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Risk Assessment and Disaster Management of Contaminated HW Sites and Methods of Remediation M. J. PERVEZ Group Head & Director (Environment) NATIONAL PRODUCTIVITY COUNCIL (Under Ministry of Commerce & Industry, Govt. of India) Utpadakta Bhavan, 5-6 Institutional Area, Lodi Road, New Delhi 110 003

Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

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Page 1: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Risk Assessment and DisasterManagement of Contaminated HWSites and Methods of Remediation

M. J. PERVEZGroup Head & Director (Environment)

NATIONAL PRODUCTIVITY COUNCIL(Under Ministry of Commerce & Industry, Govt. of India)Utpadakta Bhavan, 5-6 Institutional Area, Lodi Road,

New Delhi – 110 003

Risk Assessment and DisasterManagement of Contaminated HWSites and Methods of Remediation

M. J. PERVEZGroup Head & Director (Environment)

NATIONAL PRODUCTIVITY COUNCIL(Under Ministry of Commerce & Industry, Govt. of India)Utpadakta Bhavan, 5-6 Institutional Area, Lodi Road,

New Delhi – 110 003

Page 2: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Contaminated HW Sites

An area of land in which the soil or underlyinggroundwater or sediment contains HazardousWaste or substance in an amount or concentrationthat exceeds environmental quality standards.

A site is contaminated if it is unsuitable forspecific uses of land, water and settlement

Environmental Management Group, National Productivity Council

An area of land in which the soil or underlyinggroundwater or sediment contains HazardousWaste or substance in an amount or concentrationthat exceeds environmental quality standards.

A site is contaminated if it is unsuitable forspecific uses of land, water and settlement

Page 3: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Potential Sources of Contaminants

Direct pipeline or outfall discharges into a water body oron land from industrial facilities/areas, waste watertreatment plants, unscientific waste disposal, andleakage/spillages from hazardous waste managementfacilities

Unwarranted chemical spills into a water body /onground

Surface runoff or erosion of contaminated soil fromwaste dumps, chemical storage facilities, open mines andmine waste piles on land

Environmental Management Group, National Productivity Council

Direct pipeline or outfall discharges into a water body oron land from industrial facilities/areas, waste watertreatment plants, unscientific waste disposal, andleakage/spillages from hazardous waste managementfacilities

Unwarranted chemical spills into a water body /onground

Surface runoff or erosion of contaminated soil fromwaste dumps, chemical storage facilities, open mines andmine waste piles on land

Page 4: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Potential Sources of Contaminants

Air emissions from incinerators, pesticide applications,or other sources that may be transferred to a water bodythrough precipitation or direct deposition on land

Upwelling or seepage of contaminated ground water ornon-aqueous phase liquids (NAPL)

Direct disposal from docked and dry-docked ships, orrelease of contaminants from in-water structures andover-water structures or ship maintenance facilities

Environmental Management Group, National Productivity Council

Air emissions from incinerators, pesticide applications,or other sources that may be transferred to a water bodythrough precipitation or direct deposition on land

Upwelling or seepage of contaminated ground water ornon-aqueous phase liquids (NAPL)

Direct disposal from docked and dry-docked ships, orrelease of contaminants from in-water structures andover-water structures or ship maintenance facilities

Page 5: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Illegal or indiscriminate dumping of hazardous &toxic wastes

Contamination of soil, ground & surface water

Health hazard to general public & animals

Environmental protection & resource conservation

Risk based Remediation will address

Environmental Management Group, National Productivity Council

Illegal or indiscriminate dumping of hazardous &toxic wastes

Contamination of soil, ground & surface water

Health hazard to general public & animals

Environmental protection & resource conservation

Page 6: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Risk Assessment Risk assessment is considered a very useful tool in environmental

policy because it promises a rational and objective basis forpriority setting and decision making.

Risk assessment methodologies for contaminated land need to bebuilt on a sound scientific basis

The use of risk assessment as a formal component ofenvironmental policy has become important.

The main aim of integrating risk assessment with remediation ofcontaminated sites is to help in setting priorities for environmentalprotection in an objective and scientific way.

Environmental Management Group, National Productivity Council

Risk assessment is considered a very useful tool in environmentalpolicy because it promises a rational and objective basis forpriority setting and decision making.

Risk assessment methodologies for contaminated land need to bebuilt on a sound scientific basis

The use of risk assessment as a formal component ofenvironmental policy has become important.

The main aim of integrating risk assessment with remediation ofcontaminated sites is to help in setting priorities for environmentalprotection in an objective and scientific way.

Page 7: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Risk Management PrinciplesEarly and immediate control of contaminants’ sources

Involve the community early and often

Coordinate with states, local governments, communities,and local active NGOs

Develop a conceptual simulation model that considerscontaminant flow rate and direction

Use an iterative approach in a risk-based framework

Carefully evaluate the assumptions and uncertaintiesassociated with site characterization and hydro-gelogy.

Environmental Management Group, National Productivity Council

Early and immediate control of contaminants’ sources

Involve the community early and often

Coordinate with states, local governments, communities,and local active NGOs

Develop a conceptual simulation model that considerscontaminant flow rate and direction

Use an iterative approach in a risk-based framework

Carefully evaluate the assumptions and uncertaintiesassociated with site characterization and hydro-gelogy.

Page 8: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Risk Management Principles Select site-specific, project-specific, and sediment-

specific risk management approaches that will achieverisk-based goals

Ensure that sediment cleanup levels are clearly tied torisk management goals

Maximize the effectiveness of institutional controls andrecognize their limitations

Design remedies to minimize short-term risks whileachieving long-term environment protection

Monitor soil/groundwater remediation process to assessand document effectiveness

Environmental Management Group, National Productivity Council

Select site-specific, project-specific, and sediment-specific risk management approaches that will achieverisk-based goals

Ensure that sediment cleanup levels are clearly tied torisk management goals

Maximize the effectiveness of institutional controls andrecognize their limitations

Design remedies to minimize short-term risks whileachieving long-term environment protection

Monitor soil/groundwater remediation process to assessand document effectiveness

Page 9: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Risk Assessmentthree distinct stages in the procedure

Hazard identification: identification of hazards thatmay cause adverse effects.

Exposure analysis: estimating the intensity, frequencyand duration of exposure to the hazardous agents inquestion. Depending on context, this can includetransport and fate of contaminants in groundwater andsurface waters.

Risk characterization: evaluation and conclusions thatresult from the previous steps.

Environmental Management Group, National Productivity Council

Hazard identification: identification of hazards thatmay cause adverse effects.

Exposure analysis: estimating the intensity, frequencyand duration of exposure to the hazardous agents inquestion. Depending on context, this can includetransport and fate of contaminants in groundwater andsurface waters.

Risk characterization: evaluation and conclusions thatresult from the previous steps.

Page 10: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Framework for Risk Management

Environmental Management Group, National Productivity Council

Page 11: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Major Steps for Site Remediation

Mapping of contaminated sites to be considered for

remediation.

Investigation & risk based assessment of

contaminated sites.

Development of Action Plan including technologies

and resources for remediation

Environmental Management Group, National Productivity Council

Mapping of contaminated sites to be considered for

remediation.

Investigation & risk based assessment of

contaminated sites.

Development of Action Plan including technologies

and resources for remediation

Page 12: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Remedial Approaches for Contaminated Site

In-situ Approaches

Ex-situ Approaches

Environmental Management Group, National Productivity Council

In-situ Approaches

Ex-situ Approaches

Page 13: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

In-situ ApproachesIn-situ Capping:

Single-layer granular caps

Multi-layer granular caps

Combination granular/geotextile caps

Monitored Natural Recovery:

Physical isolation of contaminated sites

Biological transformation

Hybrid Approaches:

Thin layer placement of sand or other material to enhancerecovery via natural remediation

Environmental Management Group, National Productivity Council

In-situ Capping:

Single-layer granular caps

Multi-layer granular caps

Combination granular/geotextile caps

Monitored Natural Recovery:

Physical isolation of contaminated sites

Biological transformation

Hybrid Approaches:

Thin layer placement of sand or other material to enhancerecovery via natural remediation

Page 14: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Ex-situ Approaches

Contaminants’ diversion or dewatering of site

Pumping out contaminated ground water for treatment

Excavation of contaminated sediment and transport forprocessing

Treatment of excavated contaminants at nearbyhazardous waste management facility

Disposal of contaminated sediments or residues insecured landfill.

Environmental Management Group, National Productivity Council

Contaminants’ diversion or dewatering of site

Pumping out contaminated ground water for treatment

Excavation of contaminated sediment and transport forprocessing

Treatment of excavated contaminants at nearbyhazardous waste management facility

Disposal of contaminated sediments or residues insecured landfill.

Page 15: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Type of soil remediationtechnology

Process

Soil Washing Soil washing uses liquids (usually water, occasionally combinedwith solvents) and mechanical processes to scrub soils. Solvents areselected on the basis of their ability to solubilize specificcontaminants, and on their environmental and health effects

Soil Vapor Extraction Soil vapor extraction (SVE), also known as soil venting or vacuumextraction, is an accepted, recognized, and cost effective technologyfor remediating unsaturated soils contaminated with VOCs andSVOCs. Air ‘blowers’ are often used to aid the evaporation process(Fig. 1). Vacuums are applied through the wells near the source ofcontamination to evaporate the volatile constituents of thecontaminated mass which are subsequently withdrawn through anextraction well. Extracted vapors are then treated (commonly withcarbon adsorption) before being released into the atmosphere(USEPA, 1995a).

Type of Soil Remediation Technology

Environmental Management Group, National Productivity Council

Soil Vapor Extraction Soil vapor extraction (SVE), also known as soil venting or vacuumextraction, is an accepted, recognized, and cost effective technologyfor remediating unsaturated soils contaminated with VOCs andSVOCs. Air ‘blowers’ are often used to aid the evaporation process(Fig. 1). Vacuums are applied through the wells near the source ofcontamination to evaporate the volatile constituents of thecontaminated mass which are subsequently withdrawn through anextraction well. Extracted vapors are then treated (commonly withcarbon adsorption) before being released into the atmosphere(USEPA, 1995a).

Page 16: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Type of Soil RemediationTechnology

Process

Land Farming Land farming is an above-ground remediation technology thatreduces the concentration of petroleum constituents 4present in soilsthrough processes associated with bioremediation.

Soil Flushing In situ soil flushing is an innovative remediation technology that‘floods’ contaminated soils with a solution that moves thecontaminants to an area where they can be removed (USEPA,1996e; Otterpohl, 2002; Logsdon et al., 2002; Di Palma et al.,2003). Soil flushing is accomplished by passing an extraction fluidthrough in-place soils using an injection or infiltration process (Fig.2). Contaminated groundwater and extraction fluids are capturedand pumped to the surface using standard groundwater extractionwells. Recovered groundwater and extraction fluids with theadsorbed contaminants may need treatment to meet the appropriatedischarge standards before being recycled or released to local,publicly owned, wastewater treatment works or receiving streams(FRTR, 1999h; RAAG, 2000; Otterpohl, 2002; Son et al., 2003).

Type of Soil Remediation Technology

Environmental Management Group, National Productivity Council

In situ soil flushing is an innovative remediation technology that‘floods’ contaminated soils with a solution that moves thecontaminants to an area where they can be removed (USEPA,1996e; Otterpohl, 2002; Logsdon et al., 2002; Di Palma et al.,2003). Soil flushing is accomplished by passing an extraction fluidthrough in-place soils using an injection or infiltration process (Fig.2). Contaminated groundwater and extraction fluids are capturedand pumped to the surface using standard groundwater extractionwells. Recovered groundwater and extraction fluids with theadsorbed contaminants may need treatment to meet the appropriatedischarge standards before being recycled or released to local,publicly owned, wastewater treatment works or receiving streams(FRTR, 1999h; RAAG, 2000; Otterpohl, 2002; Son et al., 2003).

Page 17: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

HAZARDOUS WASTE MANAGEMENT- About NPC’s Experience

HAZARDOUS WASTE MANAGEMENT- About NPC’s Experience

Inventorisation & Characterisation in several states More than 30 EIA studies for site identification Comprehensive Hazardous Waste Management

System for large industrial houses - IPCL, RIL,Godrej, Sterlite etc.

More than 20 hazardous waste SLFs Designed &developed

Old Hazardous waste dump sites investigated forRemediated in the State of UP, Rajasthan, Gujarat,West Bengal & Orissa .

Environmental Management Group, National Productivity Council

Inventorisation & Characterisation in several states More than 30 EIA studies for site identification Comprehensive Hazardous Waste Management

System for large industrial houses - IPCL, RIL,Godrej, Sterlite etc.

More than 20 hazardous waste SLFs Designed &developed

Old Hazardous waste dump sites investigated forRemediated in the State of UP, Rajasthan, Gujarat,West Bengal & Orissa .

Page 18: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

“Investigation & Remediation of Old HazardousWaste Dump Sites” in :

“Investigation & Remediation of Old HazardousWaste Dump Sites” in :

Bichri, Udaipur (Rajasthan); for MoEF, Govt. of India

Ahmedabad (Gujarat); for Ahmedabad Municipal Corporation

Vadodara (Gujarat); for M/s. Gujarat Alkalies & ChemicalsLtd. (GACL)

Vadodara (Gujarat); for Gujarat Pollution Control Board(GPCB)

West Bengal; for West Bengal Pollution Control Board(WBPCB)

Orissa; for Orissa State Pollution Control Board (OSPCB)

Environmental Management Group, National Productivity Council

Bichri, Udaipur (Rajasthan); for MoEF, Govt. of India

Ahmedabad (Gujarat); for Ahmedabad Municipal Corporation

Vadodara (Gujarat); for M/s. Gujarat Alkalies & ChemicalsLtd. (GACL)

Vadodara (Gujarat); for Gujarat Pollution Control Board(GPCB)

West Bengal; for West Bengal Pollution Control Board(WBPCB)

Orissa; for Orissa State Pollution Control Board (OSPCB)

Page 19: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

NPC’s Study On

Investigation of Identified HazardousWaste Dumpsites in Orissa & their

Remediation

Environmental Management Group, National Productivity Council

NPC’s Study On

Investigation of Identified HazardousWaste Dumpsites in Orissa & their

Remediation

Page 20: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Sites Location

M /s Jaysh ree C h em ica ls3 S ites (H g )

G AN JAM

M /s IN D A L3 S ites (F , C N )

SAM BALPU RAN G U L

M /s N A LC O3 S ites (F , C N )

TALCH AR

M AYU RBH AN J

M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )

RAU RKELA

K A LU N G A IN D U S .E S TA TE (C r)4 S ites

M /s Jaysh ree C h em ica ls3 S ites (H g )

G AN JAM

M /s IN D A L3 S ites (F , C N )

SAM BALPU RAN G U L

M /s N A LC O3 S ites (F , C N )

TALCH AR

M AYU RBH AN J

M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )

RAU RKELA

K A LU N G A IN D U S .E S TA TE (C r)4 S ites

Environmental Management Group, National Productivity Council

M /s Jaysh ree C h em ica ls3 S ites (H g )

G AN JAM

M /s IN D A L3 S ites (F , C N )

SAM BALPU RAN G U L

M /s N A LC O3 S ites (F , C N )

TALCH AR

M AYU RBH AN J

M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )

RAU RKELA

K A LU N G A IN D U S .E S TA TE (C r)4 S ites

M /s Jaysh ree C h em ica ls3 S ites (H g )

G AN JAM

M /s IN D A L3 S ites (F , C N )

SAM BALPU RAN G U L

M /s N A LC O3 S ites (F , C N )

TALCH AR

M AYU RBH AN J

M /s K erb & C ies Ltd .*5 S ites (C r)M /s E C FC L td *2 S ites (F , V a )

RAU RKELA

K A LU N G A IN D U S .E S TA TE (C r)4 S ites

Page 21: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Sites Location – Ganjam, Orrisa [M/s Jayshree Chemicals Ltd. (JCL - I, II & II)]

Environmental Management Group, National Productivity Council

Page 22: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

LAGOON No. 1

SIZE 28x23x3CAPPINGCOPMPLETED

Sites Description

Environmental Management Group, National Productivity Council

70

70

SITE JCL-II

SITE JCL-I

SITE JCL-III

JCL = M/s Jayshree Chemicals Ltd.

Page 23: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Background of Concerned Industry

At Ganjam, there are 3 hazardous waste dumpsites associated

with M/s Jayshree Chemicals Ltd. (JCL). Of total 3 identified

sites, two are being used for waste dumping and one is closed.

M/s JCL is engaged in production of sodium hydroxide using

mercury cell based technology since 1967. The unit started

with the production capacity of 10 TPD of NaOH and its

present production capacity is 65-70 TPD

Environmental Management Group, National Productivity Council

At Ganjam, there are 3 hazardous waste dumpsites associated

with M/s Jayshree Chemicals Ltd. (JCL). Of total 3 identified

sites, two are being used for waste dumping and one is closed.

M/s JCL is engaged in production of sodium hydroxide using

mercury cell based technology since 1967. The unit started

with the production capacity of 10 TPD of NaOH and its

present production capacity is 65-70 TPD

Page 24: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Description of sites at GanjamSite

CodeLocation Type of Waste Size & Quantity of

wastePollutantofConcern

Status ofsite

Remarks

SiteJCL I

Outside thepremises ofM/s JCL nearriverRushikulya

Brine sludgegeneratedduringtreatment ofbrine solutionwith BaCO3,Na2CO3, NaOH

Area – 3500 sq mAvg. Depth – 1 m3500 m3 i.e. 5000MT (consideringbulk density of 1.5T/m3)

Hg Presentlysite isclosed, andwas in usefor 22 year(1967-1989)

There is difference of 30000 MTin the generated waste &existing waste, which mayindicate that part brine sludgeduring that period sludge mayfind it way to river.

SiteJCL II

Insidepremises ofM/s JCL atwaste disposaldesignatedarea in 9 no.LDPE linedlagoons

Brine sludgegeneratedduringtreatment ofbrine solutionwith BaCO3,Na2CO3, NaOH

Area – 12000 sq mAvg. Depth – 2-3 m30000 m3 i.e. 33000MT (consideringbulk density of 1.2T/m3)

Hg The site isuse forbrinesludgedumpingfor 15 yearssince 1989

Waste lying at site is nearlysame to the estimated wastequantity of 35000 MT which hasbeen generated during 1989-2004

Environmental Management Group, National Productivity Council

SiteJCL II

Insidepremises ofM/s JCL atwaste disposaldesignatedarea in 9 no.LDPE linedlagoons

Brine sludgegeneratedduringtreatment ofbrine solutionwith BaCO3,Na2CO3, NaOH

Area – 12000 sq mAvg. Depth – 2-3 m30000 m3 i.e. 33000MT (consideringbulk density of 1.2T/m3)

The site isuse forbrinesludgedumpingfor 15 yearssince 1989

Waste lying at site is nearlysame to the estimated wastequantity of 35000 MT which hasbeen generated during 1989-2004

SiteJCL III

Outside thepremises ofM/s JCL nearriverRushikulya

Hypo sludgefrom thetreatment ofchlorine

Area – 8000 sq mAvg. Depth – 2 m15000 m3 i.e. 18000MT (consideringbulk density of 1.2T/m3)

Hg The site isin use forhyposludgedumpingfor 37 yearssince 1967

There is difference of 13200 MTin the generated waste &existing waste, which mayindicate that part hypo sludgemay have gone to river duringhigh tides.

Page 25: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site Features (Site JCL-I)

Site having brine sludge (brine sludge is 0.108 T/T of NaOH

(25 % moisture) , located near river Rushikulya

Site presently closed, was in use during year 1967-1989

No bottom, top or side liner provided

Covered with native soil 1 ft thick

Waste quantity around 5000 MT much less than theexpected waste of 35000 MT during 1967-1989

Environmental Management Group, National Productivity Council

Site having brine sludge (brine sludge is 0.108 T/T of NaOH

(25 % moisture) , located near river Rushikulya

Site presently closed, was in use during year 1967-1989

No bottom, top or side liner provided

Covered with native soil 1 ft thick

Waste quantity around 5000 MT much less than theexpected waste of 35000 MT during 1967-1989

Page 26: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site JCL – II: Freshly Generated Brine Sludge Disposed in Active Ponds

Environmental Management Group, National Productivity Council

Site JCL – II: Freshly Generated Brine Sludge Disposed in Active Ponds

Site JCL – II: Photograph Showing Active as well as Close Brine Sludge

Active BrineSludge Pond

Brine Sludge Pond coveredLDPE sheet & soil

Page 27: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site JCL – II: H2SO4 being dumped on Brine Sludge for so called treatment

Environmental Management Group, National Productivity Council

Site JCL – II: H2SO4 being dumped on Brine Sludge for so called treatment

Site JCL-III: HypoSludge being disposedon the bank of RiverRushikulya

Page 28: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site JCL – III: Heaps of Hypo Sludge on the Bank of River

Environmental Management Group, National Productivity Council

Site JCL – III: Heaps of Hypo Sludge on the Bank of River

Site JCL-III: WasteSample Collectionfrom Hypo Sludge

Page 29: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site Features (Site JCL-II)

Located inside the premises of M/s JCL having 9 brinesludge ponds, 8 ponds already filled, 6 cover with coverliner

Site presently in use since year 1989

Bottom liner: Concrete Base, Soil, LDPE Sheet (0.3 mm)

Cover liner: Soil, LDPE Sheet (0.3 mm), Soil cover

Waste quantity around 33000 MT, nearly matchesexpected waste generated

Environmental Management Group, National Productivity Council

Located inside the premises of M/s JCL having 9 brinesludge ponds, 8 ponds already filled, 6 cover with coverliner

Site presently in use since year 1989

Bottom liner: Concrete Base, Soil, LDPE Sheet (0.3 mm)

Cover liner: Soil, LDPE Sheet (0.3 mm), Soil cover

Waste quantity around 33000 MT, nearly matchesexpected waste generated

Page 30: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site Features (Site JCL-III)

Site having hypo sludge (hypo sludge is 0.048 T/T of NaOH

(25 % moisture)) located on the bank of river Rushikulya

Site presently in use since year 1969

No bottom, top or side liner provided

Waste expected to find way to river (& sea) during hightide

Waste quantity around 18000 MT, about nearly 13000MT less than expected waste generated

Environmental Management Group, National Productivity Council

Site having hypo sludge (hypo sludge is 0.048 T/T of NaOH

(25 % moisture)) located on the bank of river Rushikulya

Site presently in use since year 1969

No bottom, top or side liner provided

Waste expected to find way to river (& sea) during hightide

Waste quantity around 18000 MT, about nearly 13000MT less than expected waste generated

Page 31: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Methodology

• Information collection Investigation of waste dumpsites

– Collection of information, concerned industries,ground water board

– Preparation of Schematic Map of site

– Physical investigation of dump sites

– Assessment for ‘Active’ or ‘Passive’ Sites

Environmental Management Group, National Productivity Council

• Information collection Investigation of waste dumpsites

– Collection of information, concerned industries,ground water board

– Preparation of Schematic Map of site

– Physical investigation of dump sites

– Assessment for ‘Active’ or ‘Passive’ Sites

Page 32: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

• Quantification of waste dumped– Total quantity of hazardous waste dumped at site is

estimated and compared with production data availablefrom concerned Industry such as

1. Production capacity of unit

2. Information provided by units

3. SWGF

4. Operational period of unit

• Monitoring & Laboratory Analysis– Representative waste, soil & water samples collected in

two phases & analysed at laboratories

Methodology

Environmental Management Group, National Productivity Council

• Quantification of waste dumped– Total quantity of hazardous waste dumped at site is

estimated and compared with production data availablefrom concerned Industry such as

1. Production capacity of unit

2. Information provided by units

3. SWGF

4. Operational period of unit

• Monitoring & Laboratory Analysis– Representative waste, soil & water samples collected in

two phases & analysed at laboratories

Page 33: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

• Hazard Potential & Rehabilitation Plan– Assessment of hazard potential & extent of contamination to

natural resources (soil & groundwater) based on laboratoryanalysis results of soil & groundwater samples

– Preparation of remediation/rehabilitation plan based on

• information collected,

• on-site observations,

• soil & groundwater investigations &

• regulatory requirements

Methodology

Environmental Management Group, National Productivity Council

• Hazard Potential & Rehabilitation Plan– Assessment of hazard potential & extent of contamination to

natural resources (soil & groundwater) based on laboratoryanalysis results of soil & groundwater samples

– Preparation of remediation/rehabilitation plan based on

• information collected,

• on-site observations,

• soil & groundwater investigations &

• regulatory requirements

Page 34: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Waste Sampling Details

Sample Code Location

SW5 Lagoon-5 at depth of 1 feet

SW6 Lagoon-5 at depth of 3-3.5 feet

Environmental Management Group, National Productivity Council

SW6 Lagoon-5 at depth of 3-3.5 feet

SW7 Lagoon-1 at depth of 1 feet

SW8 Lagoon - 9 at depth of 1 feet

Analysis has been carried out in 1:10 eluate to determinewater soluble concentration

Page 35: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Waste Samples

Soil Samples

pH 9.9Hg 33.6 mg/kgpH 9.3

Hg 3.72 mg/kg

pH 6.2Hg 10 mg/kg

Site Investigation(Waste Analysis Site JCL-I & III)

Environmental Management Group, National Productivity Council

pH 13.04Hg 67.6 mg/kg

pH 13.1Hg 70.5 mg/kg

pH 13.02Hg 24 mg/kg

pH 13.02Hg 82 mg/kg

pH 13.07Hg 30 mg/kg

pH 13.06Hg 4.2 mg/kg

pH 6.1Hg BDL

pH 6.2Hg 10 mg/kg

HWM Rules 2016 SCHEDULE II

Class Constituents Concentrationin mg/l

A7 Mercury 0.2

Page 36: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site Investigation(Waste Analysis Site JCL-II)

LAGOON No. 1

SIZE 28x23x3

pH 8.7Hg 2000 mg/kg

pH 7.7Hg 966 mg/kg

pH 8.6Hg 1730 mg/kg

pH 6.9Hg 15 mg/kg

pH 4.0Hg 65 mg/kg

pH 12.9Hg 29.9 mg/kg

Environmental Management Group, National Productivity Council

pH 8.7Hg 2000 mg/kg

pH 10.7Hg 440 mg/kg

pH 6.4Hg 12 mg/kg

Waste Samples

Soil Samples

Page 37: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Site Investigation (Groundwater Analysis)

pH 6.9Hg BDL

pH 6.6Hg BDL

pH 6.9Hg BDL

pH 7.7Hg BDL

pH 7.4Hg BDL

pH 7.6Hg BDL

pH 8.3Hg BDL

pH 7.1Hg BDL

Environmental Management Group, National Productivity Council

pH 6.9Hg BDL

pH 3.3Hg BDL

pH 6.9Hg BDL

pH 5.7Hg BDL

pH 7.3Hg BDL

pH 7.7Hg BDL

Groundwater Samples

Surface water Samples

Page 38: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Hazard Potential RatingSl.No.

Criteria Min. toMax.Score

Site Scores

Site JCL-ISite JCL-

IISite JCL-III

1. Locational 25-125 94 91 103

2. Environmental 50-250 120 170 120

3. Managerial 25-125 125 107 50

Environmental Management Group, National Productivity Council

3. Managerial 25-125 125 107 50

Total 100-500 339 368 273

Therefore, Comparative Hazard Potential Rating of sites

Site JCL-II (Brine Sludge), Maximum

Site JCL-I (Brine Sludge), Moderate

Site JCL-III (Hypo Sludge), Least

Page 39: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Remediation Plan (site specific)

to mitigate the adverse impacts on environment

(water & soil)

to minimize further contamination

to reduce hazard potential

to minimize health hazard to near by residents

to meet existing hazardous waste rules to the extent

possible

cost economics

With Objective

Environmental Management Group, National Productivity Council

to mitigate the adverse impacts on environment

(water & soil)

to minimize further contamination

to reduce hazard potential

to minimize health hazard to near by residents

to meet existing hazardous waste rules to the extent

possible

cost economics

Page 40: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Remediation Plan (Site JCL-I)

Excavate entire waste (around 1m) & contaminated

soil (around 0.3 m)

Dispose waste & soil to Site

Fill excavated area with native soil followed by

vegetation cover

Environmental Management Group, National Productivity Council

Excavate entire waste (around 1m) & contaminated

soil (around 0.3 m)

Dispose waste & soil to Site

Fill excavated area with native soil followed by

vegetation cover

Page 41: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Remediation Plan (Site JCL-II)

Case-1: Capping of site in-situ with cover liner

Case-2: Capping of site in-situ with cover liner& cut-off walls

Case-3: Disposal of entire waste/contaminatedsoil in newly developed SLF

Three options :

Environmental Management Group, National Productivity Council

Case-1: Capping of site in-situ with cover liner

Case-2: Capping of site in-situ with cover liner& cut-off walls

Case-3: Disposal of entire waste/contaminatedsoil in newly developed SLF

Page 42: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

LAGOON No. 1

SIZE 28x23x3CAPPING COPMPLETED

70

A

Laying ofCover Liner

Capping of Site In-situ with cut-off walls

Environmental Management Group, National Productivity Council

100WASTE FROM SITEJCL-I

A

Place the cut-off Wall

Page 43: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

POND-2 POND-5 POND-6 POND-7

GROUNDLEVEL

SOIL EMBANKMENT1 M HEIGHT

WASTE FILLING UPTO 3 M HT AT

MIDDLESOILEMBANKMENT

1 M HEIGHTTOP COVBER

LINER

SECTION AT A-A

CUT-OFF WALLSUPTO IMPERMEVIOUSLAYER (15-20 M)

Capping of Site In-situ cut-off walls

Environmental Management Group, National Productivity Council

DETAILS OF EMBANKMENT AND COVER LINER

COVERLINER

1 M

COMPACTEDWASTE

OUTERSLOPE 1:2.5

INNERSLOPE 1:2

ANCHORTRENCH

1 M

5.5 M

COMPACTED CLAY 60 CMTHICK

HDPE LINER 1.5 MM

DRAINAGE GEONET WITHONE SIDE GEOTEXT

VEGITAIVE SOIL 0F 60 CM

Page 44: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

A

A

COMPACTEDWASTE BODY

COMPACTED ANDGRADED SOILCOVER OF 60 CM

Remediation PlanRIVER SIDE A

Environmental Management Group, National Productivity Council

A

SIDE SLOPEAT 1:5

SECTION ALONG A-A

SLOPE OFCOVER AT 5%SIDE SLOPE

AT 1:5

FILLED UP ANDCOMPACTEDHYPO SLUDGE

RIVERSIDE

1 M HT

1 MDEPTH

AVERAGEGROUND LEVEL

TOP COVERDETAILS

COMPACTEDWASTE BODY

DETAILS OF TOP COVER

PLAN

Page 45: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Item Description of work Quantity Unit Unit Price(Rs)

Total(Rs in lakhs)

1 Excavation of brine sludge of1 m average depth and

4500 M3 100 4.5

Cost Estimates (Site JCL-I)

Environmental Management Group, National Productivity Council

1 Excavation of brine sludge of1 m average depth andtransportation to the site -II forcapping.

4500 M3 100 4.5

2 Filling up with borrow soil 4500 M3 250 11.25

Total 15.75

Page 46: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Cost Estimates (Site JCL-II)

Item Description of work Quantity Unit UnitPrice(Rs)

Total(Rs in lakhs)

1 Excavation of hypo sludgefrom cell-1, 7 & 8 m averagedepth and filling up in thecapping area

8000 M3 80 6.4

2 Construction of side 975 M3 250 2.5

CASE-1 : CAPPING OF WASTE

Environmental Management Group, National Productivity Council

2 Construction of sideembankment of 1 m height

975 M3 250 2.5

3 Installation of compactclay layer

1920 M3 250 4.8

4 Installation of 1.5 mm thickHDPE liner

6000 M2 300 18.0

5 Drainage geonet with on sidegeotextile

7000 M2 250 17.5

6 Installation of top vegetativesoil layer of 0.6 m thickness

3200 M3 200 6.4

TOTAL 55.6

Page 47: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

CASE-2 : CAPPING OF WASTE WITH CUT-OFF WALLS

S.no. Particulars Cost (Rs. in lakhs)

1. Capping of waste 55.6

2. Putting cut-off walls 15.2

Total 70.8

CASE-3 : DISPOSAL OF WASTE IN NEWLY BUILD LANDFILL SITE or atCSLF

Environmental Management Group, National Productivity Council

CASE-3 : DISPOSAL OF WASTE IN NEWLY BUILD LANDFILL SITE or atCSLF

S.no. Particulars Cost (Rs. in lakhs)

1. Development of landfill 105.0

2. Covering of landfill 70.0

3. Disposal of waste into CSLF (@ Rs 700/-) 245.0

Total 350.0

Page 48: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Cost Estimates (Site JCL-III)

Item Description of work Quantity Unit UnitPrice(Rs)

Total(Rs in lakhs)

1 Excavation of the side hypeembankment and filling up the3 ponds and compacting and

7200 M3 60 4.32

Environmental Management Group, National Productivity Council

3 ponds and compacting andgrading of the top at requiredslope.

2 Soil cover of 0.6 m thickabove the hypo waste.

4400 M3 250 11.0

TOTAL 15.32

Page 49: Risk Assessment and Disaster Management of Contaminated HW ... M J Pervez ,Group Head and... · and document effectiveness Environmental Management Group, National Productivity Council

Thank You

Environmental Management Group, National Productivity Council

Thank You