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School: Science Programme: Master of Science (M.Sc.)
Year : First Year Semester - II
Course: Physical Chemistry II Course Code:PCH201
Theory: 4 Hrs/Week Max. University Theory Examination: 50
Marks
Max. Time for Theory Exam.: 3 Hrs Continuous Internal Assessment: 50
Marks
Course Objectives
1 To understand the fundamental of the various Spectroscopic techniques with
Physical aspects
2 To Learn the principle behind the various spectroscopic techniques
3 To study the detail idea about Nuclear chemistry and its application
4 To learn the detail concept on radioactivity and its medical applications
5 To understand the various phenomena related to the radioactivity
Unit
Number Details Hours
1 Molecular Spectroscopy
A. Recapitulation: Width and intensity of spectral transitions, Fourier
transform, microwave spectroscopy, rotation spectra of di – and poly-
atomic molecules, Stark effect.
B. Infrared spectroscopy: Harmonic and anharmonic oscillator,
vibrational spectra of di– and poly- atomic molecules, coarse and fine
structure, Nuclear spin effect, applications.
C. Raman Spectroscopy: Introduction, Rotational Raman spectra,
vibrational Raman Spectra, polarization of light and Raman effect,
structure elucidation from combined Raman and IR spectroscopy,
applications in structure elucidation.
18
2 Electronic Spectroscopy of Molecules
A. Born – Oppenheimer approximation, electronic spectra of diatomic
molecules, vibrational coarse structure, rotational fine structure
dissociation energy and dissociation products, electronic structure of
diatomic molecules, molecular photoelectron spectroscopy,
application.
B. ESR and Mossbaur Spectroscopy Applications
C. NMR: Principles of NMR – Chemical applications of PMR in
structure elucidation.
12
3 Nuclear and Radiation Chemistry
A. Radio Chemistry: Recapitulation–type of radioactive decay,
Decay Kinetics, Detection & measurement of radiation (G.M. &
Scintillation counter).
11
B. Elements of Radiation Chemistry: Radiation chemistry,
interaction of radiation with miller, passage of nucleous through
matter, interaction of radiation with matter, Units for measuring
radiation absorption, Radiation dosimetry, Radiolsis of water, free
radiation in water Radiolsis, Radiolysis of some aqueous solution.
4 Nuclear Reactor
The fission energy, The Natural uranium reactor, the four factor
formula- The reproduction factor K, the classification of reactor.
Reactor power, Critical size of thermal reactor, excess reactivity &
control, the Breeder reactor, The Indians nuclear energy programme,
processing of spent fuel.
Recovery of Uranium & Plutonium, Nuclear waste management,
Natural nuclear reactor.
Isotopes for Nuclear Reactors
Isotope separation, separation of selected isotopes, plutonium.
12
5 Applications of Radioactivity
Typical reaction involved in preparation of radioisotopes: 3H, 14C, 22Na, 32P, 35S and 137I. General principles of using radioisotopes.
Analytical applications- neutron activation analysis, dilution analysis,
radiometric titration. Industrial applications– radiation gauging,
friction and wear out, gamma radiography.
7
Total 60
Course Outcomes
1 Students able to understand the concept of various spectroscopic phenomena with
physical aspects
2 Students able to understand the application of spectroscopic techniques in various
fields
3 Students able to explain concept regarding IR, Raman, Uv-Vis, ESR, NMR
4 Students able to understand the radioactivity and its application in various fields
5 Students able to understand the energy and various phenomena related to nuclear
reactor
Resources
Recommended
Books
Chemical Applications of Radioisotopes by H. J. M . Brown Buffer &
Jammer Ltd.
Reference
Books
1. Fundamentals of Molecular Spectroscopy by C.N. Banewell and
E.Mc. Cash, 4th edition.
2. Elements of Nuclear Chemistry by H. J. Arnikar, Wiley Estern
Ltd, 4th edition.
3. Source Book of Atomic Energy by S. Glasstanc, D. Van Norton
company.
School: Science Programme: Master of Science (M.Sc.)
Year : First Year Semester - II
Course: Inorganic Chemistry II Course Code:PCH202
Theory: 4 Hrs/Week Max. University Theory Examination:50
Marks
Max. Time for Theory Exam.:3 Hrs Continuous Internal Assessment: 50
Marks
Course Objectives
1 To understand the basic concepts of co-ordination chemistry
2 To learn the electron spectroscopy of various complexes
3 To understand the splitting of d orbital
4 To learn the basic concept of bio-inorganic chemistry
5 To learn the basic concept of catalysis
Unit
Number Details Hours
1 Co-ordination Chemistry
Concept and Scope of ligand fields.
Energy levels of transition metal ions, free ion terms, term wave
functions, and spin-orbits coupling.
Effect of ligand field on energy levels of transition metal ions, weak
cubic ligand field effect on Russell- Saunders terms, strong field
effect, correlation diagrams, Tanabe-Sugano diagrams, Spin-pairing
energies.
16
2 Electronic spectra of complexes-I Band intensities, band energies, band width & shapes, spectra of
1st , 2nd & 3rd row ions and rare earth ion complexes,
spectrochemical & nephlauxetic series, charge transfer &
luminescence, spectra, calculations of Dq, B, parameters. Magnetic
properties of complexes-paramagnetism 1st & 2nd Ordered Zeeman
effect.
10
3 Electronic spectra of complexes-II
Magnetic properties of complexes-paramagnetism 1 st& 2nd Ordered
Zeeman effect, quenching of orbital angular momentum by ligand
fields, Magnetic properties of A, E & T ground terms in complexes,
spin free spin paired equilibria
4
4 Bio-inorganic Chemistry
Overviews of Bio-inorganic Chemistry.
Principles of Coordination Chemistry related to Bio-inorganic–
Protein, Nucleic acids and other metal binding biomolecules.
11
5 Bio-inorganic Chemistry Choice, uptake and assembly of metal containing units in Biology
Catalysis : Introduction and its types
15
Total 60
Course Outcomes
1 Student able to explain the basic concept of coordination chemistry
2 Student able to analyze the electronic spectra of metal complex
3 Student able to describe the magnetic properties various coordination
compounds
4 Student able to explain the basic concept of bioinorganic chemistry
5 Student able to explain the types of catalysis
Resources
Reference
Books
1. Inorganic Electronic spectroscopy by A.B . P. Level, Elsevier
Science Publishers New York, 2nd edition 1984.
2. Biological Chemistry of the Elements by R. J. P. Williams and
F. R. Desalvia, Oxford University Press, 1991.
3. Bioinorganic Chemistry: Inorganic elements in the Chemistry
of life: An introduction & guide by W. Kaim and B .
Schwederski, VCH, 1991.
School: Science Programme: Master of Science (M.Sc.)
Year : First Year Semester - II
Course: Organic Chemistry II Course Code:PCH203
Theory: 4 Hrs/Week Max. University Theory Examination:50
Marks
Max. Time for Theory Exam.: 3 Hrs Continuous Internal Assessment: 50
Marks
Course Objectives
1 To learn the various oxidizing and reducing reagents
2 To learn the rearrangements reactions
3 To understand various spectroscopic techniques related to organic chemistry
4 To study problems in UV, IR and NMR
Unit
Number Details Hours
1 Oxidation and Reduction
CrO3 (Jones reagent), PDC, PCC, KMnO4, MnO2, Swern, SeO2,
Pb(OAc)4, Pd/C, OsO4, mCPBA, O3, NaIO4, HIO4, R3SiH, Bu3SnH,
Boranes & Hydroboration reactions, MVP, H2/ catalyst, Wilkinson’s
catalyst, NaCNBH3, NH2NH2, DIBAL etc.
12
2 A. Rearrangements
Reactive intermediates, carbocations, carbanions, carbenes, nitrenes,
Beckmann, Hofmann, Curtius, Schmidt, Wolf, Lossen, Baeyer–
Villiger, Sommelet, Favorskii, Pinacole–Pinacolone, Benzil–
Benzillic acid, Claisen and Cope Rearrangements, Fries Migration.
B. Phosphorous, Nitrogen and Sulphur Ylids
Phosphorous, Nitrogen and Sulphur ylids and stereochemistry of
compounds containing Phosphorous, Sulfur and Nitrogen
C. Enamines–formation and applications
18
3 Spectroscopy
A. Ultraviolet (U. V.) Spectroscopy
Electronic transitions, chromophores, auxochromes, Bathochromic
and hypsochromic shifts, Solvent effects, Woodward–Fieser Rules
for dienes, enones and aromatic compounds, Applications of U.V.,
instrumentation of recording of spectra.
B. Infrared (IR) Spectroscopy
Vibrational Transitions, Important group frequencies, Factors
affecting IR group frequency, Applications of I.R., Instrumentation
and recording of spectra.
10
4 Nuclear Magnetic Resonance (NMR) Spectroscopy 12
Elementary ideas of NMR Integration, Chemical shifts Factors
affecting, Chemical shifts, Coupling (First order, analysis),
Instrumentation & recording of spectra.
5 Problems in UV, IR and NMR. 8
Total 60
Course Outcomes
1 Students able to understand application of various oxidizing and reducing
reagents
2 Students able to explain various rearrangements reactions
3 Knowledge of various organic spectroscopic techniques related will help student
to elucidate structures
4 Student able to solve problems in UV, IR and NMR
Resources
Recommended
Books
1. Organic Chemistry by J. Clayden, N.Greeveset. al.
2. Stereochemistry by Eliel.
3. Stereochemistry of Organic Compounds by D. Nashipuri,
4. Spectroscopy of Organic Compounds by Pavia.
Reference
Books
1. Adv. Organic Chemistry by Carey and Sundberg, Edition III,
Part B.
2. Synthetic Organic Chemistry by H.O. House.
3. Mechanis and Structure in Organic Chemistry by E. S. Gould.
4. Organic Chemistry by R. O. C. Norman.
5. Advanced Organic Chemistry by J. March, Edition IV.
6. Spectrometric Identification of Organic Compounds by
Silversteine and Basser.
7. Organic Spectroscopy by Kalsi.
8. Infrared spectra of Complex molecules by J. Bellamy.
9. Organic Spectroscopy by I Fleming.
School: Science Programme: Master of Science (M.Sc.)
Year : First Year Semester - II
Course: Analytical Chemistry II Course Code: PCH204
Theory: 4 Hrs/Week Max. University Theory Examination: 50
Marks
Max. Time for Theory Exam: 3 Hrs Continuous Internal Assessment: 50 Marks
Course Objectives
1 To understand basic principle, and working of different gravimetric analysis
2 To learn and analyses the instrumentation and working principle of the absorption
and emission spectroscopic techniques
3 To understand polarography technique for micro analysis of elctroactive analyte
4 To study different chromatographic technique
Unit
Number Details Hours
1 Physico- Chemical techniques : Types of reference electrodes,
conductance by electrolytes, Kohlrauch's law, conductometric
titrations, strong acid – strong base pH metric titration, titration
of mixture of weak and strong acids, titration of mixtures of
strong acids, potentometric titrations and differential plots,
potentiometric titration of Fe +2 and Ce+4, numerical, .principle ,
theory, working, pH metry, conductometry, potentiometry
12
2 Thermal Methods of Analysis :Thermogravimetric Analysis –
Introduction – Principle, Instrumentation Techniques of TGA ,
Factors influencing the TGA thermograms, thermobalance –
precaution measures, applications of TGA , Differential Thermo
Analysis – theory and principle , Differential Thermo Analysis
– Instrumentation, Differential Thermo Analysis – applications
12
3 Optical methods-I : Principle , theory, working Atomic
Absorption Spectroscopy, Flame emission spectroscopy,
Turbidometry and Nephelometry, applications
12
4 Electro analytical Techniques-I: Polarography, Polarisable
and non polarisable electrodes, basic principles, residual
current, diffusion current, limiting current, dropping mercury
electrode, supporting electrolyte half wave potential, derivation
of the polarographic wave equation for a reversible reaction.
Ilkovic equation, polarographic cell, qualitative and quantitative
12
analysis, calibration curve and standard addition method,
applications.
5 Green Chemistry
Principles of Green Chemistry, Need of green Chemistry, Goals
and importance of green Chemistry, reaction efficiency
parameters, Concept of atom economy, Alternative feed
stocks/starting materials, Reagents, Solvents, Product/target
molecules, Catalysis and process analytical chemistry.
Evaluation of chemical product or process for its effect on
human health and environment, Evaluation of reaction types
and methods to design safer chemicals. Evaluating the effects
of Chemistry: Toxicity to humans, Toxicity to wildlife, Effects
on local environment, Global environmental effects. Planning a
green synthesis.
12
Total 60
Course Outcomes
1 Student will able to understand and analyses different gravimetric and
electrochemical analysis
2 Knowledge about the absorption and emission spectroscopic techniques will
help student in academic as well as in research
3 Students will come to know about polarogram, calibration curves method and
its applications
4 Theoretical concept of different chromatographic technique will help to
separate different organic and inorganic mixtures
Resources
Reference Books 1. D. Harvey, Modern Analytical Chemistry, The McGraw-Hill
Pub. 1st Edition (2000)
2. D.A. Skoog, D.M. West and F.J. Holler, Fundametals of
Analytical Chemistry, 7thEdition (printed in India in 2001)
ISBN Publication.
3. Analytical Chemistry, J.G. Dick,1973 Tata McGraw Hill
Publishing Co. Ltd. New Delhi.
4. Quantitative analysis, Dey & Underwood, Prentice Hall of
India, Pvt. Ltd. New Delhi
5. Instrumental Methods of Analysis H. H. Willard, L.L. Merritt
Jr., J.A. Dean and F.A. Settle, CBS Publisher, 7th edition.
6. Fundamentals of Analytical Chemistry by D. A. Skoog, D.M.
West, F . J. Holler and S. R. Crouch, 8th edition.
7. Principles of Instrumental Analysis, D. A. Skoog, F. J. Holler
and J.A. Niemann, (1998)
8. Standard Methods of Chemical Analysis, Eds. F. J. Welcher,
Robert E. Krieger Publishing Company, (A series of volumes)
9. Polarographic Methods in Analytical Chemistry, M. G. Arora,
Anmol Publications Pvt Ltd
School: Science Programme: Master of Science (M.Sc.)
Year: First Year Semester - II
Course: Physical and Inorganic chemistry
practical Laboratory II
Course Code: PCH211
Practical: PG – 4 Hrs./Batch (20 Students) Practical Examination:50 Marks
Term Work: 50 Marks
Course Objectives
1 To study the various chemical reactions using instrumental methods
2 To learn inorganic synthesis
3 To learn synthesis of inorganic complexes
4 To learn nano-material synthesis
Sr.
No. Description
1 Conductometry : Hydrolysis of NH4Cl or CH3COONa or aniline hydrochloride
2 Potentiomerty : Solubility of a sparingly soluble salt
3 Potentiomerty: Determine the stability constant silver-ammonia complex
4 pH metry : Determination of the acid and base dissociation constant of an amino
acid and hence the isoelectric point of the acid
5 pH metry : Determine the dissociation constant of tribasic acid
6 Non- Instrumental: Statistical treatment of experimental data.
7 Inorganic Synthesis : To prepare Tris(acetylacetonato) iron(III)
8 Inorganic Synthesis : To preparebis-ethylene diamine copper (II) sulphate
9 Synthesis of potassium trisoxalato chromate (III) trihydrate
10 Colorimetry: Determine the composition of complex between Fe and salicyclic acid
by Job’s continuous variation method
11 Nano-Chemistry: Synthesis and Characterization of graphene oxide
12 Table Work : Characterization of metal ligand bonding using IR spectroscopy
Course Outcomes
1 Students are able to analyze the various chemical reactions using instrumental
methods
2 Students are able to perform the various inorganic synthesis
3 Students are able to perform synthesis of various inorganic complexes
4 Students are able to perform the nano material synthesis
Term Work:
Term Work assessment shall be conducted for the Project, Tutorials and Seminar. Term work
is continuous assessment based on work done, submission of work in the form of
report/journal, timely completion, attendance, and understanding. It should be assessed by
subject teacher of the institute. At the end of the semester, the final grade for a Term Work
shall be assigned based on the performance of the student and is to be submitted to the
University.
Practical/Oral/Presentation:
Practical/Oral/Presentation shall be conducted and assessed jointly by internal and external
examiners. The performance in the Practical/Oral/Presentation examination shall be assessed
by at least a pair of examiners appointed as examiners by the University. The examiners will
prepare the mark/grade sheet in the format as specified by the University, authenticate and
seal it. Sealed envelope shall be submitted to the head of the department or authorized person.
Notes
1 Two experiments from the regular practical syllabus will be conducted. (Total 40
Marks).
2 Complete laboratory journal/records (05 Marks).
3 Viva-voce (05 Marks).
Notes
1 The experiments from the regular practical syllabus will be performed (30 Marks).
2 The regular attendance of students during the syllabus practical course will be
monitored and marks will be given accordingly (10 Marks).
3 Good Laboratory Practices (10 Marks)
School: Science Programme: Master of Science (M.Sc.)
Year: First Year Semester - II
Course: Organic and Analytical Chemistry
Practical Laboratory II
Course Code: PCH212
Practical: PG – 4 Hrs./Batch (20 Students) Practical Examination: 50 Marks
Term Work: 50 Marks
Course Objectives
1 To learn single-stage/double stage preparations of organic compounds
2 To learn synthesis of organic compounds using green chemistry approach
3 To learn analytical techniques
4 To learn chemistry related software’s
Sr.
No. Description
1 Preparations: Single Stage
1. Benzalacetophenone from benzaldehyde and acetophenone (Claisen-Scmidt
Reaction)
2. Benzaldehyde to dibenzylidene acetone
3. Benzhydrol from bezophenone
4. Praparation of p-nitrobenzoic acid from p-nitrotoluene
5. Preparation of borneol from camphor (Reduction)
2 Preparations: Two-stage
1. Phthalic Acid-Phthallic anhydride – Phthallimide
2. Cyclohexanone---Cyclohexane Oxime---Caprolactum
3. Acetanilide – p – Bromoacetanilide –--- p – Bromoaniline
3 Green Chemistry Experiments:
1. Bromoxynil Synthesis (Selective Herbicide)
2. Preparation of Acetanilide from aniline by using ZnO/AcOH (Acylation)
4 pH Metry: To titrate the solution of Na2CO3 against HCl pH- metrically and hence
to select appropriate indicators for two equivalence point.
5 Spectrophotometry : Spectrophotometric analysis of potassium permanganate
solutions
6 Determination of strength of commercial phosphoric acid by potentiometric titrations
using standard solution of sodium hydroxide
7 Use of Computer
Chem Draw Chem-Sketch, ISI–Draw: Draw the structure of simple aliphatic,
aromatic, heterocyclic compounds with different subsistent. Get the correct IUPAC
name and predict the 1H NMR signals.
Course Outcomes
1 Student will able to perform single and double stage preparations of organic
compounds
2 Student will able to prepare organic compound by green chemistry approach
3 Student will able to analyze concentration of unknown species by using
Electrochemical and absorption spectroscopic techniques
4 Student will learn draw structure using Chem Draw
Term Work:
Term Work assessment shall be conducted for the Project, Tutorials and Seminar. Term work
is continuous assessment based on work done, submission of work in the form of
report/journal, timely completion, attendance, and understanding. It should be assessed by
subject teacher of the institute. At the end of the semester, the final grade for a Term Work
shall be assigned based on the performance of the student and is to be submitted to the
University.
Notes
1 The experiments from the regular practical syllabus will be performed (30 Marks).
2 The regular attendance of students during the syllabus practical course will be
monitored and marks will be given accordingly (10 Marks).
3 Good Laboratory Practices (10 Marks)
Practical/Oral/Presentation:
Practical/Oral/Presentation shall be conducted and assessed jointly by internal and external
examiners. The performance in the Practical/Oral/Presentation examination shall be assessed
by at least a pair of examiners appointed as examiners by the University. The examiners will
prepare the mark/grade sheet in the format as specified by the University, authenticate and
seal it. Sealed envelope shall be submitted to the head of the department or authorized person.
Notes
1 Two experiments from the regular practical syllabus will be conducted. (Total
40 Marks).
2 Complete laboratory journal/records (05 Marks).
3 Viva-voce (05 Marks).