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    Chapter 4: Stimulated emission and LASERS

    Stimulated EmissionStimulated emission and photon amplificationStimulated emission rate and Einstein coefficients

    Light amplificationRate equations for amplifiers

    Laser Oscillation ConditionOptical threshold gainOutput characteristics

    Semiconductor laser diodePrinciplesGain spectrum under forward biasHomojunction laser diodeHeterojunction laser diodeLaser diode layout and lateral mode confinementLaser diode characteristicsSteady state semiconductor rate equationsOptimal out-couplingDistributed bragg reflection for single mode lasersGain spectrum in QW lasersLow dimensional structures & threshold current reductionVertical cavity surface emitting lasersLate News: Ge electrically pumped laser

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    Stimulated emission and photon amplification

    Photon absorption excites electronfrom E1 E2.

    Allowed process, if energy (insemiconductor: and momentum) isconserved (Ph =hPh =E2 E1).

    Two possibilities for de-excitation:i) Spontaneous emission:Eventually, also the electrons in an isolated atom will return to

    their ground state spontaneously, without external action (purely QM process), bothradiative (photon emission hPh =E2 E1) and non-radiative transitions [phononemission (lattice vibration) etc.] can occur.

    ii) Stimulated emission: The interaction of the atoms excited electron with an EMradiation in resonance with the de-excitation energy E2 E1 triggers the de-excitation.A photon coherent with the incoming EM field (in phase and with same propagationdirection relative to incoming photons) is emitted [inverse process to (stimulated)

    absorption]. Not considered until 1916 (Einstein), but required for an opticallypumped system to reach stationarity, since absorption rate depends on intensity, butspontaneous emission rate not.

    Stimulated emission is the base process for light amplification.

    Shown later: Light amplification requires more electrons in the excited state than inthe ground state(population inversion).

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    Stimulated emission rate and Einstein coefficients

    N [cm3] two level system in thermal equilibrium withradiation in black body (BB).

    N1 in groundstate @ E1, N2 in excited state @ E2,N=N1+ N2.

    Stimulated excitation (absorption) rate R12 proportional toN1, to the number of photons with h21=E2 E1 pervolume {i.e. to the energy density (h21), [] =Jsm

    3}:

    R12 =B12N1(h21), [B12] =m3J1s2

    De-excitation rate R21 =Rstim21 +R

    spont21

    analog to absorption: Rstim21 =B21N2(h21) R

    spont21 =A21N2, independent of number of photons, only

    prop. to N2.

    R21 =A21N2+ B21N2(h21)

    Above equations define Einstein coefficients B12, B21, A21as proportionality factors for the rates.

    Thermal equilibrium:a) R12 =R21.

    b) Boltzmann statistics: N2/N1 = e(E2E1)/kBT = eh21/kBT.

    c) Photon energy density in BB given by Plancks law: eq(h)= 8h3

    c3

    eh/kBT 1

    TFH SS 2012 94

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    Stimulated emission rate and Einstein coefficients

    Three equations for the three Einstein coefficients.

    Dividea)byN1 and solve for N1/N2:N2

    N1 =

    B12(h21)

    A21+ B21(h21) Using Boltzmann statisticsb)results in:

    e21/kBT =

    B12(h21)

    A21+ B21(h21) (h21) =

    A21/B21(B12/B21)e21/kBT 1

    Comparision with Plancks lawc): Equal for all T only, if

    B12 =B21 B and A21

    B21= 8h

    321

    c3 (= h Photon DOS)

    Interpretation: Stimulated emission and absorption are inverse processes and occur with equal

    probability per available initial state (2 for stim. emission, 1 for absorption) population inversion (N2 >N1) can never be achieved by intense optical pumping a

    two level sytem, at most transparancy (N1 = N2) is achieved. Spontaneous emission prop. and stimulated emission prop. are related, ratio

    increases with 3, harder to construct x-ray lasers.

    Rstim21R

    spon21

    = BA(h) = 1

    h(h)

    Photon DOS

    Ratio increases with:i) # photons available optical resonator

    ii) decreasing density of photon states optical resonatorTFH SS 2012 95

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    Light amplification

    Absorption law: dIdx

    = I I(x) =I0ex exponential decay of intensity I.

    For expressing via electron transition rates, we convert intensity I into photonflux , photon density nPh and : I = h=nPhch=c(h).

    dI

    dx =hd

    dx =ch

    dnphdx

    =hdnph

    dt =h(R12+ R21) = (N1 N2)hB(h).

    dI

    dx = (N1 N2)

    hBc

    I

    negative for population inversion (N2 >N1) exponentially growing intensity,i.e. gain.

    gain coefficient g= (N2 N1)nrefhB

    c0

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    Rate equations for amplifiers Which pump-rate is required to achieve

    gain (i.e. population inversion)?

    ideal pumping scheme involves 4 levels

    Spontaneous transition rates lumpedtogether and are expressed as inverselifetimes (i.e. Rspon21 =

    121,spon)

    example: spontaneous lifetime of level 2: 12 =121 +

    120 =

    121,sp+

    121,nr+ +

    120

    Rate equations [Wi = B(h12)]:

    dN3

    dt= R

    N3

    32

    dN2

    dt=

    N3

    32

    N2

    2 N2Wi+N1Wi

    dN1

    dt=

    N2

    21

    N1

    1+N2Wi N1Wi

    dN0

    dt= R+

    N1

    1+

    N2

    20

    32 3x N3 = R32 dN2dt

    = R N22 N2Wi+N1Wi

    stationary solution d

    dt= 0 :

    N N2 N1 = R2(1 1/21)

    1 + Wi[2+1(1 2/21)]

    N0

    1 + Wis

    N

    0

    : pop. inv. in the absence of amplifier radiation.s: saturation time.

    Non-linear gain , gain saturation.

    typically: nonr. 2 1 decay rate negligible (21 =21,sp) && 20 21,sp 1, thus: N0 R21,sp, s 21,sp.

    Attention: for strong pumping,Rnot independent of N because

    N0+ N1+ N2+ N3 =Na (atom density) and N3 N1 0 N0 Na N2 Na NTFH SS 2012 97

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    Laser oscillation conditionOptical threshold gain

    gain coefficient (stim. em.)

    g= (N2 N1)B21nrefh21

    c0 loss:

    abs : absorption: impurities in laser medium, non-inverted allowed transitions with similartransition energy, free carriers (semiconductors !!)

    sc : scattering out of resonator mode: defects and inhomogeneities.Ri : Out-coupling losses, power reflection coefficient of cavity mirrors R1,R2 1

    stationarity conditions: Pf!

    =PiPf =PiR1R2e

    2Lgthe2L(abs+sc)

    gth =

    abs+sc+ 12Lln( 1R1R2 ) threshold gain.Nth =gth

    c0

    B21nrefh0 threshold pop. inv.

    Increase R(i.e N0): g remains clamped at gthafter stationary is re-established N= Nth

    .

    102

    101

    100

    101

    102

    Wis =/s

    0.0

    0.2

    0.40.6

    0.8

    1.0

    N/N0

    =

    g/g0 laser turn-on

    loss=gth

    steady state

    time

    ph. fluxdensity

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    Laser oscillation conditionOutput characteristics

    Gain clamping: N= Nth

    Nth = N0

    1 +Wis

    Wi = 1

    s

    N0

    Nth 1

    Wi(h12)

    =s N

    0

    Nth 1, N0 >Nth

    0, N0 Nth

    steady-state laser-internalphoton-flux density

    Spontaneous emission neglected. In addition: stationarity of phase

    Fabry-Perot resonator modes.

    Simplified description of a laser oscillator.

    (N2 N1) and coherent output power P0

    vs. pump rate Runder continuous wave

    steady state operation.

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    PrinciplesoftheLaserDiode

    pn junctioninaDegenerate

    Semiconductor

    FermilevelinthepregionisbelowEv

    FemilevelinthenregionisaboveEc

    Withnoappliedvoltage, Efn=Efp yields

    averynarrowdepletionregion

    Thereisapotentialenergybarrier,eVothatpreventsnsideelectronsfrom

    diffusingto

    the

    pside

    and

    vice

    versa

    Whenvoltageisapplied

    ChangeintheFermilevelisthework

    donebytheappliedvoltage,eV

    Ifthejunctionisforwardbiased

    suchthatEfnEfp =eV >Eg

    Appliedbiasdiminishesthebuildin

    potentialbarrier

    Depletionregionisnolongerdepleted

    Therearenowmoreelectronsinthe

    conductionbandthaninthevalance

    bandnearEv Populationinversion

    p+ n+

    EFn

    (a)

    Eg

    Ev

    Ec

    Ev

    Holes in VB

    Electrons in CB

    Junction

    Electrons

    Ec

    p+

    Eg

    V

    n+

    (b )

    EFn

    eV

    EFp

    The energy band diagram of a degenerately dopedp-n with no bias. (b) Banddiagram with a sufficiently large forward bias to cause population inversion andhence stimulated emission.

    Inversionregion

    EFp

    Ec

    Ec

    eVo

    1999 S.O. Kasap,Optoelectronics(Prentice Hall)

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    PrinciplesoftheLaserDiode

    Populationinversionregionisa

    layeralongthejunctioncalledtheinversionlayer(activeregion)

    Anincomingphotonwithenergy

    EcEvcannotexciteanelectronin

    EvtoEcastherearehardlyany

    presentinthevalanceband

    withinthe

    active

    region

    Hencethereismorestimulated

    emissionthanabsorption

    Theopticalgainpresentinthe

    activeregionduetolackof

    probabilityofvalanceelectron

    absorption

    h

    Eg

    Optical gainE

    FnE

    Fp

    Optical absorption

    0

    Energy

    Ec

    Ev

    CB

    VB

    (a) The density of states and energy distribution of electrons and holes inthe conduction and valence bands respectively at T 0 in the SCLunder forward bias such thatEFnEFp>Eg. Holes in the VB are empty

    states. (b) Gain vs. photon energy.

    Density of states

    Electrons

    in CB

    Holes in VB

    = Empty states

    EFn

    EFp

    eV

    At T> 0

    At T= 0

    (a) (b )

    1999 S.O. Kasap,Optoelectronics(Prentice Hall)

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    Gain spectrum under forward bias

    TFH SS 2012 102

    Evolution of the absorption andgain curves as a function if the

    position of the quasi-Fermi level.The gray (dark) curvescorrespond t oa small (large)displacement from equilibrium.In this case, the medium absorbsall photons having energies inexcess of the bandgap. Once theenergy separation between thetwo quasi-Fermi levels exceedsthe bandgap, all photons withenergies between Eg andE

    F,cE

    F,v are amplified.

    From E. Rosencher, B. Vinter,

    Optoelectronics, Cambridge University

    Press (2002)

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    Gain spectrum under forward bias

    From A. Yariv, Quantum Electronics, 3rd edition, John Wiley & Sons, (1989)

    TFH SS 2012 103

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    ElectroopticalPerformanceofIII/VDiodes

    injectionpumping: Opticalpumpingisachievedbyforward

    diodecurrent

    and

    the

    pumping

    energy

    is

    an

    external

    battery

    Forlaserwealsoneedanopticalresonatorcavity. Thisis

    achievedthroughtheuseofaslabwaveguidewithahigh

    indexcontrastattheemissionend

    Wavelengthoftheradiationthatcanbuildupinthecavity

    dependsonthelength(L)inhalf multiples

    LElectrode

    Current

    GaAs

    GaAsn+

    p+

    Cleaved surface mirror

    Electrode

    Active region(stimulated emission region)

    A schematic illustration of a GaAs homojunction laserdiode. The cleaved surfaces act as reflecting mirrors.

    L

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    ypical output optical power vs. diode current ( I) characteristics and the correspondingutput spectrum of a laser diode.

    Laser

    LaserOptical Power

    Optical Power

    I0

    LEDOptical Power

    Ith

    Spontaneous

    emission

    Stimulated

    emission

    Optical Power

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    2criticalcurrentidentifiers

    Transparency current: Currentabove

    whichno

    net

    photon

    absorption

    occurs

    Threshold current:currentabove

    whichopticalgainovercomesall

    photonlossesinthecavity

    Lnm =

    2

    TFH SS 2012 104

    R = (nGaAs1

    nGaAs+1)2 35%

    typically: Jth = 500 Amm2 for

    homojunction LD !!

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    Heterojunction LaserDiodes

    Mainissuewithhomojunction diodesis

    that

    the

    laser

    threshold

    current

    density

    istoohighforpracticaluses.

    Ex.Jth =500A/mm2 forGaAs at300K

    Heterostructured diodesreducethesecurrentdensitiesbyordersofmagnitude

    Thisisachievedthroughacombinationofcarrierconfinement(mismatchedmaterials),andphotonconfinement(geometric

    shape

    of

    the

    waveguide)

    Doubleheterojunction (DH)deviceswithnpp layersallowfordesignedconfinementoftheactiveregion

    LowerrefractiveindexoftheAlGaAsenhancesthemodeconfinementincomparisontoahomoorsimple

    heterojunction device Significantlyreducesthresholdcurrent

    density

    Refractiveindex

    Photondensity

    Active

    region

    n~ 5%

    2 eV

    Holes in VB

    Electrons in CB

    AlGaAsAlGaAs

    1.4 eV

    Ec

    Ev

    Ec

    Ev

    (a)

    (b)

    pn p

    Ec

    (a) A doubleheterostructure diode hastwo junctions which arebetween two dif ferentbandgap semiconductors(GaAs and AlGaAs).

    2 eV

    (b) Simplified energyband diagram under alarge forward bias.Lasing recombinationtakes place in the p-GaAs layer, theactive layer

    (~0.1 m)

    (c) Higher bandgapmaterials have alower refractiveindex

    (d) AlGaAs layersprovide later al opticalconfinement.

    (c )

    (d)

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    GaAs

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    Photonics,6thedition Yariv andYeh

    igure 15.10 A typical double heterostructure GaAs/GaAlAs laser. Electrons and holes are injected into the active GaAs layer from the

    and p GaAlAs. Photons with frequencies near =Eg/h are amplified by stimulating electronhole recombination.

    Cc 2007Photonics,6thedition Yariv andYeh (OxfordUniversityPress

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    Photonics,6thedition Yariv

    andYeh 11

    Figure 15.12 The magnitude of the energy gap in Ga1x

    AlxAs as a function of the molar fraction x. For x > 0.37 the bandgap is indirect.

    (After Reference [11].)

    Cc 2007Photonics,6thedition Yariv andYeh (OxfordUniversityPress

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    Heterojunctions Laser Heterojunction diode: different materials for n & p

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    Heterojunction diode: different materials for n & p

    Different materials: significantly different index n

    Also different lattice constants

    Important point: want the lattice matched at layer boundary

    Use mixed alloy: eg GaAs and AlAsAlxGa1-1As

    x = mole fraction of Aluminum

    1-x = mole fraction of Gallium

    Heterojunctions Laser Single Heterojunctions: one sided confinement

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    Single Heterojunctions: one sided confinement

    p-GaAlAs: p-GaAs: n-GaAs

    Better confinement means lower threshold current for lasing

    Thus operates in pulsed mode at room temperature

    Double Heterojunction lasers: confines both top & bottom

    p-GaAlAs: GaAs: n-GaAlAs: n-GaAs

    Double Heterojunctions Laser Has both Band and Index steps on both top & bottom

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    Has both Band and Index steps on both top & bottom

    Doubly confines light: creates a waveguide as cavity

    Requires much less threshold current

    Thus CW operation now possible at room temperature

    Comparison of Homo/Hetero/D-Heterojunctions Lasers As add index steps get smaller light spreading

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    As add index steps get smaller light spreading

    Single hetrojunction threshold current ~5x < homojunction

    Double hetrojunction threshold ~50-100x

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    j

    Surrounded both vertical & horizontal by lower material

    1-2 microns wide: high efficiency, low threshold

    Channeled Substrate

    Etch channel in substrate: isolate active area

    Low loss

    Buried Crescent

    Fill grove to get crescent shaped active strip

    Heterojunctions with WaveguidesRidge Waveguide

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    Etch away a mesa around active region

    confines current flow to 2-3 micron strip

    Double-channel planar buried heterostructure

    Isolate active with mesa, then fill with lower index

    used with very high power InGaAsP lasers

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    EdgeEmittingLasers

    VerysimilartoELEDdevicespresentedinchapter3

    AdditionalcontactinglayerofpGaAs nexttothep=AlGaAs providesbettercontactingandavoidsSchottky junctionwhichwouldlimitthecurrentinthedevice.

    pandnAlGaAs layersprovidecarrierandopticalconfinementintheverticaldirection

    LaseremissionintheactivepGaAs(oradifferentAlGaAs constitution)regionisbetween870900

    nm

    depending

    on

    doping.

    Schematic illustration of the the structure of a double heterojunction stripecontact laser diode

    Oxide insulator

    Stripe electrode

    SubstrateElectrode

    Active region where J> Jt h.

    (Emission region)

    p -GaAs (Contacting layer)

    n -GaAs (Substrate)

    p -GaAs (Active layer)

    Current

    paths

    L

    W

    Cleaved reflecting surfaceEllipticallaser

    beam

    p -AlxGa

    1- xAs (Confining layer)

    n -AlxGa

    1- xAs (Confining layer)

    12 3

    Cleaved reflecting surface

    Substrate

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    AlGaAs andGaAs havenegligiblelattice

    mismatchyieldingveryfewdefectsin

    thecrystalthatwouldleadtoexcessive

    thresholdcurrents

    Also,thestripe electrodeacrossthetop

    confinestheelectricfieldandthusthe

    opticallyactive

    region

    providing

    additionalgeometricalconfinement

    Suchlasers arecalledgainguided,b/c

    thecurrentdensitygeneratedisguided

    bytheelectricfieldbetweenthestripe

    electrodeandthebottomelectrode

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    BuriedHeterostructure LDs

    Figure

    from

    Chapter

    15

    Photonics,

    6th

    edition

    Yariv and

    Yeh 2007

    Oxford

    University

    Press

    Althoughthestripeelectrodegeometryprovides

    some

    geometric

    confinement,

    it

    is

    more

    advantageoustorestrictlateralgeometryphysically

    throughtheuseofconfininglayersalongtheside

    ofthediode

    Creationofaopticalwaveguideinbothverticaland

    horizontaldirectionsaidsinreducingopticalcavity

    modes

    and

    promotes

    confinement Significantlyreducescurrentdensityrequiredfor

    stimulatedemission

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    ElementaryLaserDiode(LD)Characteristics

    Longitudinalmode:lengthdetermined

    Lateral

    mode:

    width

    determined

    Emissioniseithermultimodeorsingle

    modedependingontheopticalresonating

    structureandthepumpingcurrentlevel

    Height,HWidth W

    Length,L

    The laser cavity definitions and the output laser beamcharacteristics.

    Fabry-Perot cavity

    Dielectric mirror

    Diffraction

    limited laser

    beam

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    778 780 782

    Po= 1 mW

    Po= 5 mW

    Relative optical power

    (nm)

    Po= 3 mW

    Output spectra of lasing emission from an index guided LD.At sufficiently high diode currents corresponding to highoptical power, the operation becomes single mode. (Note:Relative power scale applies to each spectrum individually annot between spectra)

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

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    TFH SS 2012 118

    Steady state semiconductor rate equations

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    S y q

    Current (I) pump rate: R= IedLW

    Photon loss rate: dNph

    dt =

    Nphph

    , where ph is

    average time for a photon to be lost from

    lasing cavity mode due to transmission at end facets,scattering and absorption in the semiconductor

    Use rate equ. results (p. 97 f): assume a) 2 =21 =21,sp; b) 1 0 N1 0

    N= N01+Wis

    N2 R21,sp1+Wi21,sp

    ; in particular Nth Nth2 =Rth21,sp

    Stimulated emission rate: dN2dt

    st

    = N2Wi

    at threshold: dNth2

    dt

    st

    = dNthph

    dt

    Nthphph

    =Nth2 Wth

    i =Nth2 CN

    thph

    Nth2 = 1Cph

    , where

    C =Bh21/and B is the Einstein coefficient.

    Jth = Ith/LW = ed Rth =ed/ Cph21,sp

    gain clamping: N2 = Nth2 R21,sp

    1+CNph21,sp= Rth21,sp

    Nph = 1

    C21,sp( R

    Rth 1) =

    Jthphed

    ( JJth 1) =

    phed

    (J Jth)

    Half of the cavity photons move towards out-couple mirror, a fraction (1 Rm) Tmescapes during the transversal time in this direction

    Pout= (0.5Nph )(Cavity Volume) (Photon energy)

    time for photon to transverse cavity length (1 Rmirror) = hc20ph W(1Rmirror)

    2enref (J Jth)TFH SS 2012 119

    Sketch of BHJ laser diode layer structure

    Optimal out-coupling I

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    p p g

    Tm = 1 Rm transmission coefficient

    Pout NphTm Tm( RRth 1)= Tm(R Cph21,sp1)

    Photon lifetime Ph includes out-coupling losses, i.e Ph =Ph(Tm)

    each photon escapes with probability T within round-trip time 2nL/c0.

    dNph

    dt =

    dNphdt

    loss

    + dNph

    dt

    gain

    =

    dNph

    dt

    loss,out

    + dNph

    dt

    loss,else

    +

    dNphdt

    gain

    = [

    1/ph (Tm )

    ( T

    mc0

    2nL + 1

    loss) +N2C]Nph

    maximize Poutwith respect to Tm:

    dPout

    dTm

    d

    dTm[Tm(R C21,sp

    2nLlossTmc0loss+ 2nL

    1)] 0

    Toptm = 2Lnc0loss

    + 2Lnc0 C R21,sp N0N02

    2Lnc0loss

    Floss,int+g0Floss,int

    Floss,int internal loss fraction (probability) per round trip.

    g0 open-loop photon multiplication fractor per round trip.

    TFH SS 2012 120

    Optimal out-coupling II

    http://find/
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    p p g

    From A. Yariv, Quantum Electronics, 3rd edition, John Wiley & Sons, (1989)

    TFH SS 2012 121

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    Distributed

    Bragg

    Reflection

    for

    Single

    Mode

    Lasers

    Ensure

    single

    mode

    radiation

    in

    the

    laser

    cavity

    is

    to

    use

    frequency

    selective

    mirrors

    at

    the

    cleavedsurfaces

    Distributed

    Bragg

    reflector

    is

    a

    mirror

    that

    has

    been

    designed

    a

    reflective

    Bragg

    grating

    Reflectedwaveoccursonlywhenthewavelengthcorrespondstotwicethecorrugation

    periodicity,

    .

    The

    diffraction

    order

    of

    the

    reflector

    is

    integer,

    q

    =

    0,1,2,

    N=refractiveindexofthemirror

    Bragg

    wavelength

    of

    the

    mirror

    output

    is

    B

    Corrugated

    dielectric structure

    Distributed Bragg

    reflector

    (a) (b)

    A

    B

    q(B/2n) =

    Active layer

    (a) Distributed Bragg reflection (DBR) laser principle. (b) Partially reflected wavesat the corrugations can only constitute a reflected wave when the wavelengthsatisfies the Bragg condition. Reflected wavesAandBinterfere constructive whenq(B/2n) =.

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    = 2

    n

    q B

    TFH SS 2012 122

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    DistributedFeedbackLaser(DFB)

    InaDFBlaser,thecorrugatinggratingiscalledtheguidinglayerandrestontopofthe

    activelayer.

    ThepitchofthecorrugationprovidesopticalgainattheBraggwavelength,B.

    Travelingwavesareexcitedbytheactivelayerandcoupletotheguidinglayerasthey

    reflectbackandforthacrossthegratingtogenerateallowedDFBmodesthatarenot

    exactlymatchedtotheBraggwavelength,butareplacedsymmetricallyjustofftheideal

    modeoftheguidinglayeratm.

    Active layer

    Corrugated grating

    Guiding layer

    (a)

    (a) Distributed feedback (DFB) laser structure. (b) Ideal lasing emission output. (c)Typical output spectrum from a DFB laser.

    Optical power

    (nm)

    0.1 nm

    Ideal lasing emission

    B(b) (c)

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    ( )12

    2

    += mnL

    BBm

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    CleavedCoupledCavityLaser

    Device

    has

    two

    different

    optical

    cavities

    of

    length

    L

    and

    D.

    Each

    laser

    cavity

    is

    pumped

    by

    a

    different

    current

    Onlymodesresonantinbothcavitiesareallowedtoresonatethroughtheentiredevice,

    allowingtheengineertotuneoutcertainmodesfromoneorbothindependentlaser

    diodes

    Whypumpboththecavities? Ans. Allowedmodesinanunpumped cavitywillundergo

    recombinationifthedeviceisnotdriven.

    Active

    layer

    L D

    (a)

    Cleaved-coupled-cavity (C3) laser

    Cavity Modes

    InL

    InD

    In bothLandD

    (b)

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

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    QuantumWell(QW)Devices

    Devicewithanultrathin(50nm)narrowbandgap activeregionbetweentwowiderbandgap

    semiconductors AssumethatinQWdevicesthatthelatticematchsothatallthesemiconductors havethesame

    latticeconstantasothatcrystallinedefectsareminimized

    Badgap changesattheinterfacearethereforeonlyduetodiscontinuitiesbetweenEcandEvofthedifferingmaterialsyieldingdiscreteallowablequantumstatesthatcanbesolvedasparticleinaboxtypeproblems.

    A quantum well (QW) device. (a) Schematic illustration of a quantum well (QW) structure in which athin layer of GaAs is sandwiched between two wider bandgap semiconductors (AlGaAs). (b) Theconduction electrons in the GaAs layer are confined (by Ec) in thex-direction to a small length dso

    that their energy is quantized. (c) The density of states of a two-dimensional QW. The density of statesis constant at each quantized energy level.

    AlGaAs AlGaAs

    GaAs

    y

    z

    x

    d

    Ec

    Ev

    d

    E1

    E2

    E3

    g(EDensity of states

    E

    BulkQW

    n= 1

    Eg2Eg1

    E n= 2Ec

    BulkQW

    Ev

    (a) (b) (c)

    Dy

    Dz

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    [ ]

    ,...3,2,1,,

    888

    0)(2

    2*

    22

    2*

    22

    2*

    22

    2

    2

    =

    +++=

    =+

    zy

    zeyee

    c

    e

    nnn

    Dm

    nh

    Dm

    nh

    dm

    nhEE

    xVEm

    x

    zy

    h

    Note:potentialenergybarrierofthe

    conductionbandisdefinedbyw.r.t.Ec

    Energy

    in

    a

    quantum

    well

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    EnergySpectruminaQuantumWell(SQW)

    Ec

    Ev

    E1

    E1

    h=E1E

    1

    E

    In single quantum well (SQW) lasers electrons areinjected by the forward current into the thin GaAslayer which serves as the active layer. Populationinversion betweenE1andE1 is reached even with

    small forward current which results in stimulatedemissions.

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    TFH SS 2012 126

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    Example:AGaAs QW

    GaAs QW

    Effective

    electron

    mass

    is

    me*=0.07me

    WhatarethefirsttwoelectronenergylevelsforaQW

    ofthickness10nm?

    WhatistheholeenergybelowEviftheeffective

    electronmassofthehole,mh*=.5me?

    Whatistheemissionwavelengthw.r.t.bulkGaAs

    whichasanenergybandgap of1.42eV?

    Differenceinemissionwavelengthbetweenabulk

    GaAs LDandaQWLDis35nm

    Figure 16.1 Thelayeredstructureandthebandedges ofa

    GaAlAs/GaAs/GaAlAs quantum

    well.

    Cc

    2007

    Photonics,

    6th

    edition

    Yariv and

    Yeh (Oxford

    University

    Press

    ( ) nm

    eVnmeV

    Ehc

    nmeV

    nmeV

    E

    hc

    eVdm

    nh

    eVdm

    nh

    nng

    QW

    g

    g

    h

    n

    e

    n

    8390075.00527.042.1

    1240

    87442.1

    1240

    0075.08

    0537.08

    '

    2*

    22

    '

    2*

    22

    =

    ++

    =

    ++

    =

    =

    ==

    ==

    ==

    TFH SS 2012 127

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    TFH SS 2012 128

    Gain spectrum in QW lasers

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    Gain in a QW laser:

    a) The Fermi inversionfc(n, ) fv(n, ) at two carrier

    densities n2 >n1 for QW thicknessLz= 200A.

    b) The gain vs. at n1 and n2.

    c) The same as in a) for narrower QW(Lz= 100 A).

    d) The same as in b) for narrower QW(Lz= 100 A).

    e) The same as in a) for a bulksemiconductor.

    f) The same as in b) for a bulksemiconductor.

    The energy Ef in a) and c) corresponds tothe photon energy for which fc fv = 0which is the transparency condition

    TFH SS 2012 129

    Diff t Q t W ll T

    DOS f 0 1 2 di i l

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    Different

    Quantum

    Wells

    Types

    BasedonGeometry

    ImagefromChapter16,ofFundamentalsofPhotonics,2nd ed.BySaleh andTeich cc2007 WileyInterscience

    TFH SS 2012 130

    DOS for 0,1,2 dimensional quantum

    confined structures

    Low dimensional structures & threshold current reduction

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    from Z. Alferov, Nobel lecture Dec. 2000

    TFH SS 2012 131

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    VerticalCavitySurfaceEmittingLasers(VCSELs)

    Alternatinglayersoflowandhighindexaboveandbelow

    theQWregion createsadistributedBraggreflectorof

    dielectricmirrors

    Themirrorsareneededtomatchtheopticalgainlostby

    theshortcavitylength. Thuswiththemirrorsthelight

    passesthroughthecavitysome2030timestoobtaina

    desiredreflectanceof99%

    Thehighreflectanceincreasesthegeometriccomponent

    ofthegainrequiredforlaseremission

    A simplified schematic illustration of a vertical cavitysurface emitting laser (VCSEL).

    Contact

    Surface emission

    Dielectric mirror

    Contact

    Substrate

    /4n1

    Active layer

    /4n2 Dielectric mirror

    1999 S.O. Kasap, Optoelectronics (Prentice Hall)

    Figure 16.14 Thefielddistributionofthelasermodeinsideavertical

    cavitylaserwithL=/nwiththreequantumwells.Notethe

    evanescentdecayofthefieldenvelopeinsidetheBraggmirrorsand

    theconstantamplitudestandingwavebetweenthemirrors.

    Cc 2007Photonics,6thedition Yariv andYeh (OxfordUniversityPress

    22211

    =+ dndn

    Constructiveinterferenceofpartiallyreflectedwaves

    Ofwavelength,,attheinterface

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    VCSELAttributes

    VCSELactive

    layers

    are

    generally

    very

    thin

    0.1umandcomprisedofMQWforimprovedthresholdcurrent

    Thedeviceiscomprisedofepitaxially depositedlayeronasuitablesubstratewhichistransparentintheemissionwavelength

    Ex.980nmVCSELdevices

    InGaAs istheactivelayer

    GaAs isthesubstrate

    AlGaAs withdifferentcompositionscomprisethedielectricmirrorstack

    ThetopstackisthenetchedafterallthelayershavebeendepositedtocreatetheinvertedTshape

    presentedin

    the

    previous

    slide

    Inpractice,currentflowingthroughthedielectricmirrorsgivesrisetoanundesiredvoltagedropthatmakesthedeviceVERYsensitivetofailurefromelectrostaticdischarge. Infact,thisisthemostcommonfailuremodeduringVCSELoperationandinstallation.

    Theverticalcavity andthustheemittedbeamisgenerallycircularincrosssection

    Theheightoftheverticalcavityisseveralmicrons. Thusthelongitudinalmodeseparationissufficientlylargetoallowonlyonemodeofoperation. Howeverlateralmodesmaybepresentincertaincavitygeometries

    InpracticeVCSELShaveseverallateralmodesbutthespectralwidthisonlynmwhichissubstantiallylessthanthelongitudinalmodesofaDFBorELD.

    Also,

    VCSELS

    have

    an

    average

    beam

    divergence

    of

    about

    812o depending

    on

    their

    fabrication

    and

    materialsused

    DualwavelengthVCSELemissionisobtainedbyoperatingathighcurrents.

    TFH SS 2012 133

    Late News: Ge electrically pumped laser

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    T.-H.Cheng et al., Appl. Phys.

    Lett. 96, 211108 (2010).

    An electrically pumped germanium laser

    Rodolfo E. Camacho-Aguilera,1Yan Cai,

    1Neil Patel,

    1Jonathan T. Bessette,

    1

    Marco Romagnoli,1,2

    Lionel C. Kimerling,1and Jurgen Michel

    1,*

    1Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139, USA

    2PhotonIC Corporation, 5800 Uplander Way, Los Angeles, CA 90230, USA*[email protected]

    Abstract: Electrically pumped lasing from Germanium-on-Silicon pnn

    heterojunction diode structures is demonstrated. Room temperature

    multimode laser with 1mW output power is measured. Phosphorous doping

    in Germanium at a concentration over 4x1019

    cm3

    is achieved. AGermanium gain spectrum of nearly 200nm is observed.

    2012 Optical Society of America

    OCIS codes: (140.2020) Diode lasers; (140.3380) Laser materials; (140.5960) Semiconductor

    lasers; (160.3130) Integrated optics materials.

    References and links

    1. D. J. Lockwood and L. Pavesi, Silicon Photonics(Springer-Verlag, 2004).

    2. M. E. Groenert, C. W. Leitz, A. J. Pitera, V. Yang, H. Lee, R. Ram, and E. A. Fitzgerald, Monolithic integration

    of room-temperature cw GaAs/AlGaAs lasers on Si substrates via relaxed graded GeSi buffer layers, J. Appl.

    Phys. 93(1), 362367 (2003).3. H. Park, A. Fang, S. Kodama, and J. Bowers, Hybrid silicon evanescent laser fabricated with a silicon

    waveguide and III-V offset quantum wells, Opt. Express 13(23), 94609464 (2005).

    4. J. Liu, X. Sun, D. Pan, X. Wang, L. C. Kimerling, T. L. Koch, and J. Michel, Tensile-strained, n-type Ge as a

    gain medium for monolithic laser integration on Si, Opt. Express 15(18), 1127211277 (2007).

    5. J. Liu, X. Sun, Y. Bai, K. E. Lee, E. A. Fitzgerald, L. C. Kimerling, and J. Michel, Efficient above-band-gap

    light emission in germanium, Chin. Opt. Lett. 7(4), 271273 (2009).

    6. J. Liu, X. Sun, R. Camacho-Aguilera, L. C. Kimerling, and J. Michel, Ge-on-Si laser operating at room

    temperature, Opt. Lett. 35(5), 679681 (2010).

    7. G. Shambat, S.-L. Cheng, J. Lu, Y. Nishi, and J. Vuckovic, Direct band Ge photoluminescence near 1.6 m

    coupled to Ge-on-Si microdisk resonators, Appl. Phys. Lett. 97(24), 241102 (2010).

    8. S.-L. Cheng, J. Lu, G. Shambat, H.-Y. Yu, K. Saraswat, J. Vuckovic, and Y. Nishi, Room temperature 1.6m

    electroluminescence from Ge light emitting diode on Si substrate, Opt. Express 17(12), 1001910024 (2009).

    9. M. O. E. Kasper, T Aguirov, J. Werner, M. Kittler, J. Schulze, Room temperature direct band gap emission

    from Ge p-i-n heterojunction photodiodes, in Proceedings of Group IV Photonics 2010 (2010).

    10. X. Sun, J. Liu, L. C. Kimerling, and J. Michel, Room-temperature direct bandgap electroluminesence from Ge-

    on-Si light-emitting diodes, Opt. Lett. 34(8), 11981200 (2009).

    11. J. Liu, X. Sun, L. C. Kimerling, and J. Michel, Direct-gap optical gain of Ge on Si at room temperature, Opt.

    Lett. 34(11), 17381740 (2009).

    12. R. E. Camacho-Aguilera, Y. Cai, J. T. Bessette, D. Kita, L. C. Kimerling, and J. Michel, High active carrier

    concentration in n-type, thin film Ge using delta-doping, submitted for publication (2012).13. G. Scappucci, G. Capellini, W. M. Klesse, and M. Y. Simmons, Phosphorus atomic layer doping of germanium

    by the stacking of multiple layers, Nanotechnology22(37), 375203 (2011).

    14. R. E. Camacho-Aguilera, Y. Cai, J. T. Bessette, L. C. Kimerling, and J. Michel, Electroluminescence of highly

    doped Ge pnn diodes for Si integrated lasers, Proc. 8th IEEE Intern. Conf. GFP, Vol. 190,

    10.1109/GROUP1104.2011.6053759 (2011).

    15. S. Xiaochen, L. Jifeng, L. C. Kimerling, and J. Michel, Toward a Germanium Laser for integrated silicon

    photonics, IEEE J. Sel. Top. Quantum Electron. 16(1), 124131 (2010).

    1. Introduction

    It has been long acknowledged that a monolithically integrated laser for silicon (Si) based

    photonic circuits would be an enabling technology that could accelerate the implementation of

    silicon photonics significantly [1]. Early attempts to integrate III-V semiconductor lasers on a

    silicon platform had only limited success [2, 3]. More recently, germanium (Ge) has been

    suggested as a gain medium for lasing on Si [4]. Using a combination of tensile strain and n-

    type doping, efficient direct bandgap emission of Ge can be achieved [5]. Optically pumped

    #164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012

    (C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11316TFH SS 2012 134

    lasing in Ge was demonstrated using a Ge waveguide with polished facets [6]. Furthermore,

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    as g Ge was de o st ated us g a Ge wavegu de w t po s ed acets [6]. u t e o e,

    attempts in electrically injection have demonstrated pin and pnn Ge diodes emitting between

    1590 and 1700nm [710]. Here we present an electrically pumped pnn Ge diode laser that can

    be monolithically integrated into a CMOS process. These first laser devices produce more

    than 1 mW of output power and exhibit a Ge gain spectrum of over 200nm.

    2. Experiments and results

    Initial estimates of gain in n-type Ge based on experimental results showed that an n-type

    doping level of 1x1019cm3would yield a gain of about 50 cm 1[11]. Such a gain can lead to

    lasing when pumped optically because optical losses are mainly limited to facet losses and

    free carrier losses in Ge. For electrical pumping, additional losses due to the electrical

    contacts, free carrier losses in doped poly Si and losses due to the interaction with the contactmetal, have to be overcome. Modeling of mode propagation in Ge waveguides with electrical

    contacts shows that these additional losses are >100 cm1.To overcome by these losses, the Ge

    gain must be increased by increasing the n-type doping to a level of 3-5x10 19 cm3 [2].

    Recently, we achieved n-type doping levels of > 4x1019cm3 by using a delta-doping

    technique during epitaxial growth of Ge [12]. By correlation of photoluminescence (PL)

    intensity, n-type doping level, and measured material gain, we have determined that an n-type

    doping level of 4x1019cm3corresponds to a material gain of >400cm1, enough to overcome

    the losses in an electrically pumped laser device.

    Ge waveguides of 1m width were fabricated by selective growth of n-type Ge-on-Si in

    silicon oxide trenches using Ultra-High Vacuum Chemical Vapor Deposition (UHV-CVD)

    [3]. A delta-doped Ge layer was grown on top of the n-type Ge to serve as a phosphorousdiffusion source [12, 13]. The delta-doping technique inserts monolayers of P in the Ge film

    at low temperatures by alternating the phosphine and germane gas flow in the CVD reactor.

    After thermal annealing to drive the phosphorous into the n-type Ge layer, the delta-doped Ge

    layer was removed during planarization using chemical mechanical polishing (CMP), to reach

    a uniform doping concentration in the gain medium. The remaining thickness of the Ge

    waveguide after CMP varied between 100 and 300nm depending on wafer and location on thewafer. Due to severe dishing of the waveguides after CMP the supported optical modes in the

    waveguides could not be determined exactly. Up to six cavity modes can be supported in the

    largest waveguides. An 180nm thick amorphous-Si film was then deposited via a Plasma-

    Enhanced CVD process and subsequently phosphorus-implanted to a doping level of

    1020cm3. After a dopant activation anneal at 750C, a metal stack, consisting of Ti and Al

    was deposited for top and bottom contacts. The oxide trench provides excellent current

    confinement. In order to assure even carrier injection into the n-type Ge, the top contact metal

    was deposited on top of the waveguide. After dicing, the waveguides were cleaved to expose

    the Ge waveguide facets. A thin oxide layer was deposited on the facets to protect against

    contamination and catastrophic optical mirror damage which was observed in devices that did

    not have oxide protection.

    #164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012

    (C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11317

    Fig. 1. Schematic of the measurement set-up.

    The waveguide emission was measured using a Horiba Micro PL system equipped with acooled InGaAs detector with lock-in detection. The emission power measurement was

    calibrated using light from a commercial 1550nm laser that was coupled into a single mode

    optical fiber with the fiber end at the sample location. In the calibration we verified that the

    detection was linear with input power. The electrical pumping was supplied by a pulse

    generator with current pulse widths in the range of 20 s to 100 ms. The duty cycle was

    varied between 2 and 50%, typically 4% to reduce electrical current heating effects. The laserwas contacted with metal probes and the current was measured using an inductive sensor

    placed directly in the biasing circuit. The experimental set-up is shown in Fig. 1.

    Fig. 2. Ge laser emission spectrum before (a) and after (b) threshold. The cavity length of thewaveguide is 333m and the waveguide height about 100nm. Current injection employed pulse

    widths of 50s at 800Hz and 15C. The detector spectral resolution was 1.2nm.

    Figure 2 shows the spectrum of an electrically pumped Ge laser below and above

    threshold. The broad, direct band gap related electroluminescence spectrum, observed for

    highly doped n-type Ge LEDs, has been reported earlier [14]. The spectra in Fig. 2 employed

    short integration times to assure wide spectrum analyses. Measurement time for these large

    laser devices is ultimately limited by metal contact breakdown due to the high current flow.Figure 2(a) shows no spectral features above the noise floor. When the injection current

    density is increased above threshold, sharp laser lines appear, as shown in Fig. 2(b). The

    observed linewidth of the individual lines is below 1.2nm, the spectral resolution of the

    measurement set-up. All measurements were performed with the samples mounted on a

    thermo-electric cooler at 15C. Local device temperatures, however, are likely higher due tothe high current injection but could not be reliably determined.

    #164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012

    (C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11318

    TFH SS 2012 135

    devices, the Ge waveguide height is directly related to the modal loss. Since Ge has the

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    Fig. 3. L-I curve for a 270m long waveguide device. 40s electrical pulses were used at

    1000Hz. Measurement temperature was 15C.

    Figure 3 shows the L-I spectrum for a typical electrically pumped Ge waveguide laser.

    The lasing threshold at about 280kA/cm2is clearly visible. This measurement was taken with

    the set-up in Fig. 1 using a wide instrumental spectral resolution of 10nm, at a wavelength of

    1650nm, monitoring a single laser line. The number of datapoints is limited by metal contact

    breakdown at high current level. The optical emission power of about 1 mW corresponds to

    Fig. 3. Occasionally we observed up to 7 mW. The spectrum in Fig. 2 shows two lines. Theestimate of the cavity free spectral range is 1nm, and the line spacing in Fig. 2, 3nm, is a

    possible multiple of the FSR.

    These lasers show a dependence of emission wavelength on threshold current density that

    is consistent with the expected modal loss variation and that confirms the theoretical

    conclusions that the gain spectrum of Ge for the given doping level and strain reaches over

    more than 100nm spectral width [15]. For high doping levels of 4x1019

    cm3

    , and tensile strain

    of ~0.2%, we observed lasing in the range from 1520nm to 1700nm. Figure 4 shows selectedlaser lines between 1576nm and 1656nm for different Fabry-Perot cavities of the same gain

    material.

    Fig. 4. Spectra of Ge lasers with different Ge waveguide heights. The measured laser line

    wavelengths are (a) 1576nm, (b) 1622nm, and (c) 1656nm.

    The CMP-induced variation in cavity height provides self-consistent evidence of the wide

    gain spectrum and the gain clamping condition by lasing. Under lasing action optical gain

    (and population inversion) is clamped at exactly the value of the resonant cavity losses. In our

    #164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012

    (C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11319

    g g y

    highest refractive index in our device structure, thinner Ge layers expel more of the resonant

    mode into the highly-doped poly-Si cladding and into the lossy metal contacts. The

    wavelength corresponding to the Ge gain peak (the threshold injection level) and the cavity

    loss is the expected emission wavelength of the device. As the modal confinement decreases

    with decreasing Ge layer thickness, modal loss and correspondingly threshold current

    increases and the emission wavelength blue shifts. In Fig. 5, we show spectral threshold

    conditions for two different modal cavity losses using a parabolic band model as described in

    [8].

    A Ge waveguide of 300nm thickness has a modal loss of about 90 cm1

    due to losses in

    the doped poly Si and the metal electrode (solid line). A Ge waveguide of 100nm thickness,

    however, has a modal loss of about 1000cm 1due to the closer proximity of the mode to theelectrode (dashed line). To overcome the high losses of the thin Ge waveguide, a relatively

    high carrier injection level is needed. Lasing is therefore expected at around 1520nm, close to

    what we find in Fig. 2. For lower loss waveguides we expect lasing to occur at longer

    wavelengths as shown in Fig. 4.

    Fig. 5. Simulation of gain clamping condition for two different Ge waveguide thicknesses

    (100nm: solid line; 300nm: dashed line). The axes plot the corresponding modal loss and gainspectrum for the two different injection levels that are needed to overcome the respectivemodal losses and to achieve lasing.

    3. Conclusions

    We have observed lasing from electrically pumped n-type Ge Fabry-Perot cavities. The

    threshold current densities decrease with increased modal confinement. The emission

    linewidth is less than the 1.2nm resolution of our measurement. Laser emission wavelengths

    were observed between 1520nm and 1700nm with a variation consistent with the gain

    clamping condition for each device. Measured output powers greater than 1 mW at room

    temperature were measured. Improvements in the Ge growth, electrical contacts, and in modal

    loss reduction will decrease the lasing threshold to values comparable with Fabry-Perot diode

    lasers. The high power and observed gain spectrum of nearly 200nm indicate that the Ge lasercould be used for WDM applications. Since the laser can be monolithically integrated into any

    CMOS process flow, novel device applications and systems can be developed.

    Acknowledgments

    This work was supported by the Fully Laser Integrated Photonics (FLIP) program under APIC

    Corporation, supervised by Dr. Raj Dutt, and sponsored by the Naval Air Warfare Center -

    Aircraft Division (NAWC-AD) under OTA N00421-03-9-002. R.E.C.-A. was supported by a

    NSF Graduate Research Fellowship award number 1122374.

    #164840 - $15.00 USD Received 19 Mar 2012; revised 24 Apr 2012; accepted 27 Apr 2012; published 2 May 2012

    (C) 2012 OSA 7 May 2012 / Vol. 20, No. 10 / OPTICS EXPRESS 11320

    TFH SS 2012 136

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