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RESPONSE TO PRE-TREATMENTS AND DIGESTION INTENSIFICATION OF SEWAGE SLUDGE
Negral L., Marañón E.1, Fernández-Nava Y., Castrillón L.
University Institute of Industrial Technology of Asturias. University of Oviedo. 33203 Gijón, Spain
Le, S., Miller, K., Carlines, I.
United Utilities Group PLC, Warrington, WA5 3LP United Kingdom
1corresponding author: [email protected]
INTRODUCTION
• SEWAGE SLUDGE BACKGROUND
• PRETREATMENTS
Ultrasound
Enzymatic Hydrolysis
Grinding
• ORGANIC MATTER SOLUBILIZATION
• ENHANCED ANAEROBIC DIGESTION
• CONCLUSIONS
18/10/2013 BIOCHARS COMPOST DIGESTATES BCD 2013 2
AGRICULTURE
DEWATERING + CHEMICAL
STABILIZATION
ANAEROBIC DIGESTION + DEWATERING
AEROBIC DIGESTION + DEWATERING
DEWATERING + HEAT
DRYING + COMPOSTING CEMENT
MANUFACTURING
DEWATERING + HEAT DRYING
ANAEROBIC DIGESTION +
DEWATERING + HEAT DRYING
AEROBIC DIGESTION +
DEWATERING + HEAT DRYING
DEWATERING + INCINERATION
SEWAGE SLUDGE-BACKGROUND (I)
BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
LANDFILL DEWATERING
DESTINATION
3
SEWAGE SLUDGE-BACKGROUND (II)
4
107 tonnes (dry matter) Europe/year
Hydrolysis is the rate-limiting stage of AD
Anaerobic digestion stabilizes the sludge while leads to energy recovery and production of digestate
Classical HRT ≈ 20 days
> 50% of Total Operating Costs in WWTPs
BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
PRE-TREATMENT FOR HIDROLYSIS
ENHANCEMENT
> 95% moisture
SEWAGE SLUDGE-BACKGROUND (III)
5 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Sludge contains recalciltrant organic fraction (bacterial cell wall) which is difficult to biodegrade
COMPLEXORGANICMATTER
MONOMERSHydrolysis Acidogenesis
VolatileFatty Acids
CH3COOH
H2 + CO2
CH4 + CO2
CH4 + CO2
MethanogenesisAcetate-utilizing
methanogens
MethanogenesisHydrogen-utilizing
methanogens
Aceto
genesis
Acetogenesis
Rate limiting-step
Pre-treatments boost the biodegradability and methane yield
PRE-TREATMENTS (I)
6 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
BIOLOGICAL
Enzymatic hydrolysis
Hydrolytic bacteria
THERMAL
60-180ºC
Freeze/thaw
CHEMICAL
Oxidation
Acid addition
Alkali addition
MECHANICAL
Ultrasound
Centrifugation
High pressure
Grinding Combination of different pre-treatments
PRE-TREATMENTS (II)
7
Ultrasound
Ultrasonic equipment used:
Hielscher UP 400S, 24 kHz, 400 W
Sonotrode H22, made of titanium, Ø 22 mm
Different input energies: 50 – 21000 kJ/kg TS
BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
PRE-TREATMENTS (III)
8 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Enzymatic hydrolysis (EH) achieved by promoting endogenous enzymes at 42ºC for 48 hours under anaerobic conditions: Inverted Phase Fermentation (IPF) ®
2 phases separated from the raw sludge: a top thickened layer «Solid Phase (SP)» and a bottom clarified layer «Liquid Phase (LP)»
Subsequent Anaerobic Digestion (AD) of the LP and the SP
LP contains soluble organic matter (high in VFA), readily biodegradable
SP may be submitted to pre-treatment to enhance biodegradability
PRE-TREATMENTS (IV)
9 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
SP pre-treatment: grinding in alkaline media
Milling paremeters: 1:3 ratio sludge cake to water 100 rpm, 4 days 1:1 ratio grinding media to sludge cake 5% NaOH (dry basis), adjusted to pH 8 with HCl after milling
In theory, the higher the rate of soluble COD release from the sludge substrate, the greater the eventual methane yield from digestion
Grinding mill Zirconium oxide grinding media
SOLUBILIZATION (I)
10 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Short-term evolution of SCOD (1 day fermentation, 37ºC) after ultrasound disruption for secondary sludge
The numbers in legends indicate the specific energy applied in kJ/kgTS
Untreated 3407 6814 10599 14006 20819
For applied energy of around 7000 kJ/kgTS, the increase in CODs range from 90% for primary sludge to about 40000% for secondary sludge
0
5
10
15
20
25
Initial Ultrasound Fermentation
SCO
D (
g/L
)
0
5
10
15
20
25
Initial Enzymatichydrolysis
Fermentation
SCO
D (
g/L
)
SOLUBILIZATION (II)
11 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Short-term evolution of SCOD (1 day fermentation, 37ºC) after IPF for secondary sludge
SP = Solid Phase; LP =Liquid Phase
Solubilization by IPF led to 1500% increase for primary sludge and 20000% for secondary sludge)
Thickening of the sludge, with solid concentration factors above 2 achieved in the SP
ENHANCED ANAEROBIC DIGESTION (I)
12 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Continuous digestion of Sludge Liquor
Digestion was carried out in 5 L
UASB reactors at 37ºC
Optimum HRT reduced to 1 day!!
Methane yield rate up to: 2.3 m3CH4/m3
reactorday 70% COD removal for OLR of
18.5 kg COD/m3·day
ENHANCED ANAEROBIC DIGESTION (II)
13 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Continuous digestion of Sludge Liquor in high load reactors (UASB)
Parameter Influent A Effluent A (% removal)
Influent B Effluent B (% removal)
HRT (day) 1 2
OLR (kgTCOD/m3·day) 18.5 12.9
TCOD (g/kg) 18.46 5.51 (71%)
25.71 9.80 (62%)
SCOD (g/kg) 10.61 2.07 (80%)
7.69 2.51 (67%)
m3 biogas/kgTCOD 0.19 0.15
m3 CH4/kgTCOD 0.13 0.09
m3 biogas/m3reactorday 3.52 1.95
m3 CH4/m3reactorday 2.34 1.19
ENHANCED ANAEROBIC DIGESTION (III)
14 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Continuous digestion of the pre-treated SP in chemostats
The milled substrate was diluted with water and fed into chemostats (organic loading rates 1.0, 2.5 and 4.3 kgCOD/m3·day)
No inhibition/toxic effects observed in the digestion process
Digestion was stable when using pre-treated sludge as feed
Digestion was carried out using 5 L
chemostats at 37oC
ENHANCED ANAEROBIC DIGESTION (IV)
15 18/10/2013
Methane concentration
0
10
20
30
40
50
60
70
0 5 10 15
Time (days)
Meth
an
e c
on
cen
trati
on
(%
)
Control: 4.3 kgCOD/m3
C1: 4.3 kgCOD/m3
C2: 2.5 kgCOD/m3
C3: 1.0 kgCOD/m3
Biogas volume
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
0 5 10 15
Time (days)
Bio
gas v
olu
me (
ml)
Control: 4.3 kgCOD/m3
C1: 4.3 kgCOD/m3
C2: 2.5 kgCOD/m3
C3: 1.0 kgCOD/m3
The biogas volume and methane concentration were similar in the chemostats with the highest organic loading rates
Both the control and chemostat 1 had a loading rate of 4.3 kgCOD/m3, however the experimental chemostat produced 3.5 X more biogas than the control
The chemostat with the lowest loading rate (1.0 kgCOD/m3) and the control chemostat produced a similar quantity and quality of biogas, due to the limited availability of nutrients in their substrates
ENHANCED ANAEROBIC DIGESTION (V)
16 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
Continuous digestion of the pre-treated SP in chemostats Chemostat Digester influent Digester effluent COD reduction
TCOD
(mg/l)
SCOD
(mg/l)
TCOD
(mg/l)
SCOD
(mg/l)
TCOD
(%)
SCOD
(%)
Chemostat 1: loading rate 4.3 kgCOD/m3·day
60180 30200 36051 5503
40.1 81.8
Chemostat 2: loading rate 2.5 kgCOD/m3·day
35020 17540 25533 3486
27.1 80.1
Chemostat 3: loading rate 1.0 kgCOD/m3·day
23429 11734 17850 2203
23.8 81.2
Control Chemostat
4.3 kgCOD/m3·day
66240 3880 48304 4166
27.1 No SCOD
reduction
The novel pre-treatment IPF boosts the anaerobic digestion of sludge:
CONCLUSIONS: ENHANCED ANAEROBIC DIGESTION
17 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
The liquor from the sludge may be digested in high rate reactors (e.g.
UASB) The optimum HRT of the liquor is reduced to 1 – 2 days (18.5 – 13
kgCOD/m3·day)
Methane yield rates up to 2.3 m3CH4/m3reactor day
TCOD reductions of the liquor up to 71%
The grinding of the SP increased the biogas production to 3.5 X
TCOD reductions of pre-treated SP up to 40% at 4.3 kgCOD/m3·day
CONCLUSIONS: ENHANCED ANAEROBIC DIGESTION
18 BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
>> COD & VS REMOVAL
>> BIOGAS PRODUCTION
<< PROCESS TIME
GREATER SUSTAINABILITY
IN SLUDGE MANAGEMENT
ACKNOWLEDGEMENTS
19
The research leading to these results has received funding from the
European Union Seventh Framework Programme (FP7-
ENV.2010.3.1.1-2 ENV) under Grant Agreement no. 265269.
http://www.end-o-sludg.eu/
We are grateful to the staff at the WWTPs for their generous
cooperation during the experiments
BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013
20
THANKS FOR YOUR ATTENTION!
BIOCHARS COMPOST DIGESTATES BCD 2013 18/10/2013