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UOP 7340-0
UOP Renewable Energy & Chemicals
Renewable Fuels Integrated with Petroleum Refineries and Existing Infrastructure
Anjan Ray
April 18, 2016
May 11, 2016 Symposium on Biofuels and Bio-Energy New Delhi, India
© 2016 UOP LLC. A Honeywell Company All rights reserved.
The Goals: Reduce Fossil Energy Import Dependence and Emissions Simultaneously
1
UOP 7301A-1
India’s Commitment to Emissions Reduction
Action Proposed on Multiple Fronts
India INDCs – Towards Climate Justice, Ministry of Environment, Forests & Climate Change, 2015
Philip Massey, PwC, India: Emission Targets and Implications for Business, 2015
• Goal: Reduce emissions
intensity of GDP by ~33-35%
(2030 vs 2005)
• Avoided emissions ~ 3.59B tons
CO2e over BAU
• Thrusts on renewable energy,
green transport
• Urban air quality issues
Euro-VI transition
Ban on open biomass
burning
• Linkages to Swachh Bharat
Mission, Make in India
How ambitious is India’s 33-35% GHG intensity reduction target?
Ca
rbo
n In
ten
sit
y (
tCO
2/$
m G
DP
20
14
) 600
500
400
300
200
100
-2000 2005 2010 2015 2020 2025 2030
Businessas Usual
(-1.4% per year)
Paris Target(-2.1% per year)
Global Average2ºC Pathway
(-6.3% per year)
2
Drop-in Renewable Fuels for India
• Pipeline-compatible distillate fuels – seamless adaptation
- No separate handling, storage, distribution infrastructure needed unlike biodiesel (FAME, fatty acid methyl ester) or ethanol
• Comparable or superior quality – supports move to Euro-VI
- Ultralow sulfur, ultrahigh cetane (Green Diesel)
- Higher energy density (Green Diesel, Green Jet Fuel)
- Lower sulfur (HR F-76 Renewable Marine Fuel)
• High OEM acceptability
- European and Japanese automakers favor green diesel over FAME biodiesel
- 100% green diesel approved in select Mercedes, Volvo and Scania trucks
- Major aircraft engine and Auxiliary Power Unit (APU) manufacturers supported ASTM D7566 specification for Bio-SPK (Green Jet)
• Biomass-derived partially renewable gasoline and diesel
- Creates incentive for farmers not to burn biomass in the fields
- Converts locally available waste carbon to renewable fuels
UOP 7340-3
3
4Product Quality from the Ecofining™ process
and the UOP Renewable Jet Fuel Process™
Jet A-1
Spec.
50/50
Blend
Green
Jet
Flash Point, °C 38 min 46 45
Freeze Point,
°C
-47 max -57 -57
Energy
Density, MJ/kg
42.8 min 43.6 43.9
Thermal
Stability
Baseline Excellent Excellent
Aromatics 8 min
25 max
8.5 Nil
Green
Jet
ULSDFAME
Biodiesel
Green
Diesel
Oxygen, % 0 11 0
Cetane 40-55 50-65 75-90
Energy
Density, MJ/kg
43 38 44
Sulfur, ppm <10 < 2 < 2
Cold Flow Baseline Poor Excellent
Oxidative
Stability
Baseline Poor Excellent
Honeywell Green Diesel™
also known as:
Renewable Diesel
HVO (hydrotreated vegetable oil)
HRD (hydrotreated renewable diesel)
BHD (bio-hydrogenated diesel)
Green
DieselHoneywell Green Jet Fuel™
also known as:
Renewable Jet
SPK, or Bio-SPK(synthetic paraffinic kerosene)
HRJ (hydrotreated renewable jet)
HEFA-SPK (hydroprocessed esters and fatty acids)
High quality drop-in fuels that fully meet specifications
Technologies to Produce Low Carbon Emission Fuels
5
UOP 7301-5
UOP
Technology
Honeywell Green Jet Fuel™
Renewable Fuels from Fats, Oils & Greases
Plant-derived Oils
Animal Fats
Algal Oil
Used Cooking Oil
Honeywell Green Diesel™
Proven Technologies for Feedstock Flexible Drop-in Fuels
6
Renewable Fuel Oil from Biomass
RTP Green Fuel is “liquid wood” made from Cellulosic Biomass
7
Forest Residue
Agricultural Waste
Ensyn RTP™ UnitRenfrew, Canada RTP Green Fuel
Energy Crop
Partially
renewable
products
sent
downstream
LPG
Gasoline
Light Cycle Oil(LCO)
Vacuum Gas Oil (VGO)
Unconverted Oils (UCO)
Utilize existing refinery assets & infrastructure
8Renewable Fuel Blend Stock from FCC Co-Processing RTP Biocrude
Commercial Status of Renewable Fuels
UOP 7301-9
9
Options for Effective Use of Capital and Assets
10
UOP Renewable Fuel Projects
Adjacent to existing refinery (“brown field”)
• 10,000+ bpsd Renewable Diesel
Retrofit of existing refinery unit (s)
• 8500+ bpsd Renewable Diesel
• 2500+ bpsd Green Diesel & Green Jet
2013
2016
Natural Oils
Animal Fats
Algal Oils
Used Cooking Oil
Mu
ltip
le F
eed
sto
ck O
pti
on
s
2014
Green Diesel User – Walt Disney World
Green Diesel Used Commercially
11
®
Green Fuels On The Seas
50% HRF-76 in US Navy RCB-X Small Craft
Italian Navy Patrol Boat “Foscari”
50% HRF-76 Blend in US Navy Destroyer
New marine fuel standards can be met using Ecofining technology
12
Some Honeywell Green Jet Fuel Flights
Many demonstration, commercial and military flights since 2008
Airline Date Remarks
Air New Zealand Dec 08 First commercial airliner Bio-SPK demo
KLM Nov 09 First biofuel test flight with passengers
TAM, Brazil Nov 10 First Biofuel flight in Latin America
Honeywell (Corporate Jet)
Jun 11 First Trans-Atlantic biofuel flight. First corporate jet to fly on biofuel
Boeing, USA Jun 11 First Trans-Atlantic commercial aircraft with engines on 15% Bio-SPK blend
Aeroméxico Aug 11 First transcontinental commercial flight, 30% blend (Mexico City to Madrid)
Aeroméxico Oct 11 Weekly commercial flight, 52 flights (Mexico City to San Jose, Costa Rica)
Iberia Oct 11 First commercial flight in Spain (Madrid to Barcelona)
Air China, China Oct 11 First Biofuel demonstration flight in China
United Airlines, USA Nov 11 First U.S. commercial passenger flight (Houston to Chicago)
Porter Airlines Apr 12 Canada’s First Biofuel-Powered Revenue Flight
GOL Oct 13 Sao Paulo to Brasilia- first commercial biofuels flight in Brazil
GOL Jul 14 200 commercial flights during the FIFA World Cup™ in Brazil
13
Commercial Renewable Aviation Biofuels…Now a Reality
14
Honeywell UOP Technology Produces First Commercial Aviation Biofuel
United Airlines is first
commercial airline in
U.S. to use renewable
jet fuel on scheduled
flights
Fuel provided by AltAir
Fuels in first dedicated
commercial production
of renewable jet fuel
Concept Selection
Pilot Plant Trials
Commercial Design
Proof of Concept
EPA Part 79
EPA Part 80
Technology Deployment
FCC Co-processing Commercialization
Multiple Refiners Assessing FCC Co-Processing
15
2016
RTP Unit
Renewable Fuel Mixture
to Refinery Pool
RFO produced by outside
project developer and
delivered to refinery
Refiner co-processes RFO
with VGO to produce
renewable fuel blendstocks
RTP Green Fuel or
Pyrolysis Oil or
Renewable Fuel Oil (RFO)
Renewable Heat from RTP Green Fuel
• Switched from #4 fuel oil
• Added storage tank and modified two boilers ($500K cost)
• Five year supply agreement
Hospital inNew Hampshire
Hospital inNew Hampshire
• Switched from #2 fuel oil
• Added storage tank and new single boiler ($500K cost)
• Seven year supply agreement
• Heat & cooling for 77 building
• Displace 50% of natural gas
• Supply ~10 million liters per year
• Five year supply agreement
District heating in Ohio
Iron ore facilityin Canada
• Four month trial on three burners
• Potentially replace 20% heavy fuel oil use per year
• Negotiations for long-term contract
16
© 2016 by Honeywell International Inc. All rights reserved.
GHG and SOx Reduction Driving Adoption
The Enablers: Regulations drive adoption
UOP 7301-17
17
US Mandates Driving Renewable Fuels Adoption
Current US Renewable Environment
EPA Ruling, Nov 2015
• 20% increase in RIN values
• CA Low Carbon Fuel Standard
(LCFS) Credits >$100/MT CO2e
• Cellulosic Waiver Credits set to
more than double
18
RIN Values
$0
$20
$40
$60
$80
$100
$120
$140California LCFS ($/MT CO2e)
$1.56
$1.13
$0.78
$0.42 $0.49 $0.64
$1.33
$1.88
$-
$0.50
$1.00
$1.50
$2.00
1 2 3 4 5 6 7 8
Cellulosic Waiver Historical Prices(set by EPA)
$0.00
$0.20
$0.40
$0.60
$0.80
$1.00
$1.20
$1.40
$1.60
$1.80
RIN
Pri
ce
($
/RIN
)
D3/D7 D4
UOP Estimate
Source: Pira
Source: EPA
Source: Jacobsen
UOP Renewable Technology Options Can Address India Objectives
19
Summary
• Renewable fuel demand growing based on regulations
• Honeywell Green Diesel and Green Jet technologies provide commercially proven drop-in transportation fuels
• Renewable Diesel & Gasoline from FCC Co-Processing of RTP Fuel Oil is EPA Certified
• Seamless integration into refineries eliminates need for separate biofuels handling, storage and transport infrastructure
• Revamp of existing refinery assets significantly reduces capex
The dream of the Great Green Fleet came to life in
January, 2016 as the aircraft carrier John C.
Stennis left on its latest deployment, with five
biofuel-powered ships alongside for the first time.
Honeywell is committed to providing technology
options that enable our customers to produce the
highest quality renewable fuels
HONEYWELL RENEWABLE ENERGY & CHEMICALS
THANK YOU
UOP 7340-20