Reagent & trip blanks for MW-4UB accession #806170, tests ... · 07/02/88 07/02/88 ug/l n/a compounds results chloromethane bromomethane vinyl chloride ... (mbk) 4-methyl-2-pentanone

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SFUND RECORDS CTR

88015252

GCMS - RESULTS SFUND RECORDS CTR

0222-00699

yy/u/'iui^

REAGENT BLANK

TEST : VOLATILE ORGANICS (EPA 624)

CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 661D PROJECT NAME : HASSAYAMPA CLIENT I.D. : REAGENT BLANK

AR0573 ATI I . D . DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

806170 07/02/88 07/02/88 UG/L N/A

COMPOUNDS RESULTS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE DENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE ClII,OROnENZENE ETIIYL BENZENE STYRENE TOTAL XYLENES

SURROGATE PERCENT RECOVERIES

l,2-DICHLOROETHANE-D4 (%) BFB (%) T0LUENE-D8 (%)

<10 <10 <1 <1 TR 15 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 94 96

i \ .J^ ' - : ' , ^ - i - 1Z1O...1

7)'bt>s-5

- - \ - • - . - . . ' n

(^,777/ 77)07 -Au/B

DATA: B72 #1 CALI: B72 #2

SCANS RIC @Z^:02i^l0:05:80 SAMPLE: REAGENT BLANK 5ML CONDS.: GC4 RANGE: G 1,1268 LABEL: N 8, 4.8 QUAN: A 8/ 1.8 J 8 BASE: U 28,

1 TO 1200

100.0-1

in

in

d z D 00 O 00 LL N,

nj »* o

Q .. UJ I-I <: CJ) >•* Q Z UJ »-• I ,u. m

l-l < z o •-• H- U.

RIC

200 6:40

608

300

381

I Vy, 468 533 .

400 13:20

#

784384.

33:20 • 00 SCAN :P0 TIME

PROCEDURE DATA FILE REFERENCE NAME LIST

REPORT

DIAGNOSTIC REPDRT TCA B72 B72 VQN INITIALIZATION OPTION: VQSTDS

7/02/88 10:46:01

PROCESSING OPTION: 3

^ STANDARDS -PROC USED POSS

6 6 1 6 6 1 6 6 1

X PLUS UNKNOWNS X - LIST NAMES - > RMS PROC USED POSS RMS STANDARD/UNKNOWN 50 18 8 1 123 VQSTDS/VQl 50 18 7 5 99 VQSTDS/VQ2 50 18 11 6 67 VQSTDS/VQ3

42 COMPOUNDS PROCESSED, 14 FOUND

< COMPOUND X NO LIB ENTRY REF 1 VQ 1 2 VQ 2 3 VQ 3 4 VQ 4 5 VQ 5 6 VQ 6 7 VQ 7 8 VQ 8 9 VQ 9 10 VQ 10 11 VQ 11 12 VQ 12 13 VQ 13 14 VQ 14 *5 VQ 15 J VQ 16

17 VQ 17 18 VQ 18 19 VQ 19 20 VQ 20 21 VQ 21 22 VQ 22 23 VQ 23 24 VQ 24 25 VQ 25 26 VQ 26 27 VQ 27 28 VQ 28 29 VQ 29 30 VQ 30 31 VQ 31 32 VQ 32 33 VQ 33 34 VQ 34 35 VQ 35 36 VQ 36 37 VQ 37 38 VQ 38 39 VQ 39 40 VQ 40

VQ 41 .2 VQ 42

-300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 299 608 758 382 721 903 55 86 108 138 204 223 253 287 327 347 364 386 381 423 435 437 449 686 491 499 515 534 537 531 537 570 616 631 678 687 728 763 825 948 989 957

— SEARCH >< SAT X SEL DELTA PEAKS FIT PEAKS M/Z 300 1 608 758 381 -1 721 903

, , , , , , ^

206 2 223

684 -2 '

679 1

824 -1 949 1 989 : 958 1 ;

1 976 1 924 1 994 1 997 1 994 1 971

.

.

1 993 1 911

5 998

L 861

L 917 I 980 2 905 3 887

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

CHRO > TOP DELTA PEAKS 300 608 758 381 721 903

,

206 222 •-1

.

.

.

.

685 1

.

530

687 727 761 825 1 950 1 988 -1

.

1 1 1 1 1 1

1 1

*

1

I

Quantitation Report File: B72

Data: B72. TI 07/02/88 10:05:00 Sample: REAGENT BLANK 5ML

Ids. : GC4 1-w.rmula: Instrument: 1050 Weight: 0.004 Submitted by: Analyst: MGB Acct. No. :

AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 ^8 )

20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 183 SSI SS2 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H IIV 6V 19H 48V 15V 32V 33V)V 87V 51V 14V 4V

33VC 19V 47V

BROMOCHLOROMETHANE 1,4-DIFLUaROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1.1-DICHLOROETHANE TRANS-1, 2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM

4-METHYL-2-PENTAN0NE 16H 85V 86V 7V

38V 18H 20H

2-HEXANQNE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

XYLENES

V

No 1 2 3 \

6 6 7

10 11 12 13 14 15

22 23 24 25 26 27 28 19

31

34 35 36 37 38 39 40 41 42

m/z 128 114 117 65 98 95

NOT 8 NOT 9 NOT

NOT 84 43

NOT NOT NOT

16 NOT 17 NOT 18 NOT 19 NOT 20 NOT 21 NOT

NOT NOT 83

NOT NOT NOT NOT NOT 78

NOT 32 NOT 33 NOT

NOT NOT 164 92 112 106 104 106 NOT

Scan 300 608 758 381 721 903

FOUND FOUND FOUND FOUND

206 222

FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

685 FOUND FOUND FOUND FOUND FOUND

530 FOUND FOUND FOUND FOUND FOUND

687 727 761 825 950 988

FOUND

Time Ref RRT Meth 10:00 20: 16 25: 16 12: 42 24: 02 30:06

6: 52 7:24

22: 50

22: 54 24: 14 25:22 27:30 31:40 32: 56

1 2 3 1 3 3

1.000 1. 000 1. 000 1. 270 0.951 1. 191

0. 687 0, 740

3 3 3 3 3 3

0. 906 0. 959 1.004 1. 088 1. 253 1. 303

A A A A A A

Area(Hght) Amount

A A A A A A

BB BB BB BB BB BB

A BB A BV

1. 127 A BB

17: 40 2 0. 872 A BB

BB BB BB BB BB BV

136735. 827525. 683347. 218753. 923511. 526193.

12752. 16234.

6104.

3979.

257. 2413. 4493. 2083. 15467. 3951.

50. 000 UG/L 50. 000 UG/L 50. 000 UG/L 100. 729 X 95. 702 7. 93. 880 X

2.381 UG/L 14. 997 UG/L

0. 219 UG/L

0. 053 UG/L 0. 198 UG/L 0.309 UG/L 0. 299 UG/L 1. 287 UG/L 0. 534 UG/L

7.Tot 10. 84 10. 84 10. 84 21, 84 20,75 20. 36

0. 52 3. 25

0, 614 UG/L 0. 13

• >

9 ^ .

0, 05 / 9 -

0. 01 ''^ 0, 04 <^^ 0, 07 'A-0, 06 'TT-^ 0 . 2 8 " y ^ 0. 12 7

^

'77 <?

I r t f % f * * ' ;

/ÂnolyticolTechnologies, Inc l^^-'/UB

QUALITY CDNTROL DATA

TRIP BLANK


CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 661D PROJECT NAME: HASSAYAMPA CLIENT I.D. J TRIP BLANK

ATI I.D. I 806170-02 DATE EXTRACTED : 07/02/88 DATE ANALYZED : 07/02/88 UNITS : UQ/L DILUTION FACTORJ 1

COMPOUNDS RESULTS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIB-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 2-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYL BENZENE STYRENE TOTAL XYLENES

<10 <10 <1 <1 5 B 11 B <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1


1,2-D ICHL0R0ETHANE-D4 (7.) BFB (7.) TOLUENE-DB (7.)

118 93 96

(s7lAH TTOU - ^TAB

RIC 07/02/88 11:45:00 SAMPLE: JOB 806170-2 TRIP BLANK SML CONDS.: GC4

DATA: 806170TB «1 CALI: 80617018 «2

SCANS 1 TO 1200

100.0-1 RANGE: G — 1 / 1 2 0 0 LABEL: N Z, 4 . 0 QUAN: A 0 , 1.0 J 0 BASE: U 20. 3

721

o n ni

Q

z O

00 00 V, (M O v. N

CX . . UJ »-I < tn »-« Q Z UI u. cn

t-t

<. z CJ n h- U.

RIC

300

vJL 142

381

205

Jl (UJ 421

607

534

758

U l 826

\ Al 358400.

903

1042

200 6:40

—1 400

13:20 P«0

J0 800

26:40

—I 1000 33:20

— I «''00 SCAN

J 00 TIME

DIAGNOSTIC REPORT PROCEDURE: TCA DATA FILE: 806170TB REFERENCE: 806170TB NAME LIST: VQN INITIALIZATION OPTION:

REPORT: VQSTDS

7 / 0 2 / 8 8 1 2 : 2 5 : 3 7


^ STANDARDS PROC USED POSS RMS

6 6 1 43 6 6 1 43 6 6 1 43

X PLUS UNKNOWNS X - LIST NAMES - > PROC USED

18 18 18

POSS RMS STANDARD/UNKNOWN 8 1 115 VQSTDS/VQl 7 1 87 VQSTDS/VQ2 6 1 43 VQSTDS/VQ3


< COMPOUND X NO LIB ENTRY 1 VQ 1 -2 VQ 2 -3 VQ 3 -4 VQ 4 -5 VQ 5 -6 VQ 6 -7 VQ 7 8 VQ 8 9 VQ 9 -10 VQ 10 -11 VQ 11 -12 VQ 12 -13 VQ 13 -14 VQ 14 -<5 VQ 15 -J VQ 16 -

17 VQ 17 -18 VQ 18 -19 VQ 19 -20 VQ 20 -21 VQ 21 -22 VQ 22 -23 VQ 23 -24 VQ 24 -25 VQ 25 -26 VQ 26 -27 VQ 27 -28 VQ 28 -29 VQ 29 -30 VQ 30 -31 VQ 31 -32 VQ 32 -33 VQ 33 -34 VQ 34 -35 VQ 35 -36 VQ 36 -37 VQ 37 -38 VQ 38 -39 VQ 39 -40 VQ 40 -

VQ 41 -.A VQ 42 -

REF •300 •608 •758 -382 •721 •902 -54 -85 •107 •137 •203 •222 •252 •286 -326 •346 •363 •385 •382 •424 •436 •438 •450 •686 •491 •499 •515 '534 •537 •531 •537 •570 616 631 678 687 727 •762 •824 •947 •987 •956

PRED 299 608 758 381 721 903 54 85 107 137 203 222 252 286 326 346 363 385 381 423 435 437 449 686 490 498 514 533 536 530 536 570 616 631 678 687 727 762 824 948 988 957

- SEARCH SEL' DELTA PEAKS 299 607 -1 758 381 721 903

205 222

684 -2

X SAT X — FIT PEAKS M/Z 975 924 995 999 994 970

994 908

996

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

— CHRO > TOP DELTA PEAKS 299 . 1 607 757 381 721 903

205 222

530

725 761

950

Quantitation Report File: 806170TB

Data: 806170TB. TI 07/02/88 11:45:00 Sample: JOB 806170-2 TRIP BLANK 5ML ' Ids. : GC4 t t' mula: Instrument: 1050 Weight.: 0. Cib4 Submitted by: Analyst: MGB Acct, No. :

AM0UNT=AREA * REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

^0 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 I S3 SSI S52 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H IIV 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V

BROMOCHLOROMETHANE 1,4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 TOLUENE-DB BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1. 1-DICHLOROETHANE TRANS-1, 2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2, 2-TETRACHLOROETHANE 1, 2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM

4-METHYL-2-PENTAN0NE 16H 85V 86V 7V 38V 18H' 20H

2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

XYLENES

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 >

wX

32 33 34 35 36 37 38 39 40 41 42

m/z 128 114 117 65 98 95

NOT NQT NOT NOT 84 43

NOT NOT NOT NQT NQT NQT NQT NQT NOT NOT NOT NOT NQT NQT NQT NQT NQT 78

NQT NQT NOT NQT NQT NQT 92 112 NQT 104 NOT NQT

Scan 299 607 757 381 721 903


205 222

FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

530 FOUND FOUND FOUND FOUND FOUND FOUND

72S 761

FOUND 950

FOUND FOUND

Time 9: 58

20: 14 25: 14 12:42 24:02 30:06

6: 50 7:24

17:40

24: 10 25:22

31:40

Ref 1 2 3 1 3 3

1 1

2

3 3

3

1. 1, 1. 1. 0. 1,

0. 0.

0,

0, 1.

1,

RRT 000 000 000 274 952 193

686 742

873

958 005

255

Meth A BB A BB A DD A DB A BB A BB

A BB A BB

A BB

A DD A BD

A BB

Area(Hght) 121059, 836117, 688719. 227033. 929346. 523378.

24124. 10403.

3807,

1894, 4285,

297,

Amount 50, 000 50, 000 50. 000 118, 078 95. 555 92. 649

5, 088 10. 855

0. 208

0, 154 0.293

0. 025

UO/L UG/L UO/L X X X

UG/L UG/L

UO/L

UG/L UG/L

UO/L

XTot 10, 57 10, 57 10. 57 24, 97 20,21 19. 59

1,08 2,30

0. 04

0.03 0. 06

0,01

Z V ^

y 79^

l y—

y f

l ^

Jp

/ N AnolyticalTechnologies, Inc

*^^ GCMS - RESULTS

REAGENT BLANK

TEST : SEMI-VOLATILE ORGANICS (EPA 625)

CLIENT : MONTGOMERY fit ASSOCIATES PROJECT ^ : 661D PROJECT NAME : HASSAYAMPA CLIENT I.D. : REAGENT BLANK

717U7-VU73

ATI I.D. : DATE EXTRACTED ' DATE ANALYZED UNITS DILUTION FACTOR

806170 07/05/88

. 08/04/88 : UG/L : N/A

COMPOUNDS RESULTS

N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER

<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 <10 <10

f j ^ AnalyticolTechnologies, Inc

GCMS - RESULTS

REAGENT BLANK

TEST : SEMI-VOLATILE ORGANICS (EPA 625)

7777J~^7LB

ATI I . D . : 8 0 6 1 7 0

COMPOUNDS RESULTS

FLUORENE 4-NITROANILINE 4,6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE DIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-ETHYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE

<10 <50 <50 <10 <10 <10 <50 <10 <10 TR <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10


NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D5 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL (%)

80 74 110 51 79 52

7y'Z6' A>?a7'<7oa3

RIC DATA: BrSS ftl eSilM^SS 13:25:09 CALI: B705 #2 gAMPLE; REAGEHT BLANK 625 07/05/83 1800:IML CONOS.: .G£l " RANGE: G 1..2300 LABEL: N 8.. 4.0 QUAN: A 8,. 1.8

SCANS 1 TO 230PI

0 BASE: U 20.. 3

188.8n

RIC

59084::

>o o tf)

Q -^ z =) 00 O 00 U. N.

^ o CO

Q . . UJ H X < CO •-• Q Z UJ ^ I u. tn

t-*

< z o •-• I - UL

jJ L.L 500 8:20

J l i - ^ Ji- "n 1000 1G:4L

1500 25:00

2000 33:20

SCA T I M

PROCEDURE ÂTA FILE

FERENCE NAME LIST

REPORT

<-

PROC 2 2 2 2 2 2 2 2 1

TCA B705 B705

DIAGNOSTIC

Kl INITIALIZATION XI

STANDARDS USI ED POSS

2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 4 C

X RMS

0 0 0 0 0 0 0 0

> 0

OPTION:

PLUS PROC

11 9 9 9 12 12 11 10 7

REPORT

2

8/0


UNKNOWNS -USED

2 4 2 3 2 4 3 4 0

POSS 1 2

> RMS

0 45 0

79 0

77 80 82 0

< - LIST NAMES -STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6

8/04/88 14:34:2:


: COMPOUND X NO LIB ENTRY REF 1 SV 1 -415 2 SV 2 -600 3 SV 14 -256 4 SV 15 -398 5 SV 16 -382 6 SV 17 -393 7 SV 18 -396 8 SV 19 -408 9 SV 20 -417 10 SV 21 -451 11 SV 22 -442 12 SV 7 -397 13 SV 8 -263 14 SV 23 -480 15 SV 24 -471 16 SV 25 -503 17 SV 26 -493 18 SV 27 -485 19 SV 3 -864 20 SV 28 -503 21 SV 29 -541 22 SV 30 -550 23 SV 31 -575 24 SV 32 -613 25 SV 33 -584 26 SV 34 -595 27 SV 9 -500 28 SV 35 -596 29 SV 36 -602 30 SV 37 -628 31 SV 38 -636 32 SV 39 -713 33 SV 40 -707 34 SV 4 -1084 35 SV 41 -744 36 SV 42 -761 37 SV 43 -773 38 SV 44 -778 39 SV 45 -809

PRED 421 604 264 404 388 399 402 414 423 457 448 404 272 486 477 508 498 491 869 507 545 554 579 617 588 599 505 601 607 633 641 718 712 1089 749 766 778 783 814

- SEARCH X SAT X SEL DELTA PEAKS FIT PEAKS M/Z 421 ] 604 3

404 : 272

.

.

869

505

, ^ 1089

.

.

L 948 L 978 - i

2 997 1 963

1 993

1 941

1 976

152 L 136

42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117

2 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142

1 188 237 196 196 162 65

CHRO — TOP DELTA PEAKS 420 -1 1 604

404 272

478

869 505 544

505

606

1089

1

1 1

1

1 1 1

1

1

1

42 43 44 45 46 7

-rS 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 '3 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

48 -881 49 -868 50 -891 10 -772 11 -986 51 -940 52 -893 53 -853 54 -909 55 -956 56 -953 57 -945 58 -1337 5 -1486

59 -970 60 -975 61 -1025 62 -1039 63 -1074 64 -1087 65 -1093 66 -1205 67 -1266 6 -1692 12 -1337 68 -1763 69 -1297 70 -1427 71 -2007 72 -1483 73 -1527 74 -1489 75 -1616 76 -1643 77 -1643 78 -1683 79 -1886 80 -1898 81 -1942

886 873 896 776 776 991 992 ] 945 898 858 914 961 958 950 1344 1491 149 976 981 1030 1044 1079 1092 1098

1

1210 1211 1271 1699 1699 1342 1343 1770 1302 1433 2015 1489 1533 1533 1495 1616 1643 1643 1683 1886 1898 1942

t .

1 993 I 1 977

1 95 1

1 1 898 ,

1 966 1 1 987

, , , ,

. 1 913

.

. .

138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

776 992

961

1491

1092

1211

1699 1343

1533 1494

1 1

4

1

1

1

1 1

1 1

Quantitation Report File: B705

»:a: B705. TI x._./04/88 13:25:00 Sample: REAGENT BLANK 625 07/05/88 1000:IML Conds, : GC5 Formula: Instrument: 1050 Weight: 50,000 Submitted by: Analyst: RGM Acct. No. :

AMOUNT=AREA • REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

1, 4-DICHL0R0BENZENE-D4 (SVttl) NAPHTHALENE-D8 (SV#2) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SVttl5) ANILINE (SV#16) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1,3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SV#21) 1,2-DICHLOROBENZENE (SV#22) PHEN0L-D5 (SV#7) 2-FLUOROPHENOL (SV#8) 2-METHYLPHENOL (SV#23) BIS(2-CHLOROISOPROPYL)ETHER (SV#24) 4-METHYLPHENOL (SV#25) N-NITROSO-DI-N-PROPYLAMINE (SVtt26) HEXACHLOROETHANE (SV#27) ACENAPHTHENE-DIO (SV#3) NITROBENZENE (SV#28) ISOPHORONE (SV#29) 2-NITROPHENOL (SV#30) 2,4-DIMETHYLPHENOL (SV#31) BENZOIC ACID (SV#32) BIS(2-CHLOROETHOXY)METHANE (SV«33) 2,4-DICHLOROPHENOL (SV#34) NITR0BENZENE-D5 (SV#9) 1,2.4-TRICHLOROBENZENE (SV«35) NAPHTHALENE (SV«36) 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SVtt38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SV#40) PHENANTHRENE-DIO (SV#4) HEXACHLOROCYCLOPENTADIENE (SV#41) 2,4,6-TRICHLOROPHENOL (SV#42) 2,4,5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV#44) 2-NITROANILINE (SVtt45) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SV#47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SV«49) 2,4-DINITROPHENOL (SV#50) 2-FLUOROBIPHENYL (SVttlO) 2.4.6-TRIBROMOPHENOL (SV#11) 4-NITROPHENOL (SV«51)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 6 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name ISl IS2 61B 65A 5H IBB 24A 26B 27B 6H 25B SS2 SSI 2H 42B 4H 63B 12B IS3 56B 54B 57A 34A IH 43B 31A SS3 SB 55B 7H 52B 22A 9H IS4 53B 21A 4H 20B lOH 71B 77B IIH IB 59A SS4 SS5 58A

No Name 8 8H DIBENZOFURAN (SV#52)

-f9 35B 2.4-DINITROTOLUENE (SV#53) 50 36B 2,6-DINITROTOLUENE (SVtt54)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

m/i Scan 152 420 136 604 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 99 404 112 272 NOT FOUND 45 478

NOT FOUND NOT FOUND NOT FOUND 164 869 77 505 82 544

NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 82 505

NOT FOUND 128 606 NOT FOUND NOT FOUND NOT FOUND NOT FOUND 188 1089 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND 172 776 330 992 NOT FOUND NOT FOUND NOT FOUND NOT FOUND

Time 7: 00 10: 04

6: 44 4: 32

7: 58

14:29 8: 25 9: 04

8: 25

10:06

18: 09

12: 56 16: 32

Ref 1 2

1 1

1

19 2 2

2

2

34

19 19

RRT 1. 000 1. 000

0. 962 0. 648

1. 138

1, 000 0. 836 0. 901

0. 836

1. 003

1. 000

0. 893 1. 142

Meth A BD A BB

A BV A BB

A BB

A BB A BB A BB

A BB

A BB

A BD

A BD A BB

Area(Hgl 137231, 451345.

51259. 49542.

407.

258017. 426. 254.

98472.

381.

384567,

140799, 11836.

Amount TlTot 100. 000 NG/UL 12, 43 100. 000 NG/UL 12. 43

25. 396 NG/UL 3. 16 " - ^ 39. 605 NG/UL 4. 92 ' f\

0. 090 NG/UL 0. 01 -^ '

100. 000 NG/UL 12. 43 ' O, 134 NG/UL O. 02 -^ 0. 057 NG/UL 0. 01 -^

39. 858 NG/UL 4, 95 ^'^

0. 072 NG/UL 0. 01 ^

100. 000 NG/UL 12. 43

37.238 NG/UL 25. 922 NG/UL

4, 63 3, 22

S ^

Ouantitation Report File: B705

ta: B705. TI v/04/88 13: 25: 00

Sample: REAGENT BLANK 625 07/05/88 1000:IML Cond s. : GC5 Formula: Instrument: 1050 Weight: 50.000 Submitted by: Analyst: RGM Acct. No.:

AM0UNT=AREA » REF AMNT/(REF AREA » RESP FACT) Resp, fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 )6 67 68 69 70 71 72 73 74 75 76 77 7B 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63

Name 70B 40B SOB 12H IS5 60A 62B 41B 9B 64A 81B 78B 68B 39B IS6 SS6 5B 84B 67B 28B 72B 66B 76B 69B 74B 74B 73B 838 82B 79B

m/z 149 NOT NOT NOT 240 NOT NOT NOT NOT NOT 178 NOT 149

DIETHYL PHTHALATE (SVtt55) 4-CHLOROPHENYLPHENYL ETHER (SV#56) FLUORENE (SV#57) 4-NITROANILINE (SV#58) CHRYSENE-D12 (SV#5) 2-METHYL-4,6-DINITROPHENOL (SVtt59) N-NITROSODIPHENYLAMINE (SV#60) 4-BROMOPHENYLPHENYL ETHER (SV#61) HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SV#63) PHENANTHRENE (SVtt64) ANTHRACENE (SV«65) DI-N-BUTYL PHTHALATE (SV»66) FLUORANTHENE (SVtt67) PERYLENE-D12 (SV#6) TERPHENYL-D14 (SVttl2) BENZIDINE (SV#68) PYRENE (SV#69) BUTYL BENZYL PHTHALATE (SV#70) 3, 3'-DICHLOROBENZIDINE (SVtt71) BENZO(A)ANTHRACENE (SV#72) BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) CHRYSENE (SVtt74) DI-N-OCTYL PHTHALATE (SV#75) BENZO(B)FLUORANTHENE (SV#76) BENZO(K)FLUORANTHENE (SV#77) BENZO(A)PYRENE (SV#78) INDENOd, 2, 3-CD)PYRENE (SV<*79) DIBENZO(A.H)ANTHRACENE (SV#80) BENZO(G.H, DPERYLENE (SVttSl)

Scan Time Ref RRT Meth 961 16:01 19 1. 106 A BB

FOUND FOUND FOUND 1491 24: 51 55 1, 000 A DB

FOUND FOUND FOUND FOUND FOUND 1092 18:12 34 1.003 A BB

FOUND 1211 20: 11 34 1. 112 A BB

Area(Hght) 429.

212822,

591,

4173.

Amount 0, 165

100, 000

0. 142

1. 316

NG/UL

NG/UL

NG/UL

NG/UL

•/.Tot 0 02 <

12 43 •'

0. 02 " Jl

0, 16

No 4

J 5

66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/i NOT 264 244 NOT NOT NOT NOT NOT 149 228 NOT NOT NOT NOT NOT NOT NOT

Scan FOUND 1699 1343

FOUND FOUND FOUND FOUND FOUND 1533 1494

FOUND FOUND FOUND FOUND FOUND FOUND FOUND

Time

28: 19 22:23

25: 33 24: 54

Ref

65 55

55 55

1. 0.

1. 1.

RRT

000 901

028 002

Meth

A BB A BB

A BB A BB

Area(Hg

169916. 134423.

936, 2187,

XTot

100. 000 NG/UL 12. 43 .. ^ 55. 131 NG/UL 6, 85 ^

0, 841 NG/UL 0. 10

0. 997 NG/UL 0, 12 7.

£7^7/ ^ z s - yyi/y-'iuTb >h

Tict

DATA: 88M3B2647 «1 CALI: 88M3B2647 #2

SCANS 309 TO 2600

%0700 2-

7r)it7-517A i- cLof

RIC 08/10/88 22:37:00 SAHPLE: 50/80HG BNA STD CONDS.: IUL • ~ RANGE: G 1,2608 LABEL: N 0, 4.0 QUAN: A 8.. i.O J O BASE: U 20, 3

100.0-1

RIC

664576.

PI? 70 2009 33:20

2500 4l!'i0

qro»j

(antitation Report File: 88M3B2647

lta: 88M3B2647. TI J/lO/aS 22: 37: 00 imple: 50/80N0 BNA STD jnds. : IUL :andard ID: 2-BNA-7-1B •nsitivity ID: 2646

Instrument: 5100 Analyst: RJT Inst Cali:

lOur >sp. vJO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

aT=AREA fac.

NAME ISl IS2 I S3 IS4 ISS IS6 SS2 SSI SS3 SS4 SS5 5S6 61B 65A 5H 18B 24A 26B 27B 6H 25B 2H 42B 4H 63B 12B 56B 54D 57A 34A IH 43D 31A 8B 55B 7H 52B 22A 9H 53D 21A 4H 20D lOH 71B 77B IIH IB 59A 58A

• REF AMNT/(REF AREA * RESP FACT) from Library Entry

1, 4-DICHL0R0BENZENE-D4 (SV#1) NAPHTHALENE-D8 (SV#2) ACENAPHTHENE-DIO (SV#3) PHENANTHRENE-DIO (SV#4) CHRYSENE-D12 (SV»5) PERYLENE-D12 (SV#6) PHEN0L-D5 (SV«7) 2-FLUOROPHENOL (SV#8) NITR0BENZENE-D5 (SV#9) 2-FLUORODIPHENYL (SV#10) 2,4,6-TRIBROMOPHENOL (SV*11) TERPHENYL-D14 (SV«12) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SV#15) ANILINE (SV«16) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1.3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV«20) BENZYL ALCOHOL (SV#21) 1,2-DICHLOROBENZENE (SV#22) 2-METHYLPHENQL (SV#23) BIS(2-CHLOROISOPROPYL)ETHER (SV#24) 4-METHYLPHENOL (SV«25) N-NITROSO-DI-N-PROPYLAMINE (SV*»26) HEXACHLOROETHANE (SV«27) NITROBENZENE (SV#28) ISOPHORONE (SV«29) 2-NITROPHENOL (SV#30) 2,4-DIMETHYLPHENOL (SV#31) DENZOIC ACID (SV«32) DIS(2-CHLOROETHOXY)METHANE (SV#33) 2, 4-DICHLOROPHENOL (SV#34) 1, 2, 4-TRICHLORODENZENE (SV#35) NAPHTHALENE (SV#36) 4-CHLOROANILINE (SV*37) HEXACHLORODUTADIENE (SV«38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SV«40) HEXACHLOROCYCLOPENTADIENE (SV#41) 2, 4, 6-TRICHLOROPHENOL (SV#42) 2,4, 5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV»44) 2-NITROANILINE (SV#45) DIMETHYL PHTHALATE (SV»46) ACENAPHTHYLENE (SV«47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SV#49) 2,4-DINITROPHENOL <SV«50) 4-NITROPHENOL (SV#51)

m/z 152 136 164 188 240 264 99 112 82 172 330 244 42 94 93 93 128 146 146 108 146 108 45

108 70 117 77 82 139 122 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 184 139

Scan 673 894 121? 1494 1998 2247 640 483 773 1102 1369 1809 283 642 630 645 646 666 676 710 706 739 738 765 762 758 777 822 833 855 898 870 878 890 898 924 938 1017 1025 1070 1086 1093 1112 1144 1192 1189 1144 1225 1241 1268

Time 11: 13 14: 54 20: 19 24: 54 33: 18 37: 27 10: 40 8:03

12: 53 18:22 22: 49 30: 09 4: 43 10:42 10:30 10: 45 10: 46 11:06 11: 16 11: 50 11: 46 12: 19 12: 18 12: 45 12: 42 12:38 12: 57 13: 42 13: 53 14: 15 14: 58 14:30 14:38 14: 50 14: 58 15:24 15:38 16: 57 17:05 17: 50 18: 06 18: 13 18:32 19:04 19: 52 19: 49 19:04 20:25 20:41 21:08

Ref 1 2 3 4 5 6 1 1 2 3 3 5

2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3

RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 0. 718 0. 865 0. 904 1. 123 0. 905 0. 421 0. 954 0. 936 0. 958 0. 960 0. 990 1. 004 1. 055 1. 049 1. 098 1. 097 1. 137 1. 132 1. 126 0. 869 0. 919 0. 932 0. 956 1. 004 0. 973 0. 982 0. 996 1. 004 1. 034 1. 049 1. 138 1. 147 0. 878 0. 891 0. 897 0. 912 0. 938 0. 978 0. 975 0. 938 1. 005 1. 018 1. 040

Meth A BB A BB A QQ A BV A QB A QQ A QB A QB A BQ A QQ A BB A QQ A QB A QB A BV A VB A QQ A QV A VB A QQ A QQ A BQ A QQ A QQ A QV A BB A VB A QV A QB A QB A QB A QV A QB A QB A QB A QB A QB A QB A VB A QB M XX A VB A DB A BB A QB A QD A OD A QD A DV A QD

Area<Hght) 88930.

358628. 211617. 348336. 241414. 89276. 121189, 68867. 156647. 193838. 41664.

223608. 36965. 164279. 69024. 175485. 120928. 139112. 143100. 54354. 129571. 110225. 259727. 114623. 125053. 72413. 195978. 325249. 59453. 94943. 78072. 197554. 97228. 115975. 370777. 40973. 72955. 127863. 237298. 45634. 64988. 97634.

221915. 90388.

269398. 297278. 64289.

246542. 38206. 53321.

Amount 40. 000 40. 000 40.000 40. 000 40. 000 40. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50.000 50. 000 50. 000 50. 000 50, 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50, 000 50. 000 50. 000 50. 000 50. 000 50. 000 80. 000 50. 000 50. 000 50.000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 80. 000 50. 000 80.000 50. 000 50. 000 80. 000 50. 000 80, 000 80, 000

NG/UL NG/UL NO/UL NG/UL NO/UL NO/UL NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NO/UL NG/UL NO/UL

7.T 0. 0. 0. 0. 0. 0.

ot 87 87 87 87 87 87 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 08 73 08 08 08 08 08 08 08 08 08 08 73 08 73 08 08 73 08 . 73 . 73

Mo 1 2 3 4 5 6 7 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Ret(L) 11: 13 14: 54 20: 19 24: 54 33: 18 37:27 10: 40 8:03 12: 53 18:22 22: 49 30:09 4:43 10:42 10:30 10:45 10:46 11:06 11: 16 11: 50 11:46 12: 19 12: 18 12:45 12:42 12:38 12: 57 13:42 13:53 14: 15 14: 58 14:30 14:38 14:50 14: 58 15:24 15:38 16: 57 17:05 17: 50 18:06 18: 13 18:32 19:04 19: 52 19:49 19:04 20:25 20:41 21:08

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1.00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1.00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 0. 718 0. 865 0. 904 1. 123 0. 905 0. 421 0. 954 0. 936 0. 958 0. 960 0. 990 1. 004 1. 055 1. 049 1. 098 1. 097 1. 137 1. 132 1. 126 0. 869 0,919 0. 932 0. 956 1. 004 0. 973 0. 982 0. 996 1. 004 1. 034 1. 049 1, 138 1. 147 0. 878 0. 891 0. 897 0. 912 0. 938 0. 978 0. 975 0. 938 1. 005 1. 018 1. 040

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1, 00 1. 00 1. 00 1. 00 1, 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00

Amnt 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50.00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 80. 00 50. 00 50. 00 80. 00 50. 00 80. 00 80. 00

Amnt(L) 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50, 00 80, 00 50. 00 80. 00 50. 00 50. 00 80. 00 50. 00 80. 00 80. 00

R. Fac R 1. 000 1.000 1.000 1.000 1. 000 1. 000 1. 090 0. 620 0.349 0. 733 0. 158 0. 741 0,333 1. 478 0.621 1. 579 1. 088 1. 251 1,287 0, 489 1, 166 0.992 2. 336 1. 031 1. 125 0. 651 0. 437 0. 726 0. 133 0. 212 0. 109 0. 441 0. 217 0. 259 0. 827 0. 091 0. 163 0. 285 0. 529 0, 173 0,246 0,231 0,839 0,214 1.018 1, 124 0, 152 0.932 0. 090 0. 126

Fac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 090 0. 620 0. 349 0. 733 0. 158 0. 741 0. 333 1. 478 0. 621 1. 579 1. 088 1. 251 1, 287 0, 489 1, 166 0. 992 2. 336 1. 031 1. 125 0. 651 0. 437 0. 726 0. 133 0. 212 0. 109 0. 441 0. 217 0. 259 0. 827 0.091 0. 163 0. 285 0, 529 0. 173 0, 246 0. 231 0, 839 0,214 1.018 1, 124 0, 152 0. 932 0. 090 0. 126

Ratio 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1,00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1, 00 1. 00 1.00 1,00 1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 1,00 1. 00 1. 00 1, 00 1, 00 1. 00 1. 00 1,00 1. 00

uantitation Report File: 88M3D2647

ata: 88M3D2647. TI 8/10/88 22:37: 00 ample: 50/80NG QNA STD onds. : IUL tandard ID: 2-BNA-7-1D ensitivity ID: 2646

Instrument: 5100 Analyst: RJT Inst Cali

.MOUNT=AREA » REF AMNT/( esp. NO 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69

, fac. NAME 8H 35D 36D 70D 40D SOD 12H 60A 62D 41D 9B 64A 81B 78B 68B 39B 5B 84B 67B 28D 72D 66D 76D 69D 74D 74D 73D 83D 82D 79B

m/z 168 89 165 149 204 166 138 198 169 248 284 266 178 178 149 202 NOT 202 149

from Library

DIBENZOFURAN

REF 1 Er

• AREA ^ itry

(SV#52)

'r RESP FACT)

2, 4-DINITRGTOLUENE (SV#53) 2,6-DINITROTOLUENE (SV#54) DIETHYL PHTHALATE (SV«55) 4-CHLOROPHENYLPHENYL ETHER (SV#56) FLUORENE (SV«57] 4-NITROANILINE < 2-METHYL-4.6-

1

;SV#58) -DINITROPHENOL (SV#59)

N-NITROSODIPHENYLAMINE (SV#60) 4-BROMOPHENYLPHENYL ETHER HEXACHLOROBENZENE (SV«62) PENTACHLOROPHENOL (SV«63) PHENANTHRENE (SV«64) ANTHRACENE (SV#65) DI-N-

(SV#61)

-DUTYL PHTHALATE (SV»66) FLUORANTHENE (SV«67) BENZIDINE (SV#68) PYRENE (SV#69) DUTYL DENZYL 3,3'-

PHTHALATE -DICHLORQDENZIDINE

(SV«70) (SV#71)

DENZO(A)ANTHRACENE (SV#72 !) DIS(2-ETHYLHEXYL)PHTHALATE (SV#73) CHRYSENE (SV#74) DI-N--OCTYL PHTHALATE (SV#75) BENZO(B)FLUORANTHENE (SV«76) BENZO(K)FLUORANTHENE (SV«77) DENZO(A)PYRENE ' INDEN0(1,2, 3-

(SV#78) -CD)PYRENE

DIBENZO(A, H)ANTHRACENE (SV#79) (SV#80)

DENZO(G,H, DPERYLENE (SV#ei)

Scan 1256 1271 1200 1328 1328 1320 1346 1346 1353 1418 1439 1477 1498 1506 1639 1723

FOUND 1763 1919

Time Ref 20: 56 21: 11 20:00 22:08 22:08 22:00 22:26 22:26 22:33 23:38 23: 59 24:37 24: 58 25:06 27: 19 28: 43

29:23 31: 59

3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4

5 5

RRT 1.030 1.043 0,984 1, 089 1.089 1. 083 1. 104 0.901 0. 906 0, 949 0,963 0. 989 1. 003 1. 008 1, 097 1. 153

0. 882 0. 960

Meth A A A A A A A A A A A A A A A A

A A

DD DD DB DV DD DV DD DD DD DD DD DD DV VB QV QV

QB QB

AreaCHght) 342028, 77272, 58555.

296901. 124904. 253497. 14108, 59753. 75222. 79254. 115498. 75228.

360211. 362624. 364579. 351359.

355765, 98593.

Amc 50. 50. 50, 50, 50, 50, 80, 80, 50, 50, 50. 80, 50, 50. 50. 50.

50. 50.

lunt 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000

000 000

NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL

NG/UL NG/UL

XTot 08 08 08 08 08 08 73 73 08 08 08 73 08 08 08 08

08 08

73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

228 149 252 252 252 276 278 276

2002 2152 2187 2191 2238 2445 2451 2499

Jt, we,

33:22 35: 52 36:27 36:31 37: 18 40: 45 40: 51 41:39

5 6 6 6 6 6 6 6

1. 002 0. 958 0. 973 0. 975 0. 996 1, 088 1. 091 1. 112

Ret(L) 20: 56 21: 11 20:00 22: 08 22:08 22:00 22: 26 22: 26 22: 33 23 23 24 24

38 59 37 58

25:06 27: 19 28: 43 29:25 29:23 31: 59 31 33 34

59 14 02

33:22 35: 52 36: 36:

27 31

37: 18 40: 45 40: 51 41:39

Ratio . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 . 00 .00 . 00 . 00 . 00

. 00

. 00

. 00

.00

.00

. 00

. 00

. 00

. 00

. 00

. 00

.00

. 00

0. 0.

RRT(L) 1. 030 1. 043 0. 984 1. 089 1. 089 1. 083 1. 104 901 906

0. 949 0. 963 0. 989 1. 003 1, 008 1. 097 1. 153 0. 883 0. 882 0. 960 0. 960 0. 998 1. 022 1. 002 958 973

0. 975 0, 996 1. 088 1. 091 1. 112

0. 0.

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00

A A A A A A A A

VQ QD BV VB QB BV QD QD

Amnt 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 80. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00

i. ^ 1. J O T .

245065. 212601. 197973. 189083. 157507. 125364. 122998. 123093.

Amnt(L) 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 80. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

»^W. v ^ w w i^N»/ w u .

50. 000 50. 000 50. 000 50. 000 50, 000 SO. 000 50. 000 SO. 000

R. Fac 1. 293 0. 292 0. 221 1. 122 0. 472 0. 958 0. 033 0. 086 0. 173 0. 182 0. 265 0. 108 0. 827 0, 833 0. 837 0, 807

R.

179 327 016 791 502 812 905 774 694

1. 411 1. 123 1. 102 1. 103

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

Fac<L) 1. 293 0. 292 0. 221 1. 122 0. 472 0. 958 0. 033 0. 086

173 182 265 108

0.827 0. 833 0. 837 0. 807

1. 179 0. 327 0. 016 0. 791 0. 502 0.812 1. 905 774 694 411 123 102 103

0. 0. 0. 0.

08 08

,,08 08 08 08 08 08

Ratio 00 00 00 00

. 00

. 00 , 00 , 00 , 00 . 00 , 00 , 00 , 00 , 00 . 00 . 00

, 00 ,, 00 00

..00

..00

.. 00

., 00

., 00 ,. 00 ., 00 00 00 00

CONTINUING CALIDRATION CHECK - SEMIVOLATILE HSL COMPOUNDS ( PAGE 1 )

CASE NO: 7287 LADORATORY ID: ATI CONTRACT NO: -INSTRUMENT ID: 5100 SENSITIVITY ID: 2646

STANDARD DATE: 08/10/88 TIME: 22:37:00 STANDARD ID: 88M3D2647 CALIDRATION DATE: 06/21/88

* MAXIMUM 7.D FOR CCC IS 257. ** MINIMUM AVE RRF FOR SPCC IS 0. 05

COMPOUND AVE RRF RFSO 7.D

N-NITROSODIMETHYLAMINE (SV»14 PHENOL (SV*15) ANILINE (SV«16) DIS(2-CHLOROETHYL)ETHER (SV#1 2-CHLOROPHENOL (SV«18> 1, 3-DICHLORODENZENE (SV»19) 1,4-DICHLORODENZENE (SV«20) DENZYL ALCOHOL (SV#21) 1,2-DICHLORODENZENE (SV#22) 2-METHYLPHENOL (SV*»23) DIS(2-CHL0R0IS0PR0PYL)ETHER ( 4-METHYLPHENOL (SV#25> N-NITROSO-DI-N-PROPYLAMINE (S HEXACHLOROETHANE (SV#27) NITRQDENZENE (SV#28) ISOPHORONE (SV»29) 2-NITROPHENOL (SV#30) 2, 4-DIMETHYLPHENOL (SV#31) DENZOIC ACID (SV«32) DIS(2-CHL0R0ETH0XY)METHANE (S 2,4-DICHLOROPHENOL (SV«34) 1,2,4-TRICHLORODENZENE (SV#35 NAPHTHALENE (SV«36) 4-CHLOROANILINE (SV#37) HEXACHLORODUTADIENE (SV#38> 4-CHL0R0-3-METHYLPHEN0L (SV»3 2-METHYLNAPHTHALENE (SV#40) HEXACHLOROCYCLOPENTADIENE (SV

0. 519 1. 557 1. 126 1. 752 1. 160 1. 419 1, 547 672 438 147

2. 476 1. 097 1. 199 689 460 762 143 266 088 514 228 321

1. 014 0. 152 0. 215 0. 369 0. 901 0. 152

0. 1. 1.

0. 0. 0. 0. 0. 0. 0. 0. 0.

0. 333 1. 478 0. 621 1. 579 1. 088 1. 251 1. 287 0. 489

166 992 336 031 125 651 437 726

0. 133 0. 212 Q-06S*,<o1 0. 441 0. 217 0. 259 0. 827 0. 091 0. 163 0. 285 0. 529 0. 173

1. 0. 2. 1. 1. 0. 0. 0.

36 5 •

45 10 6 12 17 • 27 19 14 6 6 6 * * 6 5 5 7 •

20 23 14 5 » 19 18 40 24 * 23 * 41 -13 *•»

AVE RRF - AVERAGE RESPONSE FACTOR FROM INITIAL CALIDRATION RF - RESPONSE FACTOR FROM DAILY CALIDRATION 7.D - PERCENT DIFFERENCE ••» - SPCC - SYSTEM PERFORMANCE CHECK COMPOUNDS • - CCC - CALIDRATION CHECK COMPOUNDS

CONTINUING CALIBRATION CHECK - SEMIVOLATILE HSL COMPOUNDS ( PAGE 2 )

CASE NO: 7287 LADORATORY ID: ATI CONTRACT NO: -INSTRUMENT ID: 5100 SENSITIVITY ID: 2646

STANDARD DATE: 08/10/88 TIME: 22:37:00 STANDARD ID: S8M3D2647 CALIDRATION DATE: 06/21/88

» MAXIMUM 7.D FOR CCC IS 257. *•» MINIMUM AVE RRF FOR SPCC IS 0. 05

COMPOUND

2,4,6-TRICHLOROPHENOL (SV#42) 2,4.5-TRICHLOROPHENOL (SV#43) 2-CHLORaNAPHTHALENE (SV#44) 2-NITROANILINE (SV#45) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SV»47) 3-NITROANILINE (SV#4a) ACENAPHTHENE (SV#49) 2,4-DINITROPHENOL (SV#50) 4-NITROPHENOL (SV#51) DIDENZOFURAN (SV#52) 2, 4-DINITROTOLUENE (SV#53) 2,6-DINITROTOLUENE (SV#54) DIETHYL PHTHALATE (SV#55) 4-CHLORaPHENYLPHENYL ETHER (S FLUORENE (SV#57) 4-NITROANILINE (SV#58) 2-METHYL-4.6-DINITROPHENOL (S N-NITROSODIPHENYLAMINE (SV#60 4-BROMOPHENYLPHENYL ETHER (SV HEXACHLOROBENZENE (SV#62) PENTACHLOROPHENOL (SV»63) PHENANTHRENE (SV#64) ANTHRACENE (SV#65> DI-N-DUTYL PHTHALATE (SV#66) FLUORANTHENE (SV#67) DENZIOINE (SV#68) PYRENE (SV#69) DUTYL DENZYL PHTHALATE (SV#70 3. 3'-DICHLaR0DENZIDINE (SV#71 DENZO(A)ANTHRACENE (SV#72) DIS(2-ETHYLHEXYL)PHTHALATE (S CHRYSENE (SV«74) DI-N-OCTYL PHTHALATE (SV#75) DENZQ(D)FLUORANTHENE (SV#76) DENZO(K)FLUORANTHENE (SV#77) DENZO(A)PYRENE (SV#78) INDENO(1,2. 3-CD)PYRENE (SV#79 DIDENZO(A,H)ANTHRACENE (SV#80 DENZO(G. H, DPERYLENE (SV#81)

AVE RRF

0. 302 0. 328 1. 005 0. 495 1. 276 1. 518 0. 322 1. 086 0. 106 0. 174 1. 486 0. 358 0. 229 1. 327 0. 536 1. 182 0. 040 0. 097 0. 343 0. 210 0. 298 0. 122 0. 928 0. 917 1. 184 1. 003 0. 020 1. 738 0. 765 0. 143 1. 101 1.087 0. 995 1. 745 1. 360 1. 456 1. 132 1. 178 0. 869 0. 927

RFSO

0. 246 Q -lr4ir,

0. 839 iL-teO • 1. 1. 018 124

Q J i 9 e . 0. 932 Q-J&e^ . Q^ jy ;^ . 1. 0. 0. 1. 0. 0.

293 292 221 122 472 958

g,jG20 . CL-GSa-, 0. 0. 0.

173 182 265

J>-0S7-0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0.

827 833 837 807 000 179 327 016 791 502 812 905 774 694 411 123 102 103

,m\ .2,lM

,(32.

O0|O

, I7 .C

o33 .o86>

lo'3

7.D

19 • »

•56'o

17 73-3"? 20 26 ^ S 3 14 -*7 55 13 18 4 15 12 19 48 4 5 50 13 11

*• I S ** Zt

l i II

*

-^•//*

11 9

29 20 100 32 57 89 28 54 18 -8

-29 -15 -24

5 -26 -18

*

•»

*

AVERAGE 7.D FOR CCC IS: 15. 2

AVE RRF - AVERAGE RESPONSE FACTOR FROM INITIAL CALIDRATION RF - RESPONSE FACTOR FROM DAILY CALIBRATION 7.D - PERCENT DIFFERENCE * * - SPCC - SYSTEM PERFORMANCE CHECK COMPOUNDS

7r)uJ-'7uB

/j.iS^ AnolyticalTechnologies, Inc

QUALITY CONTROL DATA ATI I.D.

TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) 806170

CLIENT PROJECT # PROJECT NAME

MONTGOMERY & ASSOCIATES 661D HASSAYAMPA

REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS

80617001 07/14/88-AQUEOUS UG/L

COMPOUNDS

DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT

ND ND ND ND ND ND

2.0 2.0 2.0 2.0 2.0 2.0

2.18 2.02 1.96 1.77 2.99 2.40

109 101 98 89 150 120

1.90 1.74 1.71 1.57 2.36 2.11

95 87 86 79 118 106

14 15 14 12 24 13

% Recovery = (Spike Sample Result - Sample Result)

Spike Concentration X 100

RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result

Average of SpikecJ Sample X 100

-MS ANALYZED ON 7/13/88

HART SPEED 0.6 CM/MIN TTEN: 16 ZERO: 10$ 1 MIN/TICK

rTAT" INJECT

0 . 922

^ ^ y ? ? 2

5 R ; O F

-A BHf

"INDAN

4 . 570

5 , 5 4 4

6 , 968 7 , 126 7 , 955

9 , 0 2 6 9 , 668

1 0 . 4 7 9

1 1 , 700-) -BH^r72 . 425

= : 1 3 , 6 B 3 ^RI/

1 5 . 4 8 4 :ND©-r 1 5 , 9 8 9

)DE -S2SL

:NDR-I-N-JDD —f 1 8 , 6 9 2

—'-4-9-H^-8

INDOSO^r" 2 0 , 177

;ND Kf- fot^^"

2 3 , 3 4 8

2 4 , 5 9 1

2 5 . 7 6 5

2 2 . 7 0 5

ATTEN: 32 ZERO: 5% 1 MIN/TICK X

~ S R : 0

= " 1 0 , 9 8 8 '

^ 1 4 , 5 4 3

c 991

=• 1 7 , 0 6 6 "

" 1 8 , 2 4 1

" 1 9 , 6 0 9 . r

" 1 2 , 9 7 6

1 4 , 9 9 6

}}?7JA777B

TLE: PESTICIDES

lANNEL N O : 2

AK PFAk' o r c i i i T

kOO/-'7o - / ^ s SAMPLE: 15

23:46 13 JUL 88

METHOD: DB608

/v n r- A.

i ' U O \.' o

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 •^5

5 ^7 38

PEAK NAME .

A BHC

LINDANE

HEPTACHLO D-BHC

ALDRIN

ISODRIN

ENDO I DIELDRIN

ENDRIN DDD ENDO I I DDT ENDRIN AL

ENDO S04

METHOXY END KETON

rOTALS:

RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0,0000 0,0000 0,0000 0,0000 0.0000 0.0104 0 , 0000 0.3036 0 , 0000

.^^^2364 ' 0.0057 0,0000 0.2478 0.0000 0,0000

115.3000 0.0000 0.0000 0,0061 0,2401 0. 0002) 0.35/8 0,0160 0,0078 0,2324 0.0376 0.0000 0,0066 0.0000 0,0000 0,0000 0,0200 0,0502 0,0000

117,0740

TIME CMIN) 6.036 6. 168 6.543 6, 968 7, 126 7, 754 7,955 6.345 9.026 9.668 10.479 10.988 1 1 .700 12,033 127>?5 12,774 13,104 13,683 14,048 14,543 15,484 15,989 16,151 17,066 17,829 18,241 18,692 19,018 19,609 19,907 20.177 20.657 20,977 21,335 21,985 22,231 22,705 25,765

TIME OFFSET

-0,062

-0,072

-0,067 -0,115

-0.076

-0.117

-0,009 -0,084

-0,079 -0.058 0, 098

-0,081 -0,083

0,287

-0,249 -0,085

-0,852

AREA COUNTS 22901 1 1896 30575 14 195 25889 20500 19995 22698 24291 19970 41783

562247 9644

38885^ "" •10?24

9177 450572

8144 8415

407420 18768 13330 8912

353077 7355

168479 18860 1051 1

242097 49479 42404 9997 9140 1 1045 4880 4619

75987 1459

3160070

SEP CODE VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv BB

?

?

9 ? ? ? ?

? ? ? ? ? ? ? ? ?

? ? ? ?

? ? '> o ? ?

'>

Wl/2 (SEC) 6,40

16,40 6, 40

17. 15

7, 20 10,60 18.30 6, 60 6,40 7,65

10.50 5,30

6,60 5.40 15.70 18,05

8,25 14,00 5,40 16,70

7,80 11,30 23. 15

8,70 9.95 8,85

38,30

lETECTED P K S : 64 REJECTED P K S : 26

i l V I S O R : 1 , 0 0 0 0 0 M U L T I P L I E R : 1 , 0 0 0 0 0

I O I S E : 8 , 5 OFFSET : 5

ACK: 16 V I A L : 7 I N J : 1

RRORS: COL TEMP

OTES: DB608 PRIMARY COLUMN

3^f i-bT-

Z: PESTICIDE CONFIRMATORY

HANNEL NO: 1 SAMPLE: SAME

23:46 13 JUL 88

METHOD: DBS

ZAK 10 1 2

PEAK NAME

LINDANE

RESULT UG/ML 15.3799 0,4552

TIME CMIN)

10,660 11,320

TIME OFFSET

0,080

AREA COUNTS 341613 101 10

SEP CODE BB BB

Wl/2 CSEC) 8,85

? A. 70 1/1 OQ-7C

ITLE: PESTICIDE CONFIRMATORY

HA' "L NO: 1 SAMPLE: SAME

EAK PEAK NO NAME

1 2 LINDANE 3 4 ALDRIN 5 /t. n I Cl n o T Kl

7 ENDRIN 8 DDD 9 ENDO S04 10

OTALS:

RESULT UG/ML 15,3799 0.4552 14,9975 14,7364 13,4487 \ -Z> O T ,i -7

9,0158 2,9793 11,9047 4,1463

100,0000

TIME CMIN)

10,660 1 1 ,320 12.976 14,088 14,996 1-7 T 7 c-

17,907 18.743 19.519 20.880

23:

METHOD

TIME OFFSET

0. 080

-0.212

/ ^ '-!/% C-

\^ • u- \y •. -

0. 077 -0.017 0. 209

0.342

46 13

: DB5

AREA COUNTS 341613 10110

333119 327320 298718 - i C i - ) - ! - ! t.

200255 66176

264422 92096

2221170

JUL 88

SEP CODE BB

Wl/2 CSEC) 8.85

BB ? 6.70 BB BB BB BV VB BB BB BB

9.65 9. 90 9.90 o not

9, 15 8, 90 10, 00 8.70

REJECTED PKS; ETECTED PKS: 25

ULTIPLIER: 1.00000

OISE: 71,6 OFFSET: -1

ACK: 16 VIAL: 7 INJ: 1

OTES: DBS CONFIRMATORY COLUMN

15

HART SPEED 0 , 6 CM/MIN T T E N : 16 Z E R O : \<b% 1 MIN/TICK

STAT-T

SR:OFF

_A BffiJ 9 , 6 2 6

0 . 441 CINDA A SLE

r 4 g ? 1 2 . 3 9 8

1 5 , 4 2 9 ENDe-/I 1 5 , 9 5 5

IfDE 1- 1 -7 -70:

0,912

ATTEN: 32 ZERO: 5J« 1 MIN/TICK

=• 10.952

" 14, 503

17.021

;HHRT SPEED 0,6 CM/MIN ^TTEN: 16 ZERO: 10% 1 MIN/TICK ATTEN: 32 ZERO: S% 1 MIN/TICK

T" AT

SR:0FF

_A Bffi' 9,626 —^ 10.441

riNDAh )ANP = ^ 1 1 , 673-

D - B l d g f l 2 , 3 9 8

^=:( 1 5 . 4 2 9 "ENDe—/I 1 5 , 9 5 5

"DDE — ^ — 1 7 , 7.S 92^

J ==f 1 8 , 6 5 2

0 , 9 1 2 4 0 1

S R : 0 / F F

•ENDR-

— ^ = } _ 2 1 , 9 5 2 .EN D^JIE-T-ON

J 2 4 . 6 8 5

2 5 . 8 0 1

1 0 . 9 5 2 "

5 , 8 3 3

="14, 503 77

1 2 , 9 2 8

1 4 , 0 3 8

1 4 , 9 4 1

=" 1 7 , 0 2 1 "

~ 18, 195 ' CZ

1 9 , 8 5 9

2 2 , 6 5 9

ITLE: PESTICIDES

H' 'NEL NO: 2

EAK NO

1 2 3 4 5 A.

PEAK NAME

LINDANE

HEPTACHLO n-nur

Tr/ui-îAB

y^^j_79zz7y/99 SAMPLE: 16

RESULT UG/ML 0,0000 0. 0000 0.2647 0.0000 0.2042

10 10 11 11

TIME CMIN) 7.725

441 952 673 998

0:21 14 JUL 88

METHOD: DB608

1 1 T O O

TIME OFFSET

-0.108

-0,102

AREA COUNTS

2126 3 168

490112 2866

335925

SEP CODE BB BV VV VV VV

Wl/2 CSEC) 8,20 7, 6, 10, 4,

60 55 00 85

"IT -•: PESTICIDES

CHANNEL NO: 2

= EAK NO

1 2 3 4 5 6 7 8 9 10 : 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25

PEAK NAME

LINDANE

HEPTACHLO D-BHC

ALDRIN ISODRIN

ENDO I DDE

ENDRIN

DDD ENDO I I

DDT ENDRIN AL

ENDO S04 •

METHOXY END KETON

TOTALS:

yoC/70

SAMPLE:

RESULT UG/ML 0,0000 0,0000 0.2647 0,0000 0,2042 0,0008 0,0000 0,2160

94,1281 0,0000 0,0006 0.2186 0.0000 0,2790 0,0000 0,0019 0.0024 0,0000 0,2042 0,0364 0 , 0000 0,0007 0 , 0000 0,0057 0,0482 0, 0000

95,6115

- / n7S/>

16

TIME CMIN) 7,725 10.441 10.952 1 1 ,673 1 1 ,998 12,398 12,737 13,067 14,503 15,429 15,955 17,021 17.793 18,195 18,652 18,805 18,970 19,263 19,564 19,859 20,130 20,672 21,952 22.197 22,659 24,685

0:

METHOD

TIME OFFSET

-0,108

-0,102 -0,142

-0.113 -0.157

-0.205 0, 081

-0,125

0.055 0,050

-0.126 -0,131

0,302

-0,283 -0,131

-1,135

21 14

: DB608

AREA COUNTS

2126 3168

4901 12 2866

335925 1473 1226

392686 332608

4019 889

313691 1641

132849 5844 2228 3245 61 1

212739 47953 5177 1067 562 1309

73099 3562

2372670

JUL 88

SEP CODE BB BV VV VV VV VV VV VB VV VB BB BV VV VV VV VV VV VV VV VV VV VB BV VV VB BB

? ? ?

?

? ? ? ?

? ? ? 7

?

Wl/2 CSEC) 8,20 7,60 6,55

10, 00 4,85 14, 90 6, 55 8. 05 7, 65 7, 70 5,95 8,25 1 1 ,75 7,85 1 1 ,90

7,80 9, 80

5.10 6, 90 3,85 8,30

DETECTED PKS: 55 REJECTED PKS: 29

DIVISOR: 1,00000 MULTIPLIER: 1.00000

N O I S E : 8,5 OFFSET: 12

RACK: 16 VIAL: 8 INj: 1

NOTES:

DB608 PRIMARY COLUMN

TITLE: PESTICIDE CONFIRMATORY 0:21

CHANNEL NO: 1

PEAK

2 3 4 5 £

7

^ g

PEAK NAME

ALDRIN HEPT-EPOX DIELDRIN ENDRIN DDD ENDO S04

SAMPLE: SAME

RESULT UG/ML 15.7280

1 196 0453 2088 2538 S152 2041 9902 6346

15. 15, 13, 13, 8, 3, 10, 4,

TIME CMIN)

10.625 12, 14, 14, 17, 17, 18, 19, 20.

928 038 94 1 182 O /. /I

696 476 833

TIME OFFSET

-0,262 0,271 0, 152 n» r>t-r /\

-0,064 0, 166

1 14

DB5

AREA COUNTS 334081 321158 319580 280570 281526 1 o-ynco 4 -' 1 ^ t./ w

68058 233445 98444

JUL 88

SEP CODE BB BB BB BB BV N/D T W

BB BB BB

Wl/2 CSEC) 8,95 9.65 9,75 9. 95 9,90 9.35 9.25 9.85 9. 10

Page No. 08/17/88

A / A A AnalyticalTechnologies, Inc

ANALYTE

ORGANIC QUALITY CDNTROL REPORT

DATE OF ANALYSIS

I N I T . QC NAME

TyjLv- û77)

VALUE TRUE UNITS o FOUND VALUE *'

** ACCESSION NUMBER 806170 * METHOD 608 LINDANE ENDRIN DDT

07/13/88 TMG 07/13/88 TMG 07/13/88 TMG

GC381 GC381 GC3ai

1.95 1.16 1.74

2.00 2.00 2.00

UG/L UG/L UG/L

f? 5g a

V -y

(RT SPEED 0,6 CM/MIN •EN: 16 ZERO: 105« 1 MIN/TICK

INJECT

— 4,273

y } 5,550 ?: OFF

^ 7,858

DE=i; 16,906 17,313

20,729 21,052 21 . 731

IETHO>fY- 7? ?77 •ND KET-erN

24.636

25. 816

26,837

ATTEN: 32 ZERO;

0,924 1 ,525

5% 1 MIN/TICK

~5"R: OFF

10,6^'

" 14,565. ALDRIN 14,115

22,733

15.023

E N D I ^ W

y E N D O ^ & M —

1 7 , 9 4 3

1 9 , 5 5 3

7>770- lA7^

ITLE: PESTICIDES

h, ,NEL NO: 2

EAK PEAK NO NAME

1 2 LINDANE 3 4 ALDRIN

< ^ 1 GC 3S 1

SAMPLE:

RESULT UG/ML 0 . 0 0 0 0 0 . 2 7 1 3 0 . 0 0 0 0 0 . 0 0 2 4

4

T IME CMIN) 7 . 8 5 8

1 1 , 0 1 4 1 1 . 5 7 7 1 3 . 1 2 5

17:31 13 JUL 88

METHOD: DB608

TIME OFFSET

-0,046

-0,055

AREA . COUNTS

918 502469

1209 4413

SEP CODE BB BV VB BB

Wl/2 CSEC) 7,05 6.45

8.05

DBfi-Oe PSI MARY COLUMN

•ITLE: PESTICIDE CONFIRMATORY

;HANNEL NO: 1 SAMPLE: SAME

'EAK PEAK NO NAME

1 2 ALDRIN 3 4 ENDRIN 5 DDD 6 ENDO S04 7

rOTALS:

RESULT UG/ML

27,1439 0.7541

24,2273 9,6654 9,4092 17,9093 10.8908

100.0000

TIME CMIN)

10,699 14, 1 15 15,023 17,943 18,776 19,553 20,915

17:

METHOD

TIME OFFSET

-0,185

0, 1 13 0,016 0,243

0. 187

31 13

: DBS

AREA COUNTS 324408

9012 289551 1ISSIS 112453 214041 130161

1 195140

JUL 88

SEP CODE

Wl/2 CSEC)

BB ? 9, 10 BB BB BB BB BB BB

7. 15 9,80 8,70 10, 15 10,20 9,75

)ETECTED P K S : 10

• I U L T I ' P L I E R : 1 , 0 0 0 0 0

^ I O I S E : 5 8 , 3 OFFSET :

RACK: 16 V I A L : 9

REJECTED PKS;

0

INJ: 1

^ "S: JS CONFIRMATORY COLUMN

CHART SPEED 0,6 CM/MIN ATTEN: 16 ZERO: \(d% 1 MIN/TICK

~gTAT : INJECT

- 3}:ê^ 2, 937

4, 277 4,823

SR:OFF

BHf 9,682

, 1 0 . 8 6 7 B BHert 1 1 . 280

12.663

I'.ÎV .14.324

ATTEN: 32 ZERO: 5% 1 MIN/TICK

7[— 0,922

~SR:6FF

ITLE : PESTICIDES ,,_ , .

HANNEL N O : 2

EAK NO

1

2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25

PEAK NAME

LINDANE

ALDRIN ISODRIN DDE

DIELDRIN ENDRIN DDD

ENDO I I

DDT ENDRIN AL ENDO S04

METHOXY END KETON

OTALS:

<Ai_ ; G C

SAMPLE:

RESULT UG/ML 0.0000 0.2713 0.0000 0,0024

99,3347 0.0017 0.0000 0,0005 0.1367 0,0026 0,0000 0.0028 0.0000 0.0000 0.0000 0.1681 0.0731 0,0016 0,0000 0.0000 0.0000 0,0084 0,0734 0 , 0000 0.0000

100,0770

3 i 1 4

TIME CMIN) 7,858 11,014 1 1 ,577 13,125 14,565 16,906 17,038 17,313 18,269 18,733 18,777 18,847 19,086 19,167 19,272 19,635 19,935 20,729 20.769 20,908 21,052 22,277 22,733 25,816 26,837

17:

METHOD

TIME OFFSET

-0,046

-0,055 -0,095 -0,034

0. 163 -0,051 -0,017

-0,073

-0,055 -0,055 0.359

-0.203 -0,057

-0,219

31 13

: DB608

AREA COUNTS

918 502469

1209 4413

351006 2390 1528 716

65103 3062 1470 3736 924 994 988

175079 96229 2361 1 189 703 613 1939

1 1 1 144 799 871

1331850

JUL 88

SEP CODE BB BV VB BB BB BV VV VB BV VV VV VV VV VV VV VV VV VV VV VV VV BV VB BB BB

?

? ? ?

? ? ? ? ? ?

? ? ? ?

? ?

Wl/2 CSEC) 7,05 6,45

8,05 8, 00 8, 60

25.30

8,05 10, 80

8, 15 9,55 13,60

8, 40 8,30

28, 10 21 ,00

•ETECTED P K S : 3 2 REJECTED P K S :

) •SOR: 1 , 0 0 0 0 0 M U L T I P L I E R : 1 , 0 0 0 0 0

I O I S E : 8 , 5 OFFSET.: 17

> A C K : 16 V I A L : 9 I N J : 1

lOTES: DB608 PRIMARY COLUMN

riTLE: PESTICIDE

CHANNEL N O : 1

'EAK PEAK NO NAME

1 2 ALDRIN 3 4 ENDRIN 5 DDD 6 ENDO S04

rOTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML

27.1439 0,7541

24,2273 9.6654 9,4092 17.9093 10,8908

100.0000

SAME

TIME CMIN)

10,699 14, 115 15.023 17.943 18.776 19.553 20.915

17:

METHOD

TIME OFFSET

-0.185

0, 1 13 0,016 0.243

0, 187

31 13

: DBS

AREA COUNTS 324408

9012 289551 11SS15 112453 214041 130161

1195140

JUL 88

SEP CODE

Wl/2 CSEC)

BB ? 9.10 BB BB BB BB BB BB

7, 15 9,80 8,70

10, 15 10,20 9,75

DETECTED PKS: 10

M U L T I P L I E R : 1 , 0 0 0 0 0

REJECTED PKS;

9C-I 5rD

LOS

':>^hoi-c C O L L I ifiO he GO?, 7 l / J / i ^

..RAMETER ^ ' ^ ' ^

a -6//C dc-Hdo'^^^

B - one l / t ^ 7 a . c J u t - i ,

D Bflc OclAyU^

J/iôcLA*^*^ - S*njui-.

7/.cfi/t>.cAA^yc OfâpAiL

9-^7^ S^LtAjt^ JZ

" / j i / - c o e

' 7)A7IA'AA7^

• S f ^ C r 79lc7.Ci^*t.

\ 4< 7-7)7)0

1 SZi7.oS-.CAJ/a^ u

\ i / . i / . O D T

s/tcT/il^ ccTcTÂyyc

i S yuTos-iAA' ^ SC/</

7r7</7A^ cAAs^

(TyicllTn. /ACATM 1

'

1

i

1

i 1 1

I 1

1

1 1

1 1

;l .04,

I I . 3 ^

/ 2 . I 0

1 2 . 5 ^

\ i . \ l

,^./^c l £ . O H

IG.II^

((^.qq

17.1.?

' 6 . 3 2 .

( 8 . 7 5

/ 8 . 9 2

ii?4k' /9.S<1

2 0 . 3 ?

2 2 . V 8

2: i .79

-1 l o p t Y / O '

. o o 3 t 7

• DO i JlS-

, o /oV'^

. OOSI«J

, o o ^ t S

. OOC/i<o

i

. <r9'»

•/

1 «

* i

f t

1 f

fif : 2 . S I Go.Zpti^

. o o 5 o q

. 0 o i ' r O

. 0 0 7 0 /

• 0 0 5 0 0

. o / 7 7 f

• & 4 - ^ . £>/OQ,S

• 6 0 5 S 7

. 0 0 9 9 2

. C)0fc9Z

• OOCe^Z

• 0 3 1 0

. O O S 3 9

i

1

1 1

1 1

1 ! 1 t

1

1 ! '

1

i j

1

i

>)k7'i/(uQ

HART SPEED 0,6 CM/MIN TTEN: 16 ZERO: \ Z % 1 MIN/TICK

STAT" INJECT

v.m SR:OFF

ATTEN: 32 ZERO: 'SX 1 MIN/TICK

0.927 1 ,527

•^R:CfFF

DDE=i 17,050

ENDglN 18,275

11:11: 19.961

-DDD; "DDT-J^NDD^fe04 2 0 . 4 0 9 _ zzzj 2 1 , 4 8 1

21 , 9 0 1 - E N D - K £ T 0 N 2 2 , 6 3 2

24,605

25.788

26,976

TITLE

CHANN

F K

1 2 3 4 5 6 7 8 9 10

: PESTICIDES

IEL NO: 2

PEAK NAME

ENDRIN DDT ENDRIN AL ENDO S04

METHOXY

TOTALS:

l7i/)L & ICI^ /L . SA+ PtE-r-is

RESULT UG/ML 0,0036 0,0019 0,0024 0,0017 0,0000 0,0000 0,0000 0,0000 0,0036 0.0000

0,0132

TIME CMIN)

18,275 19,310 19,961 20,409 21 ,481 21 .616 21,901 22,154 22.632 26.976

18:

METHOD

TIME OFFSET -0,045 -0,380 -0,029 0, 039

0, 152

-0,263

40 13

: DB608

AREA COUNTS

1709 1937 31 15 2577 12476 2985 2162 2730 825 705

31221

JUL 88

SEP CODE BB VV VV VV VV VV VV VV VB BB

? ? ? ? ? ? ? ? ? ?

Wl/2 CSEC) 15.75 27.70 5, 00

26,80 16, 80

34. 10


DIVISOR: 1.00000 MULTIPLIER: 1,00000

NOISE: 8,5 OFFSET: 15

RACK: 16 VIAL: 13 INJ: 1

NOTES: DB608 PRIMARY COLUMN

TITLE: PESTICIDE CONFIRMATORY 18:40 13 JUL 88

CHANNEL NO: 1 SAMPLE: SAME METHOD: DBS

PEAK PEAK RESULT TIME TIME AREA SEP Wl/2 NO NAME UG/ML CMIN) OFFSET COUNTS CODE CSEC) TOTALS: 0,0000 0


MULTIPLIER: 1.00000

NOISE: 71,6 OFFSET: -7

RACK: 16 VIAL: 13 INJ: l

ERRORS: NO PEAKS

NOTES: DBS CONFIRMATORY COLUMN

CHART SPEED 0.6 CM/MIN ATTEN: 16 ZERO: \Z% 1 MIN/TICK ATTEN: 32 ZERO: 5% 1 MIN/TICK

STAT : i I N J E C T

S R : 0 F F

0 , 921 1 , 5 2 2

4 , 2 7 4

6 , 9 9 5

~5R

""CIND

OFF

^ . 1 ^ . .

ZP^ 1 1 , 0 0 0

9 , 6 6 7

D - B H C r ^ 1 2 . 4 7 6

^ l iP ! ^ | ^X=^^^^4 ,969 1 5 , 4 6 7

ENDO ( j - — " 1 6 , 0 9 3

1 8 . 8 5 5

1 2 , 9 9 4

1 4 , 1 0 2

__ =— 1 6 , 4 6 3 D I E J T D R T M 1 7 , 2 5 8

-ErNDlfcfcW 1 7 , 9 3 6 ^ 8 , 3 9 5

ENDa=Sn4 1 9 . 5 2 0

2 2 , 4 3 5

/ A __

y7?Ci7-v7^73

TITLE

CHANN

PEAK NO

1 2 3 4 5 6 7 8 9 10 11 1 n

: PESTICIDES

EL NO: 2

PEAK NAME

A BHC LINDANE B BHC HEPTACHLO D-BHC ALDRIN ISODRIN HEPT EPX

ENDO I nnr

0 , 2 0 ppfyx

SAMPLE:

RESULT UG/ML 0,0000 0.0283 0.0261 0,0093 0.0195 0.0205 0.0237 0.5170 0.0261 0.0000 0.0249 n /% t / i n ,

STD

7

TIME CMIN) 6,995 9,673 11,000 11,267 12.041 12,476 13.112 14.559 14.969 15.467 16.093 t ^ O-J-5

MET

TIME OFFSET

-0,057 -0,060 -0.053 -0,059 -0,064 -0.068 -0.101 -0.071

-0.067 /% /\ • ^

19:

HOD

14 13

: DB608

AREA COUNTS

634 54404 48291 15329 31997 37992 43074 1827

389 14 2277

36034

JUL 88

SEP CODE BB BB BV VB BV VV VB BV VV VV VB r . 1 .

Wl/2 CSEC) 5.90 6,75 7.00 6,60 7,80 6,60 7,95 10.05 7.75

? 7.35 7.85

- — —

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24

•. i . _ , , . . • . . ^

PEAK NAME

A BHC LINDANE B BHC HEPTACHLO D-BHC ALDRIN ISODRIN HEPT EPX

ENDO I DDE DIELDRIN ENDRIN ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

TOTALS:

^rii 1,- l_c •

RESULT UG/ML 0.0000 0,0283 0.0261 0.0093 0.019S 0.0205 0.0237 0.5170 0.0261 0.0000 0.0249 0,0140 0,0262 0,0161 0,0360 0,0155 0.0201 0.0201 0.0000 0.0000 0.0000 0.0000 0.1965 0.0236

1.0635

1'

TIME CMIN) 6.995 9,673

1 1 ,000 1 1 .267 12,041 12,476 13. 1 12 14,559 14,969 15,467 16,093 16,877 17,080 !8,258 18,855 19,627 19,926 20,307 20,676 21,146 21,267 21,517 22,435 22.727

I'lc 1 h u u

TIME OFFSET

-0.057 -0,060 -0.053 -0,059 -0,064 -0.068 -0.101 -0,071

-0,067 -0,063 -0,070 -0,062 -0,065 -0,063 -0,064 -0.063

-0,045 -0.063

-1,158

; udo'Oo

AREA COUNTS

634 54404 48291 15329 31997 37992 43074 1827

38914 2277

36034 20087 38501 7650

48643 16125 26457 30529 3095 3124 1566 1013

45371 35812

588746

SEP CODE BB BB BV VB BV VV VB BV VV VV VB BV VB BV VV VV VV VV VV VV VV VB BV VB

Wl/2 CSEC) 5,90 6,75 7,00 6,60 7,80 6,60 7,95 10,05 7,75

? 7,35 7,85

? 7,20 8.80 3,55 9,75 8. 90 9,05 9.40

? ? 6.80 ? ? ? 5,40

8.75


DIVISOR: 1.00000 MULTIPLIER: 1,00000

NOISE: 8.5 OFFSET: 13

K: 16 VIAL: 14 iNJ: l


TITLE: PESTICIDE CONFIRMATORY

CHANNEL NO: 1 SAMPLE: SAME

19:14 13 JUL 88

METHOD: DBS

PEAK NO

1 2 3 4 5 6 7 0 9 10 1

.2 13 14 15 16

PEAK NAME

LINDANE

ALDRIN ISODRIN

DIELDRIN ENDRIN

ENDO I I DDD ENDO S04

END KETON

TOTALS:

RESULT UG/ML 9.1852 2.5603 8.0957 6.8043 7,1590 7,5009 6.7999 6.1905 10.8689 1.4254 4.5528 2.6530 4.4280 6.3268 5.4327 10.0169

100.0000

TIME CMIN) 9,667 10,440 10,685 1 1 ,369 12,994 14,102 15,319 16,463 17,258 17.936 18,205 18,395 18,768 19,520 20,915 21,257

TIME OFFSET

0, 129

-0,198 -0,201

0.228 0, 106

-0,115 0,008 0,210

-0,223

-0,056

AREA COUNTS 82349 22954 72581 61003 64183 67249 60964 55500 97444 12779 40818 23785 39699 56722 48706 89806

896542

SEP CODE BB BV VB BB BB BB BB BB BB BV VV VV VB BB BV VB

Wl/2 CSEC)

? 6, 80 5.95 6, 90 6, 60 7,25 7.55 7.35 7.55

11.10 7. 60 8,90

? 13,15 10,40 9.70 8.90 10.80

Mi ILN: •" 16 •- ZERO: 10i 1 MIN/TICK

-STAT'

SR:OrR

INJECT

1 .429

4, 261 5, 148

7.757 8,280

nilNDANE

HEPTACHt^ D-BHC _=-.

ISOD _ - H E P T _ E

1 3 , 6 7 8 1 4 . 5 5 4

-EBit— —<^^L_L5^ 4 9 4

-trDE 1 7 , 6 2 1

-£tDD

' p R I N AL DO 5 0 4

,. 2 1 , 4 3 5 • ^ 2 , 0 4 5

; N D K E T Q i i -

2 4 , 1 17

2 5 , 5 5 2

i^^'TEN: 32 ZERO: 5'k l d l u / T I C K

0 , 9 2 2

- S R : 0

, y ^

. 1 /

< 1 , 0 0 2 "

3 J ^ . 0 4 9 ^ T 2 , 4 8 4

' T 4 . 980"

z7 M 6 . 880-

1 8 . 6 8 3 -

^l.UT

2 2 , 7 1 5 —

ENDO

ENDO S04

1 6 . 4 5 8

1 8 . 1 9 1

2 0 . 8 9 4

yo7i{9 " ^ u B

TITLE: PESTICIDES

CHANNEL NO:

PEAK

1

2 3 4 5 6 7 8 o

PEAK NAME

A BHC

LINDANE n nur

O. S o PPr^ S T W F L E :

RESULT UG/ML 0. 0000 0.0000 0.0000 0.0000 0.7270 0.0000 0.0000 0.7008 O, "SQ-? 1

SW

8

TIME CMIN) 6,272 7, 006 7,757 8,280 9,676 10.490 10.704 11.002 1 1 -5-?rtl

MET

TIME OFFSET

-0,054

-0,058 — A r t t t z rit

19:

HOD

48 13

: DB608

AREA COUNTS

912 5766 1343 3844

1398160 10691 7298

1297700

JUL 88

SEP CODE BB BB BV VB BV VV VV VV

Wl/2 CSEC) 7, 70 6,75 6,85 10.35 7,80 10,85

? 9,70 7,70

T L E : P E S T I C I O E S

ANNEL N O : 2

AK PEAK NAME

2 3 4 5 A BHC 6 7 8 LINDANE 9 B BHC 10 HEPTACHLO 11 D-BHC 12 13 ALDRIN 14 15 16 ISODRIN 17 HEPT EPX 18 19 ENDO I 20 21 DDE 22 DIELDRIN 23 24 25 ENDRIN 26 DDD 27 ENDO I I 28 DDT 29 ENDRIN AL 30 ENDO S04 '

33 34 35 36 37 METHOXY 38 END KETON

TALS:

Z.I. -Sc.11--/-'^> •'.'

SAMPLE: 8

RESULT UG/ML 0,0000 0,0000 0,0000 0.0000 0.7270 0.0000 0 , 0000 0,7008 0,2871 0,5843 0.6363 0.0000 0,6335 0,0000 0.0000 8,8203 0.6439 0. 0000 0.6079 0 . 0000 0,4901 0.6847 0.0000 0,0000 0,5491 0.3921 0.6738 0.5552 0.5482 0.5308 0.0000 0.0000 0 . 0000 0.0000 0.0000 0,0000 6,9734 0,6204

25,6589

Z)

TIME CMIN) 6, 272 7, 006 7,757 8,280 9,676 10,490 10,704 11,002 11,270 12,049 12,484 12,817 13,118 13,678 13.979 14,554 14,980 15,494 16,097 16,403 16,880 17,083 17,621 17,679 18,258 18,683 18,849 19,622 19,917 20,301 20,527 21,072 21,435 21,637 21,705 22,045 22,407 22,715

19 48 13

M E T H O D : DB608

TIME OFFSET

-0,054

-0,058 -0,050 -0,051 -0,056

-0,062

-0,106 -0,060

-0.063

-0,060 -0,067

-0,062 -0,067 -0,071 -0,068 -0,073 -0,069

-0,073 -0,075

-1,245

AREA COUNTS

912 5766 1343 3844

1398160 10691 7298

1297700 474586 960962 1178370

15061 1 151820

9191 5289

31 167 961111 23966

880957 6352

703180 1006910

4832 2441 1

261466 461236 910608 578339 721298 804248 139163 54665 45930 10638 36526 4556

1610480 939995

16743000

JUL 88

SEP CODE BB BB BV VB BV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv

?

? ? ? ?

?

? ?

? ?

? ? ? ? ? ? ?

Wl/2 CSEC) 7,70 6,75 6.85 10,35 7,80 10,85 9,70 7, 70 6. 40 8,00 7.20 0,90 5,80

8,40 8,25 8,85 8,35

28, 20 8,85 9,30 0,60 1 ,20 7.90 8, 30 10,20 8,35 8,55 8,10

34,35 9,90 17.50 0, 20

6, 60 9, 15

r

:TECTED PKS: 48 REJECTED PKS: 10

VISOR: 1,00000 MULTIPLIER: 1,00000

U S E : 8,5 OFFSET: 7

ICK: 16 VIAL: 15 INJ: 1

iTES: DB608 PRIMARY COLUMN

TLE: PESTICIDE CONFIRMATORY

lANNEL NO: 1 SAMPLE: SAME

19:48 13 JUL 88

METHOD: DB5

:AK 10 1

PEAK NAME

RESULT UG/ML 0. 1344

TIME CMIN) 6.994

TIME OFFSET

AREA COUNTS 12669

SEP CODE BB

Wl/2 CSEC) 6.65

?ACK: 16 IAL: 15 1 N J : 1

ÎOTES:

DB608 PRIMARY COLUMN

TITLE : PESTICIDE

CHANNEL NO: 1

PEAK N O V

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 6 .7 18 19 20 2 1 22

' 23 , 24

25 26 27

PEAK NAME

B BHC LINDANE

D-BHC

ALDRIN

ISODRIN ENDO I

DIELDRIN

ENDRIN

ENDO II DDD ENDO S04

DDT

END KETON

TOTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML 0.1344 6.6679 3,1287 6,1066 0,5933 5,8558 0.1573 0,4706 0,2972 0,2355 5,6479 5,961 1 0,4636 5.5512 0.4600 5.4831 3,5405 6.2483 2.8648 4.4228 3,8574 5,7444 1 , 1819 8,8039 0,8002 5.3005 10,0210

99,9999

SAME

TIME CMIN) 6,994 9,663 10,435 10,679 1 1 .012 11,364 1 1 ,608 11,694 12.077 12,164 12,994 14,104 15.012 15,322 16,058 16,458 17.133 17,254 17,932 18,191 18,3?3 18,756 19,235 19,510 20,293 20.894 21.217

19:

METHOD

TIME OFFSET

0. 032 0. 124

0. 157

-0.196

-0,198 0, 178

0, 103

0, 102

. /> ' ' 7

-0,004 -0,075

0,243

-0.263

0. 086

48 13

: DB5

AREA COUNTS 12669

628620 294962 575704 55938

552053 14825 44367 28023 22202

532453 561988 43709

523343 43366

516922 333781 589057 270081 416960 363653 54T552 111427 829986 75438

499709 944735

9427520

JUL 88

SEP CODE BB BV VV VV VV VV VV VV VV VB BB BV VV VV VV VV VV VV VV VV V V vv vv vv vv vv VB

?

? / ? ?

? ?

? ->

?

? ?

Wl/2 CSEC) 6.65 9,35 9, 15 9,20 13,00 9,20

16,60 4,50 12,35 9,80 10, 00 7,55 10,05 8, 60 10,25 1 1 ,70 12,50 10,05 9,90 13, 30 1 1 ,75 13,10 12.50 8,90 7,65 12, 90

REJECTED PKS; DETECTED PKS: 30

MULTIPLIER: 1,00000



NOTES:

DBS CONFIRMATORY COLUMN

CHART SPEED ATTEN: 16

-STAT"

0.6 CM/MIN ZERO: \<d% 1 MIN/TICK ATTEN;

INJECT

32 ZERO; 5% 1 MIN/TICK

:HART SPEED 0.6 CM/MIN ^TTEN: 16 ZERO: 10% 1 MIN/TICK

-1 ,T-T INJECT

2^,898 330

4,281

7.006

METHOX

ATTEN: 32 ZERO; 5% 1 MIN/TICK

-SR:qrFF

C 9,679

LIN

ALD

4=@-r458 1 I ,384

13,013

14,119

^ ^ 16,484 DIEL^Rtn 17,277

• 18,232 -DDD ( ^ 18, 800 _ENDCr'StJ4 19,550

20,942 .

-|

TITLE: PESTICIDES

c .iNNEL NO: 2

PEAK PEAK NO NAME

1 2 A BHC 3 LINDANE 4 B BHC

O . o l 9>7-anc/on7

SAMPLE: 1

RESULT UG/ML 0.0000 0.0193 0.0184 0.0072

TIME CMIN) 7. 9. 1 1 . 1 1 .

006 683 010 275

jTl/AJ

MET

TIME OFFSET

-0 -0 -0

.047

.050

.045

-^ccB 13:

HOD

45 13

: DB608

AREA COUNTS

748 37147 33999 1 1983

JUL 88

SEP CODE BB BB VV VB

Wl/2 CSEC) 5.95 6.80 6.55 6.80

K '-\ f\^ r \ _ rt n . A—\ 1 o >i o ^

ITLE: PESTICIDES

HANNEL NO: 2

EAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19

PEAK NAME

A BHC LINDANE B BHC HEPTACHLO D-BHC ALDRIN ISODRIN

ENDO I DDE DIELDRIN ENDRIN ENDO I I DDT ENDRIN AL ENDO S04 METHOXY END KETON

o. o\

SAMPLE: 1

RESULT UG/ML 0. 0000

0193 0184 0072 0118 0154 0132 1907

0.0000 0.0138

0078 0144 01 14 0204 0082 01 16 , 0075 ,0965 ,0141

0, 0, 0, 0, 0, 0, 2,

0. 0. 0, 0, 0, 0, 0, 0, 0,

TIME CMIN) 7, 9, 1 1 , 1 1 . 12. 12. 13, 14, 14. 16. 16, 17, 18, 18, 19, 19, 20, 22, 22,

006 683 010 275 058 493 133 451 989 103 900 089 263 880 652 950 335 452 747

13:

METHOD

TIME OFFSET

-0,047 -0.050 -0,045 -0,042 -0,047 -0,047 -0,209

-0,057 -0,040 -0,061 -0,057 -0,040 -0,038 -0,040 -0,035 -0,028 -0,043

45 13

: DB608

AREA COUNTS

748 37147 33999 1 1983 19483 28513 23934 7741

22529 19941 1 1 129 21220 5436

27549 8587 15274 1 1314-' 22289 21343

JUL 88

SEP CODE BB BB VV VB BV VV VB BV VB BB BV VB BV VV VV VV VB BV VB

Wl/2 CSEC) 5,95 6. 6. 6. 7. 6, 7. 14, 7, 8. 8, 8, 12, 10, 8, 8, 9, 9, 8,

80 55 80 70 70 95 75 90 00 20 90 15 50 35 40 15 10 90

OTALS: 2,4817 -0,926 350159

' •CTED PKS: 24 REJECTED PKS: 5

'IVISOR: 1,00000 MULTIPLIER: 1,00000

IOISE: 13,4 O F F S E T : 11

:ACK: 16 VIAL: 6 INJ: 1

lOTES:

DB608 P R I M A R Y COLUMN

ITLE: P E S T I C I D E CONFIRMATORY

;HANNEL NO: l

'EAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13

PEAK NAME

LINDANE

ALDRIN ISODRIN

DIELDRIN ENDO I I DDD ENDO S04

SAMPLE:

RESULT UG/ML 10.6045 3.6985 10.5355 8.6491 6.9967 6.6049 7.0489 6.1026 10.3400 4.2057 7.71 15 6.0649 4.7688

SAME

TIME CMIN) 9.679 10.458 10.699 1 1.384 13.013 14, 1 19 15.339 16.484 17.277 18,232 18,800 19.550 20.942

13:45 13 JUL 88

METHOD: DB5

TIME OFFSET

0, 144

-0. -0,

0, -0, 0,

181 181

247 278 040

0.240

AREA COUNTS 64915 22640 64493 52945 42830 40432 43150 37357 63296 25745 47206 37126 29192

SEP CODE BB BV VB 66 BB B6 BB BB BB BV VV VB BV

Wl/2 CSEC)

? 6.85 6,50 6,95 7. 10 7, 15 6. 80 7, 80 7, 90

? 12,75 8,50 9,60 10,00 8.55

/ r» •!• >^ 1 A. r k . r \ * - i \

TITLE : PESTICIDE

CHANNEL NO: 1

'EAK M-

2 3 4 5 6 7 8 9 10 1 1 12 13 14

PEAK NAME

LINDANE

ALDRIN ISODRIN

DIELDRIN ENDO I I DDD ENDO S04

END KETON

rOTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML 10.6045 3.6985 10.5355 8.6491 6,9967 6.6049 7,0489 6,1026 10.3400 4,2057 7,7115 6.0649 4.7688 6.6685

100.0000

SAME

TIME CMIN) 9. 679 10,458 10,699 1 1 ,384 13,013 14, 1 19 15,339 16,484 17.277 18,232 18,800 19,550 20,942 21,278

13:

METHOD

TIME OFFSET

0, 144

-0.181 -0,181

0,247 -0,278 0, 040 0, 240

-0,202

-0,171

45 13

: DB5

AREA COUNTS 64915 22640 64493 52945 42830 40432 43150 37357 63296 25745 47206 37126 29192 40821

612148

JUL 88

SEP CODE BB BV VB BB BB BB BB BB BB BV VV VB BV VB

Wl/2 CSEC)

? 6.85 6,50 6,95 7, 10 7, 15 6,80 7.80 7.90

? 12,75 8,50 9. 60 10, 00 8,55 10, 40

DETECTED PKS: 15

MULTIPLIER: 1.00000

^ÔISE: 131,1 OFFSET:

RACK: 16 VIAL: 6

REJECTED PKS;

39

INJ: 1

NOTES: DB5 CONFIRMATORY COLUMN

CHART SPEED 0,6 CM/MIN ATTEN: 16 ZERO: 105« 1 MIN/TICK

-STAT" INJECT

— 1 , 3 3 9

I 4 , 2 9 1

5 . 159 ~ S R : O F ^

7 . 0 1 7

—i 8 . 2 8 6

"UINDAN 't:

ey

( /

ZERO;

t ^ 1 1 , 0 1 9

1 MIN/TICK

PT(:^Cttte= •BHC_/-

ISODR^_JLi^

; . J '2 .064 J . 2 . 500 .

9 . 6 9 5

•nÊPT_£<PX ^

453

c: c

1 3 , 0 1 8

i 5 .9 i ; i 4

ENDO_^- - -- n n r

1 5 . 5 1 3 = 1 4 . 9 9 8

= 'f6.117"~ C l : « ^ A . 9 0 ? i — * ^

CHART SPEED 0.6 CM/MIN p- -EN: 16 ZERO: \<d% 1 MIN/TICK

-STAT

ATTEN: 32 ZERO: S% 1 MIN/TICK

9.695

13.018

"TTlkJ-ÛlB

.ITLE: PESTICIDES ^ ^ ^ S T n n d o r ^

?) CHANNEL NO: 2 SAMPLE: 2

5 PEAK PEAK 3 NO NAME

1 2

RESULT UG/ML 0.0000 0 . 0000 ^ ^

TIME CMIN) 6.286 7.017

14:19 13 JUL 88

METHOD: DB606

TIME OFFSET

AREA COUNTS

530 2707

SEP CODE BB 66

Wl/2 CSEC)

? 18.55 6.50

TITLE :: PESTICIDES

CHANNEL NO: 2

PEMK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 "S

1

O0

PEAK NAME

A BHC

LINDANE B BHC HEPTACHLO D-BHC ALDRIN

ISODRIN HEPT EPX

ENDO I DDE DIELDRIN

ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

TOTALS:

0 . 10

SAMPLE:

RESULT UG/ML 0.0000 0.0000 0.0000 0.1596 0.0000 0.0000 0.1433 0.0559 0.1135 0.1235 0.1317 0.0000 2.2524 0. 1346 0.0000 0.1256 0.0844 0.1485 0.0000 0.0769 0.0574 0.1462 0.0953 0.1069 0.1141 0.0000 0.0000 0.0000 1.4199 0.1424

5.6321

2

TIME CMIN) 6. 286 7.017 8.286 9.690 10,515 10,720 1 1 ,019 1 1 ,286 12.064 12.500 13.138 14.453 14.552 14.998 15.513 16.117 16,903 17,100 17,689 18.275 18.710 18.872 19.641 19.941 20.327 21.117 21.504 21.640 22.437 22.744

14:

METHOD

TIME OFFSET

-0.040

-0.041 -0,034 -0,036 -0,040 -0,042

-0.108 -0.042

-0,043 -0,037 -0.050

-0.045 -0.040 -0.048 -0.049 -0.049 -0.043

-0.043 -0,046

-0,876

19 13

: DB608

AREA COUNTS

530 2707 1 188

306942 3805 1930

265287 92387 186625 228645 .23AA2B

8377 7959

200953 4970

182044 121048 218430

4668 36613 67565 197513 99291 140594 172877 1 1645 10509 14442

327931 215798

3372750

JUL 88

SEP CODE BB BB BB BV VV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv VB

?

? ?

? ?

?

?

?

? ? ? ?

Wl/2 CSEC) 18.55 6.50 12, 15 6,70 13.50 8. 10 6.90 6.85 7.70 6.65 7.80 10.80 10.55 7.55 9.60 7,80 7.40 8.30

8.20 9.00 9. 10 8.00 8.35 8.65 9.30 15.80

5.70 8.20

DETECTED PKS: 38 REJECTED PKS:

DIVISOR: 1.00000 MULTIPLIER: 1.00000






Nu 1 2 3 4 5 6 7

PEAK NAME

LINDANE

ALDRIN

RESULT UG/ML 7.9136 3.1995 6.9896 6.4039 6.8121 0.4793 7.4965

10 10 1 1 13 13 14

TIME CMIN) 9.695

463 707 392 018 904 129

14:

METHOD

TIME OFFSET

0. 152

-0,171

19 13

: DBS

AREA COUNTS 255183 103171 225387 206502 219665 15456

?4iy%7

JUL 88

SEP CODE BB 6V VB BB BB BV vn

?

?

Wl/2 CSEC) 9.20 7.50 8.80 8.50 9.30 10. 10 o •?«;

riTLE : PESTICIDE

CHANNEL NO: 1

'EAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18

PEAK NAME

LINDANE

ALDRIN ISODRIN

DIELDRIN

ENDRIN

ENDO I I DDD ENDO S04

END KETON

OTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML 7.9136 3.1995 6.9896 6.4039 6.8121 0.4793 7.4965 6.4267 6.0393 3.4927 6.7345 1.7118 4.5300 3.3970 5.3572 8.0858 5.1350 9.7954

99.9999

SAME

TIME CMIN) 9.695 10.463 10.707 11,392 13.018 13.904 14,129 15,352 16.484 17,148 17.287 17,960 18.224 16.423 18,788 19,543 20,934 21.258

14:

METHOD

TIME OFFSET

0, 152

-0,171 -0,168

0. 1 18

0, 130

-0,087 0,028 0,233

-0,222

0,013

19 13

: DBS

AREA COUNTS 255183 103171 225387 206502 219665 15456

241732 207236 194744 1 12627 217161 55198 146076 109540 172750 260734 165584 315862

3224610

JUL 88

SEP CODE 66 BV VB BB BB BV VB 66 BB BV VB 6V VV VV VV V8 6V V6

Wl/2 CSEC)

? 9, 20 7,50 8,80 8.50 9.30

? 10.10 9.75 9.45 9.40

? 9. 30 ? 12.50

7.55 9.75

? 10.95 10. 65 1 1 .45 9.70 10.90

REJECTED PKS 'ETECTED PKS: 20

IL.- . IPLIER: 1 .00000

IOISE: 1 0 8 . 0 OFFSET: 2 8

ACK: 16 VIAL: 7 I N J : 1

OTES: 065 CONFIRMATORY COLUMN

HART SPEED 0.6 CM/MIN TTEN: 16 ZERO: 10J< 1 MIN/TICK

S"TAT~T INJECT


932

SR:0FF| ~ B R : Q F F

I: Ifi 7.006

,9. 120 9.693

NOTES: -DBS CONFIRMATORY COLUMN

CHART SPEED 0.6 CM/MIN ATTEN: 16 ZERO: \2I% 1 MIN/TICK

~"^TAT~ INJECT

- ^ \'.m

SR:OFR

4.259

5. 151

7.767 8. 178

"TINDANE

HEPTACHL r - HC

TTEPT EPX-- ^ ^ M4..II;?

15,509

-DDE

-DDT ENDO S04

METHOXY

21 .472

25.551


,932

-SR:(>rF

7.006

9. 120

1 .657

13,854

^ 14,994'

ENDO -t= 16.082 16. 899-

19.645 20,325

-ENDRIN -^DD ENDO S04 19.Pr^9

" ^ 22, 427

9.693 1 2i. 459

13,024

16.486 17.281 17.957

20.927

y ^ ^ ^ T / / ^ TITLE: PESTICIDES 14:54 13 JUL 88

ynio -û7B

: TITLE : PESTICIDES

' CHANNEL NO: 2

PL.,.K 1 NO

1 > 2

3 4 5 6

1 7 ;- B 1 9

10 1 1

'• 12 13

' 14 15

: 16 17 18

; 19 1 20

21 22 23 24

; 25 26 27 ''e ?

O0 31 32 33

^ 34

PEAK NAME

A BHC

LINDANE B BHC HEPTACHLO D-BHC ALDRIN

ISODRIN HEPT EPX

ENDO I DDE DIELDRIN ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

STOTALS:

I.ri 9> hxtxdard.

SAMPLE:

RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0,0000 1.1490 0,0000 0.0000 1.1150 0.6123 1.0477 1.0942 1.1104 0.0000 18.6542 1.1175 0.0000 1.1004 0.9313 1.2541 1.1728 0.8221 1.2165 1.0787 1.0347 1.0681 0.0000 0.0000 0.0000 0.0000 1 1 .2733 1.1066 0,0000 0.0000

47.9589

3

TIME CMIN) 6.280 7,018 7,767 8, 178 8,289 9,690 10.508 10.720 11,020 11.285 12.065 12,499 13,135 14,412 14,568 14.994 15.509 16,113 16,899 17,098 18,276 18,698 18,873 19,645 19.938 20.325 20.543 21.107 21,472 21,726 22,427 22,740 25,551 25.751

M :S4 13

METHOD: DB608

TIME OFFSET

-0.040

-0.040 -0.035 -0.035 -0.041 -0.045

-0.092 -0.046

-0.047 -0.041 -0.052 -0.044 -0,052 -0.047 -0.045 -0.052 -0,045

-0.053 -0.050

-0.902

AREA COUNTS

3184 13387 2630 3 108 6377

2209690 23041 15050

2064900 10121 10 1723140 2026310 2018950

20286 65916

1667940 59519

1594750 1336120 1844190 558472 967149 1643970 1123620 1361410 1618310 236825 106604 91547 95744

2603540 1676590

1571 121 1

29797200

JLLL_a£

SEP CODE 66 66 6V VV ve 6V VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv

. vv vv ve

L

? ?

?

?

? ?

? ?

? ? ? ?

? ?

Wl/2 CSEC) 9.95 7.20 7.00 8,00 14,20 9,20 1 1 ,25 10. 10 9, 15 6.95 9.35 8.60 10.05 12.40 9.45 9.40 10.10 9.35 8,60 10,85 8.40 8.70 10.50 8,85 8.95 8,80

34,20 13,70 14. 40 3.50 1 1 .00 10, 10


DIVISOR: 1.00000 MULTIPLIER: 1.00000




LE; PESTICIDE CONFIRMATORY


-PEAK V NO 0 1 5 2 n 3

PEAK NAME

RESULT UG/ML 0.2096 0.0865 6.6436

14:54 13 JUL 88

METHOD: DBS

TIME CMIN) 7.006 9. 120 9.693

TIME OFFSET


865774

SEP CODE 66 BB ev

Wl/2 CSEC) 7.55 7.20 10.90

)ETECTED P K S : 45 REJECTED PKS: 11

)IVIS0R: 1.00000 MU L T I P L I E R : 1.00000

1' E: 9.7 O F F S E T : 6

JACK: 16 VIAL: 8 INJ: 1

lOTES: DB608 PRIMARY COLUMN

F CHANNEL NO: 1

>EAK NO

1 2 3 4 5 6 7 8

. t)

1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30

PEAK NAME

6 6HC LINDANE

D-BHC

ALDRIN

ISODRIN ENDO I

DIELDRIN

ENDRIN

ENDO DDD ENDO

DDT

I I

S04

END KETON

•OTALS:

CONFI-RMATORY

SAMPLE:

RESULT UG/ML 0.2096 0.0865 6.6436 3.1261 5.8580 0.8408 5.6680 0.2254 0.4860 0.0834 0.5023 0.3794 5.2602 0.1883 6.0367 0.5686 5.5894 0.61 18 5.5637 3.7645 6.0360 3.0972 4.4312 4.1025 5.9364 1.3355 8.5120 0.9877 5.2570 8.6121

99.9999

SAME

TIME CMIN) 7.006 9. 120 9.693 10.459 10.707 11.030 1 1.390 1 1 .657 1 1 .718 1 1 .909 12.100 12.208 13,024 13.854 14.131 15.040 15.351 16.082 16.486 17.153 17.281 17.957 18.218 18.413 18.779 19,259 19.535 20,322 20,927 21,243

14:54 13

METHOD: DBS

TIME OFFSET

0.050 0. 150

-0.011

-0.169

-0.169 0.202

0, 123

0, 127

-0.097 0,019

-0,051

0, 272

-0,237

0,209


865774 407383 763395 109567 738629 29372 63340 10870 65458 49440

685494 24534

786682 74101

728393 79734

725041 490581 786587 403613 577463 534623 773611 174041

1109260 128716 685073 1122300

13031700

JUL 88

SEP CODE 66 66 6V VV VV VV VV VV VV VV VV VB 66 ev vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB

? ?

?

? ? ? ? ?

?

? ?

? ?

?

? ?

Wl/2 CSEC) 7.55 7.20 10.90 8.95 10.80 17.70 10,35

22,60

8, 10 27.30 10.80 8,00 1 1 . 35 8.30 11.15 9.60 1 1 .35 1 1 .80 13. 45 10.10 1 1 .20 12.75 12.20 14.40 14.35 10, 70 8. 45 15,20

REJECTED PKS: )ETECTED PKS: 33

t U L T I P L l E R : 1 .00000

IO'SE: 108.0 OFFSET: 12

!h.r<: 16 VIAL: 8 INJ: 1

<OTES: DBS CONFIRMATORY COLUMN

A 7y//M>'AuT5 A A AnalyticalTechnologies, Inc

GAS CHROMATOGRAPHY - RESULTS

REAGENT BLANK

TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) ATI I.D.

CLIENT : MONTGOMERY & ASSOCIATES DATE EXTRACTED PROJECT # : 661D DATE ANALYZED PROJECT NAME : HASSAYAMPA UNITS CLIENT I.D. : REAGENT BLANK DILUTION FACTOR

806170 07/01/88 07/13/88 UG/L N/A

COMPOUNDS RESULTS

ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 1232 AROCLOR 124 2 AROCLOR 1248 AROCLOR 1254 AROCLOR 1260

<0.05 <0.05 <0.05 <0.05 <0.05 <0.5 <0.1 <0.1 <0.1 <0.1 <0.05 <0.1 <0.1 <0.1 <0.1 <0.05 <0.05 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <1.0 <1.0


ISODRIN % 89

DETECTED PKS: 25

MULTIPLIER: 1.00000

Nl- E : 71,6 OFFSET;

RACK: 16 VIAL: 4

REJECTED PK'i

9

INJ: 1

NOTES: DBS CONFIRMATORY COLUMN

CHART SPEED ATTEN: 16

0,6 CM/MIN ZERO: 10%

10. 1,35 XINDA^^(E 10,990

11.685

,12. 895

ISODRI>)—

DDE-

~ENDB.LI

~END0-_DDT ENDRI

15.479

17.064 17.563 18,125

I 19,149 19.586 -"iL 20.212 20.928

21.912 '-METHOXY 22.7 12

24.871

25.811

1 MIN/TICK

0.918

ATTEN: ZERO: 5% 1 MIN/TICK

SR: OFF

3, 218

•' 14.54 3

I 12.100

"^LD^TN 14.079

( 14,999

TnoO' "juJB

TITLE: PESTICIDES HX^. 7/,

C NEL NO: 2 S A M P L E : 13

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19

) 20 21 22

PEAK NAME

LINDANE

HEPTACHLO

ALDRI ISODR

N<fei.D

D I E L D R I N

ENDRI ENDO DDT ENDO

END KETON

T O T A L S :

R E S U L T UG/ML 0 , 0000 0,0000 0 , 0000 0,0008 0,0000 0,0006 0,0000 0,0059

89,4359 0.0000 0,0010 0,0000 0.0127 0,0043

, 0,0069 504 X '"- 0, 0 174

0,0000 0.0000 0,0000 0,0014 0,0000 0,0000

89,4869

N I I

X

T I M E CMIN) 7 7 8 10 1 1 12 12 13 14 15 17 17 18 19 19 20 20 21 21 22 24 25

016 848 201 990 685 013 895 209 543 479 064 ,563 , 125 , 149 ,586 , 212 ,928 ,407 .912 .712 .871 .811

22:38 13 JUL 88

METHOD: DB608

TIME OFFSET

•0. 070

•0.087

0.029 -0.117

-0.086

-0.195 0. 229 -0.104 -0.158

-0.078

-0,637

AREA COUNTS

527 502 1016 1442 4748 1010 1532

10810 316028

3980 1406 3092 6051 5829 7168

26417 6627 5272 3721 2148 4461 1308

4 15095

SEP CODE 66 ev VB BB BV VB BV VB BV VB BV VV VV VV VV VV VV VV

vv VB BV VB

Wl/2 CSEC) 9,60 9,50 8,20 5.50 7,45 5,90 7, 35 12,80 8,00 9,50 7,65

24,60 29. 20 44, 00 26.00 13.15

62, 10 8,50

41 , 90 40, 30

DE-^FCTED PKS: 54 REJECTED PKS: 32

Dl iSOR: 1.00000 MULTIPLIER: 1.00000


RACK: 16 VIAL: 5 INj: 1

NOTES: DB60B PRIMARY COLUMN


CHANNEL NO: 1 S A M P L E : SAME

PEAK NO

1 2 3 4 t^

PEAK NAME D-BHC

ALDR IN

ENDO S04

RESULT UG/ML 2,2388 3.6410 2.8515

86,8016 4,4671

TIME CMIN)

12,100 13.119 14.079 14.999 19.390

TO,HLS; 100.0000

22: :

METHOD

TIME OFFSET 0. 180

-0,221

0, 080

0, 039

58 13

• DBS

AREA COUNTS

6848 1 1 137 8722

265508 13664

305879

JUL 88

SEP CODE BB BB BB 66 66

?

7

?

Wl/2 CSEC) 7,05 6,30 7,55 9,80 5,30

DETECTED PKS: 22

M U L T I P L I E R : 1,00000

N O I S E : 71,6 OFFSET;

REJECTED PKS;

-1 1

17

T/J /AZ- ' /UTS

A A i \ AnalyticalTechnologies, Inc

QUALITY CONTROL DATA


CLIENT :. MONTGOMERY & ASSOCIATES PROJECT # : 661D PROJECT NAME : HASSAYAMPA

ATI I.D.


806170

80617001 07/02/88 AQUEOUS UG/L

COMPOUNDS


1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE

ND ND ND ND ND

50 50 50 50 50

38 40 39 40 39

76 80 78 80 78

43 46 45 44 44

86 92 90 88 88

12 14 14 10 14

Cr-g /c <2H<i)/K Conh-oi

(oiH'^x^^


Spike Concentration 100


Average of Spiked Sample 100

RIC DATA: 8061701MS #1 2Z7Q272 l5:2Sim CALI: 8061701MS #2 SAMPLE: JOB 806170-1 MS »/ STD MIX 250NG SML CONDS.: GC4 " " RANGE: G 1,1200 LABEL: N 0, 4.0 QUAN: A 0, 1.0 J 0

(i 'Zy ~-û7-Û7j>

SCANS 1 TO 1200

100.0-1

ni ni

ni in

in Q ' - I Z D CO a 00 u. V.

ru 0 o I t ^

Q .. tu h-1 <C tn »-« Q Z UJ •-. I L L U )

< z . » - l i -

RIC

BASE: U 20, 759

721

686 535

Jl

374

300

205

87

Ul 139

LU U

450

U •xJ

608

UU

951

824

991

I

903

UUU I

200 6:40

400 13:20

•^0 .00

800 26:40

I 1000 33:20

-J

< \ ^

4 40.3968.

"?00 SCAN J:00 TIME

PROCEDURE DATf\ REFE NAME

FILE RENCE LIST

REPORT

, e-r '..

TCA 8061701MS 8061701MS VQN

DIAGN

INITIALIZATION VQSTDS

i3 1 riiML;i-ir\i/i3 — _ "S/"

^s. PROC USED POSS RMS

6 6 6

6 6 6

1 1 1

74 74 74

42 COMPOUNDS PROCESSED,

y rriMoni IMn "^y . V. LUnrUUiMU y-s. NO LIB ENTRY REF 1 2 3 4 5 6 7 8 9 10 11 12 13 14 ^5

1

17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 • 2

VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VO VQ VO VO VQ VQ VQ VO VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VG VQ VQ VQ VQ VQ VQ VQ

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

-300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 299 608 758 381 721 902 55 86 108 138 204 222 252 286 326 346 363 385 381 423 435 437 450 686 491 499 515 534 537 531 535 568 615 630 677 686 726 762 824 948 988 957

— __ Dl

OSTIC

OPTION

1 IO 1 IKII,

REPORT

1: 2

KimiKIC* r U w o v/iifMNui' iNvJ

PROC 18 18 18

USED 18 17 17

40 FOUND

SEL 300 608 758 381 720 903 53 87 108 140 205 223 252 287 325 345 363 384 382 423 435 438 450 685 491

, 515 533 536 530 537

. 615 615 678 686 726 760 824 949 991 959

ir\\,#ri

DELTA 1 , , ,

-1 1

-2 1 , 2 1 1 , 1

-1 -1 ,

-1 1 . . 1 ,

-1 , . .

-1 -1 -1 2 , ,

-15 1 ,

-2 , 1 3 2

POSS 1 4 2

PEAKS

2

2

2

PROCESSING

X - L

OPTION:

rex KiAMCc

7/02/88

3

^ ^ LS 1 NAntib ~ ^

RMS STANDARD/UNKNOWN 121 VQSTDS/VQl 62 VQSTDS/VQ2

414 VQSTDS/VQ3

"SJ^ G A ' T •S.V

FIT PEAKS M/Z 975 950 996 995 997 971 881 997 946 993 994 910 950 998 997 997 955 988 954 984 939 996 995 999 922

, 998 1000 995 992 999

, 995 995 992 999 909 968 937 993 911 90S

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

^Lion

13:

CHRu TOP DELTA 300 607 758 381 721 903 53 87 107 139 206 223 252 287 325 345 363 384 382 423 435 438 449 685 491 498 515 533 536 530 537

, 615 615 678 687 726 761 824 949 991 959

. -1 . . 1 . .

-1 -1 1

-1

1

1

46: 49

• > « - — a ^ — . %

PEAKS

Quantitation Report File: 8061701MS

Data: 8061701MS. TI 07/02/88 15:06:00 Sample: JOB 806170-1 MS W/ STD MIX 250NG 5ML

Ids. : GC4 hormula: Instrument: 1050 Submitted bij: Analyst: MGB

Ueight: Acct. No.

0. 004

AMOUNT=sAREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 '9 ;

20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 I S3 SSI SS2 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H IIV 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V

BROMOCHLOROMETHANE 1,4-DIFLUOROBENZENE CHL0R0QENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1, 1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1.1.2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM


38V 18H 20H


XYLENES

No 1 2 3

J

6 7 8 9 10 11 12 13 14 15 16 17 IS 19 20 21 22 23 24 25 26 27 28 '^Q

31 32 33 34 35 36 37 38 39 40 41 42

m/z 128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75

NOT 173 173 43 164 92 112 106 104 106 106

Scan 300 607 758 381 721 903 53 87 107 139 206 223 252 287 325 345 363 384 382 423 435 438 449 685 491 498 515 533 536 530 537

FOUND 615 615 678 687 726 761 824 949 991 959

Time 10: 20: 25: 12: 24: 30: 1: 2: 3: 4: 6: 7: 8: 9:

10: 11: 12: 12: 12: 14: 14: 14: 14: 22: 16: 16: 17: 17: 17: 17: 17:

20: 20: 22: 22: 24: 25: 27: 31: 33: 31:

00 14 16 42 02 06 46 54 34 38 52 26 24 34 50 30 06 48 44 06 30 36 58 50 22 36 10 46 52 40 54

30 30 36 54 12 22 28 38 02 58

Ref 1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2

2 2 3 3 3 3 3 3 3 3

1. 1. 1. 1. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1. 0, 0, 0. 0. 0. 1. 0. 0. 0, 0. 0. 0. 0.

1. 1. 0. 0. 0. 1. 1. 1. 1. 1.

RRT 000 000 000 270 951 191 177 290 357 463 687 743 840 957 083 150 210 280 629 697 717 722 740 129 809 820 848 878 883 873 885

013 013 894 906 958 004 087 252 307 265

Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

A A A A A A A A A A

BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB VB BB BB BB BB BB BB BB BB BB BB

BB BB BB BB BB BB BB BB BB BB

Area(Hght) 136284. 797100. 593480. 240552. 827491. 455890.

6855. 160961, 21618, 93325. 189276. 31122.

396060, 172041, 314320, 185578. 359409, 215721, 15629,

166987, 157048. 334421, 312281, 364915, 276888, 353399, 224263, 199252. 211687. 685984. 109774.

107622. 107622. 130084. 163614. 424456. 492980. 232307. 1022010. 511252. 283244.

Amount 50. 50. 50.

111. 98. 93. 17. 38, 15, 35, 35. 28. 31. 38. 37. 38, 40. 43. 36, 31, 32. 33, 35, 38. 33. 33. 40. 34. 38. 39. 32.

35. 44. 35. 38. 40. 39. 38. 97. 79. 40.

000 000 000 133 736 653 392 088 137 620 458 847 292 318 410 344 306 822 360 533 280 644 790 123 623 877 454 799 846 260 989

425 819 824 850 119 073 355 899 560 911

UG/L UG/L UG/L X 7. X UG/L UG/L UO/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

7.Tot 2. 2. 2. 6. 5. 5. 0. 2. 0. 1. 1. 1. 1, 2. 2. 2, 2. 2. 2, 1. 1, 1. 1, 2. 1. 1. 2. 1, 2. 2, 1,

1, 2. 1, 2. 2. 2. 2. 5. 4. 2.

77 77 77 15 47 19 96 11 84 97 96 60

\ly.-07 12 23 43 01 75 79 86 98 11 86 88 24 y ^ 93 IS / ly-^V-83

96 48 98 15 22 < /

i yA 12 42 41 27

GZT' " >?^-^^^

DATA: 8061701MSD ttl CALI: 8061701MSD #2

SCANS

100.0-1

RIC 07/02/88 15:57:00

•gAMPLE:~UQB_g0617_0-l MSD CQHD5.: GC4 RANGE: G 1,1208 LABEL: N 0, 4.8 QUAN: A 0, 1.0 J 0 BASE: U 20, 3

760

1 TO 1200 7 ^ ,

n

•Jd

z Z> 00 O 00 U. "V

ni 00 o n ""v

rs Q •• UJ y -1 <: cn tm Q Z UJ • I X

u. w l - l

< z >•- u .

RIC

456704.

686

534

L-^

608

LJ

951

LJ u

824

991

I

903

U U.-.J U'L T 200 6:40

~ n — 400

13:20 J0

— I 800

26:40 1000 33:20

" 1 "^00 SCAN

:00 TIME


REPORT

DIAGNOSTIC REPORT TCA 8061701MSD 8061701MSD VQN INITIALIZATION OPTION: VQSTDS

7/02/88 16:37:40


V. STANDARDS -PROC USED POSS

6 6 1 6 6 1 6 6 1

>< PLUS UNKNOWNS RMS PROC USED POSS 50 18 16 1 50 18 17 2 50 18 17 3

>< - LIST NAMES - > RMS STANDARD/UNKNOWN 110 VQSTDS/VQl 66 VQSTDS/VQ2

417 VQSTDS/VQ3

42 COMPOUNDS PROCESSED. 38 FOUND

< COMPOUND X NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 • _y

LIB VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

ENTRY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

REF -300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 299 608 758 382 721 903 55 86 108 138 204 223 253 287 327 347 364 386 382 424 436 438 450 686 491 499 515 534 537 531 535 568 615 630 677 686 727 762 824 948 989 957

— SEARCH SEL 300 608 758 381 721 903

, 87 ,

140 205 223 253 287 325 346 363 384 383 423 435 438 450 685 491

, 515 533 537 530 537

, 615 615 678 687 727 760 825 950 991 959

>< SAT X DELTA PEAKS FIT PEAKS M/Z

1 3 , ,

- 1 i , ,

N

1 i , , 2 j 1 J , , ,

-2 ] -1 ] -1 ] -2 i

1 ] - 1 ] - 1 'c , ,

- 1 I ,

, - 1 1 ,

-1 3 2 :

» ,

-15 ] 1 : 1 i ,

-2 ] 1 ] 2 j 2 3 2 3

L 976 L 952 L 991 L 995 L 951 L 969

. L 996

, L 972 L 993 L 907 L 953 L 998 L 1000 L 998 L 954 L 990 L 950 L 988 2 938 L 993 L 997 L 998 L 922

. L 997 L 998 L 997 L 992 L 1000

, L 998 L 998 3 991 L 997 L 909 I 970 L 931 L 998 L 909 L 909

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

CHRO - > TOP DELTA PEAKS 300 608 758 381 721 904 53 87 107 140 205 223 253 287 325 345 362 385 383 423 435 438 450 685 491 498 515 533 536 530 537

, 615 615 678 687 727 762 ; 824 950 991 960

1

1 ] 1 j 1 ]

'

1

2 J 1 i

1 1

*

Quantitation Report File: 8061701MSD

Data: 8061701MSD.TI 07/02/88 15:57:00 Sample: JOB 806170-1 MSD

Ids. : GC4 i-ormula: Instrument: 1050 Weight: 0.004 Submitted by: Analyst: MGB Acct. No. :

AMOUNT=AREA « REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 ^8

9 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 I S3 SSI SS2 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V

BROMOCHLOROMETHANE 1.4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1.1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1.2-DICHLOROETHANE 2-BUTAANONE 1,1, 1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1.1,2, 2-TETRACHLOROETHANE 1.2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1.1.2-TRICHLOROETHANE BENZENE CIS-1.3-DICHLOROPROPENE 2-CHLORDETHYL VINYL ETHER BROMOFORM

4-METHYL-2-PENTANONE 16H 85V 86V 7V

38V 18H 20H


XYLENES

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 59 D

31 32 33 34 35 36 37 38 39 40 41 42

m/z 128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75

NOT 173 173 43 164 92 112 106 104 106 106

Scan 300 608 758 381 721 904 53 87 107 140 205 223 253 287 325 345 362 385 383 423 435 438 450 685 491 498 515 533 536 530 537

FOUND 615 615 678 687 727 762 824 950 991 960

Time 10:00 20: 16 25: 16 12:42 24:02 30:08 1:46 2: 54 3:34 4:40 6: 50 7:26 8:26 9:34 10: 50 11:30 12:04 12: 50 12:46 14:06 14:30 14:36 15:00 22: 50 16:22 16:36 17: 10 17:46 17: 52 17:40 17: 54

20:30 20:30 22:36 22: 54 24: 14 25:24 27:28 31:40 33: 02 32:00

Ref 1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2

2 2 3 3 3 3 3 3 3 3

RRT 1. 000 1. 000 1, 000 1, 270 0, 951 1, 193 0. 177 0. 290 0, 357 0, 467 0, 683 0,743 0. 843 0. 957 1, 083 1. 150 1. 207 1. 283 0.630 0. 696 0. 715 0. 720 0. 740 1. 127 0. 808 0. 819 0. 847 0. 877 0. 882 0. 872 0,883

1, 012 1. 012 0. 894 0. 906 0. 959 1. 005 1. 087 1. 253 1. 307 1. 266

Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

A A A A A A A A A A

BB BB BB BB BB BB BB BB BB BB BB BV BB BB BB BB BB BB BB BB VB BB BB BB BB BB BV BB BB BB BB

BB BB BV BB BB BB BB BB BB BB

Area(Hght) 136752. 798353. 641484. 244421, 867329, 488194,

3251. 170163. 7731,

104799, 220428, 46599.

433067, 193585, 358928. , 208795. 404160. 244695. 19760,

193559, 184722. 376048. 357813. 455829. 316038, 403204, 253667. 244686, 242794. 775768. 131521.

131936. 131936. 183119. 191641. 506381. 607552. 296403. 1288250. 630724. 332667.

Amount 50. 000 50. 000 50, 000

112, 534 95. 745 92. 785 8. 220

40. 128 5. 395

39. 863 41. 153 43. 044 34. 099 42. 969 42. 573 42. 994 45, 169 49, 538 45, 898 36, 493 37, 908 37. 773 40. 944 47. 546 38, 316 38, 590 45, 686 42, 667 44, 484 44, 329 39, 462

43, 360 54. 859 46. 656 42. 099 44. 280 44. 550 45, 275 114. 169 90, 807 44. 454

UG/L UG/L UG/L 7. 7. X UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UO/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

y.Tot 2. 50 2. 50 2. 50 5.64 4. 79 4. 65 0. 41 2. 01 0. 27 2.00 2.06 2. 16 1.71 ^ 2.15 ly^^ 2. 13 2, 15 2, 26 2, 48 2. 30 1.83 1.90 1,89 2.05 2. 38 1.92 1. 93 2. 29 lA>^ 2. 14 2.23 2.22 y ^ 1.98

2. 17 2.75 2.34 2. 11 2.22 y ' ^ 2. 231^-" 2. 27 5. 72 4. 55 2. 23

7)i/Aj-'7/.t-'G,'

/ \ AnalyticalTechnologies, Inc ACCESSION: 806170

QUALITY CONTROL DATA: 188 METHOD 624 & 8240

CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 7/2/88

DICHLOROMETHANE 1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE

yt7\^ OUND

5 4 . 6 5 6 . 9 6 1 . 1 4 1 . 5 4 9 . 4 5 0 . 5 5 4 . 3 5 0 . 8 4 8 . 6 5 0 . 4

s*'' Q^ O

ACTUAL

5 2 . 7 5 0 . 8 5 4 . 5 5 0 . 9 5 9 . 2 5 2 . 3 5 4 . 3 5 0 . 2 4 9 . 8 5 1 . 6

/f 77*fer<r

/^y

//z /I-X 8Z

fe % /rii>

76/ 7S 9?

SURROGATE RECOVERY 118% l,2-DICHLOROETHANE-D4 92% BROMOFLUOROBENZENE (BFB 98% TOLUENE - D8

PROJECT MANAGER: B-7 DATE: 8 / 1 8 / 8 8

[yTJi/ - l7)/<y -7iA77>

<

DATA: QC72 #1 CALI: QC72 #2

SCANS

100.0n

RIC 07/02/88 10:54:00 gAMPLE;'TfC 188 12..5UL CONDS.: GC4 RANGE: G 1,1200 LABEL: N 0, 4.0 QUAN: A 0, 1.0 J 0 BASE: U 20, 3

760

1 TO 1200

u.

546f.

726

530 608

687

RIC

362 449

205 286

71 ^ l u u LJ

903

1-825 J l j52 1049

200 6:40

400 13:20

1 r a g

. J0

I 800

26:40

— I 1000 33:20

">m SCAN :00 TIME


REPORT

TCA QC72 QC72 VQN INITIALIZATION VQSTDS

DIAGNOSTIC REPORT 7/02/88 11:35:29

OPTION: 2 PROCESSING OPTION: 3

< STANDARDS -PROC USED POSS

6 6 6

6 6 6

RMS 50 50 50

PROC USED POSS X PLUS UNKNOWNS X - LIST NAMES - >

RMS STANDARD/UNKNOWN 97 VQSTDS/VQl

369 VQSTDS/VQ2 94 VQSTDS/VQ3

18 18 18

10 12 12


COMPOUND X NO LIB ENTRY REF 1 2 3 4 5 6 7 8 9 10 11 12 13 14 ^"7

17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

.A

VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

-300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 299 608 758 382 721 903 54 85 107 137 203 222 252 286 326 346 363 385 379 422 434 436 448 686 489 497 513 532 536 529 537 570 616 631 678 687 727 762 825 948 988 957

— SEARCH — SEL DELTA 300 608 758 381 721 903

, , , ,

205 223

.

286 •

362 , ,

423 423

,

449 686

, .

515 ,

530 , , , ,

677 687 727 761

950 988

.

1

-1

2 1 , ,

•

-1 , ,

1 -11

,

1

2

1

-1

-1

2

PEAKS

, .• , .

1 1 .

1 •

1 , ,

1 1

1 1

1

1

1 1 1 1

1 1 .

X SAT X FIT PEAKS M/Z 976 923 996 999 997 969

^ . , .

998 905

.

995 •

951 . .

989 934

.

995 903

. •

998 , .

991 , , ,

868 998 909 996

,

915 850

.

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

CHRO > TOP DELTA PEAKS 300 608 758 381 721 903

.

.

205 223

286 •

362 . .

423 423

.

449 686

514 .

•

530 , . , ..

676 687 727 761

,

951 . ,

•

—

-

1 1 1 1 1 1

1 2

1 •

1

1 1"

1 1

1 1

1

1 1 1 1 1

1 1

Quantitation Report File: QC72

Data: QC72. TI 07/02/88 10:54:00 Sample: QC 188 12, 5UL

Ids. : GC4 hurmula: Instrument: 1050 Weight: 0. 004 Submitted by: Analyst: MGB Acct, No. :


BROMOCHLOROMETHANE 1,4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2, 2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1.1.2-TRICHLOROETHANE BENZENE

CIS-1.3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM

4-METHYL-2-PENTAN0NE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 ^8 ?

20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl 182 I S3 SSI SS2 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H 11V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V 4-ME 16H 85V 86V 7V

38V 18H 20H XYLEI

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 ^9 3

31 32 33 34 35 36 37 38 39 40 41 42

•m/z 128 114 117 65 98 95

NOT NOT NOT NOT 84 43

NOT 96

NOT NOT 83

NOT NOT 97 117 NOT 83 83

NOT NOT 130 NOT NOT 78

NOT NOT NOT NOT 43 164 92 112 NOT 104 NOT NOT

Scan 300 608 758 381 721 903


205 223

FOUND 286

FOUND FOUND

362 FOUND FOUND

423 423

FOUND 449 686

FOUND FOUND

514 FOUND FOUND

530 FOUND FOUND FOUND FOUND

676 687 727 761

FOUND 951

FOUND FOUND

Time 10:00 20: 16 2S: 16 12:42 24:02 30:06

6:50 7:26

9:32

12:04

14:06 14:06

14:58 22: 52

17: 08

17:40

22:32 22: 54 24: 14 25:22

31:42

Ref 1 2 3 1 3 3

1 1

1

1

2 2

2 2

2

2

3 3 3 3

3

1. 1. 1. 1, 0. 1.

0. 0.

0.

1.

0, 0,

0, 1.

0,

0,

0. 0. 0. 1.

1.

RRT 000 000 000 270 951 191

683 743

953

207

696 696

738 128

845

872

892 906 959 004

255

Meth A A A A A A

A

BB BB DB BB BB BB

BB A*BB

A

A

A A

A A

A

A

A A A A

A

BB

BB

BB BB

BB BV

BB

BB

VV BB BB BB

BB

Area(Hght) 128198. 892608. 713449. 240230. 986179. 535545.

274169. 17640.

240222.

512653,

246207, 41296,

483068, 14382,

313779,

951792,

1501. 274679. 641433. 770653.

4560.

Amount 50. 50. 50, 117, 97. 91.

54. 17,

56.

61,

41. 7,

49. 1,

50.

48.

0. 54. 50. 50.

0.

000 000 000 984 884 517

601 381

878

117

518 580

440 342

545

645

344 255 432 810

363

UG/L UG/L UO/L '/. X 7.

UG/L UG/L

UG/L

UG/L

UG/L UG/L

UG/L UG/L

UG/L

UG/L

UG/L UG/L UG/L UG/L

UG/L

y.Tot 4. 99 4. 99 4.99 11,77 9. 76 9. 13

5. 45 1. 73

5. 67

6. 10

4. 14 0. 76

4. 93 0. 13

•

5. 04

4. 85

0, 03 5, 41 5. 03 5, 07

0.04

y

y

v ^

y ^

^

•^

/^

y ^ ' k-"

( P A A / - 77i/xj-^ly7Q

DTp

07y82/88 9:11:00 SAMPLE: STD MIX 250NG (7/1/88) CONDS.: GC4 RANGE: G

DATA: STD72 #1 CALI: STD72 #2

SCANS 1 TO 1200

r,1200 LABEL: N 0, 4.0 QUAN: A 8, 1.0 J 0 100.0-1

o n ni o

Q z o u.

00 oo ni o

Q •• UJ y -I -4: cn t-t Q Z UJ

u. to '< z U f t

\- u.

RIC

BASE: U 20, 760

494532.

200 6:40

800 26:40

1000 33:20

* 200 SCAN 1:00 TIME


REPORT

*

TCA STD72 STD72 VQN

DIAGNOSTIC

INITIALIZATION VQSTDS

NKirVAOTM5 0 i r M n u n r i u a

PROC USED POSS

4

< C NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 '5

h 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 1

-,2

6 6 6

6 6 6

1 1 1

— — - sy y s .

RMS 73 73 73

2 COMPOUNDS PROCESSED,

nMPniiwn %/• unruwiNi/ y^ LIB ENTRY VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

REF -300 -608 -758 -382 -721 -902 -54 -85

-107 -137 -203 -222 -252 -286 -326 -346 -363 -385 -382 -424 -436 -438 -450 -686 -491 -499 -515 -534 -537 -531 -537 -570 -616 -631 -678 -687 -727 -762 -824 -947 -987 -956

PRED 301 609 758 383 721 902 58 89 110 140 206 225 255 288 328 348 365 387 383 425 437 439 451 686 492 500 516 534 537 531 536 569 615 630 678 687 727 762 824 948 988 957

Dl

OPTION

1 ir? t iKii,

REPORT

i: 2

Kini tktr« — r U w O UlYrMNUNINO

PROC 18 18 18

USED 18 17 18

41 FOUND

ccAor -XA — Jstfl

SEL 302 608 758 383 721 903 56 90 111 143 208 226 254 288 327 347 364 385 383 425 436 439 450 685 492

, 516 534 537 531 538 570 615 615 678 687 727 760 825 949 991 959

DELTA 1

-1 , , ,

1 -2 1 1 3 2 1

-1 ,

-1 -1 -1 -2 , ,

-1 ,

-1 -1 ,

2 1 ,

-15 , . ,

-2 1 1 3 . 2

POSS 2 8 1

PEAKS

2

2

4

PROCESSING

X - L

OPTION:

T O T KIAMI^C-

7/02/88 < 9:

3

^ *v

IbT NAntb "" - RMS STANDARD/UNKNOWN 141 VQSTDS/VQl 66 VQSTDS/VQ2

423 VQSTDS/VQ3

-s.y O A " T* -V j^

:><. bA 1 ./"s, FIT PEAKS M/Z 970 942 994 997 995 971 939 995 951 997 994 908 954 994 1000 995 952 986 955 988 938 991 998 1000 919

, 997 1000 993 883 998 993 998 998 989 994 909 961 935 997 910 909

128 114 117 65 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

f*t_iDn

LHRO TOP DELTA 302 608 758 383 721 903 56 90 112 1 142 -1 208 226 254 288 327 347 364 386 1 384 1 425 436 439 450 685 492 499 515 534 537 531 538 570 615 615 678 687 727

1

762 2 824 -1 949 991 959

56: 32

-*- —_.^ -

PEAKS

Quantitation Report File: STD72

Data: STD72, TI 07/02/88 9: 11:00 Sample: STD MIX 250NG ( ds. : GC4 Formula: Submitted by:

(7/1/88)

Instrument: 1050 Analyst: MGB

Weight: Acct, No,

0. 004


No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 "^

20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

Name ISl IS2 183 SSI SS2 SS3 45V 46V 88V 16V 44V 13H 15H 29V 13V 30V 23V IOV 14H U V 6V 19H 48V 15V 32V 33VT 87V 51V 14V 4V

33VC 19V 47V

BROMOCHLOROMETHANE 1,4-DIFLUOROBENZENE CHL0R0BENZENE-D5 DICHL0R0ETNANE-D4 T0LUENE-D8 BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ^"^ ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE 2-BUTAANONE 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2, 2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPANE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROEtHYL VINYL ETHER BROMOFORM


38V 18H 20H XYLEN

2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES ,

IES

No 1 2 3 \ 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 09 )

31 32 33 34 35 36 37 38 39 40 41 42

m/z 128 114 117 69 98 95 50 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 173 43 164 92 112 106 104 106 106

Scan 302 608 758 383 721 903 56 90 112 142 208 226 1 254 288 327 347 364 386 384 i 425

Time 10:04 20: 16 25: 16 12:46 24:02 30:06 1:52 3:00 3:44 4:44

- 6: 56 A 7 : 3 2 ^ 8 : 2 8

9:36 10: 54 11:34 12:08 12:52

^12: 48 14: 10

436 ^ 4 : 32 439* 450 685 492 499 515 534 537 531 538 570 615

/14:38 15:00 22: 50 16:24 16:38 17: 10 17:48 17: 54 17:42 17: 56 19:00

,i20: 30 615*^0:30 678' 687 727 762 824 949' 991 959

^22:36 22: 54 24: 14 25:24 27:28

^31:38 33: 02 31: 58

Ref 1 2 3 1 3 3 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3

1. 1. 1. 1. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 1, 1, 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 0. 0. 0. 1. 1. 1. 1. 1.

RRT 000 000 000 268 951 191 185 298 371 470 689 748 841 954 083 149 205 278 632 699 717 722 740 127 809 821 847 878 883 873 885 937 012 012 894 906 959 005 087 252 307 265

Meth A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

BB BB BB BB BB BB BB BB BB BB BB BB BB BB BV BB BB VB BB BB VB BB BB BB BB BB BV BB BB BB BB BB BB BB BB BB BB BB BB BB BB BB

Area(Hght) 145333. 872637. 700455, 254664, 951328. 514760. 14605.

194855. 50107.

118462. 225183. 60367.

467839. 203793, 374517. 228173. 416908. 247508. 23073.

204144. 183881. 403641. 365967. 436568. 329140. 438246. 278548. 182993. 248338. 827357. 137597. 115055. 123203. 123203. 172262. 212563. 538967. 633021. 307874. 1291510. 628664. 341288.

Amount 50. 000 50. 000 50, 000

110. 327 96. 176 89. 597 34. 747 43. 237 32. 900 42. 399 39. 558 52. 470 34.661 42, 564 41, 799 44.210 43, 843 47, 149 49. 031 35. 213 34. 523 37. 093 38, 313 41, 661 36. 508 38. 374 45. 897 29, 193 41, 627 43, 253 37, 770 42. 928 37. 043 46. 867 40. 194 42. 764 43, 162 42. 510 43. 068 104. 822 82. 891 41. 767

UG/L UG/L UO/L X X X UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L

XTot 2. 47 2.47 2.47 5. 46 4.76 4. 43 1.72 2. 14 1, 63 2, 10 1,96 2. 59 1,71 2, 10 2. 07 2. 19 2, 17 2,33 2, 42 1.74 1,71 1. 83 1.89 2, 06 1, 81 1, 90 2. 27 1, 44 2,06 2, 14 1,87 2. 12 1. 83 2. 32 1.99 2. 11 2. 13 2. 10 2. 13 5. IS 4. 10 2. 07

^LA^ AnalyticalTechnologies, Inc

7r)Ld-yUB

TEST

QUALITY CONTROL DATA

SEMI-VOLATILE ORGANICS (EPA 625)

CLIENT PROJECT # PROJECT NAME

MONTGOMERY & ASSOCIATES 661D HASSAYAMPA

ATI I.D.


806170

80700203 08/11/88 AQUEOUS UG/L

COMPOUNDS


1,2,4-TRICHLOROBENZENE ACENAPHTHENE 2,4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1,4-DICHLOROBENZENE PENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL

ND ND ND ND ND ND ND ND ND ND ND

50 50 50 50 50 50 100 100 100 100 100

38 58 40 58 49 27 64 45 60 44 31

76 116 80 116 98 54 64 45 60 44 31

33 56 32 53 42 29 54 56 66 45 27

66 112 64 106 84 58 54 56 66 45 27

14 4 22 9 15 7 17 22 10 2 14


Spike Concentration X 100


Average of Spiked Sample

TR - Compound detected at an unquantifiable trace level

X 100

O Z ^ - Ay)7o -Û7?

RIC 08/11/98 0:38:00

DATA: 8U70023MS ttl CALI: S070023NS #2

SCANS 1 TO •:3yo

SAriPLE: JOB 807802-3 MATRIX SPIKE CONDS.: RANGE: G 1,2300 LABEL: N 8, 4 . 0 QUAN: A 0, 1.8 J O BASE: U 20 , 3

100.0-1

RIC

T 500 8:20

IAMLCZSJ I . U y k^ lA. t r 1000 16:40

1500 25:00

^ \ '\K r €

323584.

• \ f

2000 33:20

SCAN TIME


REPORT

DIAGNOSTIC REPORT TCA 8070023MS 8070023MS Kl INITIALIZATION OPTION: XI

8/11/88 9: 5B •i-


PROC 2 2 2 2 2 2 2 2 1

STANDARDS -USED POSS

2 2 2 2 2 2 2 2 2 5

X PLUS UNKNOWNS X - LIST NAMES - > RMS 302

0 0 0 0 0 0 0 0

PROC USED POSS RMS STANDARD/UNKNOWN 11 9 9 9 12 12 11 10 7

7 5 2 5 3 7 5 5 0

8 6 1 1 1 2 1 1 1

1191 105

0 76 71

346 60 52 0

Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6


COMPOUND X 0 LIB 1 SV 2 SV 3 SV 4 SV 5 SV A CU

ENTRY 1 2 14 15 16 17

REF -399 -589 -256 -381 -366 -^TP

PRED 402 593 252 377 362 n7A

— SEARCH — SEL 404 591

.

386 .

DELTA 2

-2

9 .

PEAKS 2 1

1 .

>

FIT 990 985

.

993

• < SAT PEAKS

-1

.

X M/Z 152 136 42 94 93 O T

— CHRO TOP DELTA PEAfS 404 1 591 251 1 386 1

9 10 11 12 13 '4 i5

16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39

;o 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 I O

SV SV

sv SV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv eu

20 21 22 7 8

23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 7.T

-427 -437 -427 -380 -241 -464 -458 -464 -480 -471 -857 -490 -529 -538 -563 -603 -573 -581 -487 -585 -591 -614 -626 -702 -697

-1078 -735 -753 -753 -769 -800 -839 -831 -872 -861 -881 -763 -979 -923 -886 -902 -902 -949 -946 -938

-1357 -1483 -962 -968

-1018 -1033 -1067 -1087 -1087 -1200 -1293 -1689 -1333 -1763 -1293 -1424 -2007 -1486 -1 ^DO.

423 433 423 385 249 468 462 468 483 474 858 492 531 540 565 605 575 583 491 588 594 617 629 704 699 1079 737 755 755 771 802 841 833 873 862 882 766 982 926 889 905 905 952 949 941 1360 1484 964 970 1020 1035 1069 1089 1089 1202 1295 1691 1335 1765 1295 1426 2009 1488 tnPA

411 -12

411 -12 385 250 1

, 482 -1

858

, ,

, ,

491 588

, , .

705 1 .

1079 ,

,

863 1

765 -1 982 933 7

904 -1 904 -1

1484

, ,

1069

1202 1295 1691 1335

1295 ,

, , , ,

1526

2

2 2 3

1

1

1 1

1 , 1 .

.

. 1

1 1 2

1 1

1

1

1 1 1 1

1

.

1

996

998 993 991

977

993

994 995

,

, 967

, 982

,

994

997 992 981

, 986 891

993

, ,

983

985 972 989 993

, 979

, ,

917

146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142

L 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149

385 250

482

858

491 588 594

705

1079

835

863

765 982 933

904 904 951

1484

1069 1090 1090 1202 1295 1691 1335

1295

1526

75 76 77 78 79 "go

sv sv sv SV SV SV

76 -1640 77 -1680 78 -1680 79 -1935 80 -1890 81 -1935

1640 1680 1680 1935 1890 1935

252 252 252 276 278 276

Quantitation Report File: B070023MS

Data: 8070023MS. TI 08/11/88 0:38:00 Sample: JOB 807002-3 MATRIX SPIKE Conds. : 5 Formula: IUL INJECTION Instrument: 1050 Submitted by: Analyst: RGM

Weigh t: Acct, No.

0. 003

AM0UNT=AREA » REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 1 2 3

5 6 7

Name ISl IS2 61B 65A 5H 18B 24A

8 26B

10

19> 13 14 15

6H 25B SS2 SSI 2H 42B

1. 4-DICHL0R0BENZENE-D4 (SVttl) NAPHTHALENE-D8 (SV#2) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SV«15) ANILINE (SV#16) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SVttlS) 1. 3-DICHLOROBENZENE (SV«19) 1, 4-DICHLOROBENZENE J£i(:«20) BENZYL ALC"OFfOL (SV«21) 1.2-DICHLOROBENZENE (SV»22) PHEN0L-D5 (SV#7) 2-FLUOROPHENOL (SV«8) 2-METHYLPHENOL (SV#23) BIS(2-CHLOROISOPROPYL)ETHER (SV#24)

IB 19 20 21 22 ?3 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 tg (43 44 45 46 47

12B 153 56B 54B 57A 34A IH 43B 31A SS3 8B 55B 7H 52B 22A 9H IS4 53B 21A 4H 20B lOH 71B 77B IIH IB 59A SS4 SS5 SSA

HEXACHLOROETHANE (SV#27) ACENAPHTHENE-DIO (SV#3) NITROBENZENE (SV#28) ISOPHORONE (SVtt29) 2-NITROPHENOL (SV#30) 2,4-DIMETHYLPHENOL (SV»31) BENZOIC ACID (SV#32) BIS(2-CHLOROETHOXY)METHANE (SV#33) 2.4-DICHLOROPHENOL (SV«34) NITR0BENZENE-D5 (SV#9) 1,2.4-TRICHLOROBENZENE (SV#35) NAPHTHALENE (SV#36) 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SV#38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SV«40) PHENANTHRENE-DIO (SVtt4) HEXACHLOROCYCLOPENTADIENE (SV#41)

4,6-TRICHLOROPHENOL (SV#42) 4, 5-TRICHLOROPHENOL (SV#43)

2-CHLORONAPHTHALENE (SV#44) 2-NITROANILINE (SV#45) DIMETHYL PHTHALATE (SV»46) ACENAPHTHYLENE (SVtt47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SV«49) 2,4-DINITROPHENOL (SV#50) 2-FLUOROBIPHENYL (SV#10) 2. 4. 6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SV#51)

y7 = /v/-A/'TTee5i> >T)J-AJ-(i>/iof>vjt/»MiAjG

2.

No Name 48 8H DIBENZOFURAN (SVtt52) 49 35B 2,4-DINITROTOLUENE (SV#53) 50 36B 2.6-DINITROTOLUENE (SV#54)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

m/i 152 136 42 94

NOT NOT 128 NOT NOT NOT NOT 99 112 NOT NOT NOT 70

NOT 164 NOT NOT

Scan 404 591 251 386

FOUND FOUND

384 FOUND FOUND FOUND FOUND

385 250

FOUND FOUND FOUND

482 FOUND

858 FOUND FOUND

Time 6: 44 9: 51 4: 11 6: 26

6:24

/ t G ^

6: 25 4: 10

8:02

14: 18

Ref 1 2

A 6> v.*

1

AoL,

1 1

1

19

1, 1. 0. 0.

0.

0. 0.

1.

1.

RRT 000 000 621 955

950

953 619

193

000

Mc A A A A

A

A A

A

A

(th BV BB BB BB

BB

BB BV

BV

BB

Area(Hght) 68200,

331493. 3>§.

71948.

79013,

J^\1G^-

45172. 26833,

39146.

190798.

Amc 100, 100. 58. 44,

60.

33. 29.

48.

100.

>unt 000 000 012 913

124

729 102

751

000

NG/UL NG/UL NG/UL NG/UL

NG/UL

NG/UL NG/UL

NG/UL

NG/UL

XTot 6. 61 6. 61 3.83 2. 97*^^

3. 97^*^

7 ' 2, 23 t; 1.92 5 -

3, 22-^

6, 61

24 25 26 27 28 9

-.0 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

NQT NOT NOT 82 180 128 NOT NOT 107 NOT 188 NOT NOT NOT NOT NOT NOT 152 NOT 153 NOT 172 330 139 NOT 89 165

FOUND FOUND FOUND

491 588 594

FOUND FOUND

705 FOUND 1079

FOUND FOUND FOUND FOUND FOUND FOUND

835 FOUND

863 FOUND

765 982 933

FOUND 904 904

8: 11 2 0. 831 A BB 9: 48 2 0. 995 A BB 9: 54 2 1. 005 A BB

11: 45 2 1. 193 A BB

17: 59 34 1. 000 A BB

13: 55 19 0. 973 A BB

14:23 19 1.006 A BB

46577. 53224.

670.

48805.

295169,

445.

94284.

41. 856 NG/UL 2, 77 37. 576 NG/UL 2.48-^ ' 0, 193 NG/UL 0,01

43. 971 NG/UL 2. 91 ^ ' ^

100, 000 NG/UL 6 61

4«.

12: 45 19 0. 892 A BB 16: 22 19 1, 145 A BB 15: 33 19 1. 087 A BB

15:04 19 1. 054 A BB 15: 04 19 1. 054 A BB

115528.

Jb 130^

14953. 24849.

0. 133 NG/UL 0. 01

57, 899 NG/UL 3. 83 / ^

46. 010 NG/UL 3. 04 35. 359 NG/UL 2. 34 , 30. 937 NG/UL 2. 04/'^

39. 670 NG/UL 2. 62 38. 7 NG/UL 2. 51

/ /

Quantitation Report File: a070023MS

Data: 8070023MS, TI 08/11/88 0:38:00 Sample: JOB 807002-3 MATRIX SPIKE Conds. : 5 Formula: IUL INJECTION Submitted hy:

Instrument: 1050 Analyst: RGM

Weight: Acct. No.

0, 003

AMOUNT=AREA » REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

DIETHYL PHTHALATE (SV«55) 4-CHLOROPHENYLPHENYL ETHER (SV«56) FLUORENE (SV»57) 4-NITROANILINE (SV#58) CHRYSENE-D12 (SV#5) 2-METHYL-4,6-DINITROPHENOL (SV»59) N-NITROSODIPHENYLAMINE (SV#60) 4-BROMOPHENYLPHENYL ETHER (SV#61) HEXACHLOROBENZENE (SV#62) PENTACHLOROPHENOL (SV#63) PHENANTHRENE (SVtt64) ANTHRACENE (SV#65) DI-N-BUTYL PHTHALATE (SV#66) FLUORANTHENE (SV#67) PERYLENE-D12 (SV«6)

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65

Name 70B 40B SOB 12H IS5 60A 62B 41B 9B 64A 81B 78B 68B 39B 186

60 84B' PYRENE (SV«69) 69 67B BUTYL BENZYL PHTHALATE (SV<*70) 70 28B 3.3'-DICHLOROBENZIDINE (SV»71) 71 72B BENZO(A)ANTHRACENE (SV#72) 72 66B BIS(2-ETHYLHEXYL)PHTHALATE (SV«73) 73 76B CHRYSENE (SV»74) 74 69B DI-N-OCTYL PHTHALATE (SV#75) 75 74B BENZO(B)FLUORANTHENE (SV#76) 76 74B BENZO(K)FLUORANTHENE (SV#77) 77 73B BENZO(A)PYRENE (SV#78) 78 83B INDENOd, 2, 3-CD)PYRENE (SV#79) 79 82B DIBENZO(A.H)ANTHRACENE (SV#80) 80 79B BENZO(G. H, DPERYLENE (SV#81)

No 51 52 53 54 55 56 57 58 59 60 61 62 63

m/z 149 NOT NOT NOT 240 NOT NOT NOT NOT 266 178 178 149

Scan 951

FOUND FOUND FOUND 1484

FOUND FOUND FOUND FOUND 1069 1090 1090 1202

Time Ref RRT Meth 15: 51 19 1. 108 A BB

24: 44 55 1. 000 A BB

17: 49 18: 10 18: 10 20: 02

34 34 34 34

0. 991 1. OIO 1. 010 1. 114

A A A A

BB BB BB BB

Area(Hght) 292.

156963.

22381. 434. 434.

135230.

Amount XTot 0. 177 NG/UL 0. 01

100.000 NG/UL 6. 61

64. 274 NG/UL 0.138 NG/UL 0.138 NO/UL 61.890 NO/UL

4. 25 0. 01 0. 01 4, 09

/ y

7

No 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 NOT NOT NOT 149 NOT 149 NOT NOT NOT NOT NOT NOT

Scan 1295 1691 1335

FOUND 1295


FOUND 1615


Time 21: 28: 22:

21:

25:

26:

35 11 15

35

26

55

Ref 34 65 55

55

55

65

1 1. 0.

0.

1.

0.

RRT 200 000 900

873

028

955

Me A A A

A

A

A

Jth BB BB BB

BB

BB

BB

Area(Hght) 121006, 140729. 94744.

121006.

1057.

168.

Amount 58. 062 100. 000 54. 099

57. 764

0. 922

0. 098

NG/UL NG/UL NO/UL

NG/UL

NG/UL

NG/UL

XTot 3. 84 6. 61 3, 57

3. 82

0. 06

0. 01

t y "

\ \t,t'

^Ztr -^p'^'^^s s / '

RIC DATA: 807002.3MSD #1 QSiilzSa 1:43:00 CALI: 8070023MSD #2 SAMPLE: -JOB 807882-3 MATRIX SPIKE DUPLICATE CONDS.: GCl - ^ RANGE: G 1..2022 LABEL: N O, 4 . 0 QUAN: A O.. 1.8 J 0

5CANS 1 TO 2022 A

BASE: U 20.. 3

100.0-1 .39014'

RIC

,

•

.>w^

-0 n Cf n n

a Z 00 D CO O V. u. ^

» H

O -v 00

^ o .. IU H I < 0) M Q Z UJ «-« I IL cn

1 . ^

<t z o •-< H- U.

LLi 500 8:20

: b ^ T ' " - r

. L 1, I 1 ^

^ 000 ,6:40

u : w ^ . ' i I

U. I ' ' r k. 1500 25:00

2000 SCAI TIM':


REPORT

'••- — ^ ^

PROC 2 2 2 2 2 2 2 2 1

STr USI

TCA 8070023MSD 8070023MSD Kl XI

fl^NDARDJ

DIAGNOSTIC

INITIALIZATION

, 3 —

ED POSS 2 2 2 2 2 2 2 2 5

2

2 1 0

.. ^ "S../"

*—"~ y \ . RMS 219

0 0 0 0 0 44 0 0

OPTION:

PLUS PROC

11 9 9 9 12 12 11 10 7

REPORT 8/11/86

2 PROCESSING OPTION: 3

UNKNOWNS USED

7 5 2 5 3 7 6 5 0

POSS 8 8 1 2 1 3 2 1 1

>

RMS 1203 81 0

94 0

353 151 0 0

< - LIST NAMES - > STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6

10 1 : O-r


COMPOUND X .NIO LIB ENTRY 1 BV 1 2 SV 2 3 SV 14 4 SV 15 5 SV 16 6 SV 17

REF -399 -589 -256 -381 -366 -378

PRED 401 592 250 376 361 373

— SEARCH — SEL DELTA 403 591

385

2 -1 ,

9

PEAKS 2 1 ,

1

FIT 993 984

992

< SAT PEAKS

-1 . , .

X M/Z 152 136 42 94 93 Q T

-— CHRO TOP DELTA PEAKS 403 1 591 • 1 250 1 385 1

,/

9 10 11 12 13 4

i5 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39

to 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72

SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

20 21 22 7 8

23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73

-427 -437 -427 -380 -241 -464 -458 -464 -480 -471 -857 -490 -529 -538 -563 -603 -573 -581 -487 -585 -591 -614 -626 -702 -697

-1078 -735 -753 -753 -769 -800 -839 -831 -872 -861 -881 -763 -979 -923 -886 -902 -902 -949 -946 -938

-1357 -1483 -962 -968

-1018 -1033 -1067 -1087 -1087 -1200 -1293 -1689 -1333 -1763 -1293 -1424 -2007 -1486 -1524

422 432 422 384 246 467 461 467 483 474 859 492 531 540 565 605 575 583 490 588 594 617 629 705 700 1080 737 755 755 771 802 841 833 874 863 883 766 983 927 890 906 906 953 950 942 1362 1485 966 972 1021 1036 1070 1090 1090 1203 1295 1691 1335 1765 1295 1426 2009 1488 1526

410

410 583 247

482

859

,

490 588

706

1080 . ,

. 863

765 983 934

905 905

1485

974

1069 ,

1202 1295 1691 1335

1295 .

, 1526

-12

-12 -1 1

-1

1

-1

7

-1 -1

..

2

-1

-1

2

2 2 4 ,

1

1

1 1

. 2

1

.

.

. 1

1 1 3

1 1

2

1

2

1 1 1 1

1

.

. i

996

995 979 992

.

974

996

996 997

969

990

.

994

997 998 910

984 892

995

752

979

981 979 991 994

986

9( 9

146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142

I 188 237 196 196 162 65 163, 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149

411 1

411 1 383 247

482

859

490 588

706

1080

835

863

765 983 934

905 905

1484 -1

974

1069

1202 1295 1691 1335

1295

1 Ôf-,

/•b 7b 77 78 79 ^0

SV SV SV SV SV SV

76 77 78 79 80 81

-1640 -1680 -1680 -1935 -1890 -1935

1640 1680 1680 1935 1890 1935

252 252 252 276 278 276


Data: 8070023MSD. TI 08/11/88 1:43:00 Sample: JOB 807002-3 MATRIX SPIKE DUPLICATE Conds. : GCl Formula: IUL INJECTION Instrument: 1050 Submitted by: Analyst: RGM

AMaUNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

We igh t: Acct, No.

0. 003

No 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15

Name ISl IS2 61B 65A 5H 18B 24A 26B 27B 6H 25B SS2 SSI 2H 42B

1. 4-DICHLDRDBENZENE-D4 (SVttl) NAPHTHALENE-D8 (SV*»2) N-NITROSODIMETHYLAMINE (SV«14) PHENOL (SV#15) ANILINE (SV#16) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1,3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SV#21) 1,2-DICHLOROBENZENE (SV«22) PHEN0L-D5 (SV#7) 2-FLUOROPHENOL (SV#8) 2-METHYLPHENOL (SV#23) BIS(2-CHLOROISDPROPYL)ETHER (SV»P4)

18 19 20 21 22 13 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

12B I S3 56B 54B 57A 34A IH 43B 31A SS3 8B 55B 7H 52B 22A 9H IS4 53B 21A 4H 20B lOH 71B 77B U H IB 59A SS4 SS5 58A

HEXACHLOROETHANE (SV#27) ACENAPHTHENE-DIO (SV#3) NITROBENZENE (SV#28) ISOPHORONE (SVtt29) 2-NITROPHENOL (SV#30) 2.4-DIMETHYLPHENOL (SV#31) BENZOIC ACID (SV#32) BIS (2-CHL0R0E,TH0X Y) METHANE (SV#33) 2.4-DICHLOROPHENOL (SV#34) NITR0BENZENE-D5 (SV#9) 1,2,4-TRICHLOROBENZENE (SV#35) NAPHTHALENE (SV#36) 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SVtt38) 4-CHL0R0-3-METHYLPHEN0L (SVtt39) 2-METHYLNAPHTHALENE (SV#40) PHENANTHRENE-DIO (SV«4) HEXACHLOROCYCLOPENTADIENE (SV#41) 2,4,6-TRICHLOROPHENOL (SV#42) 2, 4, 5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV#44) 2-NITROANILINE (SV#45) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SV#47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SV#49) 2,4-DINITROPHENOL (SV#50) 2-FLUOROBIPHENYL (SV#10) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SV#51)

No 48 49 50

No 1 2 3 4 5 6 7

e 9 10 11 12 13 14 15 16 17 18 19 20 21

Name 8H 35B 36B

m/z 152 136 42 94

NOT NOT 128 146 146 NOT 146 99 112 NOT NOT NOT 70

NOT 164 NOT NOT

DIBENZOFURAN 2,4-2, 6-

Scan 403 591 250 385

FOUND FOUND

383 411

-4-Jrl FOUND

411 383 247

FOUND FOUND FOUND

482 FOUND

859 FOUND FOI IND

(SV#52) •DINITROTOLUENE (SVtt53) •DINITROTOLUENE (SVtt54)

Time 6: 43 9: 51 4: 10 6:25

6:23 6: 51

y, 6: 51 ^ 0 ^

6: 51 6: 23 4: 07

8: 02

14: 19

Ref 1 2 1 1

1 1 1

1 1 1

1

19

RRT 1, 000 1. 000 0. 620 0. 955

0. 950 1. 020 1. 020

1. 020 0. 950 0, 613

1. 196

1. 000

Meth A A A A

A A A

A A A

A

A

BV BB BB BB

BB VB VB

VB BB BB

BV

BB

Area(Hght) 71018.

351876. ^ 6 ,

93566.

90718. 13567.

-4a§67, -^9= %-2.^\ 13567. 57323, 32461.

35371.

190829.

Amount 100. 000 100. 000 51. 856 56. 089

66. 291 8. 597 8. 597

8. 597 41. 103 33, 810

42. 302

100. 000


NG/UL NG/UL NG/UL

NG/UL NG/UL NG/UL

NG/UL

NG/UL

XTot 6, 67 6, 67 3. 46 / 3. 74 y - z y

4. 42 / -^

"kAi/^y V

0. 57 2. 74 2, 26

2 82 >-^

6. 67

o 1

* A^

6^

24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

NOT NOT NOT 82 180 NOT NOT NOT 107 NOT 188 NOT NOT NOT NOT NOT NOT 152 NOT 153 NOT 172 330 139 NOT 89 165

FOUND FOUND FOUND

490 588

FOUND FOUND FOUND

706 FOUND 1080


835 FOUND

863 FOUND

765 983 934

FOUND 905 905

8: 10 2 0. 829 A BB 9: 48 2 0. 995 A BB

11: 46 2 1. 195 A BB

18: 00 34 1. 000 A BB

13: 55 19 0. 972 A BB

14: 23 19 1. 005 A BB

12: 45 19 0. 891 A BB 16: 23 19 1. 144 A BB 15: 34 19 1. 087 A BB

15: 05 19 1. 054 A BB 15: 05 19 1. 054 A BB

44563. 49395.

52934.

277077.

37. 726 NG/UL 2. 52 32. 853 NG/UL 2. 19 »^

44. 928 NG/UL 3. 00

100. 000 NG/UL 6. 67

239.

91537.

111229. 9582. 5404.

12094. 22233,

0.

56.

44. 33. 27.

32. 34.

071

203

291 117 271

080 001

NG/UL

NG/UL

NG/UL NG/UL NG/UL

NG/UL NG/UL

0.

3.

2. 2. 1.

2, 2.

00

75

96 21 82

14 27


Data: 8070023MSD. TI 08/11/88 1:43:00 Sample: JOB 807002-3 MATRIX SPIKE DUPLICATE Conds. : GCl Formula: IUL INJECTION Instrument: 1050 Submitted by: ' Analyst; RGM

AMOUNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

Wei ght: Acct. No,

0. 003

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65

Name 70B 40B SOB 12H IS5 60A 62B 41B 9B 64A 81B 78B 68B 39B IS6

DIETHYL PHTHALATE (SV#55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56> FLUORENE (SVtt57) 4-NITROANILINE (SV#58) CHRYSENE-D12 (SV«5) 2-METHYL-4,6-DINITROPHENOL (SV#59) N-NITROSODIPHENYLAMINE (SVtt60) 4-BROMOPHENYLPHENYL ETHER (SV«61) HEXACHLOROBENZENE (SV#62) PENTACHLOROPHENOL (SV#63) PHENANTHRENE (SV«64) ANTHRACENE (SVtt65) DI-N-BUTYL PHTHALATE (SV#66) FLUORANTHENE (SV#67) PERYLENE-D12 (SV*»6)

68 8413 PYRENE (SV#69) 69 67B BUTYL BENZYL PHTHALATE (SVtt70) 70 28B 3,3'-DICHLOROBENZIDINE (SV#71) 71 728 BENZO(A)ANTHRACENE (SV#72) 72 66B BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) 73 76B CHRYSENE (SV#74) 74 69B DI-N-OCTYL PHTHALATE (SV#75) 75 74B BENZO(B)FLUORANTHENE (SV#76) 76 74B BENZO(K)FLUORANTHENE (SV«77> 77 73B BENZO(A)PYRENE (SVtt78) 78 83B INDENOd, 2. 3-CD>PYRENE (SV#79) 79 828 DIBENZO(A,H)ANTHRACENE (SV#80) 80 798 BENZO(G, H, DPERYLENE (SV#8l)

No m/z Scan 51 NOT FOUND 52 NOT FOUND 53 NOT FOUND 54 NOT FOUND 55 240 1484 56 NOT FOUND 57 169 974 58 NOT FOUND 59 NOT FOUND 60 266 1069 61 NOT FOUND 62 NOT FOUND 63 149 1202

Time Ref RRT Meth

24: 44 55 1. 000 A BB

16: 14 34 0. 902 A BB

17: 49 34 0. 990 A BB

20:02 34 1. 113 A VB

Area(Hght> Amount XTot

146098. 100. 000 NG/UL 6. 67

522, 0. 428 NG/UL 0. 03

17494, 53. 520 NG/UL 3, 57,

118279, 57.666 NO/UL 3,85

No 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 NOT NOT NOT 149 NOT NOT NOT NOT NOT NOT NOT NOT

Scan 1295 1691 1335

FOUND 1295


FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

T: 21: 28: 22:

21

25

ime 35 11 15

35

26

Ref 34 65 55

55

55

1. 1. 0.

0.

1.

RRT 199 000 900

873

028

Meth A A A

A

A

BB BB BB

BB

BB

Area(Hght) 103498. 120900. 81217.

103498.

3754.

Amount 52.

100. 49.

53.

3.

904 000 824

081

517

NG/UL NG/UL NG/UL

NG/UL

NG/UL

XTot 3, 55 6. 67 3. 33

3. 54

0, 23

^ \ AnalyticalTechnologies, Inc

QUALITY CONTROL DATA: 482-3 & 985 METHOD 625 & 8270

>i7o -7uie>

ACCESSION: 806170

CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 8/5/88

1,4-DICHLOROBENZENE BIS (2-CHLOROISOPROPYL) ETHER HEXACHLOROETHANE NITROBENZENE NAPHTHALENE DIMETHYLPHTHALATE ACENAPHTHENE FLUORENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER ANTHRACENE FLUORANTHENE BUTYLBENZYLPHTHALATE CHRYSENE BIS (2-ETHYLHEXYL) PHTHALATE BENZO (b) FLUORANTHENE BENZO (a) PYRENE DIBENZO (a,h) ANTHRACENE BENZO (g,h,i) PERYLENE PHENOL 2-CHLOROPHENOL 2-NITROPHENOL 2,4-DIMETHYLPHENOL 2,4-DICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2,4,6-TRICHLOROPHENOL 4-NITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL

UND

24 4 2 3 0 4 5 2 1 3 2 1 7 4 2 7 3 42 3 0 2 2 4 8 8 3 2 7 32 2 0 3 3 7 6 7 5 9 0 7 9 8 5 6 8 7 2 1 1 0 9 8 2 5 9 2

ACTUAL

2 5 3 9 3 0 7 6 2 5 4 0 2 0 5 1 7 6 4 2 4 0 3 0 5 1 7 0 2 9 4 0 2 5 4 1 8 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0

90 / t% 7oe>

5 ^

8 0

S ^ t x 9Z. 7oo

75-

7 3

^ y / l ' l

9Z

ZO ?<9 80

9 ^ -75 96

7 9 ? i -^ 8

7 2

7/0

9 i 2 S

9z

PROJECT MANAGER; ^ I j DATE: 8/18/ 88

/ CPTTS-' yûj-^/XB

RIC 08/05/88 14:10:00 SAMPCET~5C 8/05/88 1-F482-3+WP385 1:1 CONDS.: GC5 RANGE: G'

DATA: QC805 #1 CALI: QC805 #2

SCAN^ 1 TO 2300

1..2300 LABEL: N O.. 4.0 QUAN: A 8,. I.O J O BASE: U 28.. 100.0-1 *-\*-.r.r\Ar.

i-:>oo4o.

RIC

Aa - ^ L v u i Jy 500 O. OC

1000 16:40

t 1500 25:00

j \ .

2000 33:20

SCAN ;IME

PROCEDURE DATA FILE -"TFERENCE •ME LIST REPORT

<

PROC 2 2 2 2 2 2 2 2 1 2 2 2 2 2 2 2 2 1 2 2 2 2 2 2 2

TCA QC805 QCa05

DIAG


STANDARDS US ED POSS

2 1 2 1 2 1 2 1 2 1 2 1 2 ] 2 ] 6 C 2 1 2 1 2 1 2 ] 2 ] 2 1 2 : 2 ] 10 ( 2 2 2 ] 2 2 2 2

X ! RMS

0 0 0 0 0 0 0 0

) 0 L 0 L 0 L 0 L 0 L 0 L 0 L 0 L 0 ) 0 L 0 I 0 L 0 I 0 1 0 1 0 1 0

NOSTIC

OPTION

REPORT 8/05


PLUS UNKNOWNS PROC

11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

USED 7 4 6 4 6 4 7 6 4 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

POSS 2

>

RMS 1184

48 214 183 480 81

252 268 232 883 39 162 99

304 42 189 190 147 883 39 162 99

304 42 189

< - LIST NAMES - > STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4

8/05/88 14: 49: 34


COMPOUND > NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 .7 18 19 20 21 22 23

LIB SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv

ENTRY 1 2 14 15 16 17 18 19 20 21 22 7 8

23 24 25 26 27 3

28 29 30 31

< REF

-415 -600 -256 -398 -382 -393 -396 -408 -417 -451 -442 -397 -263 -480 -471 -503 -493 -485 -864 -503 -541 -550 -575

PRED 418 602 262 401 385 396 399 410 419 452 444 400 267 483 474 505 495 488 866 506 544 553 578

— SEARCH — SEL 418 602

406

401 420 420

420

,

474

,

487 866 505

553 578

DELTA

5 ,

2 10 1 .

-24 ,

.

,

,

,

-1

-1 ,

.

,

PEAKS 1 1

2

1 1 1

1

,

,

1 ,

1 1 1 .

1 I

X SAT X FIT PEAKS M/Z 981 979

,

987

987 985 990

987

,

938

.

955 986 957

.

961 993

152 136 42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122

CHRO -TOP DELTA PEAKS 418 602

406

401 420 420

420 401

,

,

474

487 866 505 545 553 578

1 1

1

1 1 1

1 1

1

1 1 1 1 1 1

26 27 28 29 30

n .2 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 7 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-595 -500 -596 -602 -628 -636 -713 -707

-1084 -744 -761 -773 -778 -809 -847 -839 -881 -868 -891 -772 -986 -940 -893 -853 -909 -956 -953 -945

-1337 -1486 -970 -975

-1025 -1039 -1074 -1087 -1093 -1205 -1266 -1692 -1337 -1763 -1297 -1427 -2007 -1483 -1527 -1489 -1616 -1643 -1643 -1683 -1886 -1898 -1942

598 503 599 605 631 639 716 710 1085 743 760 772 777 808 847 839 881 868 891 775 988 942 895 856 911 958 955 947 1337 1487 974 979 1028 1042 1077 1090 1096 1207 1268 1694 1339 1765 1299 1429 2009 1485 1529 1491 1616 1643 1643 1683 1886 1898 1942

602 .

604

718 ,

1085

764 764

848 ,

870

.

.

956 947

1487

1027

1077 1095 1095

1268 1694

1428

1490 1528 1490

1642 1642 1686

.

.

1942

4

-1

2

4 -8

1

2

1

-1

5 -1

-1

5 -1 -1

-1 -1 3

. ,

1

1

1

1

1 1

1

1

1 1

1

,

1

1 1 1

1 1 .

,

1 , 1 1 1

1 1 1

.

1

827 .

996

978

951

995 985

.

998

, ,

994

,

,

.

967 991

928

981

987 983 983

973 932

989

958 977 956

862 937 894

899

162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

600 -2 1

604 .

717 -]

1085

764 764

848

.

870

955 947

1487 975

1027

1077 1095 1095 1206 1268 1694

1301 1428

1490 1528 1490

1642 1642 1686

1942

1

L 1

1

1 1

1

1

1 1 1

1


ta: QC805. TI .j/05/88 14: 10: 00 Sample: QC 8/05/88 WP482-3+WP9a5 1:1 Conds. : GC5 Formula: Instrument: 1050 Weight: 50.000 Submitted by: Analyst: RGM Acct. No. :

AMaUNT=AREA * REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry

1.4-DICHL0R0BENZENE-D4 (SV#1) NAPHTHALENE-D8 (SV#2) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SV#15) ANILINE (SVttl6) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1.3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SV#21) 1,2-DICHLOROBENZENE (SV#22) PHEN0L-D5 (SV#7) 2-FLUOROPHENOL (SVttS) 2-METHYLPHENOL (SV«23) BIS(2-CHLOROISOPROP YL)ETHER (SV#24) 4-METHYLPHENOL (SV#25) N-NITROSO-DI-N-PROPYLAMINE (SV#26) HEXACHLOROETHANE (SV#27) ACENAPHTHENE-DIO (SV»3) NITROBENZENE (SV#28) ISOPHORONE (SVtt29) 2-NITROPHENOL (SVtt30) 2,4-DIMETHYLPHENOL (SV#31) BENZOIC ACID (SV#32) BIS(2-CHLOROETHOXY)METHANE (SV#33) 2,4-DICHLOROPHENOL (SVtt34) NITR0BENZENE-D5 (SV#9) 1,2,4-TRICHLOROBENZENE (SV#35) NAPHTHALENE (SVtt36) 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SV«38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SVtt40) PHENANTHRENE-DIO (SVtt4) HEXACHLOROCYCLOPENTADIENE (SV»41) 2,4,6-TRICHLOROPHENOL (SV#42) 2,4,5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV«44) 2-NITROANILINE (SVtt45) DIMETHYL PHTHALATE (SV»46) ACENAPHTHYLENE (SV#47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SV»49) 2.4-DINITROPHENOL (SV#50) 2-FLUOROBIPHENYL (SV#10) 2. 4. 6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SV#51)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 .6 17 IB 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name ISl IS2 61B 65A 5H 18B 24A 26B 27B 6H 25B SS2 SSI 2H 428 4H 63B 128 183 568 548 57A 34A IH 438 31A 553 SB 558 7H 528 22A 9H IS4 538 21A 4H 208 lOH 718 778 IIH IB 59A SS4 SS5 58A

No • 8

9 50

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 :2 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 17 48 49 50

Name 8H DIBENZOFURAN (SV#52) 358 2. 4-1 368 2. 6-1

m/z Scan 152 418 136 602 NOT FOUND 94 406

NOT FOUND NOT FOUND 128 401 146 420 146 420

"HOT FOUND 146 420 99 401

NOT FOUND NOT FOUND 45 474

NOT FOUND NOT FOUND 117 487 164 866 77 505 82 545 139 553 122 578 NOT FOUND NOT FOUND 162 600 NOT FOUND NOT FOUND 128 604 NOT FOUND NOT FOUND 107 717 NOT FOUND 188 1085 NOT FOUND 196 764 196 764 NOT FOUND NOT FOUND 163 848 NOT FOUND NOT FOUND 153 870 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND

DINITROTOLUENE (SV#53) DINITROTOLUENE (SV#54)

Time 6: 58 10: 02

6: 46

6: 41 7: 00 7:00

7:00 6: 41

7: 54

8:07 14: 26 8: 25 9: 05 9: 13 9: 38

10:00

10:04

11: 57

18: 05

12:44 12: 44

14:08

14: 30

\'h'\ ® '

Ref 1 2

1

1 1 1

1 1

1

1 19 2 2 2 2

2

2

2

34

19 19

19

19

W

RRT 1. 000 1. 000

0, 971

0. 959 1. 005 1. 005

1. 005 0. 959

1. 134

1. 165 1. 000 0. 839 0. 905 0. 919 0. 960

0. 997

1. 003

1. 191

1. 000

0. 882 0. 882

0. 979

1. 005

Meth A BB A BB

A 88

A 88 A 88 A 88

A 88 A BB

A BB

A BB A 88 A 88 A 88 A 88 A BB

A 88

A 88

A BB

A BB

A 88 A BB

A BB

A BB

Area(Hght) 53594. 197642.

18712.

23916. 13367. 13367.

13367. 1369.

23599.

4966. 102380. 22048.

468. 9887. 17905.

14117.

22679.

15727.

172507.

15175, 15175.

21519.

7990.

3O9I9

Amount 100. 000 100. 000

37. 344

44. 984 11. 954 12. 210

12. 922 2. 264

20. 826

15. 084 100, 000 22. 612 0. 289

39, 641 42. 314

33. 930

10. 390

36. 019

100. 000

55. 104 45. 489

16. 126

8. 709

NG/UL NG/UL

NG/UL

NG/UL NG/UL NG/UL

NG/UL NG/UL

NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

NG/UL

NG/UL

NG/UL

NG/UL

NG/UL NG/UL

NG/UL

NG/UL

XTot 7. 25 7. 25

2. 71

3. 26 0. 87 0. 89

0. 94 0. 16

1. 51

1, 09 7, 25 1 64 0. 02 2. 88 3. 07

2. 46

0, 75

2. 61

7. 25

4. 00 3. 30

1, 17

0. 63

' M ^

^ / ' ] s y

C j O ' ^

2 ^ ^

^

2 0 ^

^ y

^ . y (Jb"^

% \ ^

% ^

n.-

.v


lta: QC805. TI ^8/05/88 14: 10: 00 Sample: QC 8/05/88 Conds. : GC5 Formula: Submitted by:

WP482-3+WP985 1:1


Weight: Acct, No.

50. 000

AMOUNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63

Name 708 408 808 12H IS5 60A 628 418 9B 64A 818 788 688 398 IS6 SS6 58 848 678 288 728 66B 768 698 748 748 738 838 82B 798

m/z NOT 204 166 NOT 240 198 NOT 248 NOT 266 178 178 149

DIETHYL PHTHALATE (SV#55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56) FLUORENE (SV#57) 4-NITROANILINE (SV#58) CHRYSENE-D12 (SV#5) 2-METHYL-4,6-DINITROPHENOL (SV«59) N-NITROSODIPHENYLAMINE (SV#60) 4-BROMOPHENYLPHENYL ETHER (SV#61) HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SV#63) PHENANTHRENE (SV#64) ANTHRACENE (SV#65) DI-N-BUTYL PHTHALATE (SV«66) FLUORANTHENE (SV#67) PERYLENE-D12 (SV#6) TERPHENYL-D14 (SV#12) BENZIDINE (SV#68) PYRENE (SV#69) BUTYL BENZYL PHTHALATE 3.3'-DICHLOROBENZIDINE

(SV#70) (SV#71)

8ENZ0(A)ANTHRACENE (SV#72) 8IS(2-ETHYLHEXYL)PHTHALATE (SV#73) CHRYSENE (SVtt74) DI-N-OCTYL PHTHALATE (SV#75) BENZO(B)FLUORANTHENE (SV#76) BENZO(K)FLUORANTHENE (SVtt77) 8ENZ0(A)PYRENE (SV#78) INDENO(1,2.3-CD)PYRENE DIBENZO(A.H)ANTHRACENE

(SV#79) (SV#80)

BENZO(G.H, DPERYLENE (SV#81)

Scan Time Ref RRT FOUND

955 15: 55 19 1. 103 947 15:47 19 1.094

FOUND 1487 24:47 55 1.000 975 16:15 34 0.899

FOUND 1027 17:07 34 0.947

FOUND 1077 17:57 34 0. 993 1095 18:15 34 1.009 1095 18:15 34 1.009 1206 20:06 34 1. 112

Meth

A BB A BB

A 88 A BB

A 88

A BB A BB A 88 A BB

Area(Hght)

25539. 28746.

110093. 1030.

8519.

8880. 27714. 27714.

873.

Amount

36. 20.

100. 12.

21,

46. 14. 14. 0.

773 954

000 288

090

194 678 968 664

NG/UL NG/UL

NG/UL NG/UL

NG/UL


XTot

2. 1.

7. 0.

1.

3. 1. 1. 0.

67 52

25 89

53

35 06 09 05

^ ^

9^ A. "7 9T 3o

No \

o5 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 NOT NOT 202 149 NOT 228 149 228 NOT 252 252 252 NOT NOT 276

Scan 1268 1694

FOUND FOUND 1301 1428

FOUND 1490 1528 1490

FOUND 1642 1642 1686

FOUND FOUND 1942

Time 21:08 28: 14

21: 41 23: 48

24: 50 25:28 24: 50

27:22 27:22 28: 06

^ 7 < g (? 32: 22

Ref 34 65

55 55

55 55 55

65 65 65

1^0 65

1. 1.

0. 0.

1. 1. 1.

0. 0. 0.

^ 1

RRT 169 000

875 960

002 028 002

969 969 995

, 146

Meth A BB A BB

A BB A BB

A BB A BB A 88

A 88 A BB A BB

A BB

Area(Hght) 16753.

114947.

276. 7527.

38973. 5811.

38973.

19135. 19135. 10319.

// 4^0 27993.

Amount 11. 117

100. 000

0. 218 24. 002

32. 113 13. 254 41. 421

8. 204 8. 204 9. 753

NG/UL NG/UL

NG/UL NG/UL

NG/UL NG/UL NG/UL

NG/UL NG/UL NG/UL

o ' ^ n j ^ 37. 795 NG/UL

XTot 0. 81 1 7. 25

0. 02 . 1.74 ^*

2. 33 IM 0. 96 n^ 3. 00 <l)

0. 60 \W 0. 60 0. 71 1<=

7 n t

2,74 '^

y

y

A

A

6P75~ - ' > ^ U 7 ' ^ ^ ' ^

DATA: STD9O550 ttl CALI : STD80550 #2

;CHKS RIC 08. ' '^/88 10:12:00 SAMPLE: STD MIX 50NG (S.''5.''S8> CONDS.: GC5__ " RANGE: G l72300 LABEL: N 0, 4.0 QUAN: A 0, 1.0 J 8 BASE: U 20, 3

1 TO 2500

100.0-1

RIC

1508670.

25:00 33:20 SCAN •THE

Quantitation Report File: STDB0550

ta: STD80550. TI WJ/05/B8 10: 12:00 Sample: STD MIX 50NG (8/5/88) Conds. : GC5 Formula: Instrument: 1050 Weight: 50.000 Submitted by: Analyst: RGM Acct, No. :

AM0UNT=AREA » REF AMNT/(REF AREA * RESP FACT) Resp, fac. from Library Entry

1. 4-DICHL0R08ENZENE-D4 (SVttl) NAPHTHALENE-D8 (SV#2) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SV»15) ANILINE (SV#16) 8 IS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1. 3-DICHLOROBENZENE (SV»19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SVtt21) 1,2-DICHLOROBENZENE (SV<»22) PHEN0L-D5 (SV<*7) 2-FLUOROPHENOL (SV«8) 2-METHYLPHENOL (SV#23) BIS(2-CHLOROISOPROPYL)ETHER (SV#24) 4-METHYLPHENQL (SV#25) N-NITROSO-DI-N-PROPYLAMINE (SV#26) HEXACHLOROETHANE (SV#27) ACENAPHTHENE-DIO (SVtt3) NITROBENZENE (SV#28) ISOPHORONE (SV#29) 2-NITROPHENOL (SV#30) 2. 4-DIMETHYLPHENOL (SV#31) BENZOIC ACID (SV#32) BIS(2-CHLOROETHOXY)METHANE (SVtt33) 2.4-DICHLOROPHENOL (SV#34) NITR0BENZENE-D5 (SV«9) 1,2.4-TRICHLOROBENZENE (SVtt35) NAPHTHALENE (SV#36) 4-CHLOROANILINE (SV»37) HEXACHLOROBUTADIENE (SV4*38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SV#40) PHENANTHRENE-DIO (SV«4) HEXACHLOROCYCLOPENTADIENE (SV#41) 2.4,6-TRICHLOROPHENOL (SV#42) 2.4.5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV#44) 2-NITROANILINE (SV«45) DIMETHYL PHTHALATE (SV«»46) ACENAPHTHYLENE (SV«47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SVtt49) 2.4-DINITROPHENOL (SV«50) 2-FLUOROBIPHENYL (SV#10) 2.4.6-TRIBROMOPHENOL (SV#11) 4-NITROPHENOL (SV#51)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 .6 17 18 l"?. 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name ISl ISS 61B 65A 5H 18B 24A 26B 27B 6H 25B SS2 SSI 2H 42B 4H 63B 12B 183

" "SSB" 548 57A 34A IH 43B 31A SS3 88 55B 7H 52B 22A 9H IS4 538 21A 4H 208 lOH 71B 77B IIH IB 59A SS4 885 58A

No e ^ 50

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 ?i

23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 -

-/ 49 50

Name 8H 358 368

m/z 152 136 NOT 1 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165

DIBENZOFURAN 2.4-2,6-

Scan 418 603

-OUND 401 384 396 399 411 420 454 445 400 267 483 475 506 496 488 867 506 544 553 578 617 587 597 503 599 605 628 639 715 710 1087 747 764 774 781 811 850 842 878 871 892 775 989 934 896 856 913

(SVM52) DINITROTOLUENE (SV#53) DINITROTOLUENE (SV«»54)

Time 6: 58 10:03

6:41 6:24 6:36 6:39 6: 51 -TrOO 7:34 7:25 6:40 4:27 8:03 7: 55 8:26 8: 16 8:08 14:27 8:26 9:04 9: 13 9:38

10: 17 9:47 9: 57 8: 23 9: 59 10:05 10:28 10: 39 11: 55 11: 50 18: 07 12:27 12: 44 12: 54 13: 01 13:31 14: 10 14:02 14:38 14:31 14: 52 12: 55 16:29 15:34 14: 56 14: 16 15: 13

Ref 1 2

19 2 2 2 2 2 2 2 2 2 2 2 2 2 2

34 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19

RRT 1. 000 1. 000

0. 959 0. 919 0. 947 0. 955 0. 983 1. 005 1. 086 1. 065 0. 957 0. 639 1. 156 1. 136 1. 211 1. 187 1. 167 1. 000 0. 839 0. 902 0. 917 0. 959 1. 023 0. 973 0. 990 0. 834 0. 993 1. 003 1. 041 1. 060 1, 186 1. 177 1. 000 0. 862 0. 881 0. 893 0. 901 0. 935 0. 980 0. 971 1. 013 1. 005 1. 029 0. 894 1. 141 1. 077 1. 033 0. 987 1. 053

Me A A

A A A A A

th BB BB

VB BV VB BB BV

--A_V8 A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A

BB BB BV BB BB BB BB BV BB 88 88 BB 88 BV BV 88 BV 88 88 VB BB BB BV BV BB BB BV V8 VB 88 BV BB BV 88 88 BB BB BV 88 BB BB

Area(Hght) 122297. 344107.

5717£. 53632. 97776. 60660. 127580. 124912, 25664, 118029. 68979. 50476. 43710. 129287. 39430. 46195. 37563. 190572. 84883, 140885. 21712. 36836, 12150. 80444. 36219. 62868. 73546. 190013. 43169, 51238. 38010. 99119.

339482. 11401, 25631. 31048. 116922. 22827. 124200. JâS4^2. 14059. 85391. 3759.

125076. 24995. §797.

172903. 14633. 30288.

Amount 100, 000 100.000

50. 000 50. 000 50. 000 50.000 50. 000 50. 000 50. 000 50, 000 50. 000 50. 000 50. 000 50. 000 50, 000 50. 000 50.000

100. 000 50. 000 50. 000 50, 000 50, 000 50. 000 50. 000 50. 000 50. 000 50, 000 50. 000 50. 000 50. 000 50. 000 50.000

100, 000 50, 000 50, 000 50. 000 50. 000 50, 000 50, 000 50. 000 80, 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000

NG/UL NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NO/UL NO/UL NO/UL NO/UL NG/UL NO/UL NO/UL NG/UL NG/UL NG/UL

XT 2, 2.

ot 39 39

19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 39 19 19 19 19 19 19 19 19 19 19 19 19 19 19 39 19 19 19 19 19 19 19 91 19 19 19 19 19

. 19

. 19

. 19

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Ret(L) 6: 58 10:03 4: 16 6:41 6:24 6:36 6: 39 6: 51 7:00 7:34 7:25 6: 40 4: 27 8:03 7: 55 8: 26 8: 16 8: 08 14:27 8: 26 9: 04 9: 13 9: 38 10: 17 9:47 9: 57 8:23 9: 59 10: 05 10: 28 10: 39 11: 55 11: 50 18:07 12:27 12:44 12: 54 13: 01 13: 31 14: 10 14:02 14: 38 14: 31 14: 52 12: 55 16:29 15:34 14: 56 14: 16 15: 13

Ratio 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 1. 000 1. 000 0. 610 0. 959 0. 919 0. 947 0. 955 0. 983 1. 005 1. 086 1. 065 0. 957 0. 639 1. 156 1. 136 1. 211 1. 187 1. 167 1. 000 0. 839 0. 902 0. 917 0. 959 1. 023 0. 973 0. 990 0. 834 0. 993 1. 003 1. 041 1. 060 1. 186 1. 177 1. 000 0. 862 0. 881 0. 893 0. 901 0. 935 0. 980 0. 971 1. 013 1. 005 1. 029 0. 894 1. 141 1. 077 1. 033 0. 987 1. 053

Ratio 1. 00 1. 00

1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

Amnt 100. 00 100. 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

Amnt(L) 100. 00 100. 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50, 00 50, 00 50, 00 50. 00 50, 00

100. 00 50. 00 50, 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 80. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

R. Fac R, 1. 000 1. 000

0. 935 0. 877 1. 599 0. 992 2. 086 2. 043 0. 420 1. 930 1. 128 0. 825 0. 715 2, 114 0. 645 0. 755 0. 614 1. 000 0. 493 0. 819 0. 126 0. 214 0. 071 0. 468 0. 211 0. 365 0. 427 1. 104 0. 251 0. 298 0. 221 0. 576 1. 000 0. 120 0. 269 0. 326 1. 227 0. 240 1, 303 1, 692 0. 092 0, 896 0, 039 1. 313 0. 262 0, 061 1. 815 0, 154 0. 318

Fac(L) 1. 000 1. 000

0, 935 0. 877 1. 599 0. 992 2. 086 2, 043 0. 420 1, 930 1. 128 0. 825 0. 715 2. 114 0. 645 0. 755 0. 614 1. 000 0. 493 0. 819 0, 126 0. 214 0, 071 0. 468 0. 211 0, 365 0. 427 1. 104 0. 251 0. 298 0, 221 0. 576 1, 000 0. 120 0. 269 0. 326 1, 227 0, 240 1, 303 1, 692 0, 092 0. 896 0, 039 1. 313 0, 262 0. 061 1, 815 0, 154 0. 318

Ratio 1. 00 1. 00

1. 00 1, 00 1, 00 1. 00 1. 00 1. 00 1, 00 1, 00 1, 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1, 00 1, 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00


ta: STD80550.TI j/05/88 10:12:00

Sample: STD MIX 50NG Conds. : GC5 Formula: Submitted by:

(8/5/88)


Weight: Acct. No.

50. 000


No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 ,6 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 19 60 61 62 63

Name 708 408 808 12H IS5 60A 628 418 9B 64A 818 788 688 398 186 SS6 58 848 678 288 728 668 76B 698 748 748 738 83B 82B 79B

m/z 149 204 166 138 240 198 169 248 284 266 178 178 149

DIETHYL PHTHALATE (SV#55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56) FLUORENE (SV#57) 4-NITROANILINE (SV#58) CHRYSENE-D12 (SV#5) 2-METHYL-4. 6-DINITROPHENOL (SV#59) N-NITROSODIPHENYLAMINE (SV#60) 4-BROMOPHENYLPHENYL ETHER (SV#61) HEXACHLOROBENZENE (SV#62) PENTACHLOROPHENOL (SV#63) PHENANTHRENE (SVtt64) ANTHRACENE DI-N-BUTYL

(SV#65) PHTHALATE (SV#66)

FLUORANTHENE (SV#67) PERYLENE-D12 (SV#6) TERPHENYL-D14 (SV#12) BENZIDINE (SVtt68) PYRENE (SVtt69) BUTYL BENZYL PHTHALATE 3.3'-DICHLOROBENZIDINE

(SV#70) (SV#71)

BENZO(A)ANTHRACENE (SV#72) 8IS(2-ETHYLHEXYL)PHTHALATE (SV#73) CHRYSENE (SV#74) DI-N-OCTYL PHTHALATE (SV#75) BENZO(B)FLUORANTHENE (SV#76) BENZO(K)FLUORANTHENE (SV«*77) BENZO(A)PYRENE (SVtt78) INDENOd, 2. 3-CD)PYRENE DIBENZO(A,H)ANTHRACENE

(SVtt79) (SV#80)

BENZO(G,H, DPERYLENE (SV»81)

Scan Time 959 15: 59 956 15:56 948 15:48 1340 22: 20 1490 24: 50 973 16:13 978 16:18 1028 17: 08 1042 17:22 1077 17: 57 1090 18: 10 1097 18:17 1208 20:08

Ref RRT 19 1. 106 19 1. 103 19 1.093 19 1. 546 55 1.000 34 0. 895 34 0. 900 34 0. 946 34 0. 959 34 0. 991 34 1.003 34 1. 009 34 1. Ill

Meth A 88 A BB A BB A BB A 88 A 88 A BV A BB A 88 A BB A BV A VB A BB

Area(Hght) 105178. 64638, 127682,

1565. 259637.

8248. 78006. 39745. 65266. 18915.

185789. 182188. 129453.

Amount 50. 50. 50, 80, 100. 50, 50, 50. 50. 50. 50. 50. 50.

000 000 000 000 000 000 000 000 000 000 000 000 000

NG/UL NO/UL NO/UL NG/UL NO/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL

XTot 19 19 19 91 39 19 19 19 19 19 19 19 19

No •4 .,5 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 8 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 149 NOT 228 149 228 149 252 252 252 276 278 276

Scan T 1270 21 1697 28 1341 22

FOUND 1301 21 1431 23

FOUND 1487 24 1531 25 1493 24 1621 27 1647 27 1647 27 1687 28 1892 31 1902 31 1946 32

Ret(L) 15: 15: 15: 22: 24: 16: 16: 17: 17: 17: 18: 18: 20: 21: 28: 22: 29: 21: 23: 33: 24: 25: 24: 27: 27: 27: 28: 31: 31: 32:

59 56 48 20 50 13 18 08 22 57 10 17 08 10 17 21 23 41 51 27 47 31 53 01 27 27 07 32 42 26

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

ime Re' : 10 34 : 17 65 :21 55

:41 55 : 51 55

:47 55 : 31 55 : 53 55 :01 65 :27 65 :27 65 : 07 65 : 32 65 : 42 65 :26 65

RRT(L) 1. 106 1. 103 1. 093 1. 546 1, 000 0. 895 0. 900 0. 946 0. 959 0. 991 1. 003 1. 009 1. Ill 1. 168 1. 000 0. 900 0. 904 0. 873 0. 960 1. 003 0. 998 1. 028 1. 002 0. 955 0. 971 0. 971 0. 994 1. 115 1. 121 1. 147

f RRT 1. 168 1. 000 0. 900

0. 873 0. 960

0. 998 1. 028 1. 002 0. 955 0. 971 0. 971 0. 994 1. 115 1. 121 1. 147

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 , 00 . 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

. 00

Meth A BB A BB A BB

A BB A BB

A BV A BB A VB A BB A BB A BB A BB A BB A BB A BB

Amnt 50. 00 50.00 50. 00 80. 00 100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00

50. 00 50. 00

,

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

Area(Hght) 148280. 248821, 139815.

149583. 36978.

143108. 51697, 110947. 70928.

252434. 252434. 114510. 114068. 74260, 80165.

Amnt(L) 50. 00 50. 00 50, 00 80. 00 100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00

100, 00 50. 00

50. 00 50, 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00

Amount 50. 000

100. 000 50, 000

50. 000 50. 000

50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50, 000 50. 000

R. Fac R. 1. 104 0. 678 1. 340 0. 010 1, 000 0. 049 0. 460 0. 234 0, 385 0. Ill 1. 095 1. 073 0. 763 0, 874 1. 000 1. 077

1. 152 0, 285

1, 102 0, 398 0. 855 0. 570 2. 029 2, 029 0, 920 0, 917 0. 597 0. 644

NO/UL NG/UL NG/UL

NG/UL NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL

Fac(L) 1. 104 0. 678 1. 340 0, 010 1. 000 0. 049 0, 460 0. 234 0, 385 0, 111 1. 095 1. 073 0. 763 0, 874 1. 000 1. 077

1. 152 0. 285

1. 102 0. 398 0. 855 0, 570 2, 029 2. 029 0, 920 0, 917 0. 597 0. 644

XT ot 19 39 19

19 19

19 19 19 19 19 19 19 19 19 19

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 , 00 , 00 . 00 , 00

, 00 , 00

, 00 , 00 , 00 , 00 , 00 , 00 , 00 . 00 . 00 , 00

PROCEDURE DATA FILE

'ÊRENCE ..rtME LIST

REPORT

' • -

PROC 2 2 2 2 2 2 2 2 1 2

• 2

2 2 2 2 2 2 1 2 2 2 2 2 2 2

TCA STD80550 STD80550

DIAGNOSTIC


STANDARDS USI ED POSS

2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 8 C 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 10 C 2 ] 2 ] 2 ] 2 ] 2 ] 2 ] 2 ]

~ X RMS

0 0 0 0 0 0 0 0

• 0 0 0 0 0 0 0 0 0

) 0 0 0

L 0 0

L 0 0 0

OPTION.

REPORT 8/0


PLUS UNKNOWNS • PROC

11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

USED 10 9 9 9 11 11 11 8 7 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

POSS 48 8 3 3 4 1 4 4 4

V,

RMS 50 39 53 128 196 295 48 25 105 47 39 53

128 186 280 48 25 105 47 39 53

128 186 280 48

'C - LIST NAMES -STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4

1 7: 06


< COMPOUND X NO LIB ENTRY REF 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 '.6 17 18 19 20 21 22 23

SV SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv

1 2 14 15 16 17 18 19 20 21 22 7 8

23 24 25 26 27 3

28 29 30 31

-415 -600 -256 -398 -382 -393 -396 -408 -417 -451 -442 -397 -263 -480 -471 -503 -493 -485 -864 -503 -541 -550 -575

PRED 418 603 259 401 385 396 399 411 420 454 445 400 267 483 474 506 496 488 867 506 544 553 370

- SEARCH — SEL DELTA 418 603

401 384 396 399 412 420 454 445 400 267 483 475 506 496 488 867 506 544 553 57R

-1

1

1

PEAKS 1 1

2 1 1 2 2 3 1 2 2 2 2

> FIT 985 981

, 960 995 992 963 996 1000 985 1000 993 973 993 948 809 903 982 989 953 942 973 99n

< SAT X PEAKS M/Z

-

•

152 I 136

42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 1 DO

— CHRO TOP DELTA PEAKS 418 603

401 384 396 399 411 420 454 445 400 267 483 475 506 496 488 867 506 544 553 •i70

±

1 1

1

26 27 28 29 30 Tl J 2

33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 •>7

58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-595 -500 -596 -602 -628 -636 -713 -707 -1084 -744 -761 -773 -778 -809 -847 -839 -881 -868 -891 -772 -986 -940 -893 -853 -909 -956 -953 -945

-1337 -1486 -970 -975

-1025 -1039 -1074 -1087 -1093 -1205 -1266 -1692 -1337 -1763 -1297 -1427 -2007 -1483 -1527 -1489 -1616 -1643 -1643 -1683 -1886 -1898 -1942

598 503 599 605 631 639 716 710 1088 746 763 775 780 811 849 841 883 870 893 774 988 942 895 855 911 958 955 947 1340 1490 973 978 1028 1042 1077 1090 1096 1209 1270 1697 1341 1768 1301 1431 2012 1487 1531 1493 1620 1647 1647 1687 1891 1903 1947

597 503 600 605 628 640 715 710 1088 747 764 775 781 811 850 842 878 871

775 989 934 896 855 913 959 956 948

1490 973 978 1028 1043 1077 1090 1097 1208 1270 1697 1341

1301 1431

1487 1531 1493 1621 1647 1647 1687 1892 1901 1947

-1

-3

-1

-5

-8

2

,

1

.

1 -1

1

1 -2 .

3 - 995 1 963 1 995 1 997 -1 1 984 1 997 1 977 3 988 1 962 1 990 2 994 2 986 1 998 1 975 1 1000 1 987 1 959 1 980

• 1 993 1 991 1 970 1 977 1 946 1 906 1 987 1 986 1 983

1 919 1 986 1 873 1 983 1 994 1 993 2 970 2 971 1 972 1 962 1 889 1 981

1 966 1 988

2 955 1 987 2 950 1 956 2 893 2 943 1 940 1 957 1 924 1 933

162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

597 503 599 -1 605 628 639 -1 715 710 1087 -1 747 764 774 -1 781 811 850 842 878 871 892 775 989 934 896 856 1 913 959 956 948 1340 1490 973 978 1028 1042 -1 1077 1090 1097 1208 1270 1697 1341

1301 1431

1487 1531 1493 1621 1647 1647 1687 1892 1902 1 1946 -1

1

1

1 J

i

1 1

1 i

1 J 1 1 1 J 1 1


ta: STD80550. TI ^J/05/88 10: 12: 00 Sample: STD MIX 50NG (8/5/88) Conds. : GC5 Formula: Instrument: 1050 Weight: 50.000 Submitted by: Analyst: RGM Acct, No,:

AMOUNT=AREA » REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

1.4-DICHL0R0BENZENE-D4 (SV#1) NAPHTHALENE-D8 (SV#2) N-NITROSODIMETHYLAMINE (SV#14) PHENOL (SV#15) ANILINE (SV#16) BIS(2-CHLOROETHYL)ETHER (SVttl7) 2-CHLOROPHENOL (SV#18) 1.3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SV#21) 1.2-DICHL0R08ENZENE (SV#22) PHEN0L-D5 (SV#7) 2-FLUOROPHENOL (SV#8) 2-METHYLPHENOL (SV#23) BIS(2-CHLOROISOPROPYL)ETHER (SVtt24) 4-METHYLPHENOL (SV#25) N-NITROSO-DI-N-PROPYLAMINE (SV#26) HEXACHLOROETHANE (SVtt27) ACENAPHTHENE-DIO (SVttS) NITROBENZENE (SV#28) ISOPHORONE (SV#29) 2-NITROPHENOL (SV#30) 2.4-DIMETHYLPHENOL (SVttSl) BENZOIC ACID (SV#32) 8IS(2-CHLOROETHOXY)METHANE (SV#33) 2.4-DICHLOROPHENOL (SV#34) NITR0BENZENE-D5 (SV#9) 1.2.4-TRICHLOROBENZENE (SV#35) NAPHTHALENE (SV*»36) 4-CHLOROANIHNE (SV#37) HEXACHLOROBUTADIENE (SV#38) 4-CHL0R0-3-METHYLPHEN0L (SV#39) 2-METHYLNAPHTHALENE (SV#40) PHENANTHRENE-DIO (SV#4) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2.4,6-TRICHLOROPHENOL (SVtt42) 2,4,5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV«44) 2-NITROANILINE (SV#45) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SV#47) 3-NITROANILINE (SV#48) ACENAPHTHENE (SVtt49) 2,4-DINITROPHENOL (SV#50) 2-FLUOROBIPHENYL (SVttlO) 2.4.6-TRIBROMOPHENOL (SV#11) 4-NITROPHENOL (SV#51)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name ISl IS2 618 65A 5H 18B 24A 268 278 6H 25B SS2 SSI 2H 428 4H 63B 128 153 568 548 57A 34 A IH 43B 31A 553 8B 558 7H 528 22A 9H 154 538 21A 4H 208 lOH 718 778 IIH IB 59A SS4 SS5 58A

No Name 18 8H DIBENZOFURAN (SVtt52) r9 358 2.4-DINITROTOLUENE (SVtt53) 50 368 2.6-DINITROTOLUENE (SVtt54)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 IB 19 20 21 2

23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 17 •8 49 50

m/z 152 136

Scan 418 603

NOT FOUND 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165

401 384 396 399 411 420 454 445 400 267 483 475 506 496 488 867 506 544 553 578 617 587 597 503 599 605 628 639 715 710 1087 747 764 774 781 811 850 842 878 871 892 775 989 934 896 856 913

Time 6: 58 10: 03

6: 41 6:24 6:36 6:39 6: 51 7:00 7:34 7:25 6:40 4:27 8:03 7: 55 8: 26 8: 16 8:08 14:27 8: 26 9:04 9: 13 9: 38

10: 17 9:47 9: 57 8:23 9: 59 10: 05 10: 28 10: 39 11: 55 11: 50 18:07 12:27 12:44 12: 54 13:01 13:31 14: 10 14:02 14:38 14:31 14: 52 12: 55 16:29 15: 34 14: 56 14: 16 15: 13

Ref 1 2

19 2 2 2 2 2 2 2 2 2 2 2 2 2 2

34 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19

RRT 1. 000 1. 000

0. 959 0. 919 0, 947 0. 955 0. 983 1. 005 1. 086 1. 065 0. 957 0. 639 1. 156 1. 136 1. 211 1. 187 1. 167 1. 000 0. 839 0. 902 0. 917 0. 959 1. 023 0. 973 0. 990 0. 834 0. 993 1. 003 1. 041 1. 060 1. 186 1. 177 1. 000 0. 862 0. 881 0. 893 0. 901 0. 935 0. 980 0. 971 1. 013 1. 005 1. 029 0. 894 1. 141 1. 077 1. 033 0. 987 1. 053

Meth A BB A BB

A VB A BV A VB A BB A BV A VB A BB A BB A BV A 88 A 88 A BB A BB A BV A BB A 88 A BB A BB A BB A BV A BV A 88 A BV A BB A 88 A VB A 88 A 88 A BV A BV A BB A BB A BV A VB A VB A BB A BV A BB A BV A BB A BB A 88 A 88 A BV A BB A BB A BB

Area(Hght) 122297. 344107,

57172. 53632. 97776, 60660. 127580. 124912. 25664. 118029, 68979. 50476. 43710. 129287. 39430, 46195. 37563, 190572, 84883. 140885, 21712, 36836. 12150. 80444. 36219. 62868, 73546, 190013. 43169, 51238. 38010. 99119.

339482. 11401, 25631. 31048, 116922. 22827. 124200. 161212. 14059. 85391. 3759.

125076, 24995. 5797.

172903. 14633. 30288.

Amount 100. 000 NG/UL 100, 000 NG/UL

41. 369 NG/UL 57.817 NG/UL 40. 688 NG/UL 44.991 NG/UL 51.227 NG/UL 51. 540 NG/UL 40. 875 NG/UL 50.643 NG/UL 38. 349 NG/UL 45. 278 NG/UL 37.401 NG/UL 32. 220 NG/UL 36. 414 NG/UL 38. 406 NG/UL 40. 960 NG/UL 100. 000 NG/UL 35. 091 NG/UL 41, 208 NG/UL 43. 825 NG/UL 42. 799 NG/UL 53. 693 NG/UL 41. 132 NG/UL 51.038 NG/UL 33.377 NG/UL 53. 907 NG/UL 47.373 NG/UL 60. 887 NO/UL 59, 461 NG/UL 45, 576 NG/UL 42. 753 NG/UL 100.000 NG/UL 46, Oil NG/UL 55, 575 NG/UL 62. 922 NG/UL 44,447 NG/UL 49. 689 NG/UL 55. 135 NG/UL 46. 274 NG/UL

237. 797 NG/UL 38.692 NG/UL 69. 043 NG/UL 44, 787 NG/UL 74, 116 NG/UL 104. 760 NG/UL 52. 784 NG/UL 42. 609 NG/UL 53. 663 NG/UL

XTot 2, 30 2, 30

0. 95 1. 33 0, 93 1. 03 1. 18 1. 18 0. 94 1, 16 0, 88 1. 04 0, 86 0. 74 0, 84 0. 88 0. 94 2. 30 0, 81 0. 95 1. 01 0, 98 1. 23 0, 94 1. 17 0. 77 1. 24 1, 09 1, 40 1. 37 1. 05 0, 98 2. 30 1. 06 1, 28 1. 44 1. 02 1. 14 1, 27 1, 06 5. 46 0. 89 1. 59 1. 03 1, 70 2. 41 1. 21 0. 98 1. 23


>ta: STD80550. TI j/05/88 10: 12:00

Sample: STD MIX 50NG Conds. : GC5 Formula: Submitted by:

(8/5/88)


Weight: Acct. No,

50. 000

AMOUNT=AREA « REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 .6 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 19 JO 61 62 63

Name 708 408 808 12H IS5 60A 628 418 98 64A 81B 788 688 39B 186 SS6 58 84B 678 288 728 668 76B 698 74B 748 738 838 828 798

m/z 149 204 166 138 240 198 169 248 284 266 178 178 149

DIETHYL PHTHALATE (SV#55) 4-CHLOROPHENYLPHENYL ETHER (SV#56) FLUORENE (SV#57) 4-NITROANILINE (SV#58) CHRYSENE-D12 (SV#5) 2-METHYL-4, 6-DINITROPHENOL (SV#59) N-NITROSODIPHENYLAMINE (SV#60) 4-BROMOPHENYLPHENYL ETHER (SV4*61) HEXACHLOROBENZENE (SV#62) PENTACHLOROPHENOL (SV#63) PHENANTHRENE (SV#64) ANTHRACENE DI-N--BUTYL

(SV#65) PHTHALATE (SV#66)

FLUORANTHENE (SV#67) PERYLENE-D12 (SV#6) TERPHENYL-D14 (SV#12) BENZIDINE (SV#68) PYRENE (SV#69) BUTYL BENZYL PHTHALATE 3.3'--DICHLOROBENZIDINE

(SV#70) (SV#71)

BENZO(A)ANTHRACENE (SV#72) BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) CHRYSENE (SV#74) DI-N--OCTYL PHTHALATE (SV»75) BENZO(B)FLUORANTHENE (SVtt76> BENZO(K)FLUORANTHENE (SV#77) BENZO(A)PYRENE (SV#78) INDENOd. 2. 3-CD)PYRENE DIBENZO(A.H)ANTHRACENE

(SV#79) (SV#80)

BENZO(G,H. DPERYLENE (SV#81)

Scan 959 956 948 1340 1490 973 978 1028 1042 1077 1090 1097 1208

Time 15: 59 15: 56 15: 48 22: 20 24: 50 16: 13 16: IB 17:08 17:22 17: 57 18: 10 18: 17 20:08

Ref RRT 19 1. 106 19 1. 103 19 1.093 19 1. 546 55 1.000 34 0. 895 34 0. 900 34 0. 946 34 0. 959 34 0. 991 34 1.003 34 1. 009 34 1. Ill

Meth A BB A 88 A 88 A 88 A BB A BB A BV A BB A BB A BB A BV A VB A BB

Area(Hght) 105178. 64638, 127682.

1565. 259637.

8248. 78006, 39745. 65266. 18915.

185789. 182188. 129453.

Amount 54. 62. 50. 108. 100. 58. 47. 54. 60. 70. 50. 49. 46.

735 298 512 269 000 496 607 676 102 355 716 773 241

NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

XTot 1. 1. 1, 2. 2. 1. 1. 1. 1. 1. 1. 1. 1,

26 43 16 49 30 34 09 26 38 62 16 14 06

No A J 5

66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 149 NOT 228 149 228 149 252 252 252 276 278 276

Scan 1270 1697 1341

FOUND 1301 1431

FOUND 1487 1531 1493 1621 1647 1647 1687 1892 1902 1946

Time 21: 28: 22:

21: 23:

24: 25: 24: 27: 27: 27: 28: 31: 31: 32:

10 17 21

41 51

47 31 53 01 27 27 07 32 42 : 26

Ref 34 65 55

55 55

55 55 55 65 65 65 65 65 65 65

1. 1. 0.

0. 0.

0. 1. 1. 0. 0. 0. 0. 1. 1. 1,

RRT 168 000 900

873 960

998 028 002 955 971 971 994 115 121 147

Me A A A

A A

A A A A A A A A A A

fth BB BB 88

BB 88

BV BB VB BB BB 88 BB BB 88 BB

Area(Hght) 148280. 248821. 139815.

149583. 36978.

143108, 51697.

110947. 70928.

252434. 252434. 114510. 114068. 74260. 80165.

Amount 62. 100, 47.

41, 35.

60, ,38. 41. 25. 41. 41. 45. 80. 78. 41,

083 000 003

113 902

334 056 470 674 098 098 575 968 722 967

NG/UL NG/UL NG/UL

NG/UL NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

XTot 1. 2. 1.

0. 0.

1. 0. 0, 0. 0. 0, 1. 1. 1. 0.

43 30 08

94 82

39 87 95 59 94 94 05 86 81 96

(^25" -Ty/zJ^^Ji/AS

IV

n tti

d z 3 00 O 00 U. >v

n o IV V.

CO Q .. UJ H X < cn •H Q

Z UJ •-« I u. tn < z CJ l-l H U.

DATA: STD304 #1 CALI: STD804 #2

SCANi RIC 08/04/88 9:59:08 "SAMPLE: STD MIX 58NG (08/04/88) CONDS.: GC5^ RANGE: G 1,2.300 LABEL: N 8, 4.0 QUAN: A 0, 1.8 J 8 BASE: U 28, 3

1 TO 2300

100.0-1 187596:

RIC

oJ. 3^ 1000 16:41.

1500 25:00

2000 33:20

SCA; TIM;


ta: STD804. TI ^d/04/88 9:59:00 Sample: STD MIX 50NG (08/04/88) Conds, : OCS ' Formula: Instrument: 1050 Weight: 50.000 Submitted by: Analyst: ROM Acct. No.:

AMOUNT=AREA * REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry

2-FLUOROPHENOL (SV#8) ANILINE (SV#16) 8 IS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SVttlS) PHEN0L-D5 (SV#7) PHENOL (SV#15) 1.3-DICHL0R08ENZENE (SV#19) 1,4-DICHL0R0BENZENE-D4 (SV#1) 1,4-DICHLOROBENZENE (SV#20) 1,2-DICHLOROBENZENE (SV#22) BENZYL ALCOHOL (SV#21) BIS(2-CHLOROISOPROPYL)ETHER (SV#24) 2-METHYLPHENOL (SV#23) HEXACHLOROETHANE (5V#27) N-NITROSO-DI-N-PROPYLAMINE (SV#26) NITR0BENZENE-D5 (SV#9) NITROBENZENE (SV#28) 4-METHYLPHENOL (SVtt25) ISOPHORONE (SV#29) 2-NITROPHENOL (SV#30) 2.4-DIMETHYLPHENOL (SV#31) 8IS(2-CHLOROETHOXY)METHANE (SV#33) 2,4-DICHLOROPHENOL (SV#34) 1,2,4-TRICHLOROBENZENE (SV#35) NAPHTHALENE-D8 (SV#2) NAPHTHALENE (SVtt36) BENZOIC ACID (SVtt32) 4-CHLOROANILINE (SV«37) HEXACHLOROBUTADIENE (SV#38) 2-METHYLNAPHTHALENE (SV#40) 4-CHL0R0-3-METHYLPHEN0L (SV#39) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2, 4, 6-TRICHLOROPHENOL (SVtt42) 2-FLUOROBIPHENYL (SV#10) 2,4,5-TRICHLOROPHENOL (SVtt43) 2-CHLORONAPHTHALENE (SV#44) 2-NITROANILINE (SV#45) ACENAPHTHYLENE (SV#47) DIMETHYL PHTHALATE (SV#46) 2.4-DINITROTOLUENE (SV»53) ACENAPHTHENE-DIO (SV#3) ACENAPHTHENE (SVtt49) 3-NITROANILINE (SV#48) 2. 4-DINITROPHENOL (SV#50) DIBENZOFURAN (SV#52) 2. 6-DINITROTOLUENE (SV#54) 4-NITROPHENOL (SV#51)

No 1 2 3 4 5 6 7

(E) ^ 10 11 12 13 14 <5 6 17 IB 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

43 44 45 46 47

Name SSI 5H 188 24A SS2 65A 268 ISl 278 258 6H 428 2H 128 638 553 568 4H 548 57A 34A 43B 31A 88 152 55B IH 7H 528 9H 22A 538 21A 554 4H 208 lOH 778 718 358 153 IB IIH 59A 8H 36B 58A

No '8 49 50

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Name 808 40B 708

m/z 112 93 93 128 99 94 146 152 146 146 108 45 108 117 70 82 77 108 82 139 122 93 162 180 136 128 122 127 225 142 107 237 196 172 196 162 65 152 163 89 164 153 138 184 168 165 139 166 204 149

FLUORENE (SV#57] 1 4-CHLOROPHENYLPHENYL ETHER (SV#56) DIETHYL PHTHALATE (SV#55)

Scan 263 382 393 396 397 398 408 415 417 442 451 471 480 485 493 500 503 503 541 550 575 584 595 596 600 602 613 628 636 707 713 744 761 772 773 778 809 839 847 853 864 868 881 891 893 909 940 945 953 956

Time 4:23 6: 22 6:33 6: 36 6: 37 6: 38 6: 48 6: 55 6: 57 7: 22 7: 31 7: 51 8:00 8: 05 8: 13 8:20 8:23 8: 23 9: 01 9: 10 9:35 9:44 9: 55 9: 56 10:00 10: 02 10: 13 10: 28 10:36 11: 47 11: 53 12:24 12: 41 12: 52 12: 53 12: 58 13: 29 13: 59 14:07 14: 13 14: 24 14:28 14: 41 14: 51 14: 53 15:09 15:40 15: 45 15: 53 15: 56

Ref 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8

25 25 8

25 25 25 25 25 25 25 25 25 25 25 25 25 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41

RRT 0. 634 0. 920 0. 947 0. 954 0. 957 0. 959 0. 983 1. 000 1. 005 1. 065 1. 087 1. 135 1. 157 1. 169 1. 188 0. 833 0. 838 1. 212 0. 902 0. 917 0. 958 0. 973 0. 992 0. 993 1. 000 1. 003 1. 022 1. 047 1. 060 1. 178 1. 188 0. 861 0. 881 0. 894 0. 895 0. 900 0. 936 0. 971 0. 980 0. 987 1. 000 1. 005 1. 020 1. 031 1. 034 1. 052 1. 088 1. 094 1. 103 1. 106

Meth A BV A BV A VB A BV A BV A VB A BV A 88 A VB A 88 A 88 A BV A 88 A BB A BV A 88 A BB A 88 A 88 A BB A BV A VB A 88 A BD A 88 A VB A BB M XX A 88 A BV A 88 A 88 A BV A BB A VB A BB A BB A BV A BV A 88 A BB A BB A BV M XX A BB A 88 M XX A BB A BB A 88

Area(Hght) 79297. 65983. 170935. 95905. 127945. 98304. fTTlTl. 173983. 172392. 165778. 44661.

285420. 83132. 65232. 85557. 146169. 187713. 77023.

265314. 38446. 66790. 151771. 55070.

105874. 534072. 311265. 17560. 55020. 66871. 179916. 64720. 18064. 33621.

203587. 35972. 191772. 33490.

253975. 164218. 25036.

277855, ^60883:

6896, 3969.

238798. 41146. 4flli4.

184274, 75638. 140085.

Amount 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL

100. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50, 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NO/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NO/UL 50.000 NG/UL 100.000 NG/UL 50,000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NO/UL 50.000 NG/UL 50,000 NG/UL 50, 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50, 000 NO/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50, 000 NG/UL 50,000 NO/UL

100, 000 NG/UL 50. 000 NG/UL 80. 000 NG/UL 50, 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL

XT ot 17 17 17 17 17 17 17 34 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 34 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17

, 34 , 17 . 88 , 17 . 17 . 17 . 17 . 17 . 17 . 17

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 •^6

7 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Ret(L) 4: 23 6:22 6:33 6: 36 6: 37 6: 38 6: 48 6: 55 6: 57 7: 22 7:31 7: 51 8: 00 8:05 8: 13 8: 20 8: 23 8:23 9: 01 9: 9: 9: 9: 9:

10 35 44 55 56

10: 00 10: 02 10: 13 10: 28 10: 36 11: 47 11: 53 12:24 12: 41 12: 52 12: 53 12: 58 13: 29 13: 59 14: 07 14: 13 14:24 14: 28 14: 41 14: 51 14: 53 15: 09 15: 40 15: 45 15: 53 15: 56

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

00 00 00 00 00 00 00 00 00

1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 00

00 00 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 0. 634 0. 920 0. 947 0. 954 0. 957 0. 959 0. 983 1. 000 1. 005 1. 065 1. 087 1. 135 1. 157 1. 169 1. 188 0. 833 0. 838 1. 212 0. 902 0. 917 0. 958 0. 973 0. 992 0. 993 1. 000 1. 003 1. 022 1. 047 1. 060 1. 178 1. 188 0. 861 0. 881 0. 894 0. 895 0. 900 0. 936 0. 971 0. 980 0. 987 1. 000 1. 005

Ratio 1. 00 1. 00 1. 00

020 031 034 052 088 094 103 106

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00 00

1. 00 1. 00 1. 00

Amnt 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 100. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

Amnt(L) 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50, 00 50. 00 50. 00 50, 00 50, 00 50. 00 50. 00 100, 00 50, 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

R. Fac R. 0. 912 0. 758 1, 965 1. 102 1. 471 1. 130 2. 036 1, 000 1. 982 1. 906 0. 513 3. 281 0. 956 0. 750 0. 984 0. 547 0. 703 0. 885 0. 994 0. 144 0. 250 0. 568 0. 206 0. 396 1, 000 1. 166 0. 066 0. 206 0. 250 0. 674 0. 242

130 242 465

0. 0. 1. 0. 259 1. 380 0. 241 1. 828 1. 182 0, 180

000 158 031 029 719

0. 296 0. 029 1, 326 0. 544 1. 008

0. 0. 0. 0. 0.

Fac(L) 0. 912 0. 758 1, 965 1. 102 1. 471 1. 130 2. 036 1. 000 1. 982 1. 906 0. 513 3. 281 0. 956

750 984 547 703 885

0. 994 0. 144 0. 250 0. 568 0. 206 0, 396 1. 000 1. 166 0. 066 0, 206 0, 250 0. 674 0. 242 0, 130 0. 242 1. 465 0. 259 1. 380 0. 241 1. 828 1. 182 0. 180

Ratio

000 158 031 029 719 296 029

1. 326 0. 544 1. 008

00 00 00 00 00 00 00 00 00 00 00 00

1. 00 00 00 00

1. 00 00 00 00

1. 00 1. 00 1. 00

00 00 00 00 00 00 00 00 00 00 00 00

1. 00 00 00 00 00 00 00 00

1. 00 00 00 00 00 00 00


ta: STD804. TI _v:)/04/88 9:59:00 Sample: STD MIX 50NG Conds. : GC5 Formula: Submitted by:

(08/04/88)


Weight: Acct. No.

50. 000

AM0UNT=AREA » REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 ^5 6

67 68 69 70 71 72 73 74 75 76 77 78 79

No 51 52 53 54 55 56 57 58 59 0

ol 62 63 64

Name 60A 628 555 41B 98 64A 154 818 78B 688 398 848 556 12H 678 728 155 768 668 698 74B 74B 748 748 73B IS6 838 82B 79B

m/z 198 169 330 248 284 266 188 178 178 149 202 202 244 138

2-METHYL-4.6 -DINITROPHENOL (SVtt59) N-NITROSODIPHENYLAMINE 2,4,6

(SV#60) -TRIBROMOPHENOL (SV#11)

4-BROMDPHENYLPHENYL ETHER HEXACHLOROBENZENE (5V#62) PENTACHLOROPHENOL (5V#63) PHENANTHRENE PHENANTHRENE

-DIO (SV#4) (SV#64)

ANTHRACENE (SV#65) DI-N-

(SV#61)

BUTYL PHTHALATE (SV#66) FLUORANTHENE (SV«67) PYRENE (5V#69) TERPHENYL-D14 (SV#12) 4-NITROANILINE (SV#58) BUTYL . BENZYL PHTHALATE (SVtt70) BENZO(A)ANTHRACENE (SV#72) CHRYSENE-D12 (SV#5) CHRYSENE (SV#74) BIS(2 DI-N-

!-ETHYLHEXYL)PHTHALATE (SV#73) •OCTYL PHTHALATE (SV#75)

BENZO(B)FLUORANTHENE (SV#76) BENZO(K)FLUORANTHENE (SV#77) BENZO(K)FLUORANTHENE (SV#77) BENZO(8)FLUORANTHENE (SVtt76) BENZO(A)PYRENE (SV#78) PERYLENE-D12 INDENOd. 2, 3

(SV#6) -CD)PYRENE

DIBENZO(A,H)ANTHRACENE (SV#79) (SV#80)

BENZO(G. H, DPERYLENE (SV«81)

Scan 970 975 986 1025 1039 1074 1084 1087 1093 1205 1266 1297 1337 1337

Time 16: 10 16: 15 16:26 17:05 17: 19 17: 54 18:04 18:07 18: 13 20: 05 21:06 21: 37 22: 17 22: 17

Ref RRT 57 0. 895 57 0. 899 41 1. 141 57 0. 946 57 0. 958 57 0. 991 57 1.000 57 1.003 57 1. 008 57 1. 112 57 1. 168 67 0. 873 67 0. 900 41 1. 547

MG

A A A A A A A A A A A A A A

'th 88 BV BB 88 88 BB BB BV VB BB BB 88 88 BB

Area(Hght) 7849.

91211. 24585. 40465. 60449. 14966.

377953, 203923. 203761. 155837. 132954. 132565. 108381.

1686.

Amount 50. 50. 50. 50. 50. 50. 100. 50. 50. 50. 50. 50. 50. 80.

000 000 000 000 000 000 000 000 000 000 000 000 000 000

NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL

XI ot 17 17 17 17 17 17 34 17 17 17 17 17 17 88

No 5

06

67 68 69 70 71 72 73 74 75 76 77 78 79

No 51 52 53 54 55 56 57 58 59 hO 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 7 b 77 78 79

m/ z Sc an Time Re' 149 1427 23 228 1483 24 240 1486 24 228 1489 24 149 1527 25 149 1616 26 252 1640 27 252 1643 27 252 1643 27 252 1643 27 252 1683 28 264 1692 28 276 1886 31 278 1898 31 276 1942 32

Ret(L) 16: 10 16: 15 16:26 17: 05 17: 19 17: 54 18:04 18:07 18: 13 20:05 21:06 21:37 22: 17 22: 17 23: 47 24:43 24: 46 24:49 25:27 26: 56 27:23 27:23 27: 23 27:23 28: 03 28: 12 31:26 31:38 32:22

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00 1. 00

:47 67 : 43 67 : 46 67 :49 67 : 27 67 : 56 76 :20 76 :23 76 :23 76 :23 76 :03 76 : 12 76 :26 76 :38 76 :22 76

RRT(L) 0. 895 0. 899 1. 141 0. 946 0. 958 0. 991 1. 000 1. 003 1. 008 1. 112 1. 168 0. 873 0. 900 1. 547 0. 960 0. 998 1. 000 1. 002 1. 028 0. 955 0. 971 0. 971 0. 971 0. 971 0. 995 1. 000 1. 115 1. 122 1. 148

F RRT 0. 960 0. 998 1. 000 1. 002 1. 028 0. 955 0. 969 0. 971 0. 971 0. 971 0. 995 1. 000 1. 115 1. 122 1. 148

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00

Meth A 88 A BV A BB A VB A BB A BV M XX M XX A 88 A BB A BB A BB A 88 A BB M XX

Amnt 50. 00 50. 0 0 50. 00 50. 00 50. 00 50. 00 100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 20. 33 35. 89 50. 00 50. 00 50. 00 100. 00 50. 00 50. 00 50. 00

Area(Hght) 37527. 86423. 189200, 97477, 49496. 65974. 59648. 105276. 146681. 146681. 60001. 118839. 33643. 22527. 45616.

Amnt(L) 50. 00 50, 00 50. 00 50. 00 50, 00 50. 00 100. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50. 00 80. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50, 00 50. 00 50, 00 50. 00 100. 00 50, 00 50. 00 50. 00

Amount 50. 000 50. 000

100, 000 50. 000 50. 000 50. 000 20. 333 35. 886 50. 000 50, 000 50. 000

100. 000 50. 000 50. 000 50, 000

R. Fac R. 0, 042 0, 483 0. 177 0. 214 0. 320 0. 079 1. 000 1, 079 1, 078 0, 825 0. 704 1, 401 1. 146 0. 008 0. 397 0, 914 1, 000 1, 030 0. 523 1. 110 1. 004 1. 772 2. 469 2, 469 1, 010 1. 000 0. 566 0. 379 0, 768

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NO/UL

Fac(L) 0. 042 0. 483 0. 177 0. 214 0, 320 0. 079 1. 000 1. 079 1, 078 0, 825 0, 704 1. 401 1. 146 0, 008 0. 397 0. 914 1. 000 1. 030 0, 523 1, 110 2, 469 2. 469 2. 469 2, 469 1, 010 1. 000 0, 566 0. 379 0 768

XTot 1, 17 1. 17 2, 34 1, 17 1, 17 1, 17 0. 48 0. 84 1. 17 1. 17 1. 17 2. 34 1. 17 1. 17 1. 17

Ratio 1. 00 1. 00 1. 00 1. 00 1, 00 1, 00 1 00 1, 00 1. 00 1, 00 1. 00 1, 00 1, 00 1. 00 I, 00 1, 00 1: 00 1. 00 1, 00 1. 00 0. 41 0. 72 1, 00 1, 00 1. 00 1 00 1 00 1, 00 1 00

Documents

Reagent & trip blanks for MW-4UB accession #806170, tests ... · 07/02/88 07/02/88 ug/l n/a compounds results chloromethane bromomethane vinyl chloride ... (mbk) 4-methyl-2-pentanone