· Classification of the substance or mixture· Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xn; Harmful

R20/21: Harmful by inhalation and in contact with skin.· Classification system:

The classification was made according to the latest editions of the EU-lists,and expanded by company and literature data.

· Label elements

· Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives onHazardous Materials

· Code letter and hazard designation of product:Xn Harmful

· Hazard-determining components of labelling:2-butoxyethyl acetate

· Risk phrases:20/21 Harmful by inhalation and in contact with skin.

· Safety phrases:36/37 Wear suitable protective clothing and gloves.

· Other hazardsExposure to component solvent vapours above the occupational exposure limit,stated in Section 8, may result in adverse health effects such as mucousmembrane and respiratory system irritation, adverse effects on kidney, liverand central nervous system. Symptoms and signs include headache, dizziness,fatigue, muscular weakness, drowsiness and in extreme cases, loss ofconsciousness.Organic solvents should not be used for hand cleaning as this may lead toabsorption through the skin, skin irritation or dermatitis.

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

Emergency Contacts

International (except USA) : Chemtrec on Tel: 1 703 527 3887

United States of America : Chemtrec on Tel: 1 800 424 9300

Website : www.colorificink.com

Email : msds@colorificink.com

According to EC Directive 2001/58/EC. E&OE.

Colorific XXLS - Solvent Digital Ink

Section 1. Chemical Product & Company Information

Section 2. Hazard Information

Safety Data Sheet

Product Name : Colorific XXLS

Product Description : Solvent inks for digital printing

Product Code : COL-XXLS (C,M,YK,LC,LM,LY,LK)Manufacturer/Supplier

Colorific Ink

Unit 9, Kings Grove Industrial EstateBoyn Valley RoadMaidenheadBerkshire SL6 4DPUnited Kingdom

Tel: +44 (0) 1628 560890

Page 1 / 7

Section 4. First aid measures

Colorific XXLS - Solvent Digital Ink

· Chemical characterization: Mixtures· Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous components:

CAS: 112-07-2EINECS: 203-933-3

2-butoxyethyl acetate Xn R20/21 Acute Tox. 4, H312; Acute Tox. 4, H332

50-100%

CAS: 108-94-1EINECS: 203-631-1

Cyclohexanone Xn R20

R10 Flam. Liq. 3, H226; Acute Tox. 4, H332

5-10%

· Additional informationFor the wording of the listed risk phrases refer to section 16.

· Description of first aid measures· General information

Never make an unconscious person vomit or drink fluids.Immediately remove any clothing soiled by the product.

· After inhalation Supply fresh air; consult doctor in case of complaints.· After skin contact

Immediately wash with soap and water and rinse thoroughly.If skin irritation continues, consult a doctor.

· After eye contactRinse open eye for several minutes under running water. Then consult a doctor.

· After swallowingGive patient copious amounts of water to drink and provide fresh air. Call fora doctor immediately.

· Information for doctor· Most important symptoms and effects, both acute and delayed

No further relevant information available.· Indication of any immediate medical attention and special treatment needed

No further relevant information available.

Section 5. Firefighting Measures

· Extinguishing media· Suitable extinguishing agents

CO2, extinguishing powder or water spray. Fight larger fires with water sprayor alcohol resistant foam.

· For safety reasons unsuitable extinguishing agents Water with full jet.· Special hazards arising from the substance or mixture

In case of fire, the following can be released:Carbon monoxide (CO)Nitrogen oxides (NOx)Under certain fire conditions, traces of other toxic gases cannot be excluded.

· Advice for firefighters· Protective equipment: Wear self-contained breathing apparatus.· Additional information

Cool endangered containers with water spray.Collect contaminated fire fighting water separately. It must not enter thesewage system.

Section 6. Accidental release measures

· Personal precautions, protective equipment and emergency proceduresRefer to the protective measures stated in Sections 7 and 8. Keep unprotectedpersonnel away.Keep away from ignition sources

(Contd. on page 3)

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Safety Data Sheet

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Section 3. Composition/information on ingredients

Colorific XXLS - Solvent Digital Ink (Contd. of page 2)

Ensure adequate ventilation· Environmental precautions:

Prevent seepage into sewage system, workpits and cellars.Inform respective authorities if seepage into water course or sewage systemoccurs.Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomaceous earth, acid binders,universal binders, sawdust).Dispose of contaminated material as waste according to section 13.

· Reference to other sectionsSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.

· Handling· Precautions for safe handling

Ensure good interior ventilation.Store in cool, dry place in tightly sealed containers.Keep away from heat and direct sunlight.Ensure good ventilation and extraction at the workplace.

· Conditions for safe storage, including any incompatibilities· Storage: Store in accordance with current national regulations.· Requirements to be met by storerooms and containers: Store between 5 - 30 °C.· Information about storage in one common storage facility:

Do not store together with oxidizing and acidic materials.Do not store together with alkalis (caustic solutions).

· Further information about storage conditions:Protect from heat and direct sunlight.

· Specific end use(s) No further relevant information available.

· Additional information about design of technical systems:Provide adequate ventilation. Where reasonably practicable, this should beachieved by the use of local exhaust ventilation and good general extraction.If these are not sufficient to maintain concentrations of particulates orsolvent vapour below the occupational exposure limit stated, then suitablerespiratory protection must be worn as a temporary measure and is specifiedbelow.

· Control parameters

· Components with limit values that require monitoring at the workplace:

112-07-2 2-butoxyethyl acetate

WEL (Great Britain) Short-term value: 332 mg/m³, 50 ppmLong-term value: 133 mg/m³, 20 ppmSk

IOELV (European Union) Short-term value: 333 mg/m³, 50 ppmLong-term value: 133 mg/m³, 20 ppmSkin

108-94-1 Cyclohexanone

WEL (Great Britain) Short-term value: 82 mg/m³, 20 ppmLong-term value: 41 mg/m³, 10 ppmSk, BMGV

IOELV (European Union) Short-term value: 81.6 mg/m³, 20 ppmLong-term value: 40.8 mg/m³, 10 ppmSkin

· Ingredients with biological limit values:

108-94-1 Cyclohexanone(Contd. on page 4)

According to EC Directive 2001/58/EC. E&OE.

Safety Data Sheet

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Section 7. Handling and Storage

Section 8. Exposure controls/personal protection

Colorific XXLS - Solvent Digital Ink (Contd. of page 3)

BMGV (Great Britain) 2 mmol/mol creatinineMedium: urineSampling time: post shiftParameter: cyclohexanol

· Additional information:The instructions and information provided by the manufacturer of the personalprotective equipment on use, storage, maintenance and replacement must alwaysbe followed.

· Exposure controls

· General protective and hygienic measuresImmediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the eyes and skin.Store protective clothing separately.Keep away from foodstuffs, beverages and feed.

· Breathing equipment: CEN: A1 filter.· Protection of hands:

There is no one glove material or combination of materials that will giveunlimited resistance to any individual or combination of chemicals.The selection of single or multi-use gloves is dependent upon the level ofexposure.The performance or effectiveness of the glove may be reduced by physical/chemical damage and poor maintenance. Always ensure that gloves are free fromdefects and that they are stored and used correctly.Gloves should be replaced regularly and if there is any sign of damage to theglove material.

Single use disposable nitrile gloves (short duration exposure of few minutes,or where only splashes likely). Not to be reused when removed.

Minimum 0.4mm thick neoprene or nitrile gloves (longer duration exposure ormechanical handling activities). To be replaced immediately when punctured ordegraded.Heavy duty unlined neoprene gloves (when using solvents). To be replacedimmediately when punctured or degraded.

· Penetration time of glove materialThe exact break through time has to be obtained from the manufacturer of theprotective gloves and must be observed.

· Eye protection: Safety glasses· Body protection: Protective work clothing; disposable overalls are preferable.

· COSHH Essentials for Printers Control Guidance Sheet:Guidance is provided by the Health and Safety executive (HSE) concerning COSHH(Control of Substances Hazardous to Health) for printers.See COSHH Essentials for Printers on the HSE website:www.hse.gov.uk and enter 'COSHH Essentials for printers' in the search bar.

Section 9. Physical and Chemical properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: FluidColour: According to product specification

· Odour: Characteristic

· Change in conditionMelting point/Melting range: undeterminedBoiling point/Boiling range: undetermined

· Flash point: 66 °C

· Self igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits:Lower: Not determined.

(Contd. on page 5)

According to EC Directive 2001/58/EC. E&OE.

Safety Data Sheet

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According to EC Directive 2001/58/EC. E&OE.

Safety Data Sheet

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Section 10. Stability and reactivity

Section 11. Toxicological information

Colorific XXLS - Solvent Digital Ink

(Contd. of page 4)

Upper: Not determined.

· Vapour pressure at 20 °C: 0.3 hPa

· Density at 20 °C: 0.96 g/cm³· Water: Not miscible or difficult to mix

· Viscosity:dynamic: Not determined.kinematic: Not determined.

· Solvent content:Organic solvents: 85.6 %

· Other information No further relevant information available.

· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.· Stable until: 50 °C· Possibility of hazardous reactions No dangerous reactions known· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.

· Information on toxicological effects· Acute toxicity:

· LD/LC50 values that are relevant for classification:

112-07-2 2-butoxyethyl acetate

Oral LD50 3200 mg/kg (Mouse)

7250 mg/kg (rat)

Dermal LD50 1500 mg/kg (Rabbit)

IC50/72h >500 mg/l (Algae)

108-94-1 Cyclohexanone

Oral LD50 1620 mg/kg (rat)

Dermal LD50 1100 mg/kg (Rabbit)

Inhalation LC50 11 mg/l (rat)

LC50/96h 527 mg/l (Pimephales promelas (fathead minnow))

· Additional toxicological information:2-Butoxyethanol and its acetate are readily absorded through the skin and maycause harmful effects on the blood

Section 12. Ecological information

· Toxicity

· Aquatic toxicity:

112-07-2 2-butoxyethyl acetate

EC50/48 h 150 mg/l (Daphnia)

IC50 2800 mg/l (Bacteria)

LC50/96 h 80 mg/l (Fish)

80 mg/l (Fathead Minnows)

THOD 2.10 mg/l (-)

· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.

(Contd. on page 6)

According to EC Directive 2001/58/EC. E&OE.

Safety Data Sheet

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Section 14. Transport information

Section 13. Disposal considerations

Colorific XXLS - Solvent Digital Ink

(Contd. of page 5)

· Additional ecological information:· General notes:There are no data on the preparation itself.The preparation has been assessed following the conventional method of theDangerous Preparations Directive 1999/45/EC and is not classified as dangerousfor the environment.Do not allow product to reach ground water, water course or sewage system.

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.

· Waste treatment methods· RecommendationMust not be disposed together with household rubbish. Do not allow product toreach sewage system.

· European waste catalogue

08 03 12* waste ink containing dangerous substances

· Waste Hazard Classification: H5 - Harmful· Recommendation:Dispose of product according to official regulations.Also see Section 16 'Other Information'

· UN-Number· ADR, ADN, IMDG, IATA Void

· UN proper shipping name· ADR, ADN, IMDG, IATA Void

· Transport hazard class(es)

· ADR, ADN, IMDG, IATA· Class Void

· Packing group· ADR, IMDG, IATA Void

· Environmental hazards:· Marine pollutant: No

· Special precautions for user Not applicable.

· Transport in bulk according to AnnexII of MARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information: Not dangerous according to the abovespecifications.

Section 15. Regulatory information

· Safety, health and environmental regulations/legislation specific for thesubstance or mixture

· Markings according to EU guidelines:The product has been classified and marked in accordance with EU Directives onHazardous Materials

· Code letter and hazard designation of product:Xn Harmful

· Hazard-determining components of labelling:2-butoxyethyl acetate

(Contd. on page 7)

According to EC Directive 2001/58/EC. E&OE.

Safety Data Sheet

Page 7 / 7

Section 16. Other information

Colorific XXLS - Solvent Digital Ink

(Contd. of page 6)

· Risk phrases:20/21 Harmful by inhalation and in contact with skin.

· Safety phrases:36/37 Wear suitable protective clothing and gloves.

This information is based on our present knowledge. However, this shall notconstitute a guarantee for any specific product features and shall notestablish a legally valid contractual relationship.

· Relevant phrasesH226 Flammable liquid and vapour.H312 Harmful in contact with skin.H332 Harmful if inhaled.

R10 Flammable.R20 Harmful by inhalation.R20/21 Harmful by inhalation and in contact with skin.

· Recommended restriction of useThe product should not be used for any purpose other than that specified inSection 1.