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Reaction of cyclohexane with Br2: Cyclohexane as one of alkanes is in most occasions are unreactive, but can react in extreme conditions like radiation, high temperature... C6H12 + Br2 + high t, light ---> C6H11Br (bromcyclohexane) + HBr (you should check this somewhere, I'm not sure) KMnO4 is oxidative medium, but can't oxidate alkanes. Cyclohexene as one of alkenes succumbs the reactions of electrophylic addition, so in reaction with Br2: C6H10 + Br2 ---> C6H10Br2 (1,2-dibrom cyclohexANE) In reaction with KMnO4, Cyclohexene is oxidated to the alcohol with two hydroxyl groups. C6H10 + KMnO4 ---> C6H10(OH)2 (1,2 dihydroxicyclohexANE) + MnO2 Toluene as derivate of benzene, shows reaction of succumbs the reactions of electrophylic aromatic substitution. In reaction with Br2: C6H5CH3 + Br2 + FeBr3 (needed for reaction) ---> C6H4(CH3)Br (brom-toluene or 1-brom 2(or 3 or 4)-metyl benzene) + HBr Alkylbenzenes (toluene in this case) can react with KMnO4 and in that reaction they forming aromatic carboxylic acids where carboxylic group is directly connected to aromatic ring, so in this case: C6H5CH3 + KMnO4 (+ KOH) ---> C6H5COOH (benzoic acid) + MnO2

Reaction of Cyclohexane With Br2

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Reaction of cyclohexane with Br2:

Cyclohexane as one of alkanes is in most occasions are unreactive, but can react in extreme conditions like radiation, high temperature...

C6H12 + Br2 + high t, light ---> C6H11Br (bromcyclohexane) + HBr(you should check this somewhere, I'm not sure)

KMnO4 is oxidative medium, but can't oxidate alkanes.

Cyclohexene as one of alkenes succumbs the reactions of electrophylic addition, so in reaction with Br2:

C6H10 + Br2 ---> C6H10Br2 (1,2-dibrom cyclohexANE)

In reaction with KMnO4, Cyclohexene is oxidated to the alcohol with two hydroxyl groups.

C6H10 + KMnO4 ---> C6H10(OH)2 (1,2 dihydroxicyclohexANE) + MnO2

Toluene as derivate of benzene, shows reaction of succumbs the reactions of electrophylic aromatic substitution. In reaction with Br2:

C6H5CH3 + Br2 + FeBr3 (needed for reaction) ---> C6H4(CH3)Br (brom-toluene or 1-brom 2(or 3 or 4)-metyl benzene) + HBr

Alkylbenzenes (toluene in this case) can react with KMnO4 and in that reaction they forming aromatic carboxylic acids where carboxylic group is directly connected to aromatic ring, so in this case:

C6H5CH3 + KMnO4 (+ KOH) ---> C6H5COOH (benzoic acid) + MnO2