Safety Data Sheet - KALE KİMYA...Product Name: VERSENEX* 80E Chelating Agent Revision Date: 2014/02/24 Print Date: 25 Feb 2014 ®(TM)*Trademark Page 1 of 43 The Dow Chemical Company

Product Name: VERSENEX* 80E Chelating Agent Revision Date: 2014/02/24 Print Date: 25 Feb 2014

®(TM)*Trademark

Page 1 of 43

The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

Section 1. Identification of the substance/preparation and of the company/undertaking

1.1 Product identifiers Product Name

VERSENEX* 80E Chelating Agent

Chemical Name: Pentasodium diethylenetriaminepentaacetate CAS-No. 140-01-2 EC-No. 205-391-3 REACH Registration Number

01-2119474445-33-0000 01-2119474445-33-0001

1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Industrial uses: Manufacture of substances Formulation and (re)packing of substances and mixtures. Intermediate Use in Cleaning Agents, industrial. Use as process chemical, industrial. Use in Oil and Gas field drilling and production operations, industrial. Professional uses: Use in Cleaning Agents, professional. Consumer uses: Use in Cleaning Agents, consumer. Uses in Coatings, consumer. 1.3 Details of the supplier of the safety data sheet COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center 48674 Midland, MI United States Customer Information Number: 800-258-2436 [email protected]

1.4 EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 989-636-4400 Local Emergency Contact: 00 31 115 69 4982

Safety Data Sheet The Dow Chemical Company

Safety Data Sheet according to Reg. (EC) N. 453/2010

Product Name: VERSENEX* 80E Chelating Agent Revision Date: 2014/02/24

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Section 2. Hazards Identification

2.1 Classification of the substance or mixture Classification - REGULATION (EC) No 1272/2008

Acute toxicity (Inhalation)

Category 4 H332 Harmful if inhaled.

Skin corrosion/irritation Category 2 H315 Causes skin irritation.

Serious eye damage/eye irritation

Category 2 H319 Causes serious eye irritation.

Reproductive toxicity Category 2 H361d Suspected of damaging the unborn child.

Classification according to EU Directives 67/548/EEC or 1999/45/EC Toxic to Reproduction Category

3 R63 Possible risk of harm to the unborn child.

Xn R20 Harmful by inhalation.

Xi R36/38 Irritating to eyes and skin.

2.2 Label elements Labelling - REGULATION (EC) No 1272/2008 Hazard pictograms

Signal Word: Warning Hazard statements:

H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child.

Precautionary Statements: P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P202 Do not handle until all safety precautions have been read and understood. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P405 Store locked up. P501 Dispose of contents and container to licensed, permitted incinerator, or other thermal destruction device.

2.3 Other Hazards No information available.

3.1 Substance This product is a substance.

Section 3. Composition/information on ingredients


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CAS-No. / EC-No. / Index

REACH No. Amount Component Classification: REGULATION (EC) No 1272/2008

CAS-No. 140-01-2 EC-No.

205-391-3

01-2119474445-

33

>= 35.0 - = 1.0 - = 52.0 % Water## Not classified

CAS-No. / EC-No. / Index

Amount Component Classification: 67/548/EEC

CAS-No. 140-01-2 EC-No.

205-391-3

>= 35.0 - = 1.0 - = 52.0 % Water## Not classified.

## Voluntarily disclosed component(s). For the full text of the H-Statements mentioned in this Section, see Section 16. See Section 16 for full text of R-phrases.

Section 4. First-aid measures


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4.1 Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air; if effects occur, consult a physician. Skin Contact: Wash skin with plenty of water. Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: Do not induce vomiting. Give one cup (8 ounces or 240 ml) of water or milk if available and transport to a medical facility. Do not give anything by mouth unless the person is fully conscious.

4.2 Most important symptoms and effects, both acute and delayed Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.

4.3 Indication of immediate medical attention and special treatment needed May cause asthma-like (reactive airways) symptoms. Bronchodilators, expectorants, antitussives and corticosteroids may be of help. Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest endotracheal/esophageal control if lavage is done. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Repeated excessive exposure may aggravate preexisting lung disease.

Section 5. Fire Fighting Measures

5.1 Extinguishing Media To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.

5.2 Special hazards arising from the substance or mixture

Hazardous Combustion Products: Under fire conditions some components of this product may decompose. The smoke may contain unidentified toxic and/or irritating compounds. Combustion products may include and are not limited to: Nitrogen oxides. Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: This material will not burn until the water has evaporated. Residue can burn.

5.3 Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

Section 6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Ventilate area of leak or spill. Keep upwind of spill. Refer to Section 7, Handling, for additional precautionary


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measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. 6.2 Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

6.3 Methods and materials for containment and cleaning up: Small spills: Contain spilled material if possible. Absorb with materials such as: Dirt. Sand. Non-combustible material. Collect in suitable and properly labeled containers. Large spills: Dike area to contain spill. Water may be used for final cleaning of affected area. Wash water should be disposed of in accordance with local regulations. See Section 13, Disposal Considerations, for additional information.

Section 7. Handling and Storage

7.1 Precautions for safe handling

Handling General Handling: Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Do not swallow. Avoid breathing mist. Use with adequate ventilation. Keep container closed. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. 7.2 Conditions for safe storage, including any incompatibilities

Storage Do not store in: Opened or unlabeled containers. Zinc. Aluminum and its alloys. Carbon steel. Copper. Copper alloys. Galvanized containers. Nickel. Store in original unopened container. See Section 10 for more specific information. Additional storage and handling information on this product may be obtained by calling your sales or customer service contact.

7.3 Specific end uses See the technical data sheet on this product for further information.

Section 8. Exposure Controls / Personal Protection

8.1 Control parameters

Exposure Limits

Component List Type Value |

Sodium hydroxide; caustic soda

Ireland OELV STEL 2 mg/m3

ACGIH Ceiling 2 mg/m3

UK WEL STEL 2 mg/m3

Derived No Effect Level (DNEL)

Workers

Potential Health Effects Possible route(s) of exposure:

Value

Acute - systemic effects Skin Contact Not available Acute - systemic effects Inhalation Not available Acute - local effects Skin Contact Not available Acute - local effects Inhalation 2.5 mg/m3


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Long-term - systemic effects Skin Contact 11718 mg/kg bw/day Long-term - systemic effects Inhalation 5.7 mg/m3 Long-term - local effects Skin Contact Not available Long-term - local effects Inhalation Not available

Consumers

Potential Health Effects Possible route(s) of exposure:

Value

Acute - systemic effects Skin contact Not available Acute - systemic effects Inhalation Not available Acute - systemic effects Ingestion Not available Acute - local effects Skin contact Not available Acute - local effects Inhalation Not available Long-term - systemic effects Skin contact 11718 mg/kg bw/day Long-term - systemic effects Inhalation 2.1 mg/m3 Long-term - systemic effects Ingestion 2.3 mg/kg bw/day Long-term - local effects Skin contact Not available Long-term - local effects Inhalation Not available

Predicted No Effect Concentration (PNEC)

Compartment Value Remarks

Fresh water 6.4 mg/l Marine water 0.64 mg/l Intermittent releases 3.1 mg/l STP 51 mg/l Fresh water sediment 23 mg/kg d.w. Marine sediment 2.3 mg/kg d.w. Soil 0.853 mg/kg d.w. 8.2 Exposure controls

Personal Protection Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent. Skin Protection: Wear clean, body-covering clothing.

Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. If hands are cut or scratched, use gloves chemically resistant to this material even for brief exposures. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. Use the following CE approved air-purifying respirator: Particulate filter, type P2.


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Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating.

Engineering Controls Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.

Section 9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties Appearance Physical State Liquid. Color Colorless to yellow Odor Slightly ammoniacal Odor Threshold No test data available pH 11.0 - 11.8 (@ 1 %) Literature Melting Point Not applicable to liquids Freezing Point -28 °C Literature Pour point Boiling Point (760 mmHg) 106 °C Literature . Flash Point - Closed Cup Pensky-Martens Closed Cup ASTM D 93 No measurable flash point Evaporation Rate (Butyl Acetate = 1)

< 0.8 Estimated.

Flammability (solid, gas) Not applicable to liquids Flammable Limits In Air Lower: Not applicable Upper: Not applicable Vapor Pressure Same as water Vapor Density (air = 1) Same as water Specific Gravity (H2O = 1) 1.30 25 °C/25 °C Literature Solubility in water (by weight)

completely miscible with water

Partition coefficient, n-octanol/water (log Pow)

< -2 Measured

Autoignition Temperature Not applicable Decomposition Temperature

No test data available

Kinematic Viscosity 33 cSt @ 20 °C Literature Explosive properties no data available Oxidizing properties no data available 9.2 Other information Molecular Weight Not available

Section 10. Stability and Reactivity

10.1 Reactivity No dangerous reaction known under conditions of normal use.

10.2 Chemical stability Stable under recommended storage conditions. See Storage, Section 7.

10.3 Possibility of hazardous reactions Polymerization will not occur.


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10.4 Conditions to Avoid: Some components of this product can decompose at elevated temperatures.

10.5 Incompatible Materials: Avoid contact with metals such as: Aluminum alloys. Copper. Copper alloys. Nickel. Flammable hydrogen may be generated from contact with metals such as: Zinc. Aluminum.

10.6 Hazardous decomposition products Decomposition products depend upon temperature, air supply and the presence of other materials.

Section 11. Toxicological Information

11.1 Information on toxicological effects

Acute Toxicity Ingestion Low toxicity if swallowed. Swallowing may result in gastrointestinal irritation or ulceration. Swallowing may result in burns of the mouth and throat. LD50, rat > 2,000 mg/kg Aspiration hazard Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung injury. Dermal Prolonged skin contact is unlikely to result in absorption of harmful amounts. LD50, rat > 2,000 mg/kg No deaths occurred at this concentration. Inhalation Vapors are primarily water; single exposure is not likely to be hazardous. Prolonged excessive exposure to mist may cause serious adverse effects, even death. Mist may cause irritation of upper respiratory tract (nose and throat) and lungs. For the major component(s): , 4 h, Respirable dust., rat 1 - 5 mg/l

Eye damage/eye irritation May cause moderate eye irritation. May cause corneal injury.

Skin corrosion/irritation Prolonged contact may cause moderate skin irritation with local redness. May cause more severe response if skin is abraded (scratched or cut).

Sensitization Skin Did not cause allergic skin reactions when tested in guinea pigs. Respiratory No relevant data found.

Repeated Dose Toxicity For the minor component(s): In animals, effects have been reported on the following organs: Kidney. Urinary tract. In animals, has been shown to cause deposition of calcium salts in various urinary tract tissues.

Chronic Toxicity and Carcinogenicity Although large dietary doses of NTA have caused urinary tumors in laboratory animals, there is little likelihood that NTA could cause cancer in humans, especially at subtoxic doses.

Developmental Toxicity EDTA and its sodium salts have been reported to cause birth defects in laboratory animals only at exaggerated doses that were toxic to the mother. These effects are likely associated with zinc deficiency due to chelation. Has been toxic to the fetus in lab animals at doses nontoxic to the mother.

Reproductive Toxicity No relevant data found.

Genetic Toxicology In vitro genetic toxicity studies were negative. Component Toxicology - Nitrilotriacetate, trisodium salt (NTA)

Inhalation No deaths occurred at this concentration. LD50, 4 h, Aerosol, rat,


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male > 5.0 mg/l

Section 12. Ecological Information

12.1 Toxicity Based on information for a similar material: Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50 greater than 100 mg/L in most sensitive species). Fish Acute & Prolonged Toxicity Based on analogy. LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 h: 854 mg/l Aquatic Invertebrate Acute Toxicity Based on analogy. EC50, Daphnia carinata., static test, 48 h, immobilization: 310 mg/l Toxicity to Micro-organisms Based on analogy. EC50, activated sludge test (OECD 209), Respiration inhibition, 30 min: > 500 mg/l Fish Chronic Toxicity Value (ChV) Crimson-spotted rainbowfish (Melanotaenia fluviatilis), semi-static test, 28 d, NOEC:127 mg/l Aquatic Invertebrates Chronic Toxicity Value Daphnia carinata., static test, 18 d, number of offspring, NOEC: 64 mg/l

12.2 Persistence and Degradability Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions. OECD Biodegradation Tests: Based on analogy.

Biodegradation Exposure Time Method 10 Day Window

29 % 28 d OECD 301B Test fail

0 % 28 d OECD 301F Test fail

12.3 Bioaccumulative potential Bioaccumulation: No bioconcentration is expected because of the relatively high water solubility. Partition coefficient, n-octanol/water (log Pow): < -2 Measured

12.4 Mobility in soil Mobility in soil: Expected to be relatively immobile in soil (Koc > 5000).

12.5 Results of PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).

12.6 Other adverse effects This substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.

Section 13. Disposal Considerations

13.1 Waste treatment methods This product, when being disposed of in its unused and uncontaminated state should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste. For used, contaminated and residual materials additional evaluations may be required. Do not dump into any sewers, on the ground, or into any body of water.


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Section 14. Transport Information

ADR/RID 14.1 UN number UN3267 14.2 UN proper shipping name Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. Technical Name: Sodium Hydroxide, Pentasodium Diethylenetriaminepentaacetate 14.3 Transport hazard class(es) Hazard Class: 8 14.4 Packing Group PG III 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user Special Provisions: no data available Hazard identification No:80

ADNR / ADN 14.1 UN number UN3267 14.2 UN proper shipping name Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. Technical Name: Sodium Hydroxide, Pentasodium Diethylenetriaminepentaacetate 14.3 Transport hazard class(es) Hazard Class: 8 14.4 Packing Group PG III 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user no data available

IMDG 14.1 UN number UN3267 14.2 UN proper shipping name Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. Technical Name: Sodium Hydroxide, Pentasodium Diethylenetriaminepentaacetate 14.3 Transport hazard class(es) Hazard Class: 8 14.4 Packing Group PG III 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user EMS Number: F-A,S-B 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Product Name: Diethylenetriaminepentaacetic acid, pentasodium salt solution Ship Type: 3 Pollution Category: Z


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ICAO/IATA 14.1 UN number UN3267 14.2 UN proper shipping name Proper Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. Technical Name: Sodium Hydroxide, Pentasodium Diethylenetriaminepentaacetate 14.3 Transport hazard class(es) Hazard Class: 8 14.4 Packing Group PG III 14.5 Environmental hazards Not considered environmentally hazardous based on available data 14.6 Special precautions for user no data available

Section 15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture European Inventory of Existing Commercial Chemical Substances (EINECS) The components of this product are on the EINECS inventory or are exempt from inventory requirements.

15.2 Chemical Safety Assessment A Chemical Safety Assessment has been carried out for this substance.

Section 16. Other Information

Hazard statement in the composition section

H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child.

Risk-phrases in the Composition section R20 Harmful by inhalation. R22 Harmful if swallowed. R35 Causes severe burns. R36 Irritating to eyes. R40 Limited evidence of a carcinogenic effect. R63 Possible risk of harm to the unborn child.

Revision Identification Number: 51324 / 1001 / Issue Date 2014/02/24 / Version: 8.0


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Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document.

The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.


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Section 1 Exposure Scenario: Worker

Title Manufacture of substance, industrial

Sector of Use SU3

Process Category PROC1; PROC2; PROC3; PROC4; PROC8a; PROC8b; PROC9; PROC15

Product Category n/a

Article Category n/a

Environmental Release Category ERC1

Specific Environmental Release Category

n/a

Processes, tasks, activities covered Manufacture of the substance or use as a process chemical or extraction agent. Includes recycling/ recovery, material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities; Use of the substance within laboratory settings, including material transfers and equipment cleaning

Section 2 Operational conditions and risk management measures

Product characteristics

Physical form of product Solid

Volatility n/a

Dustiness Solid, medium dustiness

Concentration in a preparation/product (wt.%)

< 100

Other product characteristics n/a

Section 2.1 Control of worker exposure

Operational conditions

Amounts used n/a

Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently)

Human factors not influenced by risk management

n/a

Other Operational Conditions affecting worker exposure

Assumes a good basic standard of occupational hygiene is implemented

Risk Management Measures

Contributing Scenarios

General exposures Continuous process (closed systems)

No other specific measures identified

Continuous process with sample collection (closed systems)


Use in contained batch processes General exposures with sample collection


General exposures (open systems)



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Use in contained batch processes General exposures with sample collection Spraying


Mixing operations (closed systems) with sample collection


Drum and small package filling Dedicated facility

Ensure material transfers are under containment or extract ventilation

Bulk transfers Dedicated facility

Wear a respirator conforming to EN140 with Type A/P2 filter or better

Equipment cleaning and maintenance


Bulk product storage (closed systems)


Laboratory activities No other specific measures identified

Section 2.2 Control of environmental exposure


Amounts used -- Maximum daily site tonnage (kg/d)

10100

Frequency of use Continuous release.

Duration of use (Emission Days/year)

300

Environmental factors not influenced by risk management

Local freshwater dilution factor: 10. Local marine water dilution factor: 100.

Other Operational Conditions of use affecting environmental exposure

n/a


Technical conditions and measures at process level (source) to prevent release

n/a

Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil

n/a

Organisation measures to prevent/limit release from site

n/a

Conditions and measures related to municipal sewage treatment plant

Estimated substance removal from wastewater via domestic sewage treatment (%): 87

Conditions and measures related to external treatment of waste for disposal

External treatment and disposal of waste should comply with applicable local and/or national regulations.

Conditions and measures related to external recovery of waste

n/a

Other environmental measures n/a


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Section 3 Exposure Estimation

3.1 Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.

3.2 Environment Used EUSES model.

Section 4 Guidance to check compliance with the Exposure Scenario

4.1 Health Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted. Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented

4.2 Environment Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Further details on scaling and control technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html).


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Title Formulation & (re)packing of substances and mixtures, industrial

Sector of Use SU3

Process Category PROC1; PROC2; PROC3; PROC4; PROC5; PROC8a; PROC8b; PROC9; PROC14; PROC15





n/a

Processes, tasks, activities covered Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tabletting, compression, pelletisation, extrusion, large and small scale packing, sampling, maintenance and associated laboratory activities




Volatility n/a



< 100




Amounts used n/a



n/a





General exposures Continuous process no sampling (closed systems)


General exposures Continuous process with sample collection (closed systems)






Mixing operations (open systems) with sample collection

Provide extract ventilation to points where emissions occur


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Material transfers Drum/batch transfers Dedicated facility


Material transfers Dedicated facility


Drum and small package filling Dedicated facility


Transfer from/pouring from containers Manual


Production or preparation or articles by tabletting, compression, extrusion or pelletisation

Limit the substance content in the product to 5 %; Provide extract ventilation to points where emissions occur


Limit the substance content in the product to 5 %







10100



300




n/a



n/a


n/a


n/a


Estimated substance removal from wastewater via domestic sewage treatment (%): 87.3




n/a






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Title Use as an intermediate, industrial

Sector of Use SU3

Process Category PROC1; PROC2; PROC4; PROC8a; PROC8b





n/a

Processes, tasks, activities covered Use of substance as an intermediate (not related to Strictly Controlled Conditions). Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container).




Volatility n/a



< 100




Amounts used n/a



n/a





Material transfers Dedicated facility


Material transfers Non-dedicated facility


Mixing operations (closed systems) Continuous process


Mixing operations (closed systems) Continuous process with sample collection


Mixing operations (open systems) Continuous process with sample collection





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10000



350




n/a



n/a


n/a


n/a






n/a






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Title Use in Cleaning Agents, industrial

Sector of Use SU3

Process Category PROC1; PROC2; PROC3; PROC4; PROC7; PROC8a; PROC8b; PROC10; PROC13



Environmental Release Category ERC8a; ERC8d


n/a

Processes, tasks, activities covered Covers the use as a component of cleaning products including transfer from storage, pouring/unloading from drums or containers. Exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping, automated and by hand), related equipment cleaning and maintenance.




Volatility n/a



< 100




Amounts used n/a



n/a









Mixing operations (open systems)

Limit the substance content in the product to 25 % ; Avoid carrying out activities involving exposure for more than 4 hours

Filling / preparation of equipment from drums or containers. Dedicated facility


Application of cleaning products in closed systems Continuous process



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Application of cleaning products in closed systems Batch process


Material transfers Manual


Degreasing small objects in cleaning station


Cleaning Surfaces no spraying Manual


Cleaning with low-pressure washers


Cleaning with high pressure washers




Storage (closed systems)





10



200




n/a



n/a


n/a


n/a






n/a






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Title Use in Cleaning Agents, professional

Sector of Use SU3

Process Category PROC3; PROC4; PROC8a; PROC8b; PROC10; PROC11;PROC13





n/a

Processes, tasks, activities covered Covers the use as a component of cleaning products including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory phase and cleaning activities (including spraying, brushing, dipping, wiping automated and by hand).




Volatility n/a



< 100




Amounts used n/a



n/a





Mixing operations (open systems)

Limit the substance content in the product to 25 % ; Avoid carrying out activities involving exposure for more than 4 hours

Filling / preparation of equipment from drums or containers. Dedicated facility


Filling / preparation of equipment from drums or containers. Non-dedicated facility


Application of cleaning products in closed systems Batch process


Material transfers Manual

Limit the substance in product to 10 %


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Semi Automated process. (e.g.: Semi automatic application of floor care and maintenance products)


Degreasing small objects in cleaning station


Cleaning Surfaces no spraying Manual


Ad hoc manual application via trigger sprays, dipping, etc. Rolling, Brushing


Cleaning with low-pressure washers


Cleaning with high pressure washers

Limit the substance in product to 10 %




10100



365




n/a



n/a


n/a


n/a


Estimated substance removal from wastewater via domestic sewage treatment (%): 87.3




n/a







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Sector of Use SU3

Process Category PROC1; PROC2; PROC3; PROC4; PROC8a; PROC8b; PROC15



Environmental Release Category ERC8a; ERC8c


n/a





Volatility n/a



< 100




Amounts used n/a



n/a











General exposures Continuous process with sample collection (closed systems)


Use in contained batch processes with sample collection Mixing operations (closed systems)



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Mixing operations (open systems) Batch process with sample collection






10100



300




n/a



n/a


n/a


n/a






n/a






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Title Industrial use as process chemical (semi-closed systems).

Sector of Use SU3






n/a

Processes, tasks, activities covered Use as a process chemical or extraction agent. Includes recycling/recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and bulk container).




Volatility n/a



< 100




Amounts used n/a



n/a
















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Use in contained batch processes with sample collection










10100



300




n/a



n/a


n/a


n/a






n/a



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Sector of Use SU3




Environmental Release Category ERC6a


n/a





Volatility n/a



< 100




Amounts used n/a



n/a













Use in contained batch processes with sample collection





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10100



300




n/a



n/a


n/a


n/a






n/a






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Title Use in Oil and Gas field drilling and production operations, industrial

Sector of Use SU3

Process Category PROC1; PROC3; PROC4; PROC8a; PROC8b





n/a

Processes, tasks, activities covered Oil field well drilling and production operations (including drilling muds and well cleaning) including material transfers, on-site formulation, well head operations, shaker room activities and related maintenance.




Volatility n/a



< 100




Amounts used n/a



n/a





Bulk transfers from tote tanks and supply vessels


Filling / preparation of equipment from drums or containers.


Drilling mud (re-)formulation No other specific measures identified

Drill floor operations No other specific measures identified

Operation of solids filtering equipment - aerosol exposures

Limit the substance content in the product to 5 %

Cleaning of solids filtering equipment


Treatment and disposal of filtered solids


Process sampling No other specific measures identified

Material transfers (closed systems)


Pouring from small containers No other specific measures identified




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Storage (closed systems)





10100



350




n/a



n/a


n/a


n/a






n/a






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Section 1 Exposure Scenario: Consumer

Title Use in Cleaning Agents, consumer

Sector of Use SU21

Process Category n/a

Product Category PC1; PC3; PC8; PC20; PC34; PC35




n/a

Processes, tasks, activities covered Covers general exposures to consumers arising from the use of household products sold as washing and cleaning products, aerosols, coatings, de-icers, lubricants and air care products.



Physical form of product Liquid

Volatility n/a

Dustiness n/a


< 5


Section 2.1 Control of consumer exposure


Amounts used n/a

Frequency and duration of use Covers frequency up to: daily yearly use


n/a

Other Operational Conditions affecting consumer exposure

n/a


Product category/sub-category


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PC1 - Adhesives, Sealants PC3 - Air care products PC8 - Biocidal Products (e.g. Disinfectants, pest control) PC20 - Products such as pH-regulators, flocculants, precipitants, neutralization agents PC34 - Textile dyes, finishing and impregnating products: including bleaches and other processing aids PC35 - Washing and Cleaning Products (including solvent based products)

Avoid using at a product concentration greater than (%): 5


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10100


Duration of use (Emission Days/year) 365




n/a



n/a


n/a


n/a






n/a



3.1 Health The Consexpo model has been used to estimate consumer exposures unless otherwise indicated.



4.1 Health Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.



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Section 1 Exposure Scenario: Consumer

Title Uses in Coatings, consumer

Sector of Use SU21

Process Category n/a

Product Category PC5; PC9a; PC9b; PC9c; PC10; PC14; PC15; PC23; PC31


Environmental Release Category ERC8a; ERC8c; ERC8d


n/a

Processes, tasks, activities covered Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.



Physical form of product Liquid

Volatility n/a

Dustiness n/a


< 5


Section 2.1 Control of consumer exposure


Amounts used n/a

Frequency and duration of use Covers frequency up to: daily yearly use


n/a

Other Operational Conditions affecting consumer exposure

n/a


Product category/sub-category

PC9a - Coatings and paints, thinners, paint removers PC9b - Fillers, putties, plasters, modeling clay PC9c - Finger paints PC14 - Metal surface treatment products, including galvanic and electroplating products PC15 - Non-metal-surface treatment products PC23 - Leather tanning, dyes, finishing, impregnation and care products PC31 - Polishes and Wax Blends

Avoid using at a product concentration greater than (%): 5


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10100


Duration of use (Emission Days/year) 365




n/a



n/a


n/a


n/a




n/a


n/a



3.1 Health The Consexpo model has been used to estimate consumer exposures unless otherwise indicated.



4.1 Health Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.


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