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TN Ch 4.6 Date Title and Highlight Topic: EQ: Questions: Write Question out and answer it (in another color or HIghlight) based on from what you read. NOTES: Now write out the notes from my website. You may use different color pens. Number notes as you go. Space out your notes so you can add anything I say to them. BUT NO HIGHLIGTING, UNDERLINING, etc WE WILL DO OUR FOCUS NOTES TOGETHER Right Side NOTES ONLY

Right Side NOTES ONLY Title and Highlight - Chemistry · PDF fileTitle and Highlight Topic: EQ: ... Law of Octaves In 1863, he suggested that elements be ... In 1913, through his work

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TN Ch 4.6 Date

Title and

Highlight

Topic:

EQ:

Questions:

Write Question out and answer it (in

another color or HIghlight) based on

from what you read.

NOTES:

Now write out the notes from my

website. You may use different color

pens.

Number notes as you go.

Space out your notes so you can add

anything I say to them.

BUT NO HIGHLIGTING,

UNDERLINING, etc

WE WILL DO OUR FOCUS NOTES

TOGETHER

Right Side – NOTES ONLY

TN Ch 4.6

Title and

Highlight

DRAW ANY PICTURES, FIGURES,

AND WRITE OUT ANY PRACTICE

PROBLEMS/QUESTIONS.

WE WILL ANSWER THEM TOGETHER.

LEAVE SPACES SO WE CAN ANSWER

QUES.

LEFT Side – PICTURES, PRACTICE PROBLEMS, ETC

TN Ch 4.6 (part 1)

Topic:The History of the Modern Periodic Table

EQ: How was the first Periodic Table constructed and how is P.T. organized ?

READ Ch 4.6 (pg. 102-106)

Write Questions & Answer Questions #11-13 (notes side)Highlight answer

The periodic table is the most important tool in the chemist’s toolbox!

Why is the Periodic Table important to me?

• You get to use it on every test.

• It organizes lots of information about all the known elements.

Pre-Periodic Table Chemistry …

…was a mess!!!

No organization of elements.

During the nineteenth century, chemists began to categorize the elements according to similarities in their physical and chemical properties.

John Newlands

1838 - 1898

Law of Octaves

In 1863, he suggested that elements be arranged in “octaves” because he noticed (after arranging the elements in order of increasing atomic mass) that certain properties repeated every 8th element.

John Newlands

1838 - 1898 Law of Octaves

FYI – But the science community didn’t like this “repeating pattern” idea....his paper was rejected by the Chemical Society.

Dmitri Mendeleev:Father of the Periodic Table

In 1869 he published a table of the elements.

1834 - 1907

A first look at the periodic tableDmitri Mendeleev organized all of the elements that were known at the time into rows and columns based on their chem/phy similarities and their masses.

Periodic Table•The table is called “periodic” because the pattern of similar properties repeats as you move from period to period.

Lothar Meyer

1830 - 1895

At the same time, he published his own table of the elements organized by increasing atomic mass.

Dmitri MendeleevHOW HIS WORKED…

70 known elements.

Organized rows (periods) by increasing atomic weight.

Put elements in columns (groups) by their properties.

SOME PROBLEMS…

He left blank spaces for undiscovered elements. (Turned out he was right!)

He broke the pattern of increasing atomic weight.

Used his P.T. to predict the physical properties of three elements that were yet unknown.

Problems arose when new elements were discovered.Looking at our modern P.T., can you identify what problems might have caused chemists a headache?

Ar and K

Co and Ni

Te and I

Th and Pa

The fact that Mendeleev’s predictions for Sc, Ga, and Ge were amazingly close to the actual values, his table was generally accepted.

Henry Moseley

1887 - 1915

In 1913, through his work with X-rays, he determined the atomic number of the elements*……elements should be arranged in order of increasing atomic number is known as the periodic law.

Henry MoseleyHis research was halted when theBritish government sent him to serveas a foot soldier in WWI. He waskilled in the fighting in Gallipoli by asniper’s bullet, at the age of 28.Because of this loss, the Britishgovernment later restricted itsscientists to noncombatant dutiesduring WWII.

Glenn T. Seaborg

After co-discovering 10 new elements, in 1944 he moved 28 elements out of the main body of the periodic table to their current location below the main part of the P.T. :Lanthanide and Actinide series.

1912 - 1999

Glenn T. SeaborgHe is the only person to have an element named after him while still alive.

1912 - 1999

Current Periodic Table:

How the P.T. has changed over time?

Current P.T.

Increasing ATOMIC NUMBER!!

Elements in the same group have similar chemical and physical properties!! (Mendeleev did

that on purpose.)

Past P.T.

• Increasing Mass number

(not any more!!!)

• Elements in the same group have similar chemical and physical properties!!

Still the same!!!

TN Ch 4.6 (part 2)

Topic:The organization of the current Periodic Table

EQ: How is the P.T. that we use to today organized ?

READ Ch 4.6 (pg. 102-106)

Write Questions & Answer Questions #14-18 (notes side)Highlight answer

The horizontal rows of the periodic table are called PERIODS (7).

Sketch this

with notes on

right side!!!

The vertical columns are called GROUPS (18), or FAMILIES.

The elements in any grouphave similar physical andchemical properties!

Sketch this

with notes on

right side!!!

1A

2A 3A 4A 5A 6A7A

8A

Elements in the 1A-8A groups are called the representative or main group elements

Sketch this

with notes on

right side!!!

The group B are called the transition elements

Sketch this

with notes on

right side!!!

The elements in the periodic table can be broadly classified as metals,

nonmetals, and metalloids.

Types of Elements

Sketch this

with notes on

right side!!!

3 classes of elements - METALS Located to the _______ of the dark zig-zag line

All Solids!!! Except one – who is it??

shiny surface

Tend to be white/gray/silvery (common exceptions: copper and gold)

◦ ______________ (you can pound it into a flat sheet)

◦ ______________ (you can draw it into a thin wire)

◦good _______________ (heat/electricity)

◦Metals tend to LOSE electrons in chemical changes.

left

malleable

ductile

conductors

3 classes of elements - NONMETALS

Located to the ___________ of the dark zig-zag line.

◦_______ surface

◦ ______________

◦Some are solids and some are gases. Only 1 liquid.

◦good _______________ and poor conductors

◦Nonmetals tend to GAIN electrons in chemical changes.

◦Vary in color (P - red/white, S – yellow, C – black/clear, I – purple, Br – brownish red, etc)

right

dull

brittle

insulators

sulfur

Sketch this

with notes

on right

side!!!

3 classes of elements – METALLOIDS (only 8)

Located on the border of the dark zig-zag line.

◦ the dividing line between metals and nonmetals.

◦ All SOLIDS!

◦ Also called “semimetals”

◦ Behave (chemically) as nonmetals, but look physically & electrical conductivity resembles metals.

◦ Semiconductors – they do conduct some heat/electricity

◦ Used in computers, cell phones, and other modern gadgets.

silicon

Sketch this

with notes

on right

side!!!

Hydrogen

Hydrogen belongs to a family of its own.

Hydrogen is a nonmetal!!!

It’s a diatomic, reactive gas.

Facts

Hydrogen was involved in the explosion of the Hindenberg.

Hydrogen is promising as an alternative fuel source for automobiles

Group 1 - Alkali Metals(not H!!!)

•Very reactive metals (solids) with air and water, always

combined with something else in nature (like in salt).

•Soft enough to cut with a butter knife

Alkali Metal Family

Video Clip

Sketch this

with notes

on right

side!!!

Group 2 - Alkaline Earth Metals

•Reactive metals (solids) that are always

combined with nonmetals in nature.

• Mg and Ca important for our body!!!

•Also, used used in batteries

Sketch this

with notes

on right

side!!!

Groups 3-12: Transition MetalsSketch this

with notes

on right

side!!!

All solids except Mercury

Less reactive harder metals

Includes metals used in jewelry and construction.

Metals used “as metal.”

Transition MetalsGroups 3-12

InnerTransition Metals

Inner Transition elements - also

called the rare-earth elements.

Sketch this

with notes

on right

side!!!

Group 14 - Carbon Family

Elements important to life and computers (Si and Ge).

Carbon is the basis for an entire branch of chemistry.

Sketch this

with notes

on right

side!!!

Group 15 - Nitrogen Family

Nitrogen makes up over 80% of the atmosphere.

Nitrogen and phosphorus are both important in living things.

The red stuff on the tip of matches is phosphorus.

Sketch this

with notes

on right

side!!!

Group 16 - Oxygen Family or Chalcogens

Oxygen is necessary for respiration.

Many things that stink, contain sulfur (rotten eggs, garlic, skunks,etc.)

Sketch this

with notes

on right

side!!!

Group 17 - Halogens

• Very reactive, diatomic,

nonmetals

• Always combined with

other elements in nature .

• Used in some light

fixtures

• Used as disinfectants and

to strengthen teeth. Sketch this

with notes

on right

side!!!

Group 18 - Noble Gases

• VERY unreactive,

monatomic gases

• Don’t form compounds!!!

(These are also called

“Inert gases”)

• Used in lighted “neon”

signs and balloons.

Sketch this

with notes

on right

side!!!

The periodic table with groups highlighted: 1A, alkali metals; 2A, alkaline earth metals; 7A, halogens; and 8A, noble gases.

Sketch this

left side!!!

A

l

k

a

l

i

M

e

t

a

l

s

A

l

k

a

l

I

n

e

E

a

r

t

h

M

e

t

a

l

s

N

o

b

e

l

G

a

s

e

s

H

a

l

o

g

e

n

s

Transition Metals

Inner Transition Metals

Representative Elements

Transition Elements

Rep

resen

tativ

e E

lem

en

ts

METALS

Periods

Gro

up

s

Nonmetals

QUESTIONS

TN Ch 4.7

Topic: Ions

EQ: How is the atom affected by ions?

READ Ch 4.7 (pg. 106-108)

Write Questions & Answer Questions #19-21 (notes side)Highlight answer

Let’s refresh our memory about the atom and isotopes….

Atomic number (Z).

Protons determines the identity of the element.

A# = p+ = e- (atoms are

neutral)

The Mass Number (A),

(rounded to the nearest

integer)

Mass# = p+ + no

# of neutrons = mass # – p+

Isotopes: When the Number of Neutrons & Mass # Varies

All atoms of an element have the same # of protons.

Atoms with the same # of protons but different # of neutrons (this causes the mass # to also change) are called isotopes.

EXAMPLE OF AN ISOTOPE

Cl35

17 Cl37

17

20 NEUTRONS

ATOMIC MASS

18 NEUTRONS

ATOMIC NUMBER

So…

Atomic# = p+ = e-

(if atom is neutral)HOWEVER…..what if the atom is not neutral?

Electrons

•Electrons can be lost or gained = Chemical

Reaction, which make up more than 99% of

all rxns in life)

• When electrons are lost or gained, IONS are

formed.

•And electrons won’t equal protons no

more!!! Atomic# = p+ = e-

Ions: Cations vs. Anions

Positive ions (lose e-) are called cations.

Negative ions (gain e-) are called anions.

The charge of an ion is shown in the upper right corner of the symbol.

Ion Symbol Notation

XMass

number

Atomic

numberSubscript →

Superscript →+2

Lost 2 e-

So… how do you know how many electrons atoms will lose or gain to form an ion?

Ions and the Periodic Table

The # associated with the A groups above each representative (main-group) column on the P.T. —1 through 8—gives the number of valence electrons (electrons on the far outside of the atom – these e- are the ones used first for chemical bonding!!!)

The key to predicting the charge acquired by an element is its position in the periodic table relative to the noble gases. Why noble gases?

Elements that form predictable ions

If an atom has a charge associate with it, it is an ION:

88 2

38 Sr

How many protons, neutrons, and electrons are there?

Important: If an atom has a negative charge = an anion. If an atom has a positive charge = a cation.

Review Questions

1. Given

Determine the number of protons, neutrons and electrons in this atom.

356

26 Fe

Left Side

Review Questions

2.

Determine the number of protons, neutrons and electrons in this atom.

232

16

S

Left side!!!

How many protons, neutrons & electrons are there in the following?

3. Cl-38 6. 35Cl-1

4. Br-80 7. 32S-2

5. N-14 8. 56Fe+3

Left side!!!