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8/10/2019 Script Part4 Laser
1/45
Chapter 4: Stimulated emission and LASERS
Stimulated EmissionStimulated emission and photon amplificationStimulated emission rate and Einstein coefficients
Light amplificationRate equations for amplifiers
Laser Oscillation ConditionOptical threshold gainOutput characteristics
Semiconductor laser diodePrinciplesGain spectrum under forward biasHomojunction laser diodeHeterojunction laser diodeLaser diode layout and lateral mode confinementLaser diode characteristicsSteady state semiconductor rate equationsOptimal out-couplingDistributed bragg reflection for single mode lasersGain spectrum in QW lasersLow dimensional structures & threshold current reductionVertical cavity surface emitting lasersLate News: Ge electrically pumped laser
TFH SS 2012 92
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Stimulated emission and photon amplification
Photon absorption excites electronfrom E1 E2.
Allowed process, if energy (insemiconductor: and momentum) isconserved (Ph =hPh =E2 E1).
Two possibilities for de-excitation:i) Spontaneous emission:Eventually, also the electrons in an isolated atom will return to
their ground state spontaneously, without external action (purely QM process), bothradiative (photon emission hPh =E2 E1) and non-radiative transitions [phononemission (lattice vibration) etc.] can occur.
ii) Stimulated emission: The interaction of the atoms excited electron with an EMradiation in resonance with the de-excitation energy E2 E1 triggers the de-excitation.A photon coherent with the incoming EM field (in phase and with same propagationdirection relative to incoming photons) is emitted [inverse process to (stimulated)
absorption]. Not considered until 1916 (Einstein), but required for an opticallypumped system to reach stationarity, since absorption rate depends on intensity, butspontaneous emission rate not.
Stimulated emission is the base process for light amplification.
Shown later: Light amplification requires more electrons in the excited state than inthe ground state(population inversion).
TFH SS 2012 93
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Stimulated emission rate and Einstein coefficients
N [cm3] two level system in thermal equilibrium withradiation in black body (BB).
N1 in groundstate @ E1, N2 in excited state @ E2,N=N1+ N2.
Stimulated excitation (absorption) rate R12 proportional toN1, to the number of photons with h21=E2 E1 pervolume {i.e. to the energy density (h21), [] =Jsm
3}:
R12 =B12N1(h21), [B12] =m3J1s2
De-excitation rate R21 =Rstim21 +R
spont21
analog to absorption: Rstim21 =B21N2(h21) R
spont21 =A21N2, independent of number of photons, only
prop. to N2.
R21 =A21N2+ B21N2(h21)
Above equations define Einstein coefficients B12, B21, A21as proportionality factors for the rates.
Thermal equilibrium:a) R12 =R21.
b) Boltzmann statistics: N2/N1 = e(E2E1)/kBT = eh21/kBT.
c) Photon energy density in BB given by Plancks law: eq(h)= 8h3
c3
eh/kBT 1
TFH SS 2012 94
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Stimulated emission rate and Einstein coefficients
Three equations for the three Einstein coefficients.
Dividea)byN1 and solve for N1/N2:N2
N1 =
B12(h21)
A21+ B21(h21) Using Boltzmann statisticsb)results in:
e21/kBT =
B12(h21)
A21+ B21(h21) (h21) =
A21/B21(B12/B21)e21/kBT 1
Comparision with Plancks lawc): Equal for all T only, if
B12 =B21 B and A21
B21= 8h
321
c3 (= h Photon DOS)
Interpretation: Stimulated emission and absorption are inverse processes and occur with equal
probability per available initial state (2 for stim. emission, 1 for absorption) population inversion (N2 >N1) can never be achieved by intense optical pumping a
two level sytem, at most transparancy (N1 = N2) is achieved. Spontaneous emission prop. and stimulated emission prop. are related, ratio
increases with 3, harder to construct x-ray lasers.
Rstim21R
spon21
= BA(h) = 1
h(h)
Photon DOS
Ratio increases with:i) # photons available optical resonator
ii) decreasing density of photon states optical resonatorTFH SS 2012 95
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Light amplification
Absorption law: dIdx
= I I(x) =I0ex exponential decay of intensity I.
For expressing via electron transition rates, we convert intensity I into photonflux , photon density nPh and : I = h=nPhch=c(h).
dI
dx =hd
dx =ch
dnphdx
=hdnph
dt =h(R12+ R21) = (N1 N2)hB(h).
dI
dx = (N1 N2)
hBc
I
negative for population inversion (N2 >N1) exponentially growing intensity,i.e. gain.
gain coefficient g= (N2 N1)nrefhB
c0
TFH SS 2012 96
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Rate equations for amplifiers Which pump-rate is required to achieve
gain (i.e. population inversion)?
ideal pumping scheme involves 4 levels
Spontaneous transition rates lumpedtogether and are expressed as inverselifetimes (i.e. Rspon21 =
121,spon)
example: spontaneous lifetime of level 2: 12 =121 +
120 =
121,sp+
121,nr+ +
120
Rate equations [Wi = B(h12)]:
dN3
dt= R
N3
32
dN2
dt=
N3
32
N2
2 N2Wi+N1Wi
dN1
dt=
N2
21
N1
1+N2Wi N1Wi
dN0
dt= R+
N1
1+
N2
20
32 3x N3 = R32 dN2dt
= R N22 N2Wi+N1Wi
stationary solution d
dt= 0 :
N N2 N1 = R2(1 1/21)
1 + Wi[2+1(1 2/21)]
N0
1 + Wis
N
0
: pop. inv. in the absence of amplifier radiation.s: saturation time.
Non-linear gain , gain saturation.
typically: nonr. 2 1 decay rate negligible (21 =21,sp) && 20 21,sp 1, thus: N0 R21,sp, s 21,sp.
Attention: for strong pumping,Rnot independent of N because
N0+ N1+ N2+ N3 =Na (atom density) and N3 N1 0 N0 Na N2 Na NTFH SS 2012 97
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Laser oscillation conditionOptical threshold gain
gain coefficient (stim. em.)
g= (N2 N1)B21nrefh21
c0 loss:
abs : absorption: impurities in laser medium, non-inverted allowed transitions with similartransition energy, free carriers (semiconductors !!)
sc : scattering out of resonator mode: defects and inhomogeneities.Ri : Out-coupling losses, power reflection coefficient of cavity mirrors R1,R2 1
stationarity conditions: Pf!
=PiPf =PiR1R2e
2Lgthe2L(abs+sc)
gth =
abs+sc+ 12Lln( 1R1R2 ) threshold gain.Nth =gth
c0
B21nrefh0 threshold pop. inv.
Increase R(i.e N0): g remains clamped at gthafter stationary is re-established N= Nth
.
102
101
100
101
102
Wis =/s
0.0
0.2
0.40.6
0.8
1.0
N/N0
=
g/g0 laser turn-on
loss=gth
steady state
time
ph. fluxdensity
TFH SS 2012 98
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Laser oscillation conditionOutput characteristics
Gain clamping: N= Nth
Nth = N0
1 +Wis
Wi = 1
s
N0
Nth 1
Wi(h12)
=s N
0
Nth 1, N0 >Nth
0, N0 Nth
steady-state laser-internalphoton-flux density
Spontaneous emission neglected. In addition: stationarity of phase
Fabry-Perot resonator modes.
Simplified description of a laser oscillator.
(N2 N1) and coherent output power P0
vs. pump rate Runder continuous wave
steady state operation.
TFH SS 2012 99
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PrinciplesoftheLaserDiode
pn junctioninaDegenerate
Semiconductor
FermilevelinthepregionisbelowEv
FemilevelinthenregionisaboveEc
Withnoappliedvoltage, Efn=Efp yields
averynarrowdepletionregion
Thereisapotentialenergybarrier,eVothatpreventsnsideelectronsfrom
diffusingto
the
pside
and
vice
versa
Whenvoltageisapplied
ChangeintheFermilevelisthework
donebytheappliedvoltage,eV
Ifthejunctionisforwardbiased
suchthatEfnEfp =eV >Eg
Appliedbiasdiminishesthebuildin
potentialbarrier
Depletionregionisnolongerdepleted
Therearenowmoreelectronsinthe
conductionbandthaninthevalance
bandnearEv Populationinversion
p+ n+
EFn
(a)
Eg
Ev
Ec
Ev
Holes in VB
Electrons in CB
Junction
Electrons
Ec
p+
Eg
V
n+
(b )
EFn
eV
EFp
The energy band diagram of a degenerately dopedp-n with no bias. (b) Banddiagram with a sufficiently large forward bias to cause population inversion andhence stimulated emission.
Inversionregion
EFp
Ec
Ec
eVo
1999 S.O. Kasap,Optoelectronics(Prentice Hall)
TFH SS 2012 100
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PrinciplesoftheLaserDiode
Populationinversionregionisa
layeralongthejunctioncalledtheinversionlayer(activeregion)
Anincomingphotonwithenergy
EcEvcannotexciteanelectronin
EvtoEcastherearehardlyany
presentinthevalanceband
withinthe
active
region
Hencethereismorestimulated
emissionthanabsorption
Theopticalgainpresentinthe
activeregionduetolackof
probabilityofvalanceelectron
absorption
h
Eg
Optical gainE
FnE
Fp
Optical absorption
0
Energy
Ec
Ev
CB
VB
(a) The density of states and energy distribution of electrons and holes inthe conduction and valence bands respectively at T 0 in the SCLunder forward bias such thatEFnEFp>Eg. Holes in the VB are empty
states. (b) Gain vs. photon energy.
Density of states
Electrons
in CB
Holes in VB
= Empty states
EFn
EFp
eV
At T> 0
At T= 0
(a) (b )
1999 S.O. Kasap,Optoelectronics(Prentice Hall)
TFH SS 2012 101
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Gain spectrum under forward bias
TFH SS 2012 102
Evolution of the absorption andgain curves as a function if the
position of the quasi-Fermi level.The gray (dark) curvescorrespond t oa small (large)displacement from equilibrium.In this case, the medium absorbsall photons having energies inexcess of the bandgap. Once theenergy separation between thetwo quasi-Fermi levels exceedsthe bandgap, all photons withenergies between Eg andE
F,cE
F,v are amplified.
From E. Rosencher, B. Vinter,
Optoelectronics, Cambridge University
Press (2002)
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Gain spectrum under forward bias
From A. Yariv, Quantum Electronics, 3rd edition, John Wiley & Sons, (1989)
TFH SS 2012 103
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ElectroopticalPerformanceofIII/VDiodes
injectionpumping: Opticalpumpingisachievedbyforward
diodecurrent
and
the
pumping
energy
is
an
external
battery
Forlaserwealsoneedanopticalresonatorcavity. Thisis
achievedthroughtheuseofaslabwaveguidewithahigh
indexcontrastattheemissionend
Wavelengthoftheradiationthatcanbuildupinthecavity
dependsonthelength(L)inhalf multiples
LElectrode
Current
GaAs
GaAsn+
p+
Cleaved surface mirror
Electrode
Active region(stimulated emission region)
A schematic illustration of a GaAs homojunction laserdiode. The cleaved surfaces act as reflecting mirrors.
L
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
ypical output optical power vs. diode current ( I) characteristics and the correspondingutput spectrum of a laser diode.
Laser
LaserOptical Power
Optical Power
I0
LEDOptical Power
Ith
Spontaneous
emission
Stimulated
emission
Optical Power
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
2criticalcurrentidentifiers
Transparency current: Currentabove
whichno
net
photon
absorption
occurs
Threshold current:currentabove
whichopticalgainovercomesall
photonlossesinthecavity
Lnm =
2
TFH SS 2012 104
R = (nGaAs1
nGaAs+1)2 35%
typically: Jth = 500 Amm2 for
homojunction LD !!
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Heterojunction LaserDiodes
Mainissuewithhomojunction diodesis
that
the
laser
threshold
current
density
istoohighforpracticaluses.
Ex.Jth =500A/mm2 forGaAs at300K
Heterostructured diodesreducethesecurrentdensitiesbyordersofmagnitude
Thisisachievedthroughacombinationofcarrierconfinement(mismatchedmaterials),andphotonconfinement(geometric
shape
of
the
waveguide)
Doubleheterojunction (DH)deviceswithnpp layersallowfordesignedconfinementoftheactiveregion
LowerrefractiveindexoftheAlGaAsenhancesthemodeconfinementincomparisontoahomoorsimple
heterojunction device Significantlyreducesthresholdcurrent
density
Refractiveindex
Photondensity
Active
region
n~ 5%
2 eV
Holes in VB
Electrons in CB
AlGaAsAlGaAs
1.4 eV
Ec
Ev
Ec
Ev
(a)
(b)
pn p
Ec
(a) A doubleheterostructure diode hastwo junctions which arebetween two dif ferentbandgap semiconductors(GaAs and AlGaAs).
2 eV
(b) Simplified energyband diagram under alarge forward bias.Lasing recombinationtakes place in the p-GaAs layer, theactive layer
(~0.1 m)
(c) Higher bandgapmaterials have alower refractiveindex
(d) AlGaAs layersprovide later al opticalconfinement.
(c )
(d)
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
GaAs
TFH SS 2012 105
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Photonics,6thedition Yariv andYeh
igure 15.10 A typical double heterostructure GaAs/GaAlAs laser. Electrons and holes are injected into the active GaAs layer from the
and p GaAlAs. Photons with frequencies near =Eg/h are amplified by stimulating electronhole recombination.
Cc 2007Photonics,6thedition Yariv andYeh (OxfordUniversityPress
TFH SS 2012 106
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Photonics,6thedition Yariv
andYeh 11
Figure 15.12 The magnitude of the energy gap in Ga1x
AlxAs as a function of the molar fraction x. For x > 0.37 the bandgap is indirect.
(After Reference [11].)
Cc 2007Photonics,6thedition Yariv andYeh (OxfordUniversityPress
TFH SS 2012 107
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Heterojunctions Laser Heterojunction diode: different materials for n & p
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Heterojunction diode: different materials for n & p
Different materials: significantly different index n
Also different lattice constants
Important point: want the lattice matched at layer boundary
Use mixed alloy: eg GaAs and AlAsAlxGa1-1As
x = mole fraction of Aluminum
1-x = mole fraction of Gallium
Heterojunctions Laser Single Heterojunctions: one sided confinement
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Single Heterojunctions: one sided confinement
p-GaAlAs: p-GaAs: n-GaAs
Better confinement means lower threshold current for lasing
Thus operates in pulsed mode at room temperature
Double Heterojunction lasers: confines both top & bottom
p-GaAlAs: GaAs: n-GaAlAs: n-GaAs
Double Heterojunctions Laser Has both Band and Index steps on both top & bottom
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Has both Band and Index steps on both top & bottom
Doubly confines light: creates a waveguide as cavity
Requires much less threshold current
Thus CW operation now possible at room temperature
Comparison of Homo/Hetero/D-Heterojunctions Lasers As add index steps get smaller light spreading
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As add index steps get smaller light spreading
Single hetrojunction threshold current ~5x < homojunction
Double hetrojunction threshold ~50-100x
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j
Surrounded both vertical & horizontal by lower material
1-2 microns wide: high efficiency, low threshold
Channeled Substrate
Etch channel in substrate: isolate active area
Low loss
Buried Crescent
Fill grove to get crescent shaped active strip
Heterojunctions with WaveguidesRidge Waveguide
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Etch away a mesa around active region
confines current flow to 2-3 micron strip
Double-channel planar buried heterostructure
Isolate active with mesa, then fill with lower index
used with very high power InGaAsP lasers
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EdgeEmittingLasers
VerysimilartoELEDdevicespresentedinchapter3
AdditionalcontactinglayerofpGaAs nexttothep=AlGaAs providesbettercontactingandavoidsSchottky junctionwhichwouldlimitthecurrentinthedevice.
pandnAlGaAs layersprovidecarrierandopticalconfinementintheverticaldirection
LaseremissionintheactivepGaAs(oradifferentAlGaAs constitution)regionisbetween870900
nm
depending
on
doping.
Schematic illustration of the the structure of a double heterojunction stripecontact laser diode
Oxide insulator
Stripe electrode
SubstrateElectrode
Active region where J> Jt h.
(Emission region)
p -GaAs (Contacting layer)
n -GaAs (Substrate)
p -GaAs (Active layer)
Current
paths
L
W
Cleaved reflecting surfaceEllipticallaser
beam
p -AlxGa
1- xAs (Confining layer)
n -AlxGa
1- xAs (Confining layer)
12 3
Cleaved reflecting surface
Substrate
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
AlGaAs andGaAs havenegligiblelattice
mismatchyieldingveryfewdefectsin
thecrystalthatwouldleadtoexcessive
thresholdcurrents
Also,thestripe electrodeacrossthetop
confinestheelectricfieldandthusthe
opticallyactive
region
providing
additionalgeometricalconfinement
Suchlasers arecalledgainguided,b/c
thecurrentdensitygeneratedisguided
bytheelectricfieldbetweenthestripe
electrodeandthebottomelectrode
TFH SS 2012 115
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BuriedHeterostructure LDs
Figure
from
Chapter
15
Photonics,
6th
edition
Yariv and
Yeh 2007
Oxford
University
Press
Althoughthestripeelectrodegeometryprovides
some
geometric
confinement,
it
is
more
advantageoustorestrictlateralgeometryphysically
throughtheuseofconfininglayersalongtheside
ofthediode
Creationofaopticalwaveguideinbothverticaland
horizontaldirectionsaidsinreducingopticalcavity
modes
and
promotes
confinement Significantlyreducescurrentdensityrequiredfor
stimulatedemission
TFH SS 2012 116
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ElementaryLaserDiode(LD)Characteristics
Longitudinalmode:lengthdetermined
Lateral
mode:
width
determined
Emissioniseithermultimodeorsingle
modedependingontheopticalresonating
structureandthepumpingcurrentlevel
Height,HWidth W
Length,L
The laser cavity definitions and the output laser beamcharacteristics.
Fabry-Perot cavity
Dielectric mirror
Diffraction
limited laser
beam
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
778 780 782
Po= 1 mW
Po= 5 mW
Relative optical power
(nm)
Po= 3 mW
Output spectra of lasing emission from an index guided LD.At sufficiently high diode currents corresponding to highoptical power, the operation becomes single mode. (Note:Relative power scale applies to each spectrum individually annot between spectra)
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
TFH SS 2012 117
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TFH SS 2012 118
Steady state semiconductor rate equations
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S y q
Current (I) pump rate: R= IedLW
Photon loss rate: dNph
dt =
Nphph
, where ph is
average time for a photon to be lost from
lasing cavity mode due to transmission at end facets,scattering and absorption in the semiconductor
Use rate equ. results (p. 97 f): assume a) 2 =21 =21,sp; b) 1 0 N1 0
N= N01+Wis
N2 R21,sp1+Wi21,sp
; in particular Nth Nth2 =Rth21,sp
Stimulated emission rate: dN2dt
st
= N2Wi
at threshold: dNth2
dt
st
= dNthph
dt
Nthphph
=Nth2 Wth
i =Nth2 CN
thph
Nth2 = 1Cph
, where
C =Bh21/and B is the Einstein coefficient.
Jth = Ith/LW = ed Rth =ed/ Cph21,sp
gain clamping: N2 = Nth2 R21,sp
1+CNph21,sp= Rth21,sp
Nph = 1
C21,sp( R
Rth 1) =
Jthphed
( JJth 1) =
phed
(J Jth)
Half of the cavity photons move towards out-couple mirror, a fraction (1 Rm) Tmescapes during the transversal time in this direction
Pout= (0.5Nph )(Cavity Volume) (Photon energy)
time for photon to transverse cavity length (1 Rmirror) = hc20ph W(1Rmirror)
2enref (J Jth)TFH SS 2012 119
Sketch of BHJ laser diode layer structure
Optimal out-coupling I
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p p g
Tm = 1 Rm transmission coefficient
Pout NphTm Tm( RRth 1)= Tm(R Cph21,sp1)
Photon lifetime Ph includes out-coupling losses, i.e Ph =Ph(Tm)
each photon escapes with probability T within round-trip time 2nL/c0.
dNph
dt =
dNphdt
loss
+ dNph
dt
gain
=
dNph
dt
loss,out
+ dNph
dt
loss,else
+
dNphdt
gain
= [
1/ph (Tm )
( T
mc0
2nL + 1
loss) +N2C]Nph
maximize Poutwith respect to Tm:
dPout
dTm
d
dTm[Tm(R C21,sp
2nLlossTmc0loss+ 2nL
1)] 0
Toptm = 2Lnc0loss
+ 2Lnc0 C R21,sp N0N02
2Lnc0loss
Floss,int+g0Floss,int
Floss,int internal loss fraction (probability) per round trip.
g0 open-loop photon multiplication fractor per round trip.
TFH SS 2012 120
Optimal out-coupling II
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p p g
From A. Yariv, Quantum Electronics, 3rd edition, John Wiley & Sons, (1989)
TFH SS 2012 121
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Distributed
Bragg
Reflection
for
Single
Mode
Lasers
Ensure
single
mode
radiation
in
the
laser
cavity
is
to
use
frequency
selective
mirrors
at
the
cleavedsurfaces
Distributed
Bragg
reflector
is
a
mirror
that
has
been
designed
a
reflective
Bragg
grating
Reflectedwaveoccursonlywhenthewavelengthcorrespondstotwicethecorrugation
periodicity,
.
The
diffraction
order
of
the
reflector
is
integer,
q
=
0,1,2,
N=refractiveindexofthemirror
Bragg
wavelength
of
the
mirror
output
is
B
Corrugated
dielectric structure
Distributed Bragg
reflector
(a) (b)
A
B
q(B/2n) =
Active layer
(a) Distributed Bragg reflection (DBR) laser principle. (b) Partially reflected wavesat the corrugations can only constitute a reflected wave when the wavelengthsatisfies the Bragg condition. Reflected wavesAandBinterfere constructive whenq(B/2n) =.
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
= 2
n
q B
TFH SS 2012 122
n
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DistributedFeedbackLaser(DFB)
InaDFBlaser,thecorrugatinggratingiscalledtheguidinglayerandrestontopofthe
activelayer.
ThepitchofthecorrugationprovidesopticalgainattheBraggwavelength,B.
Travelingwavesareexcitedbytheactivelayerandcoupletotheguidinglayerasthey
reflectbackandforthacrossthegratingtogenerateallowedDFBmodesthatarenot
exactlymatchedtotheBraggwavelength,butareplacedsymmetricallyjustofftheideal
modeoftheguidinglayeratm.
Active layer
Corrugated grating
Guiding layer
(a)
(a) Distributed feedback (DFB) laser structure. (b) Ideal lasing emission output. (c)Typical output spectrum from a DFB laser.
Optical power
(nm)
0.1 nm
Ideal lasing emission
B(b) (c)
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
( )12
2
+= mnL
BBm
TFH SS 2012 123
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CleavedCoupledCavityLaser
Device
has
two
different
optical
cavities
of
length
L
and
D.
Each
laser
cavity
is
pumped
by
a
different
current
Onlymodesresonantinbothcavitiesareallowedtoresonatethroughtheentiredevice,
allowingtheengineertotuneoutcertainmodesfromoneorbothindependentlaser
diodes
Whypumpboththecavities? Ans. Allowedmodesinanunpumped cavitywillundergo
recombinationifthedeviceisnotdriven.
Active
layer
L D
(a)
Cleaved-coupled-cavity (C3) laser
Cavity Modes
InL
InD
In bothLandD
(b)
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
TFH SS 2012 124
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QuantumWell(QW)Devices
Devicewithanultrathin(50nm)narrowbandgap activeregionbetweentwowiderbandgap
semiconductors AssumethatinQWdevicesthatthelatticematchsothatallthesemiconductors havethesame
latticeconstantasothatcrystallinedefectsareminimized
Badgap changesattheinterfacearethereforeonlyduetodiscontinuitiesbetweenEcandEvofthedifferingmaterialsyieldingdiscreteallowablequantumstatesthatcanbesolvedasparticleinaboxtypeproblems.
A quantum well (QW) device. (a) Schematic illustration of a quantum well (QW) structure in which athin layer of GaAs is sandwiched between two wider bandgap semiconductors (AlGaAs). (b) Theconduction electrons in the GaAs layer are confined (by Ec) in thex-direction to a small length dso
that their energy is quantized. (c) The density of states of a two-dimensional QW. The density of statesis constant at each quantized energy level.
AlGaAs AlGaAs
GaAs
y
z
x
d
Ec
Ev
d
E1
E2
E3
g(EDensity of states
E
BulkQW
n= 1
Eg2Eg1
E n= 2Ec
BulkQW
Ev
(a) (b) (c)
Dy
Dz
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
[ ]
,...3,2,1,,
888
0)(2
2*
22
2*
22
2*
22
2
2
=
+++=
=+
zy
zeyee
c
e
nnn
Dm
nh
Dm
nh
dm
nhEE
xVEm
x
zy
h
Note:potentialenergybarrierofthe
conductionbandisdefinedbyw.r.t.Ec
Energy
in
a
quantum
well
TFH SS 2012 125
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EnergySpectruminaQuantumWell(SQW)
Ec
Ev
E1
E1
h=E1E
1
E
In single quantum well (SQW) lasers electrons areinjected by the forward current into the thin GaAslayer which serves as the active layer. Populationinversion betweenE1andE1 is reached even with
small forward current which results in stimulatedemissions.
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
TFH SS 2012 126
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Example:AGaAs QW
GaAs QW
Effective
electron
mass
is
me*=0.07me
WhatarethefirsttwoelectronenergylevelsforaQW
ofthickness10nm?
WhatistheholeenergybelowEviftheeffective
electronmassofthehole,mh*=.5me?
Whatistheemissionwavelengthw.r.t.bulkGaAs
whichasanenergybandgap of1.42eV?
Differenceinemissionwavelengthbetweenabulk
GaAs LDandaQWLDis35nm
Figure 16.1 Thelayeredstructureandthebandedges ofa
GaAlAs/GaAs/GaAlAs quantum
well.
Cc
2007
Photonics,
6th
edition
Yariv and
Yeh (Oxford
University
Press
( ) nm
eVnmeV
Ehc
nmeV
nmeV
E
hc
eVdm
nh
eVdm
nh
nng
QW
g
g
h
n
e
n
8390075.00527.042.1
1240
87442.1
1240
0075.08
0537.08
'
2*
22
'
2*
22
=
++
=
++
=
=
==
==
==
TFH SS 2012 127
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TFH SS 2012 128
Gain spectrum in QW lasers
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Gain in a QW laser:
a) The Fermi inversionfc(n, ) fv(n, ) at two carrier
densities n2 >n1 for QW thicknessLz= 200A.
b) The gain vs. at n1 and n2.
c) The same as in a) for narrower QW(Lz= 100 A).
d) The same as in b) for narrower QW(Lz= 100 A).
e) The same as in a) for a bulksemiconductor.
f) The same as in b) for a bulksemiconductor.
The energy Ef in a) and c) corresponds tothe photon energy for which fc fv = 0which is the transparency condition
TFH SS 2012 129
Diff t Q t W ll T
DOS f 0 1 2 di i l
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Different
Quantum
Wells
Types
BasedonGeometry
ImagefromChapter16,ofFundamentalsofPhotonics,2nd ed.BySaleh andTeich cc2007 WileyInterscience
TFH SS 2012 130
DOS for 0,1,2 dimensional quantum
confined structures
Low dimensional structures & threshold current reduction
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from Z. Alferov, Nobel lecture Dec. 2000
TFH SS 2012 131
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VerticalCavitySurfaceEmittingLasers(VCSELs)
Alternatinglayersoflowandhighindexaboveandbelow
theQWregion createsadistributedBraggreflectorof
dielectricmirrors
Themirrorsareneededtomatchtheopticalgainlostby
theshortcavitylength. Thuswiththemirrorsthelight
passesthroughthecavitysome2030timestoobtaina
desiredreflectanceof99%
Thehighreflectanceincreasesthegeometriccomponent
ofthegainrequiredforlaseremission
A simplified schematic illustration of a vertical cavitysurface emitting laser (VCSEL).
Contact
Surface emission
Dielectric mirror
Contact
Substrate
/4n1
Active layer
/4n2 Dielectric mirror
1999 S.O. Kasap, Optoelectronics (Prentice Hall)
Figure 16.14 Thefielddistributionofthelasermodeinsideavertical
cavitylaserwithL=/nwiththreequantumwells.Notethe
evanescentdecayofthefieldenvelopeinsidetheBraggmirrorsand
theconstantamplitudestandingwavebetweenthemirrors.
Cc 2007Photonics,6thedition Yariv andYeh (OxfordUniversityPress
22211
=+ dndn
Constructiveinterferenceofpartiallyreflectedwaves
Ofwavelength,,attheinterface
TFH SS 2012 132
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VCSELAttributes
VCSELactive
layers
are
generally
very
thin
0.1umandcomprisedofMQWforimprovedthresholdcurrent
Thedeviceiscomprisedofepitaxially depositedlayeronasuitablesubstratewhichistransparentintheemissionwavelength
Ex.980nmVCSELdevices
InGaAs istheactivelayer
GaAs isthesubstrate
AlGaAs withdifferentcompositionscomprisethedielectricmirrorstack
ThetopstackisthenetchedafterallthelayershavebeendepositedtocreatetheinvertedTshape
presentedin
the
previous
slide
Inpractice,currentflowingthroughthedielectricmirrorsgivesrisetoanundesiredvoltagedropthatmakesthedeviceVERYsensitivetofailurefromelectrostaticdischarge. Infact,thisisthemostcommonfailuremodeduringVCSELoperationandinstallation.
Theverticalcavity andthustheemittedbeamisgenerallycircularincrosssection
Theheightoftheverticalcavityisseveralmicrons. Thusthelongitudinalmodeseparationissufficientlylargetoallowonlyonemodeofoperation. Howeverlateralmodesmaybepresentincertaincavitygeometries
InpracticeVCSELShaveseverallateralmodesbutthespectralwidthisonlynmwhichissubstantiallylessthanthelongitudinalmodesofaDFBorELD.
Also,
VCSELS
have
an
average
beam
divergence
of
about
812o depending
on
their
fabrication
and
materialsused
DualwavelengthVCSELemissionisobtainedbyoperatingathighcurrents.
TFH SS 2012 133
Late News: Ge electrically pumped laser
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T.-H.Cheng et al., Appl. Phys.
Lett. 96, 211108 (2010).
An electrically pumped germanium laser
Rodolfo E. Camacho-Aguilera,1Yan Cai,
1Neil Patel,
1Jonathan T. Bessette,
1
Marco Romagnoli,1,2
Lionel C. Kimerling,1and Jurgen Michel
1,*
1Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139, USA
2PhotonIC Corporation, 5800 Uplander Way, Los Angeles, CA 90230, USA*[email protected]
Abstract: Electrically pumped lasing from Germanium-on-Silicon pnn
heterojunction diode structures is demonstrated. Room temperature
multimode laser with 1mW output power is measured. Phosphorous doping
in Germanium at a concentration over 4x1019
cm3
is achieved. AGermanium gain spectrum of nearly 200nm is observed.
2012 Optical Society of America
OCIS codes: (140.2020) Diode lasers; (140.3380) Laser materials; (140.5960) Semiconductor
lasers; (160.3130) Integrated optics materials.
References and links
1. D. J. Lockwood and L. Pavesi, Silicon Photonics(Springer-Verlag, 2004).
2. M. E. Groenert, C. W. Leitz, A. J. Pitera, V. Yang, H. Lee, R. Ram, and E. A. Fitzgerald, Monolithic integration
of room-temperature cw GaAs/AlGaAs lasers on Si substrates via relaxed graded GeSi buffer layers, J. Appl.
Phys. 93(1), 362367 (2003).3. H. Park, A. Fang, S. Kodama, and J. Bowers, Hybrid silicon evanescent laser fabricated with a silicon
waveguide and III-V offset quantum wells, Opt. Express 13(23), 94609464 (2005).
4. J. Liu, X. Sun, D. Pan, X. Wang, L. C. Kimerling, T. L. Koch, and J. Michel, Tensile-strained, n-type Ge as a
gain medium for monolithic laser integration on Si, Opt. Express 15(18), 1127211277 (2007).
5. J. Liu, X. Sun, Y. Bai, K. E. Lee, E. A. Fitzgerald, L. C. Kimerling, and J. Michel, Efficient above-band-gap
light emission in germanium, Chin. Opt. Lett. 7(4), 271273 (2009).
6. J. Liu, X. Sun, R. Camacho-Aguilera, L. C. Kimerling, and J. Michel, Ge-on-Si laser operating at room
temperature, Opt. Lett. 35(5), 679681 (2010).
7. G. Shambat, S.-L. Cheng, J. Lu, Y. Nishi, and J. Vuckovic, Direct band Ge photoluminescence near 1.6 m
coupled to Ge-on-Si microdisk resonators, Appl. Phys. Lett. 97(24), 241102 (2010).
8. S.-L. Cheng, J. Lu, G. Shambat, H.-Y. Yu, K. Saraswat, J. Vuckovic, and Y. Nishi, Room temperature 1.6m
electroluminescence from Ge light emitting diode on Si substrate, Opt. Express 17(12), 1001910024 (2009).
9. M. O. E. Kasper, T Aguirov, J. Werner, M. Kittler, J. Schulze, Room temperature direct band gap emission
from Ge p-i-n heterojunction photodiodes, in Proceedings of Group IV Photonics 2010 (2010).
10. X. Sun, J. Liu, L. C. Kimerling, and J. Michel, Room-temperature direct bandgap electroluminesence from Ge-
on-Si light-emitting diodes, Opt. Lett. 34(8), 11981200 (2009).
11. J. Liu, X. Sun, L. C. Kimerling, and J. Michel, Direct-gap optical gain of Ge on Si at room temperature, Opt.
Lett. 34(11), 17381740 (2009).
12. R. E. Camacho-Aguilera, Y. Cai, J. T. Bessette, D. Kita, L. C. Kimerling, and J. Michel, High active carrier
concentration in n-type, thin film Ge using delta-doping, submitted for publication (2012).13. G. Scappucci, G. Capellini, W. M. Klesse, and M. Y. Simmons, Phosphorus atomic layer doping of germanium
by the stacking of multiple layers, Nanotechnology22(37), 375203 (2011).
14. R. E. Camacho-Aguilera, Y. Cai, J. T. Bessette, L. C. Kimerling, and J. Michel, Electroluminescence of highly
doped Ge pnn diodes for Si integrated lasers, Proc. 8th IEEE Intern. Conf. GFP, Vol. 190,
10.1109/GROUP1104.2011.6053759 (2011).
15. S. Xiaochen, L. Jifeng, L. C. Kimerling, and J. Michel, Toward a Germanium Laser for integrated silicon
photonics, IEEE J. Sel. Top. Quantum Electron. 16(1), 124131 (2010).
1. Introduction
It has been long acknowledged that a monolithically integrated laser for silicon (Si) based
photonic circuits would be an enabling technology that could accelerate the implementation of
silicon photonics significantly [1]. Early attempts to integrate III-V semiconductor lasers on a
silicon platform had only limited success [2, 3]. More recently, germanium (Ge) has been
suggested as a gain medium for lasing on Si [4]. Using a combination of tensile strain and n-
type doping, efficient direct bandgap emission of Ge can be achieved [5]. Optically pumped
#164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012
(C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11316TFH SS 2012 134
lasing in Ge was demonstrated using a Ge waveguide with polished facets [6]. Furthermore,
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as g Ge was de o st ated us g a Ge wavegu de w t po s ed acets [6]. u t e o e,
attempts in electrically injection have demonstrated pin and pnn Ge diodes emitting between
1590 and 1700nm [710]. Here we present an electrically pumped pnn Ge diode laser that can
be monolithically integrated into a CMOS process. These first laser devices produce more
than 1 mW of output power and exhibit a Ge gain spectrum of over 200nm.
2. Experiments and results
Initial estimates of gain in n-type Ge based on experimental results showed that an n-type
doping level of 1x1019cm3would yield a gain of about 50 cm 1[11]. Such a gain can lead to
lasing when pumped optically because optical losses are mainly limited to facet losses and
free carrier losses in Ge. For electrical pumping, additional losses due to the electrical
contacts, free carrier losses in doped poly Si and losses due to the interaction with the contactmetal, have to be overcome. Modeling of mode propagation in Ge waveguides with electrical
contacts shows that these additional losses are >100 cm1.To overcome by these losses, the Ge
gain must be increased by increasing the n-type doping to a level of 3-5x10 19 cm3 [2].
Recently, we achieved n-type doping levels of > 4x1019cm3 by using a delta-doping
technique during epitaxial growth of Ge [12]. By correlation of photoluminescence (PL)
intensity, n-type doping level, and measured material gain, we have determined that an n-type
doping level of 4x1019cm3corresponds to a material gain of >400cm1, enough to overcome
the losses in an electrically pumped laser device.
Ge waveguides of 1m width were fabricated by selective growth of n-type Ge-on-Si in
silicon oxide trenches using Ultra-High Vacuum Chemical Vapor Deposition (UHV-CVD)
[3]. A delta-doped Ge layer was grown on top of the n-type Ge to serve as a phosphorousdiffusion source [12, 13]. The delta-doping technique inserts monolayers of P in the Ge film
at low temperatures by alternating the phosphine and germane gas flow in the CVD reactor.
After thermal annealing to drive the phosphorous into the n-type Ge layer, the delta-doped Ge
layer was removed during planarization using chemical mechanical polishing (CMP), to reach
a uniform doping concentration in the gain medium. The remaining thickness of the Ge
waveguide after CMP varied between 100 and 300nm depending on wafer and location on thewafer. Due to severe dishing of the waveguides after CMP the supported optical modes in the
waveguides could not be determined exactly. Up to six cavity modes can be supported in the
largest waveguides. An 180nm thick amorphous-Si film was then deposited via a Plasma-
Enhanced CVD process and subsequently phosphorus-implanted to a doping level of
1020cm3. After a dopant activation anneal at 750C, a metal stack, consisting of Ti and Al
was deposited for top and bottom contacts. The oxide trench provides excellent current
confinement. In order to assure even carrier injection into the n-type Ge, the top contact metal
was deposited on top of the waveguide. After dicing, the waveguides were cleaved to expose
the Ge waveguide facets. A thin oxide layer was deposited on the facets to protect against
contamination and catastrophic optical mirror damage which was observed in devices that did
not have oxide protection.
#164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012
(C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11317
Fig. 1. Schematic of the measurement set-up.
The waveguide emission was measured using a Horiba Micro PL system equipped with acooled InGaAs detector with lock-in detection. The emission power measurement was
calibrated using light from a commercial 1550nm laser that was coupled into a single mode
optical fiber with the fiber end at the sample location. In the calibration we verified that the
detection was linear with input power. The electrical pumping was supplied by a pulse
generator with current pulse widths in the range of 20 s to 100 ms. The duty cycle was
varied between 2 and 50%, typically 4% to reduce electrical current heating effects. The laserwas contacted with metal probes and the current was measured using an inductive sensor
placed directly in the biasing circuit. The experimental set-up is shown in Fig. 1.
Fig. 2. Ge laser emission spectrum before (a) and after (b) threshold. The cavity length of thewaveguide is 333m and the waveguide height about 100nm. Current injection employed pulse
widths of 50s at 800Hz and 15C. The detector spectral resolution was 1.2nm.
Figure 2 shows the spectrum of an electrically pumped Ge laser below and above
threshold. The broad, direct band gap related electroluminescence spectrum, observed for
highly doped n-type Ge LEDs, has been reported earlier [14]. The spectra in Fig. 2 employed
short integration times to assure wide spectrum analyses. Measurement time for these large
laser devices is ultimately limited by metal contact breakdown due to the high current flow.Figure 2(a) shows no spectral features above the noise floor. When the injection current
density is increased above threshold, sharp laser lines appear, as shown in Fig. 2(b). The
observed linewidth of the individual lines is below 1.2nm, the spectral resolution of the
measurement set-up. All measurements were performed with the samples mounted on a
thermo-electric cooler at 15C. Local device temperatures, however, are likely higher due tothe high current injection but could not be reliably determined.
#164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012
(C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11318
TFH SS 2012 135
devices, the Ge waveguide height is directly related to the modal loss. Since Ge has the
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Fig. 3. L-I curve for a 270m long waveguide device. 40s electrical pulses were used at
1000Hz. Measurement temperature was 15C.
Figure 3 shows the L-I spectrum for a typical electrically pumped Ge waveguide laser.
The lasing threshold at about 280kA/cm2is clearly visible. This measurement was taken with
the set-up in Fig. 1 using a wide instrumental spectral resolution of 10nm, at a wavelength of
1650nm, monitoring a single laser line. The number of datapoints is limited by metal contact
breakdown at high current level. The optical emission power of about 1 mW corresponds to
Fig. 3. Occasionally we observed up to 7 mW. The spectrum in Fig. 2 shows two lines. Theestimate of the cavity free spectral range is 1nm, and the line spacing in Fig. 2, 3nm, is a
possible multiple of the FSR.
These lasers show a dependence of emission wavelength on threshold current density that
is consistent with the expected modal loss variation and that confirms the theoretical
conclusions that the gain spectrum of Ge for the given doping level and strain reaches over
more than 100nm spectral width [15]. For high doping levels of 4x1019
cm3
, and tensile strain
of ~0.2%, we observed lasing in the range from 1520nm to 1700nm. Figure 4 shows selectedlaser lines between 1576nm and 1656nm for different Fabry-Perot cavities of the same gain
material.
Fig. 4. Spectra of Ge lasers with different Ge waveguide heights. The measured laser line
wavelengths are (a) 1576nm, (b) 1622nm, and (c) 1656nm.
The CMP-induced variation in cavity height provides self-consistent evidence of the wide
gain spectrum and the gain clamping condition by lasing. Under lasing action optical gain
(and population inversion) is clamped at exactly the value of the resonant cavity losses. In our
#164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012
(C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11319
g g y
highest refractive index in our device structure, thinner Ge layers expel more of the resonant
mode into the highly-doped poly-Si cladding and into the lossy metal contacts. The
wavelength corresponding to the Ge gain peak (the threshold injection level) and the cavity
loss is the expected emission wavelength of the device. As the modal confinement decreases
with decreasing Ge layer thickness, modal loss and correspondingly threshold current
increases and the emission wavelength blue shifts. In Fig. 5, we show spectral threshold
conditions for two different modal cavity losses using a parabolic band model as described in
[8].
A Ge waveguide of 300nm thickness has a modal loss of about 90 cm1
due to losses in
the doped poly Si and the metal electrode (solid line). A Ge waveguide of 100nm thickness,
however, has a modal loss of about 1000cm 1due to the closer proximity of the mode to theelectrode (dashed line). To overcome the high losses of the thin Ge waveguide, a relatively
high carrier injection level is needed. Lasing is therefore expected at around 1520nm, close to
what we find in Fig. 2. For lower loss waveguides we expect lasing to occur at longer
wavelengths as shown in Fig. 4.
Fig. 5. Simulation of gain clamping condition for two different Ge waveguide thicknesses
(100nm: solid line; 300nm: dashed line). The axes plot the corresponding modal loss and gainspectrum for the two different injection levels that are needed to overcome the respectivemodal losses and to achieve lasing.
3. Conclusions
We have observed lasing from electrically pumped n-type Ge Fabry-Perot cavities. The
threshold current densities decrease with increased modal confinement. The emission
linewidth is less than the 1.2nm resolution of our measurement. Laser emission wavelengths
were observed between 1520nm and 1700nm with a variation consistent with the gain
clamping condition for each device. Measured output powers greater than 1 mW at room
temperature were measured. Improvements in the Ge growth, electrical contacts, and in modal
loss reduction will decrease the lasing threshold to values comparable with Fabry-Perot diode
lasers. The high power and observed gain spectrum of nearly 200nm indicate that the Ge lasercould be used for WDM applications. Since the laser can be monolithically integrated into any
CMOS process flow, novel device applications and systems can be developed.
Acknowledgments
This work was supported by the Fully Laser Integrated Photonics (FLIP) program under APIC
Corporation, supervised by Dr. Raj Dutt, and sponsored by the Naval Air Warfare Center -
Aircraft Division (NAWC-AD) under OTA N00421-03-9-002. R.E.C.-A. was supported by a
NSF Graduate Research Fellowship award number 1122374.
#164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012
(C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11320
TFH SS 2012 136
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