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Copyright of Shell Global Solutions International B.V. RESIDUE GASIFICATION: AN ATTRACTIVE BOTTOM OF THE BARREL UPGRADING TECHNOLOGY New Horizons in Gasification The 12th European Gasification Conference 2014 Marie-Cecile Medine Process Engineer, Shell Global Solutions International B.V. March 2014

RESIDUE GASIFICATION: AN ATTRACTIVE BOTTOM OF … · RESIDUE GASIFICATION: AN ATTRACTIVE BOTTOM OF THE BARREL ... The companies in which Royal Dutch Shell plc directly and indirectly

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Copyright of Shell Global Solutions International B.V.

RESIDUE GASIFICATION: AN ATTRACTIVE BOTTOM OF THE BARREL UPGRADING TECHNOLOGY

New Horizons in Gasification

The 12th European Gasification Conference 2014

Marie-Cecile Medine Process Engineer, Shell Global Solutions International B.V.

March 2014

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DEFINITIONS AND CAUTIONARY NOTE

Resources: Our use of the term “resources” in this presentation includes quantities of oil and gas not yet classified as SEC proved oil and gas reserves. Resources are consistent with the Society of Petroleum Engineers 2P and 2C definitions.

The companies in which Royal Dutch Shell plc directly and indirectly owns investments are separate entities. In this presentation “Shell”, “Shell group” and “Royal Dutch Shell” are sometimes used for convenience where references are made to Royal Dutch Shell plc and its subsidiaries in general. Likewise, the words “we”, “us” and “our” are also used to refer to subsidiaries in general or to those who work for them. These expressions are also used where no useful purpose is served by identifying the particular company or companies. ‘‘Subsidiaries’’, “Shell subsidiaries” and “Shell companies” as used in this presentation refer to companies over which Royal Dutch Shell plc either directly or indirectly has control. Companies over which Shell has joint control are generally referred to “joint ventures” and companies over which Shell has significant influence but neither control nor joint control are referred to as “associates”. In this presentation, joint ventures and associates may also be referred to as “equity-accounted investments”. The term “Shell interest” is used for convenience to indicate the direct and/or indirect (for example, through our 23% shareholding in Woodside Petroleum Ltd.) ownership interest held by Shell in a venture, partnership or company, after exclusion of all third-party interest.

This presentation contains forward-looking statements concerning the financial condition, results of operations and businesses of Royal Dutch Shell. All statements other than statements of historical fact are, or may be deemed to be, forward-looking statements. Forward-looking statements are statements of future expectations that are based on management’s current expectations and assumptions and involve known and unknown risks and uncertainties that could cause actual results, performance or events to differ materially from those expressed or implied in these statements. Forward-looking statements include, among other things, statements concerning the potential exposure of Royal Dutch Shell to market risks and statements expressing management’s expectations, beliefs, estimates, forecasts, projections and assumptions. These forward-looking statements are identified by their use of terms and phrases such as ‘‘anticipate’’, ‘‘believe’’, ‘‘could’’, ‘‘estimate’’, ‘‘expect’’, ‘‘goals’’, ‘‘intend’’, ‘‘may’’, ‘‘objectives’’, ‘‘outlook’’, ‘‘plan’’, ‘‘probably’’, ‘‘project’’, ‘‘risks’’, “schedule”, ‘‘seek’’, ‘‘should’’, ‘‘target’’, ‘‘will’’ and similar terms and phrases. There are a number of factors that could affect the future operations of Royal Dutch Shell and could cause those results to differ materially from those expressed in the forward-looking statements included in this presentation, including (without limitation): (a) price fluctuations in crude oil and natural gas; (b) changes in demand for Shell’s products; (c) currency fluctuations; (d) drilling and production results; (e) reserves estimates; (f) loss of market share and industry competition; (g) environmental and physical risks; (h) risks associated with the identification of suitable potential acquisition properties and targets, and successful negotiation and completion of such transactions; (i) the risk of doing business in developing countries and countries subject to international sanctions; (j) legislative, fiscal and regulatory developments including regulatory measures addressing climate change; (k) economic and financial market conditions in various countries and regions; (l) political risks, including the risks of expropriation and renegotiation of the terms of contracts with governmental entities, delays or advancements in the approval of projects and delays in the reimbursement for shared costs; and (m) changes in trading conditions. All forward-looking statements contained in this presentation are expressly qualified in their entirety by the cautionary statements contained or referred to in this section. Readers should not place undue reliance on forward-looking statements. Additional risk factors that may affect future results are contained in Royal Dutch Shell’s 20-F for the year ended December 31, 2014 (available at www.shell.com/investor and www.sec.gov ). These risk factors also expressly qualify all forward looking statements contained in this presentation and should be considered by the reader. Each forward-looking statement speaks only as of the date of this presentation, 11 March 2014. Neither Royal Dutch Shell plc nor any of its subsidiaries undertake any obligation to publicly update or revise any forward-looking statement as a result of new information, future events or other information. In light of these risks, results could differ materially from those stated, implied or inferred from the forward-looking statements contained in this presentation.

We may have used certain terms, such as resources, in this presentation that United States Securities and Exchange Commission (SEC) strictly prohibits us from including in our filings with the SEC. U.S. Investors are urged to consider closely the disclosure in our Form 20-F, File No 1-32575, available on the SEC website www.sec.gov. You can also obtain these forms from the SEC by calling 1-800-SEC-0330.

March 2014 2

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AGENDA

The Energy Challenge in the Middle East

Case Study: Refinery Upgrading Schemes

Comparison of Refinery Upgrading Schemes

Shell Residue Gasification

Conclusion

March 2014 3

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THE ENERGY CHALLENGE IN THE MIDDLE EAST

Rapid population growth and need for employment

Energy consumption growth

Strong dependence on oil for power generation

Crude oil quality trending towards heavier sulphur

Tightening emission limits

Lower sulphur product specifications

Concern for future use of high sulphur bunker fuels

Lack of affordable gas in some countries

March 2014 4

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CASE STUDY: REFINERY UPGRADING SCHEMES

Comparison of theoretical refinery schemes:

Main premises: 400,000 BPD crude, 2.83 wt% sulphur in crude

Refinery to maximise diesel production, requiring hydrogen

Natural gas unavailable

Refinery products (LPG, Naphtha) used to achieve refinery fuel balance and produce H2

Power is required in the region

March 2014 5

Simple Refinery (HSFO)

Upgraded residue to H2 and Power

Vacuum residue to H2 and Power

Base Case: Option 1: Option 2:

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BASE CASE: SIMPLE REFINERY SCHEME

6

Fuel Oil Blending

Hydro - Cracking

Unit Vacuum Distillation

Unit

Refinery Products

Atm Resid

Vacuum Residue

Key

Flow, % of crude

Flow, tpd

Imported Power for Refinery, MW

Simple Refinery → HSFO

Fuel Oil

SMR H2 →To Refinery

Import Power for Refinery

LPG, Naptha

Refinery Fuel

57%

53%

38%

210

2.7%

460

25%

March 2014

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OPTION 1: CLEAN POWER WITH IGCC

7

IGCC

Hydro - Cracking

Unit Vacuum Distillation

Unit

Atm Resid

Vacuum Residue

No Upgrading → IGCC

H2 → To Refinery

73%

53% 450

25%

Refinery Products

Exported Power

Power → To Refinery

210

Key

Flow, % of crude Power to Refinery, MW

Flow, tpd Exported Power, MW

2300

Sulphur 1.3%

ɳ > 40%

March 2014

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OPTION 2: MAX PRODUCTS AND CLEAN POWER

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Hydro -Cracking

Unit Vacuum Distillation

Unit

Atm Resid

Vacuum Residue

Upgrading → IGCC

Residue Upgrading

IGCC

H2 → To Refinery

83%

660

Refinery Products

Exported Power

750

Sulphur 0.9%

53%

25%

Power → To Refinery

13%

240

ɳ > 40%

Key

Flow, % of crude Power to Refinery, MW

Flow, tpd Exported Power, MW

March 2014

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COMPARISON OF REFINERY UPGRADING SCHEMES

9

Refinery Products (EuroV)

Refinery Bottoms

Syngas

Power

Base Case: Simple Refinery

(HSFO)

57%

38%

Fuel oil

No syngas produced

Import 210MW

Option 1: Vacuum Residue to H2 and Power

73%

25%

VR

45 – 50 MMNm3/day

Export 2300MW

Option 2: Upgraded Residue to H2 and Power

83%

13%

UR

25 – 30 MMNm3/day

Export 750MW

March 2014

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POTENTIAL REFINERY REVENUES

Relative to base case – simple refinery

Revenue increases with deeper upgrading maximising the product

Power Sales *

$7.1M/d $2.3M/d * Power price - $130/MWh

10

0

1

2

3

4

5

VR to H2 & Power Upgraded residue

Δ R

even

ue ($

M/d

)

March 2014

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SHELL RESIDUE GASIFICATION

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FEEDSTOCK SYNGAS

Gasification Syngas Effluent Cooling

Carbon Removal

Residue

Oxygen

Steam

High Pressure Steam

Ash and residual carbon

Clean Syngas Raw Syngas Raw Syngas

Shell Process Overview

March 2014

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GASIFICATION – USAGE OF SYNGAS

12 March 2014

Feed

Gasification and Gas treating

Oxygen Steam

Clean syngas (CO + H2)

Hydrogen Chemicals, ammonia, methanol, oxo-alcohols

Clean syngas for refinery use

Boilers Furnaces

Synthesis of hydrocarbons

Liquid transportation fuels

Power generation IGCC

Electricity Steam

Sulphur

Power generation IGCC

Hydrogen

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SHELL GASIFICATION TECHNOLOGIES

13 March 2014

SGP SCGP Bottom Quench

Non-slagging condition Slagging condition Slagging condition

Refractory lined gasifier Membrane wall gasifier Membrane wall gasifier

Liquid feed system Dry feed system Dry feed system

Fire tube boiler Water tube boiler Bottom water quench

Soot water handling Solid slag/Some grey water handling

Solid slag/Black water handling

Liquid refinery residues

Coal and petcoke

Coal and petcoke

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CONVERTING “BOTTOM OF THE BARREL” INTO VALUABLE PRODUCTS

Proven track record since 1950s

170 reactors built , 96 reactors in operation

Suitable for range from vacuum residue to highly viscous residues

s/a thermal cracked residue, de-asphalter residue, later retrofit to heavier feedstock possible

Safe and reliable operation

Automated and fully safeguarded heat-up, start-up, shutdown sequences; reliability > 99.5%

Long burner run length and long refractory lifetime

Extensive experience in start-up, operation and maintenance of own units and licensed units

High syngas yield; low oxygen consumption and low soot formation; high thermal efficiency through syngas cooler

14 March 2014

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CONCLUSION

Economics

High value product yields, improved economics

Highly efficient power generation

Environment

Refinery becomes independent from changes in legislation

Cleaner power generation

Local Benefits

Leveraging local resources

Provides jobs to people

Flexibility

Shell gasification technology can process virtually all heavy residues

Shell Technologies are available and proven to support this

15 March 2014

China 2009 Asphalt

Canada 2008 Asphalt

Italy 2006 Residue/ Asphalt

Shell Pernis 1997 Cracked Residue

Gasification may be an answer to the challenges in the Middle East

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Q&A

16 March 2014