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APPENDIX -VIII
REPORT ON
INTELLECTUAL PROPERTY RIGHTS,
PUBLIC PRIVATE PARTNERSHIP,
SAFETY, STANDARDS, AWARENESS
AND
HUMAN RESOURCE DEVELOPMENT FOR
HYDROGEN ENERGY AND FUEL CELLS
Prepared by
Sub-Committee on IPR, PPP, Safety, Standards, Awareness
and HRD for Hydrogen Energy and Fuel Cells of
Steering Committee on Hydrogen Energy and Fuel Cells
Ministry of New and Renewable Energy,
Government of India, New Delhi
June, 2016
PREFACE
In today's automotive and industrialized World, it is needed to adopt
eco-friendly technologies to prevent climate change, reduce the toxic
emissions and enhance energy security. This is all possible, if it is innovated
to develop new technologies related to hydrogen energy and fuel cells.
Hydrogen gives water vapors while releasing energy on combustion /
oxidation. Therefore, it has been recognized as the most appropriate fuel for
future in view of the reduction of the dependence on fossil fuels, conservation
of green environment and reduction in greenhouse effect. Fuel cell
technologies have a bright future and may be deployed in automobiles for
transportation as well as power generation for centralized, decentralized,
portable and micro applications. The important dimensions for the
introduction of hydrogen and fuel cell technologies are Intellectual Property
Right (IPR), Public Private Partnership (PPP), Safety, Awareness, Standards
and Human Resource Development (HRD), which are to be given adequate
emphasis to promote this technology in the society.
India being a highly populated country is also concerned about its
contribution to climate change and therefore has been giving significant
importance to development and commercialization of new and renewable
energy technologies e.g. solar and wind. Hydrogen energy has also been a
focus of attention for quite some time. Unfortunately, required emphasis could
not be given primarily due to resource crunch and therefore the progress is
lagging far behind in the global race. Under this premises, the Ministry of New
and Renewable Energy, Government of India, New Delhi constituted a high
power Steering Committee to prepare a status report and way forward for
hydrogen energy and fuel cell technology in this country. One of the five Sub-
Committees of the Steering Committee was entrusted under my leadership
with the responsibility of preparing this particular document concerning IPR,
PPP, Safety, Awareness, Standards and HRD with regard to hydrogen energy
and fuel cells.
I express my sincere gratitude to the members of the Sub-Committee
on IPR, Safety, Awareness, Standards and HRD with regard to hydrogen
energy and fuel cells, other experts (Dr. K. S. Dhathathreyan, Centre for Fuel
Cell Technology, Chennai) for their contribution, Dr. M. R. Nouni, Scientist ‘G’,
Ministry of New and Renewable Energy and also the officials of the Project
Management Unit – Hydrogen Energy and Fuel Cells at the Ministry, Dr. Jugal
Kishor and Dr. S. K. Sharma in particular for their active role in organizing
meetings and preparing this document. Special thanks goes to Dr. S. S.
Thipse, Deputy Director, Indian Automotive Research association, Pune, who
helped me in collecting additional material, integrating it and finalizing the
report.
June, 2016
Mrs. Rashmi Urdhwareshe,
Chairman, Sub-Committee on IPR,
PPP, Safety, Standards, Awareness, and HRD
with regards to Hydrogen and Fuel Cells
Contents
S. No. Subject Page No.
I Composition of Sub-Committee on IPR, PPP, Safety,
Standards, Awareness, and HRD
i
II Terms of Reference iii
III Details of Meetings iv
1 Executive Summary 1
2 Introduction 25
3 Intellectual Property Rights -Hydrogen and Fuel Cells 37
4 Hydrogen Storage Regulations 61
5 Safety Aspects of Hydrogen 79
6 Standards on Hydrogen 101
7 Human Resource Development for Hydrogen and Fuel
Cells
113
8 Awareness about Hydrogen and Fuel Cells 129
9 Public-Private Partnership for Hydrogen Energy and
Fuel cells
137
10 Gap Analysis – Indian vs. International Scenario 145
11 Action Plan and Time Schedule of Activities 155
12 Financial Projections 163
13 Identification of Institutions and Infrastructure 167
14 Centre of Excellence on Hydrogen Vehicle Certification
@ ARAI
171
15 Conclusions and Recommendations 177
16 Bibliography 183
i
I. Composition of Sub-Committee on IPR, PPP, Safety,
Standards, Awareness, and HRD of Hydrogen and Fuel
Cells
1. Mrs. Rashmi H. Urdhwareshe, Director, Automotive Research
Association of India, Pune - Chairman
2. Ms. Varsha Joshi, Joint Secretary / Shri A. K. Dhussa, Adviser
(December, 2013 to March, 2015) / Dr. Bibek Bandyopadhyay, Adviser
(upto December, 2013), MNRE
3. Ms. Iren Cherian, Deputy Secretary (Motor Vehicle Legislation) / Shri U.
D. Bhargava (transferred in October, 2014), Ministry of Road Transport
and Highways, Government of India, New Delhi
4. Shri. Alok Sharma, Deputy General Manager (Alternate Energy), IOCL
R&D, Faridabad - Representative of Ministry of Petroleum and Natural
Gas, Government of India, New Delhi / Also representative of Dr. B.
Basu, Executive Director IOCL R&D, Faridabad (after his retirement on
30.06.2014), Member of this Committee
5. Shri Sanjay Bandyopadhyay, National Automotive Testing and R&D
Infrastructure Project (NATRIP), New Delhi / Shri Neeraj Kumar, Deputy
Secretary, Ministry of Heavy Industries & Public Enterprises,
(Repatriated to Parent Department in January, 2015) / Shri Nitin R.
Gokarn, NATRIP, New Delhi (Repatriated in June, 2014 to Parent Cadre)
– Representative of Ministry of Heavy Industries & Public Enterprises
6. Dr. Hari Om Yadav, Scientist, Council of Scientific Industrial Research,
New Delhi
7. Dr. S. Aravamuthan, Deputy Director, Vikram Sarabhai Space Centre,
Indian Space Research Organization, Thiruvanathapuram
8. Shri P. C. Srivastava, Deputy Chief Controller of Explosives, Petroleum
Explosive & Safety Organization (PESO), Nagpur
9. Prof. Debbrata Das, Indian Institute of Technology Kharakpur, Kharakpur
10. Shri R. K. Jha, Scientist ‘F, Chemical Engineering Department; / ’Shri T.
V. Singh, Scientist ‘F, Mechanical Engineering Department, Bureau of
Indian Standards, New Delhi
ii
11. Mr. Saurabh Rohilla, Shri Jaishankar, Toyota Kirloskar Motors Limited,
Shri. M. Ravi, Ashok Leyland & - Representatives of Society of Indian
Automobile Manufacturers, New Delhi
12. Dr. R.R. Sonde, Executive Vice President, Thermax India -
Representative of Confederation of Indian Industry
13. Executive Director, Centre for High Technology, Noida
14. Shri. Ravi Subramaniam / Shri Piyush Katakwar, Air Products, Pune
15. Dr. S.S. Thipse, Deputy Director, Automotive Research Association of India, Pune
iii
II. Terms of Reference
1. To review present status of filed/granted patents and to suggest the ways
to encourage generation of more intellectual property rights under the R&D
and demonstration projects being supported by Government of India.
2. To guide development of safety measures/ manuals, codes and standards
in accordance with international practices for production, storage,
distribution and handling of Hydrogen as a fuel for various applications.
3. To suggest policy initiatives and financial/ fiscal / regulatory measures
including other measures for promotion of Hydrogen as a clean fuel.
4. To give suggestions for creating awareness among different stakeholders
in the area of Hydrogen energy and fuel cells in the country.
5. To review availability of trained human resource in the area of Hydrogen
energy and fuel cells in the country and suggest ways and means for
development and training of adequate skilled manpower in this emerging
technological area in India and abroad for meeting the requirement of R&D
institutions and the industry in the years to come.
6. To suggest strategy to take up projects in Public-Private Partnership mode
for the development of technologies based on transparency, accountability
and commitment for deliverables.
7. To revisit National Hydrogen Energy Road Map with reference to IPR,
public-private partnership, safety, standards, awareness & HRD.
iv
III. Details of Meetings
The Sub-Committee on IPR, PPP, Safety, Standards, Awareness, and
HRD met on 16.12.2013. Detailed presentations were made and discussions
were held on the activities relating to Intellectual Property Rights (IPR), Public
Private Partnership (PPP), Safety, Standards, Awareness and Human
Resource Development (HRD). The second meeting was held on 31.10.2014
to discuss input write-ups (for the preparation of the draft report) submitted by
the Expert Members of the Sub-Committee. Based on the input material, the
report was drafted and presented in the 4th meeting of Steering Committee on
Hydrogen Energy and Fuel Cells held on 10.07.2015 in MNRE. The Steering
Committee gave some suggestions, which were incorporated in the draft
report. The report was further modified as per the suggestions given and
decisions taken in the meeting of the Chairpersons of all five Sub-Committees
on various aspects of Hydrogen energy and fuel cells viz. Hydrogen
Production; Fuel Cell Development; Transportation through Hydrogen fueled
Vehicles; Hydrogen Storage & Applications other than Transportation and
IPR, Safety, Standards, PPP, Awareness & HRD vehicles held on
11.09.2015, 16.12.2015 and 18.01.2016.
1
EXECUTIVE SUMMARY
2
3
1.0 Executive Summary
1.1 Introduction
1.1.1 Hydrogen is being explored as a fuel for passenger vehicles. It can be
used in fuel cells to power electric motors or burned in internal combustion
engines (ICEs). It is an environmentally friendly fuel that has the potential to
dramatically reduce our dependence on imported oil, but several significant
challenges must be overcome before it can be widely used. This report
focuses on the important dimensions with respect to introduction of Hydrogen
and fuel cell technology namely IPR, Safety, Standards, Awareness and HRD.
1.1.2 A Hydrogen internal combustion engine (ICE) vehicle uses a traditional
ICE that has been modified to use Hydrogen fuel. One of the benefits of
Hydrogen-powered ICEs is that they can run on pure Hydrogen or a blend of
Hydrogen and compressed natural gas (CNG). That fuel flexibility is very
attractive as a means of addressing the widespread lack of Hydrogen fuelling
infrastructure in the near term. The Vehicle Testing has to provide pure
Hydrogen or Hydrogen/CNG blends to the various internal combustion engine
vehicles test. The Vehicle Testing Activity evaluates Hydrogen and HCNG
internal combustion engine vehicles in closed-track and laboratory
environments (baseline performance testing), as well as in real-world
applications – including fleet testing and accelerated reliability testing
(accumulating life-cycle vehicle mileage and operational knowledge within 1 to
1.5 years). Emission testing is also conducted as per Euro norms as notified
in CMVR. Testing Hydrogen internal combustion engine vehicles also
supports development of the Hydrogen infrastructure needed for fuel cell (FC)
vehicles.
1.1.3 Fuel cell vehicles (FCVs), which run on Hydrogen, are currently more
expensive than conventional vehicles, and they are not yet available for sale
to the general public. However, costs have decreased significantly, and
commercially available FCVs are expected within the next few years. It is
clearly seen that the research activities in the field of Fuel Cell & Hydrogen
4
are still in their early phase compared to other nations. Since the activities of
fuel cell and Hydrogen are in early stages, it is inevitable to have more focus
on creating indigenous technology for its commercialization and
industrialization in India. To promote fuel cell technology based innovation,
there must be proper strategies and plans which enhance IPR activities in
India in those specific fields.
1.2 Intellectual Property Rights
1.2.1 As efforts for commercialization of patented technologies have
increased, greater focus has been placed on Manufacturability at volume and
cost effectively- patents have been generated in this area e.g. reducing
components, alternative and cheaper materials, and manufacturing process
driven improvements. It is easier to identify where innovation is likely,
possible, required rather than which patents might be filed. There remains
scope for innovation around durability, performance and cost reduction. They
will be iterative changes unless and until someone identifies a real game
changing step. Innovation is also likely to center around what technology is
being used and for which applications. If a country focuses on automotive
then the innovation will differ and probably be more focussed on the auto
challenges than if, say, the focus is on distributed power which has a wider
scope and is likely to see innovation across a wider spectrum of technologies
and end uses. Innovation is also possible in relation to deployment of FCs in
particular environments and uses- e.g. integration with other technologies or
into particular applications.
1.2.2 Patents tend to be clustered in areas where there has been significant
research, development and investment to date. These include Japan (the
auto and large technology companies), US (auto companies, large technology
companies, military applications) and Europe (auto, technology combined
heat & power applications, electrolyzer technology). Most countries have 1.5
to 2.7 times more fuel cell applications than granted patents on hydrogen.
Reasons for this could be manifold, such as applications filed to block others
5
from taking advantage of a technology or simply a greater amount of research
producing results which are worthy of a patent application.
1.2.3 It is clearly seen India is lagging in IP on Hydrogen and Fuel Cells and
that the research activities in the field of Hydrogen and Fuel Cells are still in
their early phase in India as compared to other nations. Since the activities of
fuel cell and Hydrogen are in early stages, it is inevitable to have more focus
on creating indigenous technology for its commercialization and
industrialization in India. To promote fuel cell technology based innovation
there must be proper strategies and plans which enhance IPR activities in
India in those specific fields.
1.3 Storage
1.3.1 The Gas Cylinders Rules, 2004 are required to be amended for
incorporation of Hydrogen dispensing layout/facilities once Government of
India permits inclusion of Hydrogen as an automotive fuel and CMVR are
suitably amended in this regard. The international standard ISO: 20012 -
Gaseous Hydrogen – Fuelling Station may be useful for establishment of
fuelling stations in the country on trial basis. At present ISO: 15869 is in the
draft stage for Gaseous Hydrogen and Hydrogen blend – Land Vehicle Fuel
Tanks. Since ISO: 15869 (ISO/TC-197) is going to be internationally accepted
code, the same may also be followed in this country as India being ‘P’
Member of the ISO/TC-197 Committee. IS: 15490 & IS: 7285(Part 2) are also
required to be suitably amended for to incorporate Hydrogen-CNG blend and
Hydrogen as automotive cylinders. Further, the following ISO standards may
be useful for Hydrogen storage and dispensing system:-
I. ISO: 13984 – Liquid Hydrogen – Land Vehicle Fuelling System
Interface.
II. ISO: 13985 - Liquid Hydrogen – Land Vehicle Fuel Tanks and PDTS
16111 – Transportable Hydrogen gas storage devices.
III. ISO: 15869 – Gaseous Hydrogen and Hydrogen Blends – Land
Vehicle Fuel Tanks.
IV. ISO: 20012 - Gaseous Hydrogen – Fuelling Station.
6
1.3.2 Compressed hydrogen gases filled in metallic container pose potential
hazard and threat to public life and property let the container explode. Hence,
the Govt. of India vide Notification No.M-1272(1) dated 28/09/1938 has
declared compressed gas filled in a metallic container to be deemed to be an
explosive under Section 17 of the Explosives Act, 1884. Subsequently, in
exercise of powers vested in Section 5 & 7 of the Act, the Govt. framed the
Static & Mobile Pressure Vessels Rules, 1981 to regulate filling, possession,
transport and import of compressed gases in pressure vessels. Vessels of
water capacity exceeding 1000 liters intended for the storage and transport of
compressed gas which is subjected to internal pressure exceeding 1
Atmosphere (Gauge) at maximum working temperature of 55°C including
cryogenic pressure vessel are covered under SMPV(U) Rules, 1981. Under
the SMPV (U) Rules, 1981, it is obligatory to obtain necessary approval/
license for the following:-
i) Manufacture of pressure vessels and their fittings.
ii) Storage of compressed gas in pressure vessels.
iii) Transport of compressed gas in pressure vessels.
iv) Permission for import of pressure vessels.
1.3.3 The Hydrogen safety system design should ensure the safe operation
of the equipment, within design parameters like pressure, temperature,
gas/liquid flow etc. and hence of preventing fire, explosion, release of toxic
materials or criticality which may lead to loss of material and property. This is
achieved by a built-in safety system incorporated in the design to ensure that
operating parameters are not exceeded beyond safety limits through
interlocks which control process parameters and alert operating staff by
audio-visual signals, or by action such as switching off power supply, cutting
off feed etc.
1.3.4 The Government of India has authorized the Petroleum and Explosives
Safety Organization (PESO), Nagpur to administer responsibilities delegated
under the Explosives Act 1884 and Petroleum Act 1934 and the rules made
thereunder related to manufacture, import, export, transport, possession, sale
and use of Explosives, Petroleum products and Compressed gases.
7
Provisions have been made for hydrogen cylinders, valves including
hydrogen dispensing under Gas Cylinders Rules, 2004 and Static & Mobile
Pressure Vessels (Unfired) Rules, 1981.
1.3.5 Rules related to Compressed Natural Gas (CNG) have already been
amended for the mixture of Hydrogen & Methane as automotive fuel.
However, the Gas Cylinders Rules, 2004 as well as Central Motor Vehicle
Rules are yet to be amended to incorporate Hydrogen as automotive fuel.
The approval of cylinder and valve is accorded as per Indian Standards. In
case of foreign manufacturers, only with proven track record, rich
manufacturing experience and a widely distributed market share in developed
countries are only considered for approval.
1.3.6 Type 1 cylinders conforming to IS:7285 (Part 2) 2004/ ISO:9809-1 &
Type 3 cylinders conforming NGV2-2000, EC 79/2009, EN:12245 or any other
internationally recognized standard approved by PESO are permitted for
Hydrogen service. Type 2 & 4 cylinders are not being considered at this stage
owing to various safety issues. Type 3 cylinders manufactured by M/s.
Dynetek are already permitted for Hydrogen application on trial basis.
However, the connecting equipment, valves including Hydrogen dispensing
stations shall be designed and constructed so as to be compatible with the
working pressure of the cylinders.
1.3.7 Components that are in contact with gaseous hydrogen have to be in
conformity with ISO:11114-1 & ISO:11114-2 to ensure suitability of material.
Testing may be carried out as specified in ISO:11114-4 to evaluate material of
construction, so that resistive material may be selected for hydrogen
embrittlement.
1.3.8 The Gas Cylinders Rules, 2004 are required to be amended for
incorporation of Hydrogen dispensing layout/facilities. Once Government
permits to use Hydrogen as an automotive fuel and CMVR are suitably
amended in this regard. The ISO:20012 - Gaseous Hydrogen – Fuelling
Station may be followed for establishment of fuelling stations in the country.
8
1.3.9 At present ISO:15869 is in the draft stage for Gaseous Hydrogen and
Hydrogen blend – Land Vehicle Fuel Tanks. IS:15490 & IS:7285(Part 2) are
also required to be suitably amended for to incorporate Hydrogen-CNG blend
and Hydrogen as automotive cylinders. Further, there are a few ISO
standards (ISO:13984, 13985, 15869, 20012, 5869.3, 22734-1, 17268 -2,
15594:2004 and EIGA DOC 06/02/E, which are useful for hydrogen storage
and dispensing system.
1.3.10 PESO has accorded approval for hydrogen storage (Steel Tube
Cylinders, Type 3 Composite Cylinders including steel cylinder) and
dispensing facilities in the country to various OEMs like M/s. Tata Motor Ltd.,
ISRO/HAL, Mahindra & Mahindra for R&D and demonstration purposes. M/s.
Everest Kanto Cylinders Ltd. is an approved manufacturer for tube cylinders
of water capacity up to 2500 liters for type 1 cylinders conforming to
ISO:11120. M/s. Dynetek, Germany and M/s. Luxfer Gas Cylinders, USA are
also approved manufacturers for Type 3 composite cylinders with working
pressure 350 bar, test pressure 525 bar.
1.3.11 There are many international organizations, which are working closely
for the development hydrogen standards, codes and regulations. In order to
implement hydrogen program in India, testing facilities, standards codes and
regulations for cylinders, components, vehicles and fuel need to be developed
in line with international regulations.
1.3.12 The Bureau of Indian Standards (BIS) under the aegis of Ministry of
Consumer Affairs, Food & Public Distribution, Government of India is engaged
in the formulation, setup and implementation of the Indian Standards for the
Hydrogen as a fuel and its storage. BIS has formed the Gas Cylinders
Sectional Committee MED 16 and Industrial Gases Sectional Committee CHD
6 for formulation of standards. The International and Indian standards are
available on gas cylinders and components, liquid hydrogen, hydrogen fuel,
safety aspects, transportable gas storage devices, fuelling facility operations,
vehicle refueling connection devices, hydrogen generators and metal
9
hydrides. There is no gap between the relevant Indian and International
standards. Indian standards are either adoption of ISO or international
standards used as base standard.
1.4 Safety
1.4.1 In order to ensure safety of vehicles and for technical solutions to these
issues following regulations and standards are critical. Government has
identified the development of regulations and standards as one of the key
requirements for commercialization of Hydrogen-fuelled vehicles. Regulations
and standards will help to overcome technological barriers to
commercialization, facilitate manufacturers’ investment in building Hydrogen-
fuelled vehicles and facilitate public acceptance by providing a systematic and
accurate means of assessing and communicating the risk associated with the
use of Hydrogen vehicles, be it to the general public, consumer, emergency
response personnel or the insurance industry.
1.4.2 Hydrogen is a flammable fuel with backfire and pre-ignition tendencies
and safety aspects are critical in safe handling of the fuel. Hydrogen contains
much less energy than gasoline or diesel on a per-volume basis, making it
difficult to store enough Hydrogen onboard an FCV to go as far as a
comparable gasoline vehicle. Hydrogen standards are being framed globally
which include ISO standards on Hydrogen components and storage. Similar
standards need to be developed in India. Facilities required for Hydrogen
vehicle certification are also covered in the report.
1.4.3 Only a small number of Hydrogen and fuel cell systems and
components required for the Hydrogen economy are in operation today.
Consequently, only limited data is available on the operational and safety
aspects of these new technologies and research is required to understand
Hydrogen’s behaviour as a fuel for both vehicles and stationary applications,
and to support the development of technologies for the detection and safe
management of unscheduled Hydrogen releases or incidents involving
Hydrogen systems. The relevant properties of Hydrogen differ considerably
10
from conventional fuels and the derivation of rules for its safe usage is not
straight forward but relies on careful interpretation of the interacting effects.
Therefore, it is necessary to build trust by demonstrating safety not only in the
large demonstration projects but also by the way in which this vital topic is
addressed. Understanding Hydrogen and Hydrogen system safety needs is
critical for local government officials, fire officers, and the general public.
Emergency personnel must be informed of the special properties of Hydrogen
and trained in the methods used to respond to accidents involving its use.
Public perception and confidence in Hydrogen relies on credibility,
transparency and individual benefit. Improving the understanding of
Hydrogen’s physical properties will help to communicate safety on a technical
and objective basis.
1.5 Standards
1.5.1 Lack of Codes and standards have repeatedly been identified as a
major institutional barrier to deploying Hydrogen technologies and developing
a Hydrogen economy. International Hydrogen Industry has come a long way
in the past 10 years identifying needed standards for commercialization of
Hydrogen energy systems, and participating with Standards Development
Organizations to develop Hydrogen standards. In India development of
standards to allow the installation of Hydrogen energy systems, including
stationary applications and Hydrogen refuelling stations is required. These
efforts, of course, must continue to meet commercialization timeframes. Some
Hydrogen requirements are based on other fuels, such as natural gas, or
based on industrial quantities and uses for Hydrogen. Research is needed to
complete some of the developing codes and standards, and to validate
requirements for the intended quantities and uses. Concurrent with continued
development of appropriate codes and standards, it is important to ensure
high levels of safety and environmental protection. India must now review the
current state of regulations that pertain to the transport of hazardous materials
and determine whether they are adequate for the envisioned Hydrogen
economy.
11
1.5.2 The transition in vehicle fuels from liquid hydrocarbons to gaseous
Hydrogen requires an adaptation of automobile design and safety technology
to the special properties of Hydrogen. In contrast to LPG and gasoline vapor,
Hydrogen is extremely light and rises rapidly in air. In the open this is
generally an advantage, but it can be dangerous in buildings that are not
designed for Hydrogen. Many countries’ building codes, for instance, require
garages to have ventilation openings near the ground to remove gasoline
vapor, but there is often no high level ventilation. Hydrogen released in such a
building collects at ceiling level, and a resulting explosion can be extremely
destructive. Hydrogen has been used widely for more than a hundred years in
large-scale industrial applications. There have been incidents with Hydrogen,
as there have been with other materials including gasoline, LPG and natural
gas. In general, though, experience shows that Hydrogen can be handled
safely in industrial applications as long as users stick to the appropriate
standards, regulations and best practices.
1.5.3 Several organizations are involved in new standards activity in response
to the growth of interest in Hydrogen as a fuel. The National Hydrogen
Association has created Codes and Standards Working Groups on topics
such as hydride storage, electolysers for home use, transportation
infrastructure issues and maritime applications. The Society of Automotive
Engineers, through a Fuel Cell Standards Forum Safety Task Force is
collaborating with the National Highways Authority of India (NHAI) on the
transportation issues. Much of these standards writing is taking place at the
International Organization for Standardization (ISO) level in ISO Technical
Committee 197 (Hydrogen Technologies) with input through the national
organizations. The International Electrotechnical Committee, IEC TC 105
(Fuel Cells}, ISO TC 197, and ISO TC22 SC 21 (Electric Vehicles) are all
involved in fuel cell standards activities.
1.6 Human Resource Development
1.6.1 Human resource development is the key to sustained R&D program on
Hydrogen. Hydrogen and fuel cells are considered in many countries as an
12
important alternative energy vector and a key technology for future
sustainable energy systems in the stationary power, transportation, industrial
and residential sectors. The realization of Hydrogen based economy can
generate a lot of employment throughout the country. Hydrogen production
process and Fuel cell technology requires expertise from various fields such
as electrical, mechanical, chemistry, physics, biotechnology, management
etc. In order to produce skilled manpower resource training needs have to be
identified. It is recommended to constitute Hydrogen chair faculty positions in
IITs for professors working on Hydrogen technologies for the duration of 3
years. Further 50 fellowships should be given to bright scholars for pursuing
their masters or doctoral programs related to Hydrogen technologies. Awards
should be constituted on a national scale with prizes around 1 lakh for
professionals and academia working in promotion of Hydrogen.
1.6.2 Hydrogen fuel cell technologies have the potential to provide significant
employment, economic, and environmental benefits on a national scale. It is
expected that Indian industries would soon participate in the hydrogen
technology development and commercialization which will open up
employment opportunities both in manufacturing of fuel cell systems as well
as their maintenance and also in hydrogen production and delivery
businesses. Many of these jobs require engineering and science backgrounds
related to product and technology development [Chemical engineers,
Electrical engineers, Mechanical engineers, Design Engineers, Application
developers , Product engineers, Materials scientists, Chemists , Laboratory
technicians, Machinists, Power plant and Hydrogen production plant operators
& maintenance staff , Bus, truck and other fleet drivers & maintenance team
of workers.
1.6.3 Adaptation of the hydrogen technologies can proceed effectively only
when all sections of public accept the same. To make it acceptable to general
public, training the decision makers and educating the next generation of
students is an important prerequisite for the long-term success of hydrogen
energy technologies. For this, it is necessary to create a well-trained human
resource base. Educational programs along with demonstration programs will
13
help to achieve high levels of penetration of these technologies. Such
programs should include a hydrogen education program for school teachers
and students providing them with educational materials, training program and
curricula evaluation.
1.7 Awareness
1.7.1 Hydrogen and fuel cells are considered in many countries as an
important alternative energy vector and a key technology for future
sustainable energy systems in the stationary power, transportation, industrial
and residential sectors. The realization of Hydrogen based economy can
generate a lot of employment throughout the country. Hydrogen production
process and Fuel cell technology requires expertise from various fields such
as electrical, mechanical, chemistry, physics, biotechnology, management
etc. A center for excellence is needed for each of the sector associate with
Hydrogen and Fuel Cells production. Employment would increase with
penetration of these technologies in transportation sector and energy sector.
This gives an added boon to the society in terms of decreasing in carbon
footprint. However, as with any major changes in the energy industry, the
transition to a Hydrogen economy will require several decades. Awareness
campaigns are required to inform the general public on the benefit of using
clean fuel like Hydrogen considering the elimination of carbon based
emissions. HRD aspect of Hydrogen technology involves introducing
information on Hydrogen fuel in school curriculum as well as training
programs for technicians and engineers working on the Hydrogen fuel cell
vehicles. Research and development is the key to generate IPR in this
evolving field, which would ultimately benefit the country.
1.7.2 The most important factor for fostering support and decreasing
opposition to the introduction of Hydrogen technologies is increased
knowledge. The general public must be given further education, along with
decision-makers within government and industry, regulators and policy
developers, academics etc. Therefore, information as well as an active
demonstration projects for use of Hydrogen is necessary. Results from
14
previous projects have shown that more extensive information efforts are
needed in conjunction with demonstration projects, such as Hydrogen bus
trials, fork lifts, stationary power etc. In order to maximise the acceptability of
Hydrogen technologies. Several such projects are ongoing across the world.
1.7.3 Awareness resources include traditional print materials, such as fact
sheets, and information available on the Web, and via other forms of media
including audio, CD, and video. Careful attention must be given to cost and to
traditional forms of media/information delivery to which target audiences are
accustomed. The primary distribution mechanism for education and outreach
materials will be the Program Website, via Web pages, databases, electronic
documents, and other interactive tools and resources.
1.8 Public Private Partnership
1.8.1 Coordination between industry and government can facilitate smooth
commercialization of Hydrogen and fuel cell systems. By working together,
timely priorities can be identified to promote commercial deployment of
Hydrogen technologies. Continuation of dialog among all stakeholders, as
well as applicable state agencies, to study the range of codes, standards, and
regulatory activities that are needed to ensure a smooth transition to a
Hydrogen economy, as well as the research to support them is the key.
Through continued coordination, research funding can be targeted at areas
with the greatest needs, consistent with commercialization time frames, and
consistent to support related research work timetables, reducing the need for
duplication of effort.
1.8.2 The public-private partnership focused on advancing Hydrogen
infrastructure to support more transportation energy options for consumers,
including Hydrogen and fuel cell electric vehicles (FCEVs) is the need of the
hour. New partnerships brings together automakers, government agencies,
gas suppliers, and the Hydrogen and fuel cell industries to coordinate
research and identify cost-effective solutions to deploy infrastructure that can
deliver affordable, clean Hydrogen fuel for vehicles. Hydrogen and Fuel cell
15
technologies are an important part of approach to diversify transportation
sector, reduce the dependence on foreign oil and increase competitiveness in
the global market. By bringing together key stakeholders from across the fuel
cell and Hydrogen industry, the partnership will help advance affordable fuel
cell electric vehicles that save consumers money and give drivers more
options. Partnerships bring experts together to identify and solve key
infrastructure challenges, including leveraging low cost gas resources.
1.9 Gap Analysis
1.9.1 From the above, it is clearly seen that the research activities in the field
of Fuel Cell & Hydrogen are still in their early phase compared to other
nations. Since the activities of fuel cell and Hydrogen are in early stages, it is
inevitable to have more focus on creating indigenous technology for its
commercialization and industrialization in India. To promote fuel cell
technology based innovation, there must be proper strategies and plans which
enhance Hydrogen activities in India in those specific fields.
1.9.2 Following are some specific gap issues between India and the
developed countries.
1.9.2.1 After Market Vehicle Enforcement
It is to be noted how regulations will be enforced on after-market
repairs and end-of-vehicle life. For example, Hydrogen storage tanks may not
be returned to service without requalification following a crash or at the end of
the tank service life. Vehicle tanks should not be moved between vehicles,
although it cannot really be prevented in practice. State periodic vehicle
inspection is one option, which is recently launched in India in form of
Inspection and Maintenance (I&M) regime. Tanks may have a certain number
of fills before they “expire”. This is also a concern for stationary tanks. Tanks
may be requalified. Some vehicle repair facility issues are best handled by the
states, although the central government may have a role in some cases.
Industry and government in India need to think about repair facilities, repair
16
personnel, and enforcement, and develop appropriate safeguards and
education. Fuelling station codes {similar to the International Code
Council (ICC) or the National Fire Protection Association (NFPA) codes and
Canadian Standards Association (CSA) dispenser standards} should be
operative by the time vehicles are truly commercially available in the
marketplace. There are numerous recommended practices and technical
reports being developed by the Society of Automotive Engineers (SAE).
Hydrogen and Fuel Cell Standards Committee seeks input from Original
equipment manufacturers (OEMs), fuel cell developers and on-board storage
system manufacturers. Most of this material on safety and its technical
justification may be of use to India as regulations are developed.
1.9.2.2 Hydrogen Infrastructure
Bulk Hydrogen suppliers face the road block in the development of
infrastructure to support Hydrogen vehicle fuelling. The challenge is the
shipping of the samples with small quantities of Hydrogen, which needs to be
analysed for verifying Hydrogen quality at fuelling stations. Existing shipping
procedures are recognized as difficult to implement. The quantities allowed to
be shipped are small (typically 1 litre, at 350 bar or less). Industry should be
able to ship the samples via common carriers. Special permits and CMVR
rules will be required for shipping of Hydrogen canisters to support fuel quality
testing.
1.10 Action Plan
i.) Development of on board safety systems for Hydrogen vehicles
Includes development of safety devices such as flame traps, leak
detectors, alarms, OBD etc.
ii.) After treatment solutions for Hydrogen vehicles
Includes development of NOx control strategies as well as arresting
engine oil based particulates and nano particles.
17
iii.) Development of Indigenous sensors for fuel cell vehicles
Includes development of indigenous low cost sensors such as
antiknock sensor, lambda sensor, etc.
iv.) Advanced combustion HCCI engines for Hydrogen fuel
Includes development of high efficiency IC Engines based on
advanced combustion concepts using Hydrogen fuel.
v.) Development of Hydrogen fuel cell demonstration kits for schools
Includes development of kits which could create awareness on
Hydrogen as a fuel and also demonstrate properties of Hydrogen and
explain working of fuel cell.
vi.) Enhancement of Fire Safety Measures for Hydrogen Vehicles
Includes development of fire -fighting equipment including flame
retardant materials.
vii.) CFD simulation of Hydrogen release patterns
Includes simulation studies to assess impact of Hydrogen leaks.
1.11 Institutions for Hydrogen
A comprehensive testing facility for high pressure fuel storage cylinders
used for compressed Hydrogen and compressed natural gas automotive fuel
systems requires following laboratory setups:
1.11.1 High Pressure Component Testing Laboratory
For high pressure component testing requirements, design qualification
and performance tests on compressed Hydrogen automotive fuel system
components such as pressure regulators, solenoid valves, check valves,
PRDs, etc. are required. Additionally, standard and customized durability and
destructive tests of high pressure components up to 100 MPa (1,000 bar) are
required to be carries out.
18
1.11.2 Vehicle Fuel System Testing Laboratory
Qualified engineers and technologists are required to develop and
conduct vehicle fuel system tests. The capabilities to test to custom OEM
specifications to support vehicle fuel system design validation and lifetime
endurance are required. A typical facility is equipped to perform fueling
studies, and to perform severe abuse tests of vehicle fuel systems at
pressures up to 100 MPa (1,000 bar).
1.12 Centre of Excellence
1.12.1 Development of national facility for certification of Hydrogen and fuel
cell vehicles as per future CMVR norms is need of the hour. It should include
facilities such as
1 No. Chassis Dynamometer for HCV/LCV Vehicles – suitable for both
Hydrogen and Fuel cell buses
2 Nos. Chassis Dynamometer for SUV/Passenger Cars/SCV
1 No. Chassis Dynamometer for 2/3 Wheelers
1 No. Transient dynamometer - 550 kW
2 Nos Transient dynamometers up to - 300 kW
Hydrogen Cylinder Storage and Dispensing Facility
Hydrogen Component Certification facilities
Hydrogen engine combustion development and simulation centre
1.12.2 As a multidisciplinary testing and research facility, this centre should
have leadership role in the development of clean energy solutions, such as
Hydrogen fuel. To support technology advances, this centre should provide
services in Hydrogen testing, certification and prototype development.
19
1.12 Time Plan
Sr. No. Year 2016 2017 2018 2019 2020 2021 2022
Mission Mode Projects
1 Development of National
Hydrogen Vehicle Certification
and Research Laboratory
Chassis Dynamometer for HCV/LCV
Vehicles – suitable for both hydrogen and
Fuel cell buses -1 Nos.
Chassis Dynamometer for
2/3 Wheelers - 1 Nos
Transient dynamometers, 550 kW
capacity -1 Nos.
Transient dynamometers upto 300
kW - 2 Nos.
Chassis Dynamometer for
SUV/Passenger Cars/SCV -
2 Nos.
Hydrogen Cylinder Storage and Dispensing
Facility
Hydrogen Component Certification Equipment
Hydrogen fuel quality testing and material embrittlement testing
Hydrogen engine combustion development and simulation centre
20
Sr. No. Year 2016 2017 2018 2019 2020 2021 2022
2 Research & Development
Projects
3 Basic / Fundamental
Research Projects
Development of on board safety
systems for hydrogen vehicles
After treatment solutions for
hydrogen vehicles
Development of Indigeneous sensors for fuel cell
vehicles
Development of materials for lightweight hydrogen cylinders
Advanced combustion HCCI engines for hydrogen fuel
Development of hydrogen fuel cell
demonstration kits for schools
Enhancement of Fire Safety Measures for
Hydrogen Vehicles
CFD simulation of hydrogen release
patterns
Optical engine studies on Hydrogen Combustion
Suitable odorants and dyes for hydrogen fuel
Study of hydrogen regulations and projection of
requirement of regulation in near future
Awards, Scholarships, Training, Awareness Seminars, Advertisements
Hydrogen flame studies - Visualisation
21
1.14 Financial Implications
S. No. Activity Budgeted
Amount
(INR Crore)
A HR Activity Budget
1 Standards and Regulations Development 20
2 Awards and Scholarships for Students 30
3 Training and Awareness Seminars for
Manpower Development
50
4 Hydrogen Chair in IITs 25
5 IPR Budget 100
6 Hydrogen demo Kit for schools 25
Subtotal A 250
B Mission Mode Project
1 National Hydrogen Vehicle Certification Facility
- Upgradation of Chassis dynamometer.
- Engine Dynamometers Test Cell - 350 kW
- Upgradation of EV Facility for fuel cell
- Mobile cascade fuel facility
- Liasion office for standards, awareness &
Training
- Simulation and sensor HIL development
- Hydrogen Component certification facility at
ICAT
- Test track for Hydrogen Stability
- Cylinder testing duly approved
4
10
5
1
1
4
10
5
10
Subtotal B 50
C Research and Development Projects
1 Development of on board safety systems for
Hydrogen vehicles
40
2 After treatment solutions for hydrogen vehicles 20
22
3 Advanced combustion HCCI engines for
Hydrogen fuel
40
Subtotal C 100
D Basic Research
1 Optical Engine Studies on Hydrogen engine 70
2 Hydrogen Flame Studies 20
3 Odorants for Hydrogen 10
Subtotal D 100
Grand Total (INR Crore) 500
Cash Outlay per year
SN Year Budgeted Amount
(INR Crore)
1 2016-2017 200
2 2017-2018 100
3 2018-2019 75
4 2019-2020 50
5 2020-2021 50
6 2021-2022 25
Grand Total (INR Crore) 500
1.15 Conclusions and Recommendations
Notification of Hydrogen as a fuel in India
Promote and strengthen R&D activities on Hydrogen, fuel cells, safety
& manufacturing by providing necessary autonomy and freedom for
all academic and R&D institutions, while ensuring social responsibilities
and commitments
Establishment of Centre of excellence at ARAI for Hydrogen vehicle
certification and research.
23
Development of facilities for Hydrogen component and cylinder
evaluation
Accelerate business innovation with the R&E tax credit
Rewards can be given at various stages like filing, grant and
commercialization of patents by companies to promote activities in the
area of Hydrogen and Fuel Cell.
Conduct strategic, selective demonstrations of innovative technologies
Industry cost share and potential to accelerate market transformation
Continue to conduct key analyses to guide R&D and path forward –
Life cycle cost; economic & environmental analyses, etc.
Support and protect effective intellectual property rights
Leverage activities to maximize impact and facilitating
commercialization of IPRs
Training and education: To train enforcement officers, in-house
counsels, and school students.
Faculty Chair positions in major technological institutions on Hydrogen
research.
50 scholarship awards for students related to Hydrogen research.
MNRE sponsored workshops for spreading Hydrogen awareness.
Promote foreign exchanges and cooperation in IP, stepping up forecast
of IP related information on external trade and domestic markets and
the maintenance of IP.
Unleash a clean energy revolution: For our national security, economy,
and environment, it is crucial to develop clean energy technologies.
Promote energy efficient industries, Invest in clean energy solutions
and Spur innovation through new energy standards.
Awards for technical developments related to Hydrogen fuel
Tax benefits for Hydrogen vehicle technologies
Encouragement of Hydrogen vehicle demonstration projects
Indigenous Fuel cell stack development
Promotion of fuel cell equipment such as forklifts.
Assistance for participation in international standard body ISO TC 197
meetings related to Hydrogen technology.
24
Development of BIS standards on Hydrogen technologies
PPP programs for development of solar based Hydrogen stations
Standards for fuel dispensing and composite cylinders
Constitution of a nodal committee for implementation of Hydrogen
technologies
Funding of academia basic research projects including IITs through
Grants
Providing funds to government institutions like ARAI, IOC, BHEL for
commercial Hydrogen research projects
Dissemination of Hydrogen literature and books.
Conferences on Hydrogen technology with international experts.
Collaborations with foreign institutions for information and technology
exchange on Hydrogen.
Visits to international Hydrogen R&D centres for first hand assessment
of activities and possible collaborations.
Student exchange programs with international universities on Hydrogen
technology.
25
INTRODUCTION
26
27
2.0 Introduction
A Hydrogen vehicle is a vehicle that uses the gaseous fuel Hydrogen
as its onboard fuel for motive power. Hydrogen vehicles include automobiles
and other transportation vehicles. Hydrogen vehicles convert the chemical
energy of Hydrogen to mechanical energy either by burning Hydrogen in an
internal combustion engine, or by reacting Hydrogen with oxygen in a fuel cell
to run electric motors. Widespread use of Hydrogen vehicles for fueling
transportation is a key element of the Hydrogen economy. A summary of the
various Hydrogen testing requirements, standards, safety codes and
regulations is covered.
2.1 Issues with Hydrogen Fuel
• Safety is critical due to high flammability of the fuel. Adequate safety
equipment such as flame traps is required.
• Maintaining the quality of Hydrogen through production is an issue.
• Low energy density makes vehicle range a problem.
• Leakage tendency of Hydrogen is higher.
• No distribution infrastructure.
• Metal Embrittlement tendency requires changes in engine parts and
storage.
• Backfire and preignition are some more technical issues.
2.2 Need for Hydrogen Standards and Regulations
In order to ensure safety of vehicles and for technical solutions to these
issues following regulations and standards are critical: Governments have
identified the development of regulations and standards as one of the key
requirements for commercialization of Hydrogen-fuelled vehicles. Regulations
and standards will help overcome technological barriers to commercialization,
facilitate manufacturers’ investment in building Hydrogen-fuelled vehicles and
facilitate public acceptance by providing a systematic and accurate means of
assessing and communicating the risk associated with the use of Hydrogen
28
vehicles, be it to the general public, consumer, emergency response
personnel or the insurance industry.
2.3 Hydrogen as a Fuel: Standards
ISO TC 197 is the international committee that deals with standards
related to Hydrogen. The structure of the committee is given in Figure 2.1.
Figure 2.1: ISO TC 197 Committee structure for Hydrogen.
ISO/TC 197 was created to promote the increased use of Hydrogen as an
energy carrier and fuel. Standardization is required in the field of systems and
devices for the production, storage, transport, measurement and use of
Hydrogen. The standardization efforts of the technical committee ISO/TC 197
will facilitate the emergence of a renewable, sustainable energy system based
upon Hydrogen as an energy carrier and fuel. As standardization is
undertaken simultaneously with technology development, ISO/TC 197 work
facilitates the early demonstration and implementation of the Hydrogen
technologies that will be required to move Hydrogen into widespread energy
applications. India is a member of this committee.
29
2.4 Hydrogen Vehicle Testing
A Hydrogen internal combustion engine (ICE) vehicle uses a traditional
ICE that has been modified to use Hydrogen fuel. One of the benefits of
Hydrogen-powered ICEs is that they can run on pure Hydrogen or a blend of
Hydrogen and compressed natural gas (CNG). That fuel flexibility is very
attractive as a means of addressing the widespread lack of Hydrogen fuelling
infrastructure in the near term. The Vehicle Testing has to provide pure
Hydrogen or Hydrogen/CNG blends to the various internal combustion engine
test vehicles. The Vehicle Testing Activity evaluates Hydrogen and HCNG
internal combustion engine vehicles in closed-track and laboratory
environments (baseline performance testing), as well as in real-world
applications – including fleet testing and accelerated reliability testing
(accumulating life-cycle vehicle mileage and operational knowledge within 1 to
1.5 years). Emission testing is also conducted as per Euro norms. Testing
Hydrogen internal combustion engine vehicles also supports development of
the Hydrogen infrastructure needed for fuel cell vehicles.
2.5 Facilities Required for Hydrogen Vehicle Testing
The facilities required for Hydrogen testing are provided in the
figures below (USDOE). Testing facilities include vehicle fuel cylinder
testing, setups for sensor testing, virtual testing, and vehicle emission
using chassis dynamometer, engine dynamometer, noise and vibration
testing. Such facilities need to be developed in India as shown in Figure
2.2.
30
Figure 2.2: Hydrogen Vehicle Testing Facilities
A comprehensive testing facility for high pressure fuel storage cylinders
used for compressed Hydrogen and compressed natural gas automotive fuel
systems requires following laboratory setups:
2.6 High Pressure Cylinder Testing Laboratory
Comprehensive testing facility is required to provide a variety of
services to global equipment suppliers, automotive OEMs, and regulatory
authorities. Testing services for high pressure fuel storage cylinders used for
compressed Hydrogen vehicles is required. The laboratory can conduct an
array of standard and customized durability and destructive tests of high
pressure cylinders up to 280 MPa (2,800 bar).
2.7 High Pressure Component Testing Laboratory
For high pressure component testing requirements, design qualification
and performance tests on compressed Hydrogen automotive fuel system
31
components such as pressure regulators, solenoid valves, check valves,
PRDs, etc. are required. Additionally, standard and customized durability and
destructive tests of high pressure components up to 100 MPa (1,000 bar) are
required to be carries out.
2.8 Vehicle Fuel System Testing Laboratory
Qualified engineers and technologists are required to develop and
conduct vehicle fuel system tests. The capabilities to test to custom OEM
specifications to support vehicle fuel system design validation and lifetime
endurance are required. A typical facility is equipped to perform fueling
studies, and to perform severe abuse tests of vehicle fuel systems at
pressures up to 100 MPa (1,000 bar).
2.9 Hydrogen Embrittlement Testing
To evaluate the durability of the high pressure Hydrogen cylinders, and their
susceptibility to Hydrogen embrittlement, testing services to assess the
material’s performance in a pressurized Hydrogen atmosphere up to 70 MPa
(700 bar) are included in this facility. Hydrogen testing facility offers
independent testing and certification services to international codes and
standards and to customer requirements as shown in Figure 2.3
Figure 2.3: Hydrogen Vehicle Development facilities
32
2.10 Hydrogen Vehicle Type Approval
EEC 79 / 2009 is an European regulation for type approval of
Hydrogen vehicles. Similar regulation is required in India. Some Salient
Provisions of EEC 79/2009 are
Hydrogen system installation must be remote from heat sources.
Hydrogen container should not be installed in engine compartment and be protected
against corrosion
Measures to prevent misfuelling of vehicle and leakage
The refueling connector should be protected and should have a non-return valve
Hydrogen container should be mounted and fixed properly
Hydrogen fuel system should contain an automatic shut off valve mounted on the
cylinder
In case of accidents, the shut off valve should interrupt fuel flow
Hydrogen components should not project beyond outline of the vehicle
Hydrogen system installation must be safe from damage
Hydrogen components must not be located near vehicular exhaust
Ventilation system for Hydrogen leakage should be provided
In case of accidents, the pressure relief device should function normally.
Passenger compartment must be isolated from Hydrogen
Hydrogen components should be enclosed by gas tight housing
Electrical devices should be isolated and Hydrogen fuel system should be
grounded.
Labels should be provided to identify the Hydrogen vehicle
2.11 Hydrogen Cylinder Testing Facilities:
Test facilities for Hydrogen cylinder testing including gunfire,
environmental chamber, Hydrogen cycling, bonfire and burst testing as shown
in Figure 2.4
33
Figure 2.4: Hydrogen Cylinder Testing Facilities
2.12 Fuel Cell Vehicle Standards
Fuel cell vehicles use fuel cells which produce an electric current that
runs a motor which drives the vehicle. IEC/TC 105 is the international
committee on fuel cells. There are important standards regarding fuel cell
technologies and infrastructure. IEC 62282 is a globally accepted standard for
fuel cell vehicles consists of the following parts under the general title Fuel cell
technologies:
Part 1: Terminology.
Part 2: Fuel cell modules.
Part 3-1: Stationary fuel cell power plants – Safety.
Part 3-2: Stationary fuel cell power plants – Test methods for performance.
Part 3-3: Stationary fuel cell power plants – Installation.
Part 4: Fuel cell system for propulsion and auxiliary power units.
Part 5: Portable fuel cell appliances – Safety and performance requirements.
34
Part 6-1: Micro fuel cell power systems – Safety1.
Part 6-2: Micro fuel cell power systems – Performance1.
Part 6-3: Micro fuel cell power systems – Interchangeability1.
Part 7: Single Cell Test Method for Polymer Electrolyte Fuel Cell (PEFC).
2.13 Cryogenic Liquid Hydrogen standards
Hydrogen can be stored as a cryogenic liquid at -259°C.
European Standards for cryogenic liquid Hydrogen are as follows:
Directive 97/23/EC and Harmonised Standard EN 13458 provide
framework requirements for the pressure protection of cryogenic storage
tank systems.
i) EN 13458-1, Cryogenic vessels - Static vacuum insulated vessels -Part
1: Fundamental requirements.
ii) EN 13458-2, Cryogenic vessels - Static vacuum insulated vessels -Part
2: Design, fabrication, inspection and testing.
iii) EN 13458-3, Cryogenic vessels - Static vacuum insulated vessels -Part
3: Operational requirements.
iv) EN 14197-3, Cryogenic vessels – Static non vacuum insulated
vessels–Part 3: Operational.
v) EN 13648-3: Cryogenic vessels – Safety devices for protection against
excessive pressure – part 3: Determination of required discharge
capacity and sizing for relief devices.
2.14 Hydrogen Stations
Hydrogen stations are to be considered as subject to a particular risk of
fire and explosion. The degree of risk influences the type of electrical
installation. The installation and operation of electrical systems in Hydrogen
stations must be in accordance with the Regulations, Standards and Codes of
Practice of each country. UK Directive 99/92/EC (also known as 'ATEX 137' or
the 'ATEX Workplace Directive') and Directive 94/9/EC (also known as 'ATEX
35
95' or 'the ATEX Equipment Directive') on minimum requirements for
improving the health and safety protection of workers potentially at risk from
explosive atmospheres should be followed. Following international
organizations work closely for Hydrogen standards, codes and regulations as
shown in Figure 2.5
Figure 2.5: Hydrogen International Regulatory Bodies
2.15 Hydrogen Codes
The major themes in Hydrogen standards, codes and regulations involve:
Hydrogen leak, dispersion, and ignition research (modelling and
testing)
Enhancing existing Hydrogen vehicle and container fire (bonfire) test
methodologies
Modelling and/or testing to improve specifications
Compressed Hydrogen container ruptures in the event of pressure
relief device (PRD)
Failure (testing to determine consequences)
36
General Hydrogen vehicle safety research (fuel cell safety, safety and
risk analysis,
Vehicle demonstration programs, and codes and standards)
Hydrogen cylinder design and testing
Fast-fuelling of 70 MPa compressed Hydrogen containers (modelling
and testing of thermal loads)
Liquefied Hydrogen (LHYDROGEN) storage system components and
vehicles (design, testing, and demonstration)
2.16 Conclusions:
In order for the Hydrogen program to be successful in India,
development of required testing facilities, standards codes and
regulations for cylinders, components, vehicles and fuel need to be
developed in line with international regulations.
37
INTELLECTUAL PROPERTY RIGHTS
- HYDROGEN AND FUEL CELLS
38
39
3.0 Intellectual Property Rights (IPR) - Hydrogen and
Fuel Cell
3.1 Introduction
The concern and support for the clean and renewable energies has
been become a necessary need of the hour for sustainable growth of the
human as well as nation development. Fuel cell technology, Hydrogen
production & storage technology have become one of the main streams of
clean energy because of the attractive probabilities of becoming one of the
major future energy sources replacing crude oil. Although these technologies
are still in the nascent phase of their commercialization, interest in fuel cells
and Hydrogen is global, with more than $1 billion in public investment in
RD&D annually [1]. Major Private Organizations which include the supply
chain industry, automotive and power equipment manufacturers, energy and
chemical companies, electric and natural gas utilities, universities, national
laboratories are playing a major role in the RD&D and working towards
commercialization of these technologies. In the process of this research and
innovation, IPR’s filed by different organizations have been increasing year by
year.
This review presents and analyzes both granted patents and patent
applications published in this area of research. The fuel cell patent numbers
reported here reflect the continued technological progress in the industry, and
the advent of commercialization in some fuel cell applications. This report
would also give some preliminary information on Journal papers published
which is also one of the forms of IPR’s. The information incorporated would be
useful to compare Indian Research activities with the rest of the world and
would be utilized in analyzing and planning the proper steps to be taken to
encourage the generation of more IPR in India.
Intellectual property (IP) refers to creations of the mind, such as
inventions; literary and artistic works; designs; and symbols, names and
images used in commerce. IP rights are legally recognized exclusive rights to
40
creations. Under intellectual property laws, owners are granted certain
exclusive rights to a variety of intangible assets, such as musical, literary, and
artistic works; discoveries and inventions; and words, phrases, symbols, and
designs. Common types of intellectual property rights include copyright,
trademark, patents, industrial design rights, trade dress, and in some
jurisdictions trade secrets.
Although many of the legal principles governing intellectual property
rights have evolved over centuries, it was not until the 19th Century that the
term intellectual property began to be used, and not until the late 20th Century
that it became common place in the majority of the world. The British Statute
of Anne (1710) and the Statute of Monopolies (1624) are now seen as the
origins of copy right and patent law respectively. Until recently, the purpose of
intellectual property law was to give as little protection possible in order to
encourage innovation. Historically, therefore, they were granted only when
they were necessary to encourage invention, limited in time and scope.
3.2 Objectives
The stated objective of most intellectual property law (with the
exception of trademarks) is to "Promote Progress”. By exchanging limited
exclusive rights for disclosure of inventions and creative works, society and
the patentee / copyright owner mutually benefit, and an incentive is created
for inventors and authors to create and disclose their work. Some
commentators have noted that the objective of intellectual property legislators
and those who support its implementation appears to be "absolute protection".
"If some intellectual property is desirable because it encourages innovation,
the reason, more is better. The thinking is that creators will not have sufficient
incentive to invent unless they are legally entitled to capture the full social
value of their inventions". This absolute protection or full value view treats
intellectual property as another type of "real" property, typically adopting its
law and rhetoric. Other recent developments in intellectual property law, such
as the America Invents Act, stress international harmonization.
41
3.3 Financial Incentive
These exclusive rights allow owners of intellectual property to benefit
from the property they have created, providing a financial incentive for the
creation of an investment in intellectual property, and, in case of patents, pay
associated research and development costs. Some commentators, such
as David Levine and Michele Boldrin, dispute this justification. In 2013 the
United States Patent & Trademark Office approximated that the worth of
intellectual property to the U.S. economy is more than US$ 5 trillion and
creates employment for an estimated 18 million American people. The value
of intellectual property is considered similarly high in other developed nations,
such as those in the European Union. In the UK, IP has become a recognized
asset class for use in pension-led funding and other types of business
finance. However, the UK Intellectual Property Office stated: “There are
millions of intangible business assets whose value is either not being
leveraged at all or only being leveraged inadvertently”.
3.4 Economic growth
The WIPO treaty and several related international agreements are
premised on the notion that the protection of intellectual property rights is
essential to maintaining economic growth. The WIPO Intellectual Property
Handbook gives two reasons for intellectual property laws. One is to give
statutory expression to the moral and economic rights of creators in their
creations and the rights of the public in access to those creations. The second
is to promote, as a deliberate act of Government policy, creativity and the
dissemination and application of its results and to encourage fair trading
which would contribute to economic and social development.
Economists have also shown that IP can be a disincentive to
innovation when that innovation is drastic. IP makes excludable non-
rival intellectual products that were previously non-excludable. This creates
economic inefficiency as long as the monopoly is held. A disincentive to direct
resources toward innovation can occur when monopoly profits are less than
the overall welfare improvement to society. This situation can be seen as a
market failure and an issue of appropriate ability.
42
3.5 Types of IPR
Common types of intellectual property rights include patents, copyright,
industrial design, rights, trademarks, trade dress, and in some
jurisdictions trade secrets. There are also more specialized varieties of sui
generis exclusive rights, such as circuit design rights (called mask work rights
in U.S. law, protected under the Integrated Circuit Topography Act in
Canadian law, and in European Union law by Directive 87/54/EEC of 16
December 1986 on the legal protection of topographies of semiconductor
products), plant breeders' rights, plant variety rights, industrial design
rights, supplementary protection certificates for pharmaceutical products
and database rights (in European law).
3.6 Trade secrets
A trade secret isformula, practice, process, design, instrument, pattern,
or compilation of information which is not generally known or reasonably
ascertainable, by which a business can obtain an economic advantage over
competitors or customers. In the United States, trade secret law is primarily
handled at the state level under the Uniform Trade Secrets Act, which most
states have adopted, and a federal law, the Economic Espionage Act of 1996,
which makes the theft or misappropriation of a trade secret a federal crime.
This law contains two provisions criminalizing two sorts of activity. The first
criminalizes the theft of trade secrets to benefit foreign powers. The second
criminalizes their theft for commercial or economic purposes. The statutory
penalties are different for the two offenses. Trade secret law varies from
country to country. Infringement, misappropriation, and enforcement
Unauthorized use of intellectual property rights, called "infringement"
with respect to patents, copyright, and trademarks, and "misappropriation"
with respect to trade secrets, may be a breach of civil law or criminal law,
depending on the type of intellectual property, jurisdiction, and the nature of
the action.
Patent infringement typically is caused by using or selling a patented
invention without permission from the patent holder. The scope of the
43
patented invention or the extent of protection is defined in the claims of the
granted patent. There is safe harbor in many jurisdictions to use a patented
invention for research. This safe harbor does not exist in the US unless the
research is done for purely philosophical purposes, or in order to gather data
in order to prepare an application for regulatory approval of a drug. In general,
patent infringement cases are handled under civil law (e.g., in the United
States) but several jurisdictions incorporate infringement in criminal law also
(for example, Argentina, China, France, Japan, Russia, South Korea).
Copyright infringement is reproducing, distributing, displaying or
performing a work, or to make derivative works, without permission from the
copyright holder, which is typically a publisher or other business representing
or assigned by the work's creator. It is often called "piracy". While copyright is
created the instance a work is fixed, generally the copyright holder can only
get money damages if the owner registers the copyright. Enforcement of
copyright is generally the responsibility of the copyright holder. The ACTA
trade agreement, signed in May 2011 by the United States, Japan,
Switzerland, and the EU, requires that its parties add criminal penalties,
including incarceration and fines, for copyright and trademark infringement,
and obligated the parties to active police for infringement. There is a safe
harbor to use copyrighted works under the fair use doctrine.
Trademark infringement occurs when one party uses a trademark that
is identical or confusingly similar to a trademark owned by another party, in
relation to products or services which are identical or similar to the products or
services of the other party. As with copyright, there are common law rights
protecting a trademark, but registering a trademark provides legal advantages
for enforcement. Infringement can be addressed by civil litigation and, in
several jurisdictions, under criminal law. In the United States, the Trademark
Counterfeiting Act of 1984 criminalized the intentional trade in counterfeit
goods and services and ACTA amplified the penalties.
Trade secret misappropriation is different from violations of other
intellectual property laws, since by definition trade secrets are secret, while
patents and registered copyrights and trademarks are publicly available. In
the United States, trade secrets are protected under state law, and states
44
have nearly universally adopted the Uniform Trade Secrets Act. The United
States also has federal law in the form of the Economic Espionage Act of
1996, which makes the theft or misappropriation of a trade secret a federal
crime. This law contains two provisions criminalizing two sorts of activity. The
first criminalizes the theft of trade secrets to benefit foreign powers. The
second criminalizes their theft for commercial or economic purposes. The
statutory penalties are different for the two offenses.
In Commonwealth common law jurisdictions, confidentiality and trade secrets
are regarded as an equitable right rather than a property right but penalties for
theft are roughly the same as the United States.
As of 2011 trade in counterfeit copyrighted and trademarked works was
a $600 billion industry worldwide and accounted for 5 – 7% of global trade.
India's Council of Scientific and Industrial Research (CSIR) has a
specialized service Unit for Research and Development of Information
Products (URDIP) which is involved in the pre-research and pre-development
phase of the research projects by providing intellectual property and techno-
commercial information services. URDIP provides value added information
services to wide array of clients including start-up companies, SMEs,
Research Institutes within and outside CSIR, large Indian Corporate and
Multinational Corporations. Its primary clients include R&D, legal, new
business development and multi-functional corporate teams. Patent mapping
is also being done which is very important component to know whether one
has got freedom of practice for a particular patent or not.
In India, the Office of the Controller General of Patents, Designs &
Trade Marks (CGPDTM) is located at Mumbai. The Head Office of the Patent
office is at Kolkata and its Branch offices are located at Chennai, New Delhi
and Mumbai. The Trade Marks registry is at Mumbai and its branches are
located in Kolkata, Chennai, Ahmedabad and New Delhi. The Design Office is
located at Kolkata in the Patent Office. The Offices of The Patent Information
System (PIS) and National Institute of Intellectual Property Management
(NIIPM) are at Nagpur. The Controller General supervises the working of the
Patents Act, 1970, as amended, the Designs Act, 2000 and the Trade Marks
45
Act, 1999 and also renders advice to the Government on matters relating to
these subjects. In order to protect the Geographical Indications of goods a
Geographical Indications Registry has been established in Chennai to
administer the Geographical Indications of Goods (Registration and
Protection) Act, 1999 under the CGPDTM.
Patents
Designs
Trade Marks
Geographical Indications
National Institute of Intellectual Property Management(NIIPM)
Patent Information System
Annual Reports
Result Framework Document (RFD)
Request for Proposal (RFP)
Office of the Controller General of Patents, Designs & Trade Marks
Bhoudhik Sampada Bhavan,
Antop Hill, S.M. Road, Mumbai - 400 037
Intellectual Property Office
Intellectual Property Office Building,
Plot No. 32, Sector 14, Dwarka, New Delhi-110075
Phone: 011-28034304-05
Filing Date, Number of Patents & Average Growth Projections
Figure 3.1 shows the clean energy patent growth index. Fuel Cells and
Hydrogen shows a modest growth in scientific literature and high levels of
growth in patent output in the past five years, indicating a shift from
fundamental research towards more commercial applied applications.
46
Fig. 3.1: Comparison of No. of patents granted in clean energy sector by
USPTO [2]
3.7 Fuel Cell
Fuel cell sectors have impressive run of year to year increases dating
back to 2002 with small dips in 2005, 2007 & 2011 while dominating the other
technologies until the rapid ascent of solar technology patents starting in
2009.
Table 3.I : Comparison of granted patents and applications from USPTO
Year
Total
Patents
(Global)
%
growth
Total USPTO
+
EPO Patents
%
growth
Actual
Fuel
Cell
Patents
% Growth in
fuel cell
Patents
2010 908600 - 278395 - 1806 -
2011 996800 9.7 286086 2.8 2732 51
47
Table 3.2 : Comparison of granted patents and applications from EPO [3]
Year
Total
Applications
(Global)
%
growth
Total USPTO
+
EPO
Applications
%
growth
Actual
Fuel
Cell
Appli-
cations
%
Growth
in
fuel cell
Apps
2010 1985300 - 641300 - 3634 -
2011 2140600 7.8 646392 0.8 5734 57.8
In fuel cell technology, the US and European patent offices published
a combined total of 2,732 granted fuel cell patents, equating to growth in fuel
cell related intellectual property (IP) of 51% during year 2011. This growth
compares favorably to growth in the total number of granted patents published
by these two offices in 2011, which amounted to only 3% (Table 3.1 & 3.2).
.
Figure 3.2: Application filing date for fuel cell patents granted in 2011
USPTO & EPO [3]
Figure 3.2 above illustrates the filing year of the 2,732 fuel cell patents
granted in 2011, indicating how many of these were applied for in each
preceding year. A patent application may take several years to be granted as
a patent. The number of granted patents reflects the level of research and
development activity that took place some years previously.
48
3.8 Country of Origin
As shown in the Figure 3.3 U.S. and Japan, followed by Korea and Germany
have dominated the fuel cell patents since 2002. U.S. leads the world with
43% of total fuel cell patents followed by Japan (33%), Korea (8%) and
Germany (6%) respectively.
Figure 3.3: Geographic distribution of cumulative fuel cell patents
granted by USPTO since 2012-13 [2]
Figure 3.4: Geographic distribution of fuel cell patents granted by
USPTO since 2012-13 [2]
49
Table 3.3 and Figure 3.4 shows Japan and the USA continuing to lead
the world in terms of granted fuel cell patents, Japan (1,040) has accelerated
in the past year putting it further ahead of the USA (841) in 2011. The top ten
countries in list agree with similar analysis published by WIPO.
Japanese interest originates from two main applications, automotive
development and residential micro-combined heat and power (micro-CHP).
Leading Japanese companies make up half of the top ten global holders of
granted patents in 2011.
In the USA, General Motors heads the list of granted patents for 2011
with 23% of the Country’s total and in Germany, Daimler and Siemens are the
leading contributors. South Korea remains fourth in the list, with Samsung
accounting for 80% of granted patents in the country. In Canada, Versa
Power Systems who develop 2 to 10 kW stationary systems for CHP
applications is leading with 20% of total patents.
Table 3.3 shows the ratio of granted patents to patent applications for
the top ten countries in terms of applications and give an impression of
success of applications filed. While there is no direct relationship between the
number of granted patents and patent applications in a given year, the ratios
in Table 3.3 show that, in 2011, most countries on this list had 1.5 to 2.7 times
more fuel cell applications than granted patents. Reasons for this could be
manifold, such as applications filed to block others from taking advantage of a
technology or simply a greater amount of research producing results which
are worthy of a patent application; time will tell if this results in an increase in
granted patents in the future.
Fuel Cell today has known about the dominance of Japan in fuel cell
technology for many years, both as a patenting force and commercially, but
the role of China in international fuel cell patent activities is low compared to
the rest of the world, but it is growing and it is expected to increase further in
the future. Looking back over the past ten years, no international activity was
seen in 2000, with applications being logged in 2005 but none granted. In
2010, application activity continued and it was observed that the international
50
patents being granted with China as the priority country. In 2010 and 2011,
with 78% and 49% respectively of granted patents included China. This shift
highlights the importance of the Chinese market and shows manufacturers
are keen to protect their intellectual property there.
Table 3.3: Comparison of granted patents and applications based upon the
country of origin. USPTO & EPO [3]
Country
Applied
Patents
2010
Granted
patents
2010
Ratio Applied
patents
2011
Granted
patents
2011
Ratio
Japan 1374 617 2.2 2376 1,040 2.3
USA 1080 598 1.8 1495 841 1.8
Germany 341 187 1.8 552 285 1.9
South
Korea
206 177 1.2 418 240 1.7
France 126 45 2.7 179 72 2.5
Canada 67 32 1.8 120 47 1.5
India 3 2 1.5 5 1 5
Total
(globally)
3561 1806 2 5734 2732 2
3.9 Assignees
The below Table 3.4 is the list of top ten companies in terms of
granted patents during 2010 and 2011 by USPTO & EPO. It confirms the
continued dominance of automotive companies: 40% of the top ten assignees
in 2010 and 50% in 2011.
Assignees for these patents were dominated by those from Japan and
the USA, accounting for 69% of the granted patent total in 2011. Half of the
top ten companies were from the automotive sector, highlighting their
51
continued commitment to fuel cell technology. Other leading companies in
2011 were Panasonic and Samsung, each a well-known household name.
Table 3.4 : Top ten assignees of fuel cell patents granted in 2010&2011,
USPTO & EPO
Rank 2010 2011
1 Samsung,Korea 68 Honda Motor co., Japan 217
2 Honda Motor co.,
Japan
50 GM,US 194
3 GM,US 48 Samsung, Korea 191
4 Toyota Motor Corp.,
Japan
26 Toyota Motor Corp.,
Japan
188
5 Panasonic Corp.
Japan
24 Panasonic Corp. Japan 92
6 Nissan Motor
Ltd.,Japan
22 Nissan Motor Ltd.,Japan 87
7 Hitachi Ltd. Japan 22 Hitachi Ltd. Japan 36
8 Delphi
Automotive,U.K.
17 Delphi Automotive,U.K. 33
9 Toshiba Corp.
Japan
16 UTC Power, U.S. 35
10 Canon Inc. ,Japan 12 Daimler 32
Figure 3.5 depicts the decline in the number of patents granted to
Ballard Power Systems with just two patents granted in each year may be
because of the corporate transformation which Ballard undertook which
shifted company’s focus away from long-term automotive fuel cell R&D to
concentrate on near-term commercial markets for its fuel cell products.
52
Figure 3.5: Assignees of fuel cell patents granted by USPTO since 2012-13[2]
Looking ahead, It would be expected a sustain growth in fuel cell
related granted patents, especially since the development of new commercial
products is continuing and new applications for fuel cells are entering the
market. The discovery and inclusion of advanced materials and High-
performance catalysts are just a few of the ways in which research efforts will
further help the commercialization of fuel cell technology and this will be
reflected in the patent literature.
Overall the patent landscape in relation to fuel cells is quite congested;
fuel cells have been around a long time and a lot of people have tried to
commercialize them, some successfully and some not.
Patents tend to be clustered in areas where there has been significant
research, development and investment to date. These include Japan (the
auto and large technology companies), US (auto companies, large technology
companies, military applications) and Europe (auto, technology combined
heat & power applications, electrolyzer technology).
Many patents have generic fuel cell applications but others are more specific-
e.g. large SOFC units are on the rise in the US and there are various patents
relating to that development, in Japan there has been success with CHP units
53
using SOFC, most auto patents relate to PEMFC if they are specific to a fuel
cell type.
As commercialization efforts have increased, greater focus has been placed
on:-
Manufacturability at volume and cost effectively- patents have been
generated in this area- e.g. reducing components, alternative and
cheaper materials, manufacturing process driven improvements
Involvement of industry OEMs is critical to assure large scale patent
activity. Particularly automotive OEMs play a critical role.
Durability- a key to commercialization. Patents on materials and
controls to manage and improve durability
Performance- things like power density improvements, materials,
consistency
Infrastructure and Fuelling- automotive fuelling related innovation like
storage tanks, interfaces, measuring and quality devices, portable
storage devices for non-auto applications
3.10 Hydrogen production and storage technologies
The number of patent applications related to Hydrogen energy
increased dramatically between 1998 and 2002 but have leveled off more
recently. Overall, these applications have been distributed relatively equally
between Hydrogen production and Hydrogen storage technologies, at 47
percent and 53 percent, respectively as shown in Figure 3.6. However, patent
applications for Hydrogen production were filed primarily before 2000, while
applications for Hydrogen storage have become predominant since then.
A number of research institutes as well as companies in the energy
and automotive industries have launched research and development
programs generally with the support of national governments. Among the
means for producing Hydrogen that are being investigated are water
electrolysis using electricity generated from solar heat, wind power,
geothermal heat, or other types of alternative energy and natural gas
54
reforming methods that can be integrated into conventional Hydrogen
production methods. Among the technologies being researched for Hydrogen
storage are methods involving low-temperature liquid Hydrogen, metal
hydrides, and carbon nanotubes. Metal-organic frameworks and clathrate
hydrates are also being investigated as storage materials to improve safety
and storage efficiency.
Figure 3.6 Applications for Hydrogen technologies
Table 3.4: Number of Patent Families per Country, 1995-2011
Country Hydro
gen
Produ
ction
H2
storage
PEM
FC
SOF
C
DMFC Fabrica
tion
and
testing
Electrod
e
catalyst membra
nes
U.S 6300 1372 2881 1523 514 2680 2654 2451 2638
Japan 10473 3653 11529 3502 1792 9223 9736 7587 4406
South
Korea
1590 569 1294 521 367 1995 1504 1125 1255
India 39 9 10 2 0 7 7 4 8
Table 3.4 above shows the number of patents in each category and
from each of the nations in the different areas of Fuel Cell and Hydrogen
Technology and the time period of 1995-2011. India is far behind in the list
55
less than 100 patents during the period in various facets of Hydrogen and fuel
cells.
3.11 Journal Paper Activity in Fuel Cell and Hydrogen
This part of the report would give the basic information on Scientific
Journal papers published in the area of Fuel cells and Hydrogen.
Fig. 3.7 Number of Scientific Papers per Pair of Technology Categories
Figure 3.7 visualizes the relationship between the high level energy
technology segments. The diagram can be used to quickly understand which
combinations of technology are the most popular focal points of fundamental
research in Energy. Equally, the diagram can also be used to understand
which combinations have been relatively lightly researched. Combustion has
high overlap with Fuel cells and Hydrogen. Similarly energy storage also has
good overlap with Hydrogen and fuel cell area.
The Table 3.5 above shows the number of scientific papers in each
category and from each of the nations in the different areas of Fuel Cell and
Hydrogen Technology.
56
Table 3.5 Number of Papers per Country, 1995-2011
Hydro
gen
Produ
ction
H2
storage
PEM
FC
SOFC DMFC Fabricati
on and
testing
electr
ode
cataly
st
mem
bran
es
U.S 8293 3077 2811 2836 786 1170 1189 3342 3461
China 5490 3807 1647 1913 1020 649 813 2239 3107
Japan 4196 1532 1281 1573 371 366 628 1259 1521
South
Korea
1574 734 1087 661 579 310 411 1259 1165
India 1587 520 313 285 168 101 184 397 432
3.12 Scope for the future
This is difficult as it requires innovation in order to generate patents.
So it is easier to identify where innovation is likely, possible, required rather
than which patents might be filed.
There remains scope for innovation around durability, performance and
cost reduction. They will be iterative changes unless and until
someone identifies a real game changing step.
Innovation is also likely to center around what technology is being used
and for which applications. If a country focuses on automotive then the
innovation will differ and probably be more focussed on the auto
challenges than if, say, the focus is on distributed power which has a
wider scope and is likely to see innovation across a wider spectrum of
technologies and end uses.
Innovation is also possible in relation to deployment of FCs in particular
environments and uses- e.g. integration with other technologies or into
particular applications
3.13 Strategies for encouraging generation of more IPR’s in India
From the above reports it is clearly seen that the research activities in
the field of Fuel Cell & Hydrogen are still in their early phase in India as
57
compared to other nations. Since the activities of fuel cell and Hydrogen are in
early stages, it is inevitable to have more focus on creating indigenous
technology for its commercialization and industrialization in India. To promote
fuel cell technology based innovation there must be proper strategies and
plans which enhance IPR activities in India in those specific fields.
The objective of the IPR strategy is to transform India into an
innovative economy as would reflect in high rankings in appropriate
development and innovation indices from a global standpoint and develop,
sustainable and innovation-promoting IPR management system in India while
ensuring that the IP system continues to have the appropriate checks and
balances conducive to social and economic welfare, and to a balance of rights
and obligations. Besides measures that need to be taken, the strategy also
needs to have an implementation matrix and a time bound schedule. The
aforementioned objectives are proposed to be addressed through the
following four-pronged approach.
a. Promoting respect for Intellectual Property and stimulating creation of IP
Rights
b. Creation of new IP regimes to address the specific needs of the country
and the existing gaps
c. Strengthening protection of IP
d. Facilitating Commercialization of Intellectual Property
The detailed strategies for promotion of Hydrogen IPR are as follows:
1. The Indian academia, industry, the innovator/entrepreneur community
ought to be increasingly made aware of the value of IPRs both from national
and global contexts.
2. Further, there is a need to develop a general understanding of different
processes involved in creation of IP assets.
3. With increasing globalization, there is an immediate need to encourage the
MSMEs to protect their IP through formal methods. A healthy mix of education
58
and incentives is needed to encourage MSMEs to create new IP and to
formalize the existing ones based on expert advice.
4. The Govt. intervention in existing mechanisms like the setting up of IP
facilitation centres would have to be significantly scaled up to improve impact.
5. Access to Database on patent and non-patent literature to enable prior art
search should be provided to premier institutions such as, inter alia, IITs,
National Institutes of Technology by the Government free of cost.
6. Favourable tax treatment for R& D Expenditures incurred could play a
positive role in incentivizing innovation and IP creation.
7. Since innovations and creation of IP comes at a cost, state support
mechanisms need to be tailored towards offsetting bonafide IP costs and in
facilitating technology transfer including through in-licensing from publicly
funded research institutions.
8. Indian researchers/ innovators must be made aware of basic precautions
that need to be exercised before applying for a patent, such as not publishing
or demonstrating their research/invention to the public before filing for a
patent and also by sensitizing them about not selling out their early stage
research to companies/organizations.
9. Talented scientists and engineers ought to be motivated to create
intellectual property and be encouraged to license technologies/partake in
creation of technology ventures Promoting university start-ups can also be an
effective technology transfer mechanism.
10. IP creation in sponsored/collaborative research and technology
development/transfer should be made a component of the scientific role of a
research institution. This should be included as a key performance indicator
for the institution.
11. Basic concepts of IP creation and respect for IP needs to be introduced as
a component of formal education at school, college, university and at
vocational level thereby fostering a culture of creativity in future generations.
Such education should focus on the economic and the social aspects of IP.
12. Large organizations have the know-how and the resources required for
creation and protection of IP. With increasing globalization, their key
challenge will be to create world-class IP and utilize this IP for both
organizational and national benefits. Moreover, the Government should
59
encourage these organizations to share their expertise and resources for
national benefit through public-private partnerships.
13. Research led organization should be guided into strategic tie-ups with
Government to foster co-creation of critical IP. A mechanism similar to
corporate social responsibility may be encouraged in the country to foster a
culture of open innovation.
14. While synergy and close interaction between universities, research
institutions and innovation driven industry units is extremely important for
promoting techno entrepreneurs, following measures may need to be taken to
boost this interaction:
i) Information dissemination and delivery mechanism for support services
including venture capital funding ought to be made expedient.
ii) Dedicated public institutions which offer end to end support for creation,
protection and commercialization of IP is vital for start ups. There is need to
identify such institutions and enhance their ability to provide such services.
iii) procedural mechanism adopted for giving financial support for patent filings
should be made smoother and quantum of assistance provided should be
augmented.
15. Protection of Intellectual Property is both a scope and a depth issue.
While establishing new instruments and addressing gaps in the available
instruments is a scope issue, efficiency and strength of institutions that
grant/protect IPR and extent of protection available is the depth issue.
Therefore strengthening of IP protection regime will involve improvement in
the institutions that grant IPRs and in those that are responsible for its
enforcement as also expansion of rights to include new IPRs.
16. National research laboratories, academia and other public funded
institutions should stimulate commercialization of their research resultants.
They ought to be suitably state-supported in the development and deployment
of their intellectual property and know-how in the market place – more
particularly their application into industrial production.
60
61
HYDROGEN STORAGE REGULATIONS
62
63
4.0 Hydrogen Storage Regulations
With an overall objective of ensuring safety and security of public and
property from fire and explosion, the Department of Industrial Policy
& Promotion, Ministry of Commerce and Industry, Government of India
entrusted the Petroleum Explosives Safety Organization, Nagpur,a statutory
authority to administer the Explosives Act, 1884 (Explosives Rules, 2008; Gas
Cylinder Rules, 2004; Static & Mobile Pressure Vessels (Unfired) Rules,
1981; Ammonium Nitrate Rules, 2012; Notification No. GSR 625(E) dated
07.08.1983 regarding Acetylene Generation); Petroleum Act, 1934 (Petroleum
Rules, 2002; Calcium Carbide Rules, 1987; Cinematography Film Rules,
1948) ; and Inflammable Substances Act, 1952.
4.1 Gas Cylinders Rules, 2004 – Applicable Provisions
4.1.1 The cylinders containing compressed gas are declared as an
‘explosives’ under Section 17 of the Explosives Act, 1884. The filling,
possession, import and transport of the gas cylinders meant for compressed
gases is governed under the Gas Cylinders Rules, 2004 framed under
Explosives Act, 1884. Only containers having a volume exceeding 500ml but
not exceeding 1000 liter intended for the storage and transport of compressed
gas including LPG containers, CNG cylinders fitted to a motor vehicle as its
fuel tank are covered as per the definition of ‘gas cylinders’ under rule 2(xxi)
of the Gas Cylinders Rules, 2004. The definition of ‘gas cylinders’ also include
composite cylinder and the cylinders used for storage of CNG, Nitrogen,
Compressed Air, etc. having water capacity 1000 liter to 2500 liter provided
that the diameter of such cylinders does not exceed 60cm.
4.1.2 Rule 2(viii) of the said rules has already been amended for the definition
of Compressed Natural Gas (CNG) to incorporate mixture of Hydrogen &
Methane as automotive fuel. However, the Gas Cylinders Rules, 2004 as well
as Central Motor Vehicle Rules are required to be amended to incorporate
Hydrogen as automotive fuel.
64
4.1.3 The approval of cylinder and valve is accorded under Rule 3 of the Gas
Cylinders Rules, 2004. The cylinders and valves, conforming to Indian
Standards, manufactured indigenously are covered under BIS Certification
Marks Scheme. The details of the approved manufacturers of the cylinders
and valves are specified in Schedule I of the Gas Cylinders Rules, 2004. New
Indian applicant is required to submit the particulars set forth under Schedule
III to the aforesaid rules and scrutiny fee as specified in Schedule V to the
Chief Controller of Explosives, Nagpur while forwarding the design drawing
and design calculation through Bureau of Indian Standards. After scrutiny of
the design and infrastructure created by the application, and if found
adequate, necessary permission is accorded for prototype production of the
cylinders/valves. The manufacture, inspection and testing of prototypes
cylinders and valves are witnessed by joint inspection team from PESO &
BIS. On receipt of the satisfactory joint inspection report confirming the
capability of the firm to undertake the manufacture of the product, necessary
approval is accorded under Gas Cylinders Rules, 2004 and thereafter BIS
also grant a licence for the particular product under BIS Certification Marks
Scheme. For any subsequent changes in the design drawing, a fresh approval
is required to be obtained under the said rules.
4.1.4 In case of foreign manufacturers, documents and information are
called for under Schedule III of the said rules. Foreign manufacturers only with
proven track record, rich manufacturing experience and a widely distributed
market share in developed countries are only considered for approval under
the said rules after duly following the procedure as stated in the above. The
design drawing and design calculation of the cylinders and valves
manufactured as per recognized international standards duly endorsed by
reputed third party inspection agency along with type test reports are also
required to be furnished by the foreign manufacturer for considering approval
under the said rules.
4.1.5 License for import of any filled cylinders or empty cylinders intended
to be filled with any compressed gas is governed under Rule 29 of the Gas
65
Cylinders Rules, 2004. The following documents are required to be submitted
to the Chief Controller of Explosives, Nagpur for grant of import license:-
i) An application in form ‘B’ duly filled in and signed.
ii) Copy of Chief Controller of Explosives approval letter in respect of
the manufacturer of the cylinders/valves under Rule 3.
iii) Manufacturers test & inspection certificate complete in all respects
pertaining to each lot of cylinder and valve.
iv) In case cylinders are desired to be imported duly filled with gas,
filler’s certificate in respect of item 3(vi), (vii), (ix) of the form ‘B’.
v) Demand draft drawn for the amount as shown in Schedule V drawn
on any Nationalized Bank in favor of Chief Controller of Explosives
payable at Nagpur.
vi) Copy of DGFT licence.
vii) Details of the storage licence in Form ‘F’ of the Gas Cylinders
Rules, 2004.
viii) The details of the end user and their storage licence particular
under the Gas Cylinders Rules, 2004.
ix) The available infrastructure for safe handling and storage with the
importer and user.
x) Details of emergency handling facility and equipment available in
case of leakage.
xi) Details of technical experienced and trained manpower available for
handling and storage of cylinders as per the provisions of the Gas
Cylinders Rules, 2004.
xii) The copies of the re-export bond where applicable, shall also be
furnished along with such intimation.
4.1.6 A licence for filling and possession of gas cylinders is obligatory under
Rule 43 of the Gas Cylinders Rules, 2004. The documents required to be
submitted by the applicant to the Chief Controller of Explosives for grant of
licence to fill and store any compressed gas in any cylinder is specified under
Rule 47, 49 & 50 of the said rules.
66
4.1.7 It is mentioned that only Type 1 cylinders conforming to IS:7285 (Part 2)
2004/ ISO:9809-1 & Type 3 cylinders conforming NGV2-2000, EC 79/2009,
EN:12245 or any other internationally recognized standard approved by Chief
Controller of Explosives are permitted for Hydrogen service in the interest of
safety. Type 2 & 4 cylinders are not being considered at this stage owing to
various safety issues. In case of Type 1 cylinder, the tensile strength of the
finished cylinder shall be restricted to 950 MPa. Yield and tensile ratio of the
finished cylinder shall not exceed 0.9. However, for design purpose the said
ratio shall not be more than 0.85. The Hydrogen cylinders for cascade shall
conform to IS:7285 (Part 2)2004 or any other recognized international code
i.e. ISO:9809-1, etc. approved by the Chief Controller of Explosives. Type 3
cylinders manufactured by M/s. Dynetek are already permitted for Hydrogen
application on trial basis. The office may consider approval of Hydrogen
cylinders of Type 1 & 3 manufactured by approved manufacturer for various
ranges of water capacities, filling & working pressure on submission of
relevant documents as required under Gas Cylinders Rules, 2004. However,
the connecting equipments, valves including Hydrogen dispensing stations
shall be designed and constructed so as to be compatible with the working
pressure of such cylinders.
4.1.8 Components that are in contact with gaseous Hydrogen have to be
sufficiently resistance to their chemical and physical action under normal
conditions to maintain operational and pressure containment integrity.
ISO:11114-1 & ISO:11114-2 may be used to ensure suitability of material
where applicable. The quality of Hydrogen is considered to be a critical issue
to combat the Hydrogen embrittlement and should conform to IS:14687 or as
appropriate. The material of cylinder/container is required to be resistance to
Hydrogen embrittlement, Hydrogen attack and reactivity with contained
material and maintain their integrity for the service life of the cylinder.
Recognized test methods such as those specified in ISO:11114-4 may be
used to select metallic material resistance to Hydrogen embrittlement.
Alternatively, materials known to be resistance to Hydrogen embrittlement
may be used.
67
4.1.9 The Gas Cylinders Rules, 2004 are required to be amended for
incorporation of Hydrogen dispensing layout/facilities once Government of
India permits inclusion of Hydrogen as an automotive fuel and CMVR are
suitably amended in this regard. The international standard ISO: 20012 -
Gaseous Hydrogen – Fuelling Station may be useful for establishment of
fuelling stations in the country on trial basis.
At present ISO: 15869 is in the draft stage for Gaseous Hydrogen and
Hydrogen blend – Land Vehicle Fuel Tanks. Since ISO: 15869 (ISO/TC-197)
is going to be internationally accepted code, the same may also be followed in
this country as India being ‘P’ Member of the ISO/TC-197 Committee. IS:
15490 & IS: 7285(Part 2) are also required to be suitably amended for to
incorporate Hydrogen-CNG blend and Hydrogen as automotive cylinders.
Further, the following ISO standards may be useful for Hydrogen storage and
dispensing system:
I. ISO: 13984 – Liquid Hydrogen – Land Vehicle Fuelling System
Interface.
II. ISO: 13985 - Liquid Hydrogen – Land Vehicle Fuel Tanks and
PDTS 16111 – Transportable Hydrogen gas storage devices.
III. ISO: 15869 – Gaseous Hydrogen and Hydrogen Blends – Land
Vehicle Fuel Tanks.
IV. ISO: 20012 - Gaseous Hydrogen – Fuelling Station.
3 ISO/TC 197 N 391 New Work item proposal (NWIP) on road
vehicles – compressed gaseous Hydrogen (CGH2) and
Hydrogen/methane blends fuel system components.
4 ISO: 5869.3 - Gaseous Hydrogen and Hydrogen blends – Land
vehicle fuel tanks.
5 vii) ISO: 22734-1 - Hydrogen generators using water electrolysis
process – Part 1: Industrial and commercial applications.
6 ISO: 17268 -2: Gaseous Hydrogen Land Vehicle Refueling
Connection Devices.
7 EIGA DOC 06/02/E – Safety in Storage, Handling & Distribution of
Liquid Hydrogen.
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8 ISO:15594:2004 – Airport Hydrogen Fueling Facility Operations
4.1.10 PESO has accorded approval for Hydrogen storage and dispensing
facilities in the country to various OEMs for R&D and demonstration purposes
only, as detailed below -
a) M/s. Tata Motor Ltd., ISRO and HAL have jointly developed Hydrogen
fuelled fuel cell bus and undertook successful trial run at ISRO/HAL premises
comprising of type 3 cylinders conforming to NGV2-2000 manufactured by
M/s. Dynetek Industries Ltd., inspected and certified by M/s. Powertech Labs
Inc., Canada and valves conforming to ISO:15500 and NGV 3.1.
b) M/s. Mahindra & Mahindra has also conducted trials of Hydrogen
fuelled IC vehicles for demonstration-cum-experiment purpose at Pragati
Maidan, New Delhi under a joint project titled “Development and
Demonstration of Hydrogen fuelled three wheeler vehicles” with partners, viz.
United Nations Industrial Development Organisation, Indian Institute of
Technology Delhi, Air Products, Indian Trade Practise Organisation &
Mahindra & Mahindra. The Type 3 cylinders conforming to NGV2-2000
manufactured by M/s. Dynetek Industries Ltd., inspected and certified by M/s.
Powertech Labs Inc., Canada fitted in such vehicles were filled at M/s. Air
Product’s Hydrogen dispensing premises within Pragati Maidan, New Delhi
approved by the Chief Controller of Explosives for the purpose.
4.1.11. PESO has also approved Steel Tube Cylinders, Type 3
Composite Cylinders including steel cylinder for Hydrogen application:-
i) M/s. Everest Kanto Cylinders Ltd. is already an approved
manufacturer for tube cylinders of water capacity up to 2500 liters
for type 1 cylinders conforming to ISO: 11120.
ii) M/s. Dynetek, Germany is an approved manufacturer for Type 3
composite cylinders of working pressure 350 bar, test pressure 525
bar
iii) M/s. Luxfer Gas Cylinders, USA is also an approved manufacturer
for Type 3 composite cylinders.
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4.2. STATIC AND MOBILE PRESSURE VESSELS (Unfired) Rules,1981
{SMPV} – Applicable Provisions
4.2.1 Compressed gases filled in metallic container pose potential hazard
and threat to public life and property let the container explode. Hence, the
Govt. of India vide Notification No.M-1272(1) dated 28/09/1938 has declared
compressed gas filled in a metallic container to be deemed to be an explosive
under Section 17 of the Explosives Act, 1884. Subsequently, in exercise of
powers vested in Section 5 & 7 of the Act, the Govt. framed the Static &
Mobile Pressure Vessels Rules, 1981 to regulate filling, possession, transport
and import of compressed gases in pressure vessels.
4.2.2 Vessels of water capacity exceeding 1000 liters intended for the
storage and transport of compressed gas which is subjected to internal
pressure exceeding 1 Atmosphere (Gauge) at maximum working temperature
of 55°C including cryogenic pressure vessel are covered under SMPV(U)
Rules, 1981.
4.2.3 Under the SMPV (U) Rules, 1981, it is obligatory to obtain necessary
approval/ licence for the following:-
i) Manufacture of pressure vessels and their fittings.
ii) Storage of compressed gas in pressure vessels.
iii) Transport of compressed gas in pressure vessels.
iv) Permission for import of pressure vessels.
Exemptions:
Under rule 3, certain vessels are exempted from these rules:
If the vessel(s) under consideration forms part of a processing plant,
If some unit process or unit operation is carried out in the vessel(s)
under consideration
70
If the compressed gas is received in the vessel(s) under consideration
from the same processing plant, and consumed in the same
processing plant,
If the holding capacity of the vessel(s) under consideration at the
maximum working pressure is not be more than 16 hours of
consumption in the process plant at the designated flow rate
Note: For qualifying the exemption, all the aforesaid four conditions need to
be satisfied.
4.2.4 Form of licenses, purpose and authority:
Form of
licence
Purpose Authority
Form III Storage of compressed gas
in pressure vessels in an
installation.
Chief Controller of
Explosives
Form IV Transport of compressed
gas in Mobile pressure
vessels mounted on vehicle
Chief Controller of
Explosives or Joint Chief
Controller of Explosives (duly
authorized)
4.2.5 Procedure adopted for grant of licenses under SMPV (U)
Rules,1981:
For filling of compressed gas in any pressure vessel and
storage/transportation of compressed gas contained in a pressure vessel,
the licence under these rules is obligatory (rule 4), except the exemptions
given for process as per rule 3.
No person shall deliver or dispatch any compressed gas filled in a
pressure vessel to any person other than the holder of a licence
issued under the rules.
71
Pressure vessels used for storage/transportation of compressed gas
shall be of a design approved in writing by Chief Controller of
Explosives and shall be fabricated by an approved manufacturer
under inspection of third party inspection agency.
Under the SMPV(U) Rules, 1981, different types of licenses are
granted for different purposes. The license for storage in static
vessels is granted in Form III. The license in Form IV is granted for
transportation of compressed gas in mobile tankers. The license for
auto LPG dispensing station is granted in Form V.
4.2.6 Licence in Form III
To Store Compressed Gas in Pressure Vessels in an Installation
A) Approval
Any person desiring to install pressure vessel for storing compressed gas is
required to obtain a prior approval from Chief Controller of Explosives by
submitting following documents:
1) Application Letter Duly Signed
2) Scrutiny fee of Rs 100/-
3) Land /Plot acquisition documents copy
4) Company/Firm Registration document
5) Brief description of the proposal/project.
6) Site Plan : Four copies of the site plan showing the location of the
proposed installation and facilities and other protected works within 100
mtrs. on all sides.
7) Layout plan: Four copies showing details of layout, foundation,
installation of pressure vessel, name of the gas, pump compressor
house, tank truck loading/unloading area, route of pipelines, brief
specification of pressure vessels and pipelines and electrical fittings
8) In case of toxic and flammable gas installations, Chief Controller of
Explosives may call for additional documents like risk analysis report,
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Environment Impact Assessment Report, copy of on-site emergency
plan.
Each vessel is to be fitted with at least two independent safety valves whose
set pressure shall not exceed 110% of the design pressure, pressure gauge,
drain, content gauge, temperature gauge and shut-off valves. The isolation
valves of such individual safety valve shall be kept open under normal
conditions.
In case of flammable or toxic gases of liquid (more than 3mm. dia ) and
vapour (8mm. dia) connections except relief valves and drains shall have
emergency shut-off valves, such as excess flow valve or automatic /remotely
operated control valve (refer rule 18). Pressure vessel shall be installed on a
proper design foundation taking into consideration static loading, test
loading, mean loading & operational loading (refer rule 23). In case of
flammable gases, the vessels and handling areas should be protected with
water sprinklers and sufficient number of fire hydrants/monitors connected to
an independent fire water tank should be provided and shown. Minimum
clear distances from the vessel and other facility for various types of gases
are given below:-
TABLE 4.1 Minimum safety distances for corrosive, toxic and permanent
flammable gases
Sl. No. Water capacity
of vessel (in
litres)
Minimum distance
from building or
group of buildings or
line of adjoining
property
Minimum distance
between pressure
vessels
(i) Not above 2000 5 meters 1 meter
(ii) Above 2000 but
not above 10,000
10 meters 1 meter
(iii) Above 10,000 but
not above 20,000
15 meters 1.5 meters
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(iv) Above 20,000 but
not above 40,000
20 meters 2 meters
(v) Above 40,000 30 meters 2 meters
B) Grant of Licence
After completion of the installation as per approved plan, the applicant
is to submit to Chief Controller of Explosives the following
documents:-
1. Application in form I duly filled and signed
2. Test and inspection certificates under Rule 12 (certificate of
control) issued by recognized 3rd party inspecting agency (Original
+ 2 copies).
3. Safety certificates under rule 33 issued by recognized competent
person (original + 2 copies)
4. Certificate of periodic tests of vessels and safety valve under Rules
18 & 19 (Not required for new vessels) (original + 2 copies).
5. Original no objection certificate from District Authority Under Rule
46 A of SMPV (U) Rule 1981 along with a site plan endorsed by
him ( not required for nontoxic and non-flammable gas)
6. Specimen signatures of persons authorized to make
correspondence in future with PESO.
7. Four copies of P & I Drawings
8. Four copies of replicated approved Drawings(as built)
9. Four copies of fabrication drawings of Vessel(s) duly attested by
the certifying inspector
10. Four copies of the as built installation drawings in Cad / Blue print
11. Certificate of Registration / firm Registration Copy. Land acquisition
/ allotment document Copy.
12. Requisite Licence fee drawn in as Demand Draft as calculated
below-
Rs.1000/- for first 5000 litres
74
Rs. 500/- for every additional 1000 litres of the water capacity of
the vessel/fabricated vessel subject to a maximum of Rs.10,000/-
per year. Licence can be granted for a maximum 3 years period.
4.2.7 Approval of shop for manufacture of Pressure Vessels, LPG
vaporizer and Safety Fittings (Safety valve/safety relief valve / Excess
flow valve)
Any person desiring to manufacture pressure vessels/ safety fittings
should submit the following documents to Chief Controller of Explosives for
approval of the shop :-
(a) Application in Appendix I in duplicate.
(b) Scrutiny fee of Rs.500/-
NOTE: The required details as per the Appendix I should be given in
separate annexure wherever necessary. The details of Bio-data of qualified
engineers for manufacture, quality control, testing etc., and particulars of
plant, equipments & machineries should be submitted. In addition, the
following documents are required to be submitted:
1. Three copies (Blue print) of detailed layout showing the various
equipments and machineries installed therein along with dimension of
the shed. The complete address of the manufacturing site shall be
incorporated.
2. Three copies of site plan showing approach road and various facilities
existing from the proposed fabrication shop.
3. The details of the make, model and capacity of various machines /
equipments and quality control equipments.
4. Details of material testing /radiography facilities including NDT.
5. The details of the stress relieving facilities, mechanical testing and dish
end formation facilities available.
6. The details of the calibration schedule of various instruments.
7. The preformat of various tests and inspection certificates shall be
furnished.
75
8. Details of in-house facilities available for fabrication, inspection and
testing.
9. Manufacturer, inspection and testing scheme proposed to be followed
for fabrication of pressure vessel right from raw material to finished
vessel.
10. Details of hydro test facilities available.
11. Details of qualified welders clearly indicating their name, qualification,
test passed, tests conducted, (WPS under Section IX of ASME Code).
12. Details of head of quality control section, number of quality control
engineers employed by you indicating details of ANST level II, III
qualification possessed by them with documentary evidence.
13. Details of design engineers, draftsman with documents evidence in
support of their qualification and experience.
14. Please specify the methodology proposed to be adopted for
maintenance / retrieval of records including design details, etc.
15. Details of third party inspection agency which are being engaged by
your to undertake manufacturer of pressure vessels.
16. Details of technical personnel along with their qualification, experience
& documentary evidence in support of qualification.
17. Details of technical manpower along with documentary evidence
available including quality control department for review, interpretation,
evaluation and acceptance of the reports.
18. Details of Memorandum of Article of Association of the company
including CST and VAT registration details.
19. The details of maintenance and retrieval of test and inspection reports
including traceability of the pressure vessels during manufacturer and
as end product.
20. Details of various standards/codes available with you.
On scrutiny of the documents, if the proposal appears to be in order,
Chief Controller of Explosives may call the applicant for technical
presentation in the office on the subject before referring the case to the
concerned Circle/Sub-circle office for inspection of the facilities and
appraisal of the capabilities of the applicant for manufacturing of pressure
76
vessels. On receipt of the satisfactory report of inspection and appraisal,
approval is granted in favor of the applicant. In case, the facilities of the
applicant are not adequate or if there are other deficiencies either during
scrutiny of initial proposal or during inspection of the site, the same is
communicated to the applicant.
4.2.8 Approval of design of Pressure Vessels
The pressure vessel shall be manufactured only by company/shop which is
already approved for such purpose. The design of each type/model of
pressure vessel to be manufactured by fabricator should be approved by
Chief Controller of Explosives. The design of Pressure vessel conforming to
IS:2825, ASME Sec VIII div1 or any other internationally recognized code
approved by the Chief Controller of Explosives may be considered for
Hydrogen service.
Documents required to be submitted are as follows:-
1) Three copies (static vessel)/ Seven copies (for mobile vessel) duly
vetted by the inspecting agency under whose supervision the vessel
is to be manufactured.
2) Design drawings showing the design particulars, code, methods of
construction, nozzles etc.
3) The design calculation as per the code duly vetted by the inspecting
agency.
4) Safety valve sizing calculation.
5) Scrutiny fee of Rs. 500/- for each design of vessel.
On scrutiny of the documents submitted, if the design is found in order, the
same is approved. In case of any deficiency, the matter is pointed out to the
fabricator/inspector. In case of manufacture of fittings initially a few prototype
fittings are allowed to be manufactured and subjected to inspection and
testing by the inspecting agency jointly with the field officer of the
77
Department and on receipt of the report of inspection/testing final approval is
granted.
4.2.9 Import of Pressure Vessels:
Any person intended to import pressure vessels is required to submit
to Chief Controller of Explosives the following documents:-
a. Two copies of test & inspection certificate including design
calculations of the vessel duly endorsed by the third party inspecting
agency of the country of origin.
b. Credentials of the manufacturer of the vessel.
c. Design details of the vessel, its fittings and particulars of
specifications of material used for construction.
d. Scrutiny fee of Rs. 500/-.
On scrutiny of the documents, if the design is found to be a particular
standard, international design and safe for the compressed gas in Indian
condition, permission to import the pressure vessel and approval of the said
pressure vessel is granted by the Chief Controller of Explosives.
It is mentioned that various liquid Hydrogen static and mobile vessel
have already been approved of water capacity ranging from 45M3 to 100M3
for ISRO’s Satish Dhawan Space Center with design pressure 13.7 Kg/cm2,
MOC S-304L conforming to ASME Section VIII Div. 1 and GOST Russian
standards.
78
79
SAFETY ASPECTS OF HYDROGEN
80
81
5.0 Hydrogen Safety
5.1 Introduction
Hydrogen has a long history of safe use in the chemical and aerospace
industries. An understanding of Hydrogen properties, proper safety
precautions, and established rules, regulations and standards are the keys to
this successful track record. Although Hydrogen has been safely produced,
distributed and used in chemical industry since many decades, the developed
safety procedures and technologies provide only limited guidance for mobile
Hydrogen applications. Safety will be a major issue from the standpoint of
commercialization of Hydrogen-powered vehicles. Much evidence suggests
that Hydrogen can be manufactured and used in professionally managed
systems with acceptable safety, but experts differ markedly in their views of
the safety of Hydrogen in a consumer-centered transportation system. A
particularly salient and under explored issue is that of leakage in enclosed
structures, such as garages in homes and commercial establishments.
Hydrogen safety, from both a technological and a societal perspective, will be
one of the major hurdles that must be overcome in order to achieve the
Hydrogen economy.
5.2 Properties of Hydrogen
Hydrogen is an odorless, colorless gas, with molecular weight of 2.016.
Hydrogen is the lightest element. Its density is about 14 times less than air
(0.08376 kg/m3 at standard temperature and pressure). Hydrogen is liquid at
temperatures below 20.3 K (at atmospheric pressure). Hydrogen has the highest
energy content per unit mass of all fuels - higher heating value is 141.9 MJ/kg,
almost three times higher than gasoline. Some important properties of Hydrogen
are compiled in Table 5.1.
Like any other fuel or energy carrier Hydrogen poses risks if not
properly handled or controlled. The risk of Hydrogen, therefore, must be
considered relative to the common fuels such as gasoline, propane or natural
gas. The specific physical characteristics of Hydrogen are quite different from
those common fuels. Some of those properties make Hydrogen potentially
82
less hazardous, while other Hydrogen characteristics could theoretically make
it more dangerous in certain situations.
Table 5.1: Selected properties of Hydrogen
Molecular weight -- 2.016
Density kg/m3 0.0838
Higher heating value MJ/kg 141.90
MJ/m3 11.89
Lower heating value MJ/kg 119.90
MJ/m3 10.05
Boiling temperature K 20.3
Density as liquid kg/m3 70.8
Critical point
temperature K 32.94
pressure bar 12.84
density kg/m3 31.40
Self-ignition temperature K 858
Ignition limits in air (vol. %) 4-75
Stoichiometric mixture in air (vol. %) 29.53
Flame temperature in air K 2,318
Diffusion coefficient cm2/s 0.61
Specific heat (cp) kJ/(kg ·K) 14.89
Since Hydrogen has the smallest molecule it has a greater tendency to
escape through small openings than other liquid or gaseous fuels. Based on
properties of Hydrogen such as density, viscosity and diffusion coefficient in
air, the intensity of Hydrogen to leak through holes or joints of low pressure
fuel lines may be only 1.26 to 2.8 times faster than a natural gas leak through
83
the same hole. Experiments have indicated that most leaks from residential
natural gas lines are laminar. Since natural gas has over three times the
energy density per unit volume the natural gas leak would result in more
energy release than a Hydrogen leak.
For very large leaks from high-pressure storage tanks, the leak rate is limited
by sonic velocity. Due to higher sonic velocity (1308 m/s) Hydrogen would
initially escape much faster than natural gas (sonic velocity of natural gas is
449 m/s). If a leak should occur for whatever reason, Hydrogen will disperse
much faster than any other fuel, thus reducing the hazard levels. Hydrogen is
both more buoyant and more diffusive than gasoline, propane or natural gas.
Table below compares some properties and leak rates for Hydrogen and
natural gas.
Table 5.2: Properties and leak rates of Hydrogen and natural gas
Hydrogen Natural gas
Flow parameters
Diffusion coef. (cm2/s) 0.61 0.16
Viscosity (-poise) 87.5 100
Density (kg/m3) 0.0838 0.651
Sonic velocity (m/s) 1308 449
Relative leak rates
Diffusion 3.80 1
Laminar flow 1.23 1
Turbulent flow 2.83 1
Sonic flow 2.91 1
84
Hydrogen/air mixture can burn in relatively wide volume ratios,
between 4% and 75% of Hydrogen in air. Other fuels have much lower
flammability ranges, viz., natural gas 5.3-15%, propane 2.1-10%, and
gasoline 1-7.8%. However, the range has a little practical value. In many
actual leak situations the key parameter that determines if a leak would ignite
is the lower flammability limit, and Hydrogen’s lower flammability limit is 4
times higher than that of gasoline, and 1.9 times higher than that of propane
and slightly lower than that of natural gas.
Hydrogen has a very low ignition energy (0.02 mJ), about one order of
magnitude lower than other fuels. The ignition energy is a function of fuel/air
ratio, and for Hydrogen it reaches minimum at about 25%-30% Hydrogen
content in air. At the lower flammability limit Hydrogen ignition energy is
comparable with that of natural gas. Hydrogen has a flame velocity 7 times
faster than that of natural gas or gasoline. A Hydrogen flame would, therefore,
be more likely to progress to a deflagration or even a detonation than other
fuels. However, the likelihood of a detonation depends in a complex manner
on the exact fuel/air ratio, the temperature and particularly the geometry of the
confined space. Hydrogen detonation in the open atmosphere is highly
unlikely.
The lower detonability fuel/air ratio for Hydrogen is 13%-18%, which is
two times higher than that of natural gas and 12 times higher than that of
gasoline. Since the lower flammability limit is 4% an explosion is possible only
under the most unusual scenarios, e.g., Hydrogen would first have to
accumulate and reach 13% concentration in a closed space without ignition,
and only then an ignition source would have to be triggered. Should an
explosion occur, Hydrogen has the lowest explosive energy per unit stored
energy in the fuel, and a given volume of Hydrogen would have 22 times less
explosive energy than the same volume filled with gasoline vapor.
Hydrogen flame is nearly invisible, which may be dangerous, because
people in the vicinity of a Hydrogen flame may not even know there is a fire.
85
This may be remedied by adding some chemicals that will provide the
necessary luminosity. The fumes and soot from a gasoline fire pose a risk to
anyone inhaling the smoke, while Hydrogen fires produce only water vapor
(unless secondary materials begin to burn).
Liquid Hydrogen presents another set of safety issues, such as risk of
cold burns, and the increased duration of leaked cryogenic fuel. A large spill
of liquid Hydrogen has some characteristics of a gasoline spill; however it will
dissipate much faster. Another potential danger is a violent explosion of a
boiling liquid expanding vapor in case of a pressure relief valve failure.
5.3 Hydrogen in Transport Sector:
The transition in vehicle fuels from liquid hydrocarbons to gaseous
Hydrogen requires an adaptation of automobile design and safety technology
to the special properties of Hydrogen. In contrast to LPG and gasoline vapor,
Hydrogen is extremely light and rises rapidly in air. In the open this is
generally an advantage, but it can be dangerous in buildings that are not
designed for Hydrogen. Many countries’ building codes, for instance, require
garages to have ventilation openings near the ground to remove gasoline
vapor, but there is often no high level ventilation. Hydrogen released in such a
building collects at ceiling level, and a resulting explosion can be extremely
destructive. Hydrogen has been used widely for more than a hundred years in
large-scale industrial applications. There have been incidents with Hydrogen,
as there have been with other materials including gasoline, LPG and natural
gas. In general, though, experience shows that Hydrogen can be handled
safely in industrial applications as long as users stick to the appropriate
standards, regulations and best practices. Modern, established technologies
within energy supply and transportation are at high safety standards. This
ensures a secure, safe and user-friendly supply of energy in stationary,
transport and other system applications. It is the result of a long learning
process within these technologies. Future infrastructure systems for Hydrogen
applications, as new storage media and refueling stations, need at least to
have the same high safety standards as the established technologies.
86
Guidelines issued by agencies like ISRO, DRDO, BARC based on their
experience make the large-scale industrial applications very safe in general,
but comparing with the application of natural gas the frequency of accidents is
reported 5–20 times higher for Hydrogen. The following accident causes have
been identified:
Mechanical failures of vessels, pipes, etc. often caused by Hydrogen
embrittlement or freezing
Reaction with pollutants (e.g. air)
Too low purity of Hydrogen
Accidents caused by smaller releases due to poor ventilation or flow
back of air under ventilation
Accidents during purging with inactive gases,
Non-functioning of safety equipment,
Wrong operations (by staff),
Failure in evaporating system (e.g. valve failure) or not intended
ignition/fire/explosion.
5.4 Hydrogen vehicle hazards
Hydrogen onboard a vehicle may pose a safety hazard. The hazards
should be considered in situations when vehicle is inoperable, when vehicle is
in normal operation and in collisions. Potential hazards are due to fire,
explosion or toxicity. The latter can be ignored since neither Hydrogen nor its
fumes in case of fire are toxic. Hydrogen as a source of fire or explosion may
come from the fuel storage, from the fuel supply lines or from the fuel cell. The
fuel cell poses the least hazard, although Hydrogen and oxygen are
separated by a very thin (~20-30 m) polymer membrane. In case of a
membrane rupture Hydrogen and oxygen would combine, but in that case the
fuel cell would lose its potential, which should be easily detected by a control
system. In that case the supply lines should be immediately disconnected.
The fuel cell operating temperature (60° to 90°C) is too low to be a thermal
ignition source; however, Hydrogen and oxygen may combine on the catalyst
87
surface and create ignition conditions. However, the potential damage would
be limited due to a small amount of Hydrogen present in the fuel cell and fuel
supply lines. The largest amount of Hydrogen at any given time is present in
the tank. Several tank failure modes may be considered in both normal
operation and collision, such as:
catastrophic rupture, due to manufacturing defect in tank, a defect
caused by improper handling of the tank or stress fracture, puncture by
a sharp object, external fire combined with failure of pressure relief
device to open;
massive leak, due to faulty pressure relief device tripping without cause
or chemically induced fault in tank wall; puncture by a sharp object,
operation of pressure relief device in a case of fire.
Slow leak due to stress cracks in tank liner, faulty pressure relief
device, or faulty coupling from tank to the feed line, or impact-induced
openings in fuel line connection.
A similar failure analysis may be applied to both high pressure and low
pressure fuel lines. In a study conducted on behalf of Ford Motor Company
and Directed Technologies, Inc., has performed a detailed assessment of
probabilities of the above failure modes. The conclusion of the study is that a
catastrophic rupture is a highly unlikely event. However, several failure modes
resulting in large Hydrogen release or a slow leak has been identified both in
normal operation and in collision.
Most of the above discussed failure modes may be either avoided or
their occurrence and consequences minimized by:
Leak prevention through a proper system design, selection of adequate
equipment (some further testing and investigation may be required),
allowing for tolerance of shocks and vibrations, locating a pressure
relief device vent, protecting the high pressure lines, installing a
normally closed solenoid valve on each tank feed line, etc.
88
Leak detection by either a leak detector or by adding an odorant to the
Hydrogen fuel (this may be a problem for fuel cells);
Ignition prevention, through automatically disconnecting battery bank,
thus eliminating source of electrical sparks which are the cause of 85%
gasoline fires after a collision, by designing the fuel supply lines so that
they are physically separated from all electrical devices, batteries,
motors and wires to the maximum extent possible, and by designing
the system for both active and passive ventilation (such as an opening
to allow the Hydrogen to escape upward).
The risk is typically defined as a product of probability of occurrence
and consequences. The above mentioned study by Directed Technologies
Inc. includes a detailed risk assessment of several most probable or most
severe Hydrogen accident scenarios, such as:
Fuel tank fire or explosion in unconfined spaces
Fuel tank fire or explosion in tunnels
Fuel line leaks in unconfined spaces
Fuel leak in garage
Refueling station accidents
In a collision in open spaces, a safety-engineered Hydrogen fuel cell
car should have less potential hazard than either natural gas or a gasoline
vehicle. In a tunnel collision, a Hydrogen fuel cell vehicle should be nearly as
safe as a natural gas vehicle, and both should be potentially less hazardous
than a gasoline or propane vehicle, based on computer simulations
comparing substantial post collision release of gasoline and natural gas in a
tunnel. The greatest potential risk to the public appears to be a slow leak in an
enclosed home garage, where an accumulation of Hydrogen could lead to fire
or explosion if no Hydrogen detection or risk mitigation devices or measures
are applied (such as passive or active ventilation).
Kreiser et al. in 1994 reported 287 Hydrogen related accidents
worldwide categorized into (A) “no ignition”, (B) “fire” and (C)
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“explosion/vessel burst” and found a frequency for category A as 22%, for
category B 26% and for category C 52%. Further analysis showed for
category A is pronounced higher frequency for cryogenic Hydrogen accidents
compared to pressurized Hydrogen related ones. Based on all the data it was
concluded that pressurized Hydrogen may cause more severe accidents than
the cryogenic, but that the statistics partially are biased to the non-detection of
smaller category (A) pressurized releases. In the cryogenic case, they argue,
a release is more easily detected by the condensed water vapor and,
therefore, also more frequently logged as accident. Practical and positive
experiences on handling Hydrogen safely within industries using approved
routines by skilled workers exist for pipelines and underground storages of
Hydrogen. The operating pressure in existing pipelines range from few MPa
to more than 100MPa. There are no accident reports for these pipeline
networks and the operators are reported to have positive experiences
operating the pipelines. The same applies to the underground storage. There
are substantial
Table 5.3: Safety aspects related to centralized versus on-site production
of Hydrogen
Application Environment: Centralized Scenario Environment:
Distributed /
Local Scenario
H2 production
site
Potential placement in remote area,
closed industrial site, industrial safety
rules fully applied, access only for
skilled workers
Placed at
refueling station
also in urban
areas, closed
industrial site with
fully applied
safety rules, small
production
quantities
compared to
centralized facility
90
Main and
regional
storage
Placement in less populated areas
possible, closed industrial site, industrial
safety rules fully applied, access for
skilled workers
Not necessary
Transport by
pipelines
Industrial application, placed between
e.g. production and main/regional
storages
On-site
Transport by
trucks, rail
and ship
Necessary, route planning necessary,
potential risks very much dependent on
the region (topology, meteorology,
population density etc.)
Not necessary
Transport by
power grid
N.A. Production by
electrolysers
Refueling site
storage
Buffer storages coupled with
compressors if lower pressure storage
is used
Same as above
Refueling the
vehicles
Unskilled drivers may spend 10–15 min
onsite, industrial safety standards will
not be fully applicable, a number of
passengers will be in the vehicles (cars)
and special safety precautions for them
have to be taken. The same for tourist
long distance buses that need to refuel
under a longer trip
Same as above
5.5 Safety Issues for Refueling Station:
A refueling station will comprise of either 1) Reformer or Electrolyser
with Hydrogen compressors, storage and dispenser or 2) Tanker delivery,
Hydrogen storage, pumps /compressors and dispenser. Following potential
accident scenarios may emerge:
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a) Reformer inside a closed container
Hazard
Leakage from natural gas line
Rupture of reformer tube
Pipe rupture due to H2 Embrittlement
Rupture of Hydrogen line to compressor
Safety Requirement
Ventilation inside the container
Detectors for Hydrogen and NG and proper isolation
Restricted access to the container
Venting surfaces on the container
Regular inspection of Reformer tubes as done in refineries
b) Electrolyser inside closed container
Hazard
Lye leak through cells due to overpressure or gasket failure
Oxygen leak inside the container, leading to fire enhancement
Large H2 ingress into container by backflow of Hydrogen from
storage
Safety Requirement
Preventing a mixture of H2 and O2 inside the electrolyser
Detectors for Hydrogen and oxygen with isolation system
Restricted access to the container
Regular inspection
Venting surfaces on the container
c) Compressor inside container
Hazard
Since Hydrogen will be pressurized to very high pressures up to
700 bars leakage and backflow from the storage are important
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scenarios. Further there can be issues of leakage of Hydrogen due
to vibrations can also be an issue.
Safety Requirement
Proper pressure controls, vibration control and detectors for
Hydrogen with forced ventilation can be installed as safety
measures
d) Buffer storage in Open Air
Hazard
It will contain the major Hydrogen inventory which needs to be
handled. The main hazards are Hydrogen leakage with explosion.
Due to high pressures and volumes of Hydrogen bursting of
Hydrogen bottles may take place which may trigger failure of other
bottles in the quad.
Safety Requirement
The main safety barriers against above is to limit the Hydrogen leak
rates, to isolate the leaky cylinder and to discharge the Hydrogen
inventory in a safe way.
e) Dispenser in Open Air
Hazard
Dispenser will consist of refueling unit and a dispenser hose. The
use of flexible hose and regular connection/disconnection action
increases the chances of Hydrogen leakage or line rupture. The
dispenser scenarios are critical for whole safety evaluation of filling
station as customers will be involved and located near to release
location
Safety Requirement
Safety measures can include Hydrogen leak detectors, good nozzle
and regular hose maintenance. As far as automatic filling system
can be installed actuating emergency shutdown in case of leaks /
hazards.
93
f) Compressed Hydrogen Gas in open air
Hazard
Instead of onsite production the scenario of Hydrogen delivery by
trucks involves transfer of huge quantities of Hydrogen at high
pressures. For a 700 bars filling station the delivery pressures of well
above 1000 bars will be required for reasonable discharge and time.
Hose failure or leaks are the possible accident scenarios.
Safety Requirement
Hydrogen leak detection before, during and after tanker connections,
loading of Hydrogen tanks in separately protected area and emergency
shutdown procedures can be important safety measures.
5.6 Liquid Hydrogen Storage and Safety
Hazards associated with GH2 remains with LH2 as well because of the
ease with which the liquid evaporates. Characteristic properties of LH2 of
potential safety implications are given below:
(1) Low BP (NBP 20.3 K frostbite or hypothermia, asphyxiation),
(2) Ice formation & blocking of venting valves
(3) Continuous evaporation, venting needs and air contamination through
solidification
(4) Pressure rise
(5) Pressure rise (trapped volume of LH2 can develop a pressure of 25000
psia (172 MPa) if it happens to get heated to 25 oC.
(6) High density of saturated vapour and spreading of Hydrogen cloud
A. Flammability and Ignition of Hydrogen
Major emphasis shall be on containment, detection, and ventilation
because the minimum energy of GH2 ignition in air at atmospheric pressure is
about 0.02 mJ and experience shows that escaped Hydrogen is very easily
ignited. Like GH2, LH2 with LOX is not hypergolic. Still, during mixing, the
94
mixture has ignited due to the very low ignition energy. The flammability limit
for Hydrogen in air is also very wide, from 4.1 to 74.8% and in Oxygen it
extends to 94 %.
Ignition sources must be totally eliminated or safely isolated and
operations shall be conducted as if unforeseen ignition sources could occur.
Major considerations in this regard are
(1) Geometry of flow conditions
(2) Possibility of Electric sparks, viz., electrical equipment, static electricity
from people, objects, flow of various media involved etc.
(3) Friction generated sparks
(4) Impact generated sparks
(5) Hot objects/flames; while 773 to 854 oC would result in spontaneous
ignitions, even cooler levels of 590 K can cause ignition on prolonged
contact
(6) Containment / suppressing of deflagration/detonation wherever it
cannot be avoided, using water sprays/CO2 etc.
B. Materials selection
Typical Hydrogen systems shall normally consist of structural
members, valve bodies, valve seats, electrical and thermal insulations, seals,
gaskets, adhesives, lubricants and will involve a multitude of different
materials. Major considerations towards selection of materials are
i. Properties suitable for design and operations
ii. Compatibility with environment
iii. Availability of material with appropriate test data
iv. Corrosion resistance
v. Ease of fabrication, assembly and inspection
vi. Consequences of a material failure
vii. Toxicity
viii. Hydrogen embrittlement
ix. Potential for exposure to high temperature due to a Hydrogen fire
x. Cold embrittlement
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xi. Thermal contraction
xii. Property changes at cryogenic temperatures
Generally materials with FCC structure, such as, austenitic stainless
steels, aluminum alloys, copper, and copper alloys, generally are satisfactory
for Hydrogen service, except Nickel. Unstabilised austenitic steels (300
series) might revert to martensitic structure when stressed at low temperature
reducing ductility. Ordinary carbon steels may be used in GH2 service, but
they loose their properties in LH2. Iron, low alloy steels, chromium, Mb, Nb, Zn
and most bcc materials are not acceptable for use at cryogenic temperatures.
Gray, ductile or cast iron shall not be used in Hydrogen service (29 CFR
1910.103 1996 and NFPA 50A 1994)
C. Hydrogen embrittlement
The phenomena by which Hydrogen significantly alter the mechanical
properties of the material. It involves a number of variables such as,
temperature, pressure, purity, concentration, exposure, stress rate, physical
and mechanical properties, microstructure, surface conditions, nature of crack
front of the material.
Some of the general design consideration that must be factored in are
(1) The susceptibility of an alloy to adverse Hydrogen effects increases as
the strength of the alloy increases
(2) The effect of embrittlement is maximum in the temperature range of
200 to 300 K.
(3) The susceptibility of steels increases with purity of the gas as well as
increase in tensile strength
(4) Embrittlement increases crack growth rate and reduces fatigue life
General guidelines to avoid Hydrogen embrittlement effects:
1. Aluminium shows min susceptibility; use it wherever possible
96
2. Most of LH2 equipments are made up of stainless steel and care is
taken with regard to increased thickness, surface finish, welding
techniques and material selection
3. Thicker low strength materials are safer than thinner high strength
4. Five-fold reduction in fatigue strength shall be considered for design
5. Though low temperature retard Hydrogen reaction embrittlement, it
leads to increase in environmental and internal Hydrogen
embrittlement
6. Electrical Discharge Machining shall be avoided as its enhances the
susceptibility to Hydrogen embrittlement.
Apart from the above, a serious issue with regard to LH2 is the Low
temperature embrittlement of several materials which shall be given due
importance in selection of materials for various applications.
D. Hydrogen Facilities
a. Safety policy & reviews
Safety shall be considered in all phases of a Hydrogen facility life cycle.
Safety of the design shall be done in accordance with NHB 1700.1 (1993) and
its subsequent revisions or its equivalents. Construction and construction
practices shall be done in accordance with 29 CFR 1926 (1996) and its
revisions or its equivalents.
A well laid review procedure as given below shall be followed, especially for
new facilities:
(1) Concept design review (10 % review)
(2) Preliminary design review (30/60% review)
(3) Critical design review (90%)
(4) Design certification review (100 % review)
(5) System and Hazard analyses shall be continued
(6) Further reviews: Test readiness review, emergency procedure review
and operational readiness review
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b. General facility guidelines
Facility and structure design shall include sufficient details for demonstrating
satisfactory safety in the storage and transfer areas. Major considerations
shall include
i. Electrical: Areas where flammable mixture of H2 are expected shall be
classified as Class 1, Group B, Division 1. Areas where H2 is stored,
transferred or used and where Hydrogen is normally contained are
classified as Class 1, Group B, Division 2, as a minimum. NFPA 70
(1993) & its revisions or equivalents shall be consulted wherever
necessary
- In classified areas, all ignition sources is prohibited; explosion
proof electrical equipments only shall be permitted
- Wherever explosion proof fittings are not feasible, the potential
ignitions source shall be sufficiently isolated by inert gas purging
or equivalent procedures
- Intrinsically safe installations in accordance with NFPA 70
(1993) & its revisions or equivalents shall only be used
ii. Bonding and grounding:
- Mobile Hydrogen supply units shall be electrically bonded to the
system before discharging Hydrogen (NFPA 50A 1994, 29 CFR
1910.03 1996 and its revisions or equivalents)
- LH2 containers and, static and mobile, and associated piping
shall be electrically bonded and grounded (NFPA 50B 1994 and
29 CFR 1910.103 1996 with revisions both or its equivalents)
- Facility grounding resistance shall be less than 10 ohm
resistance
- Electrical wiring and equipment located within 0.9 m of a point at
which connections are regularly made and disconnected shall
be in accordance with NFPA 70 (1993) for class I, group B,
Division 1 locations.
iii. Roadways and Area surfaces
- The roadways and area surfaces located below LH2 piping from
which liquid air may drop shall be constructed of non-
combustible materials such as concrete
98
- Asphalt shall not be used
iv. Transfer piping: Shall be installed above ground. Lines crossing roads
shall be installed in concrete channels covered with open grating. H2
carrying transmission lines shall not be located below beneath electric
power lines
v. Elimination of ignitions sources:
- Lightning protection shall be ensured
- Essential mechanisms shall be in place wherever venting is
involved
- Static charge build up/discharge shall be fully eliminated
- Electrical system involved shall be fully arcing free
vi. Spark generation shall be prevented; spark proof tools are to be used.
Accidental generation of sparks during usage of tools and other
operations must be eliminated. Conductive and non-sparking floors
have to be used. Mechanisms to be put in place to avoid any change in
the safety properties of the floors such as cutting grooves, painting,
dirtying etc.
vii. Hot objects, flames etc shall be completed avoided. Internal
combustion engines if used must be provided with exhaust system
spark arrestors.
viii. Flame arrestors designed for Hydrogen service alone shall be used,
wherever necessary.
ix. Testing: All cryogenic components shall be tested prior to acceptance
for operational use. Piping and piping components shall be tested in
accordance with ANSI / ASME B31.3 (1996) and its revisions and
vessel in accordance with ASME BPVC (1995) and is revisions.
Testing shall include, but not limited to, cold soak, thermal
performance, pressure, leakage, welding and vacuum retention.
c. Building and test chambers
Shall be consistent with the safety requirements of limiting personnel
injury and facility damage in the event of Hydrogen fires or explosions
99
Shall be in accordance with 29 CFR 1010.103 (1996), NFPA 50A
(1994) and NFPA 50B (1994) and their revisions or its equivalents and
their replacements, wherever applicable.
Buildings shall be constructed of light, non-combustible materials,
windows panes shall be shatterproof, floors, walls and ceilings shall
limit generation of static electricity. Explosion proof venting shall be
provided on exterior walls and roofs.
Any heating in Rooms and systems connected with Hydrogen shall
only be through indirect means such as steam.
Weather shelter/canopy etc. shall be of non-combustible materials
Electrical equipments shall conform to the requirements of NFPA 70
(*1993) for class 1, group B locations. Possibility of loose connections
on terminals and shorting through foreign materials etc shall be
completely eliminated
Electrical wiring and equipments located within 0.9 m of a point where
connections are regularly made and disconnected shall be in
accordance with NFPA 70 (1993) for class 1, Group B, Division 1
locations and for distances greater than 0.9 m, above standard of Div 2
shall be followed.
Wherever equipments approved for Class 1, Group B atmosphere are
not available, adequate venting shall be ensured.
Adequate ventilation is a must and a minimum air exchange to the tune
of 1 ft3 of air per square foot of solid floor in the space shall be ensured.
Location and quantity – distance guideline, exclusion areas and
Protection of Hydrogen systems and areas:
Are based on the concept that the effects of fire, fire, explosion and
detonation can be reduced to tolerable levels if the source of the
hazard is kept far enough away from people and other facilities.
These are elaborate guidelines with regard to each and every aspects
concerned and relevant standards which need to be adhered to for liquid
Hydrogen safety.
100
In conclusion, Hydrogen appears to poses risks of the same order of
magnitude as other fuels. In spite of public perception, in many aspects
Hydrogen is actually a safer fuel than gasoline and natural gas. As a matter of
fact, Hydrogen has a very good safety record, as a constituent of the “town
gas” widely used in Europe and USA in the 19th and early 20th century, as a
commercially used industrial gas, and as a fuel in space programs. There
have been accidents, but nothing that would characterize Hydrogen as more
dangerous than other fuels. Nevertheless, further research may be needed in
exploring and quantifying both causes and consequences of Hydrogen leaks,
development of new materials and couplings less susceptible to Hydrogen
leaks, lifetime and failure modes of fuel cells, etc. and CFD analysis of leaking
Hydrogen scenarios can be very useful tool. The results should be
disseminated throughout the scientific community and used to generate the
codes and standards for Hydrogen use in the vehicles. Selected information
should be fed to media and general public, in order to change the image of
Hydrogen as a dangerous fuel. Practical demonstrations may be extremely
valuable in that aspect.
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STANDARDS ON HYDROGEN
102
103
6.0 Standards on Hydrogen
6.1 Introduction
Hydrogen being the lightest element is characterized by low volume
energy density meaning that a given volume of Hydrogen contains a small
amount of energy. This presents significant challenges to storing the large
quantities of Hydrogen that will be necessary in the Hydrogen energy
economy
The Hydrogen may be stored in the liquid, compressed or absorbed form. In
view of safety for storage and transportation of the Hydrogen the following
Indian standards have been published by Mechanical Engineering
Department of Bureau of Indian Standards and ISO which covers the
terminology, design, material, construction requirement and test methods:
6.2 Hydrogen Vehicle and Engine Standards
UNECE: If approval is sought for a hydrogen vehicle, emissions, fuel
consumption and engine power can be tested according to the new hydrogen
fuel directives/ regulations.
List of directives/ regulations to be amended for road vehicles are as follows:
Subject EEC-Directive/ECE-Regulation
1. Emissions 70/220/EEC incl. latest amendment & ECE R83
2. Fuel tanks/rear protective device 70/221/EEC incl. latest amendment &
ECE R34/58
3. Identification of controls 78/316/EEC incl. latest amendment
4. Fuel consumption 80/1268/EEC incl. latest amendment & ECE R 101
5. Engine Power 80/1269/EEC incl. latest amendment & ECE R84
6. Side impact 96/27/EC & ECE R95
7. Frontal impact 96/79/EC & ECE R94
8. Roadworthiness tests 96/96/EC & PTI
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9. CO2 labelling 99/94/EC
10. Base Directive 70/156/EEC incl. latest amendment
11. Electric Vehicles NEW EC Directive & ECE R100
12. Defrost/Demist 78/317/EWG (already under progress)
European Integrated Hydrogen Project
EIHP, a partnership between the European Hydrogen Industry and the
European Commission, provided inputs for regulatory activities on a European
and global level to facilitate harmonised Procedures for the approval of
hydrogen fuelled road vehicles.
• Vehicle - continued work to develop draft UNECE regulations and initiate
work on a global level (GTR)
• Infrastructure - refuelling stations and fuelling interface - EU and North
America
• Safety studies, computer simulations and first limited safety tests
6.3 For liquid Hydrogen:
IS/ISO 13985 “Liquid Hydrogen — Land Vehicle Fuel Tanks” have
been published adopting ISO 13985 This standard lay down requirements for
protection from loss of life and property resulting from fire and explosion. This
Standard is applicable to fuel tanks intended to be permanently attached to
land vehicles.
6.4 For Compressed Hydrogen:
a) IS 7285-1:2004 Refillable Seamless Steel Gas Cylinders Part-1 Normalized
Steel Cylinders – Specification have been published based on the ISO 9809-
3,
105
b) IS 7285-2:2004 Refillable Seamless Steel Gas Cylinders Part 2 Quenched
and Tempered Steel Cylinders with Tensile Strength less than 1100 MPa (112
Kgf/mm²) – Specification has been published based on the ISO 9809-1
c) IS 8198 : 2004 “Steel Cylinders For Compressed Gases (Atmospheric
Gases, Hydrogen, High Pressure Liquefiable Gases and Dissolved Acetylene
Gases)— Code of Practice” covers filling, inspection, testing, maintenance
and use of portable steel cylinders for the storage and transportation of
atmospheric gases, Hydrogen gas, high pressure liquefiable gases and
dissolved acetylene gases in cylinders exceeding 500 ml water capacity.
d) IS 15660:2006 “Refillable transportable seamless aluminum alloy gas
cylinders – Specification” lays down the minimum requirements for the
material, design, construction, workmanship, manufacturing processes and
tests of refillable seamless aluminum alloy gas cylinders of water capacities
from 0.5 litre up to and including 150 litre for transportable compressed,
liquefied gases except liquefied petroleum gases.
e) Draft Indian Standard Cylinders for On-Board Storage of Compressed
Gaseous Hydrogen and Hydrogen Blends as a Fuel for Automotive Vehicles –
Specification - (Under Formulation) specifies the requirements for light weight
refillable cylinders intended for the onboard storage of high-pressure
compressed gaseous Hydrogen or Hydrogen blends on automotive vehicles.
6.5 Other international standards
Other international standards published for the storage of Hydrogen
are ISO 11119-1:2012 “Gas Cylinders -- Refillable Composite Gas Cylinders
and Tubes -- Design, Construction and Testing -- Part 1: Hoop wrapped fibre
reinforced composite gas cylinders and tubes up to 450 l” , ISO 11119-2:2012
“Gas cylinders -- Refillable Composite Gas Cylinders and Tubes -- Design,
Construction and Testing -- Part 2: Fully wrapped fibre reinforced composite
gas cylinders and tubes up to 450 l with load-sharing metal liners” and ISO
11119-3:2013 Gas Cylinders -- Refillable Composite Gas Cylinders and
Tubes -- Design, Construction and Testing -- Part 3: Fully wrapped fiber
reinforced composite gas cylinders and tubes up to 450 l with non-load-
sharing metallic or non-metallic liners.
106
6.6 Hydrogen Codes and Standards
Several organizations are involved in new standards activity in
response to the growth of interest in Hydrogen as a fuel. The National
Hydrogen Association has created Codes and Standards Working Groups on
topics such as hydride storage, electolysers for home use, transportation
infrastructure issues and maritime applications. The Society of Automotive
Engineers, through a Fuel Cell Standards Forum Safety Task Force is
collaborating with the National Highways Authority of India (NHAI) on the
transportation issues. Much of these standards writing is taking place at the
International Organization for Standardization (ISO) level in ISO Technical
Committee 197 (Hydrogen Technologies) with input through the national
organizations. The International Electrotechnical Committee, IEC TC 105
(Fuel Cells}, ISO TC 197, and ISO TC22 SC 21 (Electric Vehicles) are all
involved in fuel cell standards activities.
ISO TC 197 is one of the more active standards writing groups for
Hydrogen. Since new standards are being developed rapidly, ISO TC 197 and
the other organizations should be checked for possible new standards when
considering some of these newer systems. ISO/TC 197, Hydrogen
technologies, is actively developing consensus-based International Standards
that will facilitate the market entry of these new technologies. Working
together, Hydrogen can be made a sustainable energy solution.
Most of the work of ISO TC 197 is dedicated to mobile applications.
Canada, USA, and Germany are the most active countries in these working
groups. IEC TC 105 has also been very active, even though it was
established as late as in 1998. So far, ISO standards have been published on
product specifications for Hydrogen as a fuel (ISO14687) and vehicle fuelling
interfaces for liquid Hydrogen (ISO 13984). Documents close to being
published by both IEC and ISO cover basic safety considerations for
Hydrogen systems, fuel cells and airport fuelling applications.
107
6.7 International Organization for Standardization (ISO)
ISO is a worldwide federation of national standards bodies from more
than 140 countries. Established in 1947, its mission is to promote
standardization to facilitate the exchange of goods and services, and to
facilitate cooperation in intellectual, scientific, technological and economic
activities. ISO standards are developed through a consensus process.
ISO/TC 197 has many active working groups, developing international
standards for Hydrogen tanks, fuel quality for demonstration fleets, refueling
stations, Hydrogen detectors, reformers, and electrolyzers, to name a few.
The activities of various groups under TC 197 are coordinated with other
international technical committees wherever appropriate – including TC 22 for
road vehicles, TC 58 for tanks, and IEC/TC 105 for detectors.
6.8 ISO TC 197 - Hydrogen Technologies
The Committee deals with the systems and devices for the production,
storage, transport, measurement, and use of Hydrogen. Working groups
address standards and guidelines for gaseous and gaseous blends and liquid
fuel tanks for vehicles, Hydrogen safety, Hydrogen fuel quality, water
electrolysis, fuel processing and transportable gas storage devices.
6.9 ISO TC 22 - Road Vehicles
The Committee deals with compatibility, interchangeability, and safety,
with particular attention to terminology and test procedures for mopeds,
motorcycles, motor vehicles, trailers, semi-trailers, light trailers, combination
vehicles and articulated vehicles. The Electric Road Vehicle Subcommittee
(SC21) is addressing operation of vehicles, safety, and energy storage.
108
6.10 ISO TC 58 - Gas Cylinders
The Committee deals with fittings and characteristics related to the use
and manufacture of high-pressure gas storage. The working group on gas
compatibility and materials coordinates with TC 197. Thus International
Standards from ISO/TC 197 on Hydrogen refueling stations and Hydrogen
generators will play a major role in facilitating the safe introduction of
Hydrogen. Canada, USA, and Germany are the most active countries in these
working groups. IEC TC 105 has also been very active, even though it was
established as late as in 1998. So far, ISO standards have been published on
product specifications for Hydrogen as a fuel (ISO 14687) and vehicle fuelling
interfaces for liquid Hydrogen (ISO 13984). Documents close to being
published by both IEC and ISO cover basic safety considerations for
Hydrogen systems, fuel cells and airport fuelling applications.
There are 19 participating countries and 12 observing countries under the ISO
programme for Codes and Standards for Hydrogen. These Include
6.11 Participating Countries
Secretariat: Canada ( SCC )
Argentina ( IRAM ) China ( SAC ) Denmark ( DS )
Egypt ( EOS ) France ( AFNOR ) Germany ( DIN )
India ( BIS ) Italy ( UNI ) Japan ( JISC )
Korea, Republic of ( KATS ) Netherlands ( NEN ) Norway ( SN )
Russian Federation ( GOST R) Spain ( AENOR ) Sweden ( SIS )
Switzerland ( SNV ) USA ( ANSI ) U. K.( BSI )
Observing Countries
Australia ( SA ) Austria ( ON ) Brazil ( ABNT )
Czech Republic ( UNMZ ) Finland ( SFS ) Hong Kong,China( ITCHKSAR)
Hungary ( MSZT ) Jamaica ( BSJ ) Libyan Arab Jamahiriya
(LNCSM)
Serbia ( ISS ) Thailand ( TISI) Turkey ( TSE )
109
ISO/TC 197, Hydrogen technologies, is actively participating in various
levels of the UN/ECE (United Nations / Economic Commission for Europe)
where Hydrogen vehicle regulations are being developed. ISO/TC 197 brings
consensus based International Standards – such as road vehicle fuel tanks
for liquid Hydrogen and gaseous Hydrogen, refueling connectors, and the
Hydrogen fuel quality specifications which will eventually form a significant
part of the technical content of global regulations being developed by the UN.
The result of such strong cooperation between UN/ECE and ISO will help put
in place, for the first time, a series of worldwide agreed requirements
applicable to vehicles.
The various subcommittee / working group (under TC 197) working on
different areas related to Hydrogen and its usage as fuel are given in Table
6.1:
Table 6.1: Various Working groups under ISO/TC 197
Subcommittee/
Working Group
Title
TC 197/WG 5 Gaseous Hydrogen - Land vehicle filling
connectors
TC 197/WG 6 Gaseous Hydrogen and Hydrogen blends - Land
vehicle fuel tanks
TC 197/WG 8 Hydrogen generators using water electrolysis
process for Industrial and Household applications
TC 197/WG 9 Hydrogen generators using fuel processing
technologies
TC 197/WG 10 Transportable gas storage devices - Hydrogen
absorbed in reversible metal hydride
TC 197/WG 11 Gaseous Hydrogen - Service stations
TC 197/WG 12 Hydrogen fuel - Product specification
TC 197/WG 13 Hydrogen detectors
110
So far, ISO standards have been published on product specifications for
Hydrogen as a fuel (ISO 14687) and vehicle fuelling interfaces for liquid
Hydrogen (ISO 13984). Documents close to being published by both IEC and
ISO cover basic safety considerations for Hydrogen systems, fuel cells and
airport and fuelling applications. Work in progress covers vehicle storage for
gaseous, liquid and hydride-absorbed Hydrogen, fuelling systems and service
stations, Hydrogen generators and fuel cells. Safety is specifically addressed,
for example in separate sections in the IEC documents. The current status of
work under various working groups can be viewed at
http://www.hpath.org/codes-and-standards.
Bureau of Indian Standards (BIS) is giving clearances to Indian
consumers for any demonstration projects for use of Hydrogen if they conform
to the relevant ISO standards.
6.12 International Electro technical Commission (IEC)
IEC is a leading global organization for preparing and publishing
international standards for electrical, electronic and related technologies. The
IEC is developing standards for the electrical interface to fuel cells. IEC
Technical Committee 105 is primarily addressing stationary fuel cell power
plants, but has also addressed portable and propulsion fuel cells. The working
groups in TC 105 include the following: Terminology, Fuel Cell Modules,
Stationary Safety, Performance, Installation, Propulsion and Safety and
Performance of Portable Fuel Cells.
6.13 Standards Development Approach for India
India is participating in various committees of international standard
making bodies such as ISO, UN-ECE. These committees are developing
global standards for Hydrogen which could be adapted in the future by India.
In Parallel, the BIS committee on hydrogen standards is developing Indian
standards by adapting the international standards with modifications for India
specific conditions.
111
6.14 Conclusions:
A major challenge to the commercialization of Hydrogen technologies
is the need for appropriate codes and standards to ensure consistency and
facilitate deployment. Having codes and standards in place can also help
dramatically speed the transitions from laboratory developments to
marketplace. Uniform standards are needed because manufacturers cannot
cost-effectively manufacture multiple products that would be required to meet
different and inconsistent standards. ISO and IEC standards once finalized
will help in dealing with Hydrogen vehicles in particular and help in progress of
Hydrogen economy in a smoother way.
112
113
HUMAN RESOURCE DEVELOPMENT
114
115
7.0 Human Resource Development
7.1 Introduction
Hydrogen has emerged as a potential future fuel. The physical
properties of Hydrogen gas are as follows: it is colorless, odorless, tasteless
and flammable gas. It has highest energy density among known fuels (120.7
kilojoules/gram). However, its energy content per unit volume is rather low.
On combustion, Hydrogen produces water as only a by-product. Thus, it is an
efficient energy carrier, clean and environmentally benign fuel. A large
number of countries are now implementing roadmaps for the advancement of
fuel cell and Hydrogen technologies.
Thus Hydrogen economy has a great potential for creating
employment. Moreover, its environmental benefits are also gives it an upper
hand in considering it as future fuel. For implementing Hydrogen production
technologies and its use in fuel cells for electricity generation would require a
dedicated human resource. Human resource having expertise in various
domains of Hydrogen production technologies and fuel cells application would
be required. Policies and measures are needed to minimize the production
cost of such technologies. Moreover, safety issues need a serious
consideration so that Hydrogen economy booms in real way. It is essential to
change the misconception of Hydrogen energy and fuel cell technologies
being not commercially viable and markets do not readily accept them.
Market transformation approach is needed which changes the types of
products or services that are offered in the market. A market transformation
approach can promote replicable, ongoing technology transfers rather than
one-time transfers. For such an approach to be effective, the role of
government policies is important. With appropriate policy measures it is
possible to end the reign of the traditional technologies and give way to that of
a new and alternative technology. Some of the important public policy
measures to help market transformation are technology adaptation, enterprise
technological capability, incentive measures, command and control measures,
consumer education, and marketing. In addition to these holistic policy
116
measures, successful deployments require some targeted technology/end-
use specific policy prescriptions.
7.2 International status and practices
A reduction of 80% of CO2 emissions by 2050 was apparition by EU2020
strategy. Implementation of a low carbon and inclusive economy could be
realized by Hydrogen and fuel cell technologies. The increase in renewable
energy generation by European Union has mooted the use of Hydrogen as a
clean energy carrier. Combined with fuel cell technology, Hydrogen could be a
relevant alternative to all energy sectors, transportation, buildings, utilities and
industry. However, this paradigm shift will not be purely driven by the market.
A strong and determined commitment of public institutions and the private
sector are working together to support the European political ambition [3].
The period 2014-2020 is considered as critical to necessitate investments to
realize the EU 2020 vision. In terms of Hydrogen and fuel cell technologies,
significant investments are done targeting four sectors:
(a) Building up of Hydrogen refueling infrastructure for transportation
sector,
(b) Integration of renewable intermittent power sources (wind and solar)
and Hydrogen production technologies with electrical grid,
(c) Popularizing stationary fuel cell applications, with large demonstration
projects in several European cities,
(d) Identification of early markets (material handling vehicles, back-up power
systems) to allow for volume developments and decrease of system-costs.
Public private cooperation and European alignment are of critical
importance when approaching these huge challenges. As such fuel cell and
Hydrogen technology is key in the European energy policy (e.g. enabling the
storage and uptake of renewable intermittent energies) and in the European
sustainable transport policy (e.g. providing clean transport).
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Another major contributor in realizing ecofriendly Hydrogen economy is
China. It has developed its human resources towards Hydrogen economy in
every sector. From transportation sector to portable fuel cell application, it has
gain expertise in cheap production of fuel cell technologies. With heavy
investment in renewable energy sector, China has set a target of 100 GW by
2040. Integration of solar and wind energy with Hydrogen production (via
electrolysis) and conversion of it to electricity via fuel cell has gain importance
in the energy policy. The majority of fuel cell and Hydrogen related research in
China is done using government funding made available through two main
programmes: the 863 National High Technology Research and Development
Program and the 973 National Basic Research Program.
Japan has a dedicate infrastructure for Hydrogen usage in
transportation sector under its Hydrogen highway vision. It’s a network of
Hydrogen filling stations placed along roadsides that provide fuel
for Hydrogen fuel cell vehicles (HFCV). Twelve stations are already in service
and the JHFC plans to reach 100 fueling stations by 2015. Development of
PEFC Technologies for Commercialization Promotion has been target by
2015. As far as human recourse development for Hydrogen production, it has
developed a dedicated workforce working on integrating wind energy with
Hydrogen production.
7.3 National status and practices
At present, Hydrogen production in our country is majorly dependent on the
steam reforming process. It uses hydrocarbon such as naphtha and natural
gas for large scale production of Hydrogen in fertilizer industry. Following are
the various other methods of Hydrogen production are at lab scale technology
demonstration level:
Biomass gasification
Dissociation of methanol and ammonia
Thermo chemical and electrochemical water splitting
Hydrogen production through biological routes such as dark
fermentation, photo fermentation etc.
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India needs policies that would encourage research and
commercialization of Hydrogen production process. Hydrogen production
through renewable resources could be considered as ensuring step towards
energy security. As India’s energy resource is mostly coal, Government also
funded research on Hydrogen production technologies using coal. Even non
thermal plasma was explored for Hydrogen production.
Main reason of lag in implementation of Hydrogen economy could be
the gap between the emergence of Hydrogen production technologies and
usage of this Hydrogen in efficient way by fuel cells. Fuel cell research has
gained momentum in recent years. In India, the Department of Science and
Technology (DST) has established a center of excellence in fuel cells under
the name “Center for Fuel Cell Research” in Chennai. This center is validating
use of PEM fuel cells for industrial use. National chemical Laboratory (NCL),
the Central Glass and Ceramic Research Institute (CGCRI) are actively
involved in development of variety of fuel cells. Bharat Heavy Electrical
Limited (BHEL) is also involved in Solid Oxide Fuel Cells (SOFC).
7.4 Action Plan
Figure 7.1 Strategies targeting human resource development for
Hydrogen and fuel cells
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Hydrogen and fuel cells are considered in many countries as an
important alternative energy vector and a key technology for future
sustainable energy systems in the stationary power, transportation, industrial
and residential sectors. The realization of Hydrogen based economy can
generate a lot of employment throughout the country. Hydrogen production
process and Fuel cell technology requires expertise from various fields such
as electrical, mechanical, chemistry, physics, biotechnology, management
etc. As shown in Fig. 7.1, a center for excellence is needed for each of the
sector associate with HYDROGEN and FCs production. Employment would
increase with penetration of these technologies in transportation sector and
energy sector. This gives an added boon to the society in terms of decreasing
in carbon footprint. However, as with any major changes in the energy
industry, the transition to a Hydrogen economy will require several decades.
The timescale and evolution of such a transition is shown in Fig. 7.2.
Fig. 7.2 Suggested Road map for India to pursue Hydrogen economy.
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The introduction of Hydrogen as an energy carrier has also been
identified as a possible strategy for moving the India towards its voluntarily
adopted targets for a CO2 reduction of 60% from current levels by 2050
(Department of Trade and Industry, 2003).
7.5 Suggestions
An attractive feature of Hydrogen is that it can also be used as storage
medium for electricity generated from intermittent, renewable resources such
as solar, wind, wave and tidal power. It thereby provides a solution to one of
the major issues of sustainable energy, namely the vexing problem of
intermittency of supply. As long as Hydrogen is produced from non-fossil-fuel
feed stock, it is a genuinely sustainable or renewable fuel.
The efficient utilization of renewable energy in transport sector could be
realized via Hydrogen. This provides potentially large economic and energy
security advantages. Infrastructure development for HYDROGEN distribution
holds the key for popularizing Hydrogen economy. It is this key element of the
energy storage capacity of Hydrogen that provides the potent link between
sustainable energy technologies and a sustainable energy economy. The key
scientific and technical challenges facing fuel cells are cost reduction and
increased durability of materials and components.
7.6 Hydrogen Faculty Chair, Scholarships and Awards
i) It is recommended to constitute Hydrogen chair faculty positions in
IITs, NITs or other reputed educational institutes for professors working
on Hydrogen technologies for fixed duration of 3 years.
ii) Further 50 fellowships should be given to bright scholars for pursuing
their masters or doctoral programs related to Hydrogen technologies.
iii) Awards should be constituted on a national scale with prizes around 1
lakh for professionals and academia working in promotion of Hydrogen.
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7.7 HR Requirements for Hydrogen Economy
The growing concern of global warming and green house emission can
be addressed by implementation of Hydrogen economy. The development of
commercially viable technologies related to Hydrogen production, Hydrogen
storage and fuel cells that would certainly help in reducing dependence on
fossil fuels. This would help India to secure its energy supply. The evaluation
of the feasibility of Hydrogen energy economy would involve many
considerations that will have to be taken care in near future such as
development of cost effective technology by R&D and popularization of
Hydrogen economy in society for its acceptance as future fuel. Together,
Hydrogen and fuel cells have the capability of producing a revolution in
transportation sector by minimizing CO2 emissions completely. The
challenges of implementing use of such fuel are substantial and require
scientific breakthroughs and significant technological developments. Social
and political commitment also required to promote such carbon neutral fuel.
India is taking small and steady approach towards its Hydrogen roadmap and
with infrastructure development and industrial growth it can definitely realize
the path of Aksay Urja i.e renewable energy.
The updated hydrogen energy road map for the country presented in
the previous sections of this document envisages several programs with
short term , medium term and long term objectives in several aspects of
hydrogen technologies such as production , storage , power generation for
stationary & transport applications , standards & codes and safety . There
have been some demonstration of hydrogen and fuel cell technologies in the
country and a large volume of papers have been published covering aspects
of materials research, modeling etc., the high cost of the system components,
performance and durability improvements, limitation sin domestic
manufacturing are the key challenges to be addressed. Carrying out
crosscutting R&D, including basic and applied research on materials and
processes to achieve breakthrough transformations and manufacturing R&D
to lower component fabrication and stack assembly costs for both stationary
and mobile applications is essential. Similarly hydrogen generation systems
development, improvement in efficiency and reduction in cost is required.
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Hydrogen fuel cell technologies have the potential to provide significant
employment, economic, and environmental benefits on a national scale. It is
expected that Indian industries would soon participate in the hydrogen
technology development and commercialization which will open up
employment opportunities both in manufacturing of fuel cell systems as well
as their maintenance and also in hydrogen production and delivery
businesses. Many of these jobs require engineering and science backgrounds
related to product and technology development [Chemical engineers,
Electrical engineers, Mechanical engineers, Design Engineers, Application
developers , Product engineers, Materials scientists, Chemists , Laboratory
technicians, Machinists, Power plant and Hydrogen production plant operators
& maintenance staff , Bus, truck and other fleet drivers & maintenance team
of workers.
Adaptation of the hydrogen technologies can proceed effectively only when all
sections of public accept the same. To make it acceptable to general public,
training the decision makers and educating the next generation of students is
an important prerequisite for the long-term success of hydrogen energy
technologies. For this, it is necessary to create a well-trained human resource
base for the future. Educational programmes along with demonstration
programs will help to achieve high levels of penetration of these technologies.
Such programs should include, a hydrogen education program for school
teachers and students providing them with educational mataerils, training
program and curricula evaluation.
The European Union (EU) has emerged as a global leader in
developing and demonstrating hydrogen and fuel cell technologies. The
European Strategic Energy Technology Plan 17) (SET Plan) identifies fuel
cells as one of several key technologies needed to meet EU’s 20-20-20 goal
(20% share of in renewables, 20% reduction in emissions and 20% increase
in efficiency by 2020). The EU has funded hydrogen and fuel cell RD&D since
1986 through its Framework Programme structure.
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There are international co-operation in the Multilateral Technology
Initiatives (also known as Implementing Agreements) of the International
Energy Agency. Two initiatives are directly focusing on hydrogen and fuel cell
development: the IEA Advanced Fuel Cells Implementing Agreement and the
IEA Hydrogen Implementing Agreement. Several member governments of
the IPHE (International Partnership for Hydrogen and Fuel cells in the
Economy) have developed educational materials intended for a variety of
audiences. India being a member of IPHE could leverage these development
for implementing similar programs in India. For example, a project under
consideration by EPSRC in UK envisages a training program (Centre for
Doctoral Training (CDT)) for nearly 52 students ( in 9 years) who will pursue
Ph.D programs and be ready for engagement in hydrogen and fuel cell
industries. The project has an outlay of £ 4416324/-. Several universities are
partners in this project. The Centre programme consists of seven compulsory
taught modules worth 70 credit points, covering the four basic introduction
modules to Fuel Cell and Hydrogen technologies and one on Safety issues,
plus two business-oriented modules which were designed according to
suggestions from industry partners. Further - optional - modules worth 50
credits cover the more specialized aspects of Fuel Cell and fuel processing
technologies, but also include socio-economic topics and further modules on
business skills that are invaluable in preparing students for their careers in
industry. The programme covers several topics out of which the individual
students will select their area of specialization. the topics include
electrochemistry, modelling, catalysis; materials and components for low
temperature fuel cells (PEFC, 80 and 120 -130 C), and for high temperature
fuel cells (SOFC) operating at 500 to 800 C; design, components, optimization
and control for low and high temperature fuel cell systems; including direct
use of hydrocarbons in fuel cells, fuel processing and handling of fuel
impurities; integration of hydrogen systems including hybrid fuel-cell-battery
and gas turbine systems; optimization, control design and modelling;
integration of renewable energies into energy systems using hydrogen as an
enabling vector; hydrogen production from fossil fuels and carbon-neutral
feedstock, biological processes, and by photochemistry; hydrogen storage,
and purification; development of low and high temperature electrolysers;
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analysis of degradation phenomena at various scales (nano-scale in
functional layers up to systems level), including the development of
accelerated testing procedures; socio-economic and cross-cutting issues:
public health, public acceptance, economics, market introduction; system
studies on the benefits of FCH technologies to national and international
energy supply.
In Iceland a Master’s degree in fuel cell systems and hydrogen is
available. In South Africa, under HySA, three centres of competence and a
fuel cell education and training center have been opened. In Germany, under
the National Innovation Program ( NIP) which has a budget outlay of 1.4
billion Euros , 200Million Euros is earmarked for R&D ( 2007-16) which also
includes preparing fuel cell markets, everyday demonstration . Additional
basic-research-oriented funding is provided by BMBF in addition to the NIP
budget. The R&D results provide the basis for demonstration projects, and
experience from demonstration provides input to the direction of R&D. This
allows for effective linking of the two pillars of the NIP: R&D and
demonstration.
In France, one of the drivers for support of hydrogen technology
development is jobs and economic growth. The government is currently
developing a long-term action plan which will drive funding for future
demonstration projects. French National Research Academy (ANR) and the
French Environment and Energy Management Agency (ADEME) are
performing analysis to guide strategy. In Italy, supported by the Ministry of
Education, University &Research and Ministry of Environment through special
Integrative Fund for Research (FISR) , is supported 14 projects with a project
outlay of Euro 90 Million. In addition Ministry of Economic Development has
launched the “Industria 2015” program aimed at assisting Industrial
Innovation projects in different thematic areas. In Russia, with a government
funding of 1 billion rubles several hydrogen technology programs covering all
aspects of hydrogen technology are being pursued. Japan under the NREDO
and the METI programs has several hydrogen technology development and
demonstration
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In S Korea with a $7 M/year budget the hydrogen technology initiative
includes several R&D programs and concurrent research personnel
development as is the case in Australia and New Zealand. Brazil’s investment
of US$28.7 Million includes projects in five areas: Hydrogen production
(focused on biofuels reforming), PEM fuel cells, SOFC fuel cells, Systems,
integration and engineering, Utilization, applications and use.
In a study instituted by EU, the need for a new educational profile
related to hydrogen and fuel cell technologies has been identified as a crucial
element to ensure that professionals involved at various level of research,
development and installation of these technologies receive an adequate
training. Based on these findings, a EU funded project
“HYPROFESSIONALS” (Development of educational programmers and
training initiatives related to hydrogen technologies and fuel cells in Europe
)has been initiated to fill the need for certificate and degree programmers in
hydrogen fuel cell technology. This project is expected to ensure that
hydrogen fuel cell technology achieves its potential through adequate training
and education of technical personnel, research institutes, businesses,
governments and the public. A number of online courses and individual
educational modules targeted at various educational levels have been
developed.
In USA almost all the states have hydrogen research programs as also
in many states in Canada. The European Union (EU) has emerged as a
global leader in developing and demonstrating hydrogen and fuel cell
technologies. The European Strategic Energy Technology Plan 17) (SET
Plan) identifies fuel cells as one of several key technologies needed to meet
EU’s 20-20-20 goal (20% share of in renewables, 20% reduction in emissions
and 20% increase in efficiency by 2020). The EU has funded hydrogen and
fuel cell RD&D since 1986 through its Framework Programme structure.
International Centre for Hydrogen Energy Technologies ( ICHET), a
project of the United Nations Industrial Development Organization founded in
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Istanbul in 2004 and supported by the Turkish Ministry of Energy and Natural
Resources is engaged in providing hydrogen solution to for sustainable
development in many islands . Realizing the importance of the human
resource development and requirement in taking forward the hydrogen
technologies, several ERASMUS interns and part-time employees are
undergoing training in ICHET laboratories and contributing to the
dissemination of hydrogen energy knowledge in the events organized or
attended by the Centre. ICHET offers regular short training courses based
around aspects of various hydrogen energy technologies Hydrogen and Fuel
cell initiatives in Pakistan and Iran have also project development of human
resources as one of the objectives.
7.8 Investment in Human Capital
Education institutions and Government laboratories are important
players in generating and diffusing knowledge. While universities generally
account for the majority of scientific publications, government laboratories
focus on applied research and play a crucial role in bring out the technologies.
A previous initiative of MNRE to estimate the future human resources needs
in the renewable energy sector and evolve suitable HRD strategies for
meeting them can be replicated specifically for the hydrogen technology
implementation. The generic skill gaps such as Planning & co-ordination
skills in project management, grid integration of large scale RE projects,
installation and commissioning skills and techno commercial marketing skills
needs to be addressed besides the scientific / engineering manpower
requirements.
Programs similar to the one enumerated in the previous section need
to be initiated in the country which could capitalize on the vast investment the
various funding agencies have already made in several IITs ,IISc ,
Universities, National laboratories and other institutions engaged in hydrogen
related technologies. Focused programmes and pilot training sessions will
pave the way for more widespread expansion of suitable educational
opportunities in the country. Further, Industry inputs will help in identifying and
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filling the gaps in the educational and training needs. Vocational training for
ITI / Polytechnic students – ITI’s and Polytechnics in consultation with Industry
should develop focused 3 months / 6 months vocational courses, which make
the students employable by the industry.
The following mission mode programs may be considered as short
term objectives which involve demonstration with a minimum of 25 %
indigenous components. A medium term objective would involve ~50%
indigenous components.
To execute these projects itself , there is a huge man power
requirement comprising of materials scientists (4 nos. in each project),
Chemical Engineers (6 nos. in each project), Mechanical Engineers (6 nos. in
each project ), Electrical and electronics Engineers (6 nos. in each project),
Modeling Engineers (2 Nos in each project), Technical assistants ( 12 in each
project). The man power budget cost would be approximately 22% of the total
project cost.
Besides these mission mode projects there are several sub projects on
materials development, component development, BoP development, system
integration, safety etc., Each of these activities would require a large number
of Technical staff ( A or B level) , Scientists/Engineers at “C “ and “D” level
besides project Managers at least at Scientists “E “ or “F” level. A minimum
of one in each of the category will be required in each of the projects that will
come up. Besides these there will requirements of research scholars in many
of the academic institutions in place of scientists and engineers.
The universities, Institutes and R&D institutions engaged in developing
various hydrogen technologies would require research scholars. A Hydrogen
Technology Scholarship may be instituted and 100 such fellowships may be
awarded every year on a competitive basis. The training programs at school
level would requires a budget of Rs. 25 crore.
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Following strategies are important for development of skilled
manpower:
1. India’s skill development initiatives of skilling approximately 500 million
people will not only benefit India but also make India the ‘global manpower
hub’.
2. Innovative E-learning Platforms have been gaining more popularity in
recent times. They offer a greater mobile and flexible learning environment.
Students can learn and attend classes and participate in discussion forums
online, at their convenience, from their offices, homes and so on.
3. The skills challenge becomes acute for India considering that the country
has a large portion of its population below 25 years of age. This young
population can be transformed into a productive workforce giving the Indian
Economy a ‘Demographic Dividend’.
4. The diplomas and certificates with which students graduate need to be in
sync with the needs of the industry. As a result, industry will recruit adequately
skilled labour and is forced to undertake large training programs.
5. Building skills training as a mainstream and inclusive program to be
promoted by creating a formal arrangement among the three key stakeholders
in the delivery pyramid: Government, Industry and Skills providers.
6. Private sector could work in greater coordination and come together to
develop skill development programmes and by channelizing funds allocated
for corporate social responsibility into funding and supporting the skills
development initiatives by the government.
7. International collaborations could help capture the learning’s of the sector
and also creating PPP models that are around the implementation of skills
programs.
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AWARENESS ABOUT HYDROGEN &
FUEL CELLS
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8.0 Awareness of Hydrogen & Fuel Cells
8.1 Introduction
Public acceptance of fuel cell and Hydrogen technologies is an
important aspect since awareness for some safety issues still remaining
significant. Global macro benefits remain not widely quantified and known:
key features on fuel cells and Hydrogen specific advantages are not well
displayed in an easy to access format, as for instance introductions to
technology uses and supporting demonstrators, apart from cars, are not
sufficiently available. This explains that the public seems to be relatively
indifferent to developments regardless of the opportunities offered by these
technologies. In so far the problem lies not so much with performing
research into whether the public would accept widespread employment of
Hydrogen and fuel cell technologies, but to make the public, including all
stakeholders, increasingly aware of the potential of these technologies in
order to prepare a commercial market entry, through a widely accepted
vision of its macro benefits, concrete facts and figures on Hydrogen and on
safety and reliability issues, and clever and simple demonstration items and
exhibits easy to display and use for a general public audience (for instance
fuel cell assisted electric bicycles, mobile charging devices for personal
computers and phones, invertors etc.).
8.2 Safety Issues and Awareness
Only a small number of Hydrogen and fuel cell systems and
components required for the Hydrogen economy are in operation today.
Consequently, only limited data is available on the operational and safety
aspects of these new technologies and research is required to understand
Hydrogen’s behaviour as a fuel for both vehicles and stationary applications,
and to support the development of technologies for the detection and safe
management of unscheduled Hydrogen releases or incidents involving
Hydrogen systems. The relevant properties of Hydrogen differ considerably
from conventional fuels and the derivation of rules for its safe usage is not
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straightforward but relies on careful interpretation of the interacting effects.
Therefore, it is necessary to build trust by demonstrating safety not only in the
large demonstration projects but also by the way in which this vital topic is
addressed. Understanding Hydrogen and Hydrogen system safety needs is
critical for local government officials, fire officers, and the general public.
Emergency personnel must be informed of the special properties of Hydrogen
and trained in the methods used to respond to accidents involving its use.
Public perception and confidence in Hydrogen relies on credibility,
transparency and individual benefit. Improving the understanding of
Hydrogen’s physical properties will help to communicate safety on a technical
and objective basis.
8.3 Public acceptance issues
The use of Hydrogen as an energy carrier is relatively new and, as
such, may be vulnerable to inaccurate public perception. It is important to
address public perception concerns when introducing Hydrogen technologies
into society. Addressing these issues in an inappropriate way can lead to
opposition to the technology and potentially costly delays and enforced
changes to proposed initiatives. Consumers must be aware and ready to
embrace Hydrogen and fuel cell technologies before their benefits can be
realized. This is especially true for transport, stationary residential and
portable applications, where consumers will interact directly with these
technologies in everyday life, and with an element, Hydrogen, about which
they generally know and understand little. Commercialization will not develop
until public awareness is there and it has been demonstrated to the wider
public that the safety risks associated with Hydrogen can be reliably managed
and that Hydrogen can bring many other economic and environmental
advantages.
8.4 Awareness and education
The results outlined from the research projects show that the most
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important factor for fostering support and decreasing opposition to the
introduction of Hydrogen technologies is increased knowledge. The general
public must be given further education, along with decision-makers within
government and industry, regulators and policy developers, academics etc.
Therefore, information as well as an active demonstration projects for use of
Hydrogen is necessary. Results from previous projects have shown that more
extensive information efforts are needed in conjunction with demonstration
projects, such as Hydrogen bus trials, fork lifts, stationary power etc. In order
to maximise the acceptability of Hydrogen technologies. Several such projects
are ongoing across the world.
8.5 The following primary target groups need to focussed for
promoting awareness towards Hydrogen and fuel cell:
School children of all ages should be exposed to alternative energy
technologies and Hydrogen and fuel cell as part of the energy
education in the national curriculum.
College and University Students are very important targets for
alternative energy technology education. Not only are they in a very
conducive environment for learning, with access to considerable
facilities, educational budgets and teaching staff, but they are the next
generation to enter the workforce.
The General Public obviously constitutes a large proportion of
energy users. Energy education has typically been fairly scarce in the
past, and most people just do not realize that there are alternatives to
centralized energy infrastructures and traditional energy technologies
such as combustion engines, boilers and the national grid.
Traditional Energy Industry personnel, companies and
organizations are an extremely important part of the equation.
Contrary to popular opinion, the development of the fuel cell and
Hydrogen industry is not necessarily in conflict with the traditional
energy industry. Rather, the development of the fuel cell industries
has been largely funded and driven by existing energy companies.
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However, there is a gap that needs to be bridged and expedite pace
of implementation of fuel cells.
Governments around the world are very important part to fuel cell &
Hydrogen technology awareness and commercialization efforts.
Government support is essential to implement the necessary
legislation, regulation, codes & standards and financial incentives
framework for a successful and speedy transition to a more
sustainable energy paradigm. The benefits to government of mass
adoption of fuel cell & Hydrogen technologies are vast and wide-
reaching. Government aided demonstration projects can also help in
promoting public awareness in the area.
Fuel Cell & Hydrogen Industries are themselves very important
consumers of fuel cell & Hydrogen technologies. Creating demand for
particular products, technologies and energy solutions on an
individual basis serves to create demand for the technologies as a
whole. Creating demand for particular products and technologies
within the industry itself is a vital aspect of Fuel Cell Markets’
activities and in turn for public awareness also.
8.6 Public Awareness
The following are some of the methods for increasing public awareness,
education and acceptance in the area of Hydrogen and fuel cells:
• Webinars, Newsletters, and Online Media
Today's world is built on the Internet. From Smart Phones and tablets to
video conferencing, the boundaries of today’s workplace are fluid and
multi-dimensional. Webinars provided in place of traditional in-person
meetings can significantly increase audience participation. Newsletters
and news alerts sent electronically not only decrease production costs, but
increase market reach.
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• Educational Materials and Information Resources
Resources include traditional print materials, such as fact sheets, and
information available on the Web, and via other forms of media including
audio, CD, and video. Careful attention must be given to cost and to
traditional forms of media/information delivery to which target audiences
are accustomed. The primary distribution mechanism for education and
outreach materials will be the Program Website, via Web pages,
databases, electronic documents, and other interactive tools and
resources. Dedicated training on safety, awareness and usage of fuel cell
can also be considered to be deployed at selected fuel stations as being
done under Japan Hydrogen and Fuel Cell (JHFC) project.
• Third-party Case Studies, Market Reports, and Project Tools
Third-party commissioned studies provide additional tools to project
developers and industry for formulating business cases to utilize Hydrogen
and fuel cells to increase energy efficiency, reduce environmental impact,
and improve reliability and productivity. Products include industry market
reports, compendia of state activities, specific deployment case studies,
and financial tools to estimate economic impacts.
Partnerships and Collaboration
Leveraging public-private partnerships is also critical for awareness and
acceptability for Hydrogen and fuel cells.
8.7 Accept HYDROGEN project
Using survey-based methods for data collection, the
AcceptHYDROGEN project aimed to contribute significantly to a better
understanding of the public acceptability of Hydrogen technologies, and
hence enable the introduction of Hydrogen vehicles to be carried out with a
clear strategy towards public acceptance. AcceptHYDROGEN, an EU-funded
project, is a cross-continental comparative assessment of public knowledge,
acceptability and willingness to pay (WTP) for the environmental benefits
associated with Hydrogen buses. The survey determined the preference for
Hydrogen-fuelled buses, in five cities: London (UK), Luxembourg (under the
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EU-funded CUTE project), Berlin (Germany), under the framework of the
Clean Energy Partnership (CEP)-Berlin project, Oakland (US) and Perth, the
latter under the (STEP) ‘Sustainable transport energy for Perth’ project
(Western Australia).
By comparing public awareness, acceptability and preference
associated with Hydrogen transport before and after the introduction of
demonstration Hydrogen buses in different cities across the world, the project
aims to:
• Investigate the factors that determine the effectiveness of Hydrogen bus
demonstration Projects in shaping public knowledge, perceptions, values
and use
• Use the findings from the above investigation to develop recommendations
for maximising the positive influence and uptake of future demonstration
and commercial projects.
As market demand for Hydrogen and fuel cell technologies increases
across sectors of our economy, there will be an increasing need for trained
and experienced personnel and accompanying services such as qualified
maintenance technicians, installers, manufacturing professionals, trainers,
insurers, and educators, as examples.
8.8 Conclusions
In summary, public awareness and then transition to a Hydrogen
economy and the deployment of zero-emission, Hydrogen fuel cell state-wide
will increase transportation efficiency, improve environmental performance,
increase economic development, and create new jobs. The technical and
financial arrangements needed for such a transition from conventional
vehicles will require initial investment by the state and federal government and
private industry; however, such investment is well justified and will become a
necessity as concerns about public health and climate change increase and
the supply of conventional fuels becomes more limited.
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PUBLIC – PRIVATE PARTNERSHIP
FOR HYDROGEN ENERGY AND
FUEL CELLS
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9.0 Public – Private Partnership
9.1 The public-private partnership focused on advancing Hydrogen
infrastructure to support more transportation energy options for consumers,
including Hydrogen and fuel cell electric vehicles (FCEVs) is the need of the
hour. New partnerships brings together automakers, government agencies,
gas suppliers, and the Hydrogen and fuel cell industries to coordinate
research and identify cost-effective solutions to deploy infrastructure that can
deliver affordable, clean Hydrogen fuel for vehicles. Hydrogen and Fuel cell
technologies are an important part of approach to diversify transportation
sector, reduce the dependence on foreign oil and increase competitiveness in
the global market. By bringing together key stakeholders from across the fuel
cell and Hydrogen industry, the partnership will help advance affordable fuel
cell electric vehicles that save consumers money and give drivers more
options. Partnerships bring experts together to identify and solve key
infrastructure challenges, including leveraging low cost gas resources.
Through public-private partnership industry and government partners
can focus on identifying actions to encourage early adopters of fuel cell
electric vehicles, conduct coordinated technical and market analysis, and
evaluate alternative fueling infrastructure that can enable cost reductions and
economies of scale. For example, infrastructure being developed for
alternative fuels such as natural gas, as well as fuel cell applications including
tri-generation that produce heat, power and Hydrogen from natural gas or
biogas, may also provide low cost Hydrogen for vehicles. In addition,
increased fuel cell deployment for combined heat and power, back-up power
systems and fuel cell forklifts can help pave the way for mainstream Hydrogen
vehicle infrastructure.
Example of such a partnership is in the USA. Current members of the
HYDROGENUSA partnership include the American Gas Association,
Association of Global Automakers, the California Fuel Cell Partnership, the
Electric Drive Transportation Association, the Fuel Cell and Hydrogen Energy
Association, Hyundai Motor America, ITM Power, Massachusetts Hydrogen
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Coalition, Mercedes-Benz USA, Nissan North America Research and
Development, Proton Onsite, and Toyota Motor North America. With support
from the Energy Department, private industry and the Department’s national
laboratories have already achieved significant advances in fuel cell and
Hydrogen technologies – reducing costs and improving performance. These
research and development efforts have helped reduce automotive fuel cell
costs by more than 35 percent since 2008 and by more than 80 percent since
2002.
9.2 Public Private Partnerships are useful for:
– Communication of Issues and Concerns
– Best Practices
– Standard formulation efforts & results
– Progress in Code development
– Training & Education: Material & methodology
– Public outreach programmes
– Fuelling & fleet operations
– Standard making, ISO, WP 29, Harmonization
– Code and best practices
– Development of Testing methodology & centres
– Accident investigation & analysis
– In use vehicle monitoring
– R & D
• High temperature behaviour
• Two & Three wheelers
– Pilot programmes
– Training & Development
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9.3 CASE STUDIES FOR PUBLIC-PRIVATE PARTNERSHIP IN INDIA
Hydrogen Fuel Cell for Telecom Towers in India
For emerging economies like India, Hydrogen based fuel cell systems
provide an opportunity to both reduce operating costs and increase
environmental performance relative to what is possible with traditional diesel
generators. Intelligent Energy UK’s first deployed fuel cell system went into
service in July 2011 in Haryana (Figure 9.1). The site is a 3.5 hour drive by
road from Delhi. Prior to installation, the diesel generator used 438L of diesel
a month, resulting in 1170 kg of CO2 emission. On average, 42.2 kg of
Hydrogen is used a month, resulting in operational savings of 15%. Figure
below shows the telecom towers operated by fuel cells.
Figure 9.1 Fuel Cell Mobile Towers
The latest generation of Hydrogen fuel cell power unit, developed by
Intelligent Energy in the UK, has been successfully operated at a mobile
telecom tower site in India. This milestone event represents the first phase of
a commercial roll out of fuel cell units which will, over time, power a portfolio
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of telecom towers where Intelligent Energy’s subsidiary, Essential Energy
India, is providing power management services. Essential Energy currently
has more than 10,000 towers under contract since it began acquiring
customers in 2014, representing a 100MW installed power estate and
equivalent to annualized revenues of circa $75.8m (£50m). The wholly owned
operating business of Intelligent Energy expects to target, in the medium term,
a market share of the Indian telecom tower segment which translates to a
revenue opportunity of circa $1bn (£650m) per annum.
The fuel cell unit was installed at a telecom tower, owned and operated
by Ascend Telecom, in Uttar Pradesh West, a challenge due to its remote
location and regular grid power outages. The Indian telecom infrastructure
owner and service provider already uses Essential Energy’s energy
management services at a number of sites currently powered by diesel
generators and batteries when the power grid is down. Following this phase,
over time Essential Energy expects a majority of telecom tower sites within its
estate to be capable of the transition from traditional power supplies to
Hydrogen fuel cell based solutions. Despite recent halving of wholesale oil
prices, Hydrogen fuel cell installations across a majority of telecom tower sites
will still offer a more economical power supply than traditional diesel
generators, representing a significant potential cost saving for customers.
Data taken from telecom sites 1 reveals that over a six month period to
December 2014, Essential Energy has improved site power availability
significantly while reducing fuel usage by 18%. Consistent power supply is
crucial to a country whose mobile phone users are more than 935 million and
where telecom towers are currently numbered more than 400,000 and are
estimated to increase significantly over the coming years.
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9.4 Hydrogen Association of India
The Hydrogen Association of India (HAI) is a society dedicated to
promotion of Hydrogen in India and is based on PPP mode. The members
are from government institutes as well as private industries. The registered
office of the Association is at Indian Oil Corporation Ltd, R&D Centre,
Sector-13, Faridabad – 121 007, India. The aims and objectives of the
Association are to conduct scientific activities which shall include interalia
the following:
i) To promote, encourage and develop the growth of Hydrogen
Energy and its applications in the country.
ii) To establish an active association of all those persons, bodies,
institutions (private or public) and industries interested in (1) above.
iii) To disseminate information concerning the developments in
Hydrogen Energy and its applications through publications, such as
bulletins, reports, newsletters, journals, etc.
iv) To organize courses, symposia, seminars, etc. in various parts of
the country, to educate the users of Hydrogen Energy and offer a
proper platform for reporting and discussing the new developments
in various fields of Hydrogen Energy.
v) To render advice (technical or otherwise) to government and
commercial bodies on matters pertaining to Hydrogen Energy and
its applications, when needed or requested.
vi) To undertake and execute all other acts which shall promote the
aims and objectives of the Association, and it is, hereby declared
that in the interpretation of this clause, the meaning of any of the
Association’s objectives shall not be constrained except when
otherwise expressed in such paragraph or by the juxta position of
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two or more objectives and that in the event of any ambiguity, the
clause shall be constructed in such a way so as to widen, and not
restrict the powers of the Association.
The formation of Hydrogen Association of India, is expected to provide
further impetus to the Hydrogen research activities in the country. Hydrogen
Association of India provides a common platform for sharing experiences
regarding the latest technological trends in generation, usage and safety
issues related to application of Hydrogen as automotive fuel & other
purposes, with national and overseas experts. Hydrogen Association of India
shall provide an excellent networking opportunities for one & all who want to
contribute for the cause of Hydrogen Economy for a new world order.
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GAP ANALYSIS – INDIAN VS.
INTERNATIONAL SCENARIO
146
147
10.0 Gap Analysis - Indian vs. International Scenario
10.1 Gaps in Intellectual Property Rights (IPR)
10.1.1 The ratio of granted patents to patent applications for the top ten
countries in terms of applications and give an impression of success of
applications filed. In India the ratio is on the lower side. While there is no
direct relationship between the number of granted patents and patent
applications in a given year, the ratios in most countries on this list had 1.5 to
2.7 times more fuel cell applications than granted patents. Reasons for this
could be manifold, such as applications filed to block others from taking
advantage of a technology or simply a greater amount of research producing
results which are worthy of a patent application.
10.1.2 Awareness of importance IP rights is rather low in the Indian academic
and research community. Financial burdens also cause lower Patent
applications in developing countries.
10.1.3 New patents for Hydrogen fuel cells need to filed in India by research
for
Mmanufacturability at volume and cost effectively e.g. reducing
components, alternative and cheaper materials, manufacturing process
driven improvements
Durability- a key to commercialization. Patents on materials and
controls to manage and improve durability
Performance- things like power density improvements, materials,
consistency
Infrastructure and Fuelling- automotive fuelling related innovation like
storage tanks, interfaces, measuring and quality devices, portable
storage devices for non-auto applications
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10.2 Gaps in Storage of Hydrogen
10.2.1 Bulk Hydrogen suppliers face the road block in the development of
infrastructure to support Hydrogen vehicle fuelling. The challenge is the
shipping of the samples with small quantities of Hydrogen, which needs to be
analysed for verifying Hydrogen quality at fuelling stations. Existing shipping
procedures are recognized as difficult to implement. The quantities allowed to
be shipped are small (typically 1 litre, at 350 bar or less). Industry should be
able to ship the samples via common carriers. Special permits and CMVR
rules will be required for shipping of Hydrogen canisters to support fuel quality
testing.
10.2.2 At present, Type-IV composite tanks are not approved for the
deployment in passenger cars, for ground storage or for commercial transport
of gases in India. Therefore, it is not possible to use 350 bar and 700 bar
composite storage vessels for Hydrogen fuel at stations without using
pressure reducing valves. There is a need to gain industry consensus on the
suitability of composite storage cylinders for ground storage and commercial
transport. Cylinders are covered by Gas cylinder rules, 2004. PESO approved
packaging is required. Clarification is needed as to whether a sample can be
considered a material of trade. There is a continued need for a small 700 bar
composite cylinder that can be shipped based on ISO 11119 Standard. There
is a need to gain industry consensus on the suitability of composite storage
cylinders for ground storage and commercial transport, as well as clearer
requirements on the pressures as well as Hydrogen fuel quality specifications
10.2.3 Currently, there are regulations at Department of Transport, US for
validating liquid Hydrogen pipelines. It is important to note which requirements
apply to transmission pipelines versus distribution pipelines. Transmission
pipelines transport large quantities of liquid Hydrogen over longer distances.
Distribution lines consist of main lines that move gas to industrial customers,
down to the smaller service lines that connect to businesses and homes
throughout a municipality. Similar systems need to be developed in India.
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10.3 Gaps in Hydrogen Safety
10.3.1 It is to be noted how regulations will be enforced on after-market
repairs and end-of-vehicle life. For example, Hydrogen storage tanks may not
be returned to service without requalification following a crash or at the end of
the tank service life. Vehicle tanks should not be moved between vehicles,
although it cannot really be prevented in practice. State periodic vehicle
inspection is one option, which is recently launched in India in form of
Inspection and Maintenance (I&M) regime. Tanks may have a certain number
of fills before they “expire”. This is also a concern for stationary tanks. Tanks
may be requalified. Some vehicle repair facility issues are best handled by the
states, although the central government may have a role in some cases.
Industry and government in India need to think about repair facilities, repair
personnel, and enforcement, and develop appropriate safeguards and
education.
10.3.2 Odorization of Hydrogen Gas, is critical to detect leaks from safety
point of view. International rules say that a combustible gas in a distribution
line must contain a natural odorant or be odorized, so that at a concentration
in air of one-fifth of the lower explosive limit, the gas is readily detectable by a
person with a normal sense of smell. A natural odorant compatible with
Hydrogen for the use in fuel cells has not been identified and validated, and
equipment & processes to remove odorants at each point of use are not
practical. In addition, the issue of detection must apply to both gaseous and
liquid Hydrogen. Industry must either find a workable odorant or come forward
with alternatives to current odorant requirements that preserve the level of
safety intended by the regulation. For example, the regulation might be
amended to include other methods of leak detection.
10.4 Gaps in Hydrogen Standards
10.4.1 Lack of Codes and Standards has repeatedly been identified as a
major institutional barrier for the deployment of Hydrogen technologies and
development of Hydrogen economy. International Hydrogen Industry has
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come a long way in the past 10 years with identified needed standards for
commercialization of Hydrogen energy systems, and participating with
Standards Development Organizations to develop Hydrogen standards. In
India development of standards to allow the installation of Hydrogen energy
systems, including stationary applications and Hydrogen refuelling stations is
required. These efforts, of course, must continue to meet commercialization
timeframes. Some Hydrogen requirements are based on other fuels, such as
natural gas, or based on industrial quantities and uses for Hydrogen.
10.4.2 Research is needed to complete some of the developing codes and
standards, and to validate requirements for the intended qualities and uses.
Concurrent with continued development of appropriate codes and standards,
it is important to ensure high levels of safety and environmental protection.
India must now review the current state of regulations that pertain to the
transport of hazardous materials and determine whether they are adequate
for the envisioned Hydrogen economy.
10.4.3 Fuelling station codes {similar to the International Code Council (ICC)
or the National Fire Protection Association (NFPA) codes and Canadian
Standards Association (CSA) dispenser standards} should be operative by the
time vehicles are truly commercially available in the marketplace. There are
numerous recommended practices and technical reports being developed by
the Society of Automotive Engineers (SAE). Hydrogen and Fuel Cell
Standards Committee seeks input from Original equipment manufacturers
(OEMs), fuel cell developers and on-board storage system manufacturers.
Most of this material on safety and its technical justification may be of use to
India as regulations are developed.
10.5 Gaps in Human Resource Development
10.5.1 Education institutions and Government laboratories are important
players in generating and diffusing knowledge. While universities generally
account for the majority of scientific publications, government laboratories
focus on applied research and play a crucial role in bring out the technologies.
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The generic skill gaps such as Planning & co-ordination skills in project
management, grid integration of large scale RE projects, installation and
commissioning skills and techno commercial marketing skills needs to be
addressed besides the scientific/ engineering manpower requirements.
10.5.2 Programs similar to USA need to be initiated in the country which
could capitalize on the vast investment the various funding agencies have
already made in several IITs ,IISc , Universities, National laboratories and
other institutions engaged in hydrogen related technologies. Focused
programmes and pilot training sessions will pave the way for more
widespread expansion of suitable educational opportunities in the country.
10.5.3 Further, Industry inputs will help in identifying and filling the gaps in the
educational and training needs. Vocational training for ITI / Polytechnic
students – ITI’s and Polytechnics in consultation with Industry should develop
focused 3 months / 6 months vocational courses, which make the students
employable by the industry.
10.5.4 There are several sub projects on materials developments , component
development , BoP development , system integration , safety etc., Each of
these activities would require a large number of Technical staff ( A or B level) ,
Scientists/Engineers at “C “ and “D” level besides project Managers at least
at Scientists “E “ or “F” level. A minimum of one in each of the category will
be required in each of the projects that will come up. Besides these there will
requirements of research scholars in many of the academic institutions in
place of scientists and engineers.
10.5.5 The universities, Institutes and R&D institutions engaged in developing
various hydrogen technologies would require research scholars. A Hydrogen
Technology Scholarship may be instituted and 100 such fellowships may be
awarded every year on a competitive basis.
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10.6 Gaps in Awareness
10.6.1 Industrial gas suppliers provide training to employees, and offer
training to customers. Hydrogen suppliers agree that safety training for
refuelling station resupply and maintenance personnel is needed. There are a
number of training opportunities, including those offered by industrial gas
providers. The US Department of Energy has developed a basic Hydrogen
training module and plans to expand it for specific target audiences. The
National Hydrogen Association also offers workshops in properties of
Hydrogen, often calling upon the expertise of industrial gas suppliers as
presenters.
10.6.2 In India, training certification in Hydrogen safety is required in areas
such as vehicle refuelling. India should develop such training programs in
Public-Private-Partnership (PPP) mode to ensure availability and
dissemination of the education for safe Hydrogen practices broadly. The
training is sometimes implemented via video displays incorporated into
dispensers. The first time a customer uses a facility (or network of facilities), a
short video covering basic safety and operational procedures is shown and
fuelling is disabled until the video finishes. This is due to the unfamiliarity of
the user with the equipment, its operation, and basic safety practices. This
type of training may be appropriate for Hydrogen refuelling in some areas as
well. There have been organizations that are attempting to create personnel
certification programs for Hydrogen, where they are generally not required for
other fuels. Personnel, who will be working with Hydrogen, can understand
Hydrogen’s unique properties and are trained in handling Hydrogen safely.
10.7 Gaps in Public Private Partnerships
10.7.1 Coordination between industry and government can facilitate smooth
commercialization of Hydrogen and fuel cell systems. By working together,
timely priorities can be identified to promote commercial deployment of
technologies pertaining to Hydrogen and fuel cells.
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10.7.2 Continuation of dialog among all stakeholders, as well as applicable
state agencies, to study the range of codes, standards, and regulatory
activities that are needed to ensure a smooth transition to a Hydrogen
economy, as well as the research to support them, is the key. Through
continued coordination, research funding can be targeted to the areas with the
greatest needs, consistent with timeframes of commercialization & research
work, avoidance of duplication of efforts.
10.7.3 Consortium projects in PPP mode for demonstration of hydrogen and
fuel cell vehicles are required in India.
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155
ACTION PLAN – PROJECTS & TIME
SCHEDULE OF ACTIVITIES
156
157
11.0 Action Plan – Projects and Time Schedule of
Activities
A. National Mission Project
1. Development of National Hydrogen Vehicle Certification and
Research Laboratory
The development of National Facility for Certification of Hydrogen and Fuel
Cell Vehicles as per future Central Motor Vehicle Rules (CMVR) may have the
following facilities:
(i) Chassis Dynamometer for HCV/LCV Vehicles – suitable for both
Hydrogen and Fuel cell buses -1 No.
(ii) Chassis Dynamometer for SUV/Passenger Cars/SCV -2 Nos.
(iii) Chassis Dynamometer for 2/3 Wheelers -1 No.
(iv) Transient dynamometers, 550 kW capacity -1 No.
(v) Transient dynamometers upto 300 kW -2 Nos.
(vi) Hydrogen Cylinder Storage and Dispensing Facility
(vii) Hydrogen Component Certification Equipment
(viii) Hydrogen fuel quality testing and material embrittlement testing
(ix) Hydrogen engine combustion development and simulation centre
Further details of the facility are given in subsequent Chapter.
B. Research & Development Projects
The Research & Development Projects should be supported by inviting
proposals from industry and Research Institutions / academia. The projects
should be evaluated by Expert Committee of the Coordinating Ministry /
Department for their suitability for the Hydrogen program in India.
i. Development of on board safety systems for Hydrogen vehicles
Includes development of safety devices such as flame traps, leak
detectors, alarms, OBD etc.
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ii. After treatment solutions for Hydrogen vehicles
Includes development of NOx control strategies as well as arresting
engine oil based particulates and nano particles.
iii. Development of Indigenous sensors for fuel cell vehicles
Includes development of indigenous low cost sensors such as
antiknock sensor, lambda sensor, etc.
iv. Development of materials for lightweight Hydrogen cylinders
Includes development of lightweight composite materials for Hydrogen
storage which can resist embrittlement and flames.
v. Advanced combustion HCCI engines for Hydrogen fuel
Includes development of high efficiency IC Engines based on
advanced combustion concepts using Hydrogen fuel.
vi. Development of Hydrogen fuel cell demonstration kits for schools
Includes development of kits which could create awareness on
Hydrogen as a fuel demonstrate properties of Hydrogen and explain working
of fuel cell.
vii. Enhancement of Fire Safety Measures for Hydrogen Vehicles
Includes development of fire -fighting equipment including flame
retardant materials.
viii. CFD simulation of Hydrogen release patterns
Includes simulation studies to assess impact of Hydrogen leaks.
C. Basic Research Projects
These projects should be supported by inviting proposals from academic
institutions like IITs, IISC, NIT etc. The projects should also be evaluated by
the Expert Committee for their suitability for the Hydrogen program in India.
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The costing for such basic studies should be worked out based on a standard
format and defined timelines. Some identified research projects / studies are:
(i) Optical engine studies on Hydrogen Combustion
(ii) Suitable odorants and dyes for Hydrogen fuel
(iii) Study of Hydrogen regulations and projection of requirement of
regulation in near future
(iv) Hydrogen flame studies - Visualization
D. HR Related Activities
1. Awards and Scholarships for students and professionals
2. Hydrogen Chair for IIT faculty, Industry professionals
3. Training and Awareness Seminars
4. IPR Budget
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Time Schedule of Activities
Sr. No. Year 2016 2017 2018 2019 2020 2021 2022
Mission Mode Projects
1 Development of National
Hydrogen Vehicle Certification
and Research Laboratory
Chassis Dynamometer for HCV/LCV
Vehicles – suitable for both hydrogen and
Fuel cell buses -1 Nos.
Chassis Dynamometer for
2/3 Wheelers - 1 Nos
Transient dynamometers, 550 kW
capacity -1 Nos.
Transient dynamometers upto 300
kW - 2 Nos.
Chassis Dynamometer for
SUV/Passenger Cars/SCV -
2 Nos.
Hydrogen Cylinder Storage and Dispensing
Facility
Hydrogen Component Certification Equipment
Hydrogen fuel quality testing and material embrittlement testing
Hydrogen engine combustion development and simulation centre
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Sr. No. Year 2016 2017 2018 2019 2020 2021 2022
2 Research & Development
Projects
3 Basic / Fundamental
Research Projects
Development of on board safety
systems for hydrogen vehicles
After treatment solutions for
hydrogen vehicles
Development of Indigeneous sensors for fuel cell
vehicles
Development of materials for lightweight hydrogen cylinders
Advanced combustion HCCI engines for hydrogen fuel
Development of hydrogen fuel cell
demonstration kits for schools
Enhancement of Fire Safety Measures for
Hydrogen Vehicles
CFD simulation of hydrogen release
patterns
Optical engine studies on Hydrogen Combustion
Suitable odorants and dyes for hydrogen fuel
Study of hydrogen regulations and projection of
requirement of regulation in near future
Awards, Scholarships, Training, Awareness Seminars, Advertisements
Hydrogen flame studies - Visualisation
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FINANCIAL PROJECTIONS
164
165
12.0 Financial Projections
S
N
Activity Budgeted
Amount
(INR
Crore)
A HR Activity Budget
1 Standards and Regulations Development 20
2 Awards and Scholarships for Students 30
3 Training and Awareness Seminars for
Manpower Development
50
4 Hydrogen Chair in IITs 25
5 IPR Budget 100
6 Hydrogen demo Kit for schools 25
Subtotal A 250
B Mission Mode Project
1 National Hydrogen Vehicle Certification
Facility
- Upgradation of Chassis dynamometer .
- Engine Dynamometers Test Cell - 350 kW
- Upgradation of EV Facility for fuel cell
- Mobile cascade fuel facility
- Liasion office for standards, awareness &
Training
- Simulation and sensor HIL development
- Hydrogen Component certification facility at
ICAT
- Test track for Hydrogen Stability
- Cylinder testing duly approved
4
10
5
1
1
4
10
5
10
Subtotal B 50
C Research and Development Projects
166
1 Development of on board safety systems for
Hydrogen vehicles
40
2 After treatment solutions for hydrogen
vehicles
20
3 Advanced combustion HCCI engines for
Hydrogen fuel
40
Subtotal C 100
D Basic Research
1 Optical Engine Studies on Hydrogen engine 70
2 Hydrogen Flame Studies 20
3 Odorants for Hydrogen 10
Subtotal D 100
Grand Total (INR Crore) 500
Cash Outlay per year
SN Year Budgeted Amount
(INR Crore)
1 2016-2017 200
2 2017-2018 100
3 2018-2019 75
4 2019-2020 50
5 2020-2021 50
6 2021-2022 25
Grand Total (INR Crore) 500
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IDENTIFICATION OF INSTITUTIONS
AND INFRASTRUCTURE
168
169
13.0 Identification of Institutions and infrastructure
Following Institutions are identified for carrying out specific work in areas
related to hydrogen.
Table 13.1: Institutions and Facilities
S. No. Name Facility Required Facility Covered
under Committee
1 IOC,
Faridabad
Centre of excellence
on Fuel quality
storage, production
and dispensing
Transportation
2 ISRO Centre for Liquefied
Hydrogen Research
Production
3 BHEL /
CFCT
Fuel cell testing
Facilites
Fuel Cells
4 IISC Hydrogen Spray and
combustion
Visualization
IPR
5 IITs Optical engine and
basic combustion
facilities
IPR
6 ARCI Hydrogen material
research
Storage
7 IITs / NITs Hydrogen Training
and Seminars
IPR
8 RDSO Fuel cell locomotives Fuel Cells
9 Patent Cells
in IITs
Patent funding and
guidance
IPR
10 IITs Chairs and
Scholarships
IPR
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CENTRE OF EXCELLENCE
ON HYDROGEN VEHICLE
CERTIFICATION
@ ARAI
172
173
14.0 Centre of Excellence on Hydrogen Vehicle Certification
at ARAI
This project deals with development of National Facility for Certification
of Hydrogen and Fuel Cell Vehicles as per future CMVR norms. It includes
facilities such as
(i) Chassis Dynamometer for HCV/LCV Vehicles – suitable for both
Hydrogen and Fuel cell buses -1 No.
(ii) Chassis Dynamometer for SUV/Passenger Cars/SCV -1 Nos.
(iii) Transient engine dynamometers, 550 kW capacity -1 No.
(iv) Transient engine dynamometers upto 300 kW -2 Nos.
(v) Hydrogen Fuel Storage and Dispensing Facility
(vi) Hydrogen Component Certification Equipment
(vii) Hydrogen engine sensor development & simulation centre
(viii) Liaison Office for Hydrogen Type Approval/ Standard
Development/ Patent Cell
The budgeted cost is Rs. 350 Crore which includes cost of equipment,
installation, civil work, utilities, manpower and fuel infrastructure. As a
multidisciplinary testing and research facility. This centre should have
leadership role in the development of clean energy solutions, such as
Hydrogen fuel. To support technology advances, this centre should provide
services in Hydrogen testing, certification and prototype development.
Further, this centre will play an active role in development of Hydrogen type
approval standards and component certification. Some facilities required are
shown below:
A. Hydrogen & Fuel Cell Vehicle Emission Testing
This facility will cover the testing of Hydrogen vehicles as per international
norms and future Indian emission norms (BS-V and BS-VI). Hydrogen fuel
quality testing and related aspects will also be covered in this lab. The lab will
contain chassis dynamometers and engine dynamometers as shown in Figure
14.1
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Figure 14.1: Vehicle Chassis Dynamometer and Engine Dynamometer
B. Hydrogen Component Certification Facilities
This facility will provide testing and certification services to all national
and international standards for compressed Hydrogen components used in
vehicles, transportation, and fueling station applications. Refer Figure 14.2 for
the setup of the hydrogen component testing facility. Tests on individual
components including hoses, valves, pressure regulators, flowmeters, fueling
connectors, tanks, etc., to all existing and draft standards, including BIS, EEC
79, CSA HGV3.1, SAE J2579, and the United Nations GTR for Hydrogen
vehicles will be conducted. This centre will also conduct simulated lifetime
testing of complete Hydrogen vehicle fuel systems in accordance with OEM-
specified lifetime endurance tests.
175
Figure 14.2: Hydrogen Component Testing Facility
C. Hydrogen Engine Prototype Development:
This facility will deal with design and development of IC engines
running on Hydrogen fuel and its blends. Development of high performance
engines using transient test benches will be done along with combustion
analysis and prototype design. New combustion concepts like HCCI will also
be evaluated.
D. Hydrogen Simulation and Sensor development Facilities
These facilities will be required to simulate and study the release
patterns of Hydrogen in a leak as well as model explosions and dispersion of
Hydrogen from safety point of view as shown in Figure 14.4
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Figure 14.4 Hydrogen Simulation Facilities
The centre will also focus on development of low cost hydrogen sensors for
onboard deployment in automotive applications.
E. Liaison Office for Hydrogen Type Approval Standard Development
This office will participate in developing standards and extending
support to government in developing type approval regulations for Hydrogen
vehicles in India. The operational cost for the running the centre will be borne
by the government for an initial handholding period of 3 years, thereafter the
cenre is expected to break even and generate funds for its self- sustained
operation.
It is proposed to setup this National Hydrogen Vehicle Certification
Centre at ARAI, Pune. A detailed techno-commercial proposal will be
submitted to the Ministry.
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CONCLUSIONS AND RECOMMENDATIONS
178
179
15.0 Conclusions and Recommendations
Although the activities for the research & development in the area of
Hydrogen Energy and Fuel Cells were started around four decades ago in
India, but these are still in their early phase compared to other nations.
Therefore, it is inevitable to have more focus on creating its awareness and
disseminate relevant information about the use and its impact on
environment, health and society, protecting research & developmental work
through patents, commercialization of the developed technologies by
developing standards and in Private-Public-Partnership mode for wide
coverage of their deployment in shorter span of time. To promote fuel cell
technology in the country, proper strategies and plans need to be prepared.
The recommendations given below may be a few strategies to work in future:
Issue of notification for the use of Hydrogen as a fuel in India.
Promote and strengthen R&D activities on safety aspects of Hydrogen
& fuel cells through R&D and academic institutions, while ensuring
social responsibilities and commitments.
Conduct key analyses to guide R&D and path forward – Life cycle cost;
economic & environmental analyses, etc.
Conduct strategic, selective demonstrations of innovative technologies.
Encouragement of Hydrogen vehicle demonstration projects.
Financial assistance to government institutions / industry for
commercial research projects in the area of Hydrogen.
Establishment of a Centre of Excellence at ARAI for Hydrogen vehicle
certification, research in testing methods, development of Hydrogen
component in vehicle testing and cylinder evaluation.
Visits to international Hydrogen R&D centres for first hand assessment
of activities and possible collaborations.
Collaborations with foreign institutions for information and technology
exchange on Hydrogen.
Organize national and international conferences on Hydrogen
technology.
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Promote foreign cooperation for exchanges of intellectuals for
developing Intellectual Property (IP), stepping up forecast of IP related
information on external trade and domestic markets and the
maintenance of IP.
Implementation of laws of intellectual property rights effectively.
Leverage activities to maximize impact and facilitating
commercialization of patented items.
50 scholarship awards for research scholars in the area of Hydrogen
energy and fuel cells.
Student exchange programs with international universities on Hydrogen
technology.
Faculty Chair positions in major technological institutions involved in
research activities on Hydrogen energy and fuel cells.
Training to enforcement officers, in-house counsels, and addition in the
educational curriculum for school students.
Organize seminars / workshops for spreading awareness about
Hydrogen energy safety aspect of Hydrogen.
Development of BIS standards on Hydrogen and fuel cells technologies
including fuel dispensing and composite cylinders.
Assistance for participation in international standard body ISO TC 197
meetings related to Hydrogen technology.
Rewards can be given at various stages like filing, granting of patents
and commercialisation of patented items by companies to promote
manufacturing in the area of Hydrogen and Fuel Cells.
Awards for technical developments related to Hydrogen fuel
Sharing of investment / working capital of the Industry and to
accelerate market transformation
Promote energy efficient industries, invest in clean energy solutions
and Spur innovation through new energy standards.
Setting-up of solar based Hydrogen stations in PPP mode.
Accelerate business innovation with the Research & Experimentation
(R&E) tax credit.
181
Tax benefits for development, demonstration and commercialization of
Hydrogen vehicle technologies at different stages to the institutions
involved in such activities.
Constitution of a nodal committee for implementation of Hydrogen
technologies.
182
183
BIBLIOGRAPHY
184
185
16.0 Bibliography
16.1 Introduction
1. ISO TC 197 Website
2. Gas Cylinder Rules, 2004
3. CMVR rules 1989
4. Presentation from Mr. Srivastava, PESO
5. Presentation from Dr. Thipse, ARAI
6. US NHTSA Hydrogen Vehicle Safety Report
7. UNIDO-ICHET Report on Hydrogen Vehicles
8. UNECE-GRSP-49-28
9. Presentation from Clean Cities, US DOE
10. BIS Website
11. Website of HAI
12. Website of Intelligent energy, UK
13. Presentation from SIAM
14. Hydrogen roadmap by MNRE, 2005
16.2 Intellectual Property Rights (IPR) - Hydrogen and Fuel Cell
1. http://www.Hydrogen.energy.gov/pdfs/review13/03_satyapal_plenary_2
013_amr.pdf
2. http://cepgi.typepad.com/files/cepgi-2013-year-end-wrap-up.pdf
3. http://www.fuelcelltoday.com/media/1752762/2012_patent_review.pdf
4. http://www.fuelcelltoday.com/media/1587227/fuel_cells_and_Hydrogen
_in_china_2012.pdf
5. http://www.wipo.int/export/sites/www/patentscope/en/technology_focus
/pdf/landscape_alternative_energy.pdf
6. http://www.whitehouse.gov/sites/default/files/uploads/InnovationStrateg
y.pdf
7. http://dipp.nic.in/English/Schemes/Intellectual_Property_Rights/national
_IPR_Strategy_21July2014.pdf
8. www.wipo.int/sme/en/activities/.../technology_transfer_ganguli.ppt
186
9. http://www.kacst.edu.sa/en/about/publications/Other%20Publications/S
TRATEGIC%20REVIEW%20OF%20THE%20ENERGY%20TECHNOL
OGY%20LANDSCAPE.pdf
16.3 Hydrogen Storage Regulations
1. ISO TC 197 Website
2. Gas Cylinder Rules, 2004
3. CMVR rules 1989
4. Presentation from Mr. Srivastava, PESO
5. Presentation from Dr. Thipse, ARAI
6. US NHTSA Hydrogen Vehicle Safety Report
16.4 Safety of Hydrogen and Fuel Cells
1. http://www.kacst.edu.sa/en/about/publications/Other%20Publications/S
TRATEGIC%20REVIEW%20OF%20THE%20ENERGY%20TECHNOL
OGY%20LANDSCAPE.pdf
2. BarisAcıkgoz, CenkCelik et.al. Emission characteristics of an
hydrogen–CH4 fuelled spark ignition engine, Fuel 159 (2015) 298–30
3. BIS Website
4. Biohydrogen Production: Fundamentals and Technology Advances,
Debabrata Das, Namita Khanna and Chitralekha Nag Dasgupta, CRC
Press, 408 Pages, 2014 (ISBN 9781466517998).
16.5 Standards on Hydrogen
1. Basu, S., Chokalingam, R., ‘Ceria based electro-ceramic composite
materials for solid oxide fuel cell application’ (Ch 10), In Advanced
Organic-Inorganic Composites: Materials, Device and Allied
Applications, Ed. Inamuddin Siddiqui, Nova Science Publications Inc.,
N.Y. 2011
2. Surya Singh, Anil Verma, Suddhasatwa Basu, ‘Oxygen Reduction Non-
PGM Electrocatalysts for PEM Fuel Cells – Recent Advances’ (Ch 5) in
Advanced Materials and Technologies for Electrochemical Energy, Ed
P. K Shen, C. Wang, X. Sun, S. P. Jiang, and J. Zhang, CRC Press
(2014)
187
3. R. Chetty and K. Scott "AirBreathing Direct Methanol Fuel Cells
with
Catalysed Titanium MeshElectrodes" in Electrocatalysts: Research, Techn
ology and Applications, Nova Science Publishers, Inc. New York, 2009.
4. Jayati Datta, (2015) “Multi-metallic nano catalysts for anodic reaction in
direct alcohol Fuel Cell”, in “Nanomaterials for Direct Alcohol Fuel
Cells”, Pan Stanford Publishing Pte Ltd., Singapore.
16.6 Human Resource Development
1. European Hydrogen and Fuel Cell Technology Platform, 2005.
Deployment Strategy. https://www.hfpeurope.org/hfp/keydocs.
2. Dutton, A.G., 2002. Hydrogen energy technology. Tyndall Working
Paper TWP 17, Tyndall Centre for Climate Change,
http://www.tyndall.ac.uk/publications/ working papers/wp17.pdf .
3. European Commission, 2003. Hydrogen energy and fuel cells: a vision
of our future. http://www.europa.eu.int/comm/research/energy/pdf/
Hydrogen-report en.pdf.
4. Sastri, M.V.C.,1987. Hydrogen energy research and development in
India--an overview. Int. J. Hvdrogen Energy, 12(3): 137-145.
5. Powell, J.C., Peters, M.D., Ruddell, A., Halliday, J., 2002. Fuel cells for
a sustainable future? Tyndall Working Paper TWP 50, Tynd
16.7 Awareness for Hydrogen and Fuel Cells
1. www.eere.energy.gov/hydrogenandfuelcells/pdfs/fct_h2_fuelcell_factsh
eet
2. http://www.hydrogen.energy.gov/pdfs/review13/03_satyapal_plenary_2
013_amr.pdf
3. http://cepgi.typepad.com/files/cepgi-2013-year-end-wrap-up.pdf
4. http://www.fuelcelltoday.com/media/1752762/2012_patent_review.pdf
5. http://www.fuelcelltoday.com/media/1587227/fuel_cells_and_hydrogen
_in_china_2012.pdf
6. http://www.wipo.int/export/sites/www/patentscope/en/technology_focus
/pdf/landscape_alternative_energy.pdf
188
7. http://www.whitehouse.gov/sites/default/files/uploads/InnovationStrateg
y.pdf
8. http://dipp.nic.in/English/Schemes/Intellectual_Property_Rights/national
_IPR_Strategy_21July2014.pdf
9. www.wipo.int/sme/en/activities/.../technology_transfer_ganguli.ppt
16.8 Public Private Partnership for Hydrogen and Fuel cells
1. Eichlseder H, Spuller C, Heindl R, Gerbig F, Heller K, New and
innovative combustion systems for the H2eICE: compression ignition
and combined processes. SAE P. 2009-01-1421, 2009.
2. Tsujimura T, Mikami S, Achiha N, Tokunaga Y, Senda J, Fujimoto H. A
study of direct injection diesel engine fuelled with hydrogen. SAE
Technical Paper 2003; 2003-01-0761:1-16.
3. Masood M, Ishrat M. Computer simulation of hydrogenediesel dual fuel
exhaust gas emissions with experimental verification. Fuel
2008;87:1372-8.
4. Saravanan N, Nagarajan G. An experimental investigation of hydrogen-
enriched air induction in a diesel engine system. International Journal
of Hydrogen Energy 2008;33:1769-75.
5. Rakopoulos CD, Scott MA, Kyritsis DC, Giakoumis EG. Availability
analysis of hydrogen/natural gas blends combustion in internal
combustion engines. Energy 2008;33:248-55.
6. S O Bade Shrestha G A Karim, Hydrogen as an additive to methane for
spark ignition engine applications, International Journal of Hydrogen
Energy 24(1999)577-586.
16.9 Gap Analysis – India vs International Scenario
1. Website of HAI
2. Website of Intelligent energy, UK
3. Presentation from SIAM
4. UNIDO-ICHET Report on Hydrogen Vehicles
5. UNECE-GRSP-49-28
6. Presentation from Clean Cities, US DOE
189
16.10 Conclusions and Recommendations
1. K. S. Dhathathreyan, “The ARCI Fuel Cell Programme “ ISOFT e-
Bulletin Vol. 02 No.01, June 1, page 2, 2011.
2. Das LM. Near-term introduction of hydrogen engines for automotive
and agricultural application. International Journal of Hydrogen Energy
2002; 27:479-87.
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