Report Styrene Monomer Lyondell

MATERIAL SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

STYRENE MONOMER Gen. Variant: SDS_NL Version 1.0 Revision Date 11/29/2010 Print Date 11/29/2010 MSDS No.: BE645

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1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : STYRENE MONOMER Substance name : Styrene

Substance No. : 202-851-5 (EINECS)

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Manufacture of substances, Formulation & (re)packing of substance and mixtures, Distribution of substance, Polymer production, Other consumer uses

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone

Company Telephone Registration number Emergency telephone Lyondell Chemie Nederland, B.V. Weena 737 3013 AM Rotterdam Netherlands

31 (0) 10 275 55 00 01-2119457861-32-0017 +32 3 575 1235

E-mail address Responsible/issuing person

: [email protected]

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Flammable liquids, Category 3 H226: Flammable liquid and vapor. Acute toxicity, Category 4 H332: Harmful if inhaled. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters

airways. Specific target organ systemic toxicity - single exposure, Category 3

H335: May cause respiratory irritation.

Specific target organ systemic toxicity - repeated exposure, Category 1

H372: Causes damage to organs through prolonged or repeated exposure if inhaled.

Classification (67/548/EEC, 1999/45/EC)

Harmful. R10: Flammable. Irritant. R20: Harmful by inhalation. R65: Harmful: may cause lung damage if

swallowed. R48/20: Harmful: danger of serious damage to

health by prolonged exposure through inhalation.



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R36/37/38: Irritating to eyes, respiratory system and skin.

2.2 Label elements

Labeling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H226 Flammable liquid and vapor.

H332 Harmful if inhaled. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. H372 Causes damage to organs through

prolonged or repeated exposure if inhaled. H304 May be fatal if swallowed and enters

airways.

Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open

flames/hot surfaces. - No smoking. P280 Wear protective gloves/ protective clothing/

eye protection/ face protection. P261 Avoid breathing dust/ fume/ gas/ mist/

vapors/ spray. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and

water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with

water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/ physician.

P331 Do NOT induce vomiting.

2.3 Other hazards

Irritating to eyes, respiratory system and skin. This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

3. Composition/information on ingredients 3.1 Substances



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Chemical nature : Substance

Chemical Name CAS-No. EINECS-No. / ELINCS No./EC-No. Concentration [%]

Styrene 100-42-5 202-851-5

> 99.8

4. First aid measures

4.1 Description of first-aid measures

General advice : Harmful by inhalation. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Inhalation of vapors may cause signs of respiratory tract irritation (cough and difficulty breathing), CNS depression (fatigue, dizziness, headache, collapse, coma and death), possible cardiac sensitization, and irritation of the eyes, nose and throat. Aspiration into the lungs during swallowing or vomiting can cause lung damage, possibly leading to chronic lung dysfunction or death. Causes eye and skin irritation. Repeated exposures to very high concentrations of vapor may cause auditory effects. Always observe self-protection methods Wear appropriate personal protective equipment, avoid direct contact. Move out of dangerous area. Remove contaminated shoes and clothing. Get medical attention immediately. Show this material safety data sheet to the doctor in attendance.

If inhaled : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not leave the victim unattended. Keep patient warm and at rest. Immediately seek medical attention. If breathing is difficult, give oxygen. If unconscious place in recovery position and seek medical advice. In the event of unconsciousness, apnea or cardiac arrest (no pulse) apply cardiopulmonary resuscitation.

In case of skin contact : Take off contaminated clothing and shoes immediately. In case of contact, immediately flush skin with soap and plenty of water. Seek medical attention if ill effect or irritation develops. Wash contaminated clothing before reuse.

In case of eye contact : In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at



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least 15 minutes. Get medical attention immediately.

If swallowed : Clean mouth with water and drink afterwards plenty of water. DO NOT induce vomiting. If vomiting does occur, have victim lean forward to reduce risk of aspiration. Get medical attention immediately. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : Signs of eye, throat, and respiratory tract irritation (cough and difficulty breathing), CNS depression (fatigue, dizziness, headache, collapse, coma and death) and possible cardiac sensitization may occur after exposure to high vapor concentrations.

Hazards : Moderate eye irritant. Causes moderate skin irritation. Aspiration may cause pulmonary edema and pneumonitis. Potential danger from aspiration must be weighed against possible oral toxicity when deciding to induce vomiting. May cause hearing loss.

4.3 Indication of immediate medical attention and special treatment needed

Treatment : Treat symptomatically. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. Gastric lavage is indicated in those patients who require decontamination. Be sure that an endotracheal tube is in place prior to lavage; use cuffed tubes in patients over 7 years of age. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias (irregular beating) in persons exposed to this material.

5. Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media : SMALL FIRE: Use dry chemical, CO2, water spray or regular foam. LARGE FIRE: Use water spray, water fog or regular foam. Do not use straight streams.

Unsuitable extinguishing media

: Do not use solid water stream/may spread fire.

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire fighting

: Releases flammable vapors below normal ambient temperatures. May autopolymerize if uninhibited, heated or involved in a fire. Autopolymerization will be accompanied by evolution of heat,



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which may cause release of styrene vapors forming flammable mixtures with air. Liquid normally inhibited but not vapors. Vapors may condense as solids, plugging pressure relief devices, causing overpressure/rupture of storage containers during runaway polymerization. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Always stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Eliminate all sources of ignition. Sustained fire attack on vessels may result in a Boiling Liquid Expanding Vapour Explosion (BLEVE). Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

5.3 Precautions for fire-fighters

Special protective equipment for fire-fighters

: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters protective clothing will only provide limited protection.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Eliminate all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Enter area only if strictly necessary. A combustible gas detector can be used to check for flammable gas or vapors.

6.2 Environmental precautions

Environmental precautions : Prevent entry into waterways, sewers, basements or confined areas. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. If necessary, all contaminated waste water must be treated in a municipal or industrial wastewater treatment plant before release to surface water.



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Chemical removal by air and water pollution control devices must meet the minimum efficiency requirements needed to reduce exposures to an acceptable level. The discharge of treatment plant effluent to rivers and oceans must achieve the dilution ratio needed to reduce exposures to an acceptable level. The size and capacity of wastewater treatment plants must meet the minimum requirements needed to reduce exposures to an acceptable level. Waste management practices such as incineration, recycling, reuse must be enforced as needed to reduce exposures to an acceptable level. External treatment and disposal of waste should comply with applicable local and/or national regulations. The maximum allowable site tonnage and the days of use should be below the number needed to maintain exposures at an acceptable level.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Flammable liquid. Release will cause immediate fire/explosion. Eliminate all sources of ignition. All equipment used when handling this product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : May autopolymerize if uninhibited, heated or involved in a fire. Autopolymerization will be accompanied by evolution of heat, which may cause release of styrene vapors forming flammable mixtures with air. Do not handle near heat, sparks, or flame. Avoid contact with incompatible agents. Use only with adequate ventilation/personal protection. Avoid contact with eyes, skin and clothing. Do not enter storage area unless adequately ventilated. Metal containers involved in the transfer of this material should be grounded and bonded. Containers that have held styrene monomer must be thoroughly cleaned, drained and dried to prevent fire hazard from residue. Keep container tightly closed when not in use. Take necessary action to avoid static electricity discharge



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(which might cause ignition of organic vapors). Use only non-sparking tools.

Fire-fighting class : Flammable liquid.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Monitor inhibitor to maintain appropriate concentration. Keep containers tightly closed when not in use and store in a well-ventilated area. Isolate incompatible materials such as oxidizers. Containers should be clearly labeled. Metal containers used to store this material should be grounded. Store below 104°F (40°C). Empty containers may contain flammable product residues. Do not weld, solder, drill, cut or perform similar operations on or near containers. Ensure that all relevant regulations regarding explosive atmospheres, and handling and storage facilities of flammable products are followed.

7.3 Specific end uses

: (Refer to exposure scenario section for specific information).

8. Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Component Source Type: Value Note

Styrene US (ACGIH) STEL 40 ppm

None.

US (ACGIH) TWA 20 ppm

None.

NIOSH IDLH 700 ppm

None.

DN(M)EL : End Use: Workers

Routes of exposure: Inhalation Potential health effects: Acute effects Value: 289 mg/m3 Systemic effects

DN(M)EL : End Use: Workers Routes of exposure: Inhalation Potential health effects: Acute effects Value: 306 mg/m3 Local effects

DN(M)EL : End Use: Workers Routes of exposure: Skin contact Potential health effects: Long term



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Systemic effects DN(M)EL : End Use: Workers

Routes of exposure: Inhalation Potential health effects: Long term Value: 85 mg/m3 Systemic effects

DN(M)EL : End Use: General Population Routes of exposure: Inhalation Potential health effects: Acute effects Value: 174.25 mg/m3 Systemic effects

DN(M)EL : End Use: General Population Routes of exposure: Inhalation Potential health effects: Acute effects Value: 182.75 mg/m3 Local effects

DN(M)EL : End Use: General Population Routes of exposure: Skin contact Potential health effects: Long term Systemic effects

DN(M)EL : End Use: General Population Routes of exposure: Inhalation Potential health effects: Long term Value: 10.2 mg/m3 Systemic effects

DN(M)EL : End Use: General Population Routes of exposure: Ingestion Potential health effects: Long term Systemic effects

PNEC : Fresh water

Value: 0.028 mg/l Assessment factor -10

PNEC : Sea water Value: 0.0028 mg/l Assessment factor -100

PNEC : Water Value: 0.04 mg/l Intermittent Releases, Assessment factor -100

PNEC : Fresh water sediment Value: 0.614 mg/kg dw

PNEC : Sea sediment Value: 0.0614 mg/kg dw

PNEC : Sewage Treatment Plant Value: 5 mg/l Assessment factor -100

PNEC : Soil Value: 0.2 mg/kg dw



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8.2 Exposure controls

Engineering measures

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits.

Personal protective equipment

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Wear a respirator conforming to EN 140 with type A filter or better.

Hand protection : Use chemical resistant gloves appropriate to conditions of use. Wear chemical resistant gloves such as: Glove material fluoroelastomer; material thickness 0.4 mm; break through time ≥ 480 min. Gloves must be replaced after 8 hours of wear (GESTIS recommendation). The selected protective gloves have to satisfy the standard EN 374 derived from it. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection : Eye protection such as chemical splash goggles and/or face shield must be worn when possibility exists for eye contact due to splashing or spraying liquid, airborne particles, or vapor. Safety glasses are the minimum requirements. The selected goggles or glasses must satisfy the European norm standard EN 166.

Skin and body protection : When skin contact is possible, protective clothing including gloves, apron, sleeves, boots, head and face protection should be worn. The selected protective clothing has to satisfy the standard EN 13034, which describes clothing offering limited 8 hour protection against splashes. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Use PPE that is chemical resistant to the product and prevents skin contact.

Hygiene measures : Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the hazards and/or potential hazards that may be encountered during use. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet



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facilities. Take off contaminated clothing and wash before reuse.

Environmental exposure controls

General advice : See section 6.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : liquid

Color : Colorless to yellow.

Odor : Aromatic, sweet odor.

Flash point : 31 °C at 1,013 hPa

Lower explosion limit : ~1.1 vol%

Upper explosion limit : ~6.1 vol%

Flammability (solid, gas) : Flammable.

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Autoignition temperature : 490 °C at 1,013 hPa

Molecular Weight : 104.15 g/mol pH : Note: Not applicable.

Melting point/range : -31 °C

Boiling point/boiling range : 145 °C

at 1,013 hPa

Vapor pressure : 6.67 hPa at 20 °C

Water solubility : 320 g/l at 25 °C

Partition coefficient: n-octanol/water

: log Pow: 2.96 at 25 °C

Viscosity, dynamic : 0.696 mPa.s at 25 °C

Relative vapor density : ~3.6 at 15 - 20 °C Note: (Air = 1.0)



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Surface tension : Note: Surface activity is not expected or predicted based on structural considerations.

Explosive properties : Not explosive

9.2 Other information

10. Stability and reactivity

10.1 Reactivity

This product is stable with an appropriate level of TBC inhibitor (minimum 10 ppm), but reactive (unstable) without. Contact a company sales representative for information regarding adequate inhibitor levels and methods of making inhibitor level determinations.

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions : May occur. Note: Reactive (unstable) when uninhibited.

10.4 Conditions to avoid

Conditions to avoid : May autopolymerize if uninhibited, heated or involved in a fire. Autopolymerization will be accompanied by evolution of heat, which may cause release of styrene vapors forming flammable mixtures with air. Depleted inhibitor levels. High temperatures and severe oxidizing conditions. Avoid static discharge or other sources of ignition.

10.5 Incompatible materials

Materials to avoid : Strong oxidizing agents Peroxides Contaminants and catalysts for vinyl polymers. Alkali metal-graphite compounds. Aluminum chloride. Strong acids. Strong alkalies. Copper Copper alloys Rubber. Brass.

10.6 Hazardous decomposition products

Hazardous decomposition products

: On decomposition, emits acrid fumes. Carbon Monoxide and Carbon dioxide.

Thermal decomposition : Note: Thermal decomposition may produce oxides of carbon and other toxic gases and liberate heat and pressure.



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11. Toxicological information 11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity Styrene : LD50 (Oral): ~ 5,000 mg/kg

Species: rat Remarks: This substance is of low acute toxicity when administered orally. Ingestion may cause discomfort and irritation of the gastrointestinal tract, effects on lungs and kidneys, and CNS depression (fatigue, dizziness and possibly loss of concentration, with collapse, coma and death in cases of severe overexposure) Aspiration into the lung may cause fatal chemical pneumonitis. May increase the sensitivity of the heart to endogenous catecholamines leading to potentially fatal cardiac sensitization.

Acute inhalation toxicity Styrene : LC50 (Inhl): 11.8 mg/l

Exposure time: 4 HOURS Species: rat Remarks: Vapors are toxic when inhaled. Vapors may cause irritation of the eyes, nose and throat as well as CNS depression (primarily fatigue, dizziness and loss of concentration, with collapse, coma and death in cases of severe over-exposure) May increase the sensitivity of the heart to endogenous catecholamines leading to potentially fatal cardiac sensitization.

Acute dermal toxicity Styrene : LD50 (Skin): > 2,000 mg/kg

Species: rat Method: OECD Test Guideline 402

Skin corrosion/irritation

Skin irritation Styrene : Classification: Irritating to skin.

Serious eye damage/eye irritation

Eye irritation Styrene : Classification: Irritating to eyes.

Respiratory or skin sensitization



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Sensitization Styrene : Classification: Not sensitizing

Germ cell mutagenicity

Remarks Styrene : Styrene does possess some genotoxic potential in vitro

presumably reflecting conversion to styrene oxide. There is no convincing evidence from available animal and human data that styrene possesses significant mutagenic/clastogenic potential in vivo.

Carcinogenicity Remarks Styrene : Chronic inhalation resulted in hyperplasia and fibrosis and an

increased incidence of late onset lung tumors in mice, which are believe to have arisen through a non-genotoxic mechanism. Tumor incidence in rats was unaffected after chronic inhalation exposure. there is no convincing evidence that styrene possesses significant carcinogenic potential in humans.

Reproductive toxicity

Remarks Styrene : Results from reproductive toxicity studies in animals exposed

via drinking water or inhalation have shown no evidence of selective toxicity to the testis or ovary or adverse effects on fertility.

Teratogenicity Remarks Styrene : Results from animal studies demonstrate that styrene is not a

teratogen, nor is it fetotoxic at sub-maternally-toxic treatment levels. No selective effects on nervous system development have been reported. Some indication of developmental delay was observed in pups from dams exposed to high dose levels (500 ppm) however these findings were attributed to decreased pup body weight rather than a selective effect on the offspring.

Target Organ Systemic Toxicant - Repeated exposure

Styrene : Remarks: Results from repeat-dose toxicity studies demonstrate that the mouse is highly sensitive to styrene-induced toxicity, with hyperplasia and fibrosis in lung tissue and atrophy and degeneration of nasal olfactory epithelium after chronic exposure. Mild nasal changes were also observed in the rat. Mechanistic studies demonstrate greater formation of locally toxic products in mouse nose and lung, and provide a metabolic basis for these species differences in



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susceptibility (negligible metabolism likely in human respiratory tract). There is clear evidence that styrene causes a specific adverse effect on hearing in laboratory animals after long-term exposure; additionally there is an indication for styrene-induced hearing losses in humans. Minor impairment of color discrimination has been reported in workers occupationally exposed to styrene, however the magnitude of the change is small suggesting it is of negligible toxicological or clinical significance.

12. Ecological information

12.1 Toxicity

Toxicity to fish Styrene : LC50: 4.02 mg/l

Exposure time: 96 HOUR Species: Pimephales promelas (fathead minnow) Remarks: Toxic to fish.

Toxicity to daphnia and other aquatic invertebrates. Styrene : EC50: 4.7 mg/l

Exposure time: 48 HOUR Species: Daphnia magna. Remarks: This material is toxic to aquatic invertebrates (acute exposure).

Toxicity to algae Styrene : EC50: 4.9 mg/l

Exposure time: 72 HOUR Species: Pseudokirchneriella subcapitata

Toxicity to daphnia and other aquatic invertebrates. (Chronic toxicity) Styrene : NOEC: 1.01 mg/l

Exposure time: 21 d Species: Daphnia magna (Water flea)

12.2 Persistence and degradability

Biodegradability Styrene : Remarks:

Readily biodegradable in aerobic conditions.

12.3 Bioaccumulative potential



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Bioaccumulation Styrene : Remarks:

This material is not expected to bioaccumulate.

12.4 Mobility in soil

Surface tension : Note: Surface activity is not expected or predicted based on structural considerations.

Distribution among environmental compartments Styrene : Remarks:

The atmosphere is the main environmental compartment for releases of styrene. In water, volatilization will result in substantial losses to the atmosphere with a half-life of approximately 3 hours . A calculated Koc value of 352 indicates no significant potential for geoaccumulation.

12.5 Results of PBT and vPvB assessment

Styrene : This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)., This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

12.6 Other adverse effects

Additional ecological information Styrene : Toxic to fish, invertebrates and microorganisms, however,

substantial aquatic exposure is not expected based on the volatile nature of this material.

13. Disposal considerations

13.1 Waste treatment methods

Product : Contaminated product, soil, water, container residues and spill cleanup materials may be hazardous wastes. Comply with applicable local, state or international regulations concerning solid or hazardous waste disposal and/or container disposal. Contaminated product, soil or water should be considered dangerous due to potential evolution of flammable vapor. Proper grounding procedures to avoid static electricity should be followed. The product should not be allowed to enter drains, water courses or the soil.

14. Transport information



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ADR UN-Number : 2055 UN proper shipping name : STYRENE MONOMER, STABILIZED Transport hazard class(es) : 3 Packing group : III Classification Code : F1 Hazard identification No : 39 Labels : 3 Tunnel restriction code : D/E Environmentally hazardous : no

IMDG UN-Number : 2055 Description of the goods : STYRENE MONOMER, STABILIZED Class : 3 Packing group : III Labels : 3 EmS Number 1 : F-E EmS Number 2 : S-D

Marine pollutant : no

RID UN-Number : 2055 Description of the goods : STYRENE MONOMER, STABILIZED Transport hazard class(es) : 3 Packing group : III Classification Code : F1 Hazard identification No : 39 Labels : 3 Environmentally hazardous : no

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Water contaminating class (Germany)

: WGK 2 water endangering

US (ACGIH) : Not classifiable as a human carcinogen.

International Agency for Research on Cancer

: Possibly Carcinogenic to Humans Monograph 82 [2002], Monograph 60 [1994]

Notification status All ingredients are on the following inventories or are exempted from listing Country Notification Australia AICS Canada DSL China IECS European Union EINECS Japan ENCS/ISHL Korea ECL



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Philippines PICCS United States of America TSCA New Zealand NZIoC

Contact [email protected] for additional global inventory information.

15.2 Chemical Safety Assessment A Chemical Safety Assessment has been carried out for this substance.

16. Other information Material safety datasheet sections which have been updated: First Edition Updated with substance registration requirements according to EC 1907/2006 Annex II and (EC) No.1272/2008 CLP. November 29 2010 Full text of R-phrases referred to under sections 2 and 3

R10 Flammable. R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure

through inhalation. R65 Harmful: may cause lung damage if swallowed.

Full text of H-Statements referred to under sections 2 and 3.

H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H372 Causes damage to organs through prolonged or repeated exposure if

inhaled.

Disclaimer

Multiple legal entities and registration numbers may be displayed in Section 1. The Recipient shall refer to the shipping documents to identify the legal entity that supplied this product. This document is generated for the purpose of distributing health, safety, and environmental data. Information is correct to the best of our knowledge at the date of the MSDS publication. It is not a specification sheet nor should any displayed data be construed as a specification. The information on this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,



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Disclaimer

damage, or expense arising out of or in any way connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product, this MSDS information may not be applicable.



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Annex Section 1 Exposure Scenario Title Title Manufacturing of styrene CAS: 100-42-5

Sector of Use: SU3, SU8 Process Categories: PROC1, PROC2, PROC8a, PROC8b, PROC15

Use Descriptor

Environmental Release Categories: ERC1 Processes, tasks, activities covered Manufacture of the substance. Includes recycling/ recovery,

material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory activities

Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product characteristics Physical form of product Liquid, vapour pressure 0.5 - 10 kPa [OC4]. Concentration of substance in product Covers percentage substance in the product up to 100 %

(unless stated differently) [G13]. Amounts used No Limit Frequency and duration of use Covers daily exposures up to 8 hours (unless stated

differently) [G2]. Other Operational Conditions affecting worker exposure

Assumes a good basic standard of occupational hygiene is implemented [G1].

Contributing Scenarios Risk Management Measures Number of contributing Scenario 12 Use in contained systems [CS38]. De-hydrogenation Reactor PROC 2

Handle substance within a closed system [E47].

Use in contained systems [CS38]. Condensation of crude styrene - water separation PROC 2


Use in contained systems [CS38]. Vacuum Distillation PROC 2


Additivation and stabilisation [CS69]. Addition of inhibitors or retardants in distillators PROC 8b

Ensure material transfers are under containment or extract ventilation [E66].

Process sampling [CS2]. Sampling from reactors/condensors/distillators PROC 8a

Use a sampling system designed to control exposure [E89].

Laboratory activities [CS36]. Laboratory - Quality Control PROC 15

No specific measures identified [EI18].

Material transfers [CS3]. Transfert from distillator to storage tanks via pipelines. PROC 1

Transfer via enclosed lines [E52].No other specific measures identified [EI20].

Additivation and stabilisation [CS69]. Stabiliser addition for storage and transport

Ensure material transfers are under containment or extract ventilation [E66].



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PROC 8b

Material transfers [CS3]. Unloading storage tanks for road, rail or boat transport PROC 8b

Clear transfer lines prior to de-coupling [E39].Ensure operation is undertaken outdoors [E69]. Avoid carrying out activities involving exposure for more than 1 hour [OC27]

Equipment maintenance [CS5]. Manufacturing equipment maintenance: opening and cleaning manufacturing equipment for maintenance purposes PROC 8b

Avoid carrying out activities involving exposure for more than 1 hour [OC27]

Material transfers [CS3]. Waste management : recovery using condensation or adsorption/ desorption processes PROC 2


Material transfers [CS3]. Waste management : transfer of process wastes to storage containers: off-line in workplace PROC 8b


Section 3 Exposure Estimation 3.1. Health Used of ECETOC TRA Version 2 with modifications. Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Predicted exposures are not expected to exceed the

DN(M)EL when the Risk Management Measures/Operational Conditions outlined in Section 2 are implemented [G22]. Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels [G23].

Section 1 Exposure Scenario Title Title Continuous mass polymerisation of Polystyrene (HIPS and

GPPS) CAS: 100-42-5 Sector of Use: SU3, SU12 Process Categories: PROC2, PROC8a, PROC8b, PROC9, PROC14, PROC15

Use Descriptor

Environmental Release Categories: ERC6c Processes, tasks, activities covered Manufacture of polymers from monomers in continuous and

batch processes, include sparging, discharging, and reactor maintenance and immediate polymer product formation.



differently) [G2].



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Other Operational Conditions affecting worker exposure


Contributing Scenarios Risk Management Measures Number of contributing Scenario 14 Material transfers [CS3]. Loading tank storage from road, rail or boat transportPROC 8b

Clear transfer lines prior to de-coupling [E39].Avoid carrying out activities involving exposure for more than 1 hour [OC27]

Continuous process [CS54]. Styrene Storage in tanks PROC 2


Continuous process [CS54]. Charging reactor via pipeline PROC 2


Material transfers [CS3]. Heat exchange and agitator in reactor PROC 2


Continuous process [CS54]. Devolatilisation tower PROC 2


Continuous process [CS54]. Recycling styrene from tower to rector via pipeline PROC 2


Process sampling [CS2]. Sampling from reactors/devolatilisation tower PROC 8a




Extrusion and masterbatching [CS88]. Extruder - Pelletizing PROC 14

Limit the substance content in the product to 5% [OC17].

Small package filling [CS7]. Small package filling - Packaging of product PROC 9




Bulk transfers [CS14]. Finished product Loading of road tanker, railcar, container PROC






Section 3 Exposure Estimation



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3.1. Health Used of ECETOC TRA Version 2 with modifications. Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Predicted exposures are not expected to exceed the


Section 1 Exposure Scenario Title Title Batch suspension polymerisation of Polystyrene (HIPS and

GPPS) CAS: 100-42-5 Sector of Use: SU3, SU12 Process Categories: PROC2, PROC3, PROC8a, PROC8b, PROC9, PROC14, PROC15

Use Descriptor









Material transfers [CS3]. Styrene Storage in tanks PROC 2


Material transfers [CS3]. Charging reactors via pipeline PROC 3

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]

Batch process [CS55]. Dispersing and heat in reactor PROC 3


Batch process [CS55]. Washed and dried tanks PROC 3


Process sampling [CS2]. Sampling from reactors/tanks PROC 8a




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Operation of solids filtering equipment [CS117]. Pelletizing PROC 14














Section 1 Exposure Scenario Title Title Production of Expandable Polystyrene CAS: 100-42-5

Sector of Use: SU3, SU12 Process Categories: PROC2, PROC3, PROC8a, PROC8b, PROC9, PROC14, PROC15

Use Descriptor



Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product characteristics Physical form of product Liquid, vapour pressure 0.5 - 10 kPa [OC4].



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Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].

Amounts used No Limit Frequency and duration of use Covers daily exposures up to 8 hours (unless stated






Handle substance within a closed system [E47]. 0



Batch process [CS55]. Dispersing and heat in reactor PROC 3








Operation of solids filtering equipment [CS117]. Pelletizing PROC 14










Material transfers [CS3]. Waste management : transfer of process wastes to storage containers: off-line in workplace




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PROC 8b



Section 1 Exposure Scenario Title Title Production of Styrenic Copolymers CAS: 100-42-5

Sector of Use: SU3, SU12 Process Categories: PROC2, PROC3, PROC8a, PROC8b, PROC9, PROC15

Use Descriptor







Contributing Scenarios Risk Management Measures Number of contributing Scenario 13 Material transfers [CS3]. Loading tank storage from road, rail or boat transport PROC 8b






Batch process [CS55]. Dissolving and polymerisation reactor PROC 3


Batch process [CS55]. Suspension reactor PROC 3




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Section 1 Exposure Scenario Title Title Manufacturing of UP/VE resins and formulated resins

(Gelcoat, Colour Paste, Putty, Bonding paste / Adhesive, etc.) CAS: 100-42-5 Sector of Use: SU3, SU12 Process Categories: PROC1, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC15

Use Descriptor

Environmental Release Categories: ERC2 Processes, tasks, activities covered Processing of formulated polymers including material

transfers, additives handling, moulding, curing and forming activities, material re-works, storage and associated maintenance.



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Assumes a good basic standard of occupational hygiene is implemented [G1]. , Operation is carried out at elevated temperature (> 20°C above ambient temperature) [OC7].

Contributing Scenarios Risk Management Measures Number of contributing Scenario 12 General exposures [CS1]. Use in contained batch processes [CS37]. PROC 1

Use in semi-automated and predominantly enclosed filling lines [E41]. Provide a good standard of general ventilation. Natural ventilation is from windows and doors etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Ensure operatives are trained to minimise exposures [EI119]. Wear suitable gloves tested to EN374 [PPE15].

Bulk transfers [CS14]. Receipt and storage of raw materials in bulk or as packed goods, indoor and outdoor; Raw material assembly and charging; dispensing of liquids and solids via pipeline; PROC 3

Use in semi-automated and predominantly enclosed filling lines [E41]. Use bulk or semi-bulk handling systems [E43]. Provide extract ventilation to points where emissions occur [E54]. Ensure operatives are trained to minimise exposures [EI119]. Wear suitable gloves tested to EN374 [PPE15].

General exposures (closed systems) [CS15]. Dissolving linear UP/VE polymer into styrene in blending vessel (or dissolver) PROC 3

Use in semi-automated and predominantly enclosed filling lines [E41]. Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Wear suitable gloves tested to EN374 [PPE15].

Material transfers [CS3]. All internal transport Raw material assembly and charging / raw material dispensing of liquids and solids manually from bulk storage or packed goods into blending tank PROC 4

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Provide extract ventilation to points where emissions occur [E54]. Wear suitable gloves tested to EN374 [PPE15].

Drum/batch transfers [CS8]; Pouring from small containers [CS9]; Transfer from/pouring from containers [CS22]; Mixing operations (open systems) [CS30]. Mixing liquid and solid components / into final formulated resin in blending vessel; Examples are gelcoat blending and compounding PROC 5

Provide extract ventilation to points where emissions occur [E54]. Keep lids of containers closed during blendingWear suitable gloves tested to EN374 [PPE15].

Process sampling [CS2]. Sampling from blender PROC 4

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Avoid dip sampling. [E42]. Wear suitable gloves tested to EN374 [PPE15].



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Laboratory activities [CS36]. All laboratory activities Quality control work of samples from reactor and blending vessel; R&D work including handling of samples from 1 kg to 1 drum PROC 15

Carry out in a vented booth or extracted enclosure [E57]. Wear suitable gloves tested to EN374 [PPE15].

Bulk transfers [CS14]. All activities related to transport finished product to customer Dispensing final UP/VE resin (linear UP/VE polymer + styrene + additives) / into storage tank, IBC, drum or pail PROC 9

Fill containers/cans at dedicated fill points supplied with local extract ventilation [E51]. Wear suitable gloves tested to EN374 [PPE15].

Bulk transfers [CS14]. All activities related to transport finished product to customer Dispensing final UP/VE resin (linear UP/VE polymer + styrene + additives) into roadtanker . Tier2 assessment has been done to prove safe use of styrene PROC 8b

Use bulk or semi-bulk handling systems [E43]. Wear suitable gloves tested to EN374 [PPE15].

Equipment cleaning and maintenance [CS39]. Cleaning and maintenance of blending vessel, roadtankers etc. PROC 3

Drain down and flush system prior to equipment break-in or maintenance [E55]. Apply vessel entry procedures including use of forced supplied air [AP15]. Wear suitable gloves tested to EN374 [PPE15].

Equipment cleaning and maintenance [CS39]. Cleaning and maintenance of pipes, pumps, filters, etc. PROC 8a

Drain down system prior to equipment break-in or maintenance [E65]. Drain or remove substance from equipment prior to break-in or maintenance [E81]. Wear suitable gloves tested to EN374 [PPE15].

Disposal of wastes [CS28]. Waste management / handling and storage of waste for removal for off-site treatment or for on-site treatment like incineration and/or biological waste water treatment PROC 8a

Provide a good standard of general ventilation. Natural ventilation is from windows and doors etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. Dispose of empty containers and wastes safely [C&H8]. Dispose of waste in accordance with environmental legislation [C&H11]. Avoid carrying out activities involving exposure for more than 1 hour [OC27]. Wear suitable gloves tested to EN374 [PPE15]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Section 3 Exposure Estimation 3.1. Health Use of ECETOC TRA Version 2 with modificatations. Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Predicted exposures are not expected to exceed the


Section 1 Exposure Scenario Title Title FRP manufacturing in an industrial setting, using UP/VE

resins and/or formulated resins (gelcoat, bonding paste, putty etc.) CAS: 100-42-5

Use Descriptor Sector of Use: SU3, SU12



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Process Categories: Proc : 3, 5, 7, 8a, 10, 13, 14, 15 Environmental Release Categories: ERC6d

Processes, tasks, activities covered Processing of formulated polymers including material transfers, moulding and forming activities, material re-works and associated maintenance.




Assumes a good basic standard of occupational hygiene is implemented [G1]. , Assumes activities are at ambient temperature (unless stated differently) [G17].

Contributing Scenarios Risk Management Measures Number of contributing Scenario 14 Rolling, Brushing [CS51]; Roller, spreader, flow application [CS98] All open mould applications where resins is applied by brushing, rolling and other low energy spreading operations; Examples are handlamination, gelcoatbrushing, filament winding PROC 10

Provide a good standard of general ventilation (10 to 15 air changes per hour) [E40]. Use long handled brushes and rollers where possible [E58]. Ensure the ventilation system is regularly maintained and tested [E74]. Dispose of empty containers and wastes safely [C&H8]. Wear suitable gloves tested to EN374 [PPE15]. Wear suitable coveralls to prevent exposure to the skin [PPE27].

Spraying [CS10]; Spraying (automatic/robotic) [CS97] All open mould applications where resins is applied by spraying, either manually or automated or by robot. Examples are spray lamination, gelcoat spraying and "chop-hoop" filament winding PROC 7

Carry out in a vented booth or extracted enclosure [E57]. Ensure the ventilation system is regularly maintained and tested [E74]. Dispose of empty containers and wastes safely [C&H8]. Wear suitable gloves tested to EN374 [PPE15]. Wear suitable coveralls to prevent exposure to the skin [PPE27].

Spraying [CS10]; Spraying (automatic/robotic) [CS97] All open mould applications where resins is applied by spraying, either manually or automated or by robot. Examples are spray lamination, gelcoat spraying and "chop-hoop" filament winding PROC 7

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Use long handled tools where possible [E50]. Carefully pour from containers [E62]. Wear suitable gloves tested to EN374 [PPE15]. Wear suitable coveralls to prevent exposure to the skin [PPE27]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Dipping, immersion and pouring [CS4]; Rolling, Brushing [CS51]; Roller, spreader, flow application [CS98] Application of repair putties; Application of bonding pastes / adhesives. PROC 10

Limit the substance content in the product to 25% [OC18]. Provide a good standard of general ventilation (10 to 15 air changes per hour) [E40]. Wear suitable gloves (tested to EN374) and eye protection [RPE19].



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Dipping, immersion and pouring [CS4]; Continuous process [CS54]. Continuous processes with open impregnation steps, such as pultrusion with open impregnation baths and (semi-) continuous production of flat laminates PROC 13

Provide extract ventilation to points where emissions occur [E54].

Casting operations [CS32]; Mixing operations (open systems) [CS30]. Casting and mixing operations in (semi-) open containers. Examples are centrifugal casting, casting of polymer concrete and artificial marble and the manufacturing of SMC / BMC/ TMC, etcPROC 5

Limit the substance content in the product to 25% [OC18]. Provide extract ventilation to points where emissions occur [E54]. Wear suitable gloves tested to EN374 [PPE15].

General exposures (closed systems) [CS15]. Mixing liquid and solid components / into final formulated resin in blending vessel; Examples are gelcoat blending and compounding, formulation of repair putties, bonding pastes, chemical anchoring, etc PROC 5

Handle substance within a predominantly closed system provided with extract ventilation [E49]. Provide a good standard of general ventilation (10 to 15 air changes per hour) [E40]. Put lids on containers immediately after use [E9]. Wear suitable gloves tested to EN374 [PPE15].

Material transfers [CS3]; Automated process with (semi) closed systems [CS93]; Use in contained batch processes [CS37]. Resin injection and transfer processes, such as vacuüm infusion, RTM, impregnation of sewer relining sleeves PROC 3

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Put lids on containers immediately after use [E9]. Wear suitable gloves tested to EN374 [PPE15].

Material transfers [CS3]; Production or preparation or articles by tabletting, compression, extrusion or pelletisation [CS100]; Treatment by heating [CS129]; Batch processes at elevated temperatures [CS136]. Processes where curing of UP / VE resins takes place at high temperature. Examples are pultrusion with injection dies and processing of SMC / BMC / TMC, etc PROC 14

Limit the substance content in the product to 25% [OC18]. Provide a good standard of general or controlled ventilation (3 to 5 air changes per hour) [E40] or:[G9] Provide the operation with a properly sited receiving hood [E71]. Wear suitable gloves tested to EN374 [PPE15].

Material transfers [CS3]. Product delivery/storage - delivery of bulk and packaged products - outdoor / indoor PROC 3

Transfer via enclosed lines [E52]. Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11].

Drum/batch transfers [CS8]; Pouring from small containers [CS9]; Transfer from/pouring from containers [CS22]; Mixing operations (open systems) [CS30]. Loading of mixing equipment; Preparation of material for application; (liquid products) - batch, indoor PROC

Provide extract ventilation to points where emissions occur [E54]. Put lids on containers immediately after use [E9]. Wear suitable gloves tested to EN374 [PPE15].



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5

Equipment maintenance [CS5]; Maintenance of small items [CS18]. Equipment cleaning and maintenance, open indoor PROC 8a

Provide extract ventilation to points where emissions occur [E54]. Wear suitable gloves tested to EN374 [PPE15].

Laboratory activities [CS36]. Quality control work of samples from blending vessel; R&D work including handling of samples from 1 kg to 1 drum PROC 15


Disposal of wastes [CS28]. Handling of non cured waste; Waste management / handling and storage of waste for removal for off-site treatment or for on-site treatment like incineration and/or biological waste water treatment PROC 8a

Provide extract ventilation to points where emissions occur [E54]. Contain and dispose of waste according to local regulations [C&H14]. Put lids on containers immediately after use [E9]. Wear suitable gloves tested to EN374 [PPE15].



Section 1 Exposure Scenario Title Title FRP manufacturing in a professional setting, using UP/VE

resins and/or formulated resins (gelcoat, bonding paste, putty etc.) CAS: 100-42-5

Use Descriptor Sector of Use:SU22, SU12 Process Categories: Proc : 3, 4, 5, 8a, 10, 11 Environmental Release Categories: ERC6c Processes, tasks, activities covered Processing of formulated polymers including material

transfers, moulding and forming activities, material re-works and associated maintenance.



differently) [G2].



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Assumes a good basic standard of occupational hygiene is implemented [G1]. , Assumes activities are at ambient temperature (unless stated differently) [G17].

Contributing Scenarios Risk Management Measures Number of contributing Scenario 9 Rolling, Brushing [CS51]; Roller, spreader, flow application [CS98] All open mould applications where resins is applied by brushing, rolling and other low energy spreading operations; Examples are handlamination, gelcoatbrushing, semi- continuous production of flat panels and laminates PROC 10

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Use long handled brushes and rollers where possible. [E58]. Wear suitable gloves tested to EN374 [PPE15]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Spraying [CS10]. All open mould applications where resins is applied by spraying. Examples are spray lamination and gelcoat spraying PROC 11

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Keep people not involved in the activity, away from the operation. Avoid carrying out activities involving exposure for more than 4 hours [OC28]. Wear suitable gloves tested to EN374 [PPE15]. Wear a full face respirator conforming to EN140 with Type A filter or better [PPE24].

Dipping, immersion and pouring [CS4]; Rolling, Brushing [CS51]; Roller, spreader, flow application [CS98] Application of repair putties; Application of bonding pastes / adhesives. PROC 10

Limit the substance content in the product to 25% [OC18]. Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Wear suitable gloves tested to EN374 [PPE15]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Dipping, immersion and pouring [CS4]; Rolling, Brushing [CS51]; Roller, spreader, flow application [CS98] Application of floorings, mastics, coatings, castings PROC 10

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Wear suitable gloves tested to EN374 [PPE15]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Material transfers [CS3]; Pouring from small containers [CS9]. Preparation of material for application (liquids) - transfer of material from one container to another; Formulating / blending resins, gelcoats, bonding pastes, putties etc. in blending vessels PROC 5

Use drum pumps or carefully pour from container [E64]. Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Put lids on containers immediately after use [E9]. Wear suitable gloves tested to EN374 [PPE15]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Use in contained batch processes [CS37]. Sewer relining operation PROC 4

Wear suitable gloves tested to EN374 [PPE15]. Wear a respirator conforming to EN140 with Type A filter or better [PPE22].

Use in contained batch processes [CS37]. Application of chemical anchoring PROC 3

Wear suitable gloves tested to EN374 [PPE15].

Equipment maintenance [CS5]; Maintenance of small items [CS18]. Equipment cleaning and maintenance, open indoor PROC 8a

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Avoid carrying out activities involving exposure for more than 1 hour [OC27].Wear suitable gloves tested to EN374 [PPE15].



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Disposal of wastes [CS28]. Handling of non cured waste; Waste management / handling and storage of waste for removal for off-site treatment or for on-site treatment like incineration and/or biological waste water treatment PROC 8a

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11]. Dispose of empty containers and wastes safely [C&H8]. Avoid carrying out activities involving exposure for more than 1 hour [OC27]. Wear suitable gloves tested to EN374 [PPE15].



Section 1 Exposure Scenario Title Title Production of Styrene Butadiene Rubber (SBR) CAS: 100-42-

5 Sector of Use: SU3, SU11 Process Categories: PROC2, PROC3, PROC8a, PROC8b, PROC9, PROC15

Use Descriptor













Batch process [CS55]. Polymerisation reactor PROC 3




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Batch process [CS55]. Vacuum steam distillation PROC 3


Batch process [CS55]. Coagulation reactor PROC 3


Batch process [CS55]. Drying tank PROC 3


Material transfers [CS3]. Recycling styrene from distillator to reactor via pipeline PROC 3


Process sampling [CS2]. Sampling from reactors PROC 8a

Use a sampling system designed to control exposure [E89].0




Limit the substance content in the product to 5% [OC17].0











Section 1 Exposure Scenario Title Title Production of Styrene Butadiene Latex (SBL) CAS: 100-42-5 Use Descriptor Sector of Use: SU3, SU11 Process Categories: PROC2, PROC3, PROC8a, PROC8b,



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PROC9, PROC15 Environmental Release Categories: ERC6c Processes, tasks, activities covered Manufacture of polymers from monomers in continuous and












Batch process [CS55]. Polymerisation reactor PROC 3


Batch process [CS55]. Vacuum Steam distillation PROC 3


Material transfers [CS3]. Recycling styrene from distillator to reactor via pipeline PROC 3


Process sampling [CS2]. Sampling from reactors PROC 8a










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Section 1 Exposure Scenario Title Title Production of Styrene Isoprene Copolymers CAS: 100-42-5


Use Descriptor













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Section 1 Exposure Scenario Title Title Production of other Styrene based polymeric dispersions

CAS: 100-42-5



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Use Descriptor





























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Section 1 Exposure Scenario Title Title Production of filled Polyols CAS: 100-42-5


Use Descriptor







Contributing Scenarios Risk Management Measures Number of contributing Scenario 13 Material transfers [CS3]. Loading tank storage from road, rail or boat transport PROC 8b

Clear transfer lines prior to de-coupling [E39].Avoid carrying out activities involving exposure for more than 1 hour [OC27].



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Handle substance within a closed system [E47]. 0










Use a sampling system designed to control exposure [E89].00




Limit the substance content in the product to 5% [OC17].0













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Section 1 Exposure Scenario Title Title Consumer use of Liquid UP resin for repair purposes CAS:

100-42-5 Sector of Use (SU code) SU 21 Private households (= general public = consumers) Use Descriptor (PC codes) PC9a:Coatings and paints, fillers putties, thinners Processes, tasks, activities covered Covers consumer uses in liquid resins Section 2 Operational conditions and risk management measures Section 2.1 Control of consumer exposure Product characteristics Physical form of product Liquid, vapour pressure > 10 Pa [OC15]. Concentration of substance in product Unless otherwise stated, cover concentrations up to 35%

[ConsOC1]. Amounts used Unless otherwise stated, covers use amounts up to 1000 g

[ConsOC2]. Frequency and duration of use / exposure

Unless otherwise stated, covers use frequency up to 5 times per day [ConsOC4]; covers exposure up to 0.5 hours per event [ConsOC14].

Other Operational Conditions affecting consumer exposure

Unless otherwise stated, covers skin contact area up to 108 cm2 [ConsOC5].

Section 2.1.1 Product categories Number of consumer uses 1 PC9a:Coatings and paints, fillers putties, thinners--

OC: Unless otherwise stated, covers concentrations up to 35% [ConsOC1]. Covers use up to 365 days/year[ConsOC3]. Covers use up to 5 times/day of use[ConsOC4]. Covers skin contact area up to 108,00 cm2 [ConsOC5]. For each use event, covers use amounts up to 1000g [ConsOC2]. Covers use in a one car garage (34m3) under typical ventilation [ConsOC10]. Covers use in room size of 34m3[ConsOC11]. For each use event, covers exposure up to 0,50hr/event[ConsOC14]. RMM: No specific RMMs identified beyond those OCs stated

Section 1 Exposure Scenario Title Title Consumer use of Resin paste used as fillers/putties CAS:

100-42-5 Sector of Use (SU code) SU 21 Private households (= general public = consumers) Use Descriptor (PC codes) PC9b:Fillers, putties, plasters, modeling clay Processes, tasks, activities covered Covers consumer uses in resin pastes Section 2 Operational conditions and risk management measures Section 2.1 Control of consumer exposure Product characteristics Physical form of product Liquid, vapour pressure > 10 Pa [OC15]. Concentration of substance in product Unless otherwise stated, cover concentrations up to 35%

[ConsOC1]. Amounts used Unless otherwise stated, covers use amounts up to 100 g

[ConsOC2]. Frequency and duration of use / exposure

Unless otherwise stated, covers use frequency up to 5 times per day [ConsOC4]; covers exposure up to 10 minutes per event [ConsOC14].


Unless otherwise stated, covers skin contact area up to 22 cm2 [ConsOC5].



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Section 2.1.1 Product categories Number of consumer uses 1 PC9b:Fillers, putties, plasters, modelling clay--

OC: Unless otherwise stated, covers concentrations up to 5,5% [ConsOC1]. covers use up to 365 days/year[ConsOC3]. covers use up to 5 times/day of use[ConsOC4]. covers skin contact area up to 22,00 cm2 [ConsOC5]. for each use event, covers use amounts up to 100g [ConsOC2]. Covers use in a one car garage (34m3) under typical ventilation [ConsOC10]. covers use in room size of 34m3[ConsOC11]. for each use event, covers exposure up to 0,17hr/event[ConsOC14]. RMM: No specific RMMs identified beyond those OCs stated

Documents

Report Styrene Monomer Lyondell