NAME: __________________________________ PERIOD: __________

CHEMISTRY NOTES: Unit 2: Structure of Matter

Content Outline: History of the Atomic Model (2.1)

I. Democritus (400 B. C.)A. He was a Greek philosopher of science.B. First to use the term “___________” to describe the basic particle of nature.

1. “atom” means “indivisible”2. Atom –

II. John Dalton (1808)A. He was an English schoolteacher.B. He was the first to propose an “_________________________” that contains the 5 following

statements:1. All matter is composed of extremely small particles called “____________________”.2. Atoms of a given element are identical in size, mass, and other properties; atoms of

different elements differ in size, mass, and other properties.3. Atoms cannot be subdivided, created, or destroyed.4. Atoms of different elements combine in simple whole-number ratios to form chemical compounds.5. In chemical reactions, atoms are combined, separated, or rearranged.

III. Joseph John Thomson (1897)A. He was an English Physicist.B. He worked with glass gas-filled tubes referred to as ______________________________________.

1. The glass tubes were filled with a gaseous element under low pressure.2. He then passed an electrical current through the gas using a battery and wires.

a. The electrical current caused the gas within the tube to intensely glow with a beam (“ray”).i. Magnets could make the “ray” move/deflect in various directions.ii. The ray is being deflected by the ______________________________ of the magnet.iii. Negative charge repels/deflects like negative charges.iv. The ray is made of a negative charge that Thompson called

________________________ (since they were associated with the electrical current.)b. The electrical current came into the chamber (by a wire) at the ____________________

end. (The end where electricity enters the tube.)c. Hence the term Cathode Ray tubes.

C. Further investigations using different elements in Cathode-Ray tubes confirmed that every element’s atoms possess ______________________________________.

D. He proposed the “_________________________________________” model of atoms.1. It stated that ________________________________ charged electrons are evenly placed inside a

___________________________________- charged mass.

IV. Robert A. Milliken (1909)A. He was an American Physicist.B. He was the first to measure ___________________________________________________________-.

The symbol for an electron is: ____________________1. Electron charge = 1.602 x 10-19 Coulombs.

a. This is an extremely small quantity of energy.2. Electron mass = 9.11 x 10-31 kg

a. Electrons are 1/1837th the mass of a single proton or neutron.

C. Milliken’s experiments allow for 2 inferences (conclusions based upon evidence and reasoning) to be made:1. Because atoms, in the natural state, are __________________________________, they must also

contain an equal amount of ______________________________________________.2. Because electrons have so little mass, atoms must contain other particles with much

greater mass (protons & neutrons).

V. Ernest Rutherford, Hans Geiger, and Ernest Marsden (1911)A. Geiger and Marsden were students of Rutherford a New Zealand Physicist.B. They performed the _____________________________________________________-.C. They used high-energy alpha particle radiation (2 protons & 2 neutrons ejected from a

decomposing, radioactive element) to bombard a piece of gold foil that was surrounded by a fluorescent screen.1. As alpha particles struck the fluorescent screen, they would produce a small detectable

burst of light.2. As the experiment was running, they detected light burst mainly behind the gold foil,

but also occasionally all around the ring.a. These bursts of light around the ring were because of the positively charged alpha

particles been deflected by positively charged particles in the atoms of the foil.b. The particles became known as ____________________________________.

i. Just as with the electrons, positive charges repel/deflect like positive charges.c. As most of the bursts of light occurred behind the gold foil, they concluded that the

majority of space in an atom is “empty space” that the alpha particles travelled through and never hit anything.

D. _______________________________ proposes the idea of the neutrally charged _______________ particle in 1920.

VI. Niels Bohr (1913)A. He was also a student of Rutherford’s.B. He proposed the _______________________________ of an atom.

1. The electrons move in a circular pattern around the positively charged center. (Much like the planets revolve around the sun.)

VII. Dmitri Ivanenko & Victor Ambartsumian (1930)A. These gentlemen were Russian Physicists.B. They proposed a model of the nucleus of an atom that is composed of positively charged

_____________________________ and _______________________________ charged particles (neutrons).

VIII. James Chadwick (1932)A. He was an English Physicist.B. He proved that the nucleus is definitely composed of protons and neutrons through his

experiments with __________________________________________.

Content Outline: Basic Atomic Structure and Mass (2.2)

I. AtomA. The smallest particle of an element that still retains the __________________ properties of that element.B. Atoms are composed of 3 sub-atomic particles:

1. Electrons (Thomson proposed)a. Electrons possess ______________________ electrical charges.b. Electrons are found orbiting the nucleus of an atom, in what is referred to as the

_____________________________ (They move at the speed of light and “create” a cloud-like appearance.)

c. Electrons are 1/1837th the mass of a single proton or single neutron.2. Protons (Rutherford, Geiger, and Marsden proposed)

a. Protons possess a ______________________________ electrical charge.b. Protons are found clumped together within the _______________________of an atom.c. Each proton has a mass of 1 atomic mass unit (AMU) or 1 Dalton (Named after John Dalton.)

3. Neutrons (Rutherford proposed)a. Neutrons possess ______________________ electrical charged and are therefore referred to as

neutral.b. Neutrons are also found clumped together within the _____________________of an atom.c. Each neutron has a mass of 1 AMU or 1 Dalton.

C. Nuclear Forces1. These are short-range proton-to-neutron OR proton-to-proton OR neutron-to-neutron

attractive forces that help hold together the nucleus of an atom.2. These forces are greater than the repulsive same charge electrical forces exhibit by protons.

D. Atomic Radii1. This term refers to the relative size of an individual atom of an element.2. It is measured from the _________________________________________ to the outermost electron cloud.3. It is measured in picometers (pm)

a. A picometer is 1.0 x 10-12 meters (so it is very, very small)4. Charles-Augustin de Coulomb (1785)

a. He proposed ________________________________ – attractions that exist between oppositely electrically charged particles (protons & electrons) within a single atom.

b. The forces directly affect the atomic radii of an atom.i. More ______________________ than electrons = radii shrinking (getting smaller) because

the positive charge is greater than the smaller negative charges and pulls them in toward the nucleus.

ii. More ____________________________ than protons = radii increases (getting larger) because the electrons are farther away from the positive nucleus.

iii. The Natural state of atoms has protons = electrons; so atomic radii are stable (not changing) for each element.

5. Atomic radii can have an effect on the chemical properties of an element.

II. Atomic NumberA. This term refers to the _____________________________found within the nucleus of an atom for that

element.B. Each element has a ___________________________ and identifying number of protons.C. The atomic number for each element led to the creation of the Periodic Table

1. The Periodic Table was originally created by ___________________________ in 1869.a. He was a Russian Chemist.

D. The atomic number is usually written as superscript (above) the Elements Chemical symbol.1. Some of the symbols use the Latin term, instead of the English word like Iron, its symbol is Fe

for “Ferrum”.a. Latin is used because it is a “dead” language (will not change over time) and was the original

language of science.E. The Periodic Table was created based upon increasing Atomic Number.

III. Atomic Mass Units (AMU)A. Also known as the __________________________B. This term refers to the total ______________________ of an atom of that element.C. It is found by __________________________ the number of protons and neutrons together.

1. Each proton OR each neutron has a mass of 1 AMU or 1 Dalton.2. The Electrons’ mass is insignificant as they are so small (1/1837th that of protons/neutrons).

D. The Atomic Mass is usually written as a _______________________- (below) the Element symbol.E. This was based on Carbon-12 as the standard element of measure. It has 12.0 AMU.

IV. IsotopesA. This term refers to atoms of an element that have different masses (AMUs) because they have

different numbers of neutrons within the atom; even though it is the same element because they have the same number of protons. (Remember, protons identify the element.)1. The isotopes behave relatively the same as the natural atom in terms of chemical properties.2. Some Isotopes are _________________ (the nucleus is “breaking apart”).

B. To find the number of neutrons:Start with AMU, subtract the # of protons (atomic number), and that leaves the number neutrons

_____________________________ = # neutrons

C. How Isotopes are written chemically:1. Hyphen notation – symbol- number, For example: Carbon-14 OR C-14.2. Nuclear notation – AMU over Atomic Number symbol, for example 14

6 C.D. Nuclide

1. This term is used to refer to the nucleus only (no e- cloud) of an Isotope.

V. Average Atomic MassA. As some elements have several isotopes also present in nature, their masses must also be

considered to find the average mass for an element (as seen on the Periodic Table).B. How to calculate the average Atomic Mass of an element:

Step 1: Multiply the AMU for a single isotope by the % found in nature.Cu 63 – AMU of 63 = 62.93 AMU; so 62.93 x 69.15% (nature) = 62.93 x .6915 = 43.52 AMUCu 65 – AMU of 65 = 64.93AMU; so 64.93 x 30.85% (nature) = 64.93 x .3085 = 20.03 AMU

Step 2: Add the all AMUs together.43.52 + 20.03 = 63.55 AMU

Step 3: Round to two places after the decimal for each isotope calculation in Step 1.

Your Turn: Find the Average Atomic Mass of the following:

1. What is average atomic mass of Lithium if 7.42% exists as 6Li (6.015 g/mol) and 92.58% exists as 7Li (7.016 g/mol)?

2. Magnesium has three naturally occuring isotopes. 78.70% of Magnesium atoms exist as Magnesium-24 (23.9850 g/mol), 10.03% exist as Magnesium-25 (24.9858 g/mol) and 11.17% exist as Magnesium-26 (25.9826 g/mol). What is the average atomic mass of Magnesium?

3. Neon has two major isotopes, Neon-20 and Neon-22. Out of every 250 neon atoms, 225 will be Neon-20 (19.992 g/mol), and 25 will be Neon-22 (21.991 g/mol). What is the average atomic mass of Neon?

Unit 2: Structure of MatterContent Outline: Atomic Mass and the Mole Concept (2.3)

I. Mole (mol OR n)A. This is a SI (Le Système International d’ Unités) unit (remember from Unit 1) that is used to

represent the amount of a substance.B. It can be written to show the number of atoms or molecules in a working sample of some element,

compound, or molecule, such as sucrose (table sugar) – C6H12O6

1. This concept is very important because scientists, teachers and students cannot work with individual atoms or molecules because they are very, very small and can’t be handled one at a time.

2. So the mole was conceived to represent a ___________________ of a substance.C. How to calculate a mole:

1. Determine the total atomic or _____________________ mass of the substance you are working with, using the chemical formula and Periodic Table. (Remember, how to find the Atomic Mass? – Hint…subscript.)

2. Then weigh out, using an electronic balance and weigh boat, that calculated amount.3. Congratulations, you have just weighed out 1 mole of that substance!

For example: Atomic MassAluminum has an atomic mass of 26.98 AMUs. So you would weigh out 26.98

grams of Aluminum to get a workable amount called a mole.

Molecular Mass ProblemHow much does 1 mole of Salt (NaCl) weigh?

The unit for of measurement is g/mol.

D. Molarity 1. Take your 1 mole of a substance and dissolve it in a small amount of distilled water, if it will

dissolve, inside a volumetric flask. Then add distilled water to bring the volume to ________ of distilled water. You now have a 1 Molar (1 M) solution.

2. Molarity is used for ______________ solutions.E. Amedeo Avogrado (1811)

1. He was an Italian physicist.2. He proposed that the _______________________ of a gas (at a given temperature & pressure) is

proportional to the ____________________________________________, regardless of the type of gaseous substance used.a. This eventually was modified to state: That in 1 mole of a substance there will always be

___________________________________________________ atoms or molecules present. (That is a massive amount!)

b. This number became known as ______________________________________ when the French physicist Jean Perrin confirmed and proposed this in 1909 in honor of Avogrado’s work.i. Jean Perrin would win the Nobel Prize for his work in 1926.ii. The Nobel Prize is Sciences’ highest Award, The Super Bowl trophy in Pro Football.

c. Perhaps your class will celebrate Mole Day on October (10th month) 23 at 6:02 am.

II. Basic Measurements or Unit Conversions involving the Mole concept:A. More than a mole: the basic concept is: amount you have/ amount of a mole = # of moles

You have 21.6 grams of Boron (B). How many moles do you have?

You have 77.25 grams of Phosphorus (P). How many moles do you have?

B. Less than a mole: the basic concept is: amount you have/ amount of a mole = # of molesYou have 16.03 grams of Sulfur (S). How many moles do you have?

You have 2.43 grams of Magnesium (Mg). How many moles do you have?

C. Conversions from one unit to another unit involving the mole concept:

The basic concept is: Unit given x unit wanted = Unit wanted unit given

The given unit cancels out and leaves you with the unit wanted.

1. Moles Atoms/Moleculesa. You have 2.0 moles of Copper. How many atoms of Copper do you have?

b. You have 0.25 moles of Oxygen. How many atoms of Oxygen do you have?

2. Atoms/Molecules molesa. You have 1.806 x 1024 atoms of Zinc (Zn). How many moles of Zinc do you have?

b. You have 5.9 x 1022 atoms of Titanium (Ti) How many moles of Titanium do you have?

3. Grams Molesa. You have 54.0 grams of Carbon (C). How many moles of Carbon do you have?

b. You have 10.0 grams of Nickel (Ni). How many moles of Nickel do you have?

4. Moles Gramsa. You have 8.5 moles of Fluorine (F) gas. How grams of Fluorine do you have?

b. You have 0.45 moles of Scandium (Sc) gas. How grams of Scandium do you have?

Unit 2: Structure of MatterContent Outline: Working Complex Mole Concept Problems (2.4)

I. In most chemistry equations, students need to be able to perform numerous conversions, often referred to as _________________________________________.

A. Complex Mole Concept problems.1. The underlying fundamental concept map (often shown as a mole map)

Atoms/particles moles grams

We can go from one end of the map to the other end remembering:

Unit given X Unit Wanted 1 x Unit Wanted 2 = Unit Wanted 2 Unit Given Unit Wanted 1

2. Atoms/Particles gramsa. You have 9.45 x 1023 atoms of Cesium (Cs). How many grams of Cesium do you have?

b. You have 1.25 x 1023 atoms of Tin (Sn). How many grams of Tin do you have?

3. Grams Atoms/Particlesa. You have 156.90 grams of Gallium (Ga). How many atoms do you have?

b. You have 380.00 grams of Glucose (C6H12O6). How many molecules do you have?

Unit 2: Structure of MatterContent Outline: Bohr Model of atoms and Electron Energy (2.5)

I. Niels Bohr (1913)A. Danish PhysicistB. Proposed the Bohr Model of Atom structure

1. Electrons travel in set paths around the nucleus called ____________________ or _____________________.2. Each orbit corresponds with an energy level.

a. Electrons have a natural tendency to occupy the lowest (most stable) energy level first.i. The lowest energy level (____________________________) is the closest to the nucleus.ii. This is related to ________________________________-- – opposite electrical forces attract.iii. The farther away from the nucleus the greater the Potential Energy for that electron.iv. The closer to the nucleus the less Potential Energy for that electron.

b. Electrons can absorb energy (absorption) from their surroundings from another energy source, such as sunlight energy (A.K.A electromagnetic energy).i. Electrons that gain energy (absorption) are said to be “excited”.ii. Electrons that lose energy (_________________________________) emit light as they return to

a more stable (less energy) grounded state.iii. The unit of light energy is referred to as a _______________________.iv. The unit of measurement for the energy lost OR gained by an atom is a

_________________________________.

II. Electrons as Particles & WavesA. Electrons can move as particles around the nucleus because they have mass (if ever so small).B. Electrons, as they are moving, move in wave-like fashion (like waves in the Gulf of Mexico… up,

down, up, down)C. Properties of waves

1. Wavelength ( )λa. This is defined as the distance between __________________________________________ (such as crest –

top or ebb- bottom) on adjacent waves.i. As it is distance, some unit of measurement of distance (meter) is used for

wavelength, usually nanometer (nm OR 10-9).2. Frequency (v)

a. This is defined as the _________________________________ that pass a given point in a specified time, usually seconds.

b. Frequency is expressed in Hertz (Hz) or waves/sec.i. Heinrich Hertz defined 1 wave/sec = 1 Hertz.

3. Speed of light (c)a. Electrons travel at the speed of light.b. Waves are measured against the speed of light (electromagnetic radiation).c. C = ___________ is the equation for the speed of light.

i. As light speed never changes, it is considered to be a constant at 3.00 x 108 m/sec.ii. The properties of light are inversely proportional.

. As wavelength α decreases, frequency increases.b. As wavelength increases, frequency decreases.

d. As electrons gain more energy, they travel faster and get farther from the nucleus.

III. Electromagnetic Spectrum (Light Energy)A. This term refers to the whole spectrum (variations) of __________________________________________.

1. ___________________________________ is used to define the wave-like movement of light particles.2. Light moves at 3.00 x 108 m/sec.3. The electromagnetic spectrum includes: x-rays, microwaves, visible (white) light, ultra-violet

light, infrared light, and radio waves.

Unit 2: Structure of MatterContent Outline: Photoelectric Effect and Emission Spectrum (2.6)

I. PhotonA. Albert Einstein proposed this concept in 1905.B. A Photon is a unit of light energy having no mass and possessing a single quantum of energy.

1. Quantuma. Minimum quantity of energy that can be lost or gained by an atom.b. Proposed by German physicist Max Planck in 1900.c. This sets the field of Quantum Physics (nanoscale physics) in motion.d. Planck wins the Nobel Prize in 1918 for this work.

II. Photoelectric EffectA. The ______________________________- (ejection) of an electron from a metal surface when light shines on

the surface.1. This shows a direct connection between light and light possessing energy.2. This light energy is Einstein’s photon.

B. The light has to be of a _____________________________________ in order for the effect to take place.C. Each metal requires a _____________________________________frequency of light.

III. Planck’s Constant Theory1. This tries to explain the Photoelectric Effect by proposing a relationship between a

_______________________ of energy and the _____________________________ of radiation. Remember, light is considered electromagnetic radiation, so the frequency changes with the various forms of light/radiation. This is called the ___________________________________________.

A. E = hv1. E = energy for a quantum of radiation.

a. It is measured in Joules (J).2. v = frequency of the radiation.

a. measured in waves/sec. (s) -1 or Hertz3. h = Planck’s Constant

a. Defined as 6.626 x 10-34 J * s (* = times)B. Planck-Einstein Relation

1. Albert Einstein expanded on Planck’s work in 1905.2. He proposed that light has a combination of wave properties and particle properties.

a. Each particle of light carries 1 quantum of energy3. E = hv (Planck’s version) then becomes Ephoton = hv (Einstein’s version).4. Matter can only absorb Electromagnetic radiation (light) in whole number (1, 2, and so forth)

quantities of photons.5. In order for a single electron to be emitted from the metal surface, the electron must be struck

by a _________________________________- possessing at least the minimum amount of energy to eject the electron.a. This minimum amount of energy is directly related to the _________________________________

i. The _________________________ the frequency – the more possible to emit an electron from the surface.

ii. The ________________________________the frequency – the less likely to emit an electron from the surface.

b. Different metals require different frequencies for the Photoelectric effect to take place.

IV. Emission Spectrum of HydrogenA. This is an expansion of the ______________________________________ Tube experiment.

1. It uses Hydrogen gas (which glows pink) and a glass prism (triangular shaped piece) placed in the path of the light ray.a. The light ray split into 4 different colors (red, green, blue, and purple).

i. These become known as the _________________________________ spectrum.

ii. Each color represents a fixed quantity of energy for an excited electron.iii. It is later added for other frequencies of light, such Infrared and Ultra-violet.

V. These experiment set the groundwork for the Modern Quantum Atomic Model of atoms.

Unit 2: Structure of MatterContent Outline: Modern Quantum Model of Atoms (2.7)

I. Louis de Broglie (1924)A. He was a French Scientist.B. He proposed that electrons (e-) had wave-like properties using Bohr’s Atomic model.

1. He stated that electrons are confined to areas around the nucleus, known as ____________________.C. Using the Planck-Einstein Relation, he reasoned that electrons have specified energies/frequencies.

_________________________________________ (bending of waves) experiments with electron beams and light beam showed similar results, proving electrons travel like light… in waves.

D. ________________________________________ (waves overlapping) experiments with waves and electron beams showed similar results, proving electrons have particle like properties associated with energy.1. Some areas increased in energy as a result of overlap; other areas decreased in energy.

II. Werner Heisenberg (1927)A. He was a German Physicist.B. He calculated that electrons and photons have about the same amounts of energy.

1. Photons are used to help detect the presence of electrons.a. When they collide, the electron is deflected in a random direction.

C. ________________________________________________________ Principle1. This states that it is impossible to determine exactly both position and velocity simultaneously of

an electron in an orbit.

III. Erwin Schrödinger (1926)A. He was an Austrian Physicist.B. He helped develop the ________________________________ of Atoms

1. This Theory tries to describe, by mathematics, the wave-like properties of electrons and other very small particles.

2. This re-enforces that electrons travel in orbitals.a. ____________________________ is defined as a 3- Dimensional region around a nucleus that

indicates the probable location of a single electron within an orbital.C. Quantum Numbers

1. These are four numbers, written consecutively, that specify the properties of atomic orbitals and properties of the electrons within an orbital.For example: n,l,m,s 1,0,0,1/2 or 2,1,1,-1/2

2. The first number: the Principle Quantum numbera. Symbolized as “______________”.b. This states the electron energy level (or shell).c. Uses only whole numbers 1-7.d. As “n” increases, the distance from the nucleus also increases; therefore the Potential Energy

of that electron also increases.3. The second number: the Angular Momentum Quantum number

a. Symbolized as “___________”.b. This states the shape of orbitals or sub-orbitals.

i. 0 = s (sphere shaped); there is only 1 orbital/energy level.ii. 1 = p (dumbbell shaped); there can be up to 3/energy level.iii. 2 = d (4 leaf clover shaped with a possible ring); there can be up to 5/energy level.iv. 3 = f (too complex to describe); there can be up to 7/energy level.

4. The third number: the ______________________________________a. Symbolized by “m”.b. This states the orientation (up/down, left/right, forward/backward) of an orbital around

the nucleus. i. s = 0ii. p = 1, 0, -1 (are possible) iii. d = 2, 1, 0, -1, -2 (are possible)iv. f = 3, 2, 1, 0, -1, -2, -3 (are possible)

5. The fourth number: the _____________________________________________-- numbera. Symbolized as “s”b. As each orbital can only hold two negatively charged electrons, they must be opposites in

spin (motion).c. We use either +1/2 (up) or -1/2 (down) for this.

IV. Orbital Electron Configuration ModelsA. These are used to help represent the electron arrangement of an atom; electrons are represented by

numbers such as 1s1 for Hydrogen or 1s2 2s2 2p5 for Fluorine or as arrows, either B. It is important to remember that each orbital can only hold 2 electrons maximum.C. You “build the model” starting from the ______________________________________________ (lowest energy

level) and work upward, starting at 1s1 ; the exponent states the number of electrons present at that level… hint look at the periodic table ROWS. Highest is row 7.

D. This uses 3 rules:1. _____________________________ Principle (“aufbau” is German for “to build”)

a. Electrons occupy the lowest energy level first that can receive the electron. Starting at 1s and work toward row 7.

2. ___________________________________________ Principle a. Contributed by Wolfgang Pauli, an Austrian physicist.b. No 2 electrons, in the same atom, can have the same 4 Quantum numbers.

3. _________________________________ Rulea. Contributed by Friedrich Hund, a German Physicist.b. States that orbitals and sub-orbitals of equal energy are each occupied by a solo electron

before a second electron is entered into the orbital or sub-orbital and all electrons in singly occupied orbitals/sub-orbitals must have the same spin number. (Start with =1/2 ; then go back and use -1/2 )

V. Noble Gas Electron ConfigurationA. This method is used to shorten the traditional model building.B. Starting at Neon (Ne), you can begin the notation using a Noble gas first.

1. The Noble Gas must be in [ ]. Then start with the next energy row.

Unit 2: Structure of MatterContent Outline: The Periodic Table & Electron Configuration Models (2.8)

I. Dmitri Mendeleev (1869) A. He created a table of the known elements based upon similar chemical properties and known atomic

masses.B. Periodic Law

1. The physical and chemical properties of the element are periodic functions of their atomic number.

2. When elements are arranged by increasing atomic number, elements with _________________________________________ appear at regular/periodic intervals.

II. Henry Mosely (1911)A. He was an English Scientist.

B. He modified Mendeleev’s table to make it a function of increasing atomic number, not increasing atomic mass. Remember, Atomic number is the number of protons in an atom; Atomic Mass is the number of protons +neutrons. 1. This makes the organizational pattern of the table more reliable and predictable for newly

discovered elements.

III. John William Strutt & Sir William Ramsay (1894)A. John William Strutt was a British Physicist.B. Sir William Ramsay was a Scottish chemist.C. They discovered the first __________________________ gases.

1. These are the least reactive group of elements on the Periodic Table.a. The have a full ______________________________ (outer-most) electron energy shell.b. They are in column 18 of the table.

IV. The Periodic Table Reading FormatA. The Periodic table appears as rows and columns.

1. The rows are called _________________________________. (Think of it “like” a chemical sentence; a period goes at the end.)a. Each period is associated with an energy level and various orbitals/ sub-orbitals.

i. The first period only has an “s” orbital.ii. The second period has an “s” and “p” orbitals. Each “p” block has 3 sub-orbitals

(Remember orbitals can only hold 2 electrons.) The third period is just like the second.

iii. The fourth period has an “s”, “d” and “p” orbitals. Each “d” block has 5 sub-orbitals.iv. The fifth period is the same as the forth row.v. The sixth period has an “s”, “f”, “d”, and “p” orbitals. Each “f” block has 7 sub-orbitals.

. The portion of the “f” block in the sixth period is called the α Lanthanide series.b. The portion of the “f” block in the seventh period is called the Actinide series. * Most of these are synthetic elements (man-made in the laboratory) and radioactive (give off energy).

2. The vertical columns are called _________________________________________. a. Each family of elements has very similar chemical properties. b. There exist 18 families on the periodic table.

i. Family 1 is called the Alkali Metals family.ii. Family 2 is called the Alkaline Earth metals family.

. Families 1 and 2 are the “s” block/orbital.αb. They are highly reactive with air, moisture, or most other elements. * This is because family 1 has 1 valence electron; family 2 has 2 valence electrons.

iii. Families 3 – 12 are called the __________________________________ Metals elements and make up the “d”

block/orbitals.iv. Families 13 -18 are known as the “________” block elements.

. These elements are a collection of α metals, metalloids, non-metals, and gases.* The metalloids are next to the zigzag line running down through the “p”

block in the table. b. The “s” and “p” blocks collectively together are referred to as the main-group

elements.c. The family in column 17 is known as the ____________________________ family.

* They are very reactive elements as they are missing1 electron from having a full valence shell.

d. The family in column 18 is known as the _________________________ gases.* These are the least reactive elements on the table, as they possess a full

valence shell known as an “______________________” or 8 electrons in a shell.

3. Metalsa. These make up the majority of the Periodic Table.b. Metals are defined as good conductors of electricity, have a high luster (shine) and are

malleable (capable of being beat, using hammers or rollers, into wires).4. Metalloids (“oid” means “like a”) a. These are “like” metals as some are able to conduct some electricity (A.K.A. as semi- conductors). b. They are located between the metals and the gases along the zigzag line of “p” block.5. Non-metals a. These are mostly powders that are non-conductors of electricity.6. Gases a. These floating elements that have no definite shape or volume. They take the shape and volume of their container. b. Most can conduct electricity. (Remember the Cathode-Ray tubes and neon signs.)

Unit 2: Structure of MatterContent Outline: Periodic Trends associated with Electrons and Coulombs Forces (2.9)

I. Coulomb’s ForcesA. These are the attractive forces that exist between two oppositely electrically charged particles, such

as positive __________________________________ and negatively charged ______________________________. 1. Remember, in the natural state, an atom has ______________________________________ of protons and

electrons; therefore, they are electrically _____________________________.2. As the protons are larger in mass, if an atom has more protons than electrons, the electrons are

pulled inward and thereby possess less Potential Energy. See below 1 & 23. If the electron has more electrons than protons, the electrons are able to be farther from the

nucleus and thereby possess greater Potential Energy. See below 1 & 2B. The formula for Coulomb’s Force is:

l q 1q2 l This equation is affected by 1) magnitude (number) of charges (q)F = ke x r2 q1 would be the number of Protons; q2 number of electrons

2) Distance – r2

ke – is Coulomb’s constant = 8.99 x 109

II. Effective Nuclear ChargeA. This is symbolized as ____________________________B. This is the net positive charge experienced by a single outer shell electron of an atom.

1. The Pull the electron “feels” by the nucleus. 2. Electron __________________________-

a. This term refers to the inner energy level of electrons helping to reduce (shield) the outermost electrons from the full pull of the nucleus. Hence the term electron shielding.i. This allows the outermost electrons to remain farther away from the nucleus.ii. The _________________________ electrons an atom has, the greater the distance away from

the nucleus because of greater shielding.

III. The Periodic Trends in the Periodic TableA. There are trends across a Period (row), referred to as ______________________________________________.

There are trends within a Family (column), referred to as Group Trends or Family Trends.B. Atomic Radii Trends

1. Period Trendsa. Atomic Radii ___________________as you go across (left to right) a period. This is due to greater

Coulombs forces or greater ZEFF. (Nucleus has greater pull on the electrons.)2. Group Trends

a. Atomic Radii _____________________________as you gown down a group. This is due to greater numbers of electrons in higher energy levels being present and greater electron shielding. (Nucleus has less pull.)

b. Exceptions 1) – Gallium. It is because Gallium has all the Group D protons, whereas Aluminum does not. Therefore Gallium is small due to greater Coulombs forces or ZEFF. 2) At the hallway point through the “d” and “f” blocks as each sublevel is half full. It resumes when the next electron is added into a half filled orbital.

C. Ionization Energy Trends1. Ion

a. This is a charged particle that is the result of gaining or losing an electron.b. Cation

i. These are _____________________________ particles/atoms that have lost electrons.ii. Because of the ______________________________________ of Matter, the electrons must have

gone to another location.. The Law states: α

__________________________________________________________________________________________________________________________________________________________________________________________________

c. Anioni. These are _____________________________ particles/atoms that have gained electrons.

d. Ionizationi. This is the process of creating ions by gaining or losing electrons. (“tion” means

“process of”). e. Ionization Energy (IE)

i. This is the energy required to ____________________________________ one electron from a neutral atom.

ii. It is measured in kilojoules/mole (kJ/mol).2. Period Trends

a. Group 1 Metals have the _________________________ Ionization Energies. (They lose electrons easily, hence their being very reactive.)

b. Group 18 (Noble Gases) have the ________________________ Ionization Energies on the whole Periodic Table. (They do not lose electrons easily, hence their being unreactive.)

c. The Ionization Energies _______________________________ as you go across the period due to greater Coulomb Forces or increased ZEFF. (The nucleus has a greater pull…requires more energy to remove.)

3. Group Trendsa. Ionization Energies generally __________________________ as you down a group due to lesser

Coulomb Forces or weaker ZEFF. (Electrons are farther away (more shielded) from the nucleus, so less energy is needed to remove electrons.)

4. To remove ________________________________________ electron, even greater amounts of energy are needed than for the first. This information can be found on an ionization table. With each electron removed, the greater the Coulombs forces or increased ZEFF become within the atom.

D. Electron Affinity1. This term refers to the _____________________________ (positive or negative) to add an electron to an

atom.a. If the change is negative, energy has been released. (This is easy to do.)b. If the change is positive, energy has been invested into the atom. (This is hard to do.)

i. It requires a greater pushing force be put on the atom to overcome the negative repulsive forces, thus making the atom very unstable. (This is what happens in your cell phone… we use the greater electrical force to reverse the electron flow back to a “charged state”.)

2. It is measured in kilojoules/mole (kJ/mol) too.3. Period Trends

a. Group 17 (Halogens) has the __________________________ affinity as shown by large negative numbers.

b. In general, Electron Affinity ________________________--as you go across a period.c. Exception to the rule: Carbon – adding an electron allows the atom to reach a half filled p sub-

level. That makes adding the fourth into a half filled sub-orbital more difficult as seen in N.

4. Group Trendsa. In general, Electron Affinity decreases (become more difficult) as you go down a group

because of greater Atomic radii and increased electron repulsive forces.5. Adding a second electron is generally more difficult, unless it is a Group 16 element, such as

Oxygen. It needs 2 electrons to fill the valence shell.E. Ionic Radii

1. _________________________________ have decreased atomic radii due to greater Coulombs Forces or greater ZEFF. (The electron cloud gets smaller.)

2. ________________________________- have increased atomic radii due to greater electron shielding and no increase in ZEFF.

(The electron cloud gets larger.)3. Period trends

a. Ionic Radii decreases until Group 15 and then begins to increase.b. This is because Groups 1 – 14 are more Cationic. See above in F.1c. Groups 15 – 17 are more Anionic. See above in F.2

4. Group Trendsa. Ionic Radii increases as you go down a group due to greater energy levels of electrons.

F. Electronegativity1. This can be thought of as the __________________________________ negative electrons from another

atom.2. Fluorine (F) is the most electronegative element. (It has the strongest desire to be “like” a noble

gas…if it can just get that last electron in the valence shell.3. Francium (Fr) is the least electronegative element. (It has very little desire to acquire an

electron. It would rather get rid of the solo electron in its valence shell and then be “like” the Noble Gas Radon (Rn).)

4. Period Trenda. Electronegativity generally _____________________________going across a period.

5. Group Trenda. Electronegativity decreases as you go down a group because the valence electrons are

farther from the nucleus. (There is more electron shielding, so it is less desirous to acquire electrons.)

Unit 2: Structure of MatterContent Outline: Nuclear Chemistry Basics (2.10)

I. NuclideA. This term refers to the ____________________________ of an atom. It is without the electron cloud.B. Nucleons

1. This term refers to the components of an atom’s nucleus – _______________________________________.2. Remember, each proton and neutron has a mass = 1 AMU or Dalton; protons carry a positive

charge and neutrons carry no charge (neutral).C. Nuclides can be written 2 ways:

1. Hyphen notation – the name followed by the Atomic mass. For example, Radium-2282. Nuclear notation – Atomic mass over Atomic Number followed by Symbol.

For example, 22888 Ra

D. Nuclear Force1. Short-range attractive forces that help hold together the nucleus of an atom.

A. Nuclear Binding Energy This term refers to the very small amount of energy that is released when a nucleus is formed from nucleons.

B. This term can also refer to the energy required to break apart a nucleus.C. The general trend is: as the nucleus increases in size and number of nucleons, the nuclear binding

energy _______________________________ until Iron (Fe). After Iron, the nuclear binding energy decreases due to the nucleus being so large.

II. Nucleus StabilityA. Nuclear Shell Model

1. Nucleons exist in different energy levels/shells within the nucleus, just like electrons in the cloud.2. Even numbers tend to be more stable than odd numbers of nucleons.

B. As the number of protons in a nucleus increases, the stability of the nucleus decreases1. This is because the positive repulsive forces are greater than the Nuclear Force.2. To reduce this instability, neutrons are needed to increase the distance between protons and

decrease the repulsive forces between protons.a. This makes the Nuclear Force greater than the repulsive force.

C. Beyond Bismuth (Bi) with Atomic Number of 83, the repulsive forces are so great that there is no Nuclear force and each atom is unstable and radioactive.

III. Marie and Pierre Curie (1896)A. The Curie’s were a husband and wife team of French Physicists.B. Marie Curie was the first woman to win a Nobel in Prize in 1903 for her work on radioactivity. She

later won a second Nobel Prize in 1911. She is the only female to win 2 Nobel Prizes. That is awesome! Kinda like Alabama winning back-to-back National Championships.

C. Radioactive Decay 1. This is defined as the spontaneous disintegration (falling apart) of a nucleus into a smaller and

lighter (AMUs) by emitting (releasing) particles, electromagnetic radiation, or both.D. Nuclear Radiation

1. This refers to particles or electromagnetic radiation emitted from the nucleus during radioactive decay.

E. Radioactive Nuclide1. Refers to an unstable, radioactive nucleus of an atom.

IV. The types of radioactive decay- A. If you change the Atomic Number you change the element. This is known as a transmutation. So you need a Periodic Table.B. Alpha Particle Emission ( ) or (α 4

2He) - 1. This is the emission (release) of 2 protons and 2 neutrons as an alpha particle.2. This causes the Atomic Number to decrease by 2 and the Atomic Mass to decrease by 4 AMUs.3. This is the weakest penetrating radiation. (A couple sheets of paper can stop it.)

C. Beta Emission ( ) or (β 0-1 )β

1. This is when a neutron is converted to a proton and an electron. The electron is emitted from the nucleus.

2. The Atomic Number increases by 1, but the Atomic Mass remains the same in AMUs.3. This has greater penetrating strength than Alpha particle emission.

D. Positron Emission (0+1 )β

1. This is when a proton is converted to a neutron and a positron. The positron is emitted.a. Positron is a particle with the same mass as an electron, but possessing a positive charge.b. The Atomic Number decreases by one, but the atomic mass remains the same in AMUs.

E. Electron Capture1. An innermost electron is captured by the nucleus and combines with a proton to create a

neutron.2. The atomic number decreases by 1, but the Atomic Mass remains the same in AMUs.

F. Gamma Emission ( )γ1. This is high energy electromagnetic radiation that is emitted as a nucleus goes from an excited

state to a ground statea. This is similar to electrons emitting photons as the go from an excited to ground state.b. The nuclear shell is emitting energy.

2. This is the most penetrating form of radiation. (It can penetrate lead.)

Unit 2: Structure of MatterContent Outline: Nuclear Energy & Half-Life (2.11)

I. Decay SeriesA. This is a chart showing a series of radioactive nuclides produced by successive radioactive decay

until a lighter, more stable nuclide is reached in the end.1. The heaviest, most unstable nuclide in a series (at the top) is referred to as the

_________________________________________.2. The nuclides produced (in the downward trail) by the decay of the parent nuclide are referred to

as ___________________________________.

II. Half-life (t1/2) calculationsA. This is defined as the time required for half of the radioactive atoms in a sample to decay into a

lighter, more stable nuclide.1. No two radioactive isotopes possess the same rate of decay (half-life).

a. More stable nuclides decay at a slower rate.b. More unstable nuclides decay at a faster rate.

For example: 3215 P which has a half-life of roughly 14 days.

B. This calculation can be used in medicine or for telling the age of rocks & fossils.C. To detect radiation, we use instruments such as Geiger counters, Scintillation counters, and Film

Badges (worn on a person’s uniform).1. These devices measure Roentgens (R).2. The Roentgens can be used to calculate REM

a. This is a unit used to measure the dose of any type of radiation that factors into the effect on human tissue. Radiation can cause cancers by mutating DNA.

III. Nuclear Fusion (“fuse” means “to come together as one”)A. This is the process where low mass nuclei combine into heavier, more stable nuclei.B. This releases massive amounts of energy, such as seen in our Sun and stars.

Sun’s example: 4 11 H atoms 4

2He + 2 01 particles + Energyβ

IV. Nuclear Fission (“fission” means “to split”)A. This is the process of a heavy, unstable nuclide, such as U-235, splitting into smaller, more stable

nuclides.

Such as: U-235 splitting into Kr-93 and Ba-140

B. The releases large quantities of energy, such as is carried out in our Nuclear Power Plants.C. This fission starts a chain reaction (successive chemical reactions) that yields more and more

energy each time a split occurs.

1. The end product is low energy radioactive products called _________________________________ a. These are hard to dispose of once formed.b. The largest nuclear waste dump/facility is Yucca Mountain, just outside Las Vegas, Nevada.

D. Our Nuclear Power Plants use Nuclear Reactors to generate electricity.1. These use the heat energy, from the radioactive chain reaction decay of U-235, to convert liquid

water into steam. The steam is then used to power giant turbines by kinetic movement of the steam. The turbines turn and generate electricity.a. The steam is the cooled (condensed) back to liquid water. The water is reused but becomes

radioactive waste over time.2. Shielding Containment Structures

a. These are usually concrete reactor containment domes.b. The control the radioactive exposure by absorbing the lose radiation from the reactor.

3. Fuel Rodsa. These are usually long solid rods of highly reactive compact U-235.b. They eventually become nuclear waste.

4. Control Rodsa. These solid rods are used to control the amount of heat generating radiation by absorbing

free neutrons from the water surrounding the both the control and fuel rods.i. If the control rods are lowered down – less energy is produced.ii. If the control rods are raised up – more energy is produced.

5. Nuclear MeltdownA. This is where there is a breach in the containment dome because the fuel rods got to hot

(because the control rods could not be lowered) and melted through the bottom. B. When this happens massive amounts of radiation are being released into the environment.

1. This recently happened in Fukushima, Japan when a tidal wave hit the plant.2. It last happened in the U.S. at 3-Mile Island (Pennsylvania) in 1979.3. A very bad meltdown occurred in Chernobyl, Russia in 1986.4. All three sites are still highly radioactive locations.