SAFETY DATA SHEET1209855 - PERMANENT MARKER 3PK Revision Date 11-Mar-201 5 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance

SAFETY DATA SHEET Issuing Date No data available Revision Date 11-Mar-2015 Revision Number 1

® The supplier identified below generated this SDS using the UL SDS template. UL did not lest, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from public ally available regulatory data sources. UL makes no representations or warranties regarding /he completeness or accuracy of the information in this SDS and disclaims a// liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of/his SDS is ©2014 UL LLC. All rights reserved.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier

Product Name PERMANENT MARKER 3PK

Other means of identification

Synonyms None

Recommended use of the chemical and restrictions on use

Recommended Use Markers

Uses advised against No information available

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 191 0.1200)

!specific target organ toxicity (repeated exposure) !category 2

GHS Label elements. including precautionary statements

Emergency Overview

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1209855 - PERMANENT MARKER 3PK Revision Date 11 -Mar-2015

Signal word Warning

Hazard Statements May cause damage to organs through prolonged or repeated exposure

Appearance Black

Precautionary Statements - Prevention

Physical State Solid containing liquid Solid

Do not breathe dust/fume/gas/mist/vapors/spray

Precautionary Statements - Response Get medical advice/attention if you feel unwell

Precautionary Statements -Storage None

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Unknown Toxicity 37% of the mixture consists of ingredient(s) of unknown toxicity

Other information

May be harmful if swallowed Toxic to aquatic life with long lasting effects

Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-% Ethanol 64-1 7-5 10-30 Glycerol 56-81-5 7 - 13 C. I. Solvent black 27 12237-22-8 7 - 13 (2-methoxymethylethoxy)propanol 34590-94-8 5- 10 Ethylene glycol 107-21-1 3-7 Diethylene glycol 111-46-6 3-7 . .

*The exact percentage (concentration) of compositiOn has been Withheld as a trade secret

Odor Odorless

Trade Secret . • . . . .

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1209855 - PERMANENT MARKER 3PK Revision Date 11-Mar-201 5

4. FIRST AID MEASURES

First aid measures

General Advice Show this safety data sheet to the doctor in attendance.

Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician.

Skin Contact Wash with soap and water.

Inhalation Remove to fresh air.

Ingestion Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person.

Most important symptoms and effects. both acute and delayed

Most Important Symptoms and No information available. Effects

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical No information available.

Hazardous Combustion Products Carbon oxides.

Explosion Data Sensitivity to Mechanical Impact No.

Sensitivity to Static Discharge No.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHAINIOSH (approved or equivalent) and full protective gear.

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1209855 - PERMANENT MARKER 3PK Revision Date 11 -Mar-201 5

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions

Other Information

Environmental Precautions

Environmenta l Precautions

Avoid contact with eyes. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas.

Refer to protective measures listed in Sections 7 and 8.

Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for Containment

Methods for cleaning up

Precautions for safe hand ling

Handling

Prevent further leakage or spillage if safe to do so.

Pick up and transfer to properly labeled containers.

7. HANDLING AND STORAGE

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes.

Conditions for safe storage, including any incompatibilities

Storage Keep container tightly closed.

Incompatible Products None known based on information supplied.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Ethanol STEL: 1 000 ppm TWA: 1000 ppm IDLH: 3300 ppm 10% LEL 64-17-5 TWA: 1900 mg/m3 TWA: 1 000 ppm

(vacated) TWA: 1 000 ppm TWA: 1900 mgfm3 (vacated) TWA: 1900 mg/m3

Glycerol TWA: 10 mg/m3 mist TWA: 15 mgfm3 mist, total 56-81-5 particulate

TWA: 5 mg/m3 mist, respirable fraction

(vacated) TWA: 10 mg/m3 mist, total particulate

(vacated) TWA: 5 mg/m3 mist, respirable fraction

C. I. Solvent black 27 - TWA: 0.5 mgfm3 Cr IDLH: 25 mgfm3 Cr{lll) 12237-22-8 (vacated) TWA: 0.5 mg/m3 Cr TWA: 0.5 mgfm3 Cr

® Page 4 / 11

1209855 · : RMANENT MARKER 3PK Revis ion Date 11-Mar-2015

(2-mc. ,,,xymethylethoxy)propanol STEL: 150 ppm TINA: 1 00 ppm IDLH: 600 ppm 34590-94-8 TINA: 100 ppm TINA: 600 mglm3 TINA: 1 00 ppm

s· (vacated) TWA: 100 ppm TINA: 600 mglm3

(vacated) TWA: 600 mglm3 STEL: 150 ppm (vacated) STEL: 150 ppm STEL: 900 mglm3

(vacated) STEL: 900 mglm3

(vacated) s· S*

Ethylene glycol Ceiling: 100 mglm3 aerosol only (vacated) Ceiling: 50 ppm 107-21-1 (vacated) Ceiling: 125 mglm3

-ACGIH TL \ r. 1\mencan Conference of Governmentallndustnal Hygtemsts- Threshold LtmJt Value OSHA PEL: Occupattonal Safety and Health Administt aii· m - Permissible Exposure Limits Immediately Dangerous to Life or Health

Other Ex,. JSure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters

Appropri ;·;:e engineering controls

Engineering Measures Showers Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection No special protective equipment required.

Skin and Body Protection No special protective equipment required.

Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties

Physical State Appearance Color

Property pH Melting I freezing point Boiling point I boiling range Flash Point Evaporation Rate Flammability (solid, gas) Flammability Limit in Air

Solid containing liquid, Solid Black No information available

Values No data available No data available No data available No data available No data available No data available

Upper flammability limit No data available Lower flammability limit No data available

Vapor pressure No data available Vapor density No data available Specific Gravity No data available Water Solubility Limited Solubility in other solvents No data available Partition coefficient: n-octanollwaterNo data available Autoignition temperature No data available

Odor Odor Threshold

Remarks Method None known None known None known None known None known None known

None known None known None known None known None known None known None known

Odorless No information available

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1209855 - PERMANENT MARKER 3PK

Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing Properties

Other Information

Softening Point VOC Content (%) Particle Size Particle Size Distribution

Reactivity

No data available.

Chemical stability

No data available No data available No data available No data available No data available

No data available No data available No data available

None known None known None known

10. STABILITY AND REACTIVITY

Stable under recommended storage conditions.

Possibility of Hazardous Reactions None under normal processing.

Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to avoid None known based on information supplied.

Incompatible materials None known based on information supplied.

Hazardous Decomposition Products Carbon oxides.

11 . TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation Specific test data for the substance or mixture is not available.

Eye Contact Specific test data for the substance or mixture is not available.

Skin Contact Specific test data for the substance or mixture is not available.

Ingestion Specific test data for the substance or mixture is not available.

Component Information

Chemical Name Oral LD50 Dermal LD50 Ethanol - -64-17-5

Revision Date 11 -Mar-2015

Inhalation LC50 = 124.7 mg/L (Rat) 4 h

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1209655 - PERMANENT MARKER 3PK Revis ion Date 11 -Mar-2015

Glycerol - > 1 0 g/kg ( Rabbi! ) > 570 mg/m3 ( Rat ) 1 h 56-81-5

(2-methoxymethylethoxy)propanol - 5230 mg/kg ( Rat ) - 9500 mg/kg ( Rabbit ) -34590-94-8

Ethylene glycol = 4000 mg/kg ( Rat ) - -107-21-1

Diethylene glycol = 12565 mg/kg ( Rat ) = 11890 mg/kg (Rabbit) -111-46-6

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Mutagenic Effects No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH I ARC NTP OSHA Ethanol A3 Group 1 Known X 64-17-5 C.l. Solvent black 27 Group 3 12237-22-8

ACGIH (Amencan Conference of Governmentallndustnal Hyg1emsts) A3 - Animal Carcinogen /ARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3- Not Classifiable as to Carcinogenicity in Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X- Present

Reproductive Toxicity

STOT - single exposure

STOT - repeated exposure

Chronic Toxicity

Target Organ Effects

Aspiration Hazard

No information available.


Causes damage to organs through prolonged or repeated exposure. Based on classification criteria from the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200), this product has been de.termined to cause systemic target organ toxicity from chronic or repeated exposure. (STOT RE).

Avoid repeated exposure. Prolonged exposure may cause chronic effects. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.

Blood. Central Nervous System (CNS). Eyes. Kidney. Liver. Reproductive System. Respiratory system. Skin. Heart.


Numerical measures of toxicity Product Information

The following values are calculated based on chapter 3.1 of the GHS document

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ATEmix (oral) 2,468.00 mg/kg ATEmix (dermal) 46,780.00 mg/kg (ATE) ATEmix (inhalation-dust/mist) 561.20 mg/1

12. ECOLOGICAL INFORMATION

Ecotoxicitv Toxic to aquatic life with long lasting effects.

Chemical Name Toxicity to Algae

Ethanol 64-17-5

Glycerol 56-81-5

(2-methoxymethylethoxy)pro panol

34590-94-8 Ethylene glycol 96h EC50: 6500- 13000

107-21-1 mg/L (Pseudokirchnerieila subcapitata)

Diethylene glycol 111-46-6

Persistence and Degradabi lity No information available.

Bioaccumulation

Chemical Name Ethanol 64-17-5 Glycerol 56-81-5

(2-methoxymethylethoxy)propanol

Other adverse effects No information available.

34590-94-8 Ethylene glycol

107-21-1 Diethylene glycol

111-46-6

Toxicity to Fish Toxicity to Microorganisms

96h LC50: > 100 mg/L EC50 = 34634 mg/L 30 min (Pimephales promelas) 96h EC50 = 35470 mg/L 5 min LC50: 13400- 15100 mg/L (Pimephales promelas) 96h

LC50: 12.0- 16.0 mUL (Oncorhynchus mykiss) 96h LC50: 51 - 57 ml/L (Oncorhynchus mykiss)

96h LC50: > 10000 mg/L (Pimephales promelas)

96h LC50: = 41000 mg/L EC50 = 10000 mg/L 16 h (Oncorhynchus mykiss) 96h EC50 = 620 mg/L 30 min

LC50: 14- 18 ml/L EC50 = 620.0 mg/L 30 min (Oncorhynchus mykiss) 96h

LC50: = 40761 mg/L (Oncorhynchus mykiss) 96h

LC50: = 27540 mg/L (Lepomis macrochirus) 96h

LC50: = 16000 mg/L (Poecilia reticulata) 96h

LC50: 40000 - 60000 mg/L (Pimephales promelas)

96h LC50: = 75200 mg/L EC50 = 29228 mg/L 15 min (Pimephales promelas)

Log Pow -0.32

-1.76

-0.064

-1.93

-1.98

Revis ion Date 11 -Mar-201 5

Daphnia Magna (Water Flea)

48h LCSO: 9268- 14221 mg/L 48h EC50: = 2 mg/L 24h EC50: = 10800 mg/L

24h EC50: > 500 mg/L

48h LC50: = 1919 mg/L

48h EC50: = 46300 mg/L

48h EC50: = 84000 mg/L

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1209855 - PERMANENT MARKER 3PK Revision Date 11-Mar-2015

Waste treatment methods

Disposal methods

Contaminated Packaging

13. DISPOSAL CONSI :RATIONS ------------------------------------~

This material, as supplied, is not ' '1azardous waste according to Federal regulations (40 CFR 261 ). This material could bee ·me a hazardous waste if it is mixed with or otherwise comes in contact with a hazardou '.Vaste, if chemical additions are made to this material, or if the material is processed or oth', wise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardou. waste. Consult the appropriate state, regional , or local regulations for additional requiren, "1ts.

Dispose of contents/containers in ~ccordance with local regulations.

California Hazardous Waste Codes 331

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Ethanol 64-17-5

C. I. Solvent black 27 12237-22-8

DOT Proper Shipping Name Hazard Class

lATA Proper Shipping Name Hazard Class

IMDG/IMO Hazard Class

International Inventories

TSCA DSL

14. TRANSPORT INF .... RMATION

NOT REGULATED NON REGULATED N/A

Not regulated

Not regulated

Not regulated

Not regulated NON REGULATED N/A

Not regulated N/A

Not regulated

Not regulated

Not regulated

15. REGULATORY INFORMATION

Complies All components are listed either on the DSL or NDSL.

Toxic Ignitable

Toxic Corrosive Ignitable

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1209855- PERMANENT MARKER 3PK

TSCA- United States Toxic Substances Control Act Section 8(b) Inventory DSLINDSL- Canadian Domestic Substances lisUNon-Domestic Substances List

US Federal Regulations

SARA 313

Revision Date 11-Mar-2015

Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name

C.l. Solvent black 27 - 12237-22-8 (2-methoxymethylethoxy)propanol - 34590-94-8 Ethylene glycol - 107-21-1 SARA 311/312 Hazard Categones

Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden release of pressure hazard Reactive Hazard

CWA (Clean Water Act)

CAS No

12237-22-8 34590-94-8 107-21-1

No Yes No No No

Weight-% SARA 313- Threshold Values %

7- 13 1.0 5- 10 1.0 3-7 1.0

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

Chemical Name CWA - Reportable CWA- Toxic Pollutants CWA - Priority Pollutants CWA- Hazardous Quantities Substances

C. I. Solvent black 27 X 12237-22-8

CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQ RQs

Ethylene glycol 5000 1b RQ 5000 lb final RQ 107-21-1 RQ 2270 kg final RQ

US State Regulattons

California Proposition 65 This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage.

Chemical Name California Proposition 65 Ethanol- 64-17-5 Carcinogen

Developmental U.S. State R1ght-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Ethanol X 64-17-5

C. I. Solvent black 27 X X X 12237-22-8

Glycerol X 56-81-5

(2-methoxymethylethoxy)propanol X X X X X 34590-94-8

Page 10/11


Ethylene glycol 107-21-1

International Regulations

Mexico N f I a 1ona f occupa 1ona exposure

X X X

r ·t 1m1 s ComJJonent Carcinogen Status

Ethanol 64-17-5 ( 10. 30)

Glycerol 56-81-5 ( 7- 13)

(2-methoxymethylethoxy)propanol 34590-94-8 ( 5 - 1 0 )

Ethylene glycol 107-21-1 ( 3-7)

Mextco - Occupaltonal Exposure Ltmtls - Carcmogens

Canada WHMIS Hazard Class Non-controlled

-

16. OTHER INFORMATION

NFPA Health Hazards 1 Flammability

HMIS Health Hazards 2 * Flammability

Chronic Hazard Star Legend * = Chronic Health Hazard

Prepared By

Revision Date Revision Note

Disclaimer

Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 11 -Mar-2015 No information available

1 Instability 0

0 Physical Hazard

Revis ion Date 11 -Mar-201 5

X X

Exposure Limits Mexico: TWA 1000 ppm

Mexico: TWA 1900 mgfm3 1 Omg/m3 (mist) TWA

Mexico: TWA 100 ppm Mexico: TWA 60 mgfm3 Mexico: STEL 150 ppm

Mexico: STEL 900 mgfm3 Mexico: Ceiling 100 mg/m3

Physical and Chemical Hazards -

0 Personal Protection X

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

Page 11/11

Page 117

Safety Data Sheet Printing date 24.04.2008 Revision: 24.04.2008

1 Jdent(fication ld the substance/preparation ami l~/' the compauy/uudertakiug

·Product details

· Trade name: Yellow lk-100 · Registration number Not available ·Application of the substance I the prepamtion FLUORESCENT MARKER INK

· Manufacturer/Supplier: DAE MYUNG CHEMICAL INDUSTRY (SHANGHAI) CO., LTD. N0.88, YU JIA XI ROAD, YONG FENG STREET, SONG JIANG AREA SHANGHAi CITY, CHINA TEL: 67728036 FAX: 67728037

·Further information obtainable from: DAE MYUNG CHEMICAL INDUSTRY (SHANGHAI) CO., LTD. · Information in case of emergency: Zhang hong ren MP: 13817890460

· Email: [email protected] ·Reference Number: SHD2810953; SH8050137/CHEM

2 Hazards identification

· Hazard description:

Xi Irritant

· Information conceming particular hazards forlmman and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version R 36/38 Irritating to eyes and skin.

· Classification system: The classification is according to the latest editions of the EU-Iists, and extended by company and literature data.

3 Composition/information 011 ingredients

· Chemical characterization · Description:

Mixture of substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section I 6.

· Dangerous components:

CAS: 56-81-5 glycerol EINECS: 200-289-5

CAS: 107-21-1 ethanediol EINECS: 203-473-3 EU Number: 603-027-00-1

CAS: 102-71-6 2,2 ', 2 "-nitrilotriethmwl EINECS: 203-049-8

· Non-dangerous component:

CAS: 9003-54-7 Styrene-acl)•lollitrile copolymer

CAS: 7732-18-5 water, distilled, conductivity or of similar purity EINECS: 231-791-2

!Ki Xi; R 36/38 20,0%

IB] Xn; R 22 0,8%

IB] Xi; R 36/38 0,2%

40,0%

36,4%

CAS: 35869-60-4 2 -[7 -( d i ethyl amino )-2 -ox o-2 H - 1-benzopyran-3-y l 7-1,3 -dime / hyl -1 H- 1,5% EINECS: 252-770-4 benzimidazolium methyl sulphate

CAS: 2854-09-3 Polyoxyethylene( JO)nonylphenyl ether 0,8%

CAS: 57-55-6 propane-1,2-diol 0,3% EINECS: 200-338-0

(Contd. on page 2)

L------------------------------------------------------------------------------- EU

Printing date 24.0 . '008

Trade name: Yell ·fk-100

· Remark: glycerol (CAS t"o. 56-81-5) Synonym: glyc"Tine

etltanedio/ (Ct' :; No. 107-21-1) Synonym: elhy',·ne glycol

Safety Data Sheet

2,2',2"-nitrilolriethano/ (CAS No. 102-71-6) Synonym: TEA

Polyoxyethylene( 10)nonylpllenyl ether (CAS No. 2854-09-3) Synonym: NP-10

Revision: 24.04.2008

(Contd. of page I)

2-{7-( diethylamino )-2-oxo-2H-l-benzopyran-3-yl]-1,3-dimethyl-l H-benzimidazolium methyl sulphate (CAS No. 35869-60-4) Synonym: C. f. Basic yellow 40

4 First aid 1iE£tres

·After inhalation: In case of uncomciousness place patient stably in side position for transportation. ·After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under mnning water. If symptoms persist, consult a doctor.

·After swallowing: If symptoms persist consult doctor.

5 Fire-figllti1Jif!.wasures

·Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. ·Protective equipment: Wearfully protective suit.

6 Accideutal:rf!...ease measures

· Person-related safety precautions: Ensure adequa/e vemillllion Wear protective clothing.

·Measures for environmental protection: Do 1101 allow to e/1/er sewers/ swface or ground water. · Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, univerml binders, sawdust). Ensure adequate ventilation.

7 Hmulling ami storage

· Hmufling: · Information for safe handling:

Emure good ventilation/exhaustion at the workplace. Prevent formatioll of aerosols.

· Information about fil:e- and explosion protection: Keep respirat01y protective device available.

·Storage: · Requirements to be met by storerooms and receptacles: Store in a coo/location. Store only in the original receptacle.

· Information about storage in one commo11 slomge facility: Store away from foodstuffs. Store away from reducing agents.

(Contd. on page 3)

L----------------------------------------------------------------------------------------EU

Safety Data Sheet Printing date 24.04.2008

Trade name: Yellow lk-100

· Fur/Iter information about storage conditions: Keep container tightly sealed.

8 Exposure coutrols/persoual protection

·Additional information about design of technical facilities: No fiu1her data; see item 7. · Ingredients with limit values that require monitoring at t!te workplace:

56-81-5 glycerol

WEL (Great Britain) PEL(USA)

TLV (USA)

107-21-1 ethanediol

JOELV (EU)

10 mg/m3

15* 5** mg/m3

*total dust **respirable fraction 10 ppm

Short-term value: 104 mg/m3, 40 ppm Long-term value: 52 mg/m3, 20 ppm Skin

WEL (Great Britain) Short-term value: 104** mg/m3, 40** ppm Long-term value: 10* 52** mg/m3, 20** ppm Sk *particulate **vapour

TLV (USA) Short-term value: C 100 mg/m3

H

102-71-6 2,2 ',2 ''-nih"ilotriethmwl

TLV (USA) 5 mg/mJ

57-55-6 propane-1,2-diol

WEL (Great Britain) 474* 10** mg/m3, 150* ppm *total vapour and particulates **particulates

WEEL (USA) 10 mg!m3

· DNELs Not available · PNECs Not available ·Additional information: The lists valid during the making were used as basis.

· Personal protective equipment: · General protective and hygienic measures:

Keep away j i"OJn foods tuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. A void contact with the eyes and skin.

· Respirat01y protection:

Page 317


(Contd. of page 2)

In case of brief exposure or low pollution use respiratOI)' filter device. In case of intensive or longer exposure use self-contained respiratOI)' protective device.

· Protection of hands:

0 Prot.cti" glo"'

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Material of gloves The selection of tlze suitable gloves does not only depend on the material, but also 011 fi trther marks of quality and varies from manufaclllrer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

· Penetration time of glove material The exact break trough time has to be foulld out by the mwuifacturer of the protective gloves and has to be obsen1ed.

(Contd. on page 4) EU

Saf ety Data Sheet Prillfing date 24.04.2008

1i·ade name: Yellow /k-100

· Eye protection:

- Tightly ua/" 1 goggle<

9 Physical am/ chemical properties

· Geueral/uformatiou

Form: Colour: Odour:

· Change in condition Melting point/Melting range: Boiling point/Boiling range:

· Flash point:

· Flammability (solid, gaseous):

· Ignition tempemture:

· Self-igniting:

Liquid Yellow Odourless

Not available Not available

Not available

Not available

Not available

Product is not selfigniting.

Page 417


(Com d. of page 3)

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits: Lower: Upper:

· Oxidizing properties

· Vapourpressure:

· Density: · Relative density · Vapour density · Evaporation rate

· Solubility in I Miscibility with water:

·pH-value:

Not available Not available Not available

Not available

Not available Not available Not available Not available

Not available

Not available

· Segregation coefficient (u-octauollwater): Not available

· Viscosity: Dynamic: Not available

I 0 Stability and reactivity

· Thermal decomposition I conditions to be avoided: No decomposition if used according to specifications. · Dangerous reactions No dangerous reactions known. · Dangerous decomposition products: No dangerous decomposition products known.

11 Toxicological information

· Acute toxicity:

· WILCSO values relevant for classification:

107-21-1 etfwnediol

Oral (Conld. on page 5)

~----------------------------------------------------------------------------------~u

Printing date 24.04.2008


Oral LD50 5846mglkg (mouse)

8000 mglkg (rat)

2200 mg/kg (rabbit)

56-81-5 glycerol

· Primmy irritant effect:

Saf ety Data Sheet

· on the skin: Irritant to skin and 1nucom membranes. · on the eye: Irritating effect. · Sensitization: Sensitization possible. · Additional toxicological information:

Page 517


(Coord. of a e 4)

The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant

· Toxicokinetics, metabolism and tlish"ibution Not available · Acute effects (acute toxicity, irritation and corrosivity) Not available ·Repeated dose toxicity Not available · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Not available

12 Ecological information

·Information about elimination (persistence and degradability): Not available · Behaviour in euvironmental.1ystems: · Mobility and bioaccumulation potential: Not available · Ecotoxical effects: · Acquatic toxicity: Not available · General notes:

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiLuted product or large quantities of it to reach ground water, water course or sewage system.

· PBT assessments Not available

13 Disposal considerations

· Product: · Recommendation

Must not be disposed together with household garbage. Do 110t allow product to reach sewage system.

· Uncleaned packaging: · Recommendation: Disposal1mtst be made according to official regulations.

14 Transport information

·Land transport ADRIRID (cross-border) · ADRIRID class:

(Contd. on page 6) L----------------------------------------------------------------------------------- EU

Printing dale 24.04.2008

Trade name: Yellow /k-100

· Danger code (Kemler): -· UN-Number: · Hazard label: · Description of goods: · Limited quantities (LQ) -· Transport categ01y · Tunnel restriction code -

· Maritime tramport IMDG: · IMDG Class: · UN Number: ·Label · Packaging group: · EMS Number: · Marine pollutant: Yes · Proper shipping name: -

Safety Data Sheet

·Air transport TCAO-Tl and TATA-DGR: · l CAO/lATA Class: · UNITD Number: ·Label · Packaging group: · Proper shipping name: -

IS RegulalmJ• information •

·Sara

·Section 35S(extremely hazardous substances):

None of the ingredients is listed.

· TSCA(Toxic Substances Control Act):

7732-18-5 water, distilled, conductivity or of similar purity

56-81-5 glycerol

107-21-1 ethanediol

57-55-6 propane-1,2-diol

102-71-6 2,2',2"-nitrilotrietllanol

· Proposition 65

· Chemicals known to cause cancer:


· Chemicals known to cause reproductive toxicity f or females:


· Chemicals known to cause reproductive toxicity for males:


· Chemicals known to cause developmental toxicity:

None of tire ingredients is listed.

· Cancerogenity categories

· EPA(Euviroumeutal Protection Agency)


· TARC(lntemational Agency for Research on Cance1)

9003-54-7 Styrene-aClylonitrile copolymer

102-71 -6 2,2',2"-nitrilotriet/ranol

Page 617


(Contd. of page 5)

3

3 (Contd. on page 7)

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Page 717

Safety Data Sheet Printing date 24.04.2008 Re11ision: 24.04.2008


(Contd. of page 6)

· NTP(Nationnl Toxicology Program)


· TLV(Thres/wld Limit Value established by ACGIH)

· NIOSH-Ca(Nationallnstitutefor Occupational Safety am/ Health)

None of the ingrediellls is listed.

· OSHA-Ca(Occupational Safety & Health Administration)


· Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives I Ordinance 011 Hazardous Materials.

· Code letter and hazard designation of product: Xi Irritant

· Risk phmses: 36/38 Irritating to eyes and skin.

· Safety phrases: 2 Keep out of the reach of children. 23 Do not breathe gas/fwnes/vapoud.IJHay (appropriate wording to be specified by the IIU/111/facturer). 46/f.nva//owed, seek medical advice immediately and show this container or label. 56 Dispose of this material and its container to hazardous or special waste collection point.

/6 Other iuformatiou

· Relevant R-phrases 22 Harmful if swallowed. 36/38 Irritating to eyes and skin.

The contellfs and format of this MSDSISDS are in accordance with REGULATION (EC) No 1907/2006, EU Commission Directive I999/45/EC, 671548/EEC.

DISCLAIMER OF LIABILITY The info rmation in this MSDS/SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, stomge, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility all(( expressly disclaim liability for loss, damage or e,\pense arising ollf of or in any way connected with the handling, storage, use or disposal of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as a component in £mother product, this MSDSISDS information may not be applicable.

End of document L---------------------------------------------------------------------------------------- EU

Documents

SAFETY DATA SHEET1209855 - PERMANENT MARKER 3PK Revision Date 11-Mar-201 5 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance