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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31) CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B) AD-ASQ-238 Version 1.1 Page 1/6 09-Feb-2018 SECTION 1: Identification of the mixture and of the company / undertaking 1.1 Product identifier · Trade name: CHROMagar™ mSuperCARBA™ base 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the preparation : Reagent for Laboratory Use 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: CHROMagar 4, place du 18 Juin 1940 - 75006 Paris Tel: +33 1 45 48 05 05 Email : [email protected] 1.4 Emergency telephone number: France (ORFILA 24h/24) - Tel : +33 (0)1 45 42 59 59 Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24) EU Tel: 112 Belgique - Tel : 32 070/245 245 UK : 111 (NHS) / 0345 300 9923 (HSE) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 : The product is not classified according to the CLP regulation. 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 : Not classified as hazardous · Hazard pictograms : Not classified as hazardous · Signal word : Not classified as hazardous · Hazard statements : Not classified as hazardous 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition / information on ingredients 3.2 Mixtures · Description : Mixture: consisting of the following components. · Dangerous components : Not classified as hazardous. · SVHC : No · Additional information : For the wording of the listed risk phrases, refer to section 16. SECTION 4: First aid measures 4.1 Description of first aid measures · General information : Position and transport stably in side position. In case of irregular breathing or respiratory arrest provide artificial respiration.

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Page 1: SAFETY DATA SHEET AD-ASQ-238 Version 1.1 Page … · AD-ASQ-238 Version 1.1 Page 1/6 09-Feb-2018 SECTION 1: Identification of the mixture and of the company / undertaking 1 1.1 Product

SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B)

AD-ASQ-238

Version 1.1

Page 1/6 09-Feb-2018

SECTION 1: Identification of the mixture and of the company / undertaking 1

1.1 Product identifier 2 · Trade name: CHROMagar™ mSuperCARBA™ base 3

1.2 Relevant identified uses of the substance or mixture and uses advised against 4 No further relevant information available. 5 · Application of the substance / the preparation : Reagent for Laboratory Use 6

1.3 Details of the supplier of the safety data sheet 7 · Manufacturer/Supplier: 8

CHROMagar 9 4, place du 18 Juin 1940 - 75006 Paris 10 Tel: +33 1 45 48 05 05 11 Email : [email protected] 12

1.4 Emergency telephone number: 13 France (ORFILA 24h/24) - Tel : +33 (0)1 45 42 59 59 14 Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24) EU Tel: 112 15 Belgique - Tel : 32 070/245 245 16 UK : 111 (NHS) / 0345 300 9923 (HSE) 17 18 19 SECTION 2: Hazards identification 20

2.1 Classification of the substance or mixture 21 · Classification according to Regulation (EC) No 1272/2008 : 22 The product is not classified according to the CLP regulation. 23

2.2 Label elements 24 · Labelling according to Regulation (EC) No 1272/2008 : Not classified as hazardous 25 · Hazard pictograms : Not classified as hazardous 26 · Signal word : Not classified as hazardous 27 · Hazard statements : Not classified as hazardous 28

2.3 Other hazards 29 · Results of PBT and vPvB assessment 30 · PBT: Not applicable. 31 · vPvB: Not applicable. 32 33 34 SECTION 3: Composition / information on ingredients 35

3.2 Mixtures 36 · Description : Mixture: consisting of the following components. 37 · Dangerous components : Not classified as hazardous. 38 · SVHC : No 39 · Additional information : For the wording of the listed risk phrases, refer to section 16. 40 41 42 SECTION 4: First aid measures 43

4.1 Description of first aid measures 44 · General information : Position and transport stably in side position. 45

In case of irregular breathing or respiratory arrest provide artificial 46 respiration. 47

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B)

AD-ASQ-238

Version 1.1

Page 2/6 09-Feb-2018

· After excessive inhalation : Provide fresh air; consult a doctor in case of medical complaints. 48 · After skin contact : Generally the product does not irritate the skin. 49 In the event of irritation, to withdraw soiled clothing, to wash the parts 50

reached with soapy water, to rinse with large water. 51 If skin irritation continues, consult a doctor. 52 · After eye contact : Rinse opened eye for several minutes under running water. 53 · After swallowing : Do not induce vomiting; call for medical help immediately. 54

4.2 Most important symptoms and effects, both acute and delayed : 55 No further relevant information available. 56

4.3 Indication of any immediate medical attention and special treatment needed : 57 No further relevant information available. 58 59 60 SECTION 5: Firefighting measures 61

5.1 Suitable extinguishing agents: 62 CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 63

5.2 Special hazards arising from the substance or mixture : No further relevant information available. 64

5.3 Advice for firefighters 65 · Protective equipment : No special measures required. 66 67 68 SECTION 6: Accidental release measures 69

6.1 Personal precautions, protective equipment and emergency procedures : 70 No special measures required. Avoid formation of dust. 71 6.2 Environmental precautions : Do not allow product to reach sewage system or any water course. Dilute 72 with plenty of water. 73

6.3 Methods and material for containment and cleaning up : Pick up mechanically. 74

6.4 Reference to other sections : 75 See Section 7 for information on safe handling. 76 See Section 8 for information on personal protective equipment. 77 See Section 13 for disposal information. 78 79 80 SECTION 7: Handling and storage 81

7.1 Precautions for safe handling : Keep away from heat and direct sunlight. 82 Thorough dedusting. 83

· Information about fire - and explosion protection: No special measures required. 84

7.2 Conditions for safe storage, including any incompatibilities : 85 · Storage : 86 · Requirements to be met by storerooms and receptacles : Store away from light and moisture. 87 No special requirements. 88 · Information about storage in one common storage facility : Not required. 89 · Further information about storage conditions : Store in cool, dry conditions in well sealed 90

receptacles. 91 · Recommended storage temperature : 15-30°C 92

7.3 Specific end use(s) : No further relevant information available. 93

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B)

AD-ASQ-238

Version 1.1

Page 3/6 09-Feb-2018

SECTION 8: Exposure controls / personal protection 94 95 · Additional information about design of technical facilities : No further data; see section 7. 96

8.1 Control parameters 97 · Ingredients with limit values that require monitoring at the workplace : 98 The product does not contain any signifiant quantities of materials with critical values that have to be monitored at 99 the workplace. 100 · Additional information : 101 The most current valid lists have been used as a basis for the production of this document. 102

8.2 Exposure controls 103 · Personal protective equipment : 104 · General protective and hygienic measures : 105 The usual precautionary measures are to be adhered to when handling chemicals. 106 107 Respiratory protection :

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Protection of hands :

Protective gloves. EN374 gloves for chemicals.

Gloves material : Butyl rubber, BR. Eye protection :

Safety glasses.

Body protection :

Protective work clothing.

108 109 SECTION 9: Physical and chemical properties 110

9.1 Information on basic physical and chemical properties 111 · General Information 112 · Appearance : 113

Form : Powder 114 Colour : Beige 115

· Odour : Characteristic 116 · Odour threshold : Not determined. 117 · pH-value : Not applicable. 118 · Change in condition 119

Melting point/Melting range : Undetermined. 120 Boiling point/Boiling range : Undetermined. 121

· Flash point : Not applicable. 122

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B)

AD-ASQ-238

Version 1.1

Page 4/6 09-Feb-2018

· Flammability (solid, gaseous) : Not determined. 123 · Ignition temperature: Not applicable. 124 · Decomposition temperature: Not determined. 125 · Self-igniting : Product is not self igniting. 126 · Danger of explosion : Product does not present an explosion hazard. 127 · Explosion limits : 128

Lower : Not determined. 129 Upper : Not determined. 130

· Vapour pressure : Not applicable. 131 · Density at 20°C : 0.5 +/- 0.1 g/cm³ 132 · Relative density : Not determined. 133 · Vapour density : Not applicable. 134 · Evaporation rate : Not applicable. 135 · Solubility in / Miscibility with water : Partly soluble. 136 · Segregation coefficient (n-octanol/water) : Not determined. 137 · Viscosity: 138

Dynamic : Not applicable. 139 Kinematic : Not applicable. 140

9.2 Other information : No further relevant information available. 141 142 143 SECTION 10: Stability and reactivity 144

10.1 Reactivity : No further relevant information available. 145

10.2 Chemical stability : 146 · Thermal decomposition / conditions to be avoided : 147

No decomposition if used and stored according to 148 specifications. 149

10.3 Possibility of hazardous reactions : No dangerous reactions known. 150

10.4 Conditions to avoid : No further relevant information available. 151

10.5 Incompatible materials : No further relevant information available. 152

10.6 Hazardous decomposition products : No dangerous decomposition products known. 153 154 155 SECTION 11: Toxicological information 156

11.1 Information on toxicological effects 157 · Acute toxicity Based on available data, the classification criteria are not met. 158 · Primary irritant effect : 159 · On the skin : Based on available data, the classification criteria are not met. 160 · On the eyes : Based on available data, the classification criteria are not met. 161 · Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. 162 · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) : 163 · Germ cell mutagenicity : Based on available data, the classification criteria are not met. 164 · Reproductive toxicity : Based on available data, the classification criteria are not met. 165 · STOT-single exposure : Based on available data, the classification criteria are not met. 166 · STOT-repeated exposure : Based on available data, the classification criteria are not met. 167 · Aspiration hazard : Based on available data, the classification criteria are not met. 168 169 170

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B)

AD-ASQ-238

Version 1.1

Page 5/6 09-Feb-2018

SECTION 12: Ecological information 171

12.1 Toxicity 172 · Aquatic toxicity : No further relevant information available. 173

12.2 Persistence and degradability : No further relevant information available. 174

12.3 Bioaccumulative potential : No further relevant information available. 175

12.4 Mobility in soil : No further relevant information available. 176 · Additional ecological information: 177 · General notes : Generally not hazardous for water. 178

12.5 Results of PBT and vPvB assessment 179 · PBT : Not applicable. 180 · vPvB : Not applicable. 181

12.6 Other adverse effects : No further relevant information available. 182 183 184 SECTION 13: Disposal considerations 185

13.1 Waste treatment methods 186 · Recommendation : Must be specially treated according to official regulations. 187 · Uncleaned packaging : 188 · Recommendation : Disposal must be made according to official regulations. 189 190 191 SECTION 14: Transport information 192

14.1 UN-Number 193 · ADR, ADN, IMDG, IATA : Void 194

14.2 UN proper shipping name 195 · ADR, ADN, IMDG, IATA : Void 196

14.3 Transport hazard class(es) 197 · ADR, ADN, IMDG, IATA 198 · Class : Void 199

14.4 Packing group 200 · ADR, IMDG, IATA : Void 201

14.5 Environmental hazards : Not applicable. 202

14.6 Special precautions for user : Not applicable. 203

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code : 204 Not applicable. 205 · UN "Model Regulation": Void 206 207 208 SECTION 15: Regulatory information 209

15.1 Safety, health and environmental regulations/legislation specific for the mixture : 210 · Directive 2012/18/EU 211 · Named dangerous substances - ANNEX I : None of the ingredients is listed. 212

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ base Ref : SC172(B) / SC173(B)

AD-ASQ-238

Version 1.1

Page 6/6 09-Feb-2018

15.2 Chemical safety assessment : A Chemical Safety Assessment has not been carried out. 213 214 215 SECTION 16: Other information 216 217 This information is based on our present knowledge. However, this shall not constitute a guarantee for any 218 specific product features and shall not establish a legally valid contractual relationship. 219 220 · Abbreviations and acronyms: 221 ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement 222 concerning the International Carriage of Dangerous Goods by Road) 223 IMDG: International Maritime Code for Dangerous Goods 224 IATA: International Air Transport Association 225 GHS: Globally Harmonised System of Classification and Labelling of Chemicals 226 EINECS: European Inventory of Existing Commercial Chemical Substances 227 ELINCS: European List of Notified Chemical Substances 228 CAS: Chemical Abstracts Service (division of the American Chemical Society) 229 PBT: Persistent, Bioaccumulative and Toxic 230 SVHC: Substances of Very High Concern 231 vPvB: very Persistent and very Bioaccumulative 232

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ - S1 Ref : SC172(S1) / SC173(S1)

AD-ASQ-239

Version 1.1

Page 1/6 09-Feb-2018

SECTION 1: Identification of the mixture and of the company / undertaking 1

1.1 Product identifier 2 · Trade name: CHROMagar™ mSuperCARBA™ - S1 3

1.2 Relevant identified uses of the substance or mixture and uses advised against 4 No further relevant information available. 5 · Application of the substance / the preparation : Reagent for Laboratory Use 6

1.3 Details of the supplier of the safety data sheet 7 · Manufacturer/Supplier: 8

CHROMagar 9 4, place du 18 Juin 1940 - 75006 Paris 10 Tel: +33 1 45 48 05 05 11 Email : [email protected] 12

1.4 Emergency telephone number: 13 France (ORFILA 24h/24) - Tel : +33 (0)1 45 42 59 59 14 Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24) EU Tel: 112 15 Belgique - Tel : 32 070/245 245 16 UK : 111 (NHS) / 0345 300 9923 (HSE) 17 18 19 SECTION 2: Hazards identification 20

2.1 Classification of the substance or mixture 21 · Classification according to Regulation (EC) No 1272/2008 : 22 The product is not classified according to the CLP regulation. 23

2.2 Label elements 24 · Labelling according to Regulation (EC) No 1272/2008 : Not classified as hazardous 25 · Hazard pictograms : Not classified as hazardous 26 · Signal word : Not classified as hazardous 27 · Hazard statements : Not classified as hazardous 28 · Results of PBT and vPvB assessment 29 · PBT: Not applicable. 30 · vPvB: Not applicable. 31 32 33 SECTION 3: Composition / information on ingredients 34

3.2 Mixtures 35 · Description : Mixture: consisting of the following components. 36 · Dangerous components : Not classified as hazardous. 37 · SVHC : No 38 · Additional information : For the wording of the listed risk phrases, refer to section 16. 39 40 41 SECTION 4: First aid measures 42

4.1 Description of first aid measures 43 · General information : Position and transport stably in side position. 44 · After excessive inhalation : Provide fresh air; consult a doctor in case of medical complaints. 45 · After skin contact : In the event of irritation, to withdraw soiled clothing, to wash the parts 46

reached with soapy water, to rinse with large water. 47 If skin irritation continues, consult a doctor. 48

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ - S1 Ref : SC172(S1) / SC173(S1)

AD-ASQ-239

Version 1.1

Page 2/6 09-Feb-2018

· After eye contact : Rinse opened eye for several minutes under running water. 49 · After swallowing : Do not induce vomiting; call for medical help immediately. 50

4.2 Most important symptoms and effects, both acute and delayed : 51 No further relevant information available. 52

4.3 Indication of any immediate medical attention and special treatment needed : 53 No further relevant information available. 54 55 56 SECTION 5: Firefighting measures 57

5.1 Suitable extinguishing agents: 58 CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 59

5.2 Special hazards arising from the substance or mixture : No further relevant information available. 60

5.3 Advice for firefighters 61 · Protective equipment : No special measures required. 62 63 64 SECTION 6: Accidental release measures 65

6.1 Personal precautions, protective equipment and emergency procedures : 66 No special measures required. 67

6.2 Environmental precautions : Dilute with plenty of water. 68

6.3 Methods and material for containment and cleaning up : Absorb with liquid-binding material (sand, 69 diatomite, acid binders, universal binders, sawdust). 70

6.4 Reference to other sections : 71 See Section 7 for information on safe handling. 72 See Section 8 for information on personal protective equipment. 73 See Section 13 for disposal information. 74 75 76 SECTION 7: Handling and storage 77

7.1 Precautions for safe handling : No special measures required. 78 · Information about fire - and explosion protection: No special measures required. 79

7.2 Conditions for safe storage, including any incompatibilities : 80 · Storage : 81 · Requirements to be met by storerooms and receptacles : Store away from light and moisture. 82 · Information about storage in one common storage facility : Not required. 83 · Further information about storage conditions : Protect from frost. 84 · Recommended storage temperature : 15-30°C 85

7.3 Specific end use(s) : No further relevant information available. 86 87 88 89

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ - S1 Ref : SC172(S1) / SC173(S1)

AD-ASQ-239

Version 1.1

Page 3/6 09-Feb-2018

SECTION 8: Exposure controls / personal protection 90 91 · Additional information about design of technical facilities : No further data; see section 7. 92

8.1 Control parameters 93 · Ingredients with limit values that require monitoring at the workplace : 94 The product does not contain any signifiant quantities of materials with critical values that have to be monitored at 95 the workplace. 96 · Additional information : 97 The most current valid lists have been used as a basis for the production of this document. 98

8.2 Exposure controls 99 · Personal protective equipment : 100 · General protective and hygienic measures : 101 The usual precautionary measures are to be adhered to when handling chemicals. 102 103 Respiratory protection :

Not required.

Protection of hands :

Protective gloves. EN374 gloves for chemicals.

Gloves material : Butyl rubber, BR. Eye protection :

Safety glasses.

Body protection :

Protective work clothing.

104 105 SECTION 9: Physical and chemical properties 106

9.1 Information on basic physical and chemical properties 107 · General Information 108 · Appearance : 109

Form : Liquid 110 Colour : Yellowish 111

· Odour : Characteristic 112 · Odour threshold : Not determined. 113 · pH-value : Not determined. 114 · Change in condition 115

Melting point/Melting range : Undetermined. 116 Boiling point/Boiling range : Undetermined. 117

· Flash point : Not applicable. 118

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ - S1 Ref : SC172(S1) / SC173(S1)

AD-ASQ-239

Version 1.1

Page 4/6 09-Feb-2018

· Flammability (solid, gaseous) : Not applicable. 119 · Ignition temperature: Not applicable. 120 · Decomposition temperature: Not determined. 121 · Self-igniting : Product is not self igniting. 122 · Danger of explosion : Product does not present an explosion hazard. 123 · Explosion limits : 124

Lower : Not determined. 125 Upper : Not determined. 126

· Vapour pressure : Not determined. 127 · Density at 20°C : 1+/-10% g/cm³ 128 · Relative density : Not determined. 129 · Vapour density : Not determined. 130 · Evaporation rate : Not determined. 131 · Solubility in / Miscibility with water : Fully miscible. 132 · Segregation coefficient (n-octanol/water) : Not determined. 133 · Viscosity: 134

Dynamic : Not determined. 135 Kinematic : Not determined. 136

9.2 Other information : No further relevant information available. 137 138 139 SECTION 10: Stability and reactivity 140

10.1 Reactivity : No further relevant information available. 141

10.2 Chemical stability : 142 · Thermal decomposition / conditions to be avoided : 143

No decomposition if used according to specifications. 144

10.3 Possibility of hazardous reactions : No dangerous reactions known. 145

10.4 Conditions to avoid : No further relevant information available. 146

10.5 Incompatible materials : No further relevant information available. 147

10.6 Hazardous decomposition products : No dangerous decomposition products known. 148 149 150 SECTION 11: Toxicological information 151

11.1 Information on toxicological effects 152 · Acute toxicity : Based on available data, the classification criteria are not met. 153 · Primary irritant effect : 154 · On the skin : Based on available data, the classification criteria are not met. 155 · On the eyes : Based on available data, the classification criteria are not met. 156 · Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. 157 · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) : 158 · Germ cell mutagenicity : Based on available data, the classification criteria are not met. 159 · Reproductive toxicity : Based on available data, the classification criteria are not met. 160 · STOT-single exposure : Based on available data, the classification criteria are not met. 161 · STOT-repeated exposure : Based on available data, the classification criteria are not met. 162 · Aspiration hazard : Based on available data, the classification criteria are not met. 163 164 165 166

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ - S1 Ref : SC172(S1) / SC173(S1)

AD-ASQ-239

Version 1.1

Page 5/6 09-Feb-2018

SECTION 12: Ecological information 167

12.1 Toxicity 168 · Aquatic toxicity : No further relevant information available. 169

12.2 Persistence and degradability : No further relevant information available. 170

12.3 Bioaccumulative potential : No further relevant information available. 171

12.4 Mobility in soil : No further relevant information available. 172 · Additional ecological information: 173 · General notes : Generally not hazardous for water. 174

12.5 Results of PBT and vPvB assessment 175 · PBT : Not applicable. 176 · vPvB : Not applicable. 177

12.6 Other adverse effects : No further relevant information available. 178 179 180 SECTION 13: Disposal considerations 181

13.1 Waste treatment methods 182 · Recommendation : Must be specially treated according to official regulations. 183 Smaller quantities can be disposed of with household waste. 184 · Uncleaned packaging : 185 · Recommendation : Disposal must be made according to official regulations. 186 · Recommended cleansing agents : Water, if necessary together with cleansing agents. 187 188 189 SECTION 14: Transport information 190

14.1 UN-Number 191 · ADR, ADN, IMDG, IATA : Void 192

14.2 UN proper shipping name 193 · ADR, ADN, IMDG, IATA : Void 194

14.3 Transport hazard class(es) 195 · ADR, ADN, IMDG, IATA 196 · Class : Void 197

14.4 Packing group 198 · ADR, IMDG, IATA : Void 199

14.5 Environmental hazards : Not applicable. 200

14.6 Special precautions for user : Not applicable. 201 · Stowage Category : A 202

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code : 203 Not applicable. 204 · UN "Model Regulation": Void 205 206 207 208

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™ - S1 Ref : SC172(S1) / SC173(S1)

AD-ASQ-239

Version 1.1

Page 6/6 09-Feb-2018

SECTION 15: Regulatory information 209

15.1 Safety, health and environmental regulations/legislation specific for the mixture : 210 · Directive 2012/18/EU 211 · Named dangerous substances - ANNEX I : None of the ingredients is listed. 212 · Qualifying quantity (tonnes) for the application of lower-tier requirements : 200 t 213 · Qualifying quantity (tonnes) for the application of upper-tier requirements : 500 t 214

15.2 Chemical safety assessment : A Chemical Safety Assessment has not been carried out. 215 216 217 SECTION 16: Other information 218 219 This information is based on our present knowledge. However, this shall not constitute a guarantee for any 220 specific product features and shall not establish a legally valid contractual relationship. 221 222 · Abbreviations and acronyms: 223 ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement 224 concerning the International Carriage of Dangerous Goods by Road) 225 IMDG: International Maritime Code for Dangerous Goods 226 IATA: International Air Transport Association 227 GHS: Globally Harmonised System of Classification and Labelling of Chemicals 228 EINECS: European Inventory of Existing Commercial Chemical Substances 229 ELINCS: European List of Notified Chemical Substances 230 CAS: Chemical Abstracts Service (division of the American Chemical Society) 231 PBT: Persistent, Bioaccumulative and Toxic 232 SVHC: Substances of Very High Concern 233 vPvB: very Persistent and very Bioaccumulative 234

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

AD-ASQ-283

Version 1.1

Page 1/7 09-Feb-2018

SECTION 1: Identification of the mixture and of the company / undertaking 1

1.1 Product identifier 2 · Trade name : CHROMagar™ mSuperCARBA™- S2 3

1.2 Relevant identified uses of the substance or mixture and uses advised against 4 No further relevant information available. 5 · Application of the substance / the preparation : Reagent for Laboratory Use 6

1.3 Details of the supplier of the safety data sheet 7 · Manufacturer/Supplier : 8

CHROMagar 9 4, place du 18 Juin 1940 - 75006 Paris 10 Tel: +33 1 45 48 05 05 11 Email : [email protected] 12

1.4 Emergency telephone number : 13 France (ORFILA 24h/24) - Tel : +33 (0)1 45 42 59 59 14 Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24) EU Tel: 112 15 Belgique - Tel : 32 070/245 245 16 UK : 111 (NHS) / 0345 300 9923 (HSE) 17 18 19 SECTION 2: Hazards identification 20

2.1 Classification of the substance or mixture 21 · Classification according to Regulation (EC) No 1272/2008 : 22

23 GHS07 : Skin Sens. 1 H317 May cause an allergic skin reaction. 24

25

2.2 Label elements 26 · Labelling according to Regulation (EC) No 1272/2008 : 27 The product is classified and labelled according to the CLP regulation. 28 · Hazard pictograms : 29 30 31 32 · Signal word : Warning 33 · Hazard-determining components of labelling: ß-lactam antibiotic 34 · Hazard statements : 35 H317 : May cause an allergic skin reaction. 36 · Precautionary statements : 37 P261 : Avoid breathing dust/fume/gas/mist/vapours/spray. 38 P280 : Wear protective gloves/protective clothing/eye protection/face protection. 39 P333 + P313 : If skin irritation or rash occurs: Get medical advice/attention. 40 P302 + P352 : If on skin wash with plenty of water. 41 P501 : Dispose of contents/container in accordance with local/regional/national/international 42

regulations. 43 · Labelling of packages where the contents do not exceed 125 ml 44 · Hazard pictograms 45 46 47 48 · Signal word : Warning 49

GHS07

GHS07

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

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· Hazard-determining components of labelling: ß-lactam antibiotic 50 · Hazard statements : 51 H317 : May cause an allergic skin reaction. 52 · Precautionary statements : 53 P261 : Avoid breathing dust/fume/gas/mist/vapours/spray. 54 P280 : Wear protective gloves/protective clothing/eye protection/face protection. 55 P333 + P313 : If skin irritation or rash occurs: Get medical advice/attention. 56 P302 + P352 : If on skin wash with plenty of water. 57 P501 : Dispose of contents/container in accordance with local/regional/national/international 58

regulations. 59

2.3 Other hazards 60 · Results of PBT and vPvB assessment 61 · PBT : Not applicable. 62 · vPvB : Not applicable. 63 64 65 SECTION 3: Composition / information on ingredients 66

3.2 Mixtures 67 · Description : Mixture: consisting of the following components. 68 · Dangerous components : 69 70 CAS: ß-lactam antibiotic <5% 71 EINECS : Skin Irrit. 2, H315; Eye Irrit. 2, H319 ; 72

Skin Sens. 1, H317; STOT SE 3, H335 73 74

· SVHC : No 75 · Additional information : For the wording of the listed risk phrases, refer to section 16. 76 77 78 SECTION 4: First aid measures 79

4.1 Description of first aid measures 80 · General information : Position and transport stably in side position. 81

In case of irregular breathing or respiratory arrest provide artificial 82 respiration. 83

· After excessive inhalation : Provide fresh air; consult a doctor in case of medical complaints. 84 · After skin contact : Generally the product does not irritate the skin. 85 In the event of irritation, to withdraw soiled clothing, to wash the parts 86

reached with soapy water, to rinse with large water. 87 If skin irritation continues, consult a doctor. 88 · After eye contact : Rinse opened eye for several minutes under running water. 89 · After swallowing : Do not induce vomiting; call for medical help immediately. 90

4.2 Most important symptoms and effects, both acute and delayed : 91 No further relevant information available. 92

4.3 Indication of any immediate medical attention and special treatment needed : 93 No further relevant information available. 94 95 96 SECTION 5: Firefighting measures 97

5.1 Suitable extinguishing agents : 98 CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 99

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

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5.2 Special hazards arising from the substance or mixture : No further relevant information available. 100

5.3 Advice for firefighters 101 · Protective equipment : No special measures required. 102 103 104 SECTION 6: Accidental release measures 105

6.1 Personal precautions, protective equipment and emergency procedures : 106 No special measures required. Avoid formation of dust. 107

6.2 Environmental precautions : 108 Do not allow product to reach sewage system or any water course. Dilute with plenty of water. 109

6.3 Methods and material for containment and cleaning up : Pick up mechanically. 110

6.4 Reference to other sections : 111 See Section 7 for information on safe handling. 112 See Section 8 for information on personal protective equipment. 113 See Section 13 for disposal information. 114 115 116 SECTION 7: Handling and storage 117

7.1 Precautions for safe handling : Keep away from heat and direct sunlight. 118 Thorough dedusting. 119

· Information about fire - and explosion protection : No special measures required. 120

7.2 Conditions for safe storage, including any incompatibilities : 121 · Storage : 122 · Requirements to be met by storerooms and receptacles : Store away from light and moisture. 123 No special requirements. 124 · Information about storage in one common storage facility : Not required. 125 · Further information about storage conditions : Store in cool, 126 dry conditions in well sealed receptacles. 127 · Recommended storage temperature : 2-8°C 128

7.3 Specific end use(s) : No further relevant information available. 129

130 SECTION 8: Exposure controls / personal protection 131 132 · Additional information about design of technical facilities : No further data; see section 7. 133

8.1 Control parameters 134 · Ingredients with limit values that require monitoring at the workplace : 135 The product does not contain any signifiant quantities of materials with critical values that have to be monitored at 136 the workplace. 137 · Additional information : 138 The most current valid lists have been used as a basis for the production of this document. 139

8.2 Exposure controls 140 · Personal protective equipment : 141 · General protective and hygienic measures : 142 The usual precautionary measures are to be adhered to when handling chemicals. 143 144

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

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Version 1.1

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Respiratory protection :

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Protection of hands :

Protective gloves. EN374 gloves for chemicals.

Gloves material : Butyl rubber, BR Eye protection :

Safety glasses.

Body protection :

Protective work clothing.

145 146 SECTION 9: Physical and chemical properties 147

9.1 Information on basic physical and chemical properties 148 · General Information 149 · Appearance : 150

Form : Powder 151 Colour : White to off-white 152

· Odour : Characteristic. 153 · Odour threshold : Not determined. 154 · pH-value : Not applicable. 155 · Change in condition 156

Melting point/Melting range : Undetermined. 157 Boiling point/Boiling range : Undetermined. 158

· Flash point : Not applicable. 159 · Flammability (solid, gaseous) : Not determined. 160 · Ignition temperature : Not applicable. 161 · Decomposition temperature : Not determined. 162 · Self-igniting : Product is not self igniting. 163 · Danger of explosion : Product does not present an explosion hazard. 164 · Explosion limits : 165

Lower : Not determined. 166 Upper : Not determined. 167

· Vapour pressure : Not applicable. 168 · Density at 20°C : 0.5 +/- 0.1 g/cm³ 169 · Relative density : Not determined. 170 · Vapour density : Not applicable. 171 · Evaporation rate : Not applicable. 172 · Solubility in / Miscibility with water : Fully soluble. 173 · Segregation coefficient (n-octanol/water) : Not determined. 174 · Viscosity : 175

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

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Dynamic : Not applicable. 176 Kinematic : Not applicable. 177

9.2 Other information : No further relevant information available. 178 179 180 SECTION 10: Stability and reactivity 181

10.1 Reactivity : No further relevant information available. 182

10.2 Chemical stability : 183 · Thermal decomposition / conditions to be avoided : 184

No decomposition if used according to specifications. 185

10.3 Possibility of hazardous reactions : No dangerous reactions known. 186

10.4 Conditions to avoid : No further relevant information available. 187

10.5 Incompatible materials : No further relevant information available. 188

10.6 Hazardous decomposition products : No dangerous decomposition products known. 189 190 191 SECTION 11: Toxicological information 192

11.1 Information on toxicological effects 193 · Acute toxicity : Based on available data, the classification criteria are not met. 194 · Primary irritant effect : 195 · On the skin : Based on available data, the classification criteria are not met. 196 · On the eyes : Based on available data, the classification criteria are not met. 197 · Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. 198 · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) : 199 · Germ cell mutagenicity : Based on available data, the classification criteria are not met. 200 · Reproductive toxicity : Based on available data, the classification criteria are not met. 201 · STOT-single exposure : Based on available data, the classification criteria are not met. 202 · STOT-repeated exposure : Based on available data, the classification criteria are not met. 203 · Aspiration hazard : Based on available data, the classification criteria are not met. 204 205 206 SECTION 12: Ecological information 207

12.1 Toxicity 208 · Aquatic toxicity : No further relevant information available. 209

12.2 Persistence and degradability : No further relevant information available. 210

12.3 Bioaccumulative potential : No further relevant information available. 211

12.4 Mobility in soil : No further relevant information available. 212 · Additional ecological information : 213 · General notes : Generally not hazardous for water. 214

12.5 Results of PBT and vPvB assessment 215 · PBT : Not applicable. 216 · vPvB : Not applicable. 217

12.6 Other adverse effects : No further relevant information available. 218 219 220

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

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Version 1.1

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SECTION 13: Disposal considerations 221

13.1 Waste treatment methods 222 · Recommendation : Must be specially treated according to official regulations.. 223 · Uncleaned packaging : 224 · Recommendation : Disposal must be made according to official regulations. 225 226 227 SECTION 14: Transport information 228

14.1 UN-Number 229 · ADR, ADN, IMDG, IATA : Void 230

14.2 UN proper shipping name 231 · ADR, ADN, IMDG, IATA : Void 232

14.3 Transport hazard class(es) 233 · ADR, ADN, IMDG, IATA 234 · Class : Void 235

14.4 Packing group 236 · ADR, IMDG, IATA : Void 237

14.5 Environmental hazards : Not applicable. 238

14.6 Special precautions for user : Not applicable. 239

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code : Not applicable. 240 · UN "Model Regulation": Void 241 242 243 SECTION 15: Regulatory information 244

15.1 Safety, health and environmental regulations/legislation specific for the mixture : 245 · Directive 2012/18/EU 246 · Named dangerous substances - ANNEX I : None of the ingredients is listed. 247

15.2 Chemical safety assessment : A Chemical Safety Assessment has not been carried out. 248 249 250 SECTION 16: Other information 251 252 This information is based on our present knowledge. However, this shall not constitute a guarantee for any 253 specific product features and shall not establish a legally valid contractual relationship. 254 255 · Relevant phrases : 256 H315: Causes skin irritation. 257 H317: May cause an allergic skin reaction. 258 H319: Causes serious eye irritation. 259 H335: May cause respiratory irritation. 260 · Abbreviations and acronyms : 261 ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement 262 concerning the International Carriage of Dangerous Goods by Road) 263 IMDG: International Maritime Code for Dangerous Goods 264 IATA: International Air Transport Association. 265 GHS: Globally Harmonised System of Classification and Labelling of Chemicals 266 EINECS: European Inventory of Existing Commercial Chemical Substances 267

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SAFETY DATA SHEET (according 1907/2006/CE, Art. 31)

CHROMagar™ mSuperCARBA™- S2 Ref : SC172(S2) / SC173(S2)

AD-ASQ-283

Version 1.1

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ELINCS: European List of Notified Chemical Substances 268 CAS: Chemical Abstracts Service (division of the American Chemical Society) 269 PBT: Persistent, Bioaccumulative and Toxic 270 SVHC: Substances of Very High Concern 271 vPvB: very Persistent and very Bioaccumulative 272 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 273 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 274 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 275 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 276 277 278