizontal cylinder is more stable than standing

    cylinder

    Hence, a system also tends to be more stable if it has less mass. This is

    demonstrated in nuclear reactions. Light nuclei may combine or fuse to form larger nuclei with larger binding

    energies per nucleon in a process called nuclear fusion

    For this process to take place conditions of very high temperature andpressure are required, as in stars e.g. the Sun

    Heavy nuclei when bombarded with neutrons may break into 2 smallernuclei, again with larger binding energy per nucleon values in a process

    called nuclear fission. Fission rarely happens spontaneously

    Whenever nuclear fusion or fission takes place, the nucleon numbers of the

    nuclei involved change, a higher binding energy is achieved and this is

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    Nuclear fission

    Being uncharged, neutrons can penetrate the nucleus more easily, but the

    problem is that they cannot be directed and controlled by electric andmagnetic fields

    In heavy nuclei such as uranium and plutonium there are far more neutrons

    than protons, giving a neutron/proton ratio of more than 1

    e.g. uranium-235 has 92 protons and 143 neutrons giving a neutron/proton

    ratio of 1.55

    This leads to a much lower binding energy per nucleon compared with iron

    Any further increase in the number of neutrons in such nuclei is likely to

    cause the nucleus to undergo nuclear fission

    Nuclear fission is the splitting of a heavy nucleus into 2 lighter nuclei ofapproximately the same mass

    One element changing into another is called transmutation

    The energy released per atom by fission(about 200 MeV) is about 50 million

    times greater than that per atom from a chemical reaction such as burning

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    Induced nuclear fission

    When nuclear fission is started by the capture of a neutron by say a uranium

    nucleus, it is known as induced nuclear fission When a uranium-235 nucleus absorbs a neutron, it becomes unstable and

    splits into 2 lighter more stable nuclei. Although other fission reactions arepossible, the most likely reaction is

    235U92 +1n0 141Ba56 +92Kr36 +31n0 + energy

    If these released neutrons are absorbed by other uranium-235 nuclei, thesetoo may become unstable and undergo fission, thereby releasing even moreneutrons causing a chain reaction

    In such a case, the reaction continues uncontrolled and a great deal ofenergy is released in a short time

    If the reaction is controlled so that the number of fissions per unit isconstant, the rate of release of energy can be controlled

    This is precisely what is done in a modern nuclear power station wheresome of the neutrons released in the reactions are absorbed by control rods

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    Nuclear fission reactor There are several possible fission reactions which may occur in a nuclear

    reactor represented by the general equation235

    U92 +1

    n0 236

    U92 2 new nuclides + 2 or 3 neutrons + energy The nuclides formed in this reaction are called fission fragments Main type of reactor is the Pressurised water-cooled reactor(PWR)pg 372

    fig 13.15 Physics by Chris Mee

    Inside a reactor, uranium-235 is placed in long fuel rods surrounded bypressurised (150 atm) heavy water (deuterium) called a moderator whose

    role is to slow down the neutrons releasedduring fission Slow moving neutrons are more readily absorbed by uranium-235 The number of neutrons available to trigger further fission reactions is

    controlled by using control rodsmade of boron or cadmium Pushing the control rods further into the reactor core causes more neutrons

    to be absorbed and hence the rate of fission reactions decreases

    The heat energy that is produced is removed from the reactor by a coolant(water) which is then used to produce high temperature steam in a heatexchanger to drive turbine generators

    The other main type of commercial nuclear reactor for generation ofelectricity is the Advanced Gas-Cooled reactor(AGR) where helium gas isthe coolant

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    Disadvantages of nuclear fission

    If the fission material is less than a certain critical mass, too many neutrons

    escape without hitting the nuclei

    The fission of uranium-235 produces medium-speed neutrons, while slow

    neutrons are better at causing fission

    1 neutron from each fission must cause further fission to maintain a chain

    reaction

    Less than 1% of natural uranium is uranium-235 while over 99% is

    uranium-238 which absorbs medium-speed neutrons without fiffion taking

    place

    Uncontrollable chain reactions

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    Nuclear fusion

    Most of the energy on Earth comes from the Sun i.e. solar energy through

    thermonuclear reactions It is produced by nuclear fusion reactions whereby light nuclei such as

    isotopes of hydrogen join together to produce heavier more stable nuclei andin doing so release energy

    One of the fusion reactions is 2H1 +2H1 3He2 +1n0 + energy

    The binding energy per nucleon for light nuclei such as hydrogen is low, but

    if 2 light nuclei are made to fuse together, they may form a stable newheavier nucleus which has a higher binding energy per nucleon thusreleasing energy

    Fusion is much more difficult to achieve than fission

    In order to produce these thermonuclear reactions requires extremely hightemperatures(108 or more K) and pressures like that in the Sun because the

    hydrogen nuclei have to be brought very close together against thecoulombic repulsive forces which repel each other

    We are at present unable to duplicate this reaction in a controlled manneralthough work is being carried out by Joint European Torus (JET) andInternational Tomahawk Engineering Research (ITER) an internationalconcern

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    Advantages of nuclear fusion

    Advantages are:

    Fuels will be readily obtainable for example deuterium can be extracted

    from sea-water

    The main waste product is helium which is not radioactive

    Fusion reactors have built in safety features, as, if the system fails, fusion

    stops

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    Radioactive decay series

    The daughter nuclide of a radioactive decay may itself be unstable and so

    may emit radiation to give another different nuclide

    This sequence is called a radioactive decay series

    (to get picture of decay series)

    Alpha decay tends to occur in heavy nuclides which are below the stabilitylineof the NZ curve

    - - Beta decay(actually beta minus decay) tends to occur in heavy nuclides

    which are above the stability lineof the NZ curve

    During beta minus decay, a neutron is converted into a proton, an electron

    and an almost undetectable particle with no charge and near-zero mass

    called an antineutrino + - Beta plus decay is an emission of a positron with the same mass as an

    electron but a charge of +1 e. It is the antiparticleof an electron

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    Neutron vs proton number curve

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    Detecting/measuring radioactivity

    Some of the methods of detecting/measuring radioactivity are based on the

    ionising properties of the particles or radiation

    The Geiger Countera tube with argon gas at low pressure and a thin micawindow to allow radiation in. Presence of radiation causes ions pairs in the

    gas which are accelerated through a potential difference and counted

    Photographic plates when radioactive emission strikes a photographicfilm, the film reacts as if it had been exposed to a small amount of visible

    light which when developed, a fogging or blackening is seen. Used in film

    badge dosimeter where the radiation passes through different filters

    consequently the type of radiation as well as the quantity can be assessed

    The Scintillation counter this is a device that uses the principle ofphotoelectric emission. When radiation is incident on zinc sulphide it emits

    tiny pulses of light called a scintillation which causes emission ofphotoelectrons from the negative electrode of a photomultiplier tube which

    amplifies the current and is measured or counted

    All measurements should take into consideration the background radiationdue to natural radioactivity and man-made sources which should be

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    Nature of radioactive decay

    The emission of radiation is due to radioactivity is both spontaneous and

    random Spontaneous means it is not affected by any external factors such as

    temperature or pressure

    Randommeans that it is not possible to predict which nucleus in a samplewill decay next

    However there is a constant probability or chance that a nucleus willdecay in any fixed period of time

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    Random nature of radioactive decay-simulation

    A dice has 6 faces and if 6 dice are thrown simultaneously it is likely that

    one of them will show a 6

    If 12 dice are thrown, it is likely that 2 of them will show a 6 and so on

    While it is possible to predict the likely number of sixes, it is impossible to

    say which of the thrown dice will actually show a 6

    If a large number of dice say 6000 is thrown, and every time a 6 shows that

    die is removed, below is a likely scenario

    No of throws No of dice remaining No of dice removed

    0 6000

    1 5000 1000

    2 4173 827

    3 3477 696

    4 2897 580

    5 2414 483

    6 2012 402

    7 1677 335

    8 1397 280 22

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    cont

    If a graph ofno of dice remaining vs no of throws is plotted, a decay curve

    will be obtained which is not linear but has a pattern similar to the decay ofcurrent in a circuit containing a capacitor and a resistor

    This experiment can be applied to model radioactive decay where the dice

    represent the radioactive nuclei, and the 6 on the dice representing the

    radioactive emission.

    Once a nucleus has undergone radioactive decay it is no longer available for

    further decay

    A graph of the number of un-decayed nuclei in a sample against time has a

    typical decay curve as above

    The half-life of a radioactive nuclide is the time taken for the number ofun-decayed nuclei to be reduced to half its original number

    Half-life may also be expressed in terms of the activityof the material

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    Example

    The half-life of francium-221 is 4.8 minutes. Calculate the fraction of a sample

    of francium-221 remaining un-decayed after a time of 14.4 minutes.

    Solution:

    14.4 mins is 3 half-lives since 14.4/4.8 = 3

    therefore after 1st

    half-life only remainsafter 2nd half-life only remains

    after 3rd half-life only remains

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    Activity and decay constant

    On investigation, we find that the greater the number of radioactive nuclei in

    the sample, the greater the rate of decay i.e. the more undecayed nuclei thereare, the more frequently disintegrations are likely to occur

    Mathematically this is described as dN/dt N which gives

    dN/dt = - N

    where N is the number of un-decayed atoms in the sample, and dN/dt is therate at which the number in the nuclei is changing, so dN/dt represents therate of decay and is called the activity A of the source. A is measured inbecquerels (1 Bq = 1 s-1)

    Combining A = - dN/dtand dN/dt = - N we have A = N

    where

    is a constant of proportionality known as the decay constant, of units-1, yr-1 etc

    Decay constant , is defined as the probability per unit time that a nucleuswill undergo decay

    This is an important equation because it relates a quantitydN/dt which we

    can measure to a quantity which we cannot i.e. number of un-decayed nuclei Also we will see that is directl related to the half-life of the nuclei

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    Example

    Calculate the number of phosphorus-32 nuclei in a sample which has an

    activity of 5.0 x 106 Bq. (given decay constant of phosphorus-32 is 5.6 x 10-7s-1)

    Solution

    from dN/dt = - N, N = (-dN/dt)/ = (-5.0 x 106)/(5.6 x 10-7) = -8.9 x 1012

    The minus sign indicates a decay

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    Mathematical descriptions of radioactive decay

    To solve the equation dN/dt = - N requires higher level mathematics;

    however it is important to know the solution in order to find the variationwith time of the number of nuclei remaining in the sample

    The solution is N = Noe-t or N = Noexp(-t)

    where Nois the initial number of un-decayed nuclei in the sample, and Nis the number of un-decayed nuclei at time t

    This equation represents an exponential decay

    Since the activity A is proportional to N, the curve ofA against t is of thesame shape and hence we can write

    A = Aoe-t or A = Aoexp(-t)

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    Example

    A sample of phosphorus-32 contains 8.6 x 1012 nuclei at time t = 0. The decay

    constant of phosphorus-32 is 4.8 x 10-2 day-1. Calculate the number of un-decayed phosphorus-32 nuclei in the sample after 10 days.

    Solution

    using N = No

    e-t , we have N = 8.6 x 1012 x e-0.048x10 = 5.3 x 1012

    (always ensure that and t are consistent in their units i.e. days mathced to

    days, seconds matched to seconds etc)

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    Decay constant and half-life

    Using N = Noe-t we can derive an equation which relates the half-life to the

    decay constant

    For any radioactive nuclide, the number of un-decayed nuclei after 1 half-

    life is by the definition, equal to No/2 where No is the original un-decayednuclei.

    Using N = Noe-t we have at time t = t

    N = Noe-t

    and dividing each side by No

    N/No = 1/2 = e-t

    or 2 = etand taking natural logs of both sides

    lne 2 = t so that t= ln 2/ t= 0.693/

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    Example

    Calculate the half-life of radium-226 which has a decay constant of 1.42 x 10-11

    s-1.

    Solution

    Using t= 0.693/ =4.88 x 1010 s

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    Matter particles

    Matter particles

    Hadrons Leptons

    (feel the strong nuclear force) (do not feel the strong nuclear force)

    (have no size, low or no mass)

    Baryons Mesons(includes protons (particles lighter

    neutrons & heavier than protons)

    particles)

    Proton - Pion - Electron

    Neutron - Kaon - Electron-neutrino

    Lambda - etc - Muon

    Sigma - Tau

    Omega

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    Quantum numbers & quarks

    Particles have various quantum numbersassigned to them to represent

    other quantities seen during interactions

    Examples: Charge, Lepton number, Baryon number, Strangeness, Charm,

    Spin, Topness, Bottomness

    The properties and quantum numbers of hadrons can be accounted for by

    assuming that each particle is a combination of others called quarkswhichhave fractional charge

    Example: Baryons are each made up of 3 quarks, Mesons are made up of

    a quark & antiquark

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    Force carriers

    Nucleons need not be in contact to exert forces on each other

    To explain how the strong force is carried from one nucleon to another, the

    idea ofexchange particles is used

    Particles that carry the fundamental forces are known as gauge bosons

    Quarks are bound together by gluons

    Force Gauge bosons

    strong gluon

    electromagnetic photon

    weak W plus, W minus

    gravitational graviton

    Existence of a graviton is speculation only

    Grand unified theories(GUTs) seeks to link all the above forces

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