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Safety Data Sheet (SDS) Report
Applicant: Jiebao daily chemical(Xiangxi) Co.,Ltd
Floor1,building a,Guangzhou Industrial Park Industrial Center,Xiangxi Economic Development Zone Hunan, China
Sample Description:
The sample information was submitted and identified on client’s behalf to be:
Service Requested:
Based on the information provided by the applicant, the Safety Data Sheet (SDS) was generated in accordance with requirements of OSHA
HazCom Standard (2012), for details please refer to attached pages..
Authorized By:
On Behalf Of Regulatory Affairs in Intertek Testing Services Ltd., Shanghai
Anna Wang
Regulatory Consultant
This report shall not be reproduced except in full, without the written
approval of the laboratory.
Intertek Health, Environmental &Regulatory Services (HERS)
5th Floor,Building No.86,1198 QinZhou Road(North),Cao Hejing Development
Zone,ShangHai,China.
Tel: +86 021 53397917 ZIP: 200233
E-mail:[email protected]
SDS number: P202005 1102 Issue Date: 2020-05-13
Product Name : 75% alcohol wipes
Physical State : Solid
Data Received : May 11, 2020
Data Reviewed : May 13, 2020
Safety Data Sheet
Jiebao daily chemical(Xiangxi) Co.,Ltd
Version No:1.0According to OSHA HazCom Standard (2012) requirements GHS.USA.EN
SECTION 1 IDENTIFICATION
Product Identifier
Product name
Other means of identification
Recommended use of the chemical and restrictions on use
Relevant identified uses
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Supplier name Jiebao daily chemical(Xiangxi) Co.,Ltd
Address Floor1,building a,Guangzhou Industrial Park Industrial Center,Xiangxi Economic Development Zone Hunan, China
Telephone 0086-13826197561
Emergency telephone
Email [email protected]
Importer name
Address
Telephone
Emergency phone number
Association / Organisation
Emergency telephonenumbers
SECTION 2 HAZARD(S) IDENTIFICATION
Classification of the substance or mixture
Considered a Hazardous Substance by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Classified as Dangerous Goods for transport purposes.
Classification Flammable Solid Category 2, Eye Irritation Category 2A
Label elements
Hazard pictogram(s)
SIGNAL WORD WARNING
Hazard statement(s)
H228 Flammable solid.
H319 Causes serious eye irritation.
Hazard(s) not otherwise classified
Not Applicable
Supplementary statement(s)
Not Applicable
Page 1 continued...
Precautionary statement(s) General
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
SDS number: P2020051102
Issue Date:13/05/2020
75% alcohol wipes
75% alcohol wipes
Not Available
0086-13826197561
clean,disinfection,anti-bacterial
Precautionary statement(s) Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P370+P378 In case of fire: Use water jets for extinction.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
Precautionary statement(s) Storage
Not Applicable
Precautionary statement(s) Disposal
Not Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
NOTE: The liquid has been absorbed into a solid material.
Mixtures
CAS No Name
64-17-5
7732-18-5
SECTION 4 FIRST-AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin ContactIf skin contact occurs:
Seek medical attention in event of irritation.
InhalationIf fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.
IngestionImmediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Most important symptoms and effects, both acute and delayed
See Section 11
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIRE-FIGHTING MEASURES
Extinguishing media
Alcohol stable foam. Dry chemical powder.
For SMALL FIRES:Dry chemical, CO2, water spray or foam.For LARGE FIRES:Water-spray, fog or foam.
Special hazards arising from the substrate or mixture
Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Special protective equipment and precautions for fire-fighters
Ethanol
water
Continued...
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%[weight]
75
25
EC No
200-578-6
231-791-2
Issue Date:13/05/2020
75% alcohol wipesVersion No:1.0
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
Ingredient Original IDLH Revised IDLH
Fire FightingAlert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves.
Fire/Explosion Hazard
Flammable solid which burns and propagates flame easily, even when partly wetted with water. Any source of ignition, i.e. friction, heat, sparks or flame, may cause fire or explosion.
Combustion products include:carbon monoxide (CO)carbon dioxide (CO2)other pyrolysis products typical of burning organic material.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up
Minor SpillsRemove all ignition sources. DO NOT touch or walk through spilled material.
Major SpillsClear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handlingLimit all unnecessary personal contact.Wear protective clothing when risk of overexposure occurs.
Other informationFOR MINOR QUANTITIES:
Store in an indoor fireproof cabinet or in a room of noncombustible construction. Provide adequate portable fire-extinguishers in or near the storage area.
Conditions for safe storage, including any incompatibilities
Suitable container PE container.
Storage incompatibilityAvoid oxidising agents, acids, acid chlorides, acid anhydrides, chloroformates. Avoid strong bases.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
US NIOSH RecommendedExposure Limits (RELs)
EthanolAlcohol, Cologne spirit, Ethanol, EtOH, Grainalcohol
1000 ppm / 1900mg/m3
NotAvailable
NotAvailable
NotAvailable
US OSHA Permissible ExposureLevels (PELs) - Table Z1
Ethanol Ethyl alcohol (Ethanol)1000 ppm / 1900mg/m3
NotAvailable
NotAvailable
NotAvailable
US ACGIH Threshold LimitValues (TLV)
Ethanol Ethanol Not Available 1000 ppmNotAvailable
URT irr
EMERGENCY LIMITS
Ethanol Ethanol: (Ethyl alcohol) Not Available Not Available 15000* ppm
Ethanol 3,300 ppm Not Available
Exposure controls
Appropriate engineeringcontrols
For large scale or continuous use:Spark-free, earthed ventilation system, venting directly to the outside and separate from usual ventilation systems
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls canbe highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
Continued...
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75% alcohol wipesVersion No:1.0
Personal protection
Eye and face protectionSafety glasses with side shields.Chemical goggles.
Skin protection See Hand protection below
Hands/feet protectionWear physical protective gloves, e.g. leather. Wear safety footwear.
Body protection See Other protection below
Other protection
Overalls. Eyewash unit. Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce staticelectricity.For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets).
Respiratory protection
Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance White solid
Physical state Solid Relative density (Water = 1) Not Available
OdourPartition coefficient n-octanol
/ waterNot Available
Odour threshold Not Available Auto-ignition temperature (°C)
pH (as supplied) Decomposition temperature Not Available
Melting point / freezing point(°C)
Viscosity (cSt) Not Available
Initial boiling point and boilingrange (°C)
Molecular weight (g/mol) Not Available
Flash point (°C) 13(Ethanol) Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Flammable Oxidising properties Not Available
Upper Explosive Limit (%) Not AvailableSurface Tension (dyn/cm or
mN/m)Not Applicable
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Not Available pH as a solution (1%) Not Available
Vapour density (Air = 1) VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.
Possibility of hazardousreactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decompositionproducts
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute Toxicity
Ethanol
Inhalation (rat) LC50: 124.7 mg/l/4H[2]
Continued...
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characteristic odor
Not Available
Not Available
Not Available
Not Available
Not Available
Issue Date:13/05/2020
75% alcohol wipesVersion No:1.0
Ingredient Persistence: Water/Soil Persistence: Air
Ingredient Bioaccumulation
Ingredient Mobility
Air transport (ICAO-IATA / DGR)
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation Causes serious eye irritation.
Respiratory or skin sensitisation
Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwisespecified data extracted from RTECS - Register of Toxic Effect of chemical Substances
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Based on available data, the classification criteria are not met.
Persistence and degradability
Ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
Bioaccumulative potential
Ethanol LOW (LogKOW = -0.31)
Mobility in soil
Ethanol HIGH (KOC = 1)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible. DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal.
SECTION 14 TRANSPORT INFORMATION
Marine Pollutant NO
Land transport (DOT)
UN number 3175
UN proper shipping name Solids containing flammable liquid, n.o.s. (contains Ethanol)
Transport hazard class(es)Class 4.1
Subrisk Not Applicable
Packing group II
Environmental hazard Not Applicable
Special precautions for userHazard Label 4.1
Special provisions 47, IB6, IP2, T3, TP33
UN number 3175
UN proper shipping name Solids containing flammable liquid, n.o.s. * (contains Ethanol)
Continued...
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75% alcohol wipes
75% alcohol wipes
Issue Date:13/05/2020Version No:1.0
Sea transport (IMDG-Code / GGVSee)
Transport hazard class(es)
ICAO/IATA Class 4.1
ICAO / IATA Subrisk Not Applicable
ERG Code 3L
Packing group II
Environmental hazard Not Applicable
Special precautions for user
Special provisions A46
Cargo Only Packing Instructions 448
Cargo Only Maximum Qty / Pack 50 kg
Passenger and Cargo Packing Instructions 445
Passenger and Cargo Maximum Qty / Pack 15 kg
Passenger and Cargo Limited Quantity Packing Instructions Y441
Passenger and Cargo Limited Maximum Qty / Pack 5 kg
UN number 3175
UN proper shipping name SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (contains Ethanol)
Transport hazard class(es)IMDG Class 4.1
IMDG Subrisk Not Applicable
Packing group II
Environmental hazard Not Applicable
Special precautions for user
EMS Number F-A , S-I
Special provisions 216 274
Limited Quantities 1 kg
Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
NOTE: If this product meets the following speicial provisions 216 and A46, it will not be restricted under transport regulations.
Special provisions 216Mixtures of solids which are not subject to these Regulations and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1,provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or cargo transport unit is closed. Each cargo transport unit shall be leakproof whenused as a bulk packaging. Sealed packets and articles containing less than 10 ml of a packing group II or III flammable liquid absorbed into a solid material are not subject to theseRegulations provided there is no free liquid in the packet or article.Special provisions A46Mixtures of solids which are not subject to these Regulations and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1,providing there is no free liquid visible at the time the substance is packaged and for single packagings the packaging must pass a leak-proofness test at the Packing Group II level. Smallinner packagings consisting of sealed packets or articles containing less than 10 mL of a Packing Group II or III flammable liquid absorbed into a solid material are not subject to these Regulations provided there is no free liquid in the packet or article.
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL IS FOUND ON THE FOLLOWING REGULATORY LISTS
US ACGIH Threshold Limit Values (TLV)
US AIHA Workplace Environmental Exposure Levels (WEELs)
US DOE Temporary Emergency Exposure Limits (TEELs)
US NIOSH Recommended Exposure Limits (RELs)
US OSHA Permissible Exposure Levels (PELs) - Table Z1
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory
US TSCA Chemical Substance Inventory - Interim List of Active Substances
WATER IS FOUND ON THE FOLLOWING REGULATORY LISTS
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances
Federal Regulations
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SECTION 311/312 HAZARD CATEGORIES
Flammable (Gases, Aerosols, Liquids, or Solids) Yes
Gas under pressure No
Explosive No
Self-heating No
Pyrophoric (Liquid or Solid) No
Pyrophoric Gas No
Corrosive to metal No
Oxidizer (Liquid, Solid or Gas) No
Continued...
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75% alcohol wipesVersion No:1.0
Organic Peroxide No
Self-reactive No
In contact with water emits flammable gas No
Combustible Dust No
Carcinogenicity No
Acute toxicity (any route of exposure) No
Reproductive toxicity No
Skin Corrosion or Irritation No
Respiratory or Skin Sensitization No
Serious eye damage or eye irritation Yes
Specific target organ toxicity (single or repeated exposure) No
Aspiration Hazard No
Germ cell mutagenicity No
Simple Asphyxiant No
Hazards Not Otherwise Classified No
US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR 302.4)
None Reported
State Regulations
US. CALIFORNIA PROPOSITION 65
None Reported
SECTION 16 OTHER INFORMATION
Initial Date 13/05/2020
Other information
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace orother settings.
Definitions and abbreviations
PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index
end of SDS
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75% alcohol wipes
