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Radioactivity and radioisotopes • Half-life • Exponential law of decay

Radioactivity and radioisotopes Half-life Exponential law of decay

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Page 1: Radioactivity and radioisotopes Half-life Exponential law of decay

Radioactivity and radioisotopes

• Half-life • Exponential law of decay

Page 2: Radioactivity and radioisotopes Half-life Exponential law of decay

Half-lifeThe half-life of a radioactive element means:

a) The time taken for half the radioactive atoms in the element to disintegrate

b) The time taken by the radiation from the element to drop to half its original level

Radioactive atoms HALF-TIME

Radioactive atoms

Decayed atoms

HALF-TIME

Page 3: Radioactivity and radioisotopes Half-life Exponential law of decay

What does decay rate depend on?

In other words, there is a 50% chance that any radioactive atom within the sample will decay during a half-life time T½.

Consider the emitter Fe-59. Its half-life is 46 days.

Plot a graph of the fraction of undecayed atoms vs time (days).

Page 4: Radioactivity and radioisotopes Half-life Exponential law of decay

Half-life of Fe-59

1

1/2

1/4

1/80

0

1/4

1/2

3/4

1

1 1/4

0 46 92 138 184

Time (days)

Fra

cti

on

of

un

de

ca

ye

d a

tom

sClick here for radioactive decay simulation

Page 5: Radioactivity and radioisotopes Half-life Exponential law of decay

What does decay rate depend on?

Can you now answer by considering the graph you drew? Explain your answer.

The rate of radioactive decay of Fe-59 atoms depends on the number of atoms itself. In fact, our graph is not a straight line, which means that the number of atoms decaying changes with time, i.e. with the number of radioactive nuclides left. The number of radioactive nuclides left after each half-life drops to ½, not of the original amount, but of the amount left. This means that not all Fe-59 has decayed after 2 x 46 days, but only ¼ of the original amount is left.

Page 6: Radioactivity and radioisotopes Half-life Exponential law of decay

Exponential law of decayNow, plot the graph of the logarithm to base 10 of

the fraction of Fe-59 remaining against time.

Logarithm of fraction remaining - time

-1.204

-0.903

-0.602

-0.301

0

0 46 92 138 184

Time (days)

Lo

g o

f fr

acti

on

rem

ain

ing

Interpolate the logarithm of the fraction remaining after 120 days.

0.785

Page 7: Radioactivity and radioisotopes Half-life Exponential law of decay

Consider the table of data from the example on the previous slides.

Exponential law of decay

Time (day)Fraction

remaining (F)log(F)

0 1 0

46 1/2 -0.301

92 1/4 -0.602

138 1/8 -0.903

184 1/16 -1.204

Page 8: Radioactivity and radioisotopes Half-life Exponential law of decay

Can you notice any pattern in the log(F)? Explain your answer.

Each reading of F is divided by 2 (1, ½, ¼, …), therefore, the value of log(F) must have log2 subtracted from it to get the next reading.

In fact;

log(a/b) = log(a) – log(b) log(1/2) = log(1) – log(2) = 0 – 0.301 = -0.301

The same applies to the other fractions.

Exponential law of decay

Page 9: Radioactivity and radioisotopes Half-life Exponential law of decay

Using the table and similar triangles find the fraction remaining after 150 days.

x = -0.982 x = log(F150)

F150 = antilog(-0.982) = 10-0.982 = 0.10

Exponential law of decay

x

daysdays 150

903.0

138

Page 10: Radioactivity and radioisotopes Half-life Exponential law of decay

From the previous discussion, we can conclude that the rate of radioactive decay is proportional to the number of radioactive atoms:

Where N is the number of radioactive atoms still present at time t.

Exponential law of decay

Ndt

dN

Page 11: Radioactivity and radioisotopes Half-life Exponential law of decay

The previous proportionality gives the following equation:

The constant the decay constant, and it is measured in s-1.

A solution to the above equation is:

Exponential law of decay

Ndt

dN

teNN 0 x

NN

20

Page 12: Radioactivity and radioisotopes Half-life Exponential law of decay

In the previous formulae, N0 is the number of radioactive atoms at time t = 0, and x is the number of half-lives elapsed, which could also be not integer.

Exponential law of decay