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Risk Assessment and DisasterManagement of Contaminated HWSites and Methods of Remediation
M. J. PERVEZGroup Head & Director (Environment)
NATIONAL PRODUCTIVITY COUNCIL(Under Ministry of Commerce & Industry, Govt. of India)Utpadakta Bhavan, 5-6 Institutional Area, Lodi Road,
New Delhi – 110 003
Risk Assessment and DisasterManagement of Contaminated HWSites and Methods of Remediation
M. J. PERVEZGroup Head & Director (Environment)
NATIONAL PRODUCTIVITY COUNCIL(Under Ministry of Commerce & Industry, Govt. of India)Utpadakta Bhavan, 5-6 Institutional Area, Lodi Road,
New Delhi – 110 003
Contaminated HW Sites
An area of land in which the soil or underlyinggroundwater or sediment contains HazardousWaste or substance in an amount or concentrationthat exceeds environmental quality standards.
A site is contaminated if it is unsuitable forspecific uses of land, water and settlement
Environmental Management Group, National Productivity Council
An area of land in which the soil or underlyinggroundwater or sediment contains HazardousWaste or substance in an amount or concentrationthat exceeds environmental quality standards.
A site is contaminated if it is unsuitable forspecific uses of land, water and settlement
Potential Sources of Contaminants
Direct pipeline or outfall discharges into a water body oron land from industrial facilities/areas, waste watertreatment plants, unscientific waste disposal, andleakage/spillages from hazardous waste managementfacilities
Unwarranted chemical spills into a water body /onground
Surface runoff or erosion of contaminated soil fromwaste dumps, chemical storage facilities, open mines andmine waste piles on land
Environmental Management Group, National Productivity Council
Direct pipeline or outfall discharges into a water body oron land from industrial facilities/areas, waste watertreatment plants, unscientific waste disposal, andleakage/spillages from hazardous waste managementfacilities
Unwarranted chemical spills into a water body /onground
Surface runoff or erosion of contaminated soil fromwaste dumps, chemical storage facilities, open mines andmine waste piles on land
Potential Sources of Contaminants
Air emissions from incinerators, pesticide applications,or other sources that may be transferred to a water bodythrough precipitation or direct deposition on land
Upwelling or seepage of contaminated ground water ornon-aqueous phase liquids (NAPL)
Direct disposal from docked and dry-docked ships, orrelease of contaminants from in-water structures andover-water structures or ship maintenance facilities
Environmental Management Group, National Productivity Council
Air emissions from incinerators, pesticide applications,or other sources that may be transferred to a water bodythrough precipitation or direct deposition on land
Upwelling or seepage of contaminated ground water ornon-aqueous phase liquids (NAPL)
Direct disposal from docked and dry-docked ships, orrelease of contaminants from in-water structures andover-water structures or ship maintenance facilities
Illegal or indiscriminate dumping of hazardous &toxic wastes
Contamination of soil, ground & surface water
Health hazard to general public & animals
Environmental protection & resource conservation
Risk based Remediation will address
Environmental Management Group, National Productivity Council
Illegal or indiscriminate dumping of hazardous &toxic wastes
Contamination of soil, ground & surface water
Health hazard to general public & animals
Environmental protection & resource conservation
Risk Assessment Risk assessment is considered a very useful tool in environmental
policy because it promises a rational and objective basis forpriority setting and decision making.
Risk assessment methodologies for contaminated land need to bebuilt on a sound scientific basis
The use of risk assessment as a formal component ofenvironmental policy has become important.
The main aim of integrating risk assessment with remediation ofcontaminated sites is to help in setting priorities for environmentalprotection in an objective and scientific way.
Environmental Management Group, National Productivity Council
Risk assessment is considered a very useful tool in environmentalpolicy because it promises a rational and objective basis forpriority setting and decision making.
Risk assessment methodologies for contaminated land need to bebuilt on a sound scientific basis
The use of risk assessment as a formal component ofenvironmental policy has become important.
The main aim of integrating risk assessment with remediation ofcontaminated sites is to help in setting priorities for environmentalprotection in an objective and scientific way.
Risk Management PrinciplesEarly and immediate control of contaminants’ sources
Involve the community early and often
Coordinate with states, local governments, communities,and local active NGOs
Develop a conceptual simulation model that considerscontaminant flow rate and direction
Use an iterative approach in a risk-based framework
Carefully evaluate the assumptions and uncertaintiesassociated with site characterization and hydro-gelogy.
Environmental Management Group, National Productivity Council
Early and immediate control of contaminants’ sources
Involve the community early and often
Coordinate with states, local governments, communities,and local active NGOs
Develop a conceptual simulation model that considerscontaminant flow rate and direction
Use an iterative approach in a risk-based framework
Carefully evaluate the assumptions and uncertaintiesassociated with site characterization and hydro-gelogy.
Risk Management Principles Select site-specific, project-specific, and sediment-
specific risk management approaches that will achieverisk-based goals
Ensure that sediment cleanup levels are clearly tied torisk management goals
Maximize the effectiveness of institutional controls andrecognize their limitations
Design remedies to minimize short-term risks whileachieving long-term environment protection
Monitor soil/groundwater remediation process to assessand document effectiveness
Environmental Management Group, National Productivity Council
Select site-specific, project-specific, and sediment-specific risk management approaches that will achieverisk-based goals
Ensure that sediment cleanup levels are clearly tied torisk management goals
Maximize the effectiveness of institutional controls andrecognize their limitations
Design remedies to minimize short-term risks whileachieving long-term environment protection
Monitor soil/groundwater remediation process to assessand document effectiveness
Risk Assessmentthree distinct stages in the procedure
Hazard identification: identification of hazards thatmay cause adverse effects.
Exposure analysis: estimating the intensity, frequencyand duration of exposure to the hazardous agents inquestion. Depending on context, this can includetransport and fate of contaminants in groundwater andsurface waters.
Risk characterization: evaluation and conclusions thatresult from the previous steps.
Environmental Management Group, National Productivity Council
Hazard identification: identification of hazards thatmay cause adverse effects.
Exposure analysis: estimating the intensity, frequencyand duration of exposure to the hazardous agents inquestion. Depending on context, this can includetransport and fate of contaminants in groundwater andsurface waters.
Risk characterization: evaluation and conclusions thatresult from the previous steps.
Framework for Risk Management
Environmental Management Group, National Productivity Council
Major Steps for Site Remediation
Mapping of contaminated sites to be considered for
remediation.
Investigation & risk based assessment of
contaminated sites.
Development of Action Plan including technologies
and resources for remediation
Environmental Management Group, National Productivity Council
Mapping of contaminated sites to be considered for
remediation.
Investigation & risk based assessment of
contaminated sites.
Development of Action Plan including technologies
and resources for remediation
Remedial Approaches for Contaminated Site
In-situ Approaches
Ex-situ Approaches
Environmental Management Group, National Productivity Council
In-situ Approaches
Ex-situ Approaches
In-situ ApproachesIn-situ Capping:
Single-layer granular caps
Multi-layer granular caps
Combination granular/geotextile caps
Monitored Natural Recovery:
Physical isolation of contaminated sites
Biological transformation
Hybrid Approaches:
Thin layer placement of sand or other material to enhancerecovery via natural remediation
Environmental Management Group, National Productivity Council
In-situ Capping:
Single-layer granular caps
Multi-layer granular caps
Combination granular/geotextile caps
Monitored Natural Recovery:
Physical isolation of contaminated sites
Biological transformation
Hybrid Approaches:
Thin layer placement of sand or other material to enhancerecovery via natural remediation
Ex-situ Approaches
Contaminants’ diversion or dewatering of site
Pumping out contaminated ground water for treatment
Excavation of contaminated sediment and transport forprocessing
Treatment of excavated contaminants at nearbyhazardous waste management facility
Disposal of contaminated sediments or residues insecured landfill.
Environmental Management Group, National Productivity Council
Contaminants’ diversion or dewatering of site
Pumping out contaminated ground water for treatment
Excavation of contaminated sediment and transport forprocessing
Treatment of excavated contaminants at nearbyhazardous waste management facility
Disposal of contaminated sediments or residues insecured landfill.
Type of soil remediationtechnology
Process
Soil Washing Soil washing uses liquids (usually water, occasionally combinedwith solvents) and mechanical processes to scrub soils. Solvents areselected on the basis of their ability to solubilize specificcontaminants, and on their environmental and health effects
Soil Vapor Extraction Soil vapor extraction (SVE), also known as soil venting or vacuumextraction, is an accepted, recognized, and cost effective technologyfor remediating unsaturated soils contaminated with VOCs andSVOCs. Air ‘blowers’ are often used to aid the evaporation process(Fig. 1). Vacuums are applied through the wells near the source ofcontamination to evaporate the volatile constituents of thecontaminated mass which are subsequently withdrawn through anextraction well. Extracted vapors are then treated (commonly withcarbon adsorption) before being released into the atmosphere(USEPA, 1995a).
Type of Soil Remediation Technology
Environmental Management Group, National Productivity Council
Soil Vapor Extraction Soil vapor extraction (SVE), also known as soil venting or vacuumextraction, is an accepted, recognized, and cost effective technologyfor remediating unsaturated soils contaminated with VOCs andSVOCs. Air ‘blowers’ are often used to aid the evaporation process(Fig. 1). Vacuums are applied through the wells near the source ofcontamination to evaporate the volatile constituents of thecontaminated mass which are subsequently withdrawn through anextraction well. Extracted vapors are then treated (commonly withcarbon adsorption) before being released into the atmosphere(USEPA, 1995a).
Type of Soil RemediationTechnology
Process
Land Farming Land farming is an above-ground remediation technology thatreduces the concentration of petroleum constituents 4present in soilsthrough processes associated with bioremediation.
Soil Flushing In situ soil flushing is an innovative remediation technology that‘floods’ contaminated soils with a solution that moves thecontaminants to an area where they can be removed (USEPA,1996e; Otterpohl, 2002; Logsdon et al., 2002; Di Palma et al.,2003). Soil flushing is accomplished by passing an extraction fluidthrough in-place soils using an injection or infiltration process (Fig.2). Contaminated groundwater and extraction fluids are capturedand pumped to the surface using standard groundwater extractionwells. Recovered groundwater and extraction fluids with theadsorbed contaminants may need treatment to meet the appropriatedischarge standards before being recycled or released to local,publicly owned, wastewater treatment works or receiving streams(FRTR, 1999h; RAAG, 2000; Otterpohl, 2002; Son et al., 2003).
Type of Soil Remediation Technology
Environmental Management Group, National Productivity Council
In situ soil flushing is an innovative remediation technology that‘floods’ contaminated soils with a solution that moves thecontaminants to an area where they can be removed (USEPA,1996e; Otterpohl, 2002; Logsdon et al., 2002; Di Palma et al.,2003). Soil flushing is accomplished by passing an extraction fluidthrough in-place soils using an injection or infiltration process (Fig.2). Contaminated groundwater and extraction fluids are capturedand pumped to the surface using standard groundwater extractionwells. Recovered groundwater and extraction fluids with theadsorbed contaminants may need treatment to meet the appropriatedischarge standards before being recycled or released to local,publicly owned, wastewater treatment works or receiving streams(FRTR, 1999h; RAAG, 2000; Otterpohl, 2002; Son et al., 2003).
HAZARDOUS WASTE MANAGEMENT- About NPC’s Experience
HAZARDOUS WASTE MANAGEMENT- About NPC’s Experience
Inventorisation & Characterisation in several states More than 30 EIA studies for site identification Comprehensive Hazardous Waste Management
System for large industrial houses - IPCL, RIL,Godrej, Sterlite etc.
More than 20 hazardous waste SLFs Designed &developed
Old Hazardous waste dump sites investigated forRemediated in the State of UP, Rajasthan, Gujarat,West Bengal & Orissa .
Environmental Management Group, National Productivity Council
Inventorisation & Characterisation in several states More than 30 EIA studies for site identification Comprehensive Hazardous Waste Management
System for large industrial houses - IPCL, RIL,Godrej, Sterlite etc.
More than 20 hazardous waste SLFs Designed &developed
Old Hazardous waste dump sites investigated forRemediated in the State of UP, Rajasthan, Gujarat,West Bengal & Orissa .
“Investigation & Remediation of Old HazardousWaste Dump Sites” in :
“Investigation & Remediation of Old HazardousWaste Dump Sites” in :
Bichri, Udaipur (Rajasthan); for MoEF, Govt. of India
Ahmedabad (Gujarat); for Ahmedabad Municipal Corporation
Vadodara (Gujarat); for M/s. Gujarat Alkalies & ChemicalsLtd. (GACL)
Vadodara (Gujarat); for Gujarat Pollution Control Board(GPCB)
West Bengal; for West Bengal Pollution Control Board(WBPCB)
Orissa; for Orissa State Pollution Control Board (OSPCB)
Environmental Management Group, National Productivity Council
Bichri, Udaipur (Rajasthan); for MoEF, Govt. of India
Ahmedabad (Gujarat); for Ahmedabad Municipal Corporation
Vadodara (Gujarat); for M/s. Gujarat Alkalies & ChemicalsLtd. (GACL)
Vadodara (Gujarat); for Gujarat Pollution Control Board(GPCB)
West Bengal; for West Bengal Pollution Control Board(WBPCB)
Orissa; for Orissa State Pollution Control Board (OSPCB)
NPC’s Study On
Investigation of Identified HazardousWaste Dumpsites in Orissa & their
Remediation
Environmental Management Group, National Productivity Council
NPC’s Study On
Investigation of Identified HazardousWaste Dumpsites in Orissa & their
Remediation
Sites Location
M /s Jaysh ree C h em ica ls3 S ites (H g )
G AN JAM
M /s IN D A L3 S ites (F , C N )
SAM BALPU RAN G U L
M /s N A LC O3 S ites (F , C N )
TALCH AR
M AYU RBH AN J
M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )
RAU RKELA
K A LU N G A IN D U S .E S TA TE (C r)4 S ites
M /s Jaysh ree C h em ica ls3 S ites (H g )
G AN JAM
M /s IN D A L3 S ites (F , C N )
SAM BALPU RAN G U L
M /s N A LC O3 S ites (F , C N )
TALCH AR
M AYU RBH AN J
M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )
RAU RKELA
K A LU N G A IN D U S .E S TA TE (C r)4 S ites
Environmental Management Group, National Productivity Council
M /s Jaysh ree C h em ica ls3 S ites (H g )
G AN JAM
M /s IN D A L3 S ites (F , C N )
SAM BALPU RAN G U L
M /s N A LC O3 S ites (F , C N )
TALCH AR
M AYU RBH AN J
M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )
RAU RKELA
K A LU N G A IN D U S .E S TA TE (C r)4 S ites
M /s Jaysh ree C h em ica ls3 S ites (H g )
G AN JAM
M /s IN D A L3 S ites (F , C N )
SAM BALPU RAN G U L
M /s N A LC O3 S ites (F , C N )
TALCH AR
M AYU RBH AN J
M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )
RAU RKELA
K A LU N G A IN D U S .E S TA TE (C r)4 S ites
Sites Location – Ganjam, Orrisa [M/s Jayshree Chemicals Ltd. (JCL - I, II & II)]
Environmental Management Group, National Productivity Council
LAGOON No. 1
SIZE 28x23x3CAPPINGCOPMPLETED
Sites Description
Environmental Management Group, National Productivity Council
70
70
SITE JCL-II
SITE JCL-I
SITE JCL-III
JCL = M/s Jayshree Chemicals Ltd.
Background of Concerned Industry
At Ganjam, there are 3 hazardous waste dumpsites associated
with M/s Jayshree Chemicals Ltd. (JCL). Of total 3 identified
sites, two are being used for waste dumping and one is closed.
M/s JCL is engaged in production of sodium hydroxide using
mercury cell based technology since 1967. The unit started
with the production capacity of 10 TPD of NaOH and its
present production capacity is 65-70 TPD
Environmental Management Group, National Productivity Council
At Ganjam, there are 3 hazardous waste dumpsites associated
with M/s Jayshree Chemicals Ltd. (JCL). Of total 3 identified
sites, two are being used for waste dumping and one is closed.
M/s JCL is engaged in production of sodium hydroxide using
mercury cell based technology since 1967. The unit started
with the production capacity of 10 TPD of NaOH and its
present production capacity is 65-70 TPD
Description of sites at GanjamSite
CodeLocation Type of Waste Size & Quantity of
wastePollutantofConcern
Status ofsite
Remarks
SiteJCL I
Outside thepremises ofM/s JCL nearriverRushikulya
Brine sludgegeneratedduringtreatment ofbrine solutionwith BaCO3,Na2CO3, NaOH
Area – 3500 sq mAvg. Depth – 1 m3500 m3 i.e. 5000MT (consideringbulk density of 1.5T/m3)
Hg Presentlysite isclosed, andwas in usefor 22 year(1967-1989)
There is difference of 30000 MTin the generated waste &existing waste, which mayindicate that part brine sludgeduring that period sludge mayfind it way to river.
SiteJCL II
Insidepremises ofM/s JCL atwaste disposaldesignatedarea in 9 no.LDPE linedlagoons
Brine sludgegeneratedduringtreatment ofbrine solutionwith BaCO3,Na2CO3, NaOH
Area – 12000 sq mAvg. Depth – 2-3 m30000 m3 i.e. 33000MT (consideringbulk density of 1.2T/m3)
Hg The site isuse forbrinesludgedumpingfor 15 yearssince 1989
Waste lying at site is nearlysame to the estimated wastequantity of 35000 MT which hasbeen generated during 1989-2004
Environmental Management Group, National Productivity Council
SiteJCL II
Insidepremises ofM/s JCL atwaste disposaldesignatedarea in 9 no.LDPE linedlagoons
Brine sludgegeneratedduringtreatment ofbrine solutionwith BaCO3,Na2CO3, NaOH
Area – 12000 sq mAvg. Depth – 2-3 m30000 m3 i.e. 33000MT (consideringbulk density of 1.2T/m3)
The site isuse forbrinesludgedumpingfor 15 yearssince 1989
Waste lying at site is nearlysame to the estimated wastequantity of 35000 MT which hasbeen generated during 1989-2004
SiteJCL III
Outside thepremises ofM/s JCL nearriverRushikulya
Hypo sludgefrom thetreatment ofchlorine
Area – 8000 sq mAvg. Depth – 2 m15000 m3 i.e. 18000MT (consideringbulk density of 1.2T/m3)
Hg The site isin use forhyposludgedumpingfor 37 yearssince 1967
There is difference of 13200 MTin the generated waste &existing waste, which mayindicate that part hypo sludgemay have gone to river duringhigh tides.
Site Features (Site JCL-I)
Site having brine sludge (brine sludge is 0.108 T/T of NaOH
(25 % moisture) , located near river Rushikulya
Site presently closed, was in use during year 1967-1989
No bottom, top or side liner provided
Covered with native soil 1 ft thick
Waste quantity around 5000 MT much less than theexpected waste of 35000 MT during 1967-1989
Environmental Management Group, National Productivity Council
Site having brine sludge (brine sludge is 0.108 T/T of NaOH
(25 % moisture) , located near river Rushikulya
Site presently closed, was in use during year 1967-1989
No bottom, top or side liner provided
Covered with native soil 1 ft thick
Waste quantity around 5000 MT much less than theexpected waste of 35000 MT during 1967-1989
Site JCL – II: Freshly Generated Brine Sludge Disposed in Active Ponds
Environmental Management Group, National Productivity Council
Site JCL – II: Freshly Generated Brine Sludge Disposed in Active Ponds
Site JCL – II: Photograph Showing Active as well as Close Brine Sludge
Active BrineSludge Pond
Brine Sludge Pond coveredLDPE sheet & soil
Site JCL – II: H2SO4 being dumped on Brine Sludge for so called treatment
Environmental Management Group, National Productivity Council
Site JCL – II: H2SO4 being dumped on Brine Sludge for so called treatment
Site JCL-III: HypoSludge being disposedon the bank of RiverRushikulya
Site JCL – III: Heaps of Hypo Sludge on the Bank of River
Environmental Management Group, National Productivity Council
Site JCL – III: Heaps of Hypo Sludge on the Bank of River
Site JCL-III: WasteSample Collectionfrom Hypo Sludge
Site Features (Site JCL-II)
Located inside the premises of M/s JCL having 9 brinesludge ponds, 8 ponds already filled, 6 cover with coverliner
Site presently in use since year 1989
Bottom liner: Concrete Base, Soil, LDPE Sheet (0.3 mm)
Cover liner: Soil, LDPE Sheet (0.3 mm), Soil cover
Waste quantity around 33000 MT, nearly matchesexpected waste generated
Environmental Management Group, National Productivity Council
Located inside the premises of M/s JCL having 9 brinesludge ponds, 8 ponds already filled, 6 cover with coverliner
Site presently in use since year 1989
Bottom liner: Concrete Base, Soil, LDPE Sheet (0.3 mm)
Cover liner: Soil, LDPE Sheet (0.3 mm), Soil cover
Waste quantity around 33000 MT, nearly matchesexpected waste generated
Site Features (Site JCL-III)
Site having hypo sludge (hypo sludge is 0.048 T/T of NaOH
(25 % moisture)) located on the bank of river Rushikulya
Site presently in use since year 1969
No bottom, top or side liner provided
Waste expected to find way to river (& sea) during hightide
Waste quantity around 18000 MT, about nearly 13000MT less than expected waste generated
Environmental Management Group, National Productivity Council
Site having hypo sludge (hypo sludge is 0.048 T/T of NaOH
(25 % moisture)) located on the bank of river Rushikulya
Site presently in use since year 1969
No bottom, top or side liner provided
Waste expected to find way to river (& sea) during hightide
Waste quantity around 18000 MT, about nearly 13000MT less than expected waste generated
Methodology
• Information collection Investigation of waste dumpsites
– Collection of information, concerned industries,ground water board
– Preparation of Schematic Map of site
– Physical investigation of dump sites
– Assessment for ‘Active’ or ‘Passive’ Sites
Environmental Management Group, National Productivity Council
• Information collection Investigation of waste dumpsites
– Collection of information, concerned industries,ground water board
– Preparation of Schematic Map of site
– Physical investigation of dump sites
– Assessment for ‘Active’ or ‘Passive’ Sites
• Quantification of waste dumped– Total quantity of hazardous waste dumped at site is
estimated and compared with production data availablefrom concerned Industry such as
1. Production capacity of unit
2. Information provided by units
3. SWGF
4. Operational period of unit
• Monitoring & Laboratory Analysis– Representative waste, soil & water samples collected in
two phases & analysed at laboratories
Methodology
Environmental Management Group, National Productivity Council
• Quantification of waste dumped– Total quantity of hazardous waste dumped at site is
estimated and compared with production data availablefrom concerned Industry such as
1. Production capacity of unit
2. Information provided by units
3. SWGF
4. Operational period of unit
• Monitoring & Laboratory Analysis– Representative waste, soil & water samples collected in
two phases & analysed at laboratories
• Hazard Potential & Rehabilitation Plan– Assessment of hazard potential & extent of contamination to
natural resources (soil & groundwater) based on laboratoryanalysis results of soil & groundwater samples
– Preparation of remediation/rehabilitation plan based on
• information collected,
• on-site observations,
• soil & groundwater investigations &
• regulatory requirements
Methodology
Environmental Management Group, National Productivity Council
• Hazard Potential & Rehabilitation Plan– Assessment of hazard potential & extent of contamination to
natural resources (soil & groundwater) based on laboratoryanalysis results of soil & groundwater samples
– Preparation of remediation/rehabilitation plan based on
• information collected,
• on-site observations,
• soil & groundwater investigations &
• regulatory requirements
Waste Sampling Details
Sample Code Location
SW5 Lagoon-5 at depth of 1 feet
SW6 Lagoon-5 at depth of 3-3.5 feet
Environmental Management Group, National Productivity Council
SW6 Lagoon-5 at depth of 3-3.5 feet
SW7 Lagoon-1 at depth of 1 feet
SW8 Lagoon - 9 at depth of 1 feet
Analysis has been carried out in 1:10 eluate to determinewater soluble concentration
Waste Samples
Soil Samples
pH 9.9Hg 33.6 mg/kgpH 9.3
Hg 3.72 mg/kg
pH 6.2Hg 10 mg/kg
Site Investigation(Waste Analysis Site JCL-I & III)
Environmental Management Group, National Productivity Council
pH 13.04Hg 67.6 mg/kg
pH 13.1Hg 70.5 mg/kg
pH 13.02Hg 24 mg/kg
pH 13.02Hg 82 mg/kg
pH 13.07Hg 30 mg/kg
pH 13.06Hg 4.2 mg/kg
pH 6.1Hg BDL
pH 6.2Hg 10 mg/kg
HWM Rules 2016 SCHEDULE II
Class Constituents Concentrationin mg/l
A7 Mercury 0.2
Site Investigation(Waste Analysis Site JCL-II)
LAGOON No. 1
SIZE 28x23x3
pH 8.7Hg 2000 mg/kg
pH 7.7Hg 966 mg/kg
pH 8.6Hg 1730 mg/kg
pH 6.9Hg 15 mg/kg
pH 4.0Hg 65 mg/kg
pH 12.9Hg 29.9 mg/kg
Environmental Management Group, National Productivity Council
pH 8.7Hg 2000 mg/kg
pH 10.7Hg 440 mg/kg
pH 6.4Hg 12 mg/kg
Waste Samples
Soil Samples
Site Investigation (Groundwater Analysis)
pH 6.9Hg BDL
pH 6.6Hg BDL
pH 6.9Hg BDL
pH 7.7Hg BDL
pH 7.4Hg BDL
pH 7.6Hg BDL
pH 8.3Hg BDL
pH 7.1Hg BDL
Environmental Management Group, National Productivity Council
pH 6.9Hg BDL
pH 3.3Hg BDL
pH 6.9Hg BDL
pH 5.7Hg BDL
pH 7.3Hg BDL
pH 7.7Hg BDL
Groundwater Samples
Surface water Samples
Hazard Potential RatingSl.No.
Criteria Min. toMax.Score
Site Scores
Site JCL-ISite JCL-
IISite JCL-III
1. Locational 25-125 94 91 103
2. Environmental 50-250 120 170 120
3. Managerial 25-125 125 107 50
Environmental Management Group, National Productivity Council
3. Managerial 25-125 125 107 50
Total 100-500 339 368 273
Therefore, Comparative Hazard Potential Rating of sites
Site JCL-II (Brine Sludge), Maximum
Site JCL-I (Brine Sludge), Moderate
Site JCL-III (Hypo Sludge), Least
Remediation Plan (site specific)
to mitigate the adverse impacts on environment
(water & soil)
to minimize further contamination
to reduce hazard potential
to minimize health hazard to near by residents
to meet existing hazardous waste rules to the extent
possible
cost economics
With Objective
Environmental Management Group, National Productivity Council
to mitigate the adverse impacts on environment
(water & soil)
to minimize further contamination
to reduce hazard potential
to minimize health hazard to near by residents
to meet existing hazardous waste rules to the extent
possible
cost economics
Remediation Plan (Site JCL-I)
Excavate entire waste (around 1m) & contaminated
soil (around 0.3 m)
Dispose waste & soil to Site
Fill excavated area with native soil followed by
vegetation cover
Environmental Management Group, National Productivity Council
Excavate entire waste (around 1m) & contaminated
soil (around 0.3 m)
Dispose waste & soil to Site
Fill excavated area with native soil followed by
vegetation cover
Remediation Plan (Site JCL-II)
Case-1: Capping of site in-situ with cover liner
Case-2: Capping of site in-situ with cover liner& cut-off walls
Case-3: Disposal of entire waste/contaminatedsoil in newly developed SLF
Three options :
Environmental Management Group, National Productivity Council
Case-1: Capping of site in-situ with cover liner
Case-2: Capping of site in-situ with cover liner& cut-off walls
Case-3: Disposal of entire waste/contaminatedsoil in newly developed SLF
LAGOON No. 1
SIZE 28x23x3CAPPING COPMPLETED
70
A
Laying ofCover Liner
Capping of Site In-situ with cut-off walls
Environmental Management Group, National Productivity Council
100WASTE FROM SITEJCL-I
A
Place the cut-off Wall
POND-2 POND-5 POND-6 POND-7
GROUNDLEVEL
SOIL EMBANKMENT1 M HEIGHT
WASTE FILLING UPTO 3 M HT AT
MIDDLESOILEMBANKMENT
1 M HEIGHTTOP COVBER
LINER
SECTION AT A-A
CUT-OFF WALLSUPTO IMPERMEVIOUSLAYER (15-20 M)
Capping of Site In-situ cut-off walls
Environmental Management Group, National Productivity Council
DETAILS OF EMBANKMENT AND COVER LINER
COVERLINER
1 M
COMPACTEDWASTE
OUTERSLOPE 1:2.5
INNERSLOPE 1:2
ANCHORTRENCH
1 M
5.5 M
COMPACTED CLAY 60 CMTHICK
HDPE LINER 1.5 MM
DRAINAGE GEONET WITHONE SIDE GEOTEXT
VEGITAIVE SOIL 0F 60 CM
A
A
COMPACTEDWASTE BODY
COMPACTED ANDGRADED SOILCOVER OF 60 CM
Remediation PlanRIVER SIDE A
Environmental Management Group, National Productivity Council
A
SIDE SLOPEAT 1:5
SECTION ALONG A-A
SLOPE OFCOVER AT 5%SIDE SLOPE
AT 1:5
FILLED UP ANDCOMPACTEDHYPO SLUDGE
RIVERSIDE
1 M HT
1 MDEPTH
AVERAGEGROUND LEVEL
TOP COVERDETAILS
COMPACTEDWASTE BODY
DETAILS OF TOP COVER
PLAN
Item Description of work Quantity Unit Unit Price(Rs)
Total(Rs in lakhs)
1 Excavation of brine sludge of1 m average depth and
4500 M3 100 4.5
Cost Estimates (Site JCL-I)
Environmental Management Group, National Productivity Council
1 Excavation of brine sludge of1 m average depth andtransportation to the site -II forcapping.
4500 M3 100 4.5
2 Filling up with borrow soil 4500 M3 250 11.25
Total 15.75
Cost Estimates (Site JCL-II)
Item Description of work Quantity Unit UnitPrice(Rs)
Total(Rs in lakhs)
1 Excavation of hypo sludgefrom cell-1, 7 & 8 m averagedepth and filling up in thecapping area
8000 M3 80 6.4
2 Construction of side 975 M3 250 2.5
CASE-1 : CAPPING OF WASTE
Environmental Management Group, National Productivity Council
2 Construction of sideembankment of 1 m height
975 M3 250 2.5
3 Installation of compactclay layer
1920 M3 250 4.8
4 Installation of 1.5 mm thickHDPE liner
6000 M2 300 18.0
5 Drainage geonet with on sidegeotextile
7000 M2 250 17.5
6 Installation of top vegetativesoil layer of 0.6 m thickness
3200 M3 200 6.4
TOTAL 55.6
CASE-2 : CAPPING OF WASTE WITH CUT-OFF WALLS
S.no. Particulars Cost (Rs. in lakhs)
1. Capping of waste 55.6
2. Putting cut-off walls 15.2
Total 70.8
CASE-3 : DISPOSAL OF WASTE IN NEWLY BUILD LANDFILL SITE or atCSLF
Environmental Management Group, National Productivity Council
CASE-3 : DISPOSAL OF WASTE IN NEWLY BUILD LANDFILL SITE or atCSLF
S.no. Particulars Cost (Rs. in lakhs)
1. Development of landfill 105.0
2. Covering of landfill 70.0
3. Disposal of waste into CSLF (@ Rs 700/-) 245.0
Total 350.0
Cost Estimates (Site JCL-III)
Item Description of work Quantity Unit UnitPrice(Rs)
Total(Rs in lakhs)
1 Excavation of the side hypeembankment and filling up the3 ponds and compacting and
7200 M3 60 4.32
Environmental Management Group, National Productivity Council
3 ponds and compacting andgrading of the top at requiredslope.
2 Soil cover of 0.6 m thickabove the hypo waste.
4400 M3 250 11.0
TOTAL 15.32
Thank You
Environmental Management Group, National Productivity Council
Thank You