Safety Data Sheet - EPA...Ingredient CAS Nbr % by Weight Soda lime borosilicate glass 65997-17-3 97 - 100 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation

3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,

HGS4K28, HGS19K46

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Safety Data Sheet

© 2016, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly

utilising 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written

agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention

of earning a profit thereon.

Document group: 16-2219-0 Version number: 3.00

Issue Date: 14/11/2016 Supersedes date: 06/10/2014

This Safety Data Sheet has been prepared in accordance with the New Zealand, Hazardous Substances and New Organisms

Act 1996 (HSNO Act) and Regulations, as amended.

SECTION 1: Identification

1.1. Product identifier


HGS4K28, HGS19K46

Product Identification Numbers

98-0212-2988-9 UU-0031-6527-9 WF-6009-0052-7

1.2. Recommended use and restrictions on use

Recommended use

Downhole Oil and Gas Applications, Industrial use.

1.3. Supplier’s details

Address: 3M New Zealand Ltd, 94 Apollo Drive, Rosedale 0632, Auckland

Telephone: (09) 477 4040

E Mail: [email protected]

Website: 3m.co.nz

1.4. Emergency telephone number

24 hr Medical Emergency, National Poisons Centre, 0800 764 766 (0800 POISON)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

Classified as hazardous according to the New Zealand, Hazardous Substances (Minimum Degrees of Hazard) Regulations

2001 as amended. This product is considered to be an article which does not release or otherwise result in exposure to a

hazardous chemical under normal use conditions.

Not classified as a Dangerous Good according to; New Zealand, Land Transport Rule: Dangerous Goods 2005 (Rule

45001/1) as amended, NZS 5433:2012 Transport of Dangerous Goods on Land, UN Model Regulations on the Transport of

Dangerous Goods, International Maritime Dangerous Goods Code and IATA Dangerous Goods Regulations.

HSNO classification

6.1E Acute toxicity

2.2. Label elements


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SIGNAL WORD

WARNING!

HAZARD STATEMENTS:

H303 May be harmful if swallowed.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr % by Weight

Soda lime borosilicate glass 65997-17-3 97 - 100

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get

medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

5.3. Special protective actions for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,

respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment.


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6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up.

Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container.

Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

Refer to Section 15: HSNO Controls for more information.

7.1. Precautions for safe handling

For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke

when using this product. Wash thoroughly after handling.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

7.3. Approved handler test certificate

Not required

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available

for the component.

Ingredient CAS Nbr Agency Limit type Additional comments

Glass filaments 65997-17-3 New Zealand

WES

TWA(as inhalable dust)(8

hours):5 mg/m3;TWA(as

respirable dust)(8 hours):1

f/mL;TWA(Respirable

fibers)(8 hours):1 f/mL

Soda lime borosilicate glass 65997-17-3 Manufacturer

determined

TWA(as dust):10 mg/m3

ACGIH : American Conference of Governmental Industrial Hygienists

AIHA : American Industrial Hygiene Association

CMRG : Chemical Manufacturer's Recommended Guidelines

New Zealand WES : New Zealand Workplace Exposure Standards.

TWA: Time-Weighted-Average

STEL: Short Term Exposure Limit

ppm: parts per million

mg/m³: milligrams per cubic metre

CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Provide appropriate local exhaust ventilation at transfer points. Use general dilution ventilation and/or local exhaust

ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray.

If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face

protection(s) are recommended:


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Safety glasses with side shields.

Refer AS/NZS 1336 - Recommended practices for occupational eye protection and for performance specifications AS/NZS

1337, Parts 1 - 6 - Personal eye-protection.

Skin/hand protection

No chemical protective gloves are required.

Respiratory protection

Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to

decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program.

Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:

Half facepiece or full facepiece air-purifying respirator suitable for particulates.

For questions about suitability for a specific application, consult with your respirator manufacturer.

Refer AS/NZS 1715 - Selection, use and maintenance of respiratory protective equipment and AS/NZS 1716 - Respiratory

protective devices.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Solid.

Specific Physical Form: Fine Powder < 100 microns

Appearance/Odour White, Odourless

Odour threshold Not applicable.

Melting point/Freezing point No data available.

Boiling point/Initial boiling point/Boiling range Not applicable.

Flash point Not applicable.

Evaporation rate Not applicable.

Flammability (solid, gas) Not classified

Flammable Limits(LEL) Not applicable.

Flammable Limits(UEL) Not applicable.

Vapour pressure Not applicable.

Vapour density Not applicable.

Density 0.1 - 0.6 g/cm3

Relative density 0.1 - 0.6 [Ref Std:WATER=1]

Water solubility Negligible

Solubility- non-water Not applicable.

Partition coefficient: n-octanol/water No data available.

Autoignition temperature Not applicable.

Decomposition temperature Not applicable.

Viscosity Not applicable.

Molecular weight No data available.

Volatile organic compounds (VOC) Not applicable.

Percent volatile < 0.5 % weight

Softening point >=600 ºC

VOC less H2O & exempt solvents Not applicable.

SECTION 10: Stability and reactivity

10.1 Reactivity

This material is considered to be non reactive under normal use conditions


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10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

None known.

10.6 Hazardous decomposition products

Substance Condition

Oxides of sulphur. If Breakage Occurs

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient

classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be

reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be

present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be

relevant to the material as a whole.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose

and throat pain.

Skin contact

Mechanical skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.

Eye contact

Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Ingestion

May be harmful if swallowed.

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or

the data are not sufficient for classification.

Acute ToxicityName Route Species Value

Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg

Soda lime borosilicate glass Dermal LD50 estimated to be > 5,000 mg/kg


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Soda lime borosilicate glass Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/IrritationName Species Value

Soda lime borosilicate glass Professio

nal

judgemen

t

No significant irritation

Serious Eye Damage/IrritationName Species Value

Soda lime borosilicate glass Professio

nal

judgemen

t

No significant irritation

Skin Sensitisation

For the component/components, either no data are currently available or the data are not sufficient for classification.

Respiratory Sensitisation


Germ Cell MutagenicityName Route Value

Soda lime borosilicate glass In Vitro Some positive data exist, but the data are not

sufficient for classification

CarcinogenicityName Route Species Value

Soda lime borosilicate glass Inhalation Multiple

animal

species

Some positive data exist, but the data are not

sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects


Target Organ(s)

Specific Target Organ Toxicity - single exposure


Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test result Exposure

Duration

Soda lime borosilicate

glass

Inhalation respiratory system Some positive data exist, but the

data are not sufficient for

classification

Human NOAEL not

available

occupational

exposure

Aspiration Hazard


Please contact the address or phone number listed on the first page of the SDS for additional toxicological information

on this material and/or its components.


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SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient

classifications are mandated by a competent authority. Additional information leading to material classification in

Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be

reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not

expected to be available for exposure, or the data is considered not relevant to the material as a whole.

12.1. Toxicity

No product test data available.

Material CAS Number Organism Type Exposure Test endpoint Test result

Soda lime

borosilicate

glass

65997-17-3 Data not

available or

insufficient for

classification

12.2. Persistence and degradability

Material CAS Number Test type Duration Study Type Test result Protocol

Soda lime

borosilicate

glass

65997-17-3 Data not

available or

insufficient for

classification

N/A N/A N/A N/A

12.3 : Bioaccumulative potential

Material CAS Number Test type Duration Study Type Test result Protocol

Soda lime

borosilicate

glass

65997-17-3 Data not

available or

insufficient for

classification

N/A N/A N/A N/A

12.4. Mobility in soil

Please contact manufacturer for more details

12.5 Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1. Disposal methods

See Section 11.1 Information on toxicological effects

Contact your sales representative for information on reclaiming this product. Dispose of waste product in a permitted

industrial waste facility.

Packaging (that may or may not contain any residual substance) may be lawfully disposed of by householders or other

consumers through public or commercial waste collection services.

SECTION 14: Transport Information


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New Zealand Land Transport Rule: Dangerous Goods - Road/Rail Transport

UN No.: Not applicable.

Proper Shipping Name: Not applicable.

Class/Division: Not applicable.

Sub Risk: Not applicable.

Packing Group: Not applicable.

Hazchem Code:

IERG: Not applicable.

International Air Transport Association (IATA) - Air Transport






International Maritime Dangerous Goods Code (IMDG) - Marine Transport






Marine Pollutant: Not applicable.

SECTION 15: Regulatory information

HSNO Approval number HSR002503

Group standard name Additives, Intermediates, Process Chemicals and Raw Materials (Subsidiary Hazard) Group

Standard 2006

HSNO Hazard classification Refer to Section 2: Hazard identification

NZ Inventory of Chemicals (NZIoC) Status

This product is an article as defined by HSNO regulations, and is exempt from NZIoC listing requirements.

HSNO Controls

Approved handler test certificate Not required

Location and transit Depot certification test Not required

Hazardous atmosphere zone Not required

Fire extinguishers Not required

Emergency response plan 100 L or 100 kg (for a HSNO 9.1A substance); or 1,000 L or 1,000 kg (for a

HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance); or 10,000 L or 10,000 kg

(for a HSNO 6.6A, 6.8A, 6.9A, 8.3A, 9.1D substance)

Secondary containment 100 L or 100 kg (for a HSNO 9.1A substance); or 1,000 L or 1,000 kg (for a

HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance); or 10,000 L or 10,000 kg

(for a HSNO 6.6A, 6.8A, 6.9A, 8.3A, 9.1D substance)

Tracking Not required

Warning signage 100 L or 100 kg (for a HSNO 9.1A substance); or 1,000 L or 1,000 kg (for a

HSNO 8.3A, 9.1B or 9.1C substance); or 10,000 L or 10,000 kg (for a HSNO

6.1D or 9.1D substance)

SECTION 16: Other information


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Revision information:

Section 1: Product identification numbers information was modified.

Section 1: Product name information was modified.

Section 5: Fire - Extinguishing media information information was modified.

Section 8: Personal Protection - Skin/hand information information was modified.

Section 8: Skin protection - recommended gloves information information was deleted.

Section 8: Skin protection - recommended gloves text information was deleted.

Section 9: Property description for optional properties information was modified.

Section 10: Hazardous decomposition or by-products table information was modified.

Section 11: Aspiration Hazard text information was added.

Section 11: Health Effects - Ingestion information information was modified.

Section 11: Respiratory Sensitization text information was added.

Section 11: Serious Eye Damage/Irritation Table information was modified.

Section 11: Skin Corrosion/Irritation Table information was modified.

Section 11: Skin Sensitization text information was added.

Section 11: Specific Target Organ Toxicity - single exposure text information was added.

Prints No Data if Bioccumulative potential information is not present information was deleted.

Prints No Data if Persistence and Degradability information is not present information was deleted.

Section 14: Class/Div Group 2 information was added.

Section 14: IERG Group 1 information was added.

Section 14: IERG Group 2 information was added.

Section 14: Marine Pollutant Technical Name information was added.

Section 14: Packing Group Group 1 information was added.

Section 14: Packing Group Group 2 information was added.

Section 14: Special Instructions ADG Group 1 information was added.

Section 14: Special Instructions Group 2 information was added.

Section 14: Special Instructions IATA Group 1 information was added.

Section 14: Special Instructions IATA Group 2 information was added.

Section 14: Special Instructions IMDG Group 1 information was added.

Section 14: Special Instructions IMDG Group 2 information was added.

Section 14: Transport Class/Div Group 1 information was added.

Section 14: Transportation information information was deleted.

Section 14: Transportation Sub Risk Group 1 information was added.

Section 14: Transportation Sub Risk Group 2 information was added.

Section 14: UN Number IATA Group 1 information was added.

Section 14: UN Number IATA Group 2 information was added.

Section 14: UN Number information was added.

Section 14: UN Proper Shipping Name Group 1 information was added.

Section 14: UN Proper Shipping Name Group 2 information was added.

Section 14: UN Proper Shipping Name IATA Group 1 information was added.

Section 14: UN Proper Shipping Name IATA Group 2 information was added.

The information in this Safety Data Sheet (SDS) is believed to be correct as of the date of issue. TO THE EXTENT

PERMITTED BY LAW, 3M MAKES NO WARRANTY, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED

TO, ANY IMPLIED WARRANTY, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR

COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit

for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use

and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the

user evaluates the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or

application. 3M provides information in electronic form as a service to customers. Due to the remote possibility of electronic

transfer may have resulted in errors, omissions or alterations in this information; 3M makes no representations as to its

completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the

SDS available directly from 3M.

3M New Zealand SDS are available at 3M New Zealand Website: http://solutions.3mnz.co.nz


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SAFETY DATA SHEET

ACPC11340A

1 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : ACPC11340A

Other means of identification : Not applicable.

Recommended use : PARAFFIN AND/OR ASPHALTENE CHEMICAL

Restrictions on use : Refer to available product literature or ask your local Sales Representative for

restrictions on use and dose limits.

Company : Ecolab New Zealand T/A Nalco New Zealand 2 Daniel Place Te Rapa, Hamilton New Zealand TEL: +64 7 958 2319 FAX: +64 7 958 2361

Emergency telephone number

: 0800 625 253, +64 7 958 2372 (International)

Issuing date : 23.09.2018

Section: 2. HAZARDS IDENTIFICATION

HSNO Hazard classification

Flammable Liquids : 3.1 D Acute toxicity (Oral) : 6.1 E Skin irritation : 6.3 A Eye irritation : 6.4 A GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Combustible liquid

May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see supplemental first aid instructions on this label). Storage: Store in a well-ventilated place. Disposal:

SAFETY DATA SHEET

ACPC11340A


Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Concentration: (%)

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, < 2% aromatics

64742-48-9 60 - 100

Phosphoric ester salt Proprietary 10 - 30 2-Butoxyethanol 111-76-2 5 - 10

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists.

If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed - can enter lungs and cause damage. Get medical attention immediately.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Foam

Carbon dioxide Dry powder Other extinguishing agent suitable for Class B fires For large fires, use water spray or fog, thoroughly drenching the burning material.

Unsuitable extinguishing media

: None known.

Specific hazards during firefighting

: Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance.

Hazardous combustion products

: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Oxides of phosphorus

Special protective equipment for firefighters

: Use personal protective equipment.

SAFETY DATA SHEET

ACPC11340A


Specific extinguishing methods

: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up

: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Take necessary action to avoid static

electricity discharge (which might cause ignition of organic vapours). Keep away from fire, sparks and heated surfaces. Wash hands thoroughly after handling.

Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.

Suitable material : Keep in properly labelled containers.

Unsuitable material : not determined

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible concentration

Basis

2-Butoxyethanol 111-76-2 WES-TWA 25 ppm 121 mg/m3

NZ OEL

2-Butoxyethanol 111-76-2 TWA 20 ppm ACGIH

TWA 5 ppm 24 mg/m3

NIOSH REL

TWA 50 ppm 240 mg/m3

OSHA Z1

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below

occupational exposure standards. Personal protective equipment Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment: Standard glove type. Nitrile gloves

SAFETY DATA SHEET

ACPC11340A


Butyl gloves Breakthrough time: 1 – 4 hours Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : No personal respiratory protective equipment normally required.

Refer to AS/NZS 1715 and AS/NZS 1716 for selection, use and maintenance of respiratory protective equipment as applicable.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : clear colourless

Odour : hydrocarbon-like

Flash point : > 62 °C, Method: Pensky-Martens closed cup

pH : 5 - 6, (20 °C)

Odour Threshold : no data available

Melting point/freezing point : pour point: < -30 °C

Initial boiling point and boiling range

: 179 - 214 °C, Solvent

Evaporation rate : 0.04, (BuAc = 1) Based on solvent

Flammability (solid, gas) : no data available

Upper explosion limit : 6 V%, Based on solvent

Lower explosion limit : 0.7 V%

Vapour pressure : 30 - 93 hPa, Based on solvent

Relative vapour density : not determined

Relative density : 0.805 - 0.835, (20 °C),

Density : 0.803 - 0.834 g/cm3

Water solubility : emulsifiable

Solubility in other solvents : no data available

Partition coefficient: n-octanol/water

: Not applicable.

Auto-ignition temperature : 235 - 315 °C

Thermal decomposition : no data available

Viscosity, dynamic : < 10 mPa.s (20 °C)

Viscosity, kinematic : no data available

Molecular weight : no data available

VOC : no data available

SAFETY DATA SHEET

ACPC11340A


Section: 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions. Possibility of hazardous reactions

: No dangerous reaction known under conditions of normal use.

Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products

: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects Eyes : Causes serious eye irritation. Skin : Causes skin irritation. Ingestion : May be fatal if swallowed and enters airways. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Pain, Irritation Skin contact : Redness, Irritation Ingestion : Vomiting Inhalation : No symptoms known or expected. Toxicity Product

Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg

Acute inhalation toxicity : Acute toxicity estimate: > 40 mg/l Exposure time: 4 h Test atmosphere: vapour

Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg

Skin corrosion/irritation : no data available

Serious eye damage/eye irritation

: no data available

Respiratory or skin : no data available

SAFETY DATA SHEET

ACPC11340A


sensitization

Carcinogenicity : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive effects : No toxicity to reproduction

Germ cell mutagenicity : Contains no ingredient listed as a mutagen

Teratogenicity : no data available

STOT - single exposure : no data available

STOT - repeated exposure : no data available

Aspiration toxicity : May be fatal if swallowed and enters airways.

Human Hazard Characterization

Based on our hazard characterization, the potential human hazard is: High

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.

Product

Toxicity to fish : no data available

Toxicity to daphnia and other aquatic invertebrates

: no data available

Toxicity to algae : no data available

Components

Toxicity to fish : 2-Butoxyethanol LC50 : 1,474 mg/l Exposure time: 96 h

Components


: 2-Butoxyethanol EC50 : 690 mg/l Exposure time: 48 h

Components

Toxicity to algae : 2-Butoxyethanol EC50 : 911 mg/l Exposure time: 72 h

Components

Toxicity to bacteria : 2-Butoxyethanol 463 mg/l

Components

Toxicity to fish (Chronic toxicity)

: 2-Butoxyethanol NOEC: > 100 mg/l Exposure time: 21 d

SAFETY DATA SHEET

ACPC11340A


Components

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: 2-Butoxyethanol NOEC: > 100 mg/l Exposure time: 21 d

Persistence and degradability no data available Mobility no data available Bioaccumulative potential no data available Other information no data available ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low

Section: 13. DISPOSAL CONSIDERATIONS

Disposal methods : Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport Proper shipping name : PRODUCT IS NOT REGULATED DURING

TRANSPORTATION Air transport (IATA) Proper shipping name : PRODUCT IS NOT REGULATED DURING

TRANSPORTATION Sea transport (IMDG/IMO) Proper shipping name : PRODUCT IS NOT REGULATED DURING

TRANSPORTATION

Section: 15. REGULATORY INFORMATION

GROUP STANDARD NAME : Additives, Process Chemicals and Raw Materials

SAFETY DATA SHEET

ACPC11340A


(Combustible) Group Standard 2017 HSNO APPROVAL NUMBER

: HSR002490

INTERNATIONAL CHEMICAL CONTROL LAWS : United States TSCA Inventory This product contains a substance not found on the TSCA 8(b) Inventory List and can only be used under the TSCA 5(h)(3) Research Exemption. Use must be supervised by a technically qualified individual. Canadian Domestic Substances List (DSL) This product contains one or several components that are not on the Canadian DSL nor NDSL. Australia. Industrial Chemical (Notification and Assessment) Act Not in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. China Inventory of Existing Chemical Substances Not in compliance with the inventory

Section: 16. OTHER INFORMATION

Revision Date : 23.09.2018 Version Number : 1.1 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

SAFETY DATA SHEET

AS-5 ANTI-SLUDGING AGENT

Revision Date: 01-Jun-2018 Revision Number: 33

1. Identification

Product Name Product Trade Name: AS-5 ANTI-SLUDGING AGENT

Other Names Synonyms None

Hazardous Material Number: HM000078

Recommended Use Recommended Use Anti-sludging Agent

Uses advised against No information available

Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand

1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207

E-mail Address [email protected]

Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012

New Zealand National PoisonsCentre

0800 764 766 (24 hours)

2. Hazards Identification

Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA

Classification 3.1C Flammable Liquids - Medium hazard6.1D (Oral) Substances that are acutely toxic - Harmful6.3A Irritating to the skin8.3A Corrosive to ocular tissue9.1D Slightly harmful in the aquatic environment9.3C Harmful to terrestrial vertebrates

Hazard and Precautionary Statements

Hazard Pictograms

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_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018

Signal Word Danger

Hazard Statements H226 - Flammable liquid and vaporH302 - Harmful if swallowedH315 - Causes skin irritationH318 - Causes serious eye damageH401 - Toxic to aquatic lifeH433 - Harmful to the terrestrial vertebrates.

Precautionary Statements

Prevention P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignitionsources. No smoking.P233 - Keep container tightly closedP240 - Ground and bond container and receiving equipment.P241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take action to prevent static discharges.P264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protection

Response P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water [or shower].P370 + P378 - In case of fire: Use water spray for extinctionP301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP331 - Do NOT induce vomitingP302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Storage P403 + P235 - Store in a well-ventilated place. Keep cool

Disposal P501 - Dispose of contents/container to an approved incineration plant

Contains

Substances CAS Number Substance HSNO Classification

C10-C16 Alkylbenzenesulfonic acid 68584-22-5 Not applicable

Benzene, C10-16 alkyl derivatives 68648-87-3 Not applicable

Isopropanol 67-63-0 3.1B6.1E (oral)6.3B6.4A

Sulfuric acid 7664-93-9 6.1D (Inhalation6.1E (Oral)6.7A8.2B6.9A

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8.1A8.2B8.3A9.1C (Crustacean)9.1D (Fish)

2.3. Other Hazards None known

3. Composition/Information on Ingredients

Substances CAS Number PERCENT (w/w)C10-C16 Alkylbenzenesulfonic acid 68584-22-5 60 - 100%Benzene, C10-16 alkyl derivatives 68648-87-3 1 - 5%Isopropanol 67-63-0 10 - 30%Sulfuric acid 7664-93-9 1 - 5%

4. First Aid Measures

Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 30 minutes.Remove contact lenses after the first 5 minutes and continue washing. Seek immediatemedical attention/advice. Suitable emergency eye wash facility should be immediatelyavailable

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 30minutes and remove contaminated clothing, shoes and leather goods immediately. Getmedical attention immediately.

Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconsciousperson. Obtain immediate medical attention.

Workplace Facilities Required None

Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction. May causerespiratory irritation. May cause headache, dizziness, and other central nervous system effects. Harmful if swallowed.Carcinogen.

Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically

5. Fire-fighting measures

Type of Hazard Flammability HazardFlammable Liquid

5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.

Extinguishing media which must not be used for safety reasonsDo NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause splattering.

HAZCHEM Code Hazchem Code: 2YE

Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

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Special exposure hazards in a fire


Decomposition in fire may produce harmful gases.

6. Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use appropriate protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Removesources of ignition. Take precautionary measures against static discharges All equipment used when handling the productmust be grounded Avoid contact with skin, eyes and clothing.See Section 8 for additional information

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeledcontainers. Remove ignition sources and work with non-sparking tools.

6.4. Reference to other sections See Section 8 and 13 for additional information.

7. Handling and storage

7.1. Precautions for safe handling Handling PrecautionsDo not breathe dust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. Use appropriate protective equipment. Removesources of ignition. Ground and bond containers when transferring from one container to another. Avoid contact with eyes,skin, or clothing.

Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

Approved Handlers This product does NOT require an approved handler.

7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep from heat, sparks, and open flames.

Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 5 (oxidisers, organic peroxides)

Store Site Requirements No special controls required

Packaging No special packaging required

8. Exposure Controls/Personal Protection

Workplace Exposure Standards Exposure Limits

Substances CAS Number New Zealand WES ACGIH TLV-TWAC10-C16 Alkylbenzenesulfonicacid

68584-22-5 Not applicable Not applicable

Benzene, C10-16 alkylderivatives


Isopropanol 67-63-0 TWA: 400 ppmTWA: 983 mg/m3

STEL: 500 ppmSTEL: 1230 mg/m3

TWA: 200 ppmSTEL: 400 ppm

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Sulfuric acid 7664-93-9 TWA: 1 mg/m3 TWA: 0.2 mg/m3

Engineering Controls Engineering Controls Ensure adequate ventilation, especially in confined areas

Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the

selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.

Skin Protection Rubber apron. Wear impervious protective clothing, including boots, gloves, lab coat,apron, rain jacket, pants or coverall, as appropriate, to prevent skin contact.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties


Property Values Remarks/ - Method

pH: 0.98 - 1.98 (10% in 1:1 IPA:H2O)

Freezing Point / Range No data available

Melting Point / Range No data available

Boiling Point / Range No data available

Flash Point 35 °C / 95 °F PMCC

Evaporation rate No data available

Vapor Pressure No data available

Vapor Density No data available

Specific Gravity 0.998 - 1.023

Water Solubility Soluble in water

Solubility in other solvents No data available

Partition coefficient: n-octanol/water No data available

Autoignition Temperature No data available

Decomposition Temperature No data available

Viscosity No data available

Explosive Properties No information available

Oxidizing Properties No information available

9.2. Other information VOC Content (%) No data available

Liquid Density 8.32 - 8.53 lbs/gal

Bulk Density 998 - 1023 kg/m3

10. Stability and Reactivity

10.2. Chemical stability Stable

Physical State: Liquid Color Clear Light Amber to Dark Amber

Odor: Alcohol Odor Threshold: No information available

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10.4. Conditions to avoid Keep away from heat, sparks and flame.

10.5. Incompatible materials Strong oxidizers.


10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.

Hazardous Reactions Hazardous Polymerization: Will Not Occur

11. Toxicological Information

Health Effect from Likely Routes of Exposure Acute Toxicity

Product Information Under certain conditions of use, some of the product ingredients may cause thefollowing:

Inhalation May cause respiratory irritation. May cause central nervous system depression includingheadache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,giddiness and unconsciousness.

Eye Contact Causes serious eye damage.

Skin Contact Causes severe burns.

Ingestion Harmful if swallowed. Causes burns of the mouth, throat and stomach.

Chronic Effects/Carcinogenicity Contains known or suspected carcinogens.

Toxicity Data

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

C10-C16Alkylbenzenesulfonicacid

68584-22-5 530 mg/kg (Rat)775 mg/kg (Rat)

1350 mg/kg (Rat)1470 mg/kg (Rat) (similar

substance)

530 mg/kg (Rat)2000 mg/kg (Rabbit)

No data available


68648-87-3 >5000 mg/kg-bw (rat) 10200 mg/kg-bw (rabbit) 71 mg/L (rat, 4h, aerosol)(similar substance)

Isopropanol 67-63-0 5840 mg/kg-bw (rat) 12870 mg/kg-bw (rabbit) 72.6 mg/L (Rat, 4h, vapor)

Sulfuric acid 7664-93-9 2140 mg/kg-bw (rat) No data available No data available

Substances CASNumber

Skin corrosion/irritation

C10-C16Alkylbenzenesulfonic acid

68584-22-5 Skin, rabbit: Causes burns


68648-87-3 Non-irritating to the skin (Rabbit) (similar substances)

Isopropanol 67-63-0 Non-irritating to the skin (Rabbit)

Sulfuric acid 7664-93-9 Causes severe burns


Serious eye damage/irritation


68584-22-5 Eye, rabbit: Causes eye burns


68648-87-3 Non-irritating to the eye (Rabbit) (similar substances)

Isopropanol 67-63-0 Causes moderate eye irritation (Rabbit)

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Sulfuric acid 7664-93-9 Causes serious eye damage


Skin Sensitization


68584-22-5 Did not cause sensitization on laboratory animals (guinea pig)


68648-87-3 Did not cause sensitization on humans or laboratory animals. (guinea pig) (similar substances)

Isopropanol 67-63-0 Did not cause sensitization on laboratory animals (guinea pig)

Sulfuric acid 7664-93-9 Not regarded as a sensitizer.


Respiratory Sensitization


68584-22-5 No information available



Isopropanol 67-63-0 No information available

Sulfuric acid 7664-93-9 Based on available data, the classification criteria are not met.


Mutagenic Effects


68584-22-5 In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects.


68648-87-3 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects

Isopropanol 67-63-0 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.



Carcinogenic Effects





Isopropanol 67-63-0 Did not show carcinogenic effects in animal experiments

Sulfuric acid 7664-93-9 This substance is a potential carcinogen. (IARC 1).


Reproductive toxicity


68584-22-5 No data of sufficient quality are available.



Isopropanol 67-63-0 Animal testing did not show any effects on fertility.

Sulfuric acid 7664-93-9 Did not show teratogenic effects in animal experiments.


STOT - single exposure


68584-22-5 May cause respiratory irritation.



Isopropanol 67-63-0 May cause headache, dizziness, and other central nervous system effects.

Sulfuric acid 7664-93-9 May cause respiratory irritation.


STOT - repeated exposure





Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)

Sulfuric acid 7664-93-9 Not applicable due to corrosivity of the substance.


Aspiration hazard


68584-22-5 Not applicable



Isopropanol 67-63-0 Not applicable

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12. Ecological Information

12.1. Toxicity Ecotoxicity effectsVery toxic to aquatic life. Harmful to aquatic life with long lasting effects.

Product Ecotoxicity DataNo data available

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms

Toxicity toInvertebrates

C10-C16Alkylbenzenesulfonicacid

68584-22-5 EC50 (96h) 170 mg/L(Selenastrum

capricornutum)

LC50 (96h) 3 mg/L(Oncorhynchus mykiss)NOEC (90d) 0.25 mg/L(Tilapia mossambica)

(similar substance)

No information available EC50 (48h) 2.9 mg/L(Daphnia magna)

EC50 (24h) 5.9 mg/L(Daphnia magna)

Benzene, C10-16alkyl derivatives

68648-87-3 EC50 (96 h) >1000 mg/L(Pseudokirchneriella

subcapitata)

LC50 (96h) >1000 mg/L(Oncorhynchus mykiss)

No information available EC50 (48h) 0.01 mg/L(Daphnia magna)

MATC (21d) 0.075 mg/L(Daphnia magna)

Isopropanol 67-63-0 EC50 (72h) > 1000 mg/L(Desmodesmus

subspicatus)EC50 (7d) 1800 mg/L

(meanextinctionvalue)(Scenedesmus

quadricauda)

LC50 (96h) 9640 mg/L(Pimephales promelas)LC50 (7d) 7060 mg/L(Poecilia reticulata)

TT (16h) 1050 mg/L(Pseudomonas putida)

EC50 (48 h)=2285 mg/L(Daphnia sp.)

EC50 (24h) > 10,000mg/L (Daphnia magna)

Sulfuric acid 7664-93-9 No information available LC50 (96 h) 16 mg/L(Lepomis macrochirus)LC50 (96 h) 42 mg/L(Gambusia affinis)

No information available EC50 (24 h) 29 mg/L(Daphnia magna)

EC50 (48 h) 42.5 mg/L(Pandalus montagui)


Substances CAS Number Persistence and Degradability

C10-C16 Alkylbenzenesulfonic acid 68584-22-5 (94% @ 28d)

Benzene, C10-16 alkyl derivatives 68648-87-3 Readily biodegradable (60% @ 28d)

Isopropanol 67-63-0 Readily biodegradable (53% @ 5d)

Sulfuric acid 7664-93-9 Readily biodegradable

12.3. Bioaccumulative potential

Substances CAS Number Log Pow

C10-C16 Alkylbenzenesulfonic acid 68584-22-5 Log Pow = 4.15

Benzene, C10-16 alkyl derivatives 68648-87-3 7.94BCF = 35

Isopropanol 67-63-0 Not Bioaccumulative; LogPow < 4.5

Sulfuric acid 7664-93-9 No data available


Substances CAS Number Mobility

C10-C16 Alkylbenzenesulfonic acid 68584-22-5 No information available

Benzene, C10-16 alkyl derivatives 68648-87-3 No information available

Isopropanol 67-63-0 No information available

Sulfuric acid 7664-93-9 No information available

Ecotoxicity Hazard Statements Toxic to aquatic lifeHarmful to terrestrial vertebrates.

12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors

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13. Disposal Considerations


13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Contaminated packaging may be disposed of by: rendering packaging incapable ofcontaining any substance, or treating packaging to remove residual contents, or treatingpackaging to make sure the residual contents are no longer hazardous, or by disposingof packaging into commercial waste collection.

14. Transport Information

NZ 5433.1999 UN Number UN2924

UN proper shipping name: Flammable Liquid, Corrosive, N.O.S. (Contains Isopropanol, DodecylbenzenesulfonicAcid)

Transport Hazard Class(es): 3 (8)

Packing Group: III

Environmental Hazards: Marine Pollutant

IMDG/IMO UN Number UN2924


Transport Hazard Class(es): 3 (8)

Packing Group: III


EMS: EmS F-E, S-C

IATA/ICAO UN Number UN2924


Transport Hazard Class(es): 3 (8)Packing Group: III


Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

Special Precautions for User None

15. Regulatory Information

New Zealand Inventory ofChemicals

All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.

HSNO Approval Number HSR002495

Group Name Additives, Process Chemicals and Raw Materials (Flammable HSR002495)

HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz


Poisons Schedule: None Allocated

16. Other information

Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.

For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.

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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%


LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID

Revision Date: 01-Jun-2018

Revision NoteSDS sections updated:1

Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.

End of Safety Data Sheet

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SAFETY DATA SHEET

BARACARB® 50

1. Product and Company Identification

Product Name Product Trade Name: BARACARB® 50

Other Names Synonyms: None

Product Code: HM003488

Recommended Use Recommended Use Bridging Agent

Uses Advised Against No information available



E-Mail address: [email protected]

Emergency Telephone Number +64-6-7559274


0800 764 766 (24 hours)

2. Hazard(s) Identification

Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA

Classification 6.4A Irritating to the eye6.7A Known or presumed human carcinogens6.9A Toxic to human target organs or systems


Hazard Pictograms

Signal Word Danger

Hazard Statements H319 - Causes serious eye irritationH350 - May cause cancer by inhalation


Prevention P103 - Read label before useP104 - Read Safety Data Sheet before use.

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_____________________________________________________________________________________________P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing/eye protection/face protectionP281 - Use personal protective equipment as required

Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attentionP308 + P313 - IF exposed or concerned: Get medical advice/attention

Storage P405 - Store locked up

Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations

Contains


Calcium carbonate 471-34-1 6.4A

Crystalline silica, quartz 14808-60-7 6.7A6.9A

2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

3. Composition and Information on Ingredients

Substances CAS Number PERCENT (w/w)

Calcium carbonate 471-34-1 60 - 100%

Crystalline silica, quartz 14808-60-7 0.1 - 1%

4. First-Aid Measures



Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.

Skin Wash with soap and water. Get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.


Relation to Health Effect Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also beenassociated with scleroderma and kidney disease.



Type of Hazard Flammability HazardNon-flammable

5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media

Extinguishing media which must not be used for safety reasons

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BARACARB® 50 Revision Date: 26-Jun-2015

_____________________________________________________________________________________________None known.

HAZCHEM Code Hazchem Code: None Allocated

Special Protective Equipment and Precautions for Fire Fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

Special Exposure HazardsNot applicable.

6. Spillage, Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.See Section 8 for additional information


6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.



7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. This product contains quartz, cristobalite, and/ortridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use onlywith adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European StandardEn 149, or equivalent respirator when using this product. Material is slippery when wet.


Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present when the substance is being handled andwhen not in use, the substance must be locked away.

7.2. Conditions for safe storage, including any incompatibilities Store away from acids. Store in a cool, dry location. Use good housekeeping in storage and work areas to preventaccumulation of dust. Close container when not in use. Do not reuse empty container. Product has a shelf life of 60 months.



8. Exposure Controls and Personal Protection


Substances CAS Number New Zealand WES ACGIH TLV-TWA

Calcium carbonate 471-34-1 TWA: 10 mg/m3 10 mg/m3

Crystalline silica, quartz 14808-60-7 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3

Engineering Controls Engineering Controls Use in a well ventilated area. Use approved industrial ventilation and local exhaust as

required to maintain exposures below applicable exposure limits.

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_____________________________________________________________________________________________

Personal Protective Equipment (PPE) Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, or

equivalent respirator when using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be launderedbefore reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.





pH: 8-9

Freezing Point/Range No data available

Melting Point/Range No data available

Boiling Point/Range No data available

Flash Point No data available




Specific Gravity 2.7

Water Solubility Insoluble in water










10.2. Chemical Stability Stable

10.4. Conditions to Avoid None anticipated

10.5. Incompatible Materials Strong acids.

10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated temperatures to tridymite (870 C) orcristobalite (1470 C).




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Odorless


Odor Threshold: No information availablePhysical State: Solid Powder Color: White

BARACARB® 50

Odor:

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Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources iscarcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).

Eye Contact May cause mechanical irritation to eye.

Skin Contact May cause mechanical skin irritation.

Ingestion None known.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis. Symptomsinclude cough, shortness of breath, wheezing, non-specific chest illness, and reducedpulmonary function. This disease is exacerbated by smoking. Individuals with silicosisare predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimental animals forthe carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer toIARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) inconjunction with the use of these minerals. The National Toxicology Program classifiesrespirable crystalline silica as "Known to be a human carcinogen". Refer to the 9thReport on Carcinogens (2000). The American Conference of Governmental IndustrialHygienists (ACGIH) classifies crystalline silica, quartz, as a suspected humancarcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease silicosisis associated with an increased incidence of significant disease endpoints such asscleroderma (an immune system disorder manifested by scarring of the lungs, skin, andother internal organs) and kidney disease.

Toxicity Data



Calcium carbonate 471-34-1 6450 mg/kg (Rat)> 2000 mg/kg (Rat)

> 2000 mg/kg (Rat) > 3 mg/L (Rat) 4h

Crystalline silica, quartz 14808-60-7 >15,000 mg/kg (Human) No data available No data available



Calcium carbonate 471-34-1 Non-irritating to the skin (Rabbit)

Crystalline silica, quartz 14808-60-7 Non-irritating to the skin


Eye damage/irritation

Calcium carbonate 471-34-1 Non-irritating to the eye (Rabbit)

Crystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible.


Skin Sensitization

Calcium carbonate 471-34-1 Did not cause sensitization on laboratory animals (mouse)

Crystalline silica, quartz 14808-60-7 No information available.



Calcium carbonate 471-34-1 No information available

Crystalline silica, quartz 14808-60-7 No information available


Mutagenic Effects

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_____________________________________________________________________________________________Calcium carbonate 471-34-1 In vitro tests did not show mutagenic effects

Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.



Calcium carbonate 471-34-1 No information available.

Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondaryto lung injury.



Calcium carbonate 471-34-1 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.




Calcium carbonate 471-34-1 No significant toxicity observed in animal studies at concentration requiring classification.

Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.



Calcium carbonate 471-34-1 No significant toxicity observed in animal studies at concentration requiring classification.

Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)


Aspiration hazard

Calcium carbonate 471-34-1 Not applicable

Crystalline silica, quartz 14808-60-7 Not applicable


12.1. Toxicity Ecotoxicity Effects





Calcium carbonate 471-34-1 EC50(72h): > 14 mg/L(growth rate)

(Desmodesmussubspicatus)

LC50(96h): > 100 mg/L(saturated solution)

(Oncorhynchus mykiss)

EC50(3h): > 1000 mg/L(Activated sludge)

EC50(48h): > 100 mg/L(saturated solution)(Daphnia magna)

Crystalline silica,quartz

14808-60-7 No information available LL0 (96h) 10,000 mg/L(Danio rerio) (similar

substance)

No information available LL50 (24h) > 10,000mg/L (Daphnia magna)

(similar substance)



Calcium carbonate 471-34-1 The methods for determiningbiodegradability are not applicable toinorganic substances.




Calcium carbonate 471-34-1 No data available

Crystalline silica, quartz 14808-60-7 No data available


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_____________________________________________________________________________________________Substances CAS Number Mobility

Calcium carbonate 471-34-1 No information available


Ecotoxicity Hazard Statements None known



13.1. Waste treatment methods Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.


IMDG/IMO UN Number: Not restricted

UN Proper Shipping Name: Not restricted

Transport Hazard Class(es): Not applicable

Packing Group: Not applicable

Environmental Hazards: Not applicable

NZ 5433.1999 UN Number: Not restricted




IATA/ICAO UN Number: Not restricted




Special Precautions for User: None

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable



All components listed on inventory or are exempt.


Group Name Additives, Process Chemicals and Raw Materials (Toxic 6.7 HSR002512)


Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present whenthe substance is being handled and when not in use, the substance must be lockedaway.



The following sections have been revised since the last issue of this SDSNot applicable

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Revision Date: 26-Jun-2015BARACARB® 50

_____________________________________________________________________________________________





Revision Note Revision NoteSDS sections updated:2



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Revision Date: 26-Jun-2015BARACARB® 50

SAFETY DATA SHEET

BARACOR® 100

Revision Date: 14-Jul-2016 Revision Number: 53


Product Name Product Trade Name: BARACOR® 100



Recommended Use Recommended Use Corrosion Inhibitor





Emergency Telephone Number: +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012


0800 764 766 (24 hours)



Classification 3.1C Flammable Liquids - Medium hazard6.1D (Oral) Acutely Toxic Substances6.1D (Dermal) Acutely Toxic Substances8.2C Corrosive to dermal tissue if exposed for greater than 1 hour8.3A Corrosive to ocular tissue6.7B Suspected human carcinogens6.9A Toxic to human target organs or systems9.3C Harmful to terrestrial vertebrates


Hazard Pictograms

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_____________________________________________________________________________________________BARACOR® 100 Revision Date: 14-Jul-2016

Signal Word Danger

Hazard Statements H226 - Flammable liquid and vaporH302 - Harmful if swallowedH312 - Harmful in contact with skinH314 - Causes severe skin burns and eye damageH318 - Causes serious eye damageH351 - Suspected of causing cancerH361 - Suspected of damaging fertility or the unborn childH370 - Causes damage to organsH433 - Harmful to the terrestrial vertebrates.


Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP210 - Keep away from heat/sparks/open flames/hot surfaces. - No smokingP233 - Keep container tightly closedP240 - Ground/Bond container and receiving equipmentP241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take precautionary measures against static dischargeP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required

Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP331 - Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water/showerP363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a positioncomfortable for breathingP310 - Immediately call a POISON CENTER or doctor/physicianP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing

Storage P403 + P235 - Store in a well-ventilated place. Keep coolP405 - Store locked up


Contains


Ethanol, 2,2'-oxybis-, reaction products withammonia, morpholine derivatives residues

68909-77-3 6.1D (oral)8.2C 8.3A

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9.3C

Methanol 67-56-1 3.1B6.1C (Oral)6.1C (Dermal)6.1C (Inhalation)6.4A6.8B6.9A (Inhalation)9.3C

Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 6.1D (oral)6.1E (inhalation)6.7B8.2C8.3A; 9.3C

2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).


Substances CAS Number PERCENT (w/w)Ethanol, 2,2'-oxybis-, reaction products with ammonia,morpholine derivatives residues

68909-77-3 10 - 30%

Methanol 67-56-1 10 - 30%Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 1 - 5%


Requirements for First Aid or Medical Care Inhalation If inhaled, move victim to fresh air and seek medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek promptmedical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention. Remove contaminated clothing and launder beforereuse.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.


Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Harmful ifswallowed. Potential carcinogen. Potential reproductive hazard. May cause birth defects. May cause damage to internalorgans.



Type of Hazard Flammability HazardFlammable Liquid


Extinguishing media which must not be used for safety reasonsNone known.

HAZCHEM Code

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Hazchem Code: 3WE


Special exposure hazards in a fireMay be ignited by heat, sparks or flames Use water spray to cool fire exposed surfaces. Closed containers may explode in fire.Decomposition in fire may produce harmful gases. Runoff to sewer may cause fire or explosion hazard.


6.1. Personal precautions, protective equipment and emergency procedures Remove sources of ignition. Use appropriate protective equipment. Wear self-contained breathing apparatus in enclosedareas. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Evacuate all personsfrom the area.See Section 8 for additional information

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. Consult local authorities.

6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Remove ignition sources and work with non-sparking tools. Contain spill with sand orother inert materials. Scoop up and remove.



7.1. Precautions for safe handling Handling PrecautionsRemove sources of ignition. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation.Wash hands after use. Launder contaminated clothing before reuse. Ground and bond containers when transferring from onecontainer to another. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Product has ashelf life of 24 months.

Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 6 (toxic)





Substances CAS Number New Zealand WES ACGIH TLV-TWAEthanol, 2,2'-oxybis-, reaction 68909-77-3 Not applicable Not applicable

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products with ammonia,morpholine derivativesresidues

Methanol 67-56-1 TWA: 200 ppmTWA: 262 mg/m3

STEL: 250 ppmSTEL: 328 mg/m3

TWA: 200 ppmSTEL: 250 ppm

Nitrilotriacetic acid, trisodiumsalt monohydrate


Engineering Controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without

good cross ventilation.

Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Neoprene gloves. Nitrile gloves. Butyl rubber gloves. (>= .? mmthickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.

Skin Protection Rubber apron.







pH: 9-11

Freezing Point / Range -23 °C


Boiling Point / Range 100 °C / 212 °F


Upper flammability limit 36%

Lower flammability limit 6%

Evaporation rate 1.6


Vapor Density > 1




Partition coefficient: n-octanol/water -0.84






9.2. Other information

Physical State: Liquid Color Brown

Odor: Alcohol Odor Threshold: No information available

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VOC Content (%) No data available





Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 6 (toxic)

10.6. Hazardous decomposition products Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.




Inhalation May cause respiratory irritation. May cause central nervous system depression includingheadache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,giddiness and unconsciousness.

Eye Contact Causes severe eye irritation which may damage tissue.

Skin Contact Causes skin irritation. May cause an allergic skin reaction. May be absorbed through theskin.

Ingestion Harmful if swallowed.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart, centralnervous system and spleen damage. Contains nitrilotriacetic acid or its salts, which isNTP Classification 2 (Reasonably Anticipated to be a Human Carcinogen) and IARCClassification 2B (a Possible Human Carcinogen)Prolonged or repeated exposure may cause embryo and fetus toxicity.

Toxicity Data



Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues

68909-77-3 3816 mg/kg-bw (rat) > 2000 mg/kg (Rat) No toxicity at saturation (rat, 8 h,vapour)

Methanol 67-56-1 300 mg/kg-bw (human)< 790 to 13,000 mg/kg (rat)

1000 mg/kg-bw (human)17,100 mg/kg (rabbit)

10 mg/L (human, vapor, 4h)

Nitrilotriacetic acid,trisodium saltmonohydrate

5064-31-3 1740 mg/kg (Rat) > 2000 mg/kg (Rabbit) > 5 mg/L (Rat, Aerosol, 4h)




68909-77-3 Causes moderate skin irritation. (Rabbit) Skin, rabbit:

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Methanol 67-56-1 Non-irritating to the skin (Rabbit)

Nitrilotriacetic acid,trisodium salt monohydrate

5064-31-3 Non-irritating to the skin (Rabbit) Not irritating to skin in rabbits. Skin, rabbit:




68909-77-3 Causes eye burns Causes severe eye irritation. Will damage tissue.

Methanol 67-56-1 Non-irritating to the eye (Rabbit)


5064-31-3 Irritating to eyes (Rabbit) Eye, rabbit: Causes moderate eye irritation


Skin Sensitization


68909-77-3 May cause sensitization by skin contact (mouse)

Methanol 67-56-1 Did not cause sensitization on laboratory animals (guinea pig)







Methanol 67-56-1 No information available




Mutagenic Effects


68909-77-3 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Methanol 67-56-1 The weight of evidence from available in vitro and in vivo studies indicates that this substance is notexpected to be mutagenic.


5064-31-3 Not regarded as mutagenic. In vivo tests did not show mutagenic effects. In vitro tests did not showmutagenic effects





Methanol 67-56-1 No data of sufficient quality are available.


5064-31-3 Contains nitrilotriacetic acid or its salts, which is listed as a suspect carcinogen of the urinary tractand kidneys by NTP, based on feeding studies with laboratory animals. According to the ACGIHguidelines, NTA would "not be considered an occupational carcinogen of any significance." IARCcancer review classification: 2B (Possibly Carcinogenic to Humans)Available data indicate that this substance is a suspected carcinogen.




68909-77-3 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.

Methanol 67-56-1 Experiments have shown reproductive toxicity effects on laboratory animals






68909-77-3 No significant toxicity observed in animal studies at concentration requiring classification.

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Methanol 67-56-1 May cause disorder and damage to the Central Nervous System (CNS)







Methanol 67-56-1 No data of sufficient quality are available.




Aspiration hazard



Methanol 67-56-1 Not applicable




12.1. Toxicity Ecotoxicity effects






68909-77-3 EC50 (72 h) =100 mg/L(Skeletonema costatum)EC50 (72 h) >120 mg/L


NOEC (72 h) >120 mg/L(Desmodesmus

subspicatus)

LC50 (96 h) >100 mg/L(Scophthalmus

maximus)LC50 (96 h) =681.1 mg/L

(Leuciscus idus)

EC50 (3h) > 1000 mg/L(activated sludge)

LC50 (48 h) =287.2 mg/L(Acartia tonsa)

EC50 (48 h) >120 mg/L(Daphnia Magna)

Methanol 67-56-1 EC50 (96 h) =22000mg/L

(Pseudokirchnerellasubcapitata)

NOEC (8 d) =8000 mg/L(Scenedesmusquadricauda)

LC50 (96 h) =15400mg/L (Lepomismacrochirus)

EC50 (200 h) =14536mg/L (Oryzias latipes)

IC50 (3h) > 1000 mg/L(activated sludge)

EC50 (96 h) =18260mg/L (Dapnia magna)

NOEC (21 d) =208 mg/L(Dapnia magna)

Nitrilotriacetic acid,trisodium saltmonohydrate

5064-31-3 EC50 (72 h) >91.5 mg/L(Desmodesmus

subspicatus)

TL50 (96 h) =103 mg/L(Pimephales promelas)NOEC (229 d) >54 mg/L(Pimephales promelas)

NOEC (90d) >200 mg/L(activated sludge)

TL50 (96 h) range115mg/L (Gammaruspseudolimnaeus)

NOEC (147 d) =9.3 mg/L(Gammarus

pseudolimnaeus)

12.2. Persistence and degradability Not readily biodegradableSubstances CAS Number Persistence and Degradability

Ethanol, 2,2'-oxybis-, reaction products withammonia, morpholine derivatives residues

68909-77-3

Methanol 67-56-1 (95-97% @ 20d)

Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 Readily biodegradable (100% @ 14d)Marine water Persistent (6% @ 28d)

12.3. Bioaccumulative potential Does not bioaccumulate.


Ethanol, 2,2'-oxybis-, reaction products with 68909-77-3 Log Pow <1

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ammonia, morpholine derivatives residues

Methanol 67-56-1 -0.77BCF = 1.0 – 4.5 (Cyprinus carpio)

BCF < 10 (Leuciscus idus melanotus)

Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 -2.62 (calculated)



Ethanol, 2,2'-oxybis-, reaction products with ammonia,morpholine derivatives residues


Methanol 67-56-1 No information available

Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 No information available








UN proper shipping name: Flammable Liquid, N.O.S. (Contains Methanol)

Transport Hazard Class(es): 3

Packing Group: III


EMS: EmS F-E, S-E




Packing Group: III




Packing Group: III







Group Name Flammable, Corrosive, Toxic [6.7] (HSR002497)


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Approved Handlers Not Applicable

Poisons Schedule: S6




Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day


Revision Date: 14-Jul-2016




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SAFETY DATA SHEET

BARA-DEFOAM® HP

Revision Date: 11-Feb-2016 Revision Number: 17


Product Name Product Trade Name: BARA-DEFOAM® HP



Recommended Use Recommended Use Defoamer





Emergency Telephone Number +64 800 451719


0800 764 766 (24 hours)



Classification 6.1D (Oral) Acutely Toxic Substances6.4A (mild irritant) Irritating to the eye9.3C Harmful to terrestrial vertebrates


Hazard Pictograms

Signal Word Warning

Hazard Statements H302 - Harmful if swallowedH320 - Causes mild eye irritationH433 - Harmful to the terrestrial vertebrates.


Prevention P101 - If medical advice is needed, have product container or label at hand

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_____________________________________________________________________________________________BARA-DEFOAM® HP Revision Date: 11-Feb-2016

P102 - Keep out of reach of childrenP103 - Read label before useP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this product

Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention

Storage None


Contains


Oxylated polyether polyol Proprietary 6.4A

Polyether polyol Proprietary 6.1D (Oral)6.4A9.3C



Substances CAS Number PERCENT (w/w)Oxylated polyether polyol Proprietary 10 - 30%Polyether polyol Proprietary 60 - 100%





Skin Wash with soap and water. Get medical attention if irritation persists. Removecontaminated clothing and launder before reuse.



Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.




5.1. Extinguishing media

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Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.





Special Exposure HazardsAvoid spraying water directly into storage containers due to danger of boilover. Decomposition in fire may produce harmfulgases.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.See Section 8 for additional information


6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.



7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Keep floors clean of spills.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep container closed when not in use. Product has a shelf life of 36 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWAOxylated polyether polyol Proprietary Not applicable Not applicable

Polyether polyol Proprietary Not applicable Not applicable

Engineering Controls Engineering Controls Use in a well ventilated area.


selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of this

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product.

Respiratory Protection Not normally necessary.


Skin Protection Normal work coveralls.







pH: No data available

Freezing Point/Range -15 °C


Boiling Point/Range No data available

Flash Point > 182 °C / > 357 °F PMCC


Vapor Pressure < 0.01 mmHg

Vapor Density > 1

Specific Gravity 1












10.4. Conditions to Avoid Keep away from heat, sparks and flame.

10.5. Incompatible Materials Strong oxidizers. Isocyanates. Strong acids.

10.6. Hazardous Decomposition Products Aldehydes. Ketones. Organic acid vapors. Hydrocarbons. Carbon monoxide and carbon dioxide.




Inhalation Heated vapors may cause respiratory irritation.

Eye Contact May cause mild eye irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.


Physical State: Liquid Color: Clear colorless to pale yellow

Odor: Mild sweet Odor Threshold: No information available

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Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.

Toxicity Data



Oxylated polyetherpolyol

Proprietary No data available No data available No data available

Polyether polyol Proprietary > 5000 mg/kg (Rat) (similarsubstances)

> 3000 mg/kg (Rabbit) > 2.34 mg/L (Rat) (similarsubstances)







Oxylated polyetherpolyol

Proprietary No information available No information available No information available No information available

Polyether polyol Proprietary No information available LC50: > 100 mg/l(Poecilia reticulata)

No information available EC50: > 100 mg/l(Daphnia magna)



Oxylated polyether polyol Proprietary

Polyether polyol Proprietary Readily biodegradable



Oxylated polyether polyol Proprietary No data available

Polyether polyol Proprietary 0.3 - 1.13



Oxylated polyether polyol Proprietary No information available

Polyether polyol Proprietary No information available



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13.1. Waste treatment methods Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.



















All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.


Group Name Additives, Process Chemicals and Raw Materials (Subsidiary hazard HSR002503)








Key or legend to abbreviations and acronymsbw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% MARPOL – International Convention for the Prevention of Pollution fromShips mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – OccupationalExposure Limit ppm – parts per million TWA – Time-Weighted Average VOC – Volatile Organic Carbon C - Celsius IATA/ICAO- International Air Transport Association / International Civil Aviation Organization IMDG/IMO - International MaritimeDangerous Goods / International Maritime Organization mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimetermercury w/w - weight/weight d - day

_____________________________________________________________________________________________

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Revision Date: 11-Feb-2016




_____________________________________________________________________________________________

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SAFETY DATA SHEET

BARAKLEAN®-926


1. Identification

Product Name Product Trade Name: BARAKLEAN®-926



Recommended Use Recommended Use Cleaner

Uses advised against Consumer use






0800 764 766 (24 hours)



Classification 3.1D Flammable Liquids - Low hazard6.1E (Oral) Acutely Toxic Substances6.1E (Aspiration Hazard) Acutely Toxic Substances6.3A Irritating to the skin6.9B Harmful to human target organs or systems8.3A Corrosive to ocular tissue


Hazard Pictograms

Signal Word Danger

Hazard Statements H227 - Combustible liquidH303 - May be harmful if swallowed

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_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018

H304 - May be fatal if swallowed and enters airwaysH315 - Causes skin irritationH318 - Causes serious eye damageH373 - May cause damage to organs through prolonged or repeated exposure


Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignitionsources. No smoking.P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing/eye protection/face protection

Response P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physicianP331 - Do NOT induce vomitingP302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP314 - Get medical attention/advice if you feel unwellP370 + P378 - In case of fire: Use CO2, dry chemical, or foam

Storage P403 + P235 - Store in a well-ventilated place. Keep coolP405 - Store locked up


Contains


Hydrocarbons, C10-14 (even numbered),n-alkanes, isoalkanes, <2% aromatic

1174522-27-0 6.1E (asp)3.1D

Diethylene glycol monobutyl ether 112-34-5 3.1D6.1E (oral)6.1E (Dermal)6.3B6.4A6.9B (oral, Inhalation)

2-Ethyl hexanol 104-76-7 3.1D6.1D (Oral)6.1D (Dermal)6.1D (Inhalation)6.3A6.4A9.1D (Fish, Crustacean, Algae)9.3C

Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-

160875-66-1 6.1E (oral)6.1E (dermal)6.3A8.3A9.1C



Substances CAS Number PERCENT (w/w)Hydrocarbons, C10-14 (even numbered), n-alkanes,isoalkanes, <2% aromatic

1174522-27-0 60 - 100%

Diethylene glycol monobutyl ether 112-34-5 10 - 30%2-Ethyl hexanol 104-76-7 5 - 10%Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-

160875-66-1 5 - 10%

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Eyes In case of contact, immediately flush eyes with plenty of water for at least 30 minutes.Remove contact lenses after the first 5 minutes and continue washing. Seek immediatemedical attention/advice. Suitable emergency eye wash facility should be immediatelyavailable

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention.

Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconsciousperson. Obtain immediate medical attention.


Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. Aspiration into the lungs may cause chemicalpneumonitis including coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. May beharmful if swallowed May cause damage to organs through prolonged or repeated exposure

Medical Attention and Special Treatment Notes to PhysicianAspiration may cause severe lung damage. Evacuate stomach in a way which avoids aspiration.


Type of Hazard Flammability HazardCombustible liquid


Extinguishing media which must not be used for safety reasonsDo NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause splattering.



Special exposure hazards in a fireDecomposition in fire may produce harmful gases.


6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use appropriate protective equipment. Remove sources of ignition. Take precautionary measuresagainst static discharges All equipment used when handling the product must be grounded Avoid contact with skin, eyes andclothing.See Section 8 for additional information


6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeledcontainers. Remove ignition sources and work with non-sparking tools.

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6.4. Reference to other sections


See Section 8 and 13 for additional information.


7.1. Precautions for safe handling Handling PrecautionsEnsure adequate ventilation. Use appropriate protective equipment. Remove sources of ignition. Ground and bond containerswhen transferring from one container to another. Avoid contact with eyes, skin, or clothing.



7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep from heat, sparks, and open flames.






Substances CAS Number New Zealand WES ACGIH TLV-TWAHydrocarbons, C10-14 (evennumbered), n-alkanes,isoalkanes, <2% aromatic


Diethylene glycol monobutylether

112-34-5 Not applicable TWA: 10 ppm

2-Ethyl hexanol 104-76-7 Not applicable Not applicable



Engineering Controls Engineering Controls Ensure adequate ventilation, especially in confined areas




Hand Protection Use gloves which are suitable for the chemicals present in this product as well as otherenvironmental factors in the workplace.

Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket,pants or coverall, as appropriate, to prevent skin contact.

Eye Protection Safety glasses with side-shields. If splashes are likely to occur, wear: Goggles,

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Face-shield.






pH: 7.31




Flash Point 82.2 °C / 179.9 °F




Specific Gravity 0.833 at 68F

Water Solubility Dispersible Emulsifies





Viscosity 2.4 cSt







10.5. Incompatible materials Strong oxidizers. Strong acids. Strong alkalis.


10.6. Hazardous decomposition products Carbon oxides.




Inhalation May cause mild respiratory irritation.


Skin Contact Causes skin irritation.

Physical State: Liquid Color Clear colorless to pale yellow

Odor: Pungent Odor Threshold:

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No information available


Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing, difficultybreathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Toxicity Data



Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes,<2% aromatic

1174522-27-0

>2000 mg/kg-bw (rat)(similarsubstance)

>2000 mg/kg-bw (rat)(similarsubstance)

>5.3 mg/L (rat, 4h, aerosol)(similar substance)

Diethylene glycolmonobutyl ether

112-34-5 6560 mg/kg (rat) 2764 mg/kg (Rabbit) >29 ppm (rat, 2h, aerosol)

2-Ethyl hexanol 104-76-7 > 2000 mg/kg 1980 mg/kg 1.45 mg/L (rat, mist, 4h)


160875-66-1 >2000-5000 mg/kg-bw (rat) >2000-5000 mg/kg-bw (rabbit) >0.22 mg/L (rat, 4h, aerosol)(similar substances)



Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic

1174522-27-0

Not irritating to skin in rabbits. (similar substances)


112-34-5 Mild skin irritation (Rabbit)

2-Ethyl hexanol 104-76-7 Causes moderate skin irritation. (Rabbit)


160875-66-1 Causes moderate skin irritation. (similar substances)




1174522-27-0

(Rabbit) (similar substances) No eye irritation


112-34-5 Causes moderate eye irritation (Rabbit)

2-Ethyl hexanol 104-76-7 Causes moderate eye irritation (Rabbit)


160875-66-1 Causes severe eye irritation (similar substances)


Skin Sensitization


1174522-27-0

(guinea pig) (similar substances) Did not cause sensitization on laboratory animals



2-Ethyl hexanol 104-76-7 Did not cause sensitization on laboratory animals (guinea pig)


160875-66-1 (similar substances) Did not cause sensitization on laboratory animals (guinea pig)




1174522-27-0




2-Ethyl hexanol 104-76-7 Not regarded as a sensitizer.



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Mutagenic Effects


1174522-27-0

No data of sufficient quality are available.


112-34-5 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects

2-Ethyl hexanol 104-76-7 In vitro tests did not show mutagenic effects.


160875-66-1 In vivo tests did not show mutagenic effects. (similar substances) In vitro tests did not showmutagenic effects




1174522-27-0

No data of sufficient quality are available.



2-Ethyl hexanol 104-76-7 Did not show carcinogenic effects in animal experiments


160875-66-1 Did not show carcinogenic effects in animal experiments (similar substances)




1174522-27-0

(similar substances) Animal testing did not show any effects on fertility. Did not show teratogeniceffects in animal experiments.



2-Ethyl hexanol 104-76-7 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.


160875-66-1 (similar substances) Animal testing did not show any effects on fertility.




1174522-27-0

(similar substances) No significant toxicity observed in animal studies at concentration requiringclassification.



2-Ethyl hexanol 104-76-7 May cause respiratory irritation.


160875-66-1 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)




1174522-27-0

No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)



2-Ethyl hexanol 104-76-7 No significant toxicity observed in animal studies at concentration requiring classification.




Aspiration hazard


1174522-27-0

May be fatal if swallowed and enters airways

Diethylene glycol 112-34-5 Not applicable

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monobutyl ether

2-Ethyl hexanol 104-76-7 Not applicable


160875-66-1 No adverse health effects are expected from swallowing.


12.1. Toxicity Ecotoxicity effectsProduct is not classified as hazardous to the environment.





Hydrocarbons,C10-14 (evennumbered),n-alkanes, isoalkanes,<2% aromatic

1174522-27-0

EL50 (72 h) >100 mg/L(Desmodesmus

subspicatus)

LC50 (96 h) 1000 mg/L(Salmo gairdneri)

EC50 (3 h) >1000 mg/L(activated sludge)

EC50 (48 h) 1000 mg/L(Daphnia magna)

NOAEC (21 days) >1mg/L (Daphnia magna)


112-34-5 EC50 > 100 mg/L(Desmodesmus

subspicatus)

LC50 1300 mg/L(Lepomis macrochirus)

EC10 >1995 mg/L(Activated sludge,

industrial)

EC50 > 100 mg/L(Daphnia magna)

2-Ethyl hexanol 104-76-7 No information available LC50 (96h) 17.1 mg/L(Leuciscus idus

melanotus)

No information available No information available


160875-66-1 EC50 (72 h) 475.51mg/L (Skeletonema

costatum)EC50 (72 h) >10 mg/L ()

NOEC (30 d) 0.28 mg/L(Pimephales promelas)

No information available LC50 (48 h) 13.76 mg/L(Acartia tonsa)

EC50 (48 h) >10 mg/L(Daphnia magna)



Hydrocarbons, C10-14 (even numbered), n-alkanes,isoalkanes, <2% aromatic

1174522-27-0

Diethylene glycol monobutyl ether 112-34-5 No information available

2-Ethyl hexanol 104-76-7 Readily biodegradable (100% @ 14d)


160875-66-1



Hydrocarbons, C10-14 (even numbered),n-alkanes, isoalkanes, <2% aromatic

1174522-27-0 No data available


2-Ethyl hexanol 104-76-7 Not Bioaccumulative; LogPow = 2.73


160875-66-1 No data available



Hydrocarbons, C10-14 (even numbered), n-alkanes,isoalkanes, <2% aromatic



2-Ethyl hexanol 104-76-7 KOC = 26




12.6. Other adverse effects

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Endocrine Disruptor Information


This product does not contain any known or suspected endocrine disruptors





NZ 5433.1999 UN Number Not restricted

UN proper shipping name: Not restricted




IMDG/IMO UN Number Not restricted





IATA/ICAO UN Number Not restricted











Group Name Cleaning Products (Combustible, HSR002525)







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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%


LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day



Revision NoteInitial Release



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SAFETY DATA SHEET

BaraSure™ W-988Revision Date: 22-Apr-2019 Revision Number: 3

1. Identification

Product Name Product Trade Name: BaraSure™ W-988



Recommended Use Recommended Use Shale stabilizer



136-140 Connett Road East, BlockNew PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207




0800 764 766 (24 hours)



Classification 6.1E (Oral) Acutely Toxic Substances6.3B (Mildly) irritating to the skin6.4A Irritating to the eye


Hazard Pictograms

Signal Word Warning

Hazard Statements H303 - May be harmful if swallowedH316 - Causes mild skin irritationH319 - Causes serious eye irritation

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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019


Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear eye protection/face protection

Response P332 + P313 - If skin irritation occurs: Get medical advice/attentionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention

Storage None


Contains


Organic salt Proprietary 6.1E (Oral)6.3B6.4A (mild irritant)



Substances CAS Number PERCENT (w/w)Organic salt Proprietary 60 - 100%


Requirements for First Aid or Medical Care Inhalation Move person to fresh air.



Ingestion Rinse mouth with water many times. Get medical attention, if symptoms occur


Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected. Causes eye irritation Causes mild skin irritation May be harmful if swallowed




5.1. Extinguishing media Suitable Extinguishing MediaWater spray. Carbon dioxide (CO2). Foam. Dry powder



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6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Do not breathedust/fume/gas/mist/vapors/spray.See Section 8 for additional information

6.2. Environmental precautions None known.

6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeledcontainers.



7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Ensure adequate ventilation. Avoid creating or inhaling dust. Avoid extended skincontact.



7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a cool, well ventilated place





Substances CAS Number New Zealand WES ACGIH TLV-TWAOrganic salt Proprietary Not applicable Not applicable

Engineering Controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures

below applicable exposure limits. Ensure adequate ventilation, especially in confinedareas



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard

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EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.



Eye Protection Safety glasses with side-shields. If splashes are likely to occur, wear: Goggles,Face-shield.






pH: 6.5 - 8.0



Pour Point / Range No data available






Specific Gravity ~ 1.1

Water Solubility No data available











10.4. Conditions to avoid None anticipated


10.6. Hazardous decomposition products Oxides of nitrogen. Carbon oxides.





Eye Contact May cause eye irritation.

Physical State: Viscous liquid Color Clear Colorless to Light yellow

Odor: Odorless Odor Threshold: No information available

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Skin Contact May cause mild skin irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.


Toxicity Data



Organic salt Proprietary 3400 mg/kg (Rat)3900 mg/kg (mouse)

No data available No data available



Organic salt Non-irritating to the skin (Rabbit)



Organic salt Non-irritating to the eye (Rabbit)


Skin Sensitization

Organic salt Did not cause sensitization on laboratory animals (guinea pig)



Organic salt Based on available data, the classification criteria are not met.


Mutagenic Effects

Organic salt In vitro tests did not show mutagenic effects.






Organic salt Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.



Organic salt No significant toxicity observed in animal studies at concentration requiring classification.



Organic salt No significant toxicity observed in animal studies at concentration requiring classification.


Aspiration hazard








Organic salt Proprietary EC50(72h): > 500 mg/L LC50(96h): > 10000 EC50(17h): 132.8 mg/L EC50(24h): 250 mg/L

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mg/L (Leuciscus idus) (Pseudomonas putida) (Daphnia magna)EC50(48h): 500 mg/L

(Daphnia magna)NOEC(21d): 30.2 mg/L(reproduction) (Daphnia

magna)



Organic salt Proprietary Readily biodegradable (>75% @ 5d)


Substances CAS Number Bioaccumulation

Organic salt Proprietary -3.77BCF: 3.16 L/kg



Organic salt Proprietary No information available




13.1. Waste treatment methods Disposal methods Dispose in accordance with local regulations.























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Group Name Not Applicable









Revision Date: 22-Apr-2019




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SAFETY DATA SHEET

BARAZAN® D PLUS

Revision Date: 15-Aug-2018 Revision Number: 30

1. Identification

Product Name Product Trade Name: BARAZAN® D PLUS



Recommended Use Recommended Use Viscosifier



136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207




0800 764 766 (24 hours)


Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA

Classification Non-hazardous


Hazard Pictograms

Signal Word None

Hazard Statements Not Hazardous


Prevention None

Response None

Storage None

Disposal None

Contains


Contains no hazardous substances in NA Non-hazardous

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_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018

concentrations above cut-off values according tothe competent authority



Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority

NA NF











Type of Hazard Flammability HazardOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.





Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.

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See Section 8 for additional information



6.3. Methods and material for containment and cleaning up Scoop up and remove.



7.1. Precautions for safe handling Handling PrecautionsSlippery when wet. Avoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation.Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority

NA Not applicable Not applicable




Respiratory Protection Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)







9.1. Information on basic physical and chemical properties Physical State: Powder Color White to off white

Odor: Slight Odor Threshold: No information available

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pH: 7 (1%)












Autoignition Temperature 204 °C / 400 °F





9.2. Other information Molecular Weight 1000000


Bulk Density 52.4 lbs/ft3





10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.




Inhalation May impede respiration.


Skin Contact None known.



Toxicity Data



Contains no hazardoussubstances inconcentrations abovecut-off values according

NA No data available No data available No data available

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to the competentauthority







Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority

NA No information available No information available No information available No information available



Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority

NA



Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority

NA No data available




NA No information available




13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.


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HSNO Approval Number Non-Hazardous








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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - Celsius


IATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDWHO/FAO

Revision Date: 15-Aug-2018




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SAFETY DATA SHEET

BARAZAN® D



Product Name Product Trade Name: BARAZAN® D








Emergency Telephone Number: +64 800 451719


0800 764 766 (24 hours)





Hazard pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains


Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA Not applicable

2.3. Other Hazards

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_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016

This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).



NA 60 - 100%











Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.







6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information


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Scoop up and remove.



7.1. Precautions for safe handling Handling PrecautionsSlippery when wet. Avoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation.Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.











Personal Protective Equipment (PPE) Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:Dust/mist respirator. (N95, P2/P3)









pH: 7 (1%)






Physical State: Powder Color White to off white

Odor: Slight Odor Threshold:

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Bulk Density 52.4 lbs/ft3









Inhalation May impede respiration.





Toxicity Data



Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority


_____________________________________________________________________________________________

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NA



















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HSNO Approval Number Non-hazardous









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Key literature references and sources for datawww.ChemADVISOR.com/


NZ CCID





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SAFETY DATA SHEET

BARITE

Revision Date: 22-Jan-2018 Revision Number: 50


Product Name Product Trade Name: BARITE



Recommended Use Recommended Use Weight Additive







0800 764 766 (24 hours)



Classification 6.7A Known or presumed human carcinogens6.9B Harmful to human target organs or systems6.9A Toxic to human target organs or systems


Hazard Pictograms

Signal Word Danger

Hazard Statements H350i - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


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_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018

Prevention P103 - Read label before useP104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required

Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell


Disposal P501 - Dispose of contents/container to an approved landfill

Contains





Substances CAS Number PERCENT (w/w)Crystalline silica, quartz 14808-60-7 1 - 5%















Special Protective Equipment and Precautions for Fire Fighters

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Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


Special exposure hazards in a fireNone anticipated







7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposurelimits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material isslippery when wet.



7.2. Conditions for safe storage, including any incompatibilities Store in a well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use goodhousekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuseempty container.





Substances CAS Number New Zealand WES ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3


below applicable exposure limits.



Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.

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9.2. Other information Molecular Weight 233.4





10.5. Incompatible materials None known.

10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).




Inhalation Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).

Physical State: Solid Color Pink to tan to gray

Odor: Odorless Odor Threshold:

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Toxicity Data



Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available






Crystalline silica, quartz 14808-60-7 Non-irritating to the eye


Skin Sensitization






Mutagenic Effects




Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.











Aspiration hazard



12.1. Toxicity

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14808-60-7 EC50 (72 h) =440 mg/L(Selenastrum

capricornutum)(similarsubstance)

LL0 (96 h) =10000 mg/L(Danio rerio)(similar

substance)

No information available LL50 (24 h) >10000mg/L (Daphniamagna)(similar

substance)

12.2. Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.Substances CAS Number Persistence and Degradability

Crystalline silica, quartz 14808-60-7 The methods for determiningbiodegradability are not applicable toinorganic substances.










13.1. Waste treatment methods Disposal methods Follow all applicable community, national or regional regulations regarding waste

management methods.


















_____________________________________________________________________________________________

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Revision Date: 22-Jan-2018



_____________________________________________________________________________________________

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SAFETY DATA SHEET

BAROFIBRE®

Revision Date: 05-Mar-2014 Revision Number: 16

Manufacturer/Supplier

Classification

Halliburton New Zealand1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207

Product Code:

Non-hazardous

HM003539




Hazard Pictograms

Signal Word None


Recommended Use


Product Name



0800 764 766 (24 hours)

Recommended Use

Prevention None

Loss Circulation Material

Other Names

Response None


Storage None


Disposal None

Statement of Hazardous Nature

Contains

Synonyms: None

Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA

Company Name, Address and Contact Details

_____________________________________________________________________________________________

Product Trade Name:

Page 1 / 6

BAROFIBRE®

_____________________________________________________________________________________________BAROFIBRE® Revision Date: 05-Mar-2014


Under normal conditions, first aid procedures are not required.

Mixture

Type of Hazard

Not applicable

Eyes

Flammability HazardOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.

In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.

Substances CAS Number

Skin

5.1 Extinguishing media


PERCENT (w/w)

Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.

Dust can form an explosive mixture in air

Ingestion



Substance HSNO Classification

Contains no hazardous substances

HAZCHEM Code

Mixture

Hazchem Code: None Allocated

60 - 100%

Workplace Facilities Required

Substances


None

Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

Special Exposure HazardsOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.

Relation to Health Effect


Most Important Symptoms/EffectsNo significant hazards expected.


6.1 Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.

CAS Number

Contains no hazardous substances



6.2 Environmental precautions


2.3 Other Hazards

Requirements for First Aid or Medical Care

_____________________________________________________________________________________________

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Inhalation

_____________________________________________________________________________________________Revision Date: 05-Mar-2014BAROFIBRE®

Not applicable

Handling Practices

Engineering Controls

Engineering Controls Use in a well ventilated area.

7. Handling and Storage

Store Site Requirements

Personal Protective Equipment (PPE)

None known.

Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, or equivalent respirator when using this product. Selection of and instruction onusing all personal protective equipment, including respirators, should be performed by anIndustrial Hygienist or other qualified professional.

No special controls required

6.4 Reference to other sections



Eye Protection Safety glasses.

Packaging



Hygiene Measures Handle in accordance with good industrial hygiene and safety practice

No special packaging required

Approved Handlers

7.1 Precautions for Safe Handling


This product does NOT require an approved handler.

See Section 8 and 13 for additional information.

6.3 Methods and material for containment and cleaning up

9.1 Information on basic physical and chemical properties


Handling PrecautionsAvoid creating or inhaling dust.

Workplace Exposure Standards

7.2 Conditions for safe storage, including any incompatibilities

Exposure Limits

Store away from oxidizers. Store in a dry location. Product has a shelf life of 36 months.


Contains no hazardoussubstances

Mixture Not applicable

No information availableOdor: Odorless

Physical State:

_____________________________________________________________________________________________

Solid Powder Color:

Page 3 / 6

Tan

Odor Threshold:


None known.


No data available

Remarks/ - Method

Hazardous Reactions

Boiling Point/Range

Hazardous Polymerization: Will Not Occur

Specific Gravity

9.2 Other information

1.3

No data available



Property

Water Solubility

Health Effect from Likely Routes of Exposure

Insoluble in water

Acute Toxicity

Freezing Point/Range


Flash Point

Solubility in other solvents


No data available

193 °C PMCC


10.2 Chemical Stability

190 °C



Stable

Ingestion None known

No data available

Values

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% arechronic health hazards.

Evaporation rate

Autoignition Temperature

10.4 Conditions to Avoid

No data available

Toxicity Data

No data available

None anticipated

pH:

Decomposition Temperature


No data available

Melting Point/Range

10.5 Incompatible Materials

Vapor Pressure


Viscosity

Strong oxidizers.

Contains no hazardoussubstances

Mixture No data available No data available No data available

No data available

No data available

No data available


_____________________________________________________________________________________________

4.9 (1%)

10.6 Hazardous Decomposition Products

Page 4 / 6

Vapor Density

Oxidizing Properties





IMDG/IMO


UN Number: Not restricted.



Ecotoxicity Hazard Statements


None known

NZ 5433.1999


Ecotoxicity Effects


12.2 Persistence and degradability

12.6 Other adverse effects




Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors

Biodegradable.

IATA/ICAO



Substances




CAS Number Toxicity to Algae


12.3 Bioaccumulative potential

13.1 Waste treatment methods


Toxicity to Fish Toxicity toMicroorganisms

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.


Does not bioaccumulate





12.1 Toxicity


Contains nohazardoussubstances

_____________________________________________________________________________________________

12.4 Mobility in soil

Page 5 / 6

Mixture

_____________________________________________________________________________________________Revision Date: 05-Mar-2014BAROFIBRE®




Revision Date: 05-Mar-2014

16. Other information, including date of preparation or last revision

Revision Note

Not applicable






For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Compliance at 1-580-251-4335.


_____________________________________________________________________________________________

Poisons Schedule:

Page 6 / 6

None Allocated

SAFETY DATA SHEET

BENTONITE

Revision Date: 05-Feb-2018 Revision Number: 47

1. Identification

Product Name Product Trade Name: BENTONITE



Recommended Use Recommended Use Weight Additive







0800 764 766 (24 hours)



Classification 6.7A Known or presumed human carcinogen6.9B Harmful to human target organs or systems


Hazard Pictograms

Signal Word Danger

Hazard Statements H350 - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


Prevention P103 - Read label before use

_____________________________________________________________________________________________

Page 1 / 8

_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018

P104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required

Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell



Contains





Substances CAS Number PERCENT (w/w)Crystalline silica, quartz 14808-60-7 1 - 5%






Ingestion Rinse mouth with water many times. Get medical attention if symptoms occur










_____________________________________________________________________________________________

Page 2 / 8



None anticipated



6.2. Environmental precautions None known.




7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposurelimits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material isslippery when wet.



7.2. Conditions for safe storage, including any incompatibilities Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do notreuse empty container.





Substances CAS Number New Zealand WES ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3





Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection

_____________________________________________________________________________________________

Page 3 / 8


of and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)









pH: 9.9





















10.5. Incompatible materials Hydrofluoric acid.





Inhalation Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.

Physical State: Solid Color Various


_____________________________________________________________________________________________

Page 4 / 8



Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).



Ingestion May act as obstruction if swallowed.

Chronic Effects/Carcinogenicity This product contains a suspected carcinogen. May cause damage to organs throughprolonged or repeated exposure. Silicosis: Excessive inhalation of respirable crystallinesilica dust may cause a progressive, disabling, and sometimes-fatal lung disease calledsilicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.

Toxicity Data











Skin Sensitization






Mutagenic Effects















Aspiration hazard



_____________________________________________________________________________________________

Page 5 / 8











substance)


substance)













13.1. Waste treatment methods Disposal methods Follow all applicable community, national or regional regulations regarding waste

management methods.













_____________________________________________________________________________________________

Page 6 / 8






















_____________________________________________________________________________________________

Page 7 / 8

Disclaimer Statement


This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.


_____________________________________________________________________________________________

Page 8 / 8

BIOGUARD PLUSWilhelmsen Ships Service LtdCatalogue number: 778918 (25L)

Version No: 8.9

Safety Data Sheet according to HSNO Regulations

Issue Date: 13/02/2018

Print Date: 12/03/2019

S.GHS.NZL.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name BIOGUARD PLUS

Synonyms Not Available

Proper shipping name AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Dodecyl dipropylene triamine)

Other means ofidentification

778918 (25L), 778918

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Seawater Dispersant for Marine Systems

Details of the supplier of the safety data sheet

Registered companyname

Wilhelmsen ShipsService Ltd

Wilhelmsen Ships Service AS*Outback (M)SDS portal:http://jr.chemwatch.net/outb/account/autologin?login=wilhelmsen

Address6B Wagener PlaceAuckland 1025 NewZealand

Willem Barentszstraat 50 RotterdamNetherlands

--------Use our Outback portal to obtain our(M)SDSs in other languages and/orformat.--------- For questions relating to ourSDSs please use Email:[email protected] Norway

Telephone (+64) 9 8494783 +31 10 4877 777 Not Available

Fax Not Available +31 10 4877888 Not Available

Website Not Available http://www.wilhelmsen.com Not Available

Email Not Available [email protected] Not Available


Association /Organisation

CHEMTREC Dutch nat. poison centreAmerican Chemistry Council 24hrs -Chemtrec

Emergency telephonenumbers

(+64) 9 8455758 + 31 30 274 88 88 +1 703 527 3887

Other emergencytelephone numbers

Not Available Not Available (800) 424 9300

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

Continued...

Classification [1] Acute Toxicity (Oral) Category 4, Skin Corrosion/Irritation Category 1B, Specific target organ toxicity - repeated exposureCategory 2, Chronic Aquatic Hazard Category 1

Legend:1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No1272/2008 - Annex VI

Determined byChemwatch using

GHS/HSNO criteria6.1D (oral), 8.2B, 6.9B, 9.1A

Label elements

Hazard pictogram(s)

SIGNAL WORD DANGER

Hazard statement(s)

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H373 May cause damage to organs through prolonged or repeated exposure.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P270 Do not eat, drink or smoke when using this product.

Precautionary statement(s) Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.

Precautionary statement(s) Storage

P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

SubstancesSee section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

2372-82-9* 30-40

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids.

N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine

Chemwatch: 9-221869

Catalogue number: 778918 (25L)

Version No: 8.9

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BIOGUARD PLUS



Continued...

Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

For amines:If liquid amines come in contact with the eyes, irrigate immediately and continuously with low pressure flowing water,preferably from an eye wash fountain, for 15 to 30 minutes.For more effective flushing of the eyes, use the fingers to spread apart and hold open the eyelids. The eyes shouldthen be “rolled” or moved in all directions.Seek immediate medical attention, preferably from an ophthalmologist.

Skin Contact

If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons InformationCentre. Transport to hospital, or doctor.

For amines:In case of major exposure to liquid amine, promptly remove any contaminated clothing, including rings, watches, andshoe, preferably under a safety shower.Wash skin for 15 to 30 minutes with plenty of water and soap. Call a physician immediately.Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminatedclothing may be more effective than normal laundering.Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing.Discard contaminated leather articles such as shoes, belts, and watchbands.Note to Physician: Treat any skin burns as thermal burns. After decontamination, consider the use of cold packs andtopical antibiotics.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably insemi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative orbeclomethasone derivative may be considered.

This must definitely be left to a doctor or person authorised by him/her.(ICSC13719)For amines:

All employees working in areas where contact with amine catalysts is possible should be thoroughly trained in theadministration of appropriate first aid procedures.Experience has demonstrated that prompt administration of such aid can minimize the effects of accidental exposure.Promptly move the affected person away from the contaminated area to an area of fresh air. Keep the affected person calm and warm, but not hot.If breathing is difficult, oxygen may be administered by a qualified person.If breathing stops, give artificial respiration. Call a physician at once.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airwayand prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

For amines:If liquid amine are ingested, have the affected person drink several glasses of water or milk.Do not induce vomiting.Immediately transport to a medical facility and inform medical personnel about the nature of the exposure. The decisionof whether to induce vomiting should be made by an attending physician.

Indication of any immediate medical attention and special treatment neededFor acute or short-term repeated exposures to highly alkaline materials:

Respiratory stress is uncommon but present occasionally because of soft tissue edema. Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary. Oxygen is given as indicated. The presence of shock suggests perforation and mandates an intravenous line and fluid administration. Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow deep

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Continued...

penetration into the tissue. Alkalis continue to cause damage after exposure. INGESTION:

Milk and water are the preferred diluents No more than 2 glasses of water should be given to an adult.

Neutralising agents should never be given since exothermic heat reaction may compound injury. * Catharsis and emesis are absolutely contra-indicated.* Activated charcoal does not absorb alkali.* Gastric lavage should not be used. Supportive care involves the following:

Withhold oral feedings initially. If endoscopy confirms transmucosal injury start steroids only within the first 48 hours. Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention. Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).

SKIN AND EYE:Injury should be irrigated for 20-30 minutes.

Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]For amines:

Certain amines may cause injury to the respiratory tract and lungs if aspirated. Also, such products may cause tissue destruction leading to stricture. Iflavage is performed, endotracheal and/or esophagoscopic control is suggested.No specific antidote is known.Care should be supportive and treatment based on the judgment of the physician in response to the reaction of the patient.

Laboratory animal studies have shown that a few amines are suspected of causing depletion of certain white blood cells and their precursors in lymphoidtissue. These effects may be due to an immunosuppressive mechanism.Some persons with hyperreactive airways (e.g., asthmatic persons) may experience wheezing attacks (bronchospasm) when exposed to airway irritants.Lung injury may result following a single massive overexposure to high vapour concentrations or multiple exposures to lower concentrations of anypulmonary irritant material.Health effects of amines, such as skin irritation and transient corneal edema (“blue haze,” “halo effect,” “glaucopsia”), are best prevented by means offormal worker education, industrial hygiene monitoring, and exposure control methods. Persons who are highly sensitive to the triggering effect ofnon-specific irritants should not be assigned to jobs in which such agents are used, handled, or manufactured.

Medical surveillance programs should consist of a pre-placement evaluation to determine if workers or applicants have any impairments (e.g.,hyperreactive airways or bronchial asthma) that would limit their fitness for work in jobs with potential for exposure to amines. A clinical baseline can beestablished at the time of this evaluation.Periodic medical evaluations can have significant value in the early detection of disease and in providing an opportunity for health counseling.Medical personnel conducting medical surveillance of individuals potentially exposed to polyurethane amine catalysts should consider the following:

Health history, with emphasis on the respiratory system and history of infectionsPhysical examination, with emphasis on the respiratory system and the lymphoreticular organs (lymph nodes, spleen, etc.)Lung function tests, pre- and post-bronchodilator if indicatedTotal and differential white blood cell countSerum protein electrophoresis

Persons who are concurrently exposed to isocyanates also should be kept under medical surveillance.Pre-existing medical conditions generally aggravated by exposure include skin disorders and allergies, chronic respiratory disease (e.g. bronchitis,asthma, emphysema), liver disorders, kidney disease, and eye disease.Broadly speaking, exposure to amines, as characterised by amine catalysts, may cause effects similar to those caused by exposure to ammonia. Assuch, amines should be considered potentially injurious to any tissue that is directly contacted.Inhalation of aerosol mists or vapors, especially of heated product, can result in chemical pneumonitis, pulmonary edema, laryngeal edema, and delayedscarring of the airway or other affected organs. There is no specific treatment.Clinical management is based upon supportive treatment, similar to that for thermal burns.Persons with major skin contact should be maintained under medical observation for at least 24 hours due to the possibility of delayed reactions.

Polyurethene Amine Catalysts: Guidelines for Safe Handling and Disposal Technical Bulletin June 2000Alliance for Polyurethanes Industry

SECTION 5 FIREFIGHTING MEASURES

Extinguishing mediaFoam. Dry chemical powder. BCF (where regulations permit).

Special hazards arising from the substrate or mixture

Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignitionmay result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course.

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BIOGUARD PLUS



Continued...

For amines:For firefighting, cleaning up large spills, and other emergency operations, workers must wear a self-contained breathingapparatus with full face-piece, operated in a pressure-demand mode.Airline and air purifying respirators should not be worn for firefighting or other emergency or upset conditions.Respirators should be used in conjunction with a respiratory protection program, which would include suitable fit testingand medical evaluation of the user.

Fire/Explosion Hazardcarbon dioxide (CO2)other pyrolysis products typical of burning organic material.May emit corrosive fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency proceduresSee section 8

Environmental precautionsSee section 12

Methods and material for containment and cleaning up

Minor Spills

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before dischargeor disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

for amines:If possible (i.e., without risk of contact or exposure), stop the leak.Contain the spilled material by diking, then neutralize.Next, absorb the neutralized product with clay, sawdust, vermiculite, or other inert absorbent and shovel into containers.

Major Spills

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus.

For amines:First remove all ignition sources from the spill area.Have firefighting equipment nearby, and have firefighting personnel fully trained in the proper use of the equipment andin the procedures used in fighting a chemical fire.Spills and leaks of polyurethane amine catalysts should be contained by diking, if necessary, and cleaned up only byproperly trained and equipped personnel.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area.

DO NOT allow clothing wet with material to stay in contact with skin

Other information

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area.

DO NOT store near acids, or oxidising agentsNo smoking, naked lights, heat or ignition sources.

Conditions for safe storage, including any incompatibilities

Suitable container

Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum.

For low viscosity materialsDrums and jerricans must be of the non-removable head type. Where a can is to be used as an inner package, the can must have a screwed enclosure.

For materials with a viscosity of at least 2680 cSt.

Storage incompatibilityAvoid reaction with oxidising agents Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.

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Continued...

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

Ingredient Original IDLH Revised IDLH

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Not Available

EMERGENCY LIMITS

BIOGUARD PLUS Not Available Not Available Not Available Not Available

N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine

Not Available Not Available

Exposure controls

Appropriate engineeringcontrols

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactionsto provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.

Personal protection

Eye and face protection

Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as inlaboratories; spectacles are not sufficient where complete eye protection is needed such as when handlingbulk-quantities, where there is a danger of splashing, or if the material may be under pressure.Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properlyfitted.Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes;these afford face protection.

For amines:SPECIAL PRECAUTION:

Because amines are alkaline materials that can cause rapid and severe tissue damage, wearing of contact lenses whileworking with amines is strongly discouraged. Wearing such lenses can prolong contact of the eye tissue with the amine,thereby causing more severe damage. Appropriate eye protection should be worn whenever amines are handled or whenever there is any possibility of directcontact with liquid products, vapors, or aerosol mists.

Skin protection See Hand protection below

Hands/feet protection

Elbow length PVC gloves When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which varyfrom manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of theglove material can not be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.hasto be observed when making a final choice.For amines:

Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommendedWhere there is a possibility of exposure to liquid amines skin protection should include: rubber gloves, (neoprene, nitrile,or butyl).

Body protection See Other protection below

Other protectionOveralls. PVC Apron. PVC protective suit may be required if exposure severe.

Respiratory protection

Type EK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the

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Continued...

contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.

Required minimum protectionfactor

Maximum gas/vapour concentration present in air p.p.m. (byvolume)

Half-faceRespirator

Full-FaceRespirator

up to 10 1000 EK-AUS / Class1 P2 -up to 50 1000 - EK-AUS / Class 1 P2up to 50 5000 Airline * -up to 100 5000 - EK-2 P2up to 100 10000 - EK-3 P2100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogencyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methylbromide, AX = Low boiling point organic compounds(below 65 degC)

· Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygencontent.

· The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odourmay indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is not properlyfitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate.

· Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determinedthat the humidity is less than 75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily,regardless of the length of time used

Where engineering controls are not feasible and work practices do not reduce airborne amine concentrations below recommended exposure limits,appropriate respiratory protection should be used. In such cases, air-purifying respirators equipped with cartridges designed to protect against amines arerecommended.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Liquid, light, yellow, miscible with water

Physical state LiquidRelative density (Water =

1)0.97

Odour Not AvailablePartition coefficient

n-octanol / waterNot Available

Odour threshold Not AvailableAuto-ignition temperature

(°C)Not Applicable

pH (as supplied) >7Decomposition

temperatureNot Available

Melting point / freezingpoint (°C)

Not Available Viscosity (cSt) Not Available

Initial boiling point andboiling range (°C)

Not Available Molecular weight (g/mol) Not Available

Flash point (°C) Not Applicable Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Upper Explosive Limit(%)

Not ApplicableSurface Tension (dyn/cm

or mN/m)Not Available

Lower Explosive Limit(%)

Not ApplicableVolatile Component

(%vol)Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7

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Conditions to avoid See section 7

Incompatible materials See section 7

Hazardousdecomposition products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lungdamage.Inhaling corrosive bases may irritate the respiratory tract. Symptoms include cough, choking, pain and damage to themucous membrane.Inhalation of amine vapours may cause irritation of the mucous membrane of the nose and throat, and lung irritation withrespiratory distress and cough. Swelling and inflammation of the respiratory tract is seen in serious cases; with headache,nausea, faintness and anxiety.

Ingestion

Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 grammay be fatal or may produce serious damage to the health of the individual.Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations and swellings of the mucousmembranes, profuse saliva production, with an inability to speak or swallow. Both the oesophagus and stomach mayexperience burning pain; vomiting and diarrhoea may follow.Amines without benzene rings when swallowed are absorbed throughout the gut. Corrosive action may cause damagethroughout the gastrointestinal tract.

Skin Contact

The material can produce severe chemical burns following direct contact with the skin.Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models).Systemic harm, however, has been identified following exposure of animals by at least one other route and the materialmay still produce health damage following entry through wounds, lesions or abrasions.Skin contact with alkaline corrosives may produce severe pain and burns; brownish stains may develop. The corrodedarea may be soft, gelatinous and necrotic; tissue destruction may be deep.Volatile amine vapours produce irritation and inflammation of the skin. Direct contact can cause burns.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye

If applied to the eyes, this material causes severe eye damage.Direct eye contact with corrosive bases can cause pain and burns. There may be swelling, epithelium destruction, cloudingof the cornea and inflammation of the iris. Mild cases often resolve; severe cases can be prolonged with complicationssuch as persistent swelling, scarring, permanent cloudiness, bulging of the eye, cataracts, eyelids glued to the eyeballand blindness.Vapours of volatile amines irritate the eyes, causing excessive secretion of tears, inflammation of the conjunctiva andslight swelling of the cornea, resulting in 'halos' around lights. This effect is temporary, lasting only for a few hours.However this condition can reduce the efficiency of undertaking skilled tasks, such as driving a car.The material can produce severe chemical burns to the eye following direct contact. Vapours or mists may be extremelyirritating.

Chronic

Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes inthe mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumoniamay ensue.Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs orbiochemical systems.Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and relatedwhole-body problems.

BIOGUARD PLUSTOXICITY IRRITATION


N-(3-aminopropyl)-N-dodecyl-

1,3-propanediamine

TOXICITY IRRITATION

dermal (rat) LD50: >600 mg/kg *[2] Skin (rabbit): Corrosive *

Oral (rat) LD50: 245 mg/kg *[2]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances


1,3-propanediamine

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. Thepathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.

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No significant acute toxicological data identified in literature search. FND ether amines and FND amines are very similar in structure (length of chain or degree of saturation), function andtoxicity. Acute exposure to FND ether amines by oral, dermal and inhalation may produce moderate to slight toxicity butrepeated skin contact can be highly irritating. However, exposure did not produce any organ-specific toxicity, genetic,reproductive or developmental defect same as in FND amines.The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure toirritants may produce conjunctivitis.The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,swelling, the production of vesicles, scaling and thickening of the skin.For alkyl polyamines:The alkyl polyamines cluster consists of two terminal primary and at least one secondary amine groups and arederivatives of low molecular weight ethylenediamine, propylenediamine or hexanediamine. Toxicity depends on route ofexposure. Cluster members have been shown to cause skin irritation or sensitisation, eye irritation and genetic defects,but have not been shown to cause cancer.The acute oral LD50 in the rat was estimated to be ~ 260 mg/kg. Dermal LD50 was determined to be greater than 600mg/kg pure substance. The substance (in 30% concentration) is severely irritating/ corrosive to the skin but was not asensitiser when tested in low concentrations. A 90-day oral toxicity study showed at higher doses (30 and 90 mg/kg/day),a dose related increase in some liver enzymes but, no treatment related effects at doses of 5 or 10 mg/kg/day. It was notfound to produce mutations in S. typhimurium, or the Chinese hamster V-79 cell line and there were no clastogenic effectsin the Chinese hamster V-79 cell line. NICNAS Public Report 1995

BIOGUARD PLUS &N-(3-aminopropyl)-N-

dodecyl-1,3-propanediamine

Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to anon-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to highlevels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease ina non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documentedexposure to the irritant.Overexposure to most of these materials may cause adverse health effects.Many amine-based compounds can cause release of histamines, which, in turn, can trigger allergic and other physiologicaleffects, including constriction of the bronchi or asthma and inflammation of the cavity of the nose. Whole-bodysymptoms include headache, nausea, faintness, anxiety, a decrease in blood pressure, rapid heartbeat, itching, reddeningof the skin, urticaria (hives) and swelling of the face, which are usually transient.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious EyeDamage/Irritation

STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - RepeatedExposure

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

BIOGUARD PLUSENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

Not Available Not Available Not Available Not Available Not Available


1,3-propanediamine

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 0.431mg/L 2

EC50 48 Crustacea 0.073mg/L 2

EC50 96 Algae or other aquatic plants 0.054mg/L 2

NOEC 72 Algae or other aquatic plants 0.007mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - AquaticToxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic ToxicityData 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -Bioconcentration Data 8. Vendor Data

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water whencleaning equipment or disposing of equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.Prevent, by any means available, spillage from entering drains or water courses.

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Ingredient Persistence: Water/Soil Persistence: Air

Ingredient Bioaccumulation

Ingredient Mobility

DO NOT discharge into sewer or waterways.

Persistence and degradability

No Data available for all ingredients No Data available for all ingredients

Bioaccumulative potential

No Data available for all ingredients

Mobility in soil

No Data available for all ingredients

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packagingdisposal

Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.

Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be usedto store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer tolaws operating in their area. In some areas, certain wastes must be tracked.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if nosuitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant.

Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017

Disposal RequirementsPackages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from the package.The package must be disposed according to the manufacturer's directions taking into account the material it is made of.Packages which hazardous content have been appropriately treated and removed may be recycled.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM 2X

Land transport (UN)

UN number 2735

UN proper shippingname

AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Dodecyl dipropylene triamine)

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Air transport (ICAO-IATA / DGR)

Sea transport (IMDG-Code / GGVSee)

Transport hazardclass(es)

Class 8

Subrisk Not Applicable

Packing group II

Environmental hazard Environmentally hazardous

Special precautions foruser

Special provisions 274

Limited quantity 1 L

UN number 2735


Amines, liquid, corrosive, n.o.s. * (Dodecyl dipropylene triamine); Polyamines, liquid, corrosive, n.o.s. * (Dodecyldipropylene triamine)


ICAO/IATA Class 8

ICAO / IATA Subrisk Not Applicable

ERG Code 8L

Packing group II

Environmental hazard Environmentally hazardous


Special provisions A3 A803

Cargo Only Packing Instructions 855

Cargo Only Maximum Qty / Pack 30 L

Passenger and Cargo Packing Instructions 851

Passenger and Cargo Maximum Qty / Pack 1 L

Passenger and Cargo Limited Quantity Packing Instructions Y840

Passenger and Cargo Limited Maximum Qty / Pack 0.5 L

UN number 2735


AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Dodecyl dipropylene triamine)


IMDG Class 8

IMDG Subrisk Not Applicable

Packing group II

Environmental hazard Marine Pollutant


EMS Number F-A , S-B

Special provisions 274

Limited Quantities 1 L

Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixtureThis substance is to be managed using the conditions specified in an applicable Group StandardHSR No 002684 - Water Treatment Chemicals (Subsidiary Hazard) Group Standard 2017.

N-(3-AMINOPROPYL)-N-DODECYL-1,3-PROPANEDIAMINE(2372-82-9*) IS FOUND ON THE FOLLOWING REGULATORY LISTS

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International Air Transport Association (IATA) Dangerous Goods Regulations

International Maritime Dangerous Goods Requirements (IMDG Code)

New Zealand Hazardous Substances and New Organisms (HSNO) Act -Classification of Chemicals

New Zealand Hazardous Substances and New Organisms (HSNO) Act -Classification of Chemicals - Classification Data

New Zealand Inventory of Chemicals (NZIoC)

United Nations Recommendations on the Transport of Dangerous GoodsModel Regulations (Chinese)

United Nations Recommendations on the Transport of Dangerous GoodsModel Regulations (English)

United Nations Recommendations on the Transport of Dangerous GoodsModel Regulations (Spanish)

Hazardous Substance LocationSubject to the Health and Safety at Work (Hazardous Substances) Regulations 2017.

Hazard ClassQuantity beyond which controls apply forclosed containers

Quantity beyond which controls apply when use occurring inopen containers

Not Applicable Not Applicable Not Applicable

Certified HandlerSubject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

Class of substance Quantities

9.1A, 9.2A, 9.3A, and 9.4A Any quantity

Refer Group Standards for further information

Tracking RequirementsNot Applicable

National Inventory Status

National Inventory Status

Australia - AICS Yes

Canada - DSL Yes

Canada - NDSL No (N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine)

China - IECSC Yes

Europe - EINEC / ELINCS /NLP

Yes

Japan - ENCS Yes

Korea - KECI No (N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine)

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes

Legend:Yes = All ingredients are on the inventoryNo = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specificingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 13/02/2018

Initial Date 13/02/2018

CONTACT POINT

- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheetWilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.:+31 10 4877775

Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios.

Powered by AuthorITe, from Chemwatch.

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end of SDS

SAFETY DATA SHEET

CALCIUM CHLORIDE - FLAKE



Product Name Product Trade Name: CALCIUM CHLORIDE - FLAKE



Recommended Use Recommended Use Additive







0800 764 766 (24 hours)



Classification 6.1D (Oral) Acutely Toxic Substances6.1E (Dermal) Acutely Toxic Substances6.3A Irritating to the skin6.4A Irritating to the eye9.3C Harmful to terrestrial vertebrates


Hazard pictograms

Signal Word Warning

Hazard Statements H302 - Harmful if swallowedH313 - May be harmful in contact with skinH315 - Causes skin irritationH319 - Causes serious eye irritationH433 - Harmful to the terrestrial vertebrates.

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_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016


Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protection

Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP331 - Do NOT induce vomitingP312 - Call a POISON CENTER or doctor/physician if you feel unwellP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention

Storage None


Contains


Calcium chloride 10043-52-4 6.1D (Oral)6.1E (Dermal)6.3A6.4A9.3C



Substances CAS Number PERCENT (w/w)Calcium chloride 10043-52-4 60 - 100%




Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water forat least 15 minutes and get medical attention immediately after flushing.

Skin Wash with soap and water. Get medical attention if irritation persists. Removecontaminated clothing and launder before reuse.



Relation to Health Effect Most Important Symptoms/EffectsCauses eye irritation



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Special exposure hazards in a fireNone anticipated







7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensureadequate ventilation. Wash hands after use. Launder contaminated clothing before reuse.



7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location.





Substances CAS Number New Zealand WES ACGIH TLV-TWACalcium chloride 10043-52-4 Not applicable Not applicable

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Respiratory Protection Dust/mist respirator. (N95, P2/P3)









pH: 10






Vapor Pressure 1 mmHg

















10.6. Hazardous decomposition products None known.




Physical State: Solid Color White


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Eye Contact Causes eye irritation.


Ingestion Irritation of the mouth, throat, and stomach.


Toxicity Data



Calcium chloride 10043-52-4 > 1000 mg/kg (Rat)2301 mg/kg (Rat)

> 2000 mg/kg (Rat)2240 mg/kg (Rat)

5000 mg/kg (Rabbit) No data available



Calcium chloride 10043-52-4 Causes mild skin irritation (Rabbit)



Calcium chloride 10043-52-4 Causes moderate eye irritation (Rabbit)


Skin Sensitization

Calcium chloride 10043-52-4 No information available





Mutagenic Effects

Calcium chloride 10043-52-4 Did not show mutagenic effects in animal experiments






Calcium chloride 10043-52-4 Animal testing did not show any effects on fertility.



Calcium chloride 10043-52-4 No significant toxicity observed in animal studies at concentration requiring classification.



Calcium chloride 10043-52-4 No information available.


Aspiration hazard

Calcium chloride 10043-52-4 Not applicable



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Product Ecotoxicity Data


No data available




Calcium chloride 10043-52-4 ErC50 (72h) 2900 mg/L(Pseudokirchnerella

subcapitata)ErC50 (72h) 4000 mg/L


LC50 (96h) 4630 mg/L(Pimephales promelas)LC50 (48h) >6560 mg/L(Pimephales promelas)LC50 (24h) >6660 mg/L(Pimephales promelas)

No information available EC50 (48h) 2400 mg/L(Daphnia magna)

EC50 (21d) 610 mg/L(reproduction) (Daphnia

magna)



Calcium chloride 10043-52-4 The methods for determiningbiodegradability are not applicable toinorganic substances.



Calcium chloride 10043-52-4 No data available
























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Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDOSHAECHA C&L




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SAFETY DATA SHEET

CAL-SEAL 60


1. Identification

Product Name Product Trade Name: CAL-SEAL 60



Recommended Use Recommended Use Additive







0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Non-hazardous

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_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018




NA 60 - 100%
















Special exposure hazards in a fireNot applicable




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7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust.



7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location. Product has a shelf life of 24 months.







Engineering Controls Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust levels.












pH: 10.4







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Water Solubility Partly soluble


















Inhalation None known.

Eye Contact Non-irritating to rabbit's eye

Skin Contact Not irritating to skin in rabbits.

Ingestion May act as obstruction if swallowed.


Toxicity Data





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12.1. Toxicity










NA





















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National Toxicology Program (NTP)





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SAFETY DATA SHEET

CAUSTIC SODA

Revision Date: 14-Sep-2018 Revision Number: 38

1. Identification

Product Name Product Trade Name: CAUSTIC SODA



Recommended Use Recommended Use pH Control







0800 764 766 (24 hours)



Classification 6.1D (Oral) Substances that are acutely toxic - Harmful6.1D (Dermal) Substances that are acutely toxic - Harmful8.1A Corrosive to metals8.2B Corrosive to dermal tissue if exposed for greater than 3 mins.8.3A Corrosive to ocular tissue9.1D Slightly harmful in the aquatic environment9.3C Harmful to terrestrial vertebrates


Hazard Pictograms

Signal Word Danger

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_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018

Hazard Statements H290 - May be corrosive to metalsH302 - Harmful if swallowedH312 - Harmful in contact with skinH314 - Causes severe skin burns and eye damageH315 - Causes skin irritationH402 - Harmful to aquatic lifeH433 - Harmful to the terrestrial vertebrates.


Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P234 - Keep only in original packaging.P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protection

Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water [or shower].P363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable forbreathing.P310 - Immediately call a POISON CENTER or doctor/physicianP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP390 - Absorb spillage to prevent material damage



Contains


Sodium hydroxide 1310-73-2 6.1D (Oral)6.1D (Dermal)8.1A8.2B8.3A9.1D (Crustacean, Fish)9.3C



Substances CAS Number PERCENT (w/w)Sodium hydroxide 1310-73-2 60 - 100%




Skin In case of contact, immediately flush skin with plenty of soap and water for at least 30minutes and remove contaminated clothing, shoes and leather goods immediately. Getmedical attention immediately.



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Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction. May causerespiratory irritation. Harmful if swallowed.






HAZCHEM Code Hazchem Code: 2W


Special exposure hazards in a fireMay form explosive mixtures with strong acids. Reaction with steel and certain other metals generates flammable hydrogengas.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid creating and breathing dust. Ensureadequate ventilation.See Section 8 for additional information

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. Consult local authorities.

6.3. Methods and material for containment and cleaning up Neutralize to pH of 6-8. Scoop up and remove.






7.2. Conditions for safe storage, including any incompatibilities Store away from acids. Store in a cool, dry location. Store locked up.

Store Site Requirements

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No special controls required




Substances CAS Number New Zealand WES ACGIH TLV-TWASodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 Not applicable

Engineering Controls Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust levels.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. Butyl rubber gloves. (>= 0.7 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.

Skin Protection Full protective chemical resistant clothing. Rubber boots







pH: 14

















Physical State: Solid Color White to off white


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10.5. Incompatible materials Contact with acids. Peroxides. Halogenated compounds. Prolonged contact with aluminum, lead, or zinc may liberateflammable hydrogen.





Inhalation Causes severe respiratory irritation.

Eye Contact Causes severe eye burns.

Skin Contact Causes severe burns.

Ingestion Causes burns of the mouth, throat and stomach.


Toxicity Data



Sodium hydroxide 1310-73-2 Not applicable due to corrosivityof the substance.

Not applicable due to corrosivityof the substance.




Sodium hydroxide 1310-73-2 Causes severe burns



Sodium hydroxide 1310-73-2 Causes severe eye burns (Rabbit)


Skin Sensitization

Sodium hydroxide 1310-73-2 Did not cause sensitization on laboratory animals (guinea pig)



Sodium hydroxide 1310-73-2 No information available


Mutagenic Effects

Sodium hydroxide 1310-73-2 Did not show mutagenic effects in animal experiments In vitro tests did not show mutagenic effects.



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Sodium hydroxide 1310-73-2 No data of sufficient quality are available.






Sodium hydroxide 1310-73-2 May cause respiratory irritation.



Sodium hydroxide 1310-73-2 No significant toxicity observed in animal studies at concentration requiring classification. Notapplicable due to corrosivity of the substance.


Aspiration hazard

Sodium hydroxide 1310-73-2 Not applicable


12.1. Toxicity





Sodium hydroxide 1310-73-2 No information available LC50(48h) 189 mg/L(Leuciscus idus

melanotus)LLC50(48h) 189 mg/L(Leuciscus melanotus)LC50(24h) 145 mg/L(Poecilia reticulate)

LC50(96h) 125 mg/L(Gambusia affinis)

LOEL(150 d) = 25 mg/L(Lebistes reticulatus)

No information available EC50 (48h) 40.4 mg/L(Ceriodaphnia sp.)



Sodium hydroxide 1310-73-2 The methods for determiningbiodegradability are not applicable toinorganic substances.



Sodium hydroxide 1310-73-2 No data available




Ecotoxicity Hazard Statements Harmful to aquatic lifeHarmful to terrestrial vertebrates.



_____________________________________________________________________________________________

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13.1. Waste treatment methods


Disposal methods Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection. Contaminated packaging may be disposed of by: rendering packagingincapable of containing any substance, or treating packaging to remove residualcontents, or treating packaging to make sure the residual contents are no longerhazardous, or by disposing of packaging into commercial waste collection.



UN proper shipping name: Sodium Hydroxide, Solid


Packing Group: II





Packing Group: II


EMS: EmS F-A, S-B




Packing Group: II















_____________________________________________________________________________________________

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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%


LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day


Revision Date: 14-Sep-2018




_____________________________________________________________________________________________

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SAFETY DATA SHEET

CFR-3L



Product Name Product Trade Name: CFR-3L



Recommended Use Recommended Use Friction Reducer







0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Not applicable

_____________________________________________________________________________________________

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_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016




NA 60 - 100%





















_____________________________________________________________________________________________

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Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.



















pH: 7






Physical State: Liquid Color Red

Odor: Musty Odor Threshold:

_____________________________________________________________________________________________

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Liquid Density 9.75 lbs/gal














Toxicity Data





_____________________________________________________________________________________________

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12.1. Toxicity










NA












13.1. Waste treatment methods Disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state,

and local regulations. Substance should NOT be deposited into a sewage facility.








NZ 5433.1999

_____________________________________________________________________________________________

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UN Number Not restricted













HSNO Approval Number Not Hazrdous











_____________________________________________________________________________________________

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_____________________________________________________________________________________________

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SAFETY DATA SHEET

CITRIC ACID


Product Name Product Trade Name: CITRIC ACID



Recommended Use Recommended Use Scale Remover; pH Control







0800 764 766 (24 hours)



Classification 6.1E (Inhalation) Acutely Toxic Substances6.3B Mildly irritating to the skin8.3A Corrosive to ocular tissue


Hazard Pictograms

Signal Word Danger

Hazard Statements H316 - Causes mild skin irritationH318 - Causes serious eye damageH333 - May be harmful if inhaled



_____________________________________________________________________________________________

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Revision Date: 14-May-2015 Revision Number: 33

_____________________________________________________________________________________________P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P280 - Wear eye protection/face protection

Response P304 + P312 - IF INHALED: Call a POISON CENTER or doctor/physician if you feelunwellP331 - Do NOT induce vomitingP332 + P313 - If skin irritation occurs: Get medical advice/attentionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Storage None


Contains


Citric acid 77-92-9 6.1E (Inhalation)6.3B8.3A




Citric acid 77-92-9 60 - 100%




Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Getimmediate medical attention.

Skin For skin contact, wipe away excess material with dry towel. Then wash affected areaswith plenty of water, and soap if available, for several minutes. Get medical attention ifirritation occurs.



Relation to Health Effect Most Important Symptoms/EffectsCauses eye irritation. Causes eye irritation





_____________________________________________________________________________________________

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CITRIC ACID Revision Date: 14-May-2015

_____________________________________________________________________________________________




Special Exposure HazardsDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.







7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location. Product has a shelf life of 60 months.






Citric acid 77-92-9 Not applicable Not applicable



exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard

_____________________________________________________________________________________________

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_____________________________________________________________________________________________EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. (>= 0.35 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.








pH: 1.8

Freezing Point/Range No data available

Melting Point/Range 153 °C / 307.4 °F

Boiling Point/Range Decomposes

Flash Point 345 °C / 653 °F

upper flammability limit 65

lower flammability limit %


Vapor Pressure 0.00000221 Pa





Partition coefficient: n-octanol/water -1.61 to -1.80






9.2. Other information Molecular Weight 192.12




10.4. Conditions to Avoid None anticipated

10.5. Incompatible Materials Strong alkalis.

10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.

Hazardous Reactions

_____________________________________________________________________________________________

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Physical State: Solid Color: White

CITRIC ACID

Odor: Odorless

Revision Date: 14-May-2015

Odor Threshold: No information available

_____________________________________________________________________________________________

Hazardous Polymerization: Will Not Occur




Eye Contact Causes eye irritation.


Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,nausea, and diarrhea.


Toxicity Data



Citric acid 77-92-9 5400 mg/kg (Rat)5790 mg/kg (Mouse)11,700 mg/kg (Rat)

> 2000 mg/kg No data available



Citric acid 77-92-9 Not irritating to skin in rabbits.



Citric acid 77-92-9 Causes severe eye irritation.


Skin Sensitization

Citric acid 77-92-9 Patch test on human volunteers did not demonstrate sensitization properties



Citric acid 77-92-9 No information available


Mutagenic Effects

Citric acid 77-92-9 Did not show mutagenic effects in animal experiments



Citric acid 77-92-9 Did not show carcinogenic effects in animal experiments



Citric acid 77-92-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.



Citric acid 77-92-9 No data of sufficient quality are available.



Citric acid 77-92-9 No significant toxicity observed in animal studies at concentration requiring classification.


Aspiration hazard

Citric acid 77-92-9 No adverse health effects are expected from swallowing.


_____________________________________________________________________________________________

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Revision Date: 14-May-2015CITRIC ACID

_____________________________________________________________________________________________






Citric acid 77-92-9 NOEC (8d) 425 mg/L(cell density)

(Scenedesmusquadricauda)

LOEC (8d) >80 mg/L(Microcystis aeruginosa)

LC50 (96h) 1516 mg/L(Lepomis macrochirus)LC50 (48h) 440 mg/L

(Leuciscus idusmelanotus)

LC50 (96h) >100 mg/L(Pimephales promelas)

TT (72h) 485 mg/L(Entosiphon sulcatum)

TLM96 100-330 ppm(Crangon crangon)

EC50 (24h) 1535 mg/L(Daphnia magna)

LC50 (48h) 160 mg/L(Daphnia magna)

EC50 (48h) >50 mg/L(Daphnia magna)



Citric acid 77-92-9 Readily biodegradable (97% @ 28d)



Citric acid 77-92-9 -1.61 to -1.80



Citric acid 77-92-9 No information available




13.1. Waste treatment methods Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.












_____________________________________________________________________________________________

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_____________________________________________________________________________________________











ERMA Register Approval Number HSR003138








Key literature references and sources for datawww.ChemADVISOR.com/OSHAECHA C&LNZ CCID





_____________________________________________________________________________________________

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SAFETY DATA SHEET

CEMENT - CLASS G


1. Identification

Product Name Product Trade Name: CEMENT - CLASS G



Recommended Use Recommended Use Cement







0800 764 766 (24 hours)



Classification 6.1E (Inhalation) Acutely Toxic Substances8.2C Corrosive to dermal tissue if exposed for greater than 1 hour8.3A Corrosive to ocular tissue6.5B Contact sensitiser6.7A Known or presumed human carcinogen6.9A Toxic to human target organs or systems


Hazard Pictograms

Signal Word Danger

_____________________________________________________________________________________________

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_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018

Hazard Statements H314 - Causes severe skin burns and eye damageH318 - Causes serious eye damageH350i - May cause cancer by inhalationH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH333 - May be harmful if inhaledH317 - May cause an allergic skin reaction


Prevention P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required

Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water [or shower].P353 - Rinse skin with water [or shower].P363 - Wash contaminated clothing before reuseP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP304 + P312 - IF INHALED: Call a POISON CENTER or doctor/physician if you feelunwellP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell



Contains


Portland cement 65997-15-1 6.1E (Inh)8.2C8.3A6.5B




Substances CAS Number PERCENT (w/w)Portland cement 65997-15-1 60 - 100%Crystalline silica, quartz 14808-60-7 1 - 5%





Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention.


_____________________________________________________________________________________________

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Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. May causerespiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silicahas also been associated with scleroderma and kidney disease.




5.1. Extinguishing media Suitable Extinguishing MediaNone - does not burn.






6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Evacuate all persons from the area.See Section 8 for additional information





7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may becomeairborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation tokeep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalentrespirator when using this product. Material is slippery when wet. Wash hands after use. Launder contaminated clothingbefore reuse.


_____________________________________________________________________________________________

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7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Usegood housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product hasa shelf life of 24 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWAPortland cement 65997-15-1 TWA: 10 mg/m3 TWA: 1 mg/m3

Crystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3





Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.

Hand Protection Impervious rubber gloves.








pH: 12.4









Water Solubility No data available






Physical State: Solid Color Gray


_____________________________________________________________________________________________

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10.4. Conditions to avoid Keep away from any contact with water.

10.5. Incompatible materials Hydrofluoric acid.





Inhalation Causes moderate respiratory irritation. Inhaled crystalline silica in the form of quartz orcristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).There is sufficient evidence in experimental animals for the carcinogenicity of tridymite(IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).


Skin Contact Causes skin irritation. May cause alkali burns with confined contact. May cause anallergic skin reaction. Can dry skin.

Ingestion Causes burns of the mouth, throat and stomach.


Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimental animalsfor the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer toIARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) inconjunction with the use of these minerals. The National Toxicology Program classifiesrespirable crystalline silica as "Known to be a human carcinogen". Refer to the 9thReport on Carcinogens (2000). The American Conference of Governmental IndustrialHygienists (ACGIH) classifies crystalline silica, quartz, as a suspected humancarcinogen (A2). There is some evidence that breathing respirable crystalline silica orthe disease silicosis is associated with an increased incidence of significant diseaseendpoints such as scleroderma (an immune system disorder manifested by scarring ofthe lungs, skin, and other internal organs) and kidney disease.

_____________________________________________________________________________________________

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Toxicity Data



Portland cement 65997-15-1 > 2000 mg/kg (Rat) > 2000 mg/kg > 1 mg/L (Rat) 4h




Portland cement 65997-15-1 Irritating to skin. (Rabbit)




Portland cement 65997-15-1 Corrosive to eyes



Skin Sensitization

Portland cement 65997-15-1 May cause sensitization by skin contact




Portland cement 65997-15-1 No information available



Mutagenic Effects

Portland cement 65997-15-1 No data of sufficient quality are available.












Portland cement 65997-15-1 May cause respiratory irritation.







Aspiration hazard

Portland cement 65997-15-1 Not applicable



12.1. Toxicity


_____________________________________________________________________________________________

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Portland cement 65997-15-1 No information available No information available No information available No information available





substance)


substance)



Portland cement 65997-15-1 The methods for determiningbiodegradability are not applicable toinorganic substances.




Portland cement 65997-15-1 No data available




Portland cement 65997-15-1 No information available





13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance

should NOT be deposited into a sewage facility.
















_____________________________________________________________________________________________

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Group Name Construction Products (Corrosive and Toxic 6.7 HSR002543)










Revision NoteUpdate to Format

_____________________________________________________________________________________________

Page 8 / 9

Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination of


suitability of any material is the sole responsibility of the user.


_____________________________________________________________________________________________

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SAFETY DATA SHEET

CLAY GRABBER®

Revision Date: 26-Jan-2018 Revision Number: 31

1. Identification

Product Name Product Trade Name: CLAY GRABBER®










0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains


Hydrotreated light petroleum distillate 64742-47-8 6.1E (Aspiration

Ethoxylated branched C13 alcohol 78330-21-9 6.1D (Oral)6.3A

_____________________________________________________________________________________________

Page 1 / 8

_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018

8.3a9.1D



Substances CAS Number PERCENT (w/w)Hydrotreated light petroleum distillate 64742-47-8 10 - 30%Ethoxylated branched C13 alcohol 78330-21-9 1 - 5%





Skin Wash with soap and water. Get medical attention if irritation persists. Wash offimmediately with soap and plenty of water for at least 15 minutes while removing allcontaminated clothing and shoes. Flush skin with large amounts of water. If irritationpersists, get medical attention.






Type of Hazard Flammability HazardNot a Flammable Hazard.








_____________________________________________________________________________________________

Page 2 / 8

Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.




Prevent product from entering drains




7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse.

HandlingAvoid contact with skin, eyes and clothing. Do not breathing vapors or spray mist. Wash thoroughly after handling Remove andwash contaminated clothing before re-use



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Keep fromfreezing. Product has a shelf life of 12 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWAHydrotreated light petroleumdistillate


Ethoxylated branched C13alcohol





Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeation

_____________________________________________________________________________________________

Page 3 / 8


time as per EN 374): Nitrile gloves. (>= 0.35 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.








pHpH: 6.5 - 7.5




Flash Point > 392 °C / PMCC


Vapor Pressure 0.002



Water Solubility Miscible with water





Viscosity 75 - 125 mm2/s @ 40 °C







10.5. Incompatible materials Strong oxidizers. Contact with metals.

10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.




Physical State: Liquid Physical State Liquid

Color Off white Appearance Off-white

Odor: Mild hydrocarbon Odor Mild, Hydrocarbon-like

Odor Threshold: No information available

_____________________________________________________________________________________________

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Eye Contact In vitro tests indicate that the product is not an eye irritant.


Ingestion May cause mild gastric distress.


Toxicity Data



Hydrotreated lightpetroleum distillate

64742-47-8 >5000 mg/kg-bw (rat) (similarsubstance)

>2000 mg/kg-bw (rabbit) (similarsubstance)

>5.2 mg/L (rat, 4 h, vapor)(similar substance)

Ethoxylated branchedC13 alcohol

78330-21-9 1600 mg/kg-bw (rat) (similarsubstance)

>2000 mg/kg-bw (rabbit) (similarsubstance)

>0.22 mg/L (rat, 4h, aerosol,saturated) (similar substance)




64742-47-8 Non-irritating to the skin (similar substances)


78330-21-9 Skin, rabbit: Causes moderate skin irritation. (similar substances)




64742-47-8 Non-irritating to rabbit's eye (similar substances)


78330-21-9 Eye, rabbit: Causes severe eye irritation which may damage tissue. (similar substances)


Skin Sensitization


64742-47-8 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)






64742-47-8 Based on available data, the classification criteria are not met.




Mutagenic Effects


64742-47-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similarsubstances)


78330-21-9 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similarsubstances)










64742-47-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)


78330-21-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)



_____________________________________________________________________________________________

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Aspiration hazard


64742-47-8 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,wheezing, coughing up blood and pneumonia, which can be fatal.




12.1. Toxicity






64742-47-8 ErL50(72 h)>10000 mg/L(Skeletonema costatum)

LC50(96 h)>10000 mg/L(Scophthalmus

maximus)NOELC(28 d)>1000

mg/L (fish)

No information available LC50(48 h)>10000 mg/L(Acartia tonsa)

NOEC(21 d)=1000 mg/L(Daphnia magna)

Ethoxylated branchedC13 alcohol

78330-21-9 IC50(72 h)=1-10 mg/L(Desmodesmus

subspicatus)

LC50(96 h)=1-10 mg/L(Cyprinus carpio)

No information available EC50(48 h)=1-10 mg/L(Daphnia magna)

NOAEC (21d) 0.77 mg/L(Daphnia magna)



Hydrotreated light petroleum distillate 64742-47-8 Readily biodegradable (68.1% @ 28d)

Ethoxylated branched C13 alcohol 78330-21-9 Readily biodegradable (> 60% @ 28d)



Hydrotreated light petroleum distillate 64742-47-8 No data available

Ethoxylated branched C13 alcohol 78330-21-9 Not Bioaccumulative; BCF = 12.7 - 237L/Kg



Hydrotreated light petroleum distillate 64742-47-8 No information available

Ethoxylated branched C13 alcohol 78330-21-9 No information available





_____________________________________________________________________________________________

Page 6 / 8






























_____________________________________________________________________________________________

Page 7 / 8

Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limit


ppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day


Revision Date: 26-Jan-2018




_____________________________________________________________________________________________

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SAFETY DATA SHEET

CLAY SYNC™ IIRevision Date: 05-Feb-2018 Revision Number: 21

1. Identification

Product Name Product Trade Name: CLAY SYNC™ II










0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Not applicable

_____________________________________________________________________________________________

Page 1 / 7

_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018




NA 60 - 100%




















_____________________________________________________________________________________________

Page 2 / 7

Prevent from entering sewers, waterways, or low areas.





7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Slippery when wet. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a dry location. Store between 40.5 F (4.7 C) and 120.5 F (49 C). Product has a shelf life of24 months.







Engineering Controls Engineering Controls A well ventilated area to control dust levels.


exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)







9.1. Information on basic physical and chemical properties Physical State: Granules Color Off white


_____________________________________________________________________________________________

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pH: 6.5-7.5 (1%)

















9.2. Other information Molecular Weight 500,000-750,000 g/mole


Bulk Density 50 lbs/ft3 @ 20 C














Toxicity Data



Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competent


_____________________________________________________________________________________________

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authority


12.1. Toxicity Ecotoxicity effectsContains no substances known to be hazardous to the environment.










NA














_____________________________________________________________________________________________

Page 5 / 7





























_____________________________________________________________________________________________

Page 6 / 7

Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic meter


mm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day






_____________________________________________________________________________________________

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SAFETY DATA SHEET

DEXTRID® LTE


1. Identification

Product Name Product Trade Name: DEXTRID® LTE



Recommended Use Recommended Use Fluid Loss Additive







0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



_____________________________________________________________________________________________

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_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018





NA 60 - 100%
















Special exposure hazards in a fireOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential. Decomposition in fire may produce harmful gases.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid creating and breathing dust. Ensureadequate ventilation.See Section 8 for additional information

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7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust accumulations. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.















Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket,pants or coverall, as appropriate, to prevent skin contact.




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pH: 10





























Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.


Toxicity Data



Contains no hazardoussubstances in



Odor: Musty Odor Threshold: No information available

_____________________________________________________________________________________________

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concentrations abovecut-off values accordingto the competentauthority


12.1. Toxicity










NA














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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - Celsius


IATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day






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SAFETY DATA SHEET

ECONOLITE LIQUID



Product Name Product Trade Name: ECONOLITE LIQUID



Recommended Use Recommended Use Light Weight Cement Additive







0800 764 766 (24 hours)



Classification 6.1E (Oral) Acutely Toxic Substances6.3A Irritating to the skin8.3A Corrosive to ocular tissue


Hazard pictograms

Signal Word Danger

Hazard Statements H303 - May be harmful if swallowedH315 - Causes skin irritationH318 - Causes serious eye damage



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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016

P102 - Keep out of reach of childrenP103 - Read label before useP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/eye protection/face protection

Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Storage None


Contains


Sodium silicate 1344-09-8 6.1E (oral)6.3A8.3A



Substances CAS Number PERCENT (w/w)Sodium silicate 1344-09-8 30 - 60%





Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention. Remove contaminated clothing and launder beforereuse.



Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation.






HAZCHEM Code

_____________________________________________________________________________________________

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Hazchem Code: None Allocated




6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.See Section 8 for additional information


6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove. Do NOT spread spilled product with water.



7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse. Avoid breathingvapors. Avoid breathing mist. Ensure adequate ventilation. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from acids. Store in a cool well ventilated area. Keep container closed when not in use.





Substances CAS Number New Zealand WES ACGIH TLV-TWASodium silicate 1344-09-8 Not applicable Not applicable




exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.

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Dust/mist respirator. (N95, P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.

Skin Protection Full protective chemical resistant clothing.







pH: 11.2





















10.5. Incompatible materials Strong acids. Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.

10.6. Hazardous decomposition products Hydrogen




Physical State: Liquid Color Clear to hazy

Odor: Slightly soapy Odor Threshold: No information available

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Inhalation May cause respiratory irritation.


Skin Contact Causes skin irritation.



Toxicity Data



Sodium silicate 1344-09-8 3400 mg/kg (Rat) > 5000 mg/kg (Rat) (similarsubstance)

> 2.06 mg/L (Rat) 4h (similarsubstance – Potassium silicate)



Sodium silicate 1344-09-8 Causes moderate skin irritation. (Rabbit)



Sodium silicate 1344-09-8 Causes severe eye irritation which may damage tissue. (Rabbit)


Skin Sensitization

Sodium silicate 1344-09-8 Did not cause sensitization on laboratory animals (mouse) (similar substances)



Sodium silicate 1344-09-8 No information available


Mutagenic Effects

Sodium silicate 1344-09-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.






Sodium silicate 1344-09-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)



Sodium silicate 1344-09-8 No information available.



Sodium silicate 1344-09-8 No significant toxicity observed in animal studies at concentration requiring classification.


Aspiration hazard

Sodium silicate 1344-09-8 Not applicable



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Sodium silicate 1344-09-8 EC50 (72h) > 345 mg/L(growth rate)

(Scenedesmussubspicatus)

EC0 (72h) 35 mg/L(growth rate)

(Scenedesmussubspicatus)

LC50 (96h) 1108 mg/L(Danio rerio)

LC50 (96h) 260 – 310mg/L (Oncorhynchus

mykiss)

EC0 (0.5h) 3454 mg/L(Pseudomonas putida)

EC50 (48h) 1700 mg/L(Daphnia magna)



Sodium silicate 1344-09-8 The methods for determiningbiodegradability are not applicable toinorganic substances.



Sodium silicate 1344-09-8 No data available

























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Poisons Schedule: S5










_____________________________________________________________________________________________

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SAFETY DATA SHEET

EMBR11720A


Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : EMBR11720A

Other means of identification : Not applicable.

Recommended use : DEMULSIFIER

Restrictions on use : Refer to available product literature or ask your local Sales Representative for

restrictions on use and dose limits.

Company : Ecolab New Zealand T/A Nalco New Zealand 2 Daniel Place Te Rapa, Hamilton New Zealand TEL: +64 7 958 2319 FAX: +64 7 958 2361


: 0800 625 253, +64 7 958 2372 (International)

Issuing date : 23.09.2018

Section: 2. HAZARDS IDENTIFICATION

HSNO Hazard classification

Flammable Liquids : 3.1 C Acute toxicity (Oral) : 6.1 E Acute toxicity (Dermal) : 6.1 D Acute toxicity (Inhalation) : 6.1 E Skin irritation : 6.3 A Eye irritation : 6.4 A Carcinogenicity : 6.7 B Specific Target Organ Systemic Toxicity (Single Exposure or Repeated Exposure)

: 6.9 B

Aquatic toxicity (Acute or Chronic)

: 9.1 C

Ecotoxic to terrestrial vertebrates

: 9.3 C

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Flammable liquid and vapour.

May be fatal if swallowed and enters airways. May be harmful if swallowed. Harmful in contact with skin. May cause respiratory irritation. Causes skin irritation. Causes serious eye irritation.

SAFETY DATA SHEET

EMBR11720A


Suspected of causing cancer. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. Harmful to terrestrial vertebrates.

Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Storage: Store in a well-ventilated place. Disposal: Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

Xylene 1330-20-7 60 - 100 Formaldehyde, polymers with branched 4-nonylphenol, ethylene oxide and propylene oxide

153795-76-7 5 - 10

Heavy Aromatic Naphtha 64742-94-5 1 - 5 Naphthalene 91-20-3 0.1 - 1

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops and persists.

If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed - can enter lungs and cause damage. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.

Notes to physician : Treat symptomatically.

SAFETY DATA SHEET

EMBR11720A


Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Foam

Carbon dioxide Dry powder Other extinguishing agent suitable for Class B fires For large fires, use water spray or fog, thoroughly drenching the burning material.

Unsuitable extinguishing media

: None known.

Specific hazards during firefighting

: Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Hazardous combustion products

: Decomposition products may include the following materials: Carbon oxides

Special protective equipment for firefighters

: Use personal protective equipment.

Specific extinguishing methods

: Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Hazchem Code : •3Y

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up

: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Open drum carefully as content may be under

pressure. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Do not ingest. Keep away from fire, sparks and heated surfaces. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Use only with adequate ventilation.

Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated

SAFETY DATA SHEET

EMBR11720A


place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.

Suitable material : Keep in properly labelled containers.

Unsuitable material : not determined

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible concentration

Basis

Xylene 1330-20-7 WES-TWA 50 ppm 217 mg/m3

NZ OEL

Xylene 1330-20-7 TWA 100 ppm 435 mg/m3

OSHA Z1

TWA 100 ppm ACGIH

STEL 150 ppm ACGIH

Heavy Aromatic Naphtha 64742-94-5 TWA 500 ppm 2,000 mg/m3

OSHA Z1

TWA 200 mg/m3 (as total hydrocarbon vapor)

ACGIH

Biological occupational exposure limits

Component CAS-No. Control parameters

Biological specimen

Sampling time Permissible concentration

Basis

Xylene 1330-20-7

Methylhippuric acid

Urine End of shift 1.5 g/l NZ BEI

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below

occupational exposure standards. Personal protective equipment Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment: Standard glove type. NITRILE GLOVES VITON GLOVES Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Refer to AS/NZS 1715 and AS/NZS 1716 for selection, use and maintenance of respiratory protective equipment as applicable.

SAFETY DATA SHEET

EMBR11720A


Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid

Colour : Yellow to Brown

Odour : no data available

Flash point : 27 °C, Method: Pensky-Martens closed cup

pH : 10.50 - 12.10

Odour Threshold : no data available

Melting point/freezing point : no data available

Initial boiling point and boiling range

: no data available

Evaporation rate : no data available

Flammability (solid, gas) : no data available

Upper explosion limit : no data available

Lower explosion limit : no data available

Vapour pressure : no data available

Relative vapour density : no data available

Relative density : 0.87 - 0.97, (25 °C),

Density : no data available

Water solubility : no data available

Solubility in other solvents : no data available


: no data available

Auto-ignition temperature : no data available

Thermal decomposition : no data available

Viscosity, dynamic : no data available

Viscosity, kinematic : < 20.5 mm2/s (40 °C)

Molecular weight : no data available

VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions. Possibility of hazardous reactions

: No dangerous reaction known under conditions of normal use.

Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition : In case of fire, hazardous decomposition products may be produced such as:

SAFETY DATA SHEET

EMBR11720A


products Carbon oxides

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects Eyes : Causes serious eye irritation. Skin : Harmful in contact with skin. Causes skin irritation. Ingestion : May be fatal if swallowed and enters airways. May be harmful if swallowed. Inhalation : May cause respiratory tract irritation. May cause nose, throat, and lung irritation.

Inhalation may cause central nervous system effects. May cause drowsiness or dizziness. Chronic Exposure : Suspected of causing cancer. Experience with human exposure Eye contact : Redness, Pain, Irritation Skin contact : Redness, Irritation Ingestion : Vomiting Inhalation : Respiratory irritation, Cough, Dizziness, Drowsiness Toxicity Product

Acute oral toxicity : Acute toxicity estimate: 647.84 mg/kg

Acute inhalation toxicity : Acute toxicity estimate: 32.39 mg/l Exposure time: 4 h Test atmosphere: vapour

Acute dermal toxicity : Acute toxicity estimate: 1,426 mg/kg

Skin corrosion/irritation : no data available

Serious eye damage/eye irritation

: no data available

Respiratory or skin sensitization

: no data available

Carcinogenicity : This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in experimental animals and inadequate evidence in humans).

Reproductive effects : No toxicity to reproduction

Germ cell mutagenicity : Contains no ingredient listed as a mutagen

SAFETY DATA SHEET

EMBR11720A


Teratogenicity : no data available

STOT - single exposure : no data available

STOT - repeated exposure : no data available

Aspiration toxicity : May be fatal if swallowed and enters airways.

Human Hazard Characterization

Based on our hazard characterization, the potential human hazard is: High

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity Environmental Effects : Harmful to aquatic life with long lasting effects.

Harmful to terrestrial vertebrates.

Product

Toxicity to fish : no data available


: no data available

Toxicity to algae : no data available

Components

Toxicity to fish : Heavy Aromatic Naphtha LC50 Oncorhynchus mykiss (rainbow trout): 3.5 mg/l Exposure time: 96 h

Persistence and degradability no data available Mobility no data available Bioaccumulative potential no data available Other information no data available ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low

Section: 13. DISPOSAL CONSIDERATIONS

Disposal methods : The product should not be allowed to enter drains, water

courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

SAFETY DATA SHEET

EMBR11720A


Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport UN/ID No. : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Xylene Transport hazard class(es) : 3 Packing group : III Hazchem Code : •3Y Air transport (IATA) UN/ID No. : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Xylene Transport hazard class(es) : 3 Packing group : III Sea transport (IMDG/IMO) UN/ID No. : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Xylene Transport hazard class(es) : 3 Packing group : III

Section: 15. REGULATORY INFORMATION

GROUP STANDARD NAME : Additives, Process Chemicals and Raw Materials (Flammable,

Toxic [6.7]) Group Standard 2017 HSNO APPROVAL NUMBER

: HSR002502

INTERNATIONAL CHEMICAL CONTROL LAWS : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.

Section: 16. OTHER INFORMATION

Revision Date : 23.09.2018 Version Number : 1.0 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.

SAFETY DATA SHEET

EMBR11720A


The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Wilhelmsen Ships Service Ltd

ENVIROCLEAN

Catalogue number: 765018Version No: 3.3Safety Data Sheet according to HSNO Regulations

Issue Date: 09/12/2016Print Date: 20/05/2019

L.GHS.NZL.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product IdentifierProduct name ENVIROCLEAN

Synonyms Product Part Number: 765018 (25 liter)

Other means ofidentification

765018, 765018

Relevant identified uses of the substance or mixture and uses advised againstRelevant identified uses Use according to manufacturer's directions.

Details of the supplier of the safety data sheet

Registered companyname

Wilhelmsen ShipsService Ltd Wilhelmsen Ships Service AS*

Outback (M)SDS portal:http://jr.chemwatch.net/outb/account/autologin?login=wilhelmsen

Address6B Wagener PlaceAuckland 1025 NewZealand

Willem Barentszstraat 50 RotterdamNetherlands

--------Use our Outback portal to obtain our(M)SDSs in other languages and/orformat.--------- For questions relating to ourSDSs please use Email:[email protected] Norway

Telephone (+64) 9 8494783 +31 10 4877 777 Not Available

Fax Not Available +31 10 4877888 Not Available

Website Not Available http://www.wilhelmsen.com Not Available

Email Not Available [email protected] Not Available

Emergency telephone numberAssociation /Organisation CHEMTREC Dutch nat. poison centre American Chemistry Council 24hrs

- Chemtrec

Emergency telephonenumbers (+64) 9 8455758 + 31 30 274 88 88 +1 703 527 3887

Other emergencytelephone numbers Not Available Not Available (800) 424 9300

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification [1] Serious Eye Damage Category 1

Continued...

Legend:1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No1272/2008 - Annex VI

Determined byChemwatch using

GHS/HSNO criteria8.3A

Label elements

Hazard pictogram(s)

SIGNAL WORD DANGER

Hazard statement(s)H318 Causes serious eye damage.

Precautionary statement(s) GeneralP101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

Precautionary statement(s) PreventionP280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.

P310 Immediately call a POISON CENTER/doctor/physician/first aider.

Precautionary statement(s) StorageNot Applicable

Precautionary statement(s) DisposalNot Applicable

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

SubstancesSee section below for composition of Mixtures

MixturesCAS No %[weight] Name

160875-66-1* 10-30

161074-93-7* 1-5

112-34-5* 1-5

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Fatty alcohol ethoxylate

Alkylglucosid

2-(2-butoxyethoxy)ethanol

Chemwatch: 9-222074Catalogue number: 765018Version No: 3.3

Page 2 of 12

ENVIROCLEAN


Continued...

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

IngestionImmediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment neededTreat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing mediaThere is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.

Special hazards arising from the substrate or mixtureFire Incompatibility None known.

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Fire/Explosion Hazard

Non combustible. Not considered a significant fire risk, however containers may burn.

May emit poisonous fumes.May emit corrosive fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency proceduresSee section 8

Environmental precautionsSee section 12

Methods and material for containment and cleaning up

Minor Spills

Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.

Major Spills

Moderate hazard.Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage of concentrated product from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue (see Section 13 for specific agent). Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains.


Page 3 of 12

ENVIROCLEAN


Continued...

After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Avoid contact with moisture. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. DO NOT allow clothing wet with material to stay in contact with skin

Other information

Conditions for safe storage, including any incompatibilities

Suitable containerPolyethylene or polypropylene container. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storage incompatibility None known

+ X + O + + +

X — Must not be stored together0 — May be stored together with specific preventions+ — May be stored together

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATANot Available

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

2-(2-butoxyethoxy)ethanol Butoxyethoxy)ethanol, 2-(2-; (Diethylene glycol monobutyl ether) 30 ppm 33 ppm 200 ppm

Ingredient Original IDLH Revised IDLH

Fatty alcohol ethoxylate Not Available Not Available

Alkylglucosid Not Available Not Available

2-(2-butoxyethoxy)ethanol Not Available Not Available

MATERIAL DATASensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposurestandards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations requirethat nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors orsafety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results areunavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, hasbeen to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence fromirritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category systembased on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU)Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA.

Exposure controlsAppropriate engineering Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed


Page 4 of 12

ENVIROCLEAN


Continued...

controls

engineering controls can be highly effective in protecting workers and will typically be independent of worker interactionsto provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an aircontaminant if designed properly. The design of a ventilation system must match the particular process and chemical orcontaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. Thisshould include a review of lens absorption and adsorption for the class of chemicals in use and an account of injuryexperience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readilyavailable. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon aspracticable.

Skin protection See Hand protection below

Hands/feet protection

Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which varyfrom manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of theglove material can not be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.hasto be observed when making a final choice.Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves,hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.

Body protection See Other protection below

Other protection

Overalls. P.V.C. apron.Barrier cream.Skin cleansing cream.Eye wash unit.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical propertiesAppearance Liquid, orange, soluble in water

Physical state Liquid Relative density (Water =1)

1.005 - 1.010

Odour Not Available Partition coefficientn-octanol / water

Not Available

Odour threshold Not Available Auto-ignition temperature(°C)

Not Available

pH (as supplied) 10-11 Decompositiontemperature

Not Available

Melting point / freezingpoint (°C)

Not Available Viscosity (cSt) Not Available

Initial boiling point andboiling range (°C)

>100-760 Molecular weight (g/mol) Not Available

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit(%)

Not Available Surface Tension (dyn/cmor mN/m)

Not Available

Lower Explosive Limit(%)

Not Available Volatile Component(%vol)

Not Available


Page 5 of 12

ENVIROCLEAN


Continued...

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardousdecomposition products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in asubstantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to achemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process, whichinitially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce further lungdamage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory tract irritation oftenresults in an inflammatory response involving the recruitment and activation of many cell types, mainly derived from thevascular system.The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This isbecause of the lack of corroborating animal or human evidence. In the absence of such evidence, care should be takennevertheless to ensure exposure is kept to a minimum and that suitable control measures be used, in an occupationalsetting to control vapours, fumes and aerosols.

Ingestion

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This isbecause of the lack of corroborating animal or human evidence. The material may still be damaging to the health of theindividual, following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident. Presentdefinitions of harmful or toxic substances are generally based on doses producing mortality rather than those producingmorbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupationalsetting however, ingestion of insignificant quantities is not thought to be cause for concern.

Skin Contact

Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in asubstantial number of individuals following direct contact, and/or produces significant inflammation when applied to thehealthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after theend of the exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in aform of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling(oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the microscopic levelthere may be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.The material may accentuate any pre-existing dermatitis conditionSkin contact is not thought to have harmful health effects (as classified under EC Directives); the material may stillproduce health damage following entry through wounds, lesions or abrasions.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemicinjury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage issuitably protected.

EyeWhen applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours ormore after instillation.

Chronic

Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and relatedsystemic problems.Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effectsinvolving organs or biochemical systems.

ENVIROCLEANTOXICITY IRRITATION


Fatty alcohol ethoxylateTOXICITY IRRITATION


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AlkylglucosidTOXICITY IRRITATION



TOXICITY IRRITATION

Dermal (rabbit) LD50: 4120 mg/kg[2] Eye (rabbit): 20 mg/24h moderate

Oral (rat) LD50: 5660 mg/kg[2] Eye (rabbit): 5 mg - SEVERE

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

ENVIROCLEAN

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be dueto a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposureto high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of precedingrespiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes tohours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderateto severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation,without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritatinginhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritatingsubstance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to highconcentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. Thedisorder is characterised by dyspnea, cough and mucus production.

Fatty alcohol ethoxylate

Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products suchas soaps, detergents, and other cleaning products . Exposure to these chemicals can occur through ingestion, inhalation,or contact with the skin or eyes. Studies of acute toxicity show that volumes well above a reasonable intake level wouldhave to occur to produce any toxic response. Moreover, no fatal case of poisoning with alcohol ethoxylates has everbeen reported. Multiple studies investigating the acute toxicity of alcohol ethoxylates have shown that the use of thesecompounds is of low concern in terms of oral and dermal toxicity .Clinical animal studies indicate these chemicals may produce gastrointestinal irritation such as ulcerations of the stomach,pilo-erection, diarrhea, and lethargy. Similarly, slight to severe irritation of the skin or eye was generated when undilutedalcohol ethoxylates were applied to the skin and eyes of rabbits and rats.Alcohol ethoxylates are according to CESIO (2000) classified as Irritant or Harmful depending on the number of EO-units:EO < 5 gives Irritant (Xi) with R38 (Irritating to skin) and R41 (Risk of serious damage to eyes)EO > 5-15 gives Harmful (Xn) with R22 (Harmful if swallowed) - R38/41EO > 15-20 gives Harmful (Xn) with R22-41>20 EO is not classified (CESIO 2000)Oxo-AE, C13 EO10 and C13 EO15, are Irritating (Xi) with R36/38 (Irritating to eyes and skin) .AE are not included in Annex 1 of the list of dangerous substances of the Council Directive 67/548/EEC

In general, alcohol ethoxylates (AE) are readily absorbed through the skin of guinea pigs and rats and through thegastrointestinal mucosa of rats. AE are quickly eliminated from the body through the urine, faeces, and expired air(CO2).Orally dosed AE was absorbed rapidly and extensively in rats, and more than 75% of the dose was absorbed.When applied to the skin of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours). Halfof the absorbed surfactant was excreted promptly in the urine and smaller amounts of AE appeared in the faeces andexpired air (CO2) ). The metabolism of C12 AE yields PEG, carboxylic acids, and CO2 as metabolites. The LD50 valuesafter oral administration to rats range from about 1-15 g/kg body weight indicating a low to moderate acute toxicity.

Alkylglucosid

Alkyl glycosides (syn: alkyl polyglucosides, alkyl polyglycosides, APGs) are considered non-irritating to skin, butirritating to eyes at very high concentrations. A general classification of a 65% C8 alkyl glycoside solution according tothe Substance Directive 67/548/EEC is Irritating (Xi) with the risk phrase R41 (Risk of serious damage to the eyes) or R36(Irritating to the eyes) (Akzo Nobel 1998).Acute toxicity:In single dose dermal studies with caprylyl/capryl glucoside and C10-16 alkyl glucoside (both 50% a.i., n:1.6) in rabbits,the LD50 was greater than the 2000 mg/kg dose administered. In oral studies with the same test substances, none of themice dosed with 2000 mg/kg caprylyl glucoside and none of the rats dosed with 5000 mg/kg C10-16 alkyl glucoside diedduring the study.Ocular:In system studies for ocular irritation, the ocular irritation potential of decyl, lauryl, C10-16 alkyl, and coco-glucosideswas non to slightly irritating and of caprylyl/ capryl glucoside was highly irritating. In a HET-CAM study with APG ofvarying proportions of alkyl chain length, the ocular irritation potential increased with the increased proportion ofshorter-chain APGs. In studies using rabbits, neutralized lauryl glucoside produced slight ocular reactions.


The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposureto irritants may produce conjunctivitis.For diethylene glycol monoalkyl ethers and their acetates:This category includes diethylene glycol ethyl ether (DGEE), diethylene glycol propyl ether (DGPE) diethylene glycolbutyl ether (DGBE) and diethylene glycol hexyl ether (DGHE) and their acetates.


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ENVIROCLEAN


Continued...

Legend: – Data either not available or does not fill the criteria for classification– Data available to make classification

Acute toxicity: There are adequate oral, inhalation and/or dermal toxicity studies on the category members. Oral LD50values in rats for all category members are all > 3000 mg/kg bw, with values generally decreasing with increasingmolecular weight. Four to eight hour acute inhalation toxicity studies were conducted for all category members exceptDGPE in rats at the highest vapour concentrations achievable. No lethality was observed for any of these materials underthese conditions. Dermal LD50 values in rabbits range from 2000 mg/kg bw (DGHE) to 15000 mg/kg bw (DGEEA). Signsof acute toxicity in rodents are consistent with non-specific CNS depression typical of organic solvents in general.

Fatty alcohol ethoxylate &Alkylglucosid

No significant acute toxicological data identified in literature search.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious EyeDamage/Irritation STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - RepeatedExposure

Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENVIROCLEANENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

NotAvailable

Not Available Not AvailableNotAvailable

NotAvailable

Fatty alcohol ethoxylateENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

NotAvailable


NotAvailable

AlkylglucosidENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

NotAvailable


NotAvailable


ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 1-300mg/L 2

EC50 48 Crustacea 4-950mg/L 2

EC50 72 Algae or other aquatic plants 1-101mg/L 2

NOEC 96 Algae or other aquatic plants >=100mg/L 1

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - AquaticToxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic ToxicityData 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -Bioconcentration Data 8. Vendor Data

DO NOTdischarge concentrated product into sewer or waterways.

Persistence and degradabilityIngredient Persistence: Water/Soil Persistence: Air

2-(2-butoxyethoxy)ethanol LOW LOW

Bioaccumulative potentialIngredient Bioaccumulation

2-(2-butoxyethoxy)ethanol LOW (BCF = 0.46)

Mobility in soilIngredient Mobility

2-(2-butoxyethoxy)ethanol LOW (KOC = 10)


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Continued...

Chemwatch: 9-222074 Catalogue number: 765018 Version No: 3.3

Page 9 of 12 ENVIROCLEAN


Continued...

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging disposal

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate:

Reduction Reuse Recycling Disposal (if all else fails)

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be appropriate.

It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017

Disposal Requirements Packages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from the package. The package must be disposed according to the manufacturer's directions taking into account the material it is made of. Packages which hazardous content have been appropriately treated and removed may be recycled.

The hazardous substance must only be disposed if it has been treated by a method that changed the characteristics or composition of the substance and it is no longer hazardous. Only dispose to the environment if a tolerable exposure limit has been set for the substance. Only deposit the hazardous substance into or onto a landfill or sewage facility or incinerator, where the hazardous substance can be handled and treated appropriately.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

NO

Not Applicable

HAZCHEM Not Applicable

Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture This substance is to be managed using the conditions specified in an applicable Group Standard

HSR Number Group Standard

Continued...

Chemwatch: 9-222074 Catalogue number: 765018 Version No: 3.3

Page 10 of 12 ENVIROCLEAN


HSR002530 Cleaning Products (Subsidiary Hazard) Group Standard 2017

FATTY ALCOHOL ETHOXYLATE(160875-66-1*) IS FOUND ON THE FOLLOWING REGULATORY LISTS

New Zealand Inventory of Chemicals (NZIoC)

ALKYLGLUCOSID(161074-93-7*) IS FOUND ON THE FOLLOWING REGULATORY LISTS

International Air Transport Association (IATA) Dangerous Goods Regulations International Maritime Dangerous Goods Requirements (IMDG Code)

New Zealand Land Transport Rule: Dangerous Goods 2005 - Schedule 1 Quantity limits United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)

2-(2-BUTOXYETHOXY)ETHANOL(112-34-5*) IS FOUND ON THE FOLLOWING REGULATORY LISTS

GESAMP/EHS Composite List - GESAMP Hazard Profiles IMO IBC Code Chapter 17: Summary of minimum requirements IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances

IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals - Classification Data New Zealand Inventory of Chemicals (NZIoC)

Hazardous Substance Location Subject to the Health and Safety at Work (Hazardous Substances) Regulations 2017.

Hazard Class Quantity beyond which controls apply for closed containers

Quantity beyond which controls apply when use occurring in open containers

Not Applicable Not Applicable Not Applicable

Certified Handler

Subject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

Class of substance Quantities

Not Applicable Not Applicable

Refer Group Standards for further information

Tracking RequirementsNot Applicable

National Inventory StatusNational Inventory Status

Australia - AICS No (Alkylglucosid)

Canada - DSL No (Alkylglucosid; Fatty alcohol ethoxylate)

Canada - NDSL No (2-(2-butoxyethoxy)ethanol; Fatty alcohol ethoxylate)

China - IECSC Yes

Europe - EINEC / ELINCS /NLP

No (Fatty alcohol ethoxylate)

Japan - ENCS No (Fatty alcohol ethoxylate)

Korea - KECI No (Alkylglucosid)

New Zealand - NZIoC No (Alkylglucosid)

Philippines - PICCS No (Alkylglucosid; Fatty alcohol ethoxylate)

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ No (Alkylglucosid; Fatty alcohol ethoxylate)

Vietnam - NCI Yes

Russia - ARIPS No (Alkylglucosid; Fatty alcohol ethoxylate)

Thailand - TECI No (Alkylglucosid; Fatty alcohol ethoxylate)

Legend:Yes = All declared ingredients are on the inventoryNo = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specificingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 09/12/2016

Initial Date 09/12/2016

CONTACT POINT- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheetWilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.: +31 104877775

Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current oravailable engineering controls must be considered.

Definitions and abbreviationsPC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold Value


Page 11 of 12

ENVIROCLEAN


Continued...

BCF: BioConcentration FactorsBEI: Biological Exposure Index

Notes

“This composition meets the criteria for not being harmful to the marine environment according to MARPOL Annex V and may be

discharged into the sea when used to clean cargo holds and external surfaces on ships.”

Powered by AuthorITe, from Chemwatch.


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ENVIROCLEAN


end of SDS

SAFETY DATA SHEETERIFON CLS 40 (NZ) Infosafe No.: LQ92D

ISSUED Date : 19/09/2018ISSUED by: MACDERMID OFFSHORE

SOLUTIONS

1. IDENTIFICATION

GHS Product IdentifierERIFON CLS 40 (NZ)

Company NameMACDERMID OFFSHORE SOLUTIONS (ABN 84 133 834 812)

Address29 Dennis Street Campbellfield,VIC 3061 Australia

Telephone/Fax NumberTel: +61 3 9303 5150

Emergency phone number+61 3 9303 5150 (9-5pm)

Recommended use of the chemical and restrictions on useClosed loop BOP fluid.

DisclaimerMacDermid Offshore Solutions is the trading name of MacDermid Canning Limited.

2. HAZARD IDENTIFICATION

GHS classification of the substance/mixtureClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.Not classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.6.1D (Oral) - Substance that is acutely toxic6.3B Substance that is mildly irritating to the skin6.4A Substance that is irritating to the eyes6.9A (Single exposure) - Substance that is toxic to human target organs or systems6.9A (Repeated exposure) - Substance that is toxic to human target organs or systems9.3C Substance that is harmful to terrestrial vertebrates

Signal Word (s)DANGER

Hazard Statement (s)H302 Harmful if swallowed.H316 Causes mild skin irritation.H319 Causes serious eye irritation.H370 Causes damage to organs (kidney, nervous system) by ingestion.H372 Causes damage to organs (kidney) through prolonged or repeated exposure by ingestion.H433 Harmful to terrestrial vertebrates.

Page 1 / 8

Pictogram (s)Exclamation mark,Health hazard

Precautionary statement – PreventionP102 Keep out of reach of children.P103 Read label before use.P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement – ResponseP101 If medical advice is needed, have product container or label at hand.P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.P314 Get medical advice/attention if you feel unwell.P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P330 Rinse mouth.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.P337+P313 If eye irritation persists: Get medical advice/attention.P332+P313 If skin irritation occurs: Get medical advice/attention.

Precautionary statement – StorageP405 Store locked up.

Precautionary statement – DisposalP501 In the case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, alabel must provide a description of one or more appropriate and achievable methods for the disposal of a substance in accordancewith the Hazardous Substances (Disposal) Regulations 2001. This may also include any method of disposal that must be avoided.See Section 13 for disposal details.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients

Name CAS Proportion

Ethylene glycol 107-21-1 35-<50 %

1-Propanol, 2-(dimethylamino)-2-methyl- 7005-47-2 1-<3 %

Ingredients determined not to be hazardous, includingwater.

Balance

4. FIRST-AID MEASURES

InhalationIf inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seekmedical attention.

IngestionDo not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.

SkinRemove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothingbefore reuse or discard. Seek medical attention.

Page 2 / 8

Eye contactIf in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing forseveral minutes until all contaminants are washed out completely. Seek medical attention.

First Aid FacilitiesEyewash, safety shower and normal washroom facilities.

Advice to DoctorTreat symptomatically.

Other InformationFor advice in an emergency, contact a Poisons Information Centre or a doctor at once. (0800 764 766)

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing MediaUse appropriate fire extinguisher for surrounding environment.

Hazards from Combustion ProductsUnder fire conditions this product may emit toxic and/or irritating fumes, smoke and gases including carbon monoxide, carbondioxide and oxides of nitrogen.

Specific Hazards Arising From The ChemicalFollowing evaporation of the aqueous component under fire conditions, the non-aqueous component may decompose and/or burn.

Decomposition TemperatureNot available

Precautions in connection with FireFire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode.Fight fire from safe location.

6. ACCIDENTAL RELEASE MEASURES

Emergency ProceduresWear appropriate personal protective equipment and clothing to prevent exposure. If possible contain the spill. Place inertabsorbent material onto spillage. Collect the material and place into a suitable labelled container. Do not dilute material butcontain. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterwaysoccurs inform the local water and waste management authorities in accordance with local regulations.

7. HANDLING AND STORAGE

Precautions for Safe HandlingAvoid inhalation of vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when notin use. Prevent the build up of mists or vapours in the work atmosphere. Maintain high standards of personal hygiene i.e. Washinghands prior to eating, drinking, smoking or using toilet facilities.

Conditions for safe storage, including any incompatibilitiesStore in a cool, dry, well-ventilated area, out of direct sunlight. Protect from freezing. Store in suitable, labelled containers. Keepcontainers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local andnational regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure limit valuesNo exposure value assigned for this material. However, the available exposure limits for ingredients are listed below:

Ethylene glycolTWA: 50 ppm, 127 mg/m³ (Vapour and mist)Notices: Ceiling.

TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-

Page 3 / 8

hour working day, for a five-day week.Ceiling: A concentration that should not be exceeded during any part of the working day.

Source: Workplace Exposure Standards and Biological Exposure Indices.

Biological Limit ValuesNo biological limits allocated.

Appropriate Engineering ControlsThis substance is hazardous and should be used with a local exhaust ventilation system, drawing vapours away from workers'breathing zone. If the engineering controls are not sufficient to maintain concentrations of vapours/mists below the exposurestandards, suitable respiratory protection must be worn.

Respiratory ProtectionIf engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable vapor/mistfilter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements.Reference should be made to Australian Standards AS/NZS 1715 (2009), Selection, Use and Maintenance of Respiratory ProtectiveDevices; and AS/NZS 1716 (2012), Respiratory Protective Devices, in order to make any necessary changes for individualcircumstances.

Eye ProtectionSafety glasses with side shields, chemical goggles or full-face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform to relevant regulations.Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 2 & 6 (2012) - Eye Protectors for IndustrialApplications.

Hand ProtectionWear gloves of impervious material such as nitrile, latex rubber or neoprene (>8 hours breakthrough time). Final choice ofappropriate gloves will vary according to individual circumstances. i.e. methods of handling or according to risk assessmentsundertaken. Occupational protective gloves should conform to relevant regulations.Reference should be made to AS/NZS 2161.1 (2016): Occupational protective gloves - Selection, use and maintenance.

Body ProtectionSuitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron isrecommended where large quantities are handled.

9. PHYSICAL AND CHEMICAL PROPERTIES

Properties Description Properties Description

Form Liquid Appearance Liquid

Colour Straw Odour Amine-like

Decomposition Temperature Not available Melting Point Not available

Boiling Point 100 °C Solubility in Water Not available

pH 9.6 Vapour Pressure Not available

Vapour Density (Air=1) Not available Evaporation Rate Not available

Odour Threshold Not available Viscosity 4 cSt (20 °C)

Partition Coefficient: n-octanol/water

Not available Density 1.07 g/cm³ (15.6 °C)

Flash Point Not available Flammability Non flammable

Auto-Ignition Temperature Not applicable Flammable Limits - Lower Not available

Flammable Limits - Upper Not available

10. STABILITY AND REACTIVITY

Chemical StabilityStable under normal conditions of storage and handling.

Page 4 / 8

Reactivity and StabilityReacts with incompatible materials.

Conditions to AvoidExtremes of temperature and direct sunlight.

Incompatible materialsNot available

Hazardous Decomposition ProductsThermal decomposition may result in the release of toxic and/or irritating fumes, smoke and gases including: carbon monoxide,carbon dioxide and oxides of nitrogen.

Possibility of hazardous reactionsUnder normal conditions of storage and use, hazardous reactions will not occur.

11. TOXICOLOGICAL INFORMATION

Toxicology InformationThe available toxicity data for product and ingredients is given below.

Acute Toxicity - OralAcute toxicity estimates (ATE): 1214.5 mg/kg

Acute Toxicity - DermalEthylene glycolLD50(mouse - male, female): 3500 mg/kg

IngestionHarmful if swallowed. Ingestion of this product may cause irritation to the mouth, throat, oesophagus and stomach with symptomsof nausea, abdominal discomfort, vomiting and diarrhoea.

InhalationInhalation of product vapours may cause irritation of the nose, throat and respiratory system.

SkinCauses mild skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness andcracking and may lead to dermatitis.

EyeCauses serious eye irritation. On eye contact this product will cause tearing, stinging, blurred vision, and redness.

Respiratory sensitisationNot expected to be a respiratory sensitiser.

Skin SensitisationNot expected to be a skin sensitiser.

Germ cell mutagenicityNot considered to be a mutagenic hazard.

CarcinogenicityNot considered to be a carcinogenic hazard.

Reproductive ToxicityNot considered to be toxic to reproduction.

STOT-single exposureCauses damage to organs (kidney, nervous system) by ingestion.

STOT-repeated exposureCauses damage to organs (kidney) through prolonged or repeated exposure by ingestion.

Aspiration HazardNot expected to be an aspiration hazard.

Page 5 / 8

12. ECOLOGICAL INFORMATION

EcotoxicityHarmful to terrestrial vertebrates.

Persistence and degradability1-Propanol, 2-(dimethylamino)-2-methyl-Degradability: 31 % - Inherent - 28 days

MobilityNot available

Bioaccumulative PotentialEthylene glycolLogPow: -1.36, low bioaccumulative potential

Other Adverse EffectsNot available

Environmental ProtectionPrevent this material entering waterways, drains and sewers.

Acute Toxicity - FishEthylene glycolLC50(Pimephales promelas): 72,860 mg/l/96h (fresh water)LC50(Pimephales promelas): 8050 mg/l/96h (fresh water)

Acute Toxicity - DaphniaEthylene glycolEC50(Daphnia magna): >100 mg/l/48h (fresh water)LC50(Daphnia magna - Neonate): 41,000 mg/l/48h (fresh water)

Acute Toxicity - AlgaeEthylene glycolEC50(Pseudokirchneriella subcapitata): >6500 mg/l/96h (fresh water)

Acute Toxicity - Other OrganismsEthylene glycolLC50(Crangon crangon - Adult): 100 mg/l/48h (marine water)EC50(Micro-organism): >1995 mg/l/30min (fresh water)

13. DISPOSAL CONSIDERATIONS

Disposal considerationsProduct Disposal:Product wastes are controlled wastes and should be disposed of in accordance with all applicable local and national regulations.This product can be disposed through a licensed commercial waste collection service. In this specific case the product is water-based/water-soluble and therefore can be sent through a Waste Water Treatment Plant and after treatment can be dischargedinto environment through the sewerage or drainage systems as authorized.

Personal protective clothing and equipment as specified in Section 8 of this SDS must be worn during handling and disposal of thisproduct. The ventilation requirements as specified in the same section must also be followed, and the precautions given in Section7 of this SDS regarding handling must also be followed. Do not dispose into the sewerage system. Do not discharge into drains orwatercourses or dispose where ground or surface waters may be affected.

In New Zealand, the disposal agency or contractor must comply with the New Zealand Hazardous Substances (Disposal) Regulations2001. Further details regarding disposal can be obtained on the EPA New Zealand website under specific group standards.

Container Disposal:The container or packaging must be cleaned and rendered incapable of holding any substance. It can then be disposed of in amanner consistent with that of the substance it contained. In this instance the packaging can be disposed through a commercialwaste collection service.

Page 6 / 8

Alternatively, the container or packaging can be recycled if the hazardous residues have been thoroughly cleaned or rendered non-hazardous.

In New Zealand, the packaging (that may or may not hold any residual substance) that is lawfully disposed of by householders orother consumers through a public or commercial waste collection service is a means of compliance with regulations.

14. TRANSPORT INFORMATION

Transport InformationNot classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous GoodsRegulations for transport by air.Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transportby sea.

U.N. NumberNone Allocated

UN proper shipping nameNone Allocated

Transport hazard class(es)None Allocated

IMDG Marine pollutantNo

Transport in BulkNot available

Special Precautions for UserNot available

15. REGULATORY INFORMATION

Regulatory informationClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.All components of this product are listed on the New Zealand Inventory of Chemicals (NZIoC) or exempted.

Group Standard: Lubricants, Lubricant Additives, Coolants and Anti-freeze Agents (Subsidiary Hazard) Group Standard 2006

HSNO Approval NumberHSR002606

16. OTHER INFORMATION

Date of preparation or last revision of SDSSDS created: September 2018

ReferencesWorkplace Exposure Standards and Biological Exposure Indices.Transport of Dangerous goods on land NZS 5433.Preparation of Safety Data Sheets - Approved Code of Practice Under the HSNO Act 1996 (HSNO CoP 8-1 09-06).Assigning a hazardous substance to a group standard.Adopted biological exposure determinants, American Conference of Industrial Hygienists (ACGIH).

Contact Person/PointMr Anthony DalleoreGeneral Manager Ph +61 3 9303 5150

Mr Bruce GrayQES officer Ph +61 3 9303 5150

Page 7 / 8

The data included herein presented according to MacDermid Offshore Solutions practices current at the time of preparation hereof,is made available solely for the consideration, investigation and verification of the original recipients hereof and does not

constitute a representation or warranty for which MacDermid Offshore Solutions assumes legal responsibility. It is theresponsibility of a recipient for this data to remain currently informed on chemical hazard information, to design and update itsown safety program and to comply with all Federal, State and Local laws and regulations applicable to safety, occupational health,right to know and environmental protection.

END OF SDS© Copyright Chemical Safety International Pty Ltd

Copyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe SDS displayed is the intellectual property of ChemicalSafety International Pty Ltd.Copyright in the layout, presentation and appearance of each Infosafe SDS displayed is the intellectual property of Chemical Safety International Pty Ltd.The compilation of SDS’s displayed is the intellectual property of Chemical Safety International Pty Ltd.Copying of any SDS displayed is permitted for personal use only and otherwise is not permitted. In particular the SDS’s displayed cannot be copied for the purpose of sale or licence or forinclusion as part of a collection of SDS without the express written consent of Chemical Safety International Pty Ltd.

Page 8 / 8

SAFETY DATA SHEETERIFON HD 603 HP NO DYE (NZ) Infosafe No.: LQ92A

ISSUED Date : 19/09/2018ISSUED by: MACDERMID OFFSHORE

SOLUTIONS

1. IDENTIFICATION

GHS Product IdentifierERIFON HD 603 HP NO DYE (NZ)

Company NameMACDERMID OFFSHORE SOLUTIONS (ABN 84 133 834 812)

Address29 Dennis Street Campbellfield,VIC 3061 Australia

Telephone/Fax NumberTel: +61 3 9303 5150

Emergency phone number+61 3 9303 5150 (9-5pm)

Recommended use of the chemical and restrictions on useOpen loop BOP fluid.

DisclaimerMacDermid Offshore Solutions is the trading name of MacDermid Canning Limited.

2. HAZARD IDENTIFICATION

GHS classification of the substance/mixtureClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.Not classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.6.1D (Oral) - Substance that is acutely toxic6.3A Substance that is irritating to the skin6.9A (Single exposure) - Substance that is toxic to human target organs or systems6.9A (Repeated exposure) - Substance that is toxic to human target organs or systems8.3A Substance that is corrosive to ocular tissue9.1C Substance that is harmful in the aquatic environment9.3C Substance that is harmful to terrestrial vertebrates

Signal Word (s)DANGER

Hazard Statement (s)H302 Harmful if swallowed.H315 Causes skin irritation.H318 Causes serious eye damage.H370 Causes damage to organs (kidney, nervous system) by ingestion.H372 Causes damage to organs (kidney) through prolonged or repeated exposure by ingestion.H412 Harmful to aquatic life with long lasting effects.H433 Harmful to terrestrial vertebrates.

Page 1 / 9

Pictogram (s)Exclamation mark,Health hazard,Corrosion

Precautionary statement – PreventionP102 Keep out of reach of children.P103 Read label before use.P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement – ResponseP101 If medical advice is needed, have product container or label at hand.P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P330 Rinse mouth.P302+P352 IF ON SKIN: Wash with plenty of soap and water.P332+P313 If skin irritation occurs: Get medical advice/attention.P362 Take off contaminated clothing and wash before reuse.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.P310 Immediately call a POISON CENTER or doctor/physician.P314 Get medical advice/attention if you feel unwell.

Precautionary statement – DisposalP501 In the case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, alabel must provide a description of one or more appropriate and achievable methods for the disposal of a substance in accordancewith the Hazardous Substances (Disposal) Regulations 2001. This may also include any method of disposal that must be avoided.See Section 13 for disposal details.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients

Name CAS Proportion

Ethylene glycol 107-21-1 25-<35 %

Amides, tall-oil fatty, N,N-bis(hydroxyethyl) 68155-20-4 10-<20 %

Decanoic Acid 334-48-5 5-<10 %

Diethanolamine 111-42-2 5-<7 %

N,N'-methylene-bis [5-methyloxazolidine] 66204-44-2 1-<3 %

Ingredients determined not to be hazardous, includingwater.

Balance

4. FIRST-AID MEASURES

InhalationIf inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seekmedical attention.

IngestionDo not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.

Page 2 / 9

SkinRemove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothingbefore reuse or discard. Seek medical attention.

Eye contactIf in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing untiladvised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Seek immediate medical attention.

First Aid FacilitiesEyewash, safety shower and normal washroom facilities.

Advice to DoctorTreat symptomatically.

Other InformationFor advice in an emergency, contact a Poisons Information Centre or a doctor at once. (0800 764 766)

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing MediaUse appropriate fire extinguisher for surrounding environment.

Hazards from Combustion ProductsUnder fire conditions this product may emit toxic and/or irritating fumes, smoke and gases including carbon monoxide, carbondioxide and oxides of nitrogen.

Specific Hazards Arising From The ChemicalFollowing evaporation of the aqueous component under fire conditions, the non-aqueous component may decompose and/or burn.

Decomposition TemperatureNot available

Precautions in connection with FireFire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode.Fight fire from safe location.

6. ACCIDENTAL RELEASE MEASURES

Emergency ProceduresWear appropriate personal protective equipment and clothing to prevent exposure. If possible contain the spill. Place inertabsorbent material onto spillage. Collect the material and place into a suitable labelled container. Do not dilute material butcontain. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterwaysoccurs inform the local water and waste management authorities in accordance with local regulations.

7. HANDLING AND STORAGE

Precautions for Safe HandlingAvoid inhalation of vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when notin use. Prevent the build up of mists or vapours in the work atmosphere. Maintain high standards of personal hygiene i.e. Washinghands prior to eating, drinking, smoking or using toilet facilities.

Conditions for safe storage, including any incompatibilitiesStore in a cool, dry, well-ventilated area, out of direct sunlight. Protect from freezing. Store in suitable, labelled containers. Keepcontainers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local andnational regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure limit valuesNo exposure value assigned for this material. However, the available exposure limits for ingredients are listed below:

Ethylene glycol

Page 3 / 9

TWA: 50 ppm, 127 mg/m³ (Vapour and mist)Notices: Ceiling.

DiethanolamineTWA: 3 ppm, 13 mg/m³

TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day week.Ceiling: A concentration that should not be exceeded during any part of the working day.

Source: Workplace Exposure Standards and Biological Exposure Indices.

Biological Limit ValuesNo biological limits allocated.

Appropriate Engineering ControlsThis substance is hazardous and should be used with a local exhaust ventilation system, drawing vapours away from workers'breathing zone. If the engineering controls are not sufficient to maintain concentrations of vapours/mists below the exposurestandards, suitable respiratory protection must be worn.

Respiratory ProtectionIf engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable vapor/mistfilter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements.Reference should be made to Australian Standards AS/NZS 1715 (2009), Selection, Use and Maintenance of Respiratory ProtectiveDevices; and AS/NZS 1716 (2012), Respiratory Protective Devices, in order to make any necessary changes for individualcircumstances.

Eye ProtectionSafety glasses with full face shield should be used. Eye protection devices should conform to relevant regulations.Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 2 & 6 (2012) - Eye Protectors for IndustrialApplications.

Hand ProtectionWear gloves of impervious material such as nitrile, latex rubber or neoprene (>8 hours breakthrough time). Final choice ofappropriate gloves will vary according to individual circumstances. i.e. methods of handling or according to risk assessmentsundertaken. Occupational protective gloves should conform to relevant regulations.Reference should be made to AS/NZS 2161.1 (2016): Occupational protective gloves - Selection, use and maintenance.

Body ProtectionSuitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron isrecommended where large quantities are handled.

9. PHYSICAL AND CHEMICAL PROPERTIES

Properties Description Properties Description

Form Liquid Appearance Liquid

Colour Amber Odour Amine-like

Decomposition Temperature Not available Melting Point Not available

Boiling Point 100 °C Solubility in Water Not available

pH 10 Vapour Pressure Not available

Vapour Density (Air=1) Not available Evaporation Rate Not available

Odour Threshold Not available Viscosity 20 cSt (20 °C)

Partition Coefficient: n-octanol/water

Not available Density 1.06 g/cm³ (20 °C)

Flash Point Not available Flammability Non flammable

Auto-Ignition Temperature Not applicable Flammable Limits - Lower Not available

Flammable Limits - Upper Not available

Page 4 / 9

10. STABILITY AND REACTIVITY

Chemical StabilityStable under normal conditions of storage and handling.

Reactivity and StabilityReacts with incompatible materials.

Conditions to AvoidExtremes of temperature and direct sunlight.

Incompatible materialsNot available

Hazardous Decomposition ProductsThermal decomposition may result in the release of toxic and/or irritating fumes, smoke and gases including: carbon monoxide,carbon dioxide and oxides of nitrogen.

Possibility of hazardous reactionsUnder normal conditions of storage and use, hazardous reactions will not occur.

11. TOXICOLOGICAL INFORMATION

Toxicology InformationThe available toxicity data for product and ingredients is given below.

Acute Toxicity - OralAcute toxicity estimates (ATE): 1287.7 mg/kg

Acute Toxicity - InhalationAcute toxicity estimates (ATE value)Inhalation (vapours): 440 mg/lInhalation (dusts and mists): 44.44 mg/l

Acute Toxicity - DermalEthylene glycolLD50(mouse - male, female): 3500 mg/kg

IngestionHarmful if swallowed. Ingestion of this product may cause irritation to the mouth, throat, oesophagus and stomach with symptomsof nausea, abdominal discomfort, vomiting and diarrhoea.

InhalationInhalation of product vapours may cause irritation of the nose, throat and respiratory system.

SkinCauses skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness and crackingand may lead to dermatitis.

DiethanolamineSpecies: rabbitExposure: 500mg (24h)Result: Mild irritant

Decanoic AcidSpecies: rabbitExposure: 50mgResult: Mild irritant

EyeCauses eye damage. Eye contact will cause stinging, blurring, tearing, severe pain and possible burns, necrosis, permanent damageand blindness.

DiethanolamineSpecies: rabbit

Page 5 / 9

Exposure: 750 mg (24h)Result: Severe irritant

Exposure: 5500 mg (24h)Result: Severe irritant

Decanoic AcidSpecies: rabbitExposure: 72hScore: >2Result: Cornea opacity

Respiratory sensitisationNot expected to be a respiratory sensitiser.

Skin SensitisationNot expected to be a skin sensitiser.

Decanoic AcidSpecies: Guinea pigResult: Not sensitizing

Germ cell mutagenicityNot considered to be a mutagenic hazard.

CarcinogenicityNot considered to be a carcinogenic hazard.

Diethanolamine is listed as a Group 2B: Possibly carcinogenic to humans according to International Agency for Research on Cancer(IARC).

Reproductive ToxicityNot considered to be toxic to reproduction.

STOT-single exposureCauses damage to organs (kidney, nervous system) by ingestion.

STOT-repeated exposureCauses damage to organs (kidney) through prolonged or repeated exposure by ingestion.

Aspiration HazardNot expected to be an aspiration hazard.

12. ECOLOGICAL INFORMATION

EcotoxicityHarmful to aquatic life with long lasting effects. Harmful to terrestrial vertebrates.

Persistence and degradabilityDiethanolamineDegradability: 93 % - Readily - 28 days

Decanoic AcidDegradability: >60 % - Readily - 30 days (OECD 301D)

MobilityNot available

Bioaccumulative PotentialEthylene glycolLogPow: -1.36, low bioaccumulative potential

DiethanolamineLogPow: -1.43, low bioaccumulative potential

Other Adverse EffectsNot available

Page 6 / 9

Environmental ProtectionPrevent this material entering waterways, drains and sewers.

Acute Toxicity - FishEthylene glycolLC50(Pimephales promelas): 72,860 mg/l/96h (fresh water)LC50(Pimephales promelas): 8050 mg/l/96h (fresh water)

DiethanolamineLC50(Pimephales promelas - Juvenile): 100 mg/l/96h (fresh water)(fledgling, hatchling, weanling)

Decanoic AcidLC50(fish): 275 mg/l/96h

Acute Toxicity - DaphniaEthylene glycolEC50(Daphnia magna): >100 mg/l/48h (fresh water)LC50(Daphnia magna - Neonate): 41,000 mg/l/48h (fresh water)

DiethanolamineLC50(Daphnia magna): 55,000 mìcrog/l/48h (fresh water)

Decanoic AcidEC50(Daphnia): >20 mg/l/48h

Acute Toxicity - AlgaeEthylene glycolEC50(Pseudokirchneriella subcapitata): >6500 mg/l/96h (fresh water)

DiethanolamineEC50(Pseudokirchneriella subcapitata): 12 mg/l/96h (fresh water)

Acute Toxicity - Other OrganismsEthylene glycolLC50(Crangon crangon - Adult): 100 mg/l/48h (marine water)EC50(Micro-organism): >1995 mg/l/30min (fresh water)

DiethanolamineLC50(Ceriodaphnia dubia - Neonate): 28,800 mìcrog/l/48h (fresh water)

13. DISPOSAL CONSIDERATIONS

Disposal considerationsProduct Disposal:Product wastes are controlled wastes and should be disposed of in accordance with all applicable local and national regulations.This product can be disposed through a licensed commercial waste collection service. In this specific case the product is water-based/water-soluble and therefore can be sent through a Waste Water Treatment Plant and after treatment can be dischargedinto environment through the sewerage or drainage systems as authorized.

Personal protective clothing and equipment as specified in Section 8 of this SDS must be worn during handling and disposal of thisproduct. The ventilation requirements as specified in the same section must also be followed, and the precautions given in Section7 of this SDS regarding handling must also be followed. Do not dispose into the sewerage system. Do not discharge into drains orwatercourses or dispose where ground or surface waters may be affected.

In New Zealand, the disposal agency or contractor must comply with the New Zealand Hazardous Substances (Disposal) Regulations2001. Further details regarding disposal can be obtained on the EPA New Zealand website under specific group standards.

Container Disposal:The container or packaging must be cleaned and rendered incapable of holding any substance. It can then be disposed of in amanner consistent with that of the substance it contained. In this instance the packaging can be disposed through a commercialwaste collection service.

Page 7 / 9

Alternatively, the container or packaging can be recycled if the hazardous residues have been thoroughly cleaned or rendered non-hazardous.

In New Zealand, the packaging (that may or may not hold any residual substance) that is lawfully disposed of by householders orother consumers through a public or commercial waste collection service is a means of compliance with regulations.

14. TRANSPORT INFORMATION

Transport InformationNot classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous GoodsRegulations for transport by air.Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transportby sea.

U.N. NumberNone Allocated

UN proper shipping nameNone Allocated

Transport hazard class(es)None Allocated

IMDG Marine pollutantNo

Transport in BulkNot available

Special Precautions for UserNot available

15. REGULATORY INFORMATION

Regulatory informationClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.All components of this product are listed on the New Zealand Inventory of Chemicals (NZIoC) or exempted.

Group Standard: Lubricants, Lubricant Additives, Coolants and Anti-freeze Agents (Subsidiary Hazard) Group Standard 2006

HSNO Approval NumberHSR002606

16. OTHER INFORMATION

Date of preparation or last revision of SDSSDS created: September 2018

ReferencesWorkplace Exposure Standards and Biological Exposure Indices.Transport of Dangerous goods on land NZS 5433.Preparation of Safety Data Sheets - Approved Code of Practice Under the HSNO Act 1996 (HSNO CoP 8-1 09-06).Assigning a hazardous substance to a group standard.Adopted biological exposure determinants, American Conference of Industrial Hygienists (ACGIH).

Contact Person/PointMr Anthony DalleoreGeneral Manager Ph +61 3 9303 5150

Mr Bruce GrayQES officer Ph +61 3 9303 5150

Page 8 / 9

The data included herein presented according to MacDermid Offshore Solutions practices current at the time of preparation hereof,is made available solely for the consideration, investigation and verification of the original recipients hereof and does not

constitute a representation or warranty for which MacDermid Offshore Solutions assumes legal responsibility. It is theresponsibility of a recipient for this data to remain currently informed on chemical hazard information, to design and update itsown safety program and to comply with all Federal, State and Local laws and regulations applicable to safety, occupational health,right to know and environmental protection.

END OF SDS© Copyright Chemical Safety International Pty Ltd

Copyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe SDS displayed is the intellectual property of ChemicalSafety International Pty Ltd.Copyright in the layout, presentation and appearance of each Infosafe SDS displayed is the intellectual property of Chemical Safety International Pty Ltd.The compilation of SDS’s displayed is the intellectual property of Chemical Safety International Pty Ltd.Copying of any SDS displayed is permitted for personal use only and otherwise is not permitted. In particular the SDS’s displayed cannot be copied for the purpose of sale or licence or forinclusion as part of a collection of SDS without the express written consent of Chemical Safety International Pty Ltd.

Page 9 / 9

SAFETY DATA SHEET

EZ-MUD® DP

Revision Date: 03-Mar-2016 Revision Number: 20


Product Name Product Trade Name: EZ-MUD® DP



Recommended Use Recommended Use Shale Inhibitor





Emergency Telephone Number +64 800 451719


0800 764 766 (24 hours)





Hazard pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains


Contains no hazardous substances inconcentrations above cut-off values according to

NA Not applicable

_____________________________________________________________________________________________

Page 1 / 7

_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016

the competent authority




NA 60 - 100%


















6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Slippery when wet.See Section 8 for additional information


_____________________________________________________________________________________________

Page 2 / 7






7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment. Slippery when wet.























Odor: Mild Odor Threshold:

_____________________________________________________________________________________________

Page 3 / 7



pH: 6-8


















Bulk Density 40 lbs/ft3














Toxicity Data





_____________________________________________________________________________________________

Page 4 / 7













NA















_____________________________________________________________________________________________

Page 5 / 7



UN proper shipping name Not restricted

Transport Hazard Class(es) Not applicable


Environmental Hazards Not applicable













All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.










Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% MARPOL – International Convention for the Prevention of Pollution fromShips mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – OccupationalExposure Limit ppm – parts per million TWA – Time-Weighted Average VOC – Volatile Organic Carbon C - Celsius IATA/ICAO- International Air Transport Association / International Civil Aviation Organization IMDG/IMO - International MaritimeDangerous Goods / International Maritime Organization mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimetermercury w/w - weight/weight d - day




_____________________________________________________________________________________________

Page 6 / 7

Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is


obtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.


_____________________________________________________________________________________________

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CS: 3.3.2

Page: 1

Safety Data Sheet

7of

Emergency Response Number: 1800 625 526

Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :

Fluoresceine DyeProduct Name :

Classified as hazardous

1. Identification

Fluoresceine DyeGHS Product

Identifier5406263Product Code

IMCD Australia Limited (ABN 44 000 005 578)Company Name

1st Floor, 372 Wellington Road MulgraveVictoria 3170 Australia

Address

Tel: (03)8544 3100 (Business hours) Fax: (03)8544 3299

Telephone/Fax

Number1800 625 526Emergency phone

numberNEW ZEALANDEmergency Response: 0800 500 288IMCD New Zealand Limited459 Great South RoadPenrose, AucklandPh: (09) 582 0250Fax (09) 525 0030

Emergency Contact

Address

[email protected] Address

Colouring product for various applicationsRecommended use of

the chemical and

restrictions on useName Product CodeOther Names

Fluoresceine Dye 5406326

It is the user's responsibility to determine the suitability of this product for their applications and their methods of use.

Additional

InformationTHIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS.OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

Other Information

2. Hazard Identification

Acute Toxicity - Oral: Category 5Eye Damage/Irritation: Category 2ASensitization - Skin: Category 1Skin Corrosion/Irritation: Category 2Classified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.

GHS classification of

the

substance/mixture

WARNINGSignal Word (s)

H303 May be harmful if swallowed.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.

Hazard Statement (s)

Exclamation markPictogram (s)

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P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P264 Wash contaminated skin thoroughly after handling.P272 Contaminated work clothing should not be allowed out of the workplace.P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary

statement –

Prevention

P302+P352 IF ON SKIN: Wash with plenty of soap and water.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P312 Call a POISON CENTER or doctor/physician if you feel unwell.P332+P313 If skin irritation occurs: Get medical advice/attention.P333+P313 If skin irritation or rash occurs: Get medical advice/attention.P337+P313 If eye irritation persists: Get medical advice/attention.P362 Take off contaminated clothing and wash before reuse.P363 Wash contaminated clothing before reuse.

Precautionary

statement – Response

P501 Dispose of contents/container according to local regulations.Precautionary

statement – DisposalHSNO Approval Number: HSR002503Haz classes: 6.1E, 6.3A, 6.4A, 6.5BGroup Standard: Additives, Process Chemicals and Raw Materials (Subsidiary Hazard)

Other Information

3. Composition/information on ingredients

Name CAS ProportionIngredients

Sodium carbonate 497-19-8 <60 %

Fluorescein 2321-07-5 44-47 %

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other Information

4. First-aid measures

You should call a doctor or Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. Have the Safety Data Sheet with you when you call.

First Aid Measures

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Inhalation

Do NOT induce vomiting if the product is swallowed or enters mouth; wash out mouth with water and provide water to drink. Never give anything by mouth to unconscious person. If large quantities of this material is swallowed, call a physician immediately. Loosen tight clothing such as collar, tie, belt or waistband.

Ingestion

Excess product may be washed off. Flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed, if irritation does occur.

Skin

Flush the exposed eye(s) with lukewarm gently flowing water immediately, while holding the eyelid(s) open until the product have been removed. Seek medical attention if the eye(s) continue to be irritated, or if product is trapped in surface of the eye(s). If exposed person is wearing contact lenses, special care must be taken.

Eye contact

Maintain eyewash fountain and safety shower in work area.First Aid Facilities


If involved in fire, Firefighters must wear selfcontained breathing apparatus and protective clothingin fighting large fires. If safe to do so, remove containers from path of

Fire Fighting

Measures

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fire.Use Dry Chemical Powder or water jet. Fight larger fires with water sprays, fog or foam.

Suitable

extinguishing mediaIf involved with a fire, the following can be released: Carbon Monoxide and Carbon Dioxide.

Hazards from

Combustion

ProductsIf a significant quantity of this product is involved in a fire, call the fire brigade. Do not scatter spilled material with high pressure water jets.

Specific Methods

Combustion is unlikely to occur. Inhalation of heated toxic and/or oxygen deficient fire gases is typically the major hazard in fires.

Specific hazards

arising from the

chemicalNo data available.Decomposition Temp.

6. Accidental release measures

Avoid accidents, clean up immediately. Clear area of unprotected personnel. Wear protective equipment to prevent eye contact. Collect and seal in properly labelled containers or drums for disposal. Wash area down with excess water.

Emergency

Procedures

If safe to do so, stop leak, and contain spill. Prevent from entering into soil, ditches, sewers, water ways, and/or ground water. Use absorbent (soil, sand or other inert) material. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by consultingregulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

Methods and

materials for

containment and

cleaning up

Prevent from entering into soil, ditches, sewers, water ways, and/or ground water. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.

Environmental

Precautions


Keep container tightly sealed. Store in cool dry place away from heat and sources of ignition. Keep locked up. Ensure good ventilation/exhaustion at the workplace. Do not breathe dust. Avoid contact with skin and eyes.

Precautions for Safe

Handling

Make sure that containers of this product are kept tightly closed. Keep containers dry and away from water. Make sure that the product does not come into contact with substances listed under 'Incompatibilities' in Section 10. Check packaging - there may be further storage instructions on the label. Keep away from children.

Conditions for safe

storage, including

any incompatibilities

8. Exposure controls/personal protection

The following Australian and New Zealand Standards will provide general advice regarding safety clothing and equipment:Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

Exposure Controls,

Personal Protection

No exposure standards have been established for this product by Worksafe Australia, however, the TWA exposure standard for dusts not otherwise specified is 10 mg/m3.

Occupational

exposure limit values

Ensure ventilation is adequate and that air concentrations of components are controlled below quoted Workplace Exposure Standards. Keep containers closed when not in use. If in the handling and application of this material, safe exposure levels could be exceeded, the use of engineering controls such as local exhaust must be considered and results documented. If achieving safe exposure levels does not require engineering controls, then a detailed and documented risk

Appropriate

engineering controls

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assessment using the relevant Personal Protective Equipment (PPE) (refer to PPE section below) as a basis must be carried out to determine the minimum PPE requirements.If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable dust mask. Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.

Respiratory

Protection

Wear suitable protective glasses or goggles.Eye Protection

The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when the skin contact is likely.We suggest that protective clothing be made from the following materials: cotton, rubber, PVC.

Hand Protection

Protective clothing.We suggest that protective clothing be made from the following materials: cotton, rubber, PVC.

Body Protection

Ensure that eyewash stations and safety showers are close to the workstation location. General industrial hygiene practice.

Hygiene Measures

9. Physical and chemical properties

SolidForm

Solid crystalline powder.Appearance

Yellow (Yellowish–Red) to RedColour

No odour.Odour

No data available.Decomposition

Temperature315 °CMelting Point

No data available.Freezing Point

No data available.Boiling Point

Insoluble in cold waterSolubility in Water

Insoluble in diethyl ether, petroleum ether, benzene. Soluble in methanol, hot alcohol,, glacial acetic acid, alkali hydroxides and carbonates.

Solubility in Organic

Solvents

No data available.Specific Gravity

No data available.pH

Negligible at normal ambient temperatures.Vapour Pressure

No data available.Vapour Density

(Air=1)No data available.Evaporation Rate

No data available.Coefficient

Water/Oil Distr.No data available.Odour Threshold

Nil at normal ambient temperatures.Volatile Component

No data available.Flash Point

No data available.Flammability

Not applicable - does not burn.Auto-Ignition

TemperatureNo data available.Flammable Limits -

Lower

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No data available.Flammable Limits -

UpperNo data available.Explosion Properties

No data available.Oxidising Properties

10. Stability and reactivity

This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.

Reactivity

Moisture.Excess heat, excess dust generation incompatible materials.

Conditions to Avoid

Reactive with oxidizing agents.Incompatible

MaterialsNo significant quantities of decomposition products are expected at temperatures normally achieved in a fire

Hazardous

Decomposition

ProductsWill not occur.Hazardous

Polymerization


No data is available on the product itself.Components:Sodium carbonate: LD50, rat: 4090 mg/kg (NZ CCID)Fluorescein: LD50, mouse: 4738 mg/kg (NZ CCID)

Acute Toxicity - Oral

No data available.Acute Toxicity -

DermalNo data is available on the product itself.Components:Sodium carbonate: LC50, rat, dust/mist 2hr: 2.3mg (NZ CCID)

Acute Toxicity -

Inhalation

Swallowing may result in nausea, vomiting, abdominal pain to gastrointestinal tract.

Ingestion

Breathing in mist or aerosols may produce respiratory irritation.Inhalation

Contact to skin may cause mild irritation.Skin

Spray or mist can cause mild eye irritationEye

No data available.Respiratory

sensitisationMay cause an allergic skin reaction.Skin Sensitisation

No data available.Germ cell

mutagenicityNo data available.Carcinogenicity

No data available.Reproductive

ToxicityNo data available.STOT-single

exposureNo data available.STOT-repeated

exposureNo data available.Aspiration Hazard

Mutagenic effects: Mutagenic for bacteria and/or yeast.Chronic Effects

May cause eye irritation.Serious eye

damage/irritationRepeated prolonged contact may cause drying of the skin leading to flaking.Skin

corrosion/irritation

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12. Ecological information

This product is unlikely to adversely affect the environment. Salts, acids and bases are typically diluted and neutralised when released to the environment in small quantities. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Expected to not be an environmental hazard.

Ecological

Information

No data available.Ecotoxicity

No data available.Persistence and

degradabilityNo data available.Mobility

No data available.Bioaccumulative

PotentialNo data available.Other Adverse

Effects

13. Disposal considerations

Dispose of waste according to applicable local, state and federal regulations.Disposal

ConsiderationsThis product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these options is suitable, consider landfill. Refer to Waste Management Authority. Dispose of contents/container in accordance with local/regional/national/international regulations.

Waste Disposal

14. Transport information

Not classified as a Dangerous Good according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. Not regulated for transport of Dangerous Goods: ADG7, UN, IATA, IMDG.

Transport

Information

15. Regulatory information

All components of this material are listed on or exempt from the New Zealand Inventory of Chemicals (NZIoC).

Regulatory

InformationNot ScheduledPoisons Schedule

HSR002503HSNO Approval

NumberAll components of this material are listed on or exempt from the Australian Inventory of Chemical Substances (AICS).

AICS (Australia)

16. Other Information

An electronic version of this SDS is available at www.imcdgroup.comContact Person/Point

ADG Code: Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th EditionAICS: Australian Inventory of Chemical SubstancesASCC: Office of the Australian Safety and Compensation CouncilBCF: Bioconcentration FactorCAS number: Chemical Abstracts Service Registry NumberCMR: Carcinogenic, Mutagenic or toxic to ReproductionDMEL: Derived Minimum Effect LevelDNEL: Desired NO Effect LevelEPA: Environmental Protection AgencyGHS: Globally Harmonised System of Classification and Labelling of ChemicalsHazchem Code: Emergency action code of numbers and letters that provide information to emergency services especially fire fightersIARC: International Agency for Research on Cancer

Other Information

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IOELV: Indicative Occupational Exposure Limit ValueLC50: Lethal Concentration, 50 percentLD50: Lethal Dose, 50 percentNICNAS: National Industrial Notification & Assessment SchemeNIOSH: National Institute for Occupational Safety & HealthNOAEL: No Observed Adverse Effect LevelNOEC: No Observed Effect ConcentrationNOS: Not otherwise specifiedNTP: National Toxicology Program (USA)OEL: Occupational Exposure LimitOSHA: Occupational Safety & Health AdministrationPBT: Persistent Bioaccumulative Toxic chemicalPMCC: Pensky Martens Closed CupPNEC: Predicted No Effect ConcentrationR-Phrase: Risk PhraseSTEL: Short Term Exposure LimitSTOT-SE: Specific Target Organ Toxicity (Single Exposure)STOT-RE: Specific Target Organ Toxicity (Repeated Exposure)SUSMP: Standard for the Uniform Scheduling of Medicines & PoisonsTWA: Time Weighted AverageUN Number: United Nations NumbervPvB: Very Persistent and Very BioaccumulativeWEEL: Workplace Environmental Exposure LevelWEL-TWA: Workplace Exposure Limit, Time Weighted Average...End Of MSDS...

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Copyright in the layout, presentation and appearance of each Infosafe MSDS displayed is the intellectual property of Acohs Pty Ltd. The compilation of MSDS's displayed is the intellectual property of Acohs Pty Ltd.

Copying of any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose of sale or licence or for inclusion as part of a collection of MSDS without the express written consent of Acohs Pty Ltd.

Print Date: 4/03/2019 CS: 3.3.2

SAFETY DATA SHEET

GASCON 469


1. Identification

Product Name Product Trade Name: GASCON 469



Recommended Use Recommended Use Cement Additive







0800 764 766 (24 hours)



Classification 6.3B (Mildly) irritating to the skin


Hazard Pictograms

Signal Word Warning

Hazard Statements H316 - Causes mild skin irritation


Prevention P103 - Read label before useP104 - Read Safety Data Sheet before use.

Response P332 + P313 - If skin irritation occurs: Get medical advice/attention

Storage None

Disposal P501 - Dispose of contents/container to an approved waste disposal plant

Contains


_____________________________________________________________________________________________

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_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018

Sodium hydroxide 1310-73-2 6.1D (Oral)6.1D (Dermal)8.1A8.2B8.3A9.1D (Crustacean, Fish)9.3C



Substances CAS Number PERCENT (w/w)Sodium hydroxide 1310-73-2 0.1 - 1%








Relation to Health Effect Most Important Symptoms/EffectsCauses mild skin irritation.











_____________________________________________________________________________________________

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Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate


ventilation.See Section 8 for additional information





7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep from excessive heat. Keep from freezing. Keep container closed when not in use.Store in non-rusting containers. Product has a shelf life of 12 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWASodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 Not applicable





Hand Protection None known.






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pH: 10









Water Solubility Soluble in water (10g/100ml)








9.2. Other information VOC Content (%) 80




10.5. Incompatible materials Strong oxidizers. Strong acids.







Skin Contact Causes mild skin irritation.



Toxicity Data



Sodium hydroxide 1310-73-2 Not applicable due to corrosivityof the substance.



Substances CAS Skin corrosion/irritation

Physical State: Liquid Color Transparent


_____________________________________________________________________________________________

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Number

Sodium hydroxide 1310-73-2 Causes severe burns



Sodium hydroxide 1310-73-2 Causes severe eye burns (Rabbit)


Skin Sensitization

Sodium hydroxide 1310-73-2 Did not cause sensitization on laboratory animals (guinea pig)





Mutagenic Effects

Sodium hydroxide 1310-73-2 Did not show mutagenic effects in animal experiments In vitro tests did not show mutagenic effects.



Sodium hydroxide 1310-73-2 No data of sufficient quality are available.






Sodium hydroxide 1310-73-2 May cause respiratory irritation.



Sodium hydroxide 1310-73-2 No significant toxicity observed in animal studies at concentration requiring classification. Notapplicable due to corrosivity of the substance.


Aspiration hazard

Sodium hydroxide 1310-73-2 Not applicable


12.1. Toxicity





Sodium hydroxide 1310-73-2 No information available LC50(48h) 189 mg/L(Leuciscus idus

melanotus)LLC50(48h) 189 mg/L(Leuciscus melanotus)LC50(24h) 145 mg/L(Poecilia reticulate)

LC50(96h) 125 mg/L(Gambusia affinis)

LOEL(150 d) = 25 mg/L(Lebistes reticulatus)

No information available EC50 (48h) 40.4 mg/L(Ceriodaphnia sp.)



Sodium hydroxide 1310-73-2 The methods for determiningbiodegradability are not applicable toinorganic substances.


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Sodium hydroxide 1310-73-2 No data available








Incineration recommended in approved incinerator according to federal, state, and localregulations. Substance should NOT be deposited into a sewage facility.




























_____________________________________________________________________________________________

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SAFETY DATA SHEET

GEM™ CPRevision Date: 15-Mar-2017 Revision Number: 21


Product Name Product Trade Name: GEM™ CP










0800 764 766 (24 hours)



Classification 6.1D (Inhalation) Acutely Toxic Substances6.9B Harmful to human target organs or systems


Hazard Pictograms

Signal Word Warning

Hazard Statements H332 - Harmful if inhaledH373 - May cause damage to organs through prolonged or repeated exposure



_____________________________________________________________________________________________

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_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017

P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP271 - Use only outdoors or in a well-ventilated area

Response P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER or doctor/physician if you feel unwellP331 - Do NOT induce vomitingP314 - Get medical attention/advice if you feel unwell

Storage None

Disposal P501 - Dispose of contents/container to an approved incineration plant

Contains


Methyloxirane polymer with oxirane, monbutylether




Substances CAS Number PERCENT (w/w)Methyloxirane polymer with oxirane, monbutyl ether 9038-95-3 60 - 100%


Requirements for First Aid or Medical Care Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.





Relation to Health Effect Most Important Symptoms/EffectsHarmful if inhaled.







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Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid breathing vapors. Avoid contact with skin, eyes and clothing. Ensure adequateventilation. Evacuate all persons from the area.See Section 8 for additional information





7.1. Precautions for safe handling Handling PrecautionsAvoid breathing vapors. Avoid breathing mist. Ensure adequate ventilation. Avoid contact with eyes, skin, or clothing. Useappropriate protective equipment. Wash hands after use. Launder contaminated clothing before reuse.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store away from acids. Store away from alkalis. Keep container closed when not in use. Producthas a shelf life of 60 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWAMethyloxirane polymer withoxirane, monbutyl ether






Respiratory Protection Organic vapor respirator with a dust/mist filter. (A2P2/P3)

Hand Protection Impervious rubber gloves. Polyvinylchloride gloves. Neoprene gloves.


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pH: 5-7.5 (10%)





Evaporation rate < 0.1

Vapor Pressure < 0.01 mmHg

Vapor Density > 1




Partition coefficient: n-octanol/waterAutoignition Temperature 370 °C / 698 °F















Inhalation Harmful if inhaled.





Toxicity Data

Physical State: Liquid Color Clear light yellow

Odor: Mild Odor Threshold:

_____________________________________________________________________________________________

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Methyloxirane polymerwith oxirane, monbutylether

9038-95-3 >5000 mg/kg-bw (rat) >8000 mg/kg-bw (rabbit) >1 - <5 mg/L (rat, 4 h, aerosol)



Methyloxirane polymer withoxirane, monbutyl ether

9038-95-3 Not a dermal irritant Non-irritating to the skin




9038-95-3 Non-irritating to the eye


Skin Sensitization


9038-95-3 No sensitization responses were observed (similar substances)






Mutagenic Effects




















Aspiration hazard




12.1. Toxicity





Methyloxirane 9038-95-3 EC50(72 h)=465 mg/L LC50(96 h)=3200 mg/L No information available EC50(48 h)=4400 mg/L

_____________________________________________________________________________________________

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polymer with oxirane,monbutyl ether

(Skeletonema costatum) (Pimephales promelas)LC50(96 h)>1800 mg/L

(Scophthalmusmaximus)

(Daphnia magna)LC50(48 h)=356 mg/L

(Acartia tonsa)



Methyloxirane polymer with oxirane, monbutyl ether 9038-95-3 (24% @ 20d)



Methyloxirane polymer with oxirane, monbutylether

9038-95-3 Log Pow=0.353



Methyloxirane polymer with oxirane, monbutyl ether 9038-95-3 No information available



























_____________________________________________________________________________________________

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SAFETY DATA SHEET

GEM™ GP


Product Name Product Trade Name: GEM™ GP










0800 764 766 (24 hours)



Classification 6.1D (Oral) Acutely Toxic Substances


Hazard Pictograms

Signal Word Warning

Hazard Statements H302 - Harmful if swallowed


Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P264 - Wash face, hands and any exposed skin thoroughly after handling

_____________________________________________________________________________________________

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Revision Date: 14-May-2015 Revision Number: 41

_____________________________________________________________________________________________P270 - Do not eat, drink or smoke when using this product

Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP331 - Do NOT induce vomiting

Storage None


Contains


Polyethylene glycol butyl ether 9004-77-7 6.1D (Oral)




Polyethylene glycol butyl ether 9004-77-7 60 - 100%







Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue.



Type of Hazard Flammability HazardCombustible liquid





Special Exposure HazardsDecomposition in fire may produce harmful gases.

_____________________________________________________________________________________________

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GEM™ GP Revision Date: 14-May-2015

_____________________________________________________________________________________________







7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothingbefore reuse. Ensure adequate ventilation. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store away from acids. Keep container closed when not in use.






Polyethylene glycol butyl ether 9004-77-7 Not applicable Not applicable




exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. (>= 0.35 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result of

_____________________________________________________________________________________________

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_____________________________________________________________________________________________the many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.








pH: 6.5 - 9

Freezing Point/Range -45 °C


Boiling Point/Range 126 °C / 260 °F


upper flammability limit 3.8 %

lower flammability limit 0.8 %


Vapor Pressure 0.002 mmHg






Autoignition Temperature 203 °C / 397.4 °F


Viscosity 10-11 cP @ 20°C






10.4. Conditions to Avoid Keep away from heat, sparks and flame.

10.5. Incompatible Materials Strong oxidizers. Mineral acids.

10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.







Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

_____________________________________________________________________________________________

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Physical State: Liquid

GEM™ GP

Color: Yellow to brown


Odor: Mild Odor Threshold: No information available

_____________________________________________________________________________________________nausea, and diarrhea.


Toxicity Data



Polyethylene glycol butylether

9004-77-7 > 5000 mg/kg (Rat)> 2000 mg/kg (Rat)

6540 mg/kg (Rat)3540 mg/kg (Rabbit) (similar

substance)> 2000 mg/kg (Rat) (similar

substance)

> 2.6 mg/L (Rat) 4h (similarsubstance)

> 2000 mg/L (Rat) 1h (similarsubstance)




9004-77-7 Non-irritating to the skin (Rabbit)




9004-77-7 Eye, rabbit: Causes severe eye irritation which may damage tissue.


Skin Sensitization




Mutagenic Effects


9004-77-7 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects (similarsubstances)




9004-77-7 No information available.




9004-77-7 Not regarded as a reproductive and developmental toxicant. Did not show teratogenic effects inanimal experiments. (similar substances)










Aspiration hazard





_____________________________________________________________________________________________

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Revision Date: 14-May-2015GEM™ GP

_____________________________________________________________________________________________





Polyethylene glycolbutyl ether

9004-77-7 EC50(72h): 391 mg/L(growth rate)

(Skeletonema costatum)

EC50: 475 ppm (Abraalba)

LC50(96h): >1800 mg/L(Scophthalmus

maximus)

IC50(16h): > 5000 mg/L(Growth inhibition,

Activated sludge) (similarsubstance –

2-(2-(2-butoxyethoxy)ethoxy)ethanol)

EC10(30m): > 1995mg/L (respiration rate,

activated sludge) (similarsubstance –

2-(2-(2-butoxyethoxy)ethoxy)ethanol)

TLM48: 310 mg/l(Acartia tonsa)

EC50(48h): > 3200 mg/L(Daphnia magna)(similar substance –ethanol, 2-butoxy-,

manufacture of,by-products from)



Polyethylene glycol butyl ether 9004-77-7 Readily biodegradable (68% @ 28d)

12.3. Bioaccumulative potential Does not bioaccumulate


Polyethylene glycol butyl ether 9004-77-7 0.436



Polyethylene glycol butyl ether 9004-77-7 Log Kow < 4.5




13.1. Waste treatment methods Disposal Method Disposal should be made in accordance with federal, state, and local regulations.













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ERMA Register Approval Number HSR003673













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Revision Date: 14-May-2015GEM™ GP

SAFETY DATA SHEET

HALAD® 344 CEMENT ADDITIVE



Product Name Product Trade Name: HALAD® 344 CEMENT ADDITIVE










0800 764 766 (24 hours)





Hazard pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Not applicable

2.3. Other Hazards

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_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016

This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).



NA 60 - 100%




Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Getimmediate medical attention.
















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7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location. Store away from oxidizers. Keep container closed when not in use. Product has a shelf life of 60months.









exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection None known.












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9.2. Other information Molecular Weight > 600






10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide. Oxides of sulfur.







Ingestion No adverse health effects are expected from swallowing.


Toxicity Data





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12.2. Persistence and degradability Not readily biodegradableSubstances CAS Number Persistence and Degradability


NA















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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organization


mg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day






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SAFETY DATA SHEET



1. Identification











0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Non-hazardous

_____________________________________________________________________________________________

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NA 60 - 100%



















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7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.




















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pH: 7.5






















10.6. Hazardous decomposition products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.









Toxicity Data





Physical State: Solid Color Brown-black

Odor: Sweet Odor Threshold: No information available

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12.1. Toxicity










NA















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_____________________________________________________________________________________________

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SAFETY DATA SHEET

HALAD® 413L CEMENT ADDITIVE


1. Identification

Product Name Product Trade Name: HALAD® 413L CEMENT ADDITIVE










0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



_____________________________________________________________________________________________

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_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018





NA 60 - 100%


















6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors.See Section 8 for additional information


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7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothingbefore reuse. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Product has a shelf life of 24 months.










Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)







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pH: 7.5



























Eye Contact None known.




Toxicity Data





Physical State: Liquid Color Brown-black

Odor: Sweet Odor Threshold: No information available

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12.1. Toxicity










NA















_____________________________________________________________________________________________

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_____________________________________________________________________________________________

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SAFETY DATA SHEET



1. Identification











0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Non-hazardous

_____________________________________________________________________________________________

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NA 60 - 100%





Skin Wash with soap and water.













6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing.See Section 8 for additional information


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Physical State: Solid Color Brown

Odor: Characteristic Odor Threshold:

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Toxicity Data





_____________________________________________________________________________________________

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12.1. Toxicity










NA

















_____________________________________________________________________________________________

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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimeter


mmHg - millimeter mercuryw/w - weight/weightd - day






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SAFETY DATA SHEET

HR-5


1. Identification

Product Name Product Trade Name: HR-5



Recommended Use Recommended Use Cement Retarder







0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Non-hazardous

_____________________________________________________________________________________________

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_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018




NA 60 - 100%




















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7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.






















pH: 9.5-10.3

Physical State: Solid Color Black

Odor: Molasses Odor Threshold:

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Water Solubility Soluble in water (25g/100ml)













10.6. Hazardous decomposition products Oxides of sulfur.









Toxicity Data





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12.1. Toxicity










NA
















NZ 5433.1999

_____________________________________________________________________________________________

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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic meter


mm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day






_____________________________________________________________________________________________

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SAFETY DATA SHEET

HR-6L


1. Identification

Product Name Product Trade Name: HR-6L










0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Non-hazardous

_____________________________________________________________________________________________

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_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018




NA 60 - 100%





















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Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors.



7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep container closed when not in use.










Respiratory Protection Not normally necessary.









pH: 9.5





Physical State: Liquid Color Dark brown

Odor: Molasses Odor Threshold:

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Liquid Density 10.08 lbs/gal














Toxicity Data





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12.1. Toxicity










NA












13.1. Waste treatment methods Disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local

regulations.








IMDG/IMO

_____________________________________________________________________________________________

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NZ CCID





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SAFETY DATA SHEET

HR-25L

Revision Date: 28-Nov-2018 Revision Number: 36

1. Identification

Product Name Product Trade Name: HR-25L






136-140 Connett Road East, BlockNew PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207




0800 764 766 (24 hours)



Classification 8.3A Corrosive to ocular tissue9.3C Harmful to terrestrial vertebrates


Hazard Pictograms

Signal Word Danger

Hazard Statements H318 - Causes serious eye damageH433 - Harmful to the terrestrial vertebrates.


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_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018

Prevention P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P280 - Wear eye protection/face protection

Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician

Storage None

Disposal P501 - Dispose of contents/container to an approved waste disposal plant

Contains


Tartaric acid 87-69-4 8.3A9.3C



Substances CAS Number PERCENT (w/w)Tartaric acid 87-69-4 30 - 60%








Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue.








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Decomposition in fire may produce harmful gases.




6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove.



7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.



7.2. Conditions for safe storage, including any incompatibilities Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not inuse. Product has a shelf life of 60 months.





Substances CAS Number New Zealand WES ACGIH TLV-TWATartaric acid 87-69-4 Not applicable Not applicable





Hand Protection Impervious rubber gloves.

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pH: 1.7



Pour Point / Range No data available



















10.5. Incompatible materials Strong oxidizers. Strong alkalis.










Physical State: Liquid Color Light yellow-green


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Toxicity Data



Tartaric acid 87-69-4 2000 - 5000 mg/kg (Rat) > 2000 mg/kg (Rat) No data available



Tartaric acid 87-69-4 Non-irritating to the skin (Rabbit) (in vitro)



Tartaric acid 87-69-4 Causes severe eye irritation (Rabbit)


Skin Sensitization

Tartaric acid 87-69-4 Did not cause sensitization on laboratory animals (mouse)



Tartaric acid 87-69-4 No information available


Mutagenic Effects

Tartaric acid 87-69-4 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.



Tartaric acid 87-69-4 Did not show carcinogenic effects in animal experiments (Rat) (similar substances)



Tartaric acid 87-69-4 Did not show teratogenic effects in animal experiments.



Tartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.



Tartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.


Aspiration hazard

Tartaric acid 87-69-4 Not applicable


12.1. Toxicity Ecotoxicity effectsHarmful to aquatic life.





Tartaric acid 87-69-4 E(B)C50 2575.2 mg/L(Skeletonema costatum)

E(R)C50 1198 mg/L(Skeletonema costatum)

EC50 791.25 mg/L(Skeletonema costatum)

EC50 (72h) 51.4043mg/L


LC50 250 mg/L(Scophthalmus

maximus)LC50 (96h) > 100 mg/L

(Danio rerio)

EC50 (3h) > 1000 mg/L(Activated sludge)

TLM96 330-1000 ppm(Crangon crangon)

EC50 46.04 - 165.37mg/L (Ceriodaphnia

dubia)LC50 3753.85 (Acartia

tonsa)EC50 (48h) 93.313 mg/L

(Daphnia magna)

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12.2. Persistence and degradability Readily biodegradableSubstances CAS Number Persistence and Degradability

Tartaric acid 87-69-4 Readily biodegradable (85% @ 28d)



Tartaric acid 87-69-4 -1



Tartaric acid 87-69-4 No information available

Ecotoxicity Hazard Statements Harmful to terrestrial vertebrates.




Incineration recommended in approved incinerator according to federal, state, and localregulations. Substance should NOT be deposited into a sewage facility.
























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Revision Date: 28-Nov-2018




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SAFETY DATA SHEET

HR-601


1. Identification

Product Name Product Trade Name: HR-601










0800 764 766 (24 hours)





Hazard Pictograms

Signal Word None



Prevention None

Response None

Storage None

Disposal None

Contains



NA Non-hazardous

_____________________________________________________________________________________________

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NA 60 - 100%



















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7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.





















Property Values

Physical State: Solid Color Brown

Odor: Woody Odor Threshold: No information available

_____________________________________________________________________________________________

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Remarks/ - Method

pH: 7.8





Upper flammability limit 3.5 oz/ft3

Lower flammability limit 0.2 oz/ft3














Bulk Density 30.5 lbs/ft3 @ 20 C














Toxicity Data



Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competent


_____________________________________________________________________________________________

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authority


12.1. Toxicity










NA












13.1. Waste treatment methods Disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local

regulations. Bury in a licensed landfill according to federal, state, and local regulations.



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Documents

Safety Data Sheet - EPA...Ingredient CAS Nbr % by Weight Soda lime borosilicate glass 65997-17-3 97 - 100 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation