SAFETY DATA SHEETsds.staples.com/msds/2056102.pdf4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse

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2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Specific target organ toxicity (single exposure) Category 3

GHS Label elements, including precautionary statements

Emergency Overview_____________________________________________________________________________________________

Recommended use of the chemical and restrictions on use

Recommended Use Pens

Uses advised against No information available

Details of the supplier of the safety data sheet

Supplier Name Wenzhou Aihao Pen Trade Co., Ltd

Supplier Address No.128, Wenchang Road, Longwan ZoneWenzhouZhejiang325011CN

Supplier Phone Number Phone:86-13524536325Contact Phone86-021-68622126

Supplier Email [email protected]

Emergency telephone number

The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, andall information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representationsor warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this informationor the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.

SAFETY DATA SHEETRevision Date 11-May-2015 Revision Number 2Issuing Date No data available

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKING

Product identifier

Product Name dry erase marker black ink

Other means of identification

Synonyms None

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Precautionary Statements - PreventionAvoid breathing dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated area

Precautionary Statements - Response

InhalationIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingCall a POISON CENTER or doctor/physician if you feel unwell

Precautionary Statements - StorageStore in a well-ventilated place. Keep container tightly closedStore locked up

Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Unknown Toxicity18.7% of the mixture consists of ingredient(s) of unknown toxicity

Other information

Toxic to aquatic life

Interactions with Other ChemicalsUse of alcoholic beverages may enhance toxic effects.

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Revision Date 11-May-2015

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Hazard StatementsMay cause drowsiness or dizziness

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Signal word Warning

Appearance Black Physical state Solid containing liquid Odor Alcohol

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4. FIRST AID MEASURES

First aid measures

General Advice Show this safety data sheet to the doctor in attendance.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist,call a physician.

Skin contact Wash with soap and water.

Inhalation Remove to fresh air.

Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water.Never give anything by mouth to an unconscious person. Call a physician.

Most important symptoms and effects, both acute and delayed

Most Important Symptoms andEffects

Inhalation of high vapor concentrations may cause symptoms like headache,dizziness, tiredness, nausea and vomiting.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

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3. COMPOSITION/INFORMATION ON INGREDIENTS

.

Chemical Name CAS No Weight-% Trade SecretThird Party Formulation (TP # 1114535) Proprietary 40 - 70 *Third Party Formulation (TP # 1114535) Proprietary 10 - 30 *Third Party Formulation (TP # 1114535) Proprietary 1 - 5 *

*The exact percentage (concentration) of composition has been withheld as a trade secret

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Hazardous Combustion ProductsCarbon oxides.

Explosion Data Sensitivity to Mechanical Impact No.

Sensitivity to Static Discharge No.

Protective equipment and precautions for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with eyes. Ensure adequate ventilation. Use personal protective equipmentas required.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental precautions Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing mediaCAUTION: Use of water spray when fighting fire may be inefficient.

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Specific hazards arising from the chemicalNo information available.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHThird Party Formulation (TP # 1114535) STEL: 1000 ppm TWA: 1000 ppm

TWA: 1900 mg/m3

(vacated) TWA: 1000 ppm(vacated) TWA: 1900 mg/m3

IDLH: 3300 ppm 10% LELTWA: 1000 ppm

TWA: 1900 mg/m3

Third Party Formulation (TP # 1114535) STEL: 100 ppmTWA: 50 ppm


(vacated) STEL: 150 ppm(vacated) STEL: 540 mg/m3

TWA: 100 ppmTWA: 360 mg/m3

STEL: 150 ppmSTEL: 540 mg/m3

Third Party Formulation (TP # 1114535) TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3

(vacated) TWA: 3.5 mg/m3

IDLH: 1750 mg/m3

TWA: 3.5 mg/m3

TWA: 0.1 mg/m3 Carbon black inpresence of Polycyclic aromatic

hydrocarbons PAHACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and HealthAdministration - Permissible Exposure Limits Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962(11th Cir., 1992) See section 15 for national exposure control parameters

Appropriate engineering controls

Engineering Measures ShowersEyewash stationsVentilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection No special protective equipment required.

Skin and body protection No special protective equipment required.

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits areexceeded or irritation is experienced, ventilation and evacuation may be required.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or

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Incompatible Products None known based on information supplied.


7. HANDLING AND STORAGE

Precautions for safe handling

Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact withskin, eyes or clothing. Do not eat, drink or smoke when using this product. Take offcontaminated clothing and wash before reuse.

Conditions for safe storage, including any incompatibilities

Storage

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Keep container tightly closed.

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smoke when using this product. Wash hands before breaks and immediately after handlingthe product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties

Physical state Solid containing liquid

Explosive properties No data availableOxidizing properties No data available

Other Information

Softening Point No data availableVOC Content (%) No data availableParticle Size No data availableParticle Size Distribution

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Vapor pressure No data available

None known

None known

Color

Vapor density No data available

Melting / freezing point

None known

No data available

Specific Gravity No data available

No information available

None known

None known

Water Solubility Difficult solubility None knownSolubility in other solvents No data available

Boiling point / boiling range No data available

None knownPartition coefficient: n-octanol/waterNo data available

Odor Threshold

None known

None known

Autoignition temperature No data available


None known

Flash Point

Decomposition temperature No data available

No data available

None known

Appearance

Kinematic viscosity No data available

None known

None known

Black

Dynamic viscosity No data available None known

Evaporation Rate No data available


None known

Property

Flammability (solid, gas) No data available

Values

None known

Odor

Flammability Limit in Air

Remarks Method

Alcohol

Upper flammability limit No data available

pH No data available

Lower flammability limit

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No data available

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11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information .

Inhalation Specific test data for the substance or mixture is not available. May cause drowsiness anddizziness.

Eye contact Specific test data for the substance or mixture is not available.

Skin contact Specific test data for the substance or mixture is not available.

Ingestion Specific test data for the substance or mixture is not available.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Third Party Formulation (TP #1114535)

- - = 124.7 mg/L ( Rat ) 4 h

Third Party Formulation (TP #1114535)

= 5200 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) = 54.6 mg/L ( Rat ) 4 h> 24 mg/L ( Rat ) 1 h


> 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit ) -

Information on toxicological effects

Symptoms Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,tiredness, nausea and vomiting.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

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10. STABILITY AND REACTIVITY

Reactivity

Chemical stabilityStable under recommended storage conditions.Possibility of Hazardous ReactionsNone under normal processing.Hazardous PolymerizationHazardous polymerization does not occur.

Conditions to avoidNone known based on information supplied.Incompatible materialsNone known based on information supplied.

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Hazardous Decomposition ProductsCarbon oxides.


No data available.

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Mutagenic Effects No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.The listed substance(s) has been shown to be carcinogenic in long-term studies only whenconsumed orally. This is not a relevant route of exposure for this product.

Chemical Name ACGIH IARC NTP OSHAThird Party Formulation (TP# 1114535)

A3 Group 1 Known X

Third Party Formulation (TP# 1114535)

A3 Group 2B X

ACGIH (American Conference of Governmental Industrial Hygienists)A3 - Animal CarcinogenIARC (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to HumansNTP (National Toxicology Program)Known - Known CarcinogenOSHA (Occupational Safety and Health Administration of the US Department of Labor)X - Present

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Chronic Toxicity May cause adverse effects on the bone marrow and blood-forming system. May causeadverse liver effects. The listed substance(s) has been shown to be carcinogenic and toxicto reproduction in long-term studies only when consumed orally. This is not a relevant routeof exposure for this product.

Target Organ Effects Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Blood. Central Nervous System(CNS). Liver. Lymphatic System. Reproductive System. Lungs.

Aspiration Hazard No information available.

Numerical measures of toxicity Product Information

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral)20,131.00 mg/kgATEmix (dermal)50,329.00 mg/kgATEmix (inhalation-dust/mist)93.00 mg/l

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Daphnia Magna (WaterFlea)


96h LC50: > 100 mg/L(Pimephales promelas) 96hLC50: 13400 - 15100 mg/L(Pimephales promelas) 96h

LC50: 12.0 - 16.0 mL/L(Oncorhynchus mykiss)

EC50 = 34634 mg/L 30 minEC50 = 35470 mg/L 5 min

48h LC50: 9268 - 14221mg/L 48h EC50: = 2 mg/L24h EC50: = 10800 mg/L


96h LC50: = 20.8 g/L(Pimephales promelas) 96hLC50: 4600 - 10000 mg/L

(Leuciscus idus)

48h EC50: = 23300 mg/L


24h EC50: > 5600 mg/L

Persistence and DegradabilityNo information available.

Bioaccumulation

Chemical Name Log PowThird Party Formulation (TP # 1114535) -0.32

Third Party Formulation (TP # 1114535) -0.437

Other adverse effectsNo information available.


13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40CFR 261). This material could become a hazardous waste if it is mixed with or otherwisecomes in contact with a hazardous waste, if chemical additions are made to this material, orif the material is processed or otherwise altered. Consult 40 CFR 261 to determine whetherthe altered material is a hazardous waste. Consult the appropriate state, regional, or localregulations for additional requirements.

Contaminated Packaging Dispose of contents/containers in accordance with local regulations.

California Hazardous Waste Codes 331

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous WasteThird Party Formulation (TP # 1114535) Toxic

Ignitable

12. ECOLOGICAL INFORMATION

Ecotoxicity Toxic to aquatic organisms.

Chemical Name

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Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms

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14. TRANSPORT INFORMATION

DOT NOT REGULATEDProper Shipping Name NON REGULATEDHazard Class N/A

TDG Not regulated

MEX Not regulated

ICAO Not regulated

IATA Not regulatedProper Shipping Name NON REGULATEDHazard Class N/A

IMDG/IMO Not regulatedHazard Class N/A

RID Not regulated

ADR Not regulated

ADN Not regulated

15. REGULATORY INFORMATIONInternational Inventories

TSCA CompliesDSL All components are listed either on the DSL or NDSL.

TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

US Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard YesChronic Health Hazard NoFire Hazard NoSudden release of pressure hazard NoReactive Hazard No

CWA (Clean Water Act)This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material

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US State Regulations

California Proposition 65This product contains the following Proposition 65 chemicals.

Chemical Name California Proposition 65Third Party Formulation (TP # 1114535) - Carcinogen

DevelopmentalThird Party Formulation (TP # 1114535) - Carcinogen

U.S. State Right-to-Know Regulations

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Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island IllinoisThird Party Formulation (TP # 1114535) X

Third Party Formulation (TP # 1114535) X X X

Third Party Formulation (TP # 1114535) X X X X

International Regulations

MexicoNational occupational exposure limits

Component Carcinogen Status Exposure LimitsThird Party Formulation (TP # 1114535)

( 40 - 70 )Mexico: TWA 1000 ppm

Mexico: TWA 1900 mg/m3

Third Party Formulation (TP # 1114535) ( 1 - 5 )

Mexico: TWA 3.5 mg/m3

Mexico: STEL 7 mg/m3

Mexico - Occupational Exposure Limits - Carcinogens

CanadaWHMIS Hazard ClassNot determined

16. OTHER INFORMATION

Prepared By Product Stewardship23 British American Blvd.Latham, NY 121101-800-572-6501

Revision Date 11-May-2015Revision Note No information available

DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief atthe date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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Physical andChemical Hazards -


HMIS

NFPA

Health Hazards 2 Flammability 0 Physical Hazard 0 Personal ProtectionX

Health Hazards 1 Flammability 0


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Instability 0

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Classification

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).


Emergency Overview

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Product identifier

Product Name dry erase marker red ink


Synonyms None

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Precautionary Statements - PreventionObtain special instructions before use

Precautionary Statements - ResponseNone

Precautionary Statements - StorageNone

Precautionary Statements - DisposalNone


Not applicable

Unknown Toxicity100% of the mixture consists of ingredient(s) of unknown toxicity

Other information

May cause slight eye irritation

Interactions with Other ChemicalsNo information available.


First aid measures

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist,call a physician.



Ingestion Rinse mouth immediately and drink plenty of water. Never give anything by mouthto an unconscious person.


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The product contains no substances which at their given concentration, are considered to be hazardous to health.


*The exact percentage (concentration) of composition has been withheld as a trade secret

Revision Date 13-May-20151242305 - dry erase marker red ink

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Physical state SolidAppearance / Odor Alcohol

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No information available.



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Personal precautions Avoid contact with eyes.









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Control parameters

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies







Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.



Physical state Solid

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Property Values


Remarks Method pH No data available None known

Handling

Melting / freezing point No data available

Handle in accordance with good industrial hygiene and safety practice. Avoid contact witheyes.

None knownBoiling point / boiling range No data available None known


Flash Point 13 C / 55 F None knownEvaporation Rate No data available

Storage Keep container tightly closed.

None knownFlammability (solid, gas) No data available None known

Incompatible Products


None known based on information supplied.



Appearance / Odor Alcohol

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Color No information available

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Odor Threshold No information available

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Other Information




Product Information Specific test data for the substance or mixture is not available.

Inhalation Specific test data for the substance or mixture is not available.





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Reactivity


Conditions to avoidNone known based on information supplied.Incompatible materialsNone known based on information supplied.Hazardous Decomposition ProductsCarbon oxides.

None known

None known

Autoignition temperature No data available None known

Vapor density


No data available

None known

Lower flammability limit No data available


None known

None knownDynamic viscosity No data available


None known

Specific Gravity No data available None knownWater Solubility Difficult solubility None knownSolubility in other solvents No data available


None known


Partition coefficient: n-octanol/water

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No data available

No data available.

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Symptoms No information available.




Carcinogenicity Contains no ingredient listed as a carcinogen.




Chronic Toxicity No known effect based on information supplied.

Target Organ Effects None known.



The following values are calculated based on chapter 3.1 of the GHS documentNot applicable

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BioaccumulationNo information available




Ecotoxicity The environmental impact of this product has not been fully investigated.

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TDG Not regulated

MEX Not regulated

ICAO Not regulated



RID Not regulated

ADR Not regulated

ADN Not regulated





SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any_____________________________________________________________________________________________






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chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard NoChronic Health Hazard NoFire Hazard NoSudden release of pressure hazard NoReactive Hazard No




California Proposition 65This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

This product does not contain any substances regulated by state right-to-know regulations.








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HMIS

NFPA


Health Hazards 1


Flammability 1

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Instability 0

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Classification


Serious eye damage/eye irritation Category 2Specific target organ toxicity (single exposure) Category 3


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Product identifier

Product Name dry erase marker blue ink


Synonyms None

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Emergency Overview

Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handlingWear protective gloves/protective clothing/eye protection/face protectionAvoid breathing dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated areaWear eye/face protection


EyesIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attention





Not applicable

Unknown Toxicity12.6% of the mixture consists of ingredient(s) of unknown toxicity

Other information

Toxic to aquatic lifePROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION


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Warning

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Hazard StatementsCauses serious eye irritationMay cause drowsiness or dizziness

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Signal word

Odor AlcoholAppearance / Physical state Solid containing liquid

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First aid measures


Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Keep eye wide open while rinsing. Do not rub affected area. Get medical attentionif irritation develops and persists.



Ingestion Rinse mouth immediately and drink plenty of water. Never give anything by mouthto an unconscious person. Do NOT induce vomiting. Call a physician.



Burning sensation. Inhalation of high vapor concentrations may cause symptomslike headache, dizziness, tiredness, nausea and vomiting.



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Third Party Formulation (TP # 1114526) Proprietary 1 - 5 **The exact percentage (concentration) of composition has been withheld as a trade secret

1242308 - dry erase marker blue ink Revision Date 13-May-2015


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Chemical Name CAS No Weight-% Trade SecretThird Party Formulation (TP # 1114526) Proprietary 30 - 60 *Third Party Formulation (TP # 1114526) Proprietary 10 - 30 *Third Party Formulation (TP # 1114526) Proprietary

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7 - 13 *

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Uniform Fire Code Irritant: Solid





Revision Date 13-May-20151242308 - dry erase marker blue ink



Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.










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Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLHThird Party Formulation (TP # 1114526) STEL: 1000 ppm TWA: 1000 ppm

TWA: 1900 mg/m3



TWA: 1900 mg/m3










IDLH: 2000 ppm 10% LELTWA: 980 mg/m3

TWA: 400 ppmSTEL: 500 ppm

STEL: 1225 mg/m3

Third Party Formulation (TP # 1114526) TWA: 1 mg/m3 Cu dust and mist - IDLH: 100 mg/m3 Cu dust andmist

TWA: 1 mg/m3 Cu dust and mistACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and HealthAdministration - Permissible Exposure Limits Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962(11th Cir., 1992) See section 15 for national exposure control parameters




Eye/face protection None required for consumer use. If there is a risk of contact:. Wear safety glasses with sideshields (or goggles).

Skin and body protection None required for consumer use. Wear protective gloves and protective clothing.

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Storage Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Products Strong oxidizing agents. Acids. Chlorinated compounds.




Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact withskin, eyes or clothing. Do not eat, drink or smoke when using this product.


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Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact withskin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink orsmoke when using this product.



Physical state Solid containing liquid


Other Information


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None known

None known

Color



None known

No data available


Blue

None known

None known

Water Solubility Difficult solubility None knownSolubility in other solvents No data available



Odor Threshold

None known

None known



None known

Flash Point


No data available

None known

Appearance


None known

None known

/


Evaporation Rate No data available


None known

Property


Values

None known

Odor


Remarks Method

Alcohol



Lower flammability limit

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No data available

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Inhalation Specific test data for the substance or mixture is not available. May cause irritation ofrespiratory tract. May cause drowsiness and dizziness.

Eye contact Specific test data for the substance or mixture is not available. Expected to be an irritantbased on components. May cause redness, itching, and pain. May cause temporary eyeirritation.

Skin contact Specific test data for the substance or mixture is not available. May cause irritation.Prolonged contact may cause redness and irritation.

Ingestion Specific test data for the substance or mixture is not available. Ingestion may causeirritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,vomiting and diarrhea.


Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Third Party Formulation (TP #1114526)

- - = 124.7 mg/L ( Rat ) 4 h


= 5200 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) = 54.6 mg/L ( Rat ) 4 h> 24 mg/L ( Rat ) 1 h


= 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rabbit ) = 16000 ppm ( Rat ) 8 h


Symptoms May cause redness and tearing of the eyes. Inhalation of high vapor concentrations maycause symptoms like headache, dizziness, tiredness, nausea and vomiting.

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Conditions to avoidNone known based on information supplied.Incompatible materialsStrong oxidizing agents. Acids. Chlorinated compounds.Hazardous Decomposition ProductsCarbon oxides.



Reactivity


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No data available.

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Chemical Name ACGIH IARC NTP OSHAThird Party Formulation (TP# 1114526)

A3 Group 1 Known X


Group 3 X

ACGIH (American Conference of Governmental Industrial Hygienists)A3 - Animal CarcinogenIARC (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 3 - Not Classifiable as to Carcinogenicity in HumansNTP (National Toxicology Program)Known - Known CarcinogenOSHA (Occupational Safety and Health Administration of the US Department of Labor)X - Present




Chronic Toxicity May cause adverse effects on the bone marrow and blood-forming system. May causeadverse liver effects. The listed substance(s) has been shown to be carcinogenic and toxicto reproduction in long-term studies only when consumed orally. This is not a relevant routeof exposure for this product.

Target Organ Effects Eyes. Blood. Central Nervous System (CNS). Kidney. Liver. Reproductive System.Respiratory system. Skin. Spleen. Systemic Toxicity.




ATEmix (oral)13,767.00 mg/kgATEmix (dermal)36,450.00 mg/kg (ATE)ATEmix (inhalation-dust/mist)110.40 mg/lATEmix (inhalation-vapor)441.85 ATEmix

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Chemical Name Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms









(Leuciscus idus)

48h EC50: = 23300 mg/L


96h EC50: > 1000 mg/L(Desmodesmus

subspicatus) 72h EC50: >1000 mg/L (Desmodesmus

subspicatus)

96h LC50: > 1400000 µg/L(Lepomis macrochirus) 96h

LC50: = 11130 mg/L(Pimephales promelas) 96h

LC50: = 9640 mg/L(Pimephales promelas)

48h EC50: = 13299 mg/L


48h LC50: > 100 mg/L(Oryzias latipes)


Bioaccumulation

Chemical Name Log PowThird Party Formulation (TP # 1114526) -0.32


Third Party Formulation (TP # 1114526) 0.05






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TDG Not regulated

MEX Not regulated

ICAO Not regulated



RID Not regulated

ADR Not regulated

ADN Not regulated



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Chemical Name California Hazardous WasteThird Party Formulation (TP # 1114526) Toxic

IgnitableThird Party Formulation (TP # 1114526) Toxic



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SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name CAS No Weight-% SARA 313 - ThresholdValues %

Third Party Formulation (TP # 1114526) - 7 - 13 1.0



CWA (Clean Water Act)This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42)

Chemical Name CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances


X



California Proposition 65This product contains the following Proposition 65 chemicals.

Chemical Name California Proposition 65Third Party Formulation (TP # 1114526) - Carcinogen

DevelopmentalU.S. State Right-to-Know Regulations

.

Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island IllinoisThird Party Formulation (TP # 1114526) X



Third Party Formulation (TP # 1114526) X X


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( 30 - 60 )Mexico: TWA 1000 ppm



Mexico: TWA 400 ppmMexico: TWA 980 mg/m3

Mexico: STEL 500 ppmMexico: STEL 1225 mg/m3








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HMIS

NFPA


Health Hazards 2


Flammability 0

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Instability 0


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Classification


Specific target organ toxicity (single exposure) Category 3


Emergency Overview_____________________________________________________________________________________________











SAFETY DATA SHEETRevision Date 13-May-2015 Revision Number 2Issuing Date 18-Jan-2016


Product identifier

Product Name dry erase marker green ink


Synonyms None

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Precautionary Statements - PreventionAvoid breathing dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated area






Not applicable

Unknown Toxicity13 % of the mixture consists of ingredient(s) of unknown toxicity

Other information

Toxic to aquatic lifePROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION


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.

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Hazard StatementsMay cause drowsiness or dizziness

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Signal word Warning

Appearance / Physical state Solid Odor Alcohol

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First aid measures


Eye contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call aphysician.



Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never giveanything by mouth to an unconscious person. Call a physician.



Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,tiredness, nausea and vomiting.



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1 - 5 **The exact percentage (concentration) of composition has been withheld as a trade secret

Revision Date 13-May-20151242311 - dry erase marker green ink


.

Chemical name CAS No Weight-% Trade SecretThird Party Formulation (TP # 1303905)





Explosion Data Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.


Trade Secret 30 - 60 *Third Party Formulation (TP # 1303905) Trade Secret 10 - 30 *Third Party Formulation (TP # 1303905) Trade Secret 5 - 10 *

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Third Party Formulation (TP # 1303905) Trade Secret

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Control parameters

Exposure Guidelines

Chemical name ACGIH TLV OSHA PEL NIOSH IDLHThird Party Formulation (TP # 1303905) STEL: 1000 ppm TWA: 1000 ppm

TWA: 1900 mg/m3



TWA: 1900 mg/m3










IDLH: 2000 ppm 10% LELTWA: 980 mg/m3

TWA: 400 ppmSTEL: 500 ppm

STEL: 1225 mg/m3

Third Party Formulation (TP # 1303905) TWA: 1 mg/m3 Cu dust and mist - IDLH: 100 mg/m3 Cu dust and_____________________________________________________________________________________________


Handling Handle in accordance with good industrial hygiene and safety practice.


Storage Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Products Strong oxidizing agents. Acids. Chlorinated compounds.



Personal precautions Ensure adequate ventilation. Use personal protective equipment as required. Evacuatepersonnel to safe areas.



Environmental precautions See Section 12 for additional Ecological Information.




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mistTWA: 1 mg/m3 Cu dust and mist

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and HealthAdministration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962(11th Cir., 1992)






Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approvedrespiratory protection should be worn. Positive-pressure supplied air respirators may berequired for high airborne contaminant concentrations. Respiratory protection must beprovided in accordance with current local regulations.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.



Physical state Solid


_____________________________________________________________________________________________

Alcohol



Lower flammability limit No data available



None known

None known

Color



None known

No data available



None known

None known

Water Solubility Difficult solubility


None knownSolubility in other solvents No data available



Odor Threshold

None known

None known



None known

Flash Point


No data available

None known

Appearance


None known

None known

/


Evaporation Rate No data available None known

Property


Values

None known

Odor


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Remarks Method

_____________________________________________________________________________________________

Other Information





Inhalation May cause drowsiness or dizziness.





Chemical name Oral LD50 Dermal LD50 Inhalation LC50Third Party Formulation (TP #1303905)

= 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h


= 5000 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) > 6 mg/L ( Rat ) 4 h


= 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h


> 3000 mg/kg ( Rat ) - -


Symptoms Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,tiredness, nausea and vomiting.

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Chemical stabilityStable under recommended storage conditions.Possibility of Hazardous ReactionsNone under normal processing.Conditions to avoidNone known based on information supplied.Incompatible materialsStrong oxidizing agents. Acids. Chlorinated compounds.Hazardous Decomposition ProductsCarbon oxides.

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Reactivity

No data available.

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Chemical name ACGIH IARC NTP OSHAThird Party Formulation (TP# 1303905)

A3 Group 1 Known X


Group 3 X

ACGIH (American Conference of Governmental Industrial Hygienists)A3 - Animal CarcinogenIARC (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 3 - Not Classifiable as to Carcinogenicity in HumansNTP (National Toxicology Program)Known - Known CarcinogenOSHA (Occupational Safety and Health Administration of the US Department of Labor)X - Present




Chronic Toxicity No known effect based on information supplied. Repeated or prolonged inhalation to highconcentrations of vapors may cause respiratory irritation or central nervous system effects.

Target Organ Effects Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Blood. Central Nervous System(CNS). Kidney. Liver. Reproductive System. Spleen. Systemic Toxicity.




ATEmix (oral)5,665.00 mg/kgATEmix (dermal)28,692.00 mg/kg (ATE)ATEmix (inhalation-dust/mist)154.90 mg/l

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Chemical name Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms









(Leuciscus idus)

48h EC50: = 23300 mg/L


96h EC50: > 1000 mg/L(Desmodesmus

subspicatus) 72h EC50: >1000 mg/L (Desmodesmus

subspicatus)

96h LC50: > 1400000 µg/L(Lepomis macrochirus) 96h

LC50: = 11130 mg/L(Pimephales promelas) 96h

LC50: = 9640 mg/L(Pimephales promelas)

48h EC50: = 13299 mg/L


96h LC50: = 752.4 mg/L(Lepomis macrochirus)

EC50 > 10000 mg/L 30 min 24h EC50: > 500 mg/L


Bioaccumulation

Chemical name Log PowThird Party Formulation (TP # 1303905) -0.32




Revision Date 13-May-20151242311 - dry erase marker green ink



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TDG Not regulated

MEX Not regulated

ICAO Not regulated



RID Not regulated

ADR Not regulated

ADN Not regulated



_____________________________________________________________________________________________







Chemical name California Hazardous WasteThird Party Formulation (TP # 1303905) Toxic




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SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name CAS No Weight-% SARA 313 - ThresholdValues %






California Proposition 65This product contains the following Proposition 65 chemicals. The listed substance(s) is only a considered a Proposition 65developmental hazard when it is ingested as an alcoholic beverage.

Chemical name California Proposition 65Third Party Formulation (TP # 1303905) - Carcinogen

DevelopmentalU.S. State Right-to-Know Regulations

.

Chemical name New Jersey Massachusetts Pennsylvania Rhode Island IllinoisThird Party Formulation (TP # 1144126) X X



Third Party Formulation (TP # 1144126) X X




( 30 - 60 )Mexico: TWA 1000 ppm


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Mexico: TWA 400 ppmMexico: TWA 980 mg/m3

Mexico: STEL 500 ppmMexico: STEL 1225 mg/m3





Issuing Date 18-Jan-2016Revision Date 13-May-2015Revision Note No information available



_____________________________________________________________________________________________

HMIS

NFPA

Health Hazards 1


Flammability 1 Physical Hazard 0 Personal ProtectionX

Health Hazards 1


Flammability 1 Instability 0

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Documents

SAFETY DATA SHEETsds.staples.com/msds/2056102.pdf4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse