SAFETY DATA SHEET AD-ASQ-263 CHROMagar™ STEC base … · Page 1/6 09-Feb-2018 SECTION 1: Identification of the mixture and of the company / undertaking 1 1.1 Product identifier

SAFETY DATA SHEET (according 1907/2006/CE, Art. 31) CHROMagar™ STEC base

Ref : ST160(B) / ST162(B) / ST163(B)

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SECTION 1: Identification of the mixture and of the company / undertaking 1

1.1 Product identifier 2 · Trade name: CHROMagar™ STEC base 3

1.2 Relevant identified uses of the substance or mixture and uses advised against 4 No further relevant information available. 5 · Application of the substance / the preparation : Reagent for Laboratory Use 6

1.3 Details of the supplier of the safety data sheet 7 · Manufacturer/Supplier : 8

CHROMagar 9 4, place du 18 Juin 1940 - 75006 Paris 10 Tel: +33 1 45 48 05 05 11 Email : [email protected] 12

1.4 Emergency telephone number : 13 France (ORFILA 24h/24) - Tel : +33 (0)1 45 42 59 59 14 Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24) EU Tel: 112 15 Belgique - Tel : 32 070/245 245 16 UK : 111 (NHS) / 0345 300 9923 (HSE) 17 18 19 SECTION 2: Hazards identification 20

2.1 Classification of the substance or mixture 21 · Classification according to Regulation (EC) No 1272/2008 : 22 The product is not classified according to the CLP regulation. 23

2.2 Label elements 24 · Labelling according to Regulation (EC) No 1272/2008 : Not classified as hazardous 25 · Hazard pictograms : Not classified as hazardous 26 · Signal word : Not classified as hazardous 27 · Hazard statements : Not classified as hazardous 28 29 · Additional information : EUH210 Safety data sheet available on request. 30

2.3 Other hazards 31 · Results of PBT and vPvB assessment 32 · PBT : Not applicable. 33 · vPvB : Not applicable. 34 35 36 SECTION 3: Composition / information on ingredients 37

3.2 Mixtures 38 · Description : Mixture: consisting of the following components. 39 · Dangerous components : 40 41 CAS: 302-95-4 sodium 3-alpha,12-alpha-dihydroxy-5-ß-cholan-24-oate < 5% EINECS: 206-132-7 Acute Tox. 4, H302; STOT SE 3, H335 42 · SVHC : No 43 · Additional information : For the wording of the listed risk phrases, refer to section 16. 44 45 46


Ref : ST160(B) / ST162(B) / ST163(B)

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47 SECTION 4: First aid measures 48

4.1 Description of first aid measures 49 · General information : Position and transport stably in side position. 50

In case of irregular breathing or respiratory arrest provide artificial 51 respiration. 52

· After excessive inhalation : Provide fresh air; consult a doctor in case of medical complaints. 53 · After skin contact : Generally the product does not irritate the skin. 54 In the event of irritation, to withdraw soiled clothing, to wash the parts 55

reached with soapy water, to rinse with large water. 56 If skin irritation continues, consult a doctor. 57 · After eye contact : Rinse opened eye for several minutes under running water. 58 · After swallowing : Do not induce vomiting; call for medical help immediately. 59

4.2 Most important symptoms and effects, both acute and delayed : 60 No further relevant information available. 61

4.3 Indication of any immediate medical attention and special treatment needed : 62 No further relevant information available. 63 64 65 SECTION 5: Firefighting measures 66

5.1 Suitable extinguishing agents : 67 CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 68

5.2 Special hazards arising from the substance or mixture : No further relevant information available. 69

5.3 Advice for firefighters 70 · Protective equipment : No special measures required. 71 72 73 SECTION 6: Accidental release measures 74

6.1 Personal precautions, protective equipment and emergency procedures : 75 No special measures required. Avoid formation of dust. 76

6.2 Environmental precautions : Do not allow product to reach sewage system or any water course. 77 Dilute with plenty of water. 78

6.3 Methods and material for containment and cleaning up : Pick up mechanically. 79

6.4 Reference to other sections : 80 See Section 7 for information on safe handling. 81 See Section 8 for information on personal protective equipment. 82 See Section 13 for disposal information. 83 84 85 SECTION 7: Handling and storage 86

7.1 Precautions for safe handling : Keep away from heat and direct sunlight. 87 Thorough dedusting. 88

· Information about fire - and explosion protection: No special measures required. 89

7.2 Conditions for safe storage, including any incompatibilities : 90 · Storage : 91


Ref : ST160(B) / ST162(B) / ST163(B)

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· Requirements to be met by storerooms and receptacles : Store away from light and moisture. 92 No special requirements. 93 · Information about storage in one common storage facility : Not required. 94 · Further information about storage conditions : Store in cool, 95 dry conditions in well sealed receptacles. 96 · Recommended storage temperature : 15-30°C 97

7.3 Specific end use(s) : No further relevant information available. 98

99 SECTION 8: Exposure controls / personal protection 100 101 · Additional information about design of technical facilities : No further data; see section 7. 102

8.1 Control parameters 103 · Ingredients with limit values that require monitoring at the workplace : 104 The product does not contain any signifiant quantities of materials with critical values that have to be monitored at 105 the workplace. 106 · Additional information : 107 The most current valid lists have been used as a basis for the production of this document. 108

8.2 Exposure controls 109 · Personal protective equipment : 110 · General protective and hygienic measures : 111 The usual precautionary measures are to be adhered to when handling chemicals. 112 113 Respiratory protection :

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Protection of hands :

Protective gloves. EN374 gloves for chemicals.

Gloves material : The selection of suitable gloves does not depend only on the material, but also on further marks of quality which may vary from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked before use.

Eye protection :

Safety glasses.

Body protection :

Protective work clothing.

114 115 116


Ref : ST160(B) / ST162(B) / ST163(B)

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SECTION 9: Physical and chemical properties 117

9.1 Information on basic physical and chemical properties 118 · General Information 119 · Appearance : 120

Form : Powder 121 Colour : Beige 122

· Odour : Characteristic 123 · Odour threshold : Not determined. 124 · pH-value : Not applicable. 125 · Change in condition 126

Melting point/Melting range : Undetermined. 127 Boiling point/Boiling range : Undetermined. 128

· Flash point : Not applicable. 129 · Flammability (solid, gaseous) : Not determined. 130 · Ignition temperature : Not applicable. 131 · Decomposition temperature : Not determined. 132 · Self-igniting : Product is not self igniting. 133 · Danger of explosion : Product does not present an explosion hazard. 134 · Explosion limits : 135

Lower : Not determined. 136 Upper : Not determined. 137

· Vapour pressure : Not applicable. 138 · Density at 20°C : 0.5 +/- 0.1 g/cm³ 139 · Relative density : Not determined. 140 · Vapour density : Not applicable. 141 · Evaporation rate : Not applicable. 142 · Solubility in / Miscibility with water : Partly soluble. 143 · Segregation coefficient (n-octanol/water) : Not determined. 144 · Viscosity: 145

Dynamic : Not applicable. 146 Kinematic : Not applicable. 147

9.2 Other information : No further relevant information available. 148 149 150 SECTION 10: Stability and reactivity 151

10.1 Reactivity : No further relevant information available. 152

10.2 Chemical stability : 153 · Thermal decomposition / conditions to be avoided : 154

No decomposition if used according to specifications. 155

10.3 Possibility of hazardous reactions : No dangerous reactions known. 156

10.4 Conditions to avoid : No further relevant information available. 157

10.5 Incompatible materials : No further relevant information available. 158

10.6 Hazardous decomposition products : No dangerous decomposition products known. 159 160 161 SECTION 11: Toxicological information 162

11.1 Information on toxicological effects 163 · Acute toxicity : Based on available data, the classification criteria are not met. 164


Ref : ST160(B) / ST162(B) / ST163(B)

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· LD/LC50 values relevant for classification: 165 302-95-4 sodium 3-alpha,12-alpha-dihydroxy-5-ß-cholan-24-oate 166 Oral LD50 500 mg/kg (ATE) 167 · Primary irritant effect : 168 · On the skin : Based on available data, the classification criteria are not met. 169 · On the eyes : Based on available data, the classification criteria are not met. 170 · Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. 171 · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) : 172 · Germ cell mutagenicity : Based on available data, the classification criteria are not met. 173 · Reproductive toxicity : Based on available data, the classification criteria are not met. 174 · STOT-single exposure : Based on available data, the classification criteria are not met. 175 · STOT-repeated exposure : Based on available data, the classification criteria are not met. 176 · Aspiration hazard : Based on available data, the classification criteria are not met. 177 178 SECTION 12: Ecological information 179

12.1 Toxicity 180 · Aquatic toxicity : No further relevant information available. 181

12.2 Persistence and degradability : No further relevant information available. 182

12.3 Bioaccumulative potential : No further relevant information available. 183

12.4 Mobility in soil : No further relevant information available. 184 · Additional ecological information : 185 · General notes : Generally not hazardous for water. 186

12.5 Results of PBT and vPvB assessment 187 · PBT : Not applicable. 188 · vPvB : Not applicable. 189

12.6 Other adverse effects : No further relevant information available. 190 191 192 SECTION 13: Disposal considerations 193

13.1 Waste treatment methods 194 · Recommendation : Must be specially treated according to official regulations. 195 · Uncleaned packaging : 196 · Recommendation : Disposal must be made according to official regulations. 197 198 199 SECTION 14: Transport information 200

14.1 UN-Number 201 · ADR, ADN, IMDG, IATA : Void 202

14.2 UN proper shipping name 203 · ADR, ADN, IMDG, IATA : Void 204

14.3 Transport hazard class(es) 205 · ADR, ADN, IMDG, IATA 206 · Class : Void 207

14.4 Packing group 208 · ADR, IMDG, IATA : Void 209


Ref : ST160(B) / ST162(B) / ST163(B)

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14.5 Environmental hazards : Not applicable. 210

14.6 Special precautions for user : Not applicable. 211

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code : 212 Not applicable. 213 · UN "Model Regulation": Void 214 215 216 SECTION 15: Regulatory information 217

15.1 Safety, health and environmental regulations/legislation specific for the mixture : 218 · Directive 2012/18/EU 219 · Named dangerous substances - ANNEX I : None of the ingredients is listed. 220

15.2 Chemical safety assessment : A Chemical Safety Assessment has not been carried out. 221 222 223 SECTION 16: Other information 224 225 This information is based on our present knowledge. However, this shall not constitute a guarantee for any 226 specific product features and shall not establish a legally valid contractual relationship. 227 228 · Relevant phrases : 229 H302 Harmful if swallowed. 230 H335 May cause respiratory irritation. 231 232 · Abbreviations and acronyms : 233 ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement 234 concerning the International Carriage of Dangerous Goods by Road) 235 IMDG: International Maritime Code for Dangerous Goods 236 IATA: International Air Transport Association 237 GHS: Globally Harmonised System of Classification and Labelling of Chemicals 238 EINECS: European Inventory of Existing Commercial Chemical Substances 239 ELINCS: European List of Notified Chemical Substances 240 CAS: Chemical Abstracts Service (division of the American Chemical Society) 241 LC50: Lethal concentration, 50 percent 242 LD50: Lethal dose, 50 percent 243 PBT: Persistent, Bioaccumulative and Toxic 244 SVHC: Substances of Very High Concern 245 vPvB: very Persistent and very Bioaccumulative 246 Acute Tox. 4: Acute toxicity, Hazard Category 4 247 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 248

SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ STEC supplement Ref : ST160(S) / ST162(S)

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1.1 Product identifier 2 · Trade name: CHROMagar™ STEC supplement 3





2.1 Classification of the substance or mixture 21 · Classification according to Regulation (EC) No 1272/2008 : 22 The product is not classified according to the CLP regulation. 23

2.2 Label elements 24 · Labelling according to Regulation (EC) No 1272/2008 : Not classified as hazardous 25 · Hazard pictograms : Not classified as hazardous 26 · Signal word : Not classified as hazardous 27 · Hazard statements : Not classified as hazardous 28 29 · Additional information : 30 EUH210 Safety data sheet available on request. 31


3.2 Mixtures 39 · Description : Mixture: consisting of the following components. 40 · Dangerous components : 41 42 CAS: 123333-66-4 Potassium Tellurite hydrate < 5%

EINECS: 232-213-1 Acute Tox. 3, H301;

Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335



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· SVHC : No 43 · Additional information : For the wording of the listed risk phrases, refer to section 16. 44 45 46 SECTION 4: First aid measures 47









5.3 Advice for firefighters 69 · Protective equipment : No special measures required. 70 71 72 SECTION 6: Accidental release measures 73


6.2 Environmental precautions : Do not allow product to reach sewage system or any water course. 76 Dilute with plenty of water. 77




· Information about fire - and explosion protection : No special measures required. 88



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7.2 Conditions for safe storage, including any incompatibilities : 89 · Storage : 90 · Requirements to be met by storerooms and receptacles : Store away from light and moisture. 91 No special requirements. 92 · Information about storage in one common storage facility : Not required. 93 · Further information about storage conditions : Store in cool, 94 dry conditions in well sealed receptacles. 95 · Recommended storage temperature : 15-30°C 96








Gloves material : The selection of suitable gloves does not depend only on the material, but also on further marks of quality which may vary from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked before use.

Eye protection :

Safety glasses.

Body protection :


113



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114 SECTION 9: Physical and chemical properties 115


Form : Lyophilized 119 Colour : White to yellowish 120

· Odour : Odourless 121 · Odour threshold : Not determined. 122 · pH-value : Not applicable. 123 · Change in condition 124




· Vapour pressure : Not applicable. 136 · Density at 20°C : 0.5 +/- 0.1 g/cm³ 137 · Relative density : Not determined. 138 · Vapour density : Not applicable. 139 · Evaporation rate : Not applicable. 140 · Solubility in / Miscibility with water : Fully soluble. 141 · Segregation coefficient (n-octanol/water) : Not determined. 142 · Viscosity: 143


9.2 Other information : No further relevant information available. 146 147 148 SECTION 10: Stability and reactivity 149








11.1 Information on toxicological effects 161



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· Acute toxicity : Based on available data, the classification criteria are not met. 162 · LD/LC50 values relevant for classification : 163 123333-66-4 Potassium Tellurite hydrate 164 Oral LD50 100 mg/kg (ATE) 165 · Primary irritant effect : 166 · On the skin : Based on available data, the classification criteria are not met. 167 · On the eyes : Based on available data, the classification criteria are not met. 168 · Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. 169 · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) : 170 · Germ cell mutagenicity : Based on available data, the classification criteria are not met. 171 · Reproductive toxicity : Based on available data, the classification criteria are not met. 172 · STOT-single exposure : Based on available data, the classification criteria are not met. 173 · STOT-repeated exposure : Based on available data, the classification criteria are not met. 174 · Aspiration hazard : Based on available data, the classification criteria are not met. 175 176 177 SECTION 12: Ecological information 178






12.6 Other adverse effects : No further relevant information available. 189 190 191 SECTION 13: Disposal considerations 192

13.1 Waste treatment methods 193 · Recommendation : Must be specially treated according to official regulations. 194 · Uncleaned packaging : 195 · Recommendation : Disposal must be made according to official regulations. 196 197 198 SECTION 14: Transport information 199






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14.7 Transport in bulk according to Annex II of Marpol and the IBC Code : 211 Not applicable. 212 · UN "Model Regulation": Void 213 214 215 SECTION 15: Regulatory information 216


15.2 Chemical safety assessment : A Chemical Safety Assessment has not been carried out. 220 221 222 SECTION 16: Other information 223 224 This information is based on our present knowledge. However, this shall not constitute a guarantee for any 225 specific product features and shall not establish a legally valid contractual relationship. 226 227 · Relevant phrases : 228 H301 Toxic if swallowed. 229 H315 Causes skin irritation. 230 H319 Causes serious eye irritation. 231 H335 May cause respiratory irritation. 232 233 · Abbreviations and acronyms : 234 ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement 235 concerning the International Carriage of Dangerous Goods by Road) 236 IMDG: International Maritime Code for Dangerous Goods 237 IATA: International Air Transport Association 238 GHS: Globally Harmonised System of Classification and Labelling of Chemicals 239 EINECS: European Inventory of Existing Commercial Chemical Substances 240 ELINCS: European List of Notified Chemical Substances 241 CAS: Chemical Abstracts Service (division of the American Chemical Society) 242 LC50: Lethal concentration, 50 percent 243 LD50: Lethal dose, 50 percent 244 PBT: Persistent, Bioaccumulative and Toxic 245 SVHC: Substances of Very High Concern 246 vPvB: very Persistent and very Bioaccumulative 247 Acute Tox. 3: Acute toxicity, Hazard Category 3 248 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 249 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 250 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 251


CHROMagar™ STEC supplement Ref : ST163(S)

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1.1 Product identifier 2 · Trade name : CHROMagar™ STEC supplement 3





2.1 Classification of the substance or mixture 21 · Classification according to Regulation (EC) No 1272/2008 : 22

23 GHS07 : Acute Tox. 4 H302 Harmful if swallowed. 24

25

2.2 Label elements 26 · Labelling according to Regulation (EC) No 1272/2008 : 27 The product is classified and labelled according to the CLP regulation. 28 · Hazard pictograms : 29 30 31 32 · Signal word : Warning 33 · Hazard-determining components of labelling: Potassium Tellurite hydrate 34 · Hazard statements : 35 H302 : Harmful if swallowed. 36 · Precautionary statements : 37 P264 : Wash hands thoroughly after handling. 38 P270 : Do not eat, drink or smoke when using this product. 39 P301 + P312 : If swallowed call a poison center/doctor if you feel unwell. 40 P501 : Dispose of contents/container in accordance with local/regional/national/international 41

regulations. 42 43 · Labelling of packages where the contents do not exceed 125 ml 44 · Hazard pictograms 45 46 47 48 · Signal word : Warning 49

GHS07

GHS07



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· Hazard-determining components of labelling: Potassium Tellurite hydrate 50 · Hazard statements : Not classified as hazardous 51 · Precautionary statements : 52 P301 + P312 : If swallowed : call a poison center/doctor if you feel unwell. 53


3.2 Mixtures 61 · Description : Mixture: consisting of the following components. 62 · Dangerous components : 63 64 CAS: 123333-66-4 Potassium Tellurite hydrate 5-10% 65 EINECS: 232-213-1 Acute Tox. 3, H301; Skin Irrit. 2, H315; Eye Irrit. 2, H319; 66

STOT SE 3, H335 67 68 · SVHC : No 69 · Additional information : For the wording of the listed risk phrases, refer to section 16. 70 71 72 SECTION 4: First aid measures 73









5.3 Advice for firefighters 95 · Protective equipment : No special measures required. 96 97 98



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SECTION 6: Accidental release measures 99


6.2 Environmental precautions : 102 Do not allow product to reach sewage system or any water course. Dilute with plenty of water. 103




· Information about fire - and explosion protection : No special measures required. 114

7.2 Conditions for safe storage, including any incompatibilities : 115 · Storage : 116 · Requirements to be met by storerooms and receptacles : Store away from light and moisture. 117 No special requirements. 118 · Information about storage in one common storage facility : Not required. 119 · Further information about storage conditions : Store in cool, 120 dry conditions in well sealed receptacles. 121 · Recommended storage temperature : 15-30°C 122








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Gloves material : Butyl rubber, BR Eye protection :

Safety glasses.

Body protection :


139 140 SECTION 9: Physical and chemical properties 141


Form : Powder 145 Colour : White 146

· Odour : Characteristic. 147 · Odour threshold : Not determined. 148 · pH-value : Not applicable. 149 · Change in condition 150




· Vapour pressure : Not applicable. 162 · Density at 20°C : 0.5 +/- 0.1 g/cm³ 163 · Relative density : Not determined. 164 · Vapour density : Not applicable. 165 · Evaporation rate : Not applicable. 166 · Solubility in / Miscibility with water : Fully soluble. 167 · Segregation coefficient (n-octanol/water) : Not determined. 168 · Viscosity : 169


9.2 Other information : No further relevant information available. 172 173



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SECTION 10: Stability and reactivity 174








11.1 Information on toxicological effects 186 · Acute toxicity : Harmful if swallowed. 187 · LD/LC50 values relevant for classification : 188 189

123333-66-4 Potassium Tellurite hydrate 190 Oral LD50 100 mg/kg (ATE) 191

192 · Primary irritant effect : 193 · On the skin : Based on available data, the classification criteria are not met. 194 · On the eyes : Based on available data, the classification criteria are not met. 195 · Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. 196 · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) : 197 · Germ cell mutagenicity : Based on available data, the classification criteria are not met. 198 · Reproductive toxicity : Based on available data, the classification criteria are not met. 199 · STOT-single exposure : Based on available data, the classification criteria are not met. 200 · STOT-repeated exposure : Based on available data, the classification criteria are not met. 201 · Aspiration hazard : Based on available data, the classification criteria are not met. 202 203 204 SECTION 12: Ecological information 205






12.6 Other adverse effects : No further relevant information available. 216 217



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SECTION 13: Disposal considerations 218

13.1 Waste treatment methods 219 · Recommendation : Must be specially treated according to official regulations.. 220 · Uncleaned packaging : 221 · Recommendation : Disposal must be made according to official regulations. 222 223 224 SECTION 14: Transport information 225







14.7 Transport in bulk according to Annex II of Marpol and the IBC Code : Not applicable. 237 · UN "Model Regulation": Void 238 239 240 SECTION 15: Regulatory information 241


15.2 Chemical safety assessment : A Chemical Safety Assessment has not been carried out. 245 246 247 SECTION 16: Other information 248 249 This information is based on our present knowledge. However, this shall not constitute a guarantee for any 250 specific product features and shall not establish a legally valid contractual relationship. 251 252 · Relevant phrases : 253 H301: Toxic if swallowed. 254 H315: Causes skin irritation. 255 H319: Causes serious eye irritation. 256 H335: May cause respiratory irritation. 257 · Abbreviations and acronyms : 258 ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement 259 concerning the International Carriage of Dangerous Goods by Road) 260 IMDG: International Maritime Code for Dangerous Goods 261 IATA: International Air Transport Association. 262 GHS: Globally Harmonised System of Classification and Labelling of Chemicals 263 EINECS: European Inventory of Existing Commercial Chemical Substances 264



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ELINCS: European List of Notified Chemical Substances 265 CAS: Chemical Abstracts Service (division of the American Chemical Society) 266 LC50: Lethal concentration, 50 percent 267 LD50: Lethal dose, 50 percent 268 PBT: Persistent, Bioaccumulative and Toxic 269 SVHC: Substances of Very High Concern 270 vPvB: very Persistent and very Bioaccumulative 271 Acute Tox. 3: Acute toxicity, Hazard Category 3 272 Acute Tox. 4: Acute toxicity, Hazard Category 4 273 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 274 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 275 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 276 277 278

Documents

SAFETY DATA SHEET AD-ASQ-263 CHROMagar™ STEC base … · Page 1/6 09-Feb-2018 SECTION 1: Identification of the mixture and of the company / undertaking 1 1.1 Product identifier