$QQH[XUH, …environmentclearance.nic.in/writereaddata/online/EC/...Hardoi, Uttar Pradesh E\ MIs Swarup Chemicals Pvt. Ltd. - Terms of Reference - Reg. Ref. No.: Your Proposal No

$Page 1: $QQH[XUH, …environmentclearance.nic.in/writereaddata/online/EC/...Hardoi, Uttar Pradesh E\ MIs Swarup Chemicals Pvt. Ltd. - Terms of Reference - Reg. Ref. No.: Your Proposal No$
Annexure I: NABET Accreditation Certification


Annexure II: Approved Terms of Reference

F. No. J-11011j324j2016-IA-II (I)

Government of India

Ministry of Environment, Forest and Climate Change

(IADivision)

Indira Paryavaran Bhawan

Aliganj, Jor Bagh Road

New Delhi - 110 003

To

E-mail: [email protected]

Telefax: 011-24695365

Dated: 31st January, 2017

The Director,

Mj s Swaru p Chemicals Pvt. Ltd

Plot No B-15 to B-22 Sandila Phase - II,UPSIDCINDUSTRIALAREA,

HARDOI,U. P.

Sub: Proposed Agrochemical and Intermediates Manufacturing Plant at

Sandila II, Plot B, 15-22, UPSIDC, Industrial Area, Tehsil Sandila,

Hardoi, Uttar Pradesh by MIs Swarup Chemicals Pvt. Ltd. - Terms of

Reference - Reg.

Ref. No.: Your Proposal No. IA/UP/IND2/58942/2016 dated 12thSeptember,

2016.

Sir,

This has reference to your Proposal No. IAjUPjlND2j58942j2016 dated12th September, 2016, submitting to this Ministry for seeking Terms of

Reference (ToR) in terms of the provisions of the Environment Impact

Assessment (EIA) Notification, 2006 under the Environment (Protection) Act,1986.

Proposal No. IAjUPjIND2j58942j2016

Page 1 of3

2. The proposal was considered by the Expert Appraisal Committee (EAC)in the Ministry for (Industry-2), in its 14thmeeting held on 26th - 27th October,

2016. The details of the project, as per the documents submitted by the project

proponent, and also as informed during the above said EAC meeting, arereported to be as under:-

(i) The project involves proposed Agrochemical and Intermediates

Manufacturing Plant at Sandila II, Plot B 15-22, UPSIDC, Industrial

Area, Tehsil Sandila, Hardoi, and Uttar Pradesh by Mjs Swarup

Chemicals Pvt. Ltd. Following are the details of proposed capacity ofproducts:-

S.No Name of product Capacity MT/Month1. Kresoxym- Methyl 252. Dinotefuron 303. Difenthiuron 504. Pyriproxyfen 505. ZDC 100

mailto:[email protected]

3. The EAC recommended the project for grant of ToR. As per the

recommendation of the EAC, the Ministry of Environment, Forest and ClimateChange hereby accords following specific and additional ToR in addition to

generic ToR provided at Annexure - I (refers to Ministry's website) to the

'Proposed Agrochemical and Intermediates Manufacturing Plant at

Sandila 11,Plot B 15-22, UPSIDC,Industrial Area, Tehsil Sandila, Hardoi,Uttar Pradesh by Mjs Swarup Chemicals Pvt. Ltd for preparation of the

Environment Impact Assessment (EIA)Report and Environment Management

Plan (EMP):- .e: f).'yk:'t

A. Specific TOR

6. Ziram 100

7. Thiram 100

B. captan 100

9. Folpet 100

10. Metam Sodium 200

11. Zineb 50

Intermediates

12. pthalide 100

13. N-NDimethyl carbamoyl chloride 50

14. N-NDimethyl thiocarbamoyl 50

chloride

Formulation

15. Solid Formulation-WDG,WP 500

16. Liquid Formulation-EC,SL 1000

(ii) Total Plot area is 2.693 ha, out of which 33 % area will be developed as

greenbelt.

(iii) Power requirement: Power requirement during operational phase will beBOO KVAwhich will be sourced from UP State Electricity Board and 2 DG

Set of 350 KVAwill be used as a stand by.

(iv) Rice husk fired Boiler of 3 TPH capacity will be installed.

(v) Total Water requirement for proposed project will be 90m3/ day, which will

be sourced from ground water. Total waste water generation will be

60m3/day out of which industrial waste water generation will be

4Bm3 / day, which will be treated in ETP.

(vi) Process wastes/residue, Chemical sludge containing residue insecticidesand Date expired and off-specification insecticides will be collected and

stored at separate identified place and suitably disposed off to authorized

agencies.

(vii) Wildlife issues: It is reported that no national parks, Reserve/protected

forest and WildlifeSanctuaries lies within 10 km distance of project site.

(viii) Water bodies: No water body is present within 10 Km radius of project

site.(ix) Investment/cost: Cost of proposed expansion project is ~ 15 crore.

Proposal No. IA/UP/IND2/58942/2016

Page 2 of3

(i) Public Hearing to be conducted and issues raised and commitments

made by the project proponent on the same should be included in

EIA/EMP Report in the form of tabular chart with financial budget forcomplying with the commitments made.

(ii) Feasibility of bio pesticide to be worked out along with proposed pesticideproducts.

4. A detailed draft EIA/EMP report shall be prepared in terms of the above

additional ToRs and shall be submitted to the concerned State Pollution Control

Board for conduct of Public Hearing. Public Hearing to be conducted for the

project in accordance with the provisions of Environmental Impact Assessment

Notification, 2006 and the issues/commitments raised by the public, shall be

addressed in the EIA/EMP in the form of tabular chart with financial budget forcomplying with the commitments made. The Public Hearing should be

conducted based on the ToR letter issued by the Ministry and not on the basisof Minutes of the .Meetingavailable on the web-site.

5. You are requested to kindly submit the detailed final EIA/EMP prepared

as per ToRs including issues raised during Public Hearing to the Ministry for

considering the proposal for environmental clearance within 3 years as per the

MoEF&CCO.M. No.J-11013/41/2006-IA-II(I) (P)dated 8th October, 2014.

6. The consultants involved in preparation of EIA/EMP report after

accreditation with Quality Council of India/National Accreditation Board of

Education and Training (QCI/NABET)would need to include a certificate in this

regard in the EIA/EMP reports prepared by them and data provided by other

Organization(s)/Laboratories including their status of approvals etc. vide

notification of the MoEF dated 19th July, 2013. h ~.~,\.~b\1

(Yogendra Pal Singh)

Scientist 'D'

Copyto:

1.0 The Member Secretary, Uttar Pradesh Pollution Control Board, Building

No. TC-12V, Vibhuti Khand, Gomti Nagar, Lucknow, Uttar~ Rdesh

226010. 07 t"'

~\ .,.z_o\l(Yogendra Pal Singh)

Scientist 'D'

Proposal No. IA/UP/IND2/58942/2016

Page 3 of3

Annexure III: Land Document

Kl:uJ:) J I:KI:U A.U

U. P. State 'Industrial Development Corporation Umited I

, . (Head Office: A-1/4, LAKHANPUR, POSTBOX NO. 1050, ｾｐｕｒＭＲＰＸ 024),.,; I \ I': .

. , : , j'

Regional OfIk:e.:.....R.ekYlFl.Qb,.1.Uckncw....... ...............................................,.................. ｾｔＮｾｾ ............... 6098 ;. ,., ! " . · 1q: . 31J03flO1I

ReI. No::'" _ ...ｾＮ SaMIlit.Jl..O&att..Hardol..Ptot Nor...&J5.&16.&.1J.......:........·...... ＧｉｾＧ［Ｇ .......... Dated.............. .

. , ," : ＱＧﾷｾｾｌｅｳｈｋｕｍａｒ＠ I , : ＮｷｾＱ＠ｾｉ＠Ｇ＠ . ｾＺ＠ -'r' · tl i •• . : ... ....... "'1' ｾＭＮｲｬ｜ＭＭＭＭﾷＭｉﾷＭﾷＭ

I.

..i'.. ﾷﾷﾷﾷﾷﾷﾷﾷﾷﾷﾷ;

ｾｬｴ＠ｬﾷﾷﾷ＠ .. ＿Ｚ＠Ｌｾ＠ : : Ｎ＠ｾｾＮｾｾｾﾷｲｾｲｾﾷｾｲＺｾﾷ .... ｾﾷﾷﾷﾷＭﾷﾷＺＮＮ＠ : ;,( . '.' ｾ＠ｉ＠ｩｬＺＧ＠ I .'. Ii ,yl. ＧＮｾＮ＠ＧｾｾｾＧＢｐｦＭﾷｾｩｾﾷｬ＠ＮＮＺ .... _l.. .... ＭＮｾ ....,.. I" '; ' 1 ' . • '.;. ｩＢｾＱ＠ "!i , ! :I I . ＧｾｉＧ＠ Oistt. H8rdoi ' ,,; ｾ｢Ｎ＠ : • A.IoIJ'nInf ｾｾ Ir1 ｾｾＮｾ｟Ｌ｟ＮＬ［Ｂ .........t ...........................................; .................. ..

. . " ;!) J

J I : ! • I , - -#8'-1· , ; .. 1 I . 'I1iICII . . . I : .: ;: ' .I", .,,.

. . I" • .08/0912010IAlith reference to your application dated......: .............................................. ........ for allotment of 1;lnd In our Industl

Are a... .... .... ..... ｓ｡ｮ､｜ｬ｡ｾｬｬ .. Distt .. Hardo\ .. at ....... ' ................. ... ... . , ... Regional. Office•.Lud<n.ow..... ....... ... .... ..

we have allotted to you plot No... B.,15.Br.1fi.S,1Z ................. in our Industrial Area ｾｾＮｾＮｾＮｾＺＮｾｾｾｾ . ..... .. ... .............. ..

l .. .......... ｾｾｾＮｉＮｉａＮｾ｜｜Ｍ .. ｴ［Ｎｾ ...................... on the conditions noted below for setting up an Industrial unit to manufactuJi P ST1C1DESlfUNGICIOES &FORMULAnON . ••• • • & ...."., ••• , ••••••••••• u· .." ........ _ .....;••••••• , ........• ••• ﾷＭｾﾷﾷｲﾷﾷ .......,....•......··........ : . t Ｇ＠ｉｾ＠ !

,. the .,.. or plot II :.:.10,AM 00 ... ｾ ....... ｾＮＺ｟ ... ｾＭＺＭ ...ｊｾＮ｟ ..... sq. nr. The precise ｾｴ and the area of the land In

tM pIot . • ｦＪＧｾｾｾｾﾷｉＮ＠Ｑ＠Ｑ＠ I i ＱｾＺ＠ｬ＠ｩＢＧ＠ , 'ill . The dlltof ｴｨｬｬｬｉｴｉｉｬｾ be ｾ .. ｯｉｾ｡ｲｴｨ･ abO',Ie plat klT:i.your,.

.s.. . The""dWgeIbIIi'..PI!( c11u116 ｾ on ... (totaI) ;baIince outstanding " , ｾｷｩｊｉ＠ be computed from the da

cI ｾＮｾ In ｾ 2, abQve ｾｾ hlllfyeartt, on 1st ｾｉ of January and . ｾ day of July ch year. The fi

1 ｦＧｾ pql'nlnil'f'1l. ｾｾ on ＮｪｉｬＮｊ｡｡ｲｮＮＲｑＱＲｾＮ＠ ; I ｾ＠ｉｬ＠ .I

by

4,

(I ｾＮｾｾｾｶ｡ｊｾｒｌｪＢｾＭＭＴ .ＮＮＮＺＭＭＭｾＮＢ ...exlaIlng on !he plot, ±of ｗｨｾ shall have to be pal,

ｾｾｬｾＢｾｾｱｰ･ＢｾＧ＠ .. . ! .1f, ; (

Ｈ｢Ｉｔｨ･ｩ･ＬＮＮＬｾｾｾｾＺｯｮ＠ the plc;)t.costofwhich as per valuation made by the Corporation ｾ＠

have fa paId by you .wfthln ｾｬｲ｢Ｇ＠ days from ｾＬ date :0'demand letter. , .

You shall deposit at this office an amount of Rs....3S9,12S.00................................ (Earnest Money of R .... . 200.000.00.. ..

has been adjusted) towards reservation money in respect of lhe above plot ｬ｡ｴ･ｾｴ＠ by .. .ｾＮｏＡＧｑＺＴｴ［＿ＮｑＮＱ＠ＮＱＮＮＮ＠ ..........1 hiS amount

\togetherwith Earnest money) is approximately equal to ..1O.. 00 ............................percent oHnetotal premium of the plot at tt

provIsional rate of Rs 500.00 ........ .. . .. .. .. per sq.mtr. and Iocational charges @ Rs.. 25...QQ ... Ｚｾ .. ;. .... ...... ... .... per sq. mtr. for

I .. I hvtl ｩｬｃｉ･ｾ＠ and IS subject to adjustment according to actual measurement of the plol If ｾ above amoun falls short of th

a nounl equal to ..... 10.00.........................percentage of the total premium according to actual measurement, the balance will

be depoabd by you withln seven days of the receipt of demand from us

If the payments ill not made as ltipulated above this allotment wiU stand automatically ｾｬｉ･､ｊ｡ｮ､＠ the whole amount of

... n nr.z Monty depoaUed by you wW stand fotfeJted to this Corporation, even if the area of the plot either e) ceeds or is .less

than the area applied for to the extent of 20% or less of the area applied for. HaveveT, if the area of the land allotted either

axc:eec:Jt the atN applied for or falls short of the area applied for by an area more than 20% of it, the Ea nest Money will I

be forfeited It thJs aJJotment Is not accepted, provided an intimation Is sent to us In this respect by the date stipulated above.

Page 1 of 5

The CorporatIOn at ,t IOio ｾ upon the request In wratmg trom you ana aner oelng sausnea WIUl UII:l \1I:lIlUUIIII:lII ': ::':' UI

'1e resona put forth may extend the date of depositing of the reservation money/cost of construction/properties provided

/ljmWm ,.d the lnduItriIIlIeI hal not fncreaIed Iinc:e the data of aDotmenlln such a ｾ Interest O..14.00..·...·percent

pe4twam IhIII ｴｉｉＢＧＬｾｾ ,of baIanct Im04U1t of roservation money/cost of ｾｰｲｯｰ･ｲｴｩ･｡ from the date of

upto receipt oIlh1 payment In the CorporatIon.ln the event of nonpayment of dues bY the extended date ,the

Illnt,.,.N IhlllIUIOmatIcIIy ｾ with the ｯｯｮ｡･ｱｾ as per dause7 below. ,I i

ｦｴＦＦＮｯｬｾ＠ II pIOViUonaI and II liable ｾ'. The ーｮｭｕｮｾ＠ｉ＠ be enhanced kl'::1'0 r'o ,' ' the provlaioM of Ucense .. ｾ＠ｉｉＧ＠ I' i 'l l' . I

I l' I • , ＧＸＰＮｾ＠ j ., j " l • :II . ﾷＧﾷＧﾷＡＮｉｾＭＭＮＮＢＮｾ ....ｾｾﾷ､ｯＧＡｴｾ］［ＭＭＴ］ｾｾｲＮＮＺＮＡｉＭｾｾ］］Ｍｯｉ＠

, .. III due tor.' on Y.4 I 110712013 I ! :The secood and ｾ i\stalIments of·...ri1bliiw. ' I ",.._ , I t IJJ .. ｾ＠ I 1 ! . • ill I ... ｾｾｾｾｐＧｾＭｔ＠ r ＢｔｾＱＢ､｡ＱｾＢ＠ I T·t earJ1 r" ｍＮＮＮＮＬＮｾ .."pet ｾｴｨｉｉ .. ｾｾｉｨ･ｾ (balance) ーｮｷｮｩｵｭｾ effect from the date 01 ftlINI"""' andwilbe payable 'along MIh Ntalfnientof;pnMriIum as .,.dated in dause 3 abov8,sUbject to a rebate of.3..00...% per annum on payment on Of before the ｾ date and ｩｉｾ are no arrears 01 dues. Th,e amount 01 the balance ,

m and the Int.etut due on It from tfme to time shaU remain first charge on the land and the building and machIn ry erected thBraon tJU It Is , (they are) paid In full. ,' ," f: ,

.jote: The premium mentioned herem is provisional and is liable to be enhanced in accordance with the orovlslons ( f l ease

J. The ,tamp duty, the registration charges and legal expenses involved in the execution of the lease Oeed and other agreements from time to time wlU have to be borne by you.

I. In the event 01 canceUation of aJIotment on acx:ount of any default on your part, the following amounts wiU stand f rfeited to U.P. SlIIe InduItrial DeveJopment CorporaUcn Limited : i '

t I

(I) O"..1t,QQ.._•••••ｾｰｯｲ annum &em the date of aIIcbnent on the total unpaid premium from time to time till th date of C81Q'ltion d IIobnInt WIhout allowing rebate In Interest. mentioned in dause 5 above irrespective of the tact whe ler the

hadbeonptid In ｴｉｭ･ｾｮｯｌ＠ II. I! I .

I AND ! : ; .• ' , I

(b) ua. and occupation Chatgee/leue RenUMalntenance Levy/Service Charges! and paid/outstanding interest the, eon/other from IhI date 01 aIIo&mInt WI the date 01 Cacellation. ' ' , . ' l ' I,, ' i ｾ＠ AND I

" " , ' .:', I i I I'" " . ,

ee) In ChI Cue ofc:onattUctod Iheda allotted bY UPSIOC Ltd., 5% of the cost of shed towards depreciation.

ｾｾｾＢｫＮＧ｣ｬｾＧｾｊＡ､･ｰｯｳｬｾ＠ｾｾｾ til ｾＬ after deducting the ｡ｭｯｵｾｴｳ＠ to be forfeHed as ve. will be refundable. In case the total of the amounts 'paid Is less than the amounts to be forfeited you shall be hable to pay the difference and t.'e same shall be recoverable by the Corporation from you.

8. In the event of surrender of the allotment, the following amounts will stand forfeited to the U.P. State Industrial evelopment Corporation limited :

(a) Interest C....·.·l4..QO...........per annum from the date of allotment upto the date of surrender of the allotment on the total balance (unpaJd) premium from time to time allowing the rebate (in interest) irrespective of the fact whether the payn ents

(e made In time ()( nol AND

(b) Uu and occupation ChaJges /lease RenVMaintenance Levy/Service Chargesl and paid/outstanding Interest the' eon/other dues from tho date of allotment till the date of surrender.

AND

(c) 5% of tM coat ot the aheel towards depreciation in case of constructedsheel allotted by UPSIDC.

e balance ｡ｲｮｯｵｮｾ＠ If any, out of the deposits made by you tiU the date of Eurrender after deducting the amounts to be

f rteded 8$ above, will be refundable. In case the total of the amounts paid is less than the amounts to be forfeited, you shall be liable to pay the difference and the same shaU be recoverable by the corporation from you. " . , I

4 , The plot has been allotted on as i,t is where it is basis and levelling etc., if any, is to be undertaken by you at exp nses. You Will pay to the U, p , Slate Industrial Development Corporation Ltd. within 30 days from the date of the demands made by th iS ｾｯｲｰｯｲ｡ｴｩｯｮ＠ from time to time such recurring fee In the nature of Ｚ･Ｇｙｾ､ / or maintenance charges as dett:nnined by thIS Corporation. In case of default you will be liable to pay interest @ ....... : ..... .. % p.a. on the amount Clue.

Page 2 f 5

. (c) ｾ＠

ｾ＠

,'; ＺＮＨ｣ｴＩ＠ｾＬ＠

·

ＭＭｾＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭｾＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭＭ

10. (a) You WID obey and lubmd to the rules of Municipal or authority nc:Ni existing or hereafter to exist so far as the same relate to the ImmovIbAl ptoporty In the Industrial area or so far as they affect the health, safety and convenience of the others, inhabUants of the ｾＬ and wit not release any obnoxious gaseous, liquid or solid effluents from the unit in any case. .

( ou wi! ･ｾ It your own cost an appropriate and efficient effluent treatment system/plant and will ensure that it is ready and functionai at per the norma and specifications expected laid down or stipulated by the State Effluent Boardl U.P. PollUtion ,ConttoIBoIId and any other authority established by law for the time beUlg in force before the production IS

ｾ［ｉｮ＠ the ｾｉＧＢｾ on ｾ plot of land covered by this letter. / t i ｾ［＠ｾ Coq)cnUon or Board Cantonment 8oaId. Zia PMshad. TOMl ｾｾ (any) other Ioc:aJ bodies (body)

takao.w: IhiI ｾＮ 01 UPSlOC. you wi ｾ liable to pay and .disc:ta'ge aI ｾｬｴ｡ｸ･ｳＮ＠ charges, claims and cNrgIIbIemIn4 8IIeIIInIN 01 ｾｾｾ may be I charged or Imposed upon then

.. ｾＮ＠ ahWa I the Iawt M..chc:tion 0I1he local body., 1 11'

ＮＺｬｪﾷｦｦ［Ｎ＠ｩｈｌｾＱ＠ Ti Ａ＠ＭｬｾｬＮｬｩ＠ ,}"r II I I' : r, ' " Ｌｾｾ＼＠ｾｾｴｦ＠ｾｙｐｕＢ､ｄｉｮｾｦｲ｡ｲｮｾｬｾ｣ｯｮ｣･ｭ･､Ｎ＠

· ＨｾｖｾＮｾｾ＠ I ｉｾｫﾷ . • ' I ·. il' , ".,., . ｾ｡ｉｾｬｮｹ｣ｵｲｵｮｩｴ＠ff.Vou WlappIf ilfI. ｾｾ , ｾ .,.. ｾ｡ｧ･ｮ｣ｹｾＮｰＮｬｐＹｷ･ｲ＠ as the case may be at your iI,

ｗｬ､Ｌｉｬｊ､ｃｏｬｴｎｯＢｲｪｾｾｾｾｆｦｍｲ｡ｮｹｾｙｾｩｮｾｾｾｮＮ＠ I ' ' !

12.' Before execution of lease Deed you shall have to: -

(a) Submit valid S.S.1. registration certificate Issued by Disbict Industries Centre or copy of receipt of filing memolandum with SIA or Letter of IntenV\ndustriai License as the case may be for the item manufacturing for whlch this allotment Is made.

(b) Clear all dues upto the date of executing Lease Deed as mentioned In dause3, 4 and 5 of this letter.

I (e) Nrt other folrnaJitieI requlted.1f any.

13. You d hawt to executa Che l.eaIe Deed and get the same registered within 60 days from the date of the letter trom the CorpotaUon asJdng you to do 10 faWng which the allotment Is liable to be cancelled with the consequences as per lause7 1bOYt.

14. You wlU have to taJte 0Ytf poasoulon arter executing Lease Deed within 30 days from the date of inviting you to do so IaIng wtUch the aIotment 1$ liable to be cancelled with the same consequences as in Clause7 above.

'.5. , ' ("n. ｾ Leue deed may be transferred to FlnanciallntitutionlBnak upon requesr in writing from you andth '

, ConcImId FInIndII Jntitub1IBank provided the loan has been sanctioned for the project for which this allotment b beingmadf by the FInIndaIIBInk reqWr1ng creation of moertgage and the same has assured in writing to UPSIDe Ltd.for making the J)IYmII1t01 foCal balance premJum of land In lumpsump out of the first disbursement of the sanctioned loan on half of UI6 alIoUN oralternatively the aJJottee ,makes payment ot total balance premium prior to transfer of lease deed.Aft r fulfillment of the above,the Corporation may allow to first charge to such Institution and transfer to it th'e onginal Lepse Deed In exchange for registered copy thereof '

(b) The original lease deed for the plot(s) may be transferred to the allotteellessee in exchange for registered duplicate copy thereot provided there area nl arrears of dues and the factorylbuilding has been established and commercial produ tion started/activity commenced tor which this allotment has been made to satisfaction of the Corporation and the allottee/lessee has aubmitted an undertaking on the prescribed fonn that he will obtain no objection from the Corporationllessee fore transferring the Lease Deed to any FinancJallntitutionlBank for creation of mortgage. Such a permission will be gra ted under proyiIion of dauM15(a) and thelr fulfilment

, 18. The aMoCment d be canc:eJIed If and when there happen BIlY of the events mentioned below and the same conaequenc:a wi tobv as stated In clause 7 above.

· (I) "you fall to executa Lease Deed and/or take possession of the land 81 contained In clause nos. 13 &14 within the time . etfpI.latad In dause 13, the time being of essence.

OR (b) If you fall to made payment of Interest and lor premium nad lor maintenance levy/service charges/and interest tI areon on or before tha dua date(s) as mentioned In clause 5 or this letter.

. , i

.; I I Ii, OR • • ' I I ｾ＠ , ' , I I : l I 1

tc)\f ':fou fall to sel up unit on the plot as per clause23 of if you violate any of the terms and conditions herein or of th lease deed.

OR (d) If it Is found that you have presented wrong facts,misrepresented before the Corporation.

OR (e) If the plot(s) is /are found to be under use different than allowed herein or allowed subsequently.

Page 3 of 5

-

. Index prevaJJlng . . . a/lottee.The allottee pay to the Corporation such maintenance charges on the first day of July each year.ln ca of nonpayment of the maintenance charges as mentioned above, the allottee shall have to pay interest @ .14.00..... per annum.Further, the Corporation reserve the right to cancel the allotment on nonpayment of maintenance charges.

ORlAND

You IhIIt pay aoMce charges C Ra...................per Sqm.per annum to the Corpola:tion from the date of allotment or on the

U mIY be rtMMd by the,COrporation fn?m ｾ to lima and intimated to you. I 20. The ｾ prenUn along wI#a ｾ .ta!", Interest will CORItitutB the rnt charge on the allotted P'ot till fully paid.

. . . , . I· ;1

y"" wi pay LIM and oocupation chIrguIIease'rent at the rate of Rs. Ｑｾ hectare per year during the t thirty As. ｾ per hodn pel 'lUI during the next thirty years after expiry of the first thirty years and Rs.500001..per

tIedn PIt)'611 dut1ng the next thJrty yeat'I after expiry of the first &lxty years. Use and occupation charges are pay ble till the ..... II gtant6d to ｾ where after lease rent wW have to be paid.

2%. .1bt ｾ･･ of UPSiDe Ltd. wiU mention in the postal address of this correspondence letters invariably

n.wne 01 UPSIDe InduatriaI area.

23. N Ihe pi)'montI to ｾ corporation should be made only through Bank Draft/pay order in favour of PSIDC Ltd payab e ｡ｴＮＮＮｊＮｾＢｈＧＧＧＧＧＧ＠ＧＧ＠ No payments In case or through cheques would be accepted.

24. You wia utiUze mJnJmum 30% area of the plot by covering It by rooflperrilanent shed within the specified period s c:ontaJned In the LeaM Coed, taJUngwhlch the allotment otthe pJot(s) will be canceUed.The Corporation In its discretion and

'upon satisfaction with UJe stepa taken by the 8IIotteelJessee for the setting up of the unit on the plot may grant extem lon of . time withlwithou\ payment aT fee and on such terms and conditions as amy be decided by it

25. It will be your &.Ole responsibility to get NOC from UPPCB (U.P. Pollution Control Board) and if it is not furnished to this Corpola:tion, you wW be I&at»e for action according to law and UPSIDC would not be responsible tOf any of yocs act for ｯｭＱｳ｡ｩｯｮ｡Ｇｾ may be In contravention to the U'p. Pollution Control Boatd rules environmental laws.

28.ThIs dolmInt IhaIII&Ind 8Utomatic:a1ly canceJIed ., there is 8lI'I change In the contitution Orthe aJIottee be It proprietorshlp, ｾ LmItad company Of c:IwngeI In MnhoIdIng position of the c:ompany etc. prevallng on the date of IIOCrNlnl WlhoYt prior ｾ In the writing _ CorpQratian. PermIssion ofchange In ｾ Of changes in .1hInbddIng paUem ruuIIqI either In retaInment Ollou of contIa of the original group of shareholders amy be granted on such lInnt and c:anditianI and upon payment 01 additional premiumIIevy as may be decided by the Corporation from time to

• . . ' If..

27. Tune extenalon fee &hall be payable as per rules of the COfl>OIclOOn if the unit does not come into productiQn within two yeatS from the dale of the allotment . 28. AI. present the plevaiUng rates are Ra.500.00........ pet sq.mtr. The allotment, transfer. resotratjon offer shall expile on the

mentioned In the allotment. tranafet. reatolatIon letter vmereatt.er the otfet shaI be treated as withdrawn. It after expiry of : ｾｾ＠ＭＢＧＭｾ ..... ＭＭＮｾＮＮＮ＠ + w"',.A ..... ｾ Jha ｾ "'" the default submit1ad.by him are found just & propElr

1!; .. ｦ［Ｚｾｪ＠Ｚ＠Ｚ＠ 111 ' It I l ! 11: ｾＺｾｴｨ･＠, :. ! rl l

11

29 . The allottee of plot will submit No Objection Certificate issued from U.P. Pollution Control Board before execution of lease deed .

ｾｯｲｰｮＮ＠ Ltd

Page 4 of 5

Copy torwwded tor Irlfonnation and necessary action to:

t. · InchaIge ＨｴａＩｾ＠ UPSiDe ｾＬ A-1/4, Lakhanpur. Kanpw. 208024 , l,: ' . . I,: . . I

.2. GInerII ｾ 0iIaric:l Centre.__ ｾＮ｟ .................._..;...............•'. ','! ｾＬＢ＠ i I;:) :' ! " i ,',' . I It ｾ＠ . '. r . . l

ﾷＢＡＧｾﾷﾷﾷﾷﾷﾷﾷＭＭﾷﾷﾷﾷｲﾷﾷﾷＧﾷﾷﾷﾷﾷＺｾﾷﾷﾷﾷﾷﾷﾷﾷﾷ＠

ｉｄｭｬｬｭｾｄｬ＠ｓ｣ｨｾｵｬ･＠I ,

Oue Date of Interest Due InataJJment'

'I

01(0112012 i I 418562.51

ｾｊＰＷｦｬＰＱｾＷＱ＠ 275254.49 I '

01/0112013 278279.26

4 01/0712013 274492.08

5 0110112014 251137.50

S 01/0712014 219593.66

7 0110112015 195329.17

8 01/0712015 164695.25

9 01/0112016 139520.84

10 01/0712016 110101.80

11 01/0112017 83483.78

12 01/0712017 54898.42

13 .. I 01/01/2018 27904.17

Nl).:.. .. ....... .. .ISIDClN .. ｾＮｾＮｾＮｾＮｾＮｉＮ＿ｾＮＧ .. ｾｾｾＮｾｾｾｾ .. .IA1IoUlA .... .ｾｾｾｾｩＮｉＮｾＮｾｉＮｉＮＧ .. ｾｾｾｾＮｾＮｾＮｾｾｩ .... ..... ............ ......... . Plot N ＱｽＮＺｾＮｾｉｊｽＮＺｴｾ .• ｾｾＮＱｉ .................... ......................................................................................Dated............ .. ........ .

m_ ••.•••· ............ ..

Regional Manager

Premium Due

0.00

0.00 " . ｬｾＧｩＧ＠

0.00

503212.50

503212.50 ,

503212.50

503212.50

503212.50

503212.50

503212.50

503212.50

503212.50

503212.50

Total Amount

418,582.51

275,254.49

278,279.26

m ,704.58

7 ,350.00 "

722,806.16

698, 541 .67

667,907.75

642733.34

613,314. 30

506,696.28

5& 8,1 10.92

5 1,116.67

Page ｾ＠ of 5

Annexure IV: Baseline Monitoring Report










































Annexure V: MSDS of PRODUCT

AMVAC CHEMICAL CORPORATION Page 1 of 9

VAPAM® SOIL FUMIGANT; METAM SODIUM AMVAC MSDS No.: 140_22

MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME(S): VAPAM® Soil Fumigant; VAPAM® Soil Fumigant Solution for All

Crops; METAM SODIUM; AMVAC METAM; METAM SODIUM Soil Fumigant

For All Crops; POLEFUME; VAPAM® Liquid Solution Soil Fumigant

CHEMICAL NAME: Sodium N-methyldithiocarbamate solution

MOLECULAR FORMULA: C2H4NNaS2

GENERAL USE: Soil Fumigant

PRODUCT DESCRIPTION: Orange to light yellow-green liquid with the possibility of an amine or a sulfur

odor.

EPA Registration Number(s): 5481-350; 5481-466; 5481-467; 5481-418; 5481-420; 5481-470

Registration Number(s) (Under the Canadian Pest Control Products Act): 6453; 13139

MSDS No.: 140_22

Current Revision Date: 14 November, 2007

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS:

AMVAC CHEMICAL CORPORATION MANUFACTURER: 323-264-3910

4100 E. Washington Blvd. TRANSPORTATION (24 HOURS)

Los Angeles, CA 90023-4406 CHEMTREC: 800-424-9300

Phone: 323-264-3910 OTHER (24 HOURS)

FAX: 323-268-1028 AMVAC: 323-264-3910

2. COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENT WT % CAS No.

Sodium N-methyldithiocarbamate (VAPAM®, Metam

Sodium)

32.7% 137-42-8

Inert Ingredients 67.3%

Ingredients not precisely identified are proprietary or nonhazardous.

Values are not product specifications.

OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)

COMPONENT HAZARD OSHA

PEL*

ACGIH

TLV*

NONE LISTED

* Exposure Limits 8 hrs. TWA (ppm)

VAPAM® is a registered Trademark of AMVAC Chemical Corporation.



EMERGENCY OVERVIEW:

DANGER! Dilution with water may generate poisonous gases (Methyl

isothiocyanate (MITC) or Hydrogen sulfide). Dilution with acids may

generate flammable gases (Carbon disulfide or Monomethylamine).

WARNING: Product is corrosive to skin. Prolonged or frequently repeated

skin contact may cause allergic reactions in some individuals. Harmful if

swallowed. Harmful if inhaled. Harmful if absorbed through the skin.

Irritating to eyes, nose and throat. Do not get on skin or clothing. Avoid

breathing vapor or spray mist. Do not get in eyes.

Toxic to fish. Do not contaminate water bodies.

3. HAZARDS IDENTIFICATION

POTENTIAL HEALTH EFFECTS

ROUTE(S) OF ENTRY: Skin contact, inhalation, ingestion, and eye contact with the liquid product.

As a result of use of the product, applicators and other persons present in the area of the

application can be exposed to MITC and/or hydrogen sulfide. These chemicals can be

evolved as gases from the soil of an application. MITC has a horseradish like odor and can

be very irritating to the eyes. Hydrogen sulfide has a rotten egg odor and can be very

offensive. If either odor is detected near an application of Metam Sodium, notify the

applicator of the problem and take appropriate measures to minimize/avoid exposure. The

nose becomes deadened to a hydrogen sulfide odor, so not being able to detect the odor any

longer does not mean the exposure has ended.

SIGNS OF ACUTE OVEREXPOSURE: Overexposure to Metam Sodium as sold may result in

damage to the skin, excessive salivation, sweating, fatigue, weakness, nausea, headache,

dizziness, eye, nose, throat and respiratory tract irritation. In addition, dilution to use levels

results in the release of methyl isothiocyanate (MITC) and/or hydrogen sulfide.

Overexposure to MITC may result in strong skin and eye irritation, running nose, dizziness,

cramps, nausea, vomiting, and mild to severe disturbances of the nervous system.

Overexposure to hydrogen sulfide may result in severe irritation to the eyes and mucous

membranes. In addition, exposure may result in headache, dizziness, excitement, staggering

gait, diarrhea, difficult or painful urination, difficult breathing, chronic pulmonary edema,

coma and death.

SIGNS OF CHRONIC OVEREXPOSURE: Same as above, plus conjunctivitis, photophobia,

digestive disturbances, weight loss, general bodily weakness and blurred vision. In addition,

laboratory studies have shown that exposure to the active ingredient, followed by ingestion

of alcohol, may cause an adverse reaction, including low blood pressure, rapid heart beat,

and flushing of the skin. Consumption of alcohol during and after exposure to this product

should be avoided.



3. HAZARDS IDENTIFICATION, cont'd

OTHER POTENTIAL HEALTH EFFECTS: Laboratory studies have shown some carcinogenic

effects and some developmental effects in laboratory animals. In vitro laboratory studies have

shown some evidence of mutagenicity, but there is no conclusive evidence in vivo. Exposure

monitoring studies conducted during agricultural applications of Metam sodium have shown

that human exposure is extremely low; therefore, any potential risk to humans from Metam

sodium exposure is considered minimal.

MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Impaired pulmonary

function and preexisting eye problems may be aggravated. Preexisting skin diseases may

also be aggravated by exposure to the decomposition products.

Care should be exercised and all label instructions should be followed, in the handling

of products containing Metam Sodium.

4. FIRST AID MEASURES

EYES: Immediately flush the eyes with copious amounts of clear, cool running water for a minimum

of 15 minutes. Hold the eyelids apart during the flushing to ensure rinsing of the entire

surface of the eyes and lids with water. Contact a physician immediately. If there will be

a delay in getting medical attention, rinse the eyes for at least another 15 minutes.

INHALATION: Remove victim to fresh air. If breathing has ceased, clear the victim's airway and

start mouth-to-mouth artificial respiration. If breathing is difficult, give oxygen. Contact a

physician immediately.

INGESTION: Immediately dilute the swallowed product by giving large quantities of water, but do

not induce vomiting. If vomiting occurs, give fluids again. Have a physician determine if

condition of patient will permit induction of vomiting or evacuation of stomach. Never give

anything by mouth to an unconscious person. Contact a physician immediately.

SKIN: Immediately flush all affected areas with large amounts of clear water for at least 15 minutes.

Remove contaminated clothing. Do not attempt to neutralize with chemical agents. Wash

clothing before reuse. If skin irritation develops, contact a physician immediately.

NOTE TO PHYSICIANS: Treat symptomatically. Contact your local, state, or national Poison

Control Center for additional information.

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES

Flash Point: > 200/F (TCC)

Autoignition Temperature: Not available



5. FIRE FIGHTING MEASURES, cont'd

Flammable Limits:

Lower flammable limit: Not available

Upper flammable limit: Not available

EXPLOSIVITY:

Mechanical Impact: Not available. Not expected to be sensitive to mechanical impact.

Static Discharge: Not available

Rate of Burning: Not available

Explosive Power: Not available

HAZARDOUS COMBUSTION PRODUCTS: This product can release toxic fumes of methyl

isothiocyanate (MITC) and hydrogen sulfide, as well as nitrogen oxides, when heated to

decomposition or diluted with water.

EXTINGUISHING MEDIA: This product is not flammable. However, this product may support

combustion under fire conditions and will generate toxic fumes under fire conditions. Base

extinguisher media on surrounding materials. NOTE: Dilution with water may cause

generation of flammable and toxic fumes of MITC and Hydrogen sulfide. See Chemical

Stability information in SECTION 10.

FIRE FIGHTING INSTRUCTIONS: Evacuate nonessential personnel from the area. Wear self-

contained breathing apparatus and impervious clothing. Clean all clothing before reuse.

6. ACCIDENTAL RELEASE MEASURES

GENERAL: Use adequate ventilation and appropriate personal protective equipment (PPE, Section

8). Contact with moisture in the soil can generate the flammable and toxic gases MITC and

Hydrogen sulfide. Keep bystanders upwind and away from the spill.

SMALL SPILL: Cover with absorbent (clay, sawdust, straw, kitty litter, etc.), to absorb the liquid

and vapors. Sweep into an open drum. Clean the area with common powdered household

detergent and a stiff brush and just enough water to make a slurry. Absorb and sweep into

the same open drum. Rinse with water, absorb, and add to the waste drum. Close the drum

and dispose of properly.

LARGE SPILL: Dike the spill to prevent contamination of local water sources. Siphon the majority

of the liquid into drums for use or disposal, depending on the circumstances. Clean the area

as described for a small spill.

7. HANDLING AND STORAGE

HANDLING: Prevent skin contact. Do not breathe fumes. Wear appropriate personal protective

equipment (Section 8). Wash thoroughly and change clothes after handling. See product

label for more detailed handling procedures.



7. HANDLING AND STORAGE, cont’d

STORAGE: Do not contaminate water, food or feed by storage or disposal. Store product in a cool,

dry, locked place out of reach of children. Do not store below 0/F. Product crystallizes at

lower temperatures. See label for specific instructions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: A well-ventilated area is recommended for handling Metam

Sodium. Use of mechanical or local exhaust systems is recommended.

RESPIRATORY PROTECTION: A properly FIT-TESTED NIOSH/MSHA approved respirator

fitted with organic vapor cartridges may be required when working with this product.

Specific use regulations are listed on the label.

SKIN PROTECTION: Chemical resistant gloves, body covering clothing that has long sleeves and

long pants, and chemical resistant shoes or boots, are required to prevent skin contamination.

A chemical resistant apron may be required under certain circumstances. Wear clean clothes

daily. Wash well with soap and water after handling this product. See the label for more

specific instructions.

EYE PROTECTION: Safety glasses must be worn whenever working with chemicals. Face-sealing

goggles (or full-face respirators) are required whenever ventilation is poor or a rotten egg

odor is detected.

OTHER PROTECTION: An eyewash station and a safety shower should be located in the work

area.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Liquid

APPEARANCE: Orange to light yellow-green liquid.

ODOR: Essentially odorless to fairly strong odor of amine or

sulfur.

BOILING POINT: 110/C/230/FFREEZING/MELTING POINT: -17/C/0/FVAPOR PRESSURE (mm/Hg): 24 mm Hg @ 25/CVAPOR DENSITY: Not available

SPECIFIC GRAVITY: 1.158 g/mL @ 20/C/4/C(68/F/39/F)

BULK DENSITY: 9.65 lb/gal

EVAPORATION RATE: 1.0 as compared to water.

PERCENT VOLATILE BY VOL: 67% (@ 100/C)

SOLUBILITY IN WATER: Miscible

pH: 9.0 - 10.5

PARTITION COEFFICIENT (W/O): Not applicable



10. STABILITY AND REACTIVITY

CHEMICAL STABILITY (Conditions to avoid): Metam Sodium decomposes, when diluted

with water, to methyl isothiocyanate (MITC, a lachrymator and moderate poison) and/or

to hydrogen sulfide (a highly poisonous gas). Use the solution promptly after mixing. Do

not allow the solution to stand. As originally packaged, Metam Sodium solutions are

stable under normal storage conditions for up to 2 years.

Metam Sodium can also decompose to carbon disulfide and monomethylamine (both

highly flammable) if contacted with a strong acid.

INCOMPATIBILITY: This product is incompatible with additional water and strong aqueous acids.

In addition, it is corrosive to copper, brass, and zinc, and may soften and/or discolor iron.

HAZARDOUS DECOMPOSITION PRODUCTS: When treated with water or heated to

decomposition, this product can give off toxic fumes of methyl isothiocyanate (MITC),

hydrogen sulfide, and nitrogen oxides. If treated with strong acids, fumes of carbon disulfide

and monomethylamine will be given off.

HAZARDOUS POLYMERIZATION: This product will not polymerize.

11. TOXICOLOGICAL INFORMATION

Information has been included for the product and for two potential decomposition products in order

to help potential users to have a clearer idea of the hazards associated with this product.

Toxicological

Category

Specific

Application

Metam

Sodium

(Product)*

MITC

(Decomposition)

Hydrogen sulfide

(Decomposition)

INGESTION Oral LD50 (rat): 812 mg/kg 55-220 mg/kg

INHALATION Inhalation LC50

(rat)

2.28 mg/L 1.9 mg/L air (1

hr)

444 ppm

DERMAL Skin LD50

(rabbit)

>2020 mg/kg 33 - 202 mg/kg

IRRITATION Eye (rabbit)

Skin (rabbit)

Mild Irritant

Moderate

Irritant

Corrosive

Corrosive

Corrosive

No information

OTHER Skin

sensitization

(guinea pig)

Sensitizer Sensitizer No Information

TERATOGENICITY: Laboratory studies on a related Metam sodium product* have shown some

developmental effects in laboratory animals.



11. TOXICOLOGICAL INFORMATION, cont’d

MUTAGENICITY: Laboratory studies on a related Metam sodium product* have shown some

evidence of mutagenicity in vitro but no conclusive evidence in vivo.

CARCINOGENICITY: Laboratory studies on a related Metam sodium product* have shown some

carcinogenic effects in laboratory animals.

REPRODUCTIVE TOXICITY: Laboratory studies on a related Metam sodium product* have

shown no evidence of reproductive toxicity in laboratory animals.

TOXICOLOGICALLY SYNERGISTIC PRODUCTS: No data are available for Metam Sodium

products.

* The data in this section were generated using Metam Sodium solutions with 42% active ingredient.

12. ECOLOGICAL INFORMATION

GENERAL: This product is toxic to fish. Do not apply directly to water, to areas where surface

water is present, or to intertidal areas below the mean high water mark. Do not contaminate

water when disposing of equipment washwaters.

13. DISPOSAL CONSIDERATIONS

PESTICIDE DISPOSAL: Do not contaminate water, food or feed by disposal. Wastes resulting

from the use of this product may be disposed on site by use according to the label or at an

approved waste disposal facility. Be sure to check with the appropriate Federal, State and

local authorities to determine the current regulations for your area.

CONTAINER DISPOSAL: Do not reuse the empty container. Triple rinse (or equivalent). Then

offer for recycling or reconditioning, or puncture and dispose in a sanitary landfill, or by

incineration, or, if allowed by State and local authorities, by burning. If the container is

burned stay out of the smoke. Be sure to check with the appropriate Federal, State and local

authorities to determine the current regulations for your area.

14. TRANSPORTATION INFORMATION

DOT CLASS: 8

UN NUMBER: UN3266

IMDG CLASS (sea): 8

MARINE POLLUTANT: Yes

IATA (air): 8

PACKING GROUP: III

HAZARD LABEL(s): CORROSIVE

ADR CLASS (road): Not listed in ADR

PROPER SHIPPING NAME(s): Corrosive liquid, basic, inorganic, n.o.s. (Metam

Sodium 32.7%)

REPORTABLE QUANTITY: No



14. TRANSPORTATION INFORMATION, cont’d

PACKAGING

GENERAL DESCRIPTION: Bulk tankers and trucks

15. REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS: This product is registered under EPA/FIFRA Regulations. It is

a violation of Federal Law to use this product in any manner inconsistent with its labeling.

Read and follow all label directions. This product is excluded from listing requirements

under EPA/TSCA.

When these products are used for small areas they are considered to be RESTRICTED USE

PESTICIDES. Due to acute toxicity, retail sale to and use only by Certified Applicators or

persons under their direct supervision and only for those uses covered by the Certified

Applicator’ s Certification.

CANADIAN REGULATIONS: This product is registered under the Pest Control Product Act of

Canada (CPR). It is a violation of Canadian Law to use this product in any manner

inconsistent with its labeling. Read and follow all label directions.

This product has been classified according to the hazard criteria of the CPR and the MSDS

contains all the information required by the CPR.

EUROPEAN UNION REGULATIONS: This product is registered in the European Union. It is a

violation of European Union regulations to use this product in any manner inconsistent with

its labeling. Read and follow all label directions.

SARA TITLE III DATA

Section 311 & 312 Hazard Categories:

Immediate Health Hazard: Yes

Delayed Health Hazard: Yes

Fire Hazard: No

Reactive Hazard: No

Sudden Pressure Release Hazard: No

Section 302 Extremely Hazardous Substances: None

Section 313 Toxic Chemicals: Metam Sodium (CAS 137-42-8) - 32.7%

CERCLA/EHS Reportable Quantity (RQ): None

STATE REGULATIONS:

CALIFORNIA (Proposition 65): Warning: This product contains Metam Sodium, a chemical

known to the State of California to cause cancer, birth defects or other reproductive harm.



16. OTHER INFORMATION

MSDS STATUS:

Date This Revision: 14 November, 2007

Date Previous Revision: 24 August, 2004

Person Responsible for Preparation: Gary A. Braden

REASONS FOR REVISION: Annual review. A change was made in section 6 to clarify the

information present. A change was made in section 14 to update the packaging descriptions.

DISCLAIMER: This information is provided for the limited guidance to the user. While AMVAC

believes that the information is, as of the date hereof, reliable, it is the user's responsibility

to determine the suitability of the information for its purposes. The user is advised not to

construe the information as absolutely complete since additional information may be

necessary or desirable when particular, exceptional, or variable conditions or circumstances

exist (like combinations with other materials), or because of applicable regulations. No

express or implied warranty of merchantability or fitness for a particular purpose or

otherwise is made hereunder with respect to the information or the product to which the

information relates.

ABBREVIATIONS:

ACGIH - American Conference of Governmental Industrial Hygienists

CERCLA - Comprehensive Environmental Response, Compensation, and

Liability Act

DOT - Department of Transportation

EHS - Extremely Hazardous Substance

EPA - Environmental Protection Agency

FIFRA - Federal Insecticide, Fungicide, and Rodenticide Act

HIS - Health Information Services

IARC - International Agency for Research on Cancer

IATA - International Air Transport Association

IMDG - International Maritime Dangerous Goods

NTP - National Toxicology Program

OSHA - Occupational Safety and Health Agency

SARA - Superfund Amendments and Reauthorization Act

TSCA - Toxic Substances Control Act

This is the last page of this MSDS. There should be 9 pages.

Product Name: Captan FS

Page 1 of 5

This revision is issued: June, 2012

MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600

Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227

SECTION 1 - PRODUCT & COMPANY IDENTIFICATION

ARYSTA LifeScience South Africa (Pty) Ltd Tel: 031 514 5600 Co. Reg. No.: 2009/019713/07 Fax: 031 514 5611 7 Sunbury Office Park, Off Douglas Saunders Drive, La Lucia Ridge, South Africa, 4019 e-mail: [email protected] Web address: arystalifescience.co.za

Substance: captab Product Name: CAPTAN FS Product Use: Fungicide Creation Date: October 2007 Revision Date: October 13 24 Hr Emergency Number: 082 771 2712 In case of Poisoning: Poison Information Centre 082 446 8946 Tygerberg Hospital: (021) 931 6129 Poison Emergency Enquiries (021) 689 5227 In case of Spillage: HAZMAT: 0800 147 112

SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS

Common name: Captab (South Africa) Chemical Name: N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide (IUPAC) CAS No.: 133-06-2 Chemical Family: N-trihalomethylthio Chemical Formula: C9H8Cl3NO2S (Mol. Wt.: 300.6). Use: Fungicide with protective and curative action. Formulation: Captab: 500 g/kg Flowable fungicide seed-dressing UN number: 3082 Active Ingredient: Captab SYMBOLS: Xn RISK-PHRASE(S): R 36, R 40, R 43

SECTION 3 - HAZARD IDENTIFICATION

Toxicity class: WHO Table; EPA – III A low toxicity fungicide. Likely routes of exposure: Skin and eye contact, inhalation and ingestion. The product may cause eye irritation. Skin contact: Minimally toxic. May cause mild skin irritation and may have moderate sensitizing properties (guinea pig). Ingestion: Minimally toxic. Inhalation: May be irritating to the respiratory system.

SECTION 4 - FIRST AID MEASURES AND PRECAUTIONS

Reactions are not likely to occur unless the absorbed dose is extraordinary. Symptoms of repeated exposure to the product may cause contact dermatitis. When product comes in contact with eyes the effect is redness of and tears. Inhalation: Remove source of contamination or move victim to fresh air and well-ventilated area. Monitor for respiratory distress. Give oxygen or artificial respiration if needed. Seek medical attention if necessary. Skin contact: Remove contaminated clothing, shoes and leather goods. Gently wipe off excess chemical. Wash skin gently and thoroughly with water and non-abrasive soap. Seek medical advice if necessary. Persons who become sensitized may require specialized medical management with anti-inflammatory agents.


Page 2 of 5




Eye contact: Immediately flush the eyes with gently flowing lukewarm water for 20 minutes. Obtain medical attention if necessary. Ingestion: Wash out mouth thoroughly with clean water. In case of ingestion of significant quantities of the fungicide, medical advice should be sought immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Advice to physician: No specific antidotes are available against Captan FS poisoning. If a large amount of Captan FS has been ingested in the last few hours, and if copious vomiting has not already occurred, the stomach must be emptied and steps taken to limit gastrointestinal absorption. If the patient is fully alert and nervous system depression is not anticipated, it is recommended to empty the stomach. When vomiting stops after induced emesis, give activated charcoal and cathartic orally by adding sorbitol to the charcoal slurry. Dosage of Activated Charcoal: Adults and children over 12 years: 50 to 100 mg in 300 to 800 ml water. Children under 12 years: 15 to 30 mg in 100 to 300 ml water. Dosage of Sorbitol: Adults and children over 12 years: 1 to 2 mg/kg body weight to a maximum of 150 mg per dose. Children under 12 years: 1.0 to 1.5 mg/kg body weight to a maximum of 50 mg per dose. If sorbitol is given separately, it should be diluted with an equal volume of water before administration. If there are any indications of central nervous system depression, or if the patient fails to vomit within 30 minutes of Syrup of Ipecac administration, measures should be taken to protect the respiratory tract from aspiration of gastric contents, then the stomach should be emptied by gastric intubation, aspiration and lavage with a slurry of activated charcoal. Install activated charcoal following lavage. Unless diarrhoea has already commenced, include a cathartic to hasten elimination. CAUTION: Do not instill fluid so rapidly that overloading of the stomach leads to vomiting or regurgitation, followed by aspiration. Serious electrolyte disturbances may follow catharsis, especially in young children. If contact with the toxicant has been minimal, administration of charcoal without the cathartic, followed by careful observation of the patient, probably represent optimal management.

SECTION 5 - FIRE-FIGHTING MEASURES

Fire hazard and explosion hazard: Slight fire hazard when exposed to heat or flame. Not highly flammable and not explosive. Hazardous decomposition products: Product releases CSCl2, HCl, SOx, NOx, CO and CO2 when exposed to very high temperatures. Extinguishing agents: Extinguish small fires with carbon dioxide, dry or foam chemical. Water spray can be used for cooling of unaffected stock, but avoid water coming in contact with the product. In case of large fires use water spray, fog or regular foam. Dike fire control water for later disposal. Firefighting: Fight fire from maximum distance. Remove container/bag from fire area if possible. Contain fire control agents for later disposal. Use a recommended extinguishing agent for the type of surrounding fire. Water can be used to cool unaffected containers/bags. Avoid inhaling hazardous vapours. Keep upwind. Personal protective equipment: Fire may produce irritating or poisonous vapours (toxic oxides of carbon, nitrogen and sulphur) of combustion. Fire fighters and others that may be exposed should wear full chemical protective clothing and self-contained breathing apparatus.

SECTION 6 - ACCIDENTAL RELEASE MEASURES (SPILLAGE)

Personal precautions: Avoid contact with skin and eyes. Do not breathe in fumes. For personal protection see Section 8. Environmental precautions: Do not allow entering drains or watercourses. When the product contaminates public waters, inform appropriate authorities immediately in accordance with local regulations. Occupational spill: For small dry spills, sweep up with damp earth or sand or other suitable absorbent and taking care not to raise a dust cloud. Place the material into a clean, dry container and cover for subsequent disposal. All contaminated cleaning materials should be placed in closeable receptacles. In situations where product comes in contact with water, contain contaminated water for later disposal. Do not flush spilled material into drains. Keep spectators away and upwind.


Page 3 of 5




SECTION 7 - HANDLING AND STORAGE REQUIREMENTS

Handling: Avoid contact with eyes, prolonged contact with skin, and inhalation of dust and vapour. Use with adequate ventilation. Wash hands before eating, drinking, chewing gum, smoking, or using the toilet. Remove clothing immediately if the product gets inside. Then wash skin thoroughly using a non-abrasive soap and put on clean clothing. Do not apply directly to areas where surface water is present, or to intertidal areas below the mean high water mark. Water used to clean equipment must be disposed of correctly to avoid contamination. Storage: Keep out of reach of unauthorized persons, children and animals. Store in its original labeled container/bag in shaded, well-ventilated area, away from heat, sparks and other sources of ignition - NO SMOKING. Store in dry area and protect from temperatures below 00C and above 500C. Avoid breaking the container/bag, spillage or leaks. Do not allow the product to become wet or overheated in storage, decomposition, impaired activity or fire may result. Not to be store next to foodstuffs and water supplies. Local regulations should be complied with.

SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION

It is essential to provide adequate ventilation. The measures appropriate for a particular work site depend on how this material is used and on the extent of exposure. Ensure that control systems are properly designed and maintained. Comply with occupational safety, environmental, fire, and other applicable regulations. PERSONAL PROTECTIVE EQUIPMENT: Respirator: An approved full-face respirator suitable for protection from dusts and mists of pesticides is required. Limitations of respirator use specified by the approving agency and the manufacturer must be observed. Respirator with P2 filter is recommended. Acceptable exposure limit for Captan: TLV (USA): TWA: 5 mg/m3; A3 (1996) Clothing: Employee must wear appropriate protective (impervious) clothing, boots, hat and equipment to prevent repeated or prolonged skin contact with this substance. Do not wear leather clothing. Gloves: Employee must wear appropriate chemical resistant protective gloves to prevent contact with this substance. Eye protection: The use of a face-shield is recommended. Emergency eyewash: Where there is any possibility that an employee’s eyes may be exposed to this substance; the employer should provide an eye wash fountain or appropriate alternative within the immediate work area for emergency use.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Solid – off-white amorphous wettable powder. Odour: Faint odour – characteristic. Explosive properties: Not explosive. Flammability: Not highly flammable. pH of a 1% aqueous solution: 6 - 9 Bulk density: 0.64 g/l Storage stability: Stable for 2 years under normal, dry storage conditions in unopened bags/containers. The product is

stable after 14 days at 54 oC (accelerated storage test). Solubility in water: Soluble in water. Melting point: 158 to 164°C. Boiling point: Captab decomposes. Vapour Pressure: 2.01 x 10-4 Pa at a temperature of 50°C (pure). Octanol/Water partition coefficient: KOW = 610.

SECTION 10 - STABILITY AND REACTIVITY

Stability: Considered stable in unopened containers/bags. Slowly decomposed by heat and moisture. No decomposition if stored and applied as directed. Incompatibility: Avoid contact with alkali materials, such as lime and Bordeaux mixture. Contact with these products will reduce fungicidal activity. Hazardous reactions: Hazardous polymerization will not occur.


Page 4 of 5




Hazardous decomposition products: CSCl2, HCl, SOx, NOx, CO and CO2.

SECTION 11 - TOXICOLOGICAL INFORMATION

Acute oral LD50: > 5000 mg/kg in rats. Acute dermal LD50: > 2000 mg/kg in rats. Acute inhalation LC50: > 2.6 mg/l in rats for 4 hours. Dermal sensitization: The product provokes moderate dermal sensitization by skin contact (Guinea pigs – maximization test). Skin irritation: Mildly irritant to skin of rabbits. Eye irritation: Irritating to eyes of rabbits. Carcinogenicity: A two-year study of Captan indicated duodenal tumors in mice after repeated administration of high dose levels. The NOEL (No Observed Effect Level) was 400 ppm. No evidence of carcinogenicity was observed in long-term studies with rats. Information on the mechanism of these tumors establishes a threshold for the duodenal tumors, and indicates that this tumor type is not relevant for human risk assessment at likely exposure levels. Teratogenicity: Animal studies did not detect any teratogenic effects. No human data available. Mutagenicity: Results taken from in-vivo tests suggest that the product is not mutagenic.

SECTION 12 - ECOLOGICAL INFORMATION

Degradability: The product is readily biodegraded in the environment. Mobility: The product has now mobility and does not leach. Accumulation: The product shows no tendency to bio-accumulate in aquatic organisms. ECOTOXICOLOGY: For active ingredients:

Birds: LD50: mallard ducks & pheasants > 5000 mg/kg

bobwhite quail 2000 – 4000 mg/kg Fish: Toxic to aquatic organisms (fish and algae), in laboratory experiments. Low toxicity in actual use, due to its hydrolytic instability. LC50 (96 h) bluegill sunfish 0.072 mg/l

harlequin fish 0.3 mg/l brook trout 0.034 mg/l

Bees: ED50 oral: 91 μg/bee contact: 788 μg/bee Daphnia: LC50 (48 h) 7 to 10 ppm Other Aquatic organisms: Moderately toxic to aquatic invertebrates.

SECTION 13 - DISPOSAL CONSIDERATION

Pesticide disposal Contaminated absorbents, used containers, surplus product, etc., should be burnt at > 1000oC in an incinerator, preferably designed for pesticide disposal, or buried in an approved landfill. Comply with local legislation applying to waste disposal. Do not allow material to contaminate ground water system and surface water. Package product wastes: Do not re-use empty container/bags for any other purpose. Do not contaminate dams, rivers, drinking water and boreholes with chemical or used container. Incinerate the material at a facility that complies with local, state and federal regulations.


Page 5 of 5




SECTION 14 - TRANSPORT INFORMATION

UN NUMBER: 3082 ADR/IRD: Class: 9 Substance ID no.: 3082 Hazard ID no.: 90 ITEM: 12(c) PACKING GROUP: III Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Captab 500 g/kg) IMDG/IMO: Packaging group: III Class: 9 Shipping name: Environmentally hazardous substance, liquid, n.o.s. (contains Captab 500 g/kg) IMDG Page: 9029

SECTION 15 - REGULATORY INFORMATION

Symbol: Xn Indication of danger: Harmful Risk phrases: R 36 May cause eye irritation R 40 Possible risks of irreversible effects. R 43 May cause sensitization by skin contact. Safety phrases: S 1/2 Keep locked up and out of reach children. S 13 Keep away from food, drink and animal feeding stuffs. S 22 Do not breathe dust. S 24/25 Avoid contact with skin and eyes. S 36/37 Wear suitable protective clothing and gloves. S 46 If swallowed seek medical advice immediately and show this container and label.

SECTION 16 - OTHER INFORMATION

Packing: Packed in 1, 2, 5, 10, 20, 25 & 50 kg paper lined bags and/or containers and labeled according to South African regulations and guidelines. Disclaimer: The information on this sheet is not a specification; it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage use of the product. It is not applicable to unusual or non-standard uses of the product nor where instructions or recommendations are not followed. All information is given in good faith but without guarantee in respect of accuracy, and no responsibility is accepted for errors and omissions or the consequence thereof.

Aldrich - D152803 Page 1 of 7

SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 Version 6.0 Revision Date 30.03.2016

Print Date 03.05.2017 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers Product name : Dimethylcarbamyl chloride

Product Number : D152803 Brand : Aldrich Index-No. : 006-041-00-0 REACH No. : 01-2119472139-34-XXXX CAS-No. : 79-44-7

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Company : Sigma-Aldrich Chemical Pvt Limited Industrial Area, Anekal Taluka Plot No 12, 12 Bommasandra - Jigani Link Road 560100 BANGALORE INDIA

1.4 Emergency telephone number

Emergency Phone # : +91 98802 05043

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Carcinogenicity (Category 1B), H350 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008 Pictogram

Signal word Danger Hazard statement(s) H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled.


H335 May cause respiratory irritation. H350 May cause cancer. Precautionary statement(s) P201 Obtain special instructions before use. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face

protection. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for

breathing. Call a POISON CENTER/doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Supplemental Hazard Statements

none

2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.1 Substances Formula : C3H6ClNO

Molecular weight : 107.54 g/mol CAS-No. : 79-44-7 EC-No. : 201-208-6 Index-No. : 006-041-00-0 Registration number : 01-2119472139-34-XXXX

Hazardous ingredients according to Regulation (EC) No 1272/2008

Component Classification Concentration

Dimethylcarbamoyl chloride

CAS-No. EC-No. Index-No. Registration number

79-44-7 201-208-6 006-041-00-0 01-2119472139-34-XXXX

Acute Tox. 4; Acute Tox. 3; Skin Irrit. 2; Eye Irrit. 2; Carc. 1B; STOT SE 3; H302, H331, H315, H319, H350, H335 Concentration limits: >= 0.001 %: Carc. 1B, H350;

<= 100 %


SECTION 4: First aid measures

4.1 Description of first aid measures

General advice Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.


4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information Use water spray to cool unopened containers.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.

6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections For disposal see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Moisture sensitive. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8: Exposure controls/personal protection

8.1 Control parameters

8.2 Exposure controls

Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Personal protective equipment

Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use (US) or type ABEK (EN 14387) respirator cartridges as a backup to enginee protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

a) Appearance Form: clear, liquid Colour: colourless

b) Odour No data available

c) Odour Threshold No data available

d) pH No data available

e) Melting point/freezing point

Melting point/range: -33 °C

f) Initial boiling point and boiling range

167 - 168 °C at 1033 hPa

g) Flash point 82 °C - closed cup

h) Evaporation rate No data available

i) Flammability (solid, gas) No data available

j) Upper/lower flammability or explosive limits

No data available

k) Vapour pressure No data available


l) Vapour density No data available

m) Relative density 1.168 g/mL at 25 °C

n) Water solubility No data available

o) Partition coefficient: n-octanol/water

No data available

p) Auto-ignition temperature

No data available

q) Decomposition temperature

No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties No data available

9.2 Other safety information No data available

SECTION 10: Stability and reactivity

10.1 Reactivity No data available

10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions No data available

10.4 Conditions to avoid Heat, flames and sparks.

10.5 Incompatible materials Strong oxidizing agents, Strong bases

10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas Other decomposition products - No data available In the event of fire: see section 5

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Oral - Rat - 1,000 mg/kg(Dimethylcarbamoyl chloride) LC50 Inhalation - Rat - 6.0 h - 180. ppm(Dimethylcarbamoyl chloride) LD50 Intraperitoneal - Mouse - 300 mg/kg(Dimethylcarbamoyl chloride)

Skin corrosion/irritation No data available(Dimethylcarbamoyl chloride)

Serious eye damage/eye irritation No data available(Dimethylcarbamoyl chloride)

Respiratory or skin sensitisation No data available(Dimethylcarbamoyl chloride)

Germ cell mutagenicity


No data available(Dimethylcarbamoyl chloride)

Carcinogenicity This product is or contains a component that has been reported to be proba EPA classification.(Dimethylcarbamoyl chloride) Possible human carcinogen(Dimethylcarbamoyl chloride) (Dimethylcarbamoyl chloride)

IARC: 2A - Group 2A: Probably carcinogenic to humans (Dimethylcarbamoyl chloride)

Reproductive toxicity No data available(Dimethylcarbamoyl chloride)

Specific target organ toxicity - single exposure May cause respiratory irritation.(Dimethylcarbamoyl chloride) May cause respiratory irritation.(Dimethylcarbamoyl chloride) May cause respiratory irritation.(Dimethylcarbamoyl chloride)

Specific target organ toxicity - repeated exposure No data available

Aspiration hazard No data available(Dimethylcarbamoyl chloride)

Additional Information RTECS: Not available Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Inhalation may provoke the following symptoms:, spasm, inflammation and edema of the bronchi, spasm, inflammation and edema of the larynx, pneumonitis, pulmonary edema, Symptoms and signs of poisoning are:, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Contact with eyes can cause:, Lachrymation(Dimethylcarbamoyl chloride)

SECTION 12: Ecological information

12.1 Toxicity No data available

12.2 Persistence and degradability No data available

12.3 Bioaccumulative potential No data available

12.4 Mobility in soil No data available(Dimethylcarbamoyl chloride)

12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.


Contaminated packaging Dispose of as unused product.

SECTION 14: Transport information

14.1 UN number ADR/RID: 2262 IMDG: 2262 IATA: 2262

14.2 UN proper shipping name ADR/RID: DIMETHYLCARBAMOYL CHLORIDE IMDG: DIMETHYLCARBAMOYL CHLORIDE IATA: Dimethylcarbamoyl chloride

14.3 Transport hazard class(es) ADR/RID: 8 IMDG: 8 IATA: 8

14.4 Packaging group ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user No data available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3.

H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H335 May cause respiratory irritation. H350 May cause cancer.

Further information Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

1

Diafenthiuron -MATERIAL SAFETY DATA SHEET

Manufacturer/information service:

ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: [email protected] [email protected]

1. Chemical Product Identification

Product Name: Diafenthiuron

Molecular Formula: C23H32N2OS

Molecular Weight: 384.6

Structural Formula:

Chemical Name: 1-tert-butyl-3-(2,6-di-isopropyl-4-phenoxyphenyl)thiourea

Form: Solid

Color: White powder. Odor: Odorless CAS No.: 80060-09-9

2. Composition / Information on Ingredients

Composition CAS No. Content %

Diafenthiuron 80060-09-9 95.0

Other ingredients 5.0

3. Hazards Identification

2

May cause sensitization by skin contact. Harmful: Danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.

4. First Aid Measures

In case of poisoning by any exposure route contact a doctor or Poisons Information Centre.

Swallowed: If swallowed, contact medical care immediately.

Eye: If product gets in eyes, flush eyes with running water for at least 15 minutes.

Skin: If skin contact occurs, remove contaminated clothing and wash affected areas thoroughly with soap and water. Wash contaminated clothing before re-use.

Inhaled: Move affected person to fresh air and keep at rest until recovered.

5. Fire-Fighting Measures

This product is non-flammable. Extinguish warehouse and factory fires using fine-water spray or foam. When fighting a major fire wear a respirator. Do not allow fire-water to enter drains.

6. Accidental Release Measures

In case of spillage it is important to take all steps necessary to: Avoid eye and skin contact. Avoid contamination of waterways.

7. Handling and Storage

Store in tightly sealed original containers in a dry secure place away from fertilisers, seed, feed and food. Store out of direct sunlight. Keep out of reach of children, unauthorised persons and animals.

8. Exposure Controls/Personal Protection

Engineering Controls:

No special requirements. Product is used outdoors.

Manual flagging is not permitted during aerial spraying of PEGASUS.

Personal Protection:

Will irritate the eyes and skin. Avoid contact with eyes and skin. Do not inhale spray mist.

When opening the container, preparing the spray and using the prepared spray wear:

Cotton overalls buttoned to the neck and wrist.

A washable hat, and

Elbow length PVC gloves.

3

Wash hands after used. After each day’s use, wash gloves and contaminated clothing.

Only use protective equipment bearing the mark .

9. Physical and Chemical Properties

Specific gravity: 1.050 g/cm3 (at 20°C) Behaviour in water: Dispersible PH: 7.0 - 7.5

Melting point: 144.6-147.7°C.

Vapor pressure: <2 × 10-3 mPa (25°C).

Solubility at 25°C in: acetone 320 g/l, ethanol 43 g/l, n -hexane 9.6 g/l, n -octanol 26 g/l, toluene 330 g/l.

10. Stability and Reactivity

Stability : stable at room temperature

Corrosiveness: Non-corrosive

Flammability: This product is non-flammable and non-combustible.

11. Toxicological Information

ACUTE:

Toxicity: This product is moderately hazardous (WHO Hazard Class II)

Swallowed: LOW TOXICITY

Tests indicate low toxicity following single doses of the undiluted product.

(LD50 = 1950 mg/kg)

Dermal absorption: LOW TOXICITY

Tests indicate a low toxicity due to skin contact of the undiluted product.

(LD50 = >4000 mg/kg)

Irritation:

Eye: Slight irritant.

Skin: Slight irritant.

Sensitization:

Skin: Not a sensitiser.

12. Ecological and Ecotoxicological Information

Toxicity on aquatic organisms

4

LC50 (96h) : carp 0.0038mg/l

Rainbow trout 0.0007mg/l

Bluegill 0.0013mg/l

Toxicity on birds

Acute oral LD50 (mg/kg) : mallard and bobwhite quail >1500

LC50 (8days) ; mallard and bobwhite quail >1500mg/kg

Toxicity on other organisms

Bee LD50 (48h) : 2.1μg/bee(oral) , 1.5μg/bee(contact)

13. Disposal Considerations

Dispose of empty, used containers by:

Triple rinsing or preferably pressure rinsing containers with water. Add the

rinsings to the spray tank. Do not dispose of undiluted chemicals on site.

If recycling, replace cap and return clean containers to recycler or designated collection point.

If not recycling, break, crush or puncture and bury empty containers in a local authority landfill. If no landfill is available, bury the containers below 500 mm in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots. Empty containers and product should not be burnt.

14. Transport Information

Not applicable.

15. Regulatory Information

Not applicable.

16. Other Information

All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.

Safety Data Sheet ALPINE DUST INSECTICIDE Revision date : 2009/12/18 Page: 1/7

Version: 1.0 (30472990/SDS_GEN_US/EN)

1. Product and Company Identification

24 Hour Emergency Response Information Company BASF CORPORATION 100 Campus Drive Florham Park, NJ 07932, USA

CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Synonyms: Dinotefuran


Emergency overview CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Moderately irritating to the eyes. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling. State of matter: solid Colour: white Odour: earthy Potential health effects Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Acute toxicity: Relatively nontoxic after single ingestion. Relatively nontoxic after short-term skin contact. Relatively nontoxic after short-term inhalation. Irritation / corrosion: May cause moderate but temporary irritation to the eyes. May cause slight irritation to the skin. Sensitization: Skin sensitizing effects were not observed in animal studies.




CAS Number Content (W/W) Chemical name 165252-70-0 0.25 % dinotefuran 61790-53-2 99.75 % Diatomaceous Earth

4. First-Aid Measures

General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow.


Flash point: not applicable

Self-ignition temperature: not self-igniting

Suitable extinguishing media: foam, dry extinguishing media, carbon dioxide, water spray Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

6. Accidental release measures

Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.



Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund'). Cleanup: Dike spillage. Sweep/shovel up. Avoid raising dust. Use wet cleaning methods when applicable. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.


Handling

General advice: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage

General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Storage incompatibility: General advice: Segregate from foods and animal feeds. Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Storage stability: May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet.

8. Exposure Controls and Personal Protection

Components with workplace control parameters

OSHA TWA value 20 millions of particles per cubic foot of air ; TWA value 0.8 mg/m3 ; The value is calculated from a specified equation using a value of 100%. Lower values of % will give higher exposure limits. See regulation for specific equation.

Diatomaceous Earth



Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.


Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.


Form: powder Odour: earthy Colour: white pH value: not soluble

Melting point: 760 °C

Boiling point: not applicable

Density: 0.035 g/cm3

Solubility in water: slightly soluble


Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme temperatures. Avoid prolonged exposure to extreme heat. Avoid contamination. Avoid electro-static discharge. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded. Substances to avoid: organic acids Hazardous reactions: The product is chemically stable.



Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: not fire-propagating

11. Toxicological information

Acute toxicity Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg Inhalation: Type of value: LC50 Species: rat Value: > 2.08 mg/l Dermal: Type of value: LD50 Species: rat Value: > 5,000 mg/kg Irritation / corrosion Skin: Species: rabbit Result: Slightly irritating. Eye: Species: rabbit Result: moderately irritating Sensitization: Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies. Genetic toxicity Information on: dinotefuran No mutagenic effects reported. ---------------------------------- Carcinogenicity Information on: dinotefuran In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed. ----------------------------------



Reproductive toxicity Information on: dinotefuran No reproductive toxic effects reported. ---------------------------------- Development: Information on: dinotefuran No indications of a developmental toxic / teratogenic effect were seen in animal studies. ----------------------------------

12. Ecological Information Fish Information on: dinotefuran Acute: Oncorhynchus mykiss/LC50 (96 h): > 100 mg/l ---------------------------------- Aquatic invertebrates Information on: dinotefuran Acute: shrimp/LC50 (96 h): 0.79 mg/l ----------------------------------

13. Disposal considerations

Waste disposal of substance: Pesticide wastes are regulated. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Must be dumped or incinerated in accordance with local regulations. Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.


Land transport USDOT

Not classified as a dangerous good under transport regulations

Sea transport IMDG




Air transport IATA/ICAO



Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt EPCRA 311/312 (Hazard categories): Acute;


Recommended use: insecticide BASF supports worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

Aldrich - 135895 Page 1 of 7

SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 Version 6.0 Revision Date 31.03.2016

Print Date 03.05.2017 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA


1.1 Product identifiers Product name : Dimethylthiocarbamoyl chloride

Product Number : 135895 Brand : Aldrich REACH No. : A registration number is not available for this substance as the substance

or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

CAS-No. : 16420-13-6




Company : Sigma-Aldrich Chemical Pvt Limited Industrial Area, Anekal Taluka Plot No 12, 12 Bommasandra - Jigani Link Road 560100 BANGALORE INDIA


Emergency Phone # : +91 98802 05043



Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Skin corrosion (Category 1B), H314 Skin sensitisation (Category 1), H317


2.2 Label elements

Labelling according Regulation (EC) No 1272/2008 Pictogram

Signal word Danger Hazard statement(s) H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.


Precautionary statement(s) P280 Wear protective gloves/ protective clothing/ eye protection/ face

protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. Supplemental Hazard Statements

none

2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachrymator., Stench.


3.1 Substances Formula : C3H6ClNS

Molecular weight : 123.60 g/mol CAS-No. : 16420-13-6 EC-No. : 240-468-5 Hazardous ingredients according to Regulation (EC) No 1272/2008


Dimethylthiocarbamoyl chloride

CAS-No. EC-No.

16420-13-6 240-468-5

Acute Tox. 4; Skin Corr. 1B; Skin Sens. 1; H302, H314, H317

<= 100 %




General advice Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.

In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed No data available



5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride gas

5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information No data available


6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections For disposal see section 13.


7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Recommended storage temperature 2 - 8 °C

Moisture sensitive. Storage class (TRGS 510): Non-combustible, corrosive hazardous materials

7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated




Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.


Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).


Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use (EN 143) respirator cartridges as a backup to engineering controls. If th full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure Do not let product enter drains.



a) Appearance Form: crystalline Colour: light yellow

b) Odour No data available

c) Odour Threshold No data available

d) pH No data available

e) Melting point/freezing point

Melting point/range: 39 - 43 °C - lit.

f) Initial boiling point and boiling range

90 - 95 °C at 0.7 hPa - lit.

g) Flash point 98 °C - closed cup

h) Evaporation rate No data available

i) Flammability (solid, gas) No data available

j) Upper/lower flammability or explosive limits

No data available

k) Vapour pressure No data available

l) Vapour density No data available

m) Relative density No data available

n) Water solubility No data available

o) Partition coefficient: n-octanol/water

No data available

p) Auto-ignition temperature

No data available

q) Decomposition temperature

No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties No data available


9.2 Other safety information No data available


10.1 Reactivity No data available

10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions No data available

10.4 Conditions to avoid No data available

10.5 Incompatible materials Strong oxidizing agents, Amines, Strong bases, Keep away from water.

10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride gas Other decomposition products - No data available In the event of fire: see section 5



Acute toxicity No data availableDimethylthiocarbamoyl chloride

Skin corrosion/irritation No data available(Dimethylthiocarbamoyl chloride)

Serious eye damage/eye irritation No data available(Dimethylthiocarbamoyl chloride)

Respiratory or skin sensitisation

Germ cell mutagenicity No data available(Dimethylthiocarbamoyl chloride)

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity No data available(Dimethylthiocarbamoyl chloride)

Specific target organ toxicity - single exposure No data available(Dimethylthiocarbamoyl chloride)

Specific target organ toxicity - repeated exposure No data available

Aspiration hazard No data available(Dimethylthiocarbamoyl chloride)

Additional Information RTECS: Not available Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea(Dimethylthiocarbamoyl chloride)



12.1 Toxicity No data available

12.2 Persistence and degradability No data available

12.3 Bioaccumulative potential No data available

12.4 Mobility in soil No data available(Dimethylthiocarbamoyl chloride)

12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects No data available



Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chem scrubber.

Contaminated packaging Dispose of as unused product.


14.1 UN number ADR/RID: 3261 IMDG: 3261 IATA: 3261

14.2 UN proper shipping name ADR/RID: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Dimethylthiocarbamoyl chloride) IMDG: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Dimethylthiocarbamoyl chloride) IATA: Corrosive solid, acidic, organic, n.o.s. (Dimethylthiocarbamoyl chloride)

14.3 Transport hazard class(es) ADR/RID: 8 IMDG: 8 IATA: 8

14.4 Packaging group ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user No data available


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out




H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

Further information Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

1

Folpet-MATERIAL SAFETY DATA SHEET




Product Name: Folpet

Molecular Formula: C9H4Cl3NO2S.


Structural Formula:

Chemical Name: N- [(Trichloromethyl) thio] phthalimide

Form: Solid

Color: Off-white.

Odor: Faint odor (characteristic).

CAS No.: 133-07-3

2. Composition / Information On Ingredients


Folpet 133-07-3 95.0



Human health hazards: Irritating to eyes. May cause sensitization by skin contact.

Environmental hazards: Toxic to aquatic organisms.

2


Inhalation: Remove victim to fresh air. Keep victim warm and at rest. If breathing is difficult: give oxygen. If not breathing: apply artificial respiration.

Get medical attention.

Ingestion: Induce vomiting. Never give anything by mouth to an unconscious person. Wash out mouth with water. Consult a doctor.

Skin contact: Remove contaminated clothing. Wash off with plenty of water and soap. Consult a doctor in the event of any complaints.

Eye contact: Wash off with plenty of water for at least 15 minutes. If pain persists, consult an eye specialist.

Notes to a physician: There is no specific antidote. Treat symptomatically and give supportive therapy. If ingested perform gastric lavage and administer activated charcoal.


Extinguishing media: In case of a small fire: foam or dry chemical, carbon dioxide. In case of a large fire: Water spray, fog or regular foam.

Hazardous decomposition products: CSCl2, HCl, SOx, NOx, CO, CO2

Fire-fighting procedures: Firefighters should wear suitable protective clothing. Self-contained breathing apparatus. Fight fires from a protected location. Dike fire control water for later disposal.


Action to take for spills: Collect spilled material with shovel, place into a clean container and cover container loosely. Avoid contact, isolate area and keep animals and unprotected persons. Confine spills.

Personal Precautions: Use appropriate protection

Environmental Precautions: Dispose of this material and its container at hazardous or special waste collection point. If the product has contaminated surface water, inform the appropriate authorities.

7. Handling And Storage

Handling: Avoid generation of dust. Do not breathe dust. Avoid contact with skin and eyes.

Storage: Keep locked up. Keep container tightly closed. Keep only in the original container in a cool, well-ventilated place. Keep container dry.


3

Engineering measures: Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower.

Hygiene measures: Wash hands thoroughly after handling. Wash clothing separately before re-use.

Respiratory system: During spraying wear suitable respiratory equipment.

Skin and body: Wear suitable protective clothing and chemical resistant boots.

Hands: Wear suitable gloves.

Eyes: Safety goggles or face shield.


Melting point: 117℃

Vapor pressure: 2.10X 10-5Pa @ 25℃

Density : 1.72@20℃

Partition coefficient : KowlogP=3.11

PH: 6

Solubility in water: Insoluble in water (0.8mg/L)

Flammability: Not flammable

Explosivity: Not explosive


Stability: Stable under normal dry conditions.

Conditions to avoid : Protect from (sun)light, open flame sources of heat and humidity.

Materials to avoid: Alkali materials, such as lime and Bordeaux mixture will reduce fungicidalactivity.

Hazardous reactions :Hazardous polymerization will not occur.

Hazardous decomposition products: CSCl2, HCl, SOX, NOX, CO, CO2


Acute toxicity

Oral: LD50 > 9000 mg/kg (rat).

Dermal: LD50 > 4500 mg/kg (rabbit).

Inhalation: Not applicable.

Skin irritation: Mildly irritating (rabbit).

Eye irritation: Irritating to eyes (rabbit).

4

Sensitization: Guinea pig maximization test: sensitizer.

Reproductive Effects: A 2-generation reproductive study in rats produced a parental NOEL of 34.5 mg/kg/day. The same study showed decreased weight gain in F1 offspring. The NOEL in F2 matings was 40 mg/kg/day based on decreased body weight gain, decreased fertility of males and a Lowest Effect Level (LEL) of 180 mg/kg/day. Another study reported no significant effect on reproductive performance over three generations in rats at 1,000 mg/kg diet. The result from one study of pregnant hamsters given a single dose of between 500 and 900 mg/kg on days seven or eight of gestation, was an increase in fetal mortality and the production of some abnormal fetuses. Chronic administrations to pregnant rabbits of a cumulative dose of 488 mg/kg for 13 days produced adverse effects on fertility. Treatment of male mice by Bateman's dominant lethal procedure did not induce dominant lethal mutations as measured by increase in early post-implantation deaths. Chronic inhalation exposure to folpet showed an increase of fetal mortality in an inhaltion study of pregnant mice exposed to 491 mg/m3/4 hours/day for 8 days

Teratogenic Effects: Folpet was found to be positive in producing developmental effects in both rabbits and rats. In rabbits, the developmental NOEL was 10 mg/kg and the LEL was 20 mg/kg (hydrocephalus, domed skull, and irregularly shaped fontanelles). In rats, the NOEL was 60 mg/kg and the developmental LEL was 360 mg/kg.

Mutagenic Effects: In both E. coli and S. typhimurium, reverse mutations occurred, with a positive direct acting mutagen. In vivo, the Drosophila sex-linked recessive assay was positive using folpet. In a mouse somatic cell mutation assay, the results were negative, although a significant pup mortality occurred at all dose levels.

Carcinogenic Effects: In a carcinogenicity study in mice, folpet was found to be a carcinogen with a dose-related increased incidence of adenocarcinomas in the duodenum (a rare neoplasma in CD-1 mice) in all dose groups (142.321, 714.3 and 1714.2 mg/kg/day respectively). Another carcinogenicity study in mice also found folpet to be a positive carcinogen with a dose-related increased incidence of adenocarcinomas in the duodenum (a rare neoplasma in B6C3F1 mice) in all dose groups (142.9, 714.3 and 1428.6 mg/kg/day respectively). In another study, Sprague-Dawley rats were fed a diet of 200, 800, or 3,200 ppm of folpet. No carcinogenic effects were reported.

Organ Toxicity: In a 90-day feeding study in rats, the NOEL was established at 3,000 ppm and the LEL was 10,000 ppm. Noted effects were decreased brain weight and decreased total blood protein including albumin.

12. Ecological And Ecotoxicological Information

Effects on Birds: Acute oral studies indicated that folpet is slightly toxic to upland game bird species. Subacute dietary toxicity studies with bobwhite quail and mallard ducks also indicate that folpet is slightly toxic to birds when it is ingested in the diet of these birds. The avian reproductive studies indicate that technical folpet is not expected to cause reproductive impairment. Folpet is considered slightly toxic to avian species. The LC50 for bobwhite quail is >2,510 mg/kg and the LC50 for the mallard duck is >5,000 ppm.

Effects on Aquatic Organisms: Studies with typical end-use products indicate that folpet is highly toxic to both rainbow trout and bluegill sunfish. Rainbow trout were the most

5

sensitive species and the folpet product tested was classified in the very highly toxic range of toxicity for this species. The 96-hr LC50 for bluegill sunfish is 675 ppb and the 96-hr LC50 for rainbow trout is 185 ppb. Folpet is characterized as being "highly toxic" to both coldwater and warmwater fish. Data from a study with a typical end-use product of folpet indicate that folpet is toxic to aquatic invertebrtates. The 48-hr LC50 for Daphnia magna is 0.60 ppm, which is considered very highly toxic to aquatic invertebrates.

Effects on Other Animals (Nontarget species): Folpet is considered relatively non-toxic to honeybees.


Disposal according to the local legislation.


Not applicable.


Not applicable.



Safety Data Sheet SOVRAN FUNGICIDE Revision date : 2012/06/12 Page: 1/8Version: 2.0 (30172959/SDS_CPA_CA/EN)

1. Product and Company Identification

24 Hour Emergency Response Information Company

BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA

CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)

Molecular formula: C(18) H(19) N O(4)

Chemical family: strobilurine

PCP # 26257 Synonyms: kresoxim methyl


Emergency overview CAUTION: POISON. WARNING: Contains the allergen soy. KEEP OUT OF REACH OF CHILDREN. Causes eye irritation. HARMFUL IF SWALLOWED. Avoid contact with the skin, eyes and clothing. Do not breathe dust. Do not breathe vapours/mists. State of matter: solid Colour: dark brown Odour: sulfur-like, mild Potential health effects Acute toxicity: Harmful if swallowed. Irritation / corrosion: May cause slight irritation to the skin. May cause moderate but temporary irritation to the eyes. Irritation is possible when the product comes in contact with the skin, respiratory tract or the eyes. Sensitization: There is no evidence of a skin-sensitizing potential. Medical conditions aggravated by overexposure:


Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures. Potential environmental effects Aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Terrestrial toxicity: Acutely harmful to terrestrial organisms.


Not WHMIS controlled.

4. First-Aid Measures

General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. Assist in breathing if necessary. Consult a physician. If on skin: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. If in eyes: Hold eyelids open to facilitate rinsing. Flush with copious amounts of water for at least 15 minutes. If symptoms persist, seek medical advice. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting. Immediate medical attention required. Note to physician Antidote: No known specific antidote. Treatment: Treat symptomatically.


Autoignition: 340 °C

Upper explosion limit: not determined

Flammability: not highly flammable

(Directive 84/449/EEC, A.10)

Self-ignition temperature: 248 °C (Directive 92/69/EEC, A.16) Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen oxide, nitrogen dioxide, Hydrocarbons,


The substances/groups of substances mentioned can be released if the product is involved in a fire. If product is heated above decomposition temperature, toxic vapours will be released. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental release measures

Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. Cleanup: Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.


Handling

General advice: Avoid contact with the skin, eyes and clothing. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage

General advice: Keep away from heat. Protect against moisture. Protect from direct sunlight. Storage incompatibility: General advice: Segregate from foods and animal feeds. Temperature tolerance Changes in the properties of the product may occur if substance/product is stored below indicated temperature for extended periods of time. Protect from temperatures above: 40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

8. Exposure Controls and Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.



Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) TC23C Chemical/Mechanical type filter system to remove a combination of particles, gas and vapours. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Suitable materials, rubber, plastic Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Avoid inhalation of dust. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.


Form: granules Odour: sulfur-like, mild Odour threshold: No data available. Colour: dark brown pH value: 5.8

approx. 4 - 6 ( 1 %(m), 20 °C)

Melting point: approx. 99 °C The data given are those of the active ingredient.

Density: approx. 1.30 g/cm3 ( 20 °C) (OECD Guideline 109) Vapour density: not determined

Partitioning coefficient n-octanol/water (log Pow):

not applicable

Viscosity, dynamic: not applicable

Solubility in water: dispersible

Molar mass: 313.8 g/mol


Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded. Substances to avoid: strong oxidizing agents, strong bases, strong acids


Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: 150 °C, 2 K/min (DSC (DIN 51007)) Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen monoxide, nitrogen dioxide, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. 210 °C, 2 K/min (DSC (DIN 51007)) Oxidizing properties: not fire-propagating (Directive 92/69/EEC, A.17)

11. Toxicological information

Acute toxicity Oral: Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg (Directive 84/449/EEC, B.1) No mortality was observed. Inhalation: Type of value: LC50 Species: rat Value: > 5.7 mg/l (OECD Guideline 403) Exposure time: 4 h Tested as dust aerosol. No mortality was observed. Dermal: Type of value: LD50 Species: rat (male/female) Value: > 2,000 mg/kg (OECD Guideline 402) No mortality was observed. Irritation / corrosion Skin: Species: rabbit Result: non-irritant Method: Directive 84/449/EEC, B.4 Eye: Species: rabbit Result: non-irritant Method: Directive 84/449/EEC, B.5 Sensitization: Buehler test Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies. Method: Directive 84/449/EEC, B.6


Genetic toxicity Information on: Kresoxim-methyl No mutagenic effect was found in various tests with microorganisms and mammals. ---------------------------------- Carcinogenicity Information on: Kresoxim-methyl Very high concentrations in the range of the maximum tolerated dose (MTD) have caused liver tumors in rats after chronic exposure. These concentrations will not be achieved under practical conditions. Indication of possible carcinogenic effect in animal tests. ---------------------------------- Reproductive toxicity Information on: Kresoxim-methyl The results of animal studies gave no indication of a fertility impairing effect. ---------------------------------- Development: Information on: Kresoxim-methyl No indications of a developmental toxic / teratogenic effect were seen in animal studies. ---------------------------------- Other Information: Misuse can be harmful to health.

12. Ecological Information Fish Acute: Directive 84/449/EEC, C.1 static Oncorhynchus mykiss/LC50 (96 h): approx. 0.5 mg/l Aquatic invertebrates Acute: Directive 79/831/EEC static Daphnia magna/EC50 (48 h): 0.31 mg/l Aquatic plants Toxicity to aquatic plants: OECD Guideline 201 green algae/EC50 (72 h): 0.532 mg/l Other adverse effects: Do not discharge product into the environment without control.

13. Disposal considerations

Waste disposal of substance: See product label for disposal and recycling instructions.



Land transport TDG

Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

(contains KRESOXIM-METHYL 50%)

Sea transport IMDG

Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.


Air transport IATA/ICAO

Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.



Federal Regulations Registration status: Chemical DSL, CA released; restriction on quantity / not listed Crop Protection DSL, CA released / exempt WHMIS does not apply to this product. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.


Recommended use: fungicide We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible


Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

MSDS Prepared by:

BASF NA Product Regulations

[email protected] BASF HOTLINE (800) 454 – COPE (2673) MSDS Prepared on: 2012/06/12 END OF DATA SHEET

SAFETY DATA SHEET

Revision Date 10-Feb-2015 Revision Number 1

1. Ident ificat ion

Product Name Phthalide

Cat No. : AC131090000; AC131090050; AC131091000; AC131095000

Synonyms 1-Phthalanone; Phthalolactone.

Recommended Use Laboratory chemicals.

Uses advised against No Information available

Details of the supplier of the safety data sheet

2. Hazard(s) ident ificat ionClassification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Label Elements

Signal WordWarning

Hazard StatementsCauses serious eye irritation

Precautionary Statements

PreventionWash face, hands and any exposed skin thoroughly after handlingWear eye/face protection

EyesIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

CompanyFisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100

Entity / Business NameAcros OrganicsOne Reagent LaneFair Lawn, NJ 07410

Emergency Telephone NumberFor information US call: 001-800-ACROS-01

/ Europe call: +32 14 57 52 11

Emergency Number US:001-201-796-7100 /

Europe: +32 14 57 52 99

CHEMTREC Tel. No.US:001-800-424-9300 /

Europe:001-703-527-3887

______________________________________________________________________________________________

Serious Eye Damage/Eye Irritation Category 2

Page 1 / 6

______________________________________________________________________________________________Phthalide Revision Date 10-Feb-2015

If eye irritation persists: Get medical advice/attention

Hazards not otherwise classified (HNOC) None identified

3. Composit ion / information on ingredients

Component CAS-No Weight %

1(3H)-Isobenzofuranone 87-41-2 99

4. First -a id measures

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Obtain medical attention.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Obtain medical attention.

Inhalation Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. Ifnot breathing, give artificial respiration. Obtain medical attention.

Ingestion Clean mouth with water. Get medical attention.

Most important symptoms/effects No information available.

Notes to Physician Treat symptomatically

5. Fire-fight ing measuresSuitable Extinguishing Media Water spray. Carbon dioxide (CO 2). Dry chemical. chemical foam.

Unsuitable Extinguishing Media No information available

Flash Point 152 °C / 305.6 °F

Method - No information available

Autoignition Temperature No information available

Explosion Limits

Upper No data available

Lower No data available

Sensitivity to Mechanical Impact No information available

Sensitivity to Static Discharge No information available

Specific Hazards Arising from the ChemicalKeep product and empty container away from heat and sources of ignition.

Hazardous Combustion ProductsCarbon monoxide (CO) Carbon dioxide (CO2)

Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.

NFPA

6. Accidental re lease measuresPersonal Precautions

______________________________________________________________________________________________

Ensure adequate ventilation. Use personal protective equipment.

Environmental Precautions See Section 12 for additional ecological information.

Page 2 / 6

Health2

Flammability0

Instability0

Physical hazardsN/A


Methods for Containment and CleanUp

Sweep up or vacuum up spillage and collect in suitable container for disposal. Do not letthis chemical enter the environment.

7. Handling and storageHandling Avoid contact with skin and eyes. Do not breathe dust. Do not breathe vapors or spray mist.

Do not ingest.

Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

8. Exposure controls / personal protect ionExposure Guidelines This product does not contain any hazardous materials with occupational exposure limits

established by the region specific regulatory bodies.

9. Physical and chemical propert iesPhysical State Powder Solid

Appearance Beige

Odor Odorless

Odor Threshold No information available

pH No information available

Melting Point/Range 70 - 73 °C / 158 - 163.4 °F

Boiling Point/Range 290 °C / 554 °F @ 760 mmHg

Flash Point 152 °C / 305.6 °F

Evaporation Rate No information available

Flammability (solid,gas) No information available

Flammability or explosive limitsUpper No data available

Lower No data available

Vapor Pressure No information available

Vapor Density No information available

Relative Density No information available

Solubility No information available

Partition coefficient; n-octanol/water No data available

Autoignition Temperature No information available

Decomposition Temperature No information available

Viscosity No information available

Molecular Formula C8 H6 O2

Molecular Weight 134.13

10. Stability and react ivity

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stationsand safety showers are close to the workstation location.

Personal Protective Equipment

Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described byOSHA's eye and face protection regulations in 29 CFR 1910.133 or European StandardEN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

______________________________________________________________________________________________

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European StandardEN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator ifexposure limits are exceeded or if irritation or other symptoms are experienced.

Page 3 / 6

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.


Reactive Hazard None known, based on information available

Stability Stable under normal conditions.

Conditions to Avoid Incompatible products.

Incompatible Materials Strong oxidizing agents

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological informationAcute Toxicity

Product Information No acute toxicity information is available for this product

Component InformationToxicologically SynergisticProducts

No information available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation No information available

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS-No IARC NTP ACGIH OSHA Mexico

1(3H)-Isobenzofuranone

87-41-2 Not listed Not listed Not listed Not listed Not listed

Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT - single exposure None known

STOT - repeated exposure None known

Aspiration hazard No information available

Symptoms / effects,both acute anddelayed


Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated. See actual entry in RTECS forcomplete information.

12. Ecological informationEcotoxicity

______________________________________________________________________________________________

Do not empty into drains.

Persistence and Degradability

Page 4 / 6


Bioaccumulation/ Accumulation No information available.


Mobility No information available.

13. Disposal considerat ionsWaste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a

hazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classification.

14. Transport informationDOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG/IMO Not regulated

15. Regulatory information

International Inventories

Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL

1(3H)-Isobenzofuranone X X - 201-744-0 417-930-1

X X X X X

Legend:X - ListedE - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designatedpolymer made with any free-radical initiator regardless of the amount used.P - Indicates a commenced PMN substanceR - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.S - Indicates a substance that is identified in a proposed or final Significant New Use RuleT - Indicates a substance that is the subject of a Section 4 test rule under TSCA.XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data BaseProduction and Site Reports (40 CFR 710(B).Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactantsthat comprises one of the eligibility criteria for the exemption rule.

U.S. Federal Regulations

TSCA 12(b) Not applicable

SARA 313 Not applicable

SARA 311/312 Hazardous CategorizationAcute Health Hazard Yes

Chronic Health Hazard No

Fire Hazard No

Sudden Release of Pressure Hazard No

Reactive Hazard No

Clean Water Act Not applicable

Clean Air Act Not applicable

______________________________________________________________________________________________

OSHA Occupational Safety and Health AdministrationNot applicable

CERCLANot applicable

Page 5 / 6

California Proposition 65 This product does not contain any Proposition 65 chemicals


State Right-to-Know Not applicable

U.S. Department of Transportation

Reportable Quantity (RQ): NDOT Marine Pollutant NDOT Severe Marine Pollutant N

U.S. Department of Homeland SecurityThis product does not contain any DHS chemicals.

Other International Regulations

Mexico - Grade No information available

CanadaThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) andthe MSDS contains all the information required by the CPR

WHMIS Hazard Class D2B Toxic materials

16. Other informationPrepared By Regulatory Affairs

Thermo Fisher ScientificEmail: [email protected]

Revision Date 10-Feb-2015

______________________________________________________________________________________________

Print Date 10-Feb-2015

Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standardreplacing the current legislation under 29 CFR 1910.1200 to align with the GloballyHarmonized System of Classification and Labeling of Chemicals (GHS)

Page 6 / 6

DisclaimerThe information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the text.

End of SDS

CAT# 23006

Date Updated: Oct. 19, 2012

MATERIAL SAFETY DATA SHEET

www.capotchem.com [email protected]


1.1 Product identifiers

Product name : Pyriproxyfen

Product Number : 23006

CASNo. : 95737681




Company : Capot Chemical Co.,Ltd.

Joinhands Science Park, No.4028 Nanhuan Road

Hangzhou, Zhejiang, China 310053

Telephone : 008657185586718

Fax : 008657185864795

Email address : [email protected]


Emergency Phone # : 008657185586718



Classification according to Regulation (EC) No 1272/2008

Hazardous to the aquatic environment, longterm hazard (Category 1), H410

For the full text of the HStatements mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

not available

For the full text of the Rphrases mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram GHS09

Signal word Warning

Hazard statement(s)

H410 Very toxic to aquatic life with long lasting effects

Precautionary statement(s)

http://www.capotchem.com

http://www.capotchem.com/95737-68-1.html

Supplemental Hazard Statements None

2.3 Other hazards

None


3.1 Substances

Synonyms : 2(1Methyl2(4phenoxyphenoxy)ethoxy)pyridine;Pyroproxifen

Formula : C20H19NO3

Molecular Weight : C20H19NO3 g/mol

CASNo. : 95737681

ECNo. : not available

Hazardous ingredients according to Regulation (EC) No 1272/2008


Pyriproxyfen

CASNo. 95737681

ECNo. not availableH410 <= 100 %

Hazardous ingredients according to Directive 1999/45/EC


Pyriproxyfen

CASNo. 95737681

ECNo. not availablenot available <= 100 %

For the full text of the HStatements and RPhrases mentioned in this Section, see Section 16



General adviceConsult a physician. Show this safety data sheet to the doctor in attendanc.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

no data available


5.1 Extinguishing mediaSuitable extinguishing mediaUse water spray, alcoholresistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

carbon dioxide,nitrogen oxides (NOx),Hydrogen chloride gas

5.3 Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

no data available


6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.


7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and wellventilated place.

Store under inert gas. Hygroscopic.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated



Components with workplace control parameters


Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.Personal protective equipment

Eye/face protectionSafety glasses with sideshields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.Body Protection

impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.Respiratory protection

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEKP2 (EU EN 143) respirator cartridges.

Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).Control of environmental exposureDo not let product enter drains.



Appearance White to offwhite crystal powder

pH Not available

Melting point 4547ºC

Boiling point Not available

Autoignition Temperature Not available

Flash Point Not available

Explosion Limits: Lower Not available

Explosion Limits: Upper Not available

Decomposition Temperature Not available

Solubility in water Not available

Specific Gravity/Density 1.32

9.2 Other safety information

no data available


10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

Avoid moisture.

10.5 Incompatible materials

acids, Acid chlorides, Acid anhydrides, Oxidizing agents

10.6 Hazardous decomposition products

Other decomposition products no data available

In the event of fire: see section 5



Acute toxicityno data availableSkin corrosion/irritationno data availableSerious eye damage/eye irritationno data availableRespiratory or skin sensitisationProlonged or repeated exposure may cause allergic reactions in certain sensitive individuals. The preceding data, or interpretation of data, was determined using Quantitative Structure Activity Relationship (QSAR) modeling.Germ cell mutagenicityno data availableCarcinogenicity

IARC : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.Reproductive toxicityno data availableSpecific target organ toxicity - single exposureInhalation May cause respiratory irritation.Specific target organ toxicity - repeated exposureno data availableAspiration hazardno data availableAdditional InformationRTECS: Not availableTo the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


12.1 Toxicity

no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

no data available



ProductBurn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in

igniting as this material is highly flammable. Offer surplus and nonrecyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.Contaminated packagingDispose of as unused product.


DOT (US) UN3077 9/PG 3IMDGUN3077 9/PG 3IATAUN3077 9/PG 3


This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out



H410 Very toxic to aquatic life with long lasting effects

Full text of R-phrases referred to under sections 2 and 3.

Further information

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Capot Chemical Co., Ltd. shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

Copyright © 20122016 Capot Chemical Co., Ltd. License granted to make unlimited paper copies for internal use only. If you have any comments and suggestions, please contact us by [email protected].

Pyriproxyfen SAFETY DATA SHEET

CAPOT CHEMICAL COMPANY LIMITED

Joinhands Science Park, No.4028 Nanhuan Road, Hangzhou, Zhejiang, P.R.China, 310053

Tel:+8657185586718 Fax:+8657185864795 [email protected] www.capotchem.com

Copyright © 2012-2017 Capot Chemical Co., Ltd.

1

Thiram -MATERIAL SAFETY DATA SHEET



Trade name: Thiram 80% WP 1. Chemical Product Identification

Product Name: Thiram

Molecular Formula: C6H12N2S4


Structural Formula:

Chemical Name:

tetramethylthiuram disulfide (IUPAC);

Form: crystals

Color: colourless

Odor: odorless

CAS No.: 137-26-8



Thiram 137-26-8 80.0



2

Component Symbol R phrases

Thiram Xn;Xi; R 68-20/22-36/37-43

More important danger for the man: None

Dangers for the environment: Thiram is highly toxic to fish. Thiram is not expected to bioconcentrate in aquatic organisms.

Physical-chemical dangers: none


Skin: Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.

Eyes: First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.

Inhalation: Move affect person to fresh air and keep at rest until recovered. If not breathing, give artificial respiration and get to a doctor.

Ingestion: Do not induce vomiting if the person is conscious. Give glass of water. Get to a doctor.

Notes to physician: No specific antidote if ingested. Treat symptomatically.


Extinguishing media

To be used: Powder, foam, and sand.

Don’t use: Not applicable

Particular risk: None

Measures of personal protection: Safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants.

Environmental cautions

EX: Prevent the contamination of the floor and the beds of water.

6. Accidental Release Measures Personal cautions: Safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants. Cleaning methods EX: The empty container may be decontaminated by rinsing two or three times with water and detergent and scrubbing the sides. Environmental cautions EX: prevent the contamination of the floor and beds of water.

3


Handling: Do not apply to humans, their clothing, or bedding. Do not contaminate food or use on household tanks.

Storage: Store at normal temperatures, away from children, domestic animals, food and feed products, seed and fertilizer. Do not contaminate other stored products or the storage area by handling or storage of this product. Keep in a well-ventilated room.

8. Exposure Controls / Personal Protection Personal protective equipment Respiratory protection: Approved respirator

Protective gloves: Rubber gloves

Eye protection: Safety goggles or face shield.

Industrial hygiene: adequate ventilation.

9. Physical And Chemical Properties

Melting point: none;.

Density: 0.55

Water solubility: 18mg/L (room temperature)

Other solubility: In ethanol <10, acetone 80, chloroform 230(all in g/l, room temperature); In hexane 0.04, dichloromethane 170, toluene 18, isopropanol 0.7 (all in g/l, 20℃).

Ph value: 5.0-8.0;

Flash point: non-inflammable;

Ignition temperature: not applicable

10. Stability And Reactivity

Conditions to avoid: none

Products to avoid: acidic media.

Thermal decomposition: none

Hazardous decomposition products: none.

Hazardous reaction: Not applicable


Contact with the skin: slight irritant to skin

Contact with the eyes: moderate irritant to eye.

4

Inhalation: itching, scratchy throat, hoarseness, sneezing, coughing, inflammation of the nose or throat, bronchitis, dizzines, headache, fatigue, nausea, diarrhea, and other gastrointestinal complaints.

Ingestion: Ingestion of thiram and alcohol together may cause stomach pains, nausea, vomiting, headache, slight fever, and possible dermatitis..

Effects for chronic toxicity:

Reproductive: : Very high oral doses of approximately 1200 mg/kg/day thiram to mice on days 6 to 17 of pregnancy caused resorption of embryos and retarded fetal development. In another study, doses of 132 mg/kg/day for 13 weeks produced infertility in male mice, while doses of 96 mg/kg/day for 14 days delayed the estrous cycle in females. The feeding of 50 mg/kg/day thiram from day 16 of pregnancy to 21 days after birth caused reduced growth and survival of the pups. Pups that were transferred to untreated dams at birth remained healthy, while pups transferred from untreated to treated dams showed toxic effects. These data suggest that reproductive effects occur at high doses not likely to be experienced by humans.

Carcinogenicity: When administered to mice at the highest dose possible, thiram was not carcinogenic. Dietary levels as high as 125 mg/kg/day for 2 years did not cause tumors in rats. These data indicate that thiram is not carcinogenic.

Teratogenicity: Maternal doses of 125 mg/kg/day thiram were teratogenic in hamsters, causing incomplete formation of the skull and spine, fused ribs, abnormalities of the legs, heart, great vessels, and kidneys. Developmental toxicity was observed in a three-generation study of rats fed 5.0 mg/kg/day. These data suggest that high doses are required to cause teratatogenic effects.

Mutagenicity: Thiram has been found to be mutagenic in some test organisms but not in others. Thus, the evidence is inconclusive.

Sensisation: skin sensitiser (guinea pigs);


Aquatic organisms:

LC50 (96 h) for bluegill sunfish 0.0445, rainbow trout 0.128 mg/l. Daphnia LC50 (48 h) 0.21 mg/l, Algae EC50 (72 h) 0.065 mg/l.

Bird: Acute oral LD50 for male ring-necked pheasants 673, mallard ducks >2800, starlings >100, redwing blackbirds >100mg/kg. LC50 (8 d) for ring-necked pheasants >5000, mallard ducks >5000, bobwhite quail >3950, Japaneses quail >5000 ppm.

Other Animals (Non-target species)

Bee: Thiram is nontoxic to bees.

13. Disposal Considerations Material which can not be used at the site should be disposed of in an approved waste

disposal facility following all applicable Federal, State and Local regulations. If burned, stay out of smoke. Do not contaminate water supplies by disposal of wastes or containers.

5


Not applicable.


Not applicable.



p. 1

1

2 0

He a lt h

Fire

Re a c t iv it y

Pe rs o n a lPro t e c t io n

2

1

0

E

Material Safety Data SheetZinc Diethyldithiocarbamate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Zinc Diethyldithiocarbamate

Catalog Codes: SLZ1093

CAS#: 136947

RTECS: ZH0350000

TSCA: TSCA 8(b) inventory: Zinc Diethyldithiocarbamate

CI#: Not available.

Synonym: Diethyldithiocarbamic acid zinc salt

Chemical Name: Zinc Diethyldithiocarbamate

Chemical Formula: C10H22N2S4.Zn

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:18004249300

International CHEMTREC, call: 17035273887

For non-emergency assistance, call: 12814414400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Zinc Diethyldithiocarbamate 136947 100

Toxicological Data on Ingredients: Zinc Diethyldithiocarbamate: ORAL (LD50): Acute: 700 mg/kg [Rat]. 1400 mg/kg[Mouse]. 400 mg/kg [Rabbit].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: ClassifiedNone. for human. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to blood, lungs. Repeated orprolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact:After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with runningwater and nonabrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with anemollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

http://www.sciencelab.com/

p. 2

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an antibacterial cream. Seek immediate medicalattention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation: Not available.

Ingestion:Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication thatthe toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,tie, belt or waistband. If the victim is not breathing, perform mouthtomouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: CLOSED CUP: 204.6°C (400.3°F).

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2,SO3...).

Fire Hazards in Presence of Various Substances: Not available.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.

Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.

Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under afume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing Incase of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents, acids, alkalis.

Storage:

p. 3

Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in acool, wellventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizingagents.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.

Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Solid powder.)

Odor: Not available.

Taste: Not available.

Molecular Weight: Not available.

Color: Offwhite.

pH (1% soln/water): Not applicable.

Boiling Point: Not available.

Melting Point: 174°C (345.2°F)

Critical Temperature: Not available.

Specific Gravity: 1.47 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: Is not dispersed in cold water, hot water.

Solubility: Insoluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

p. 4

Conditions of Instability: Not available.

Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.

Corrosivity: Not available.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 400 mg/kg [Rabbit].

Chronic Effects on Humans:TERATOGENIC EFFECTS: Classified None. for human. The substance is toxic to blood, lungs.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Zinc Diethyldithiocarbamate

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

p. 5

Other Classifications:

WHMIS (Canada):CLASS D1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D2A: Material causing other toxic effects(VERY TOXIC).

DSCL (EEC):R36/38 Irritating to eyes and skin. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 12:19 AM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we

make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for

their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for

lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com

has been advised of the possibility of such damages.

1

Zineb -MATERIAL SAFETY DATA SHEET




Product Name: Zineb

Molecular Formula: C4H6N2S4Zn


Structural Formula:

Chemical Name: [[2-[(dithiocarboxy) amino] ethyl] carbamodithioato]] (2- )-kS,kS′]zinc

Form: Solid

Color: slight yellow

Odor: N/A

CAS No.: 12122-67-7 2. Composition / Information on Ingredients


Zineb 12122-67-7 85.0



Effects of Overexposure:

2

Eyes: Irritation and inflammation. Skin: Irritation and inflammation. Ingestion: N/K (FPN/ORNL). Inhalation: Irritation and inflammation of nose and throat.


Swallowed: If poisoning occurs, contact a doctor or Poisons Information Centre. Avoid giving alcohol.

Eyes: If in eyes, hold eyelids open, flood with water for at least 15 minutes and see a doctor.

Skin: If skin contact occurs remove contaminated clothing and wash skin thoroughly.

Inhaled: Remove from contaminated area. Apply artificial respiration if not breathing. 5. Fire-Fighting Measures

Dust clouds may become explosive in the presence of an ignition source. Toxic fumes may be emitted if involved in a fire. Decomposition products may include carbon disulphide. Fire personnel should wear appropriate self contained breathing apparatus. All other personnel should remain upwind.


Spills and disposal: Spillage should preferably be vacuumed to avoid generation of dust. Place in sealed containers and dispose of at a land fill site approved by the relevant authorities.


Store in a cool dry place away from direct sunlight. Product has a shelf life of approximately 2 years and loss of efficacy may occur after this time.


Engineering Controls: In an enclosed environment, mechanical dust extraction may be necessary to ensure above exposure standards are met.

Personal Protection: Do not breath dust or spray. Appropriate agricultural respirator should be worn if necessary. Avoid contact with eyes and skin. Wear cotton overalls buttoned to the neck and wrist and washable hat, elbow length PVC gloves and face shield or goggles.


Water Solubility: 10 mg/L @ 25℃

Solubility in Other Solvents: s. in carbon disulfide; s.s. in pyridine; practically i.s. in common organic solvents

Melting Point: Thermal decomposition @ 157℃

Vapor Pressure: <0.01 mPa @ 20℃

Partition Coefficient: <1.3010 at 20℃

3

Adsorption Coefficient: 1000 (estimated) 10. Stability and Reactivity Conditions to avoid: Keep dry and avoid excessive heat and ignition sources. Toxic and

flammable gases are evolved when material is heated above 176℉


Acute:

Swallowed: Low oral toxicity. May irritate throat.

Eyes: May irritate eyes.

Skin: May irritate skin.

Inhaled: May irritate nose and throat.

Reproductive effects: It is advisable that pregnant women avoid exposure to zineb, as it can damage the fetus, as well as cause adverse reproductive system effects. A single intraperitoneal injection of approximately 160 mg/kg of zineb in mice, during the second half of pregnancy, resulted in abortions and weak offspring. Oral doses of zineb, at a rate of 100 mg/kg/day for 2 months or more, produced sterility, resorption of fetuses, and abnormal tails in offspring. After oral ingestion of zineb, similar concentrations of ETU, a metabolite of this pesticide, were found in both maternal and fetal tissues of rats.

Teratogenic effects: Offspring of rats given a near lethal oral dose of 2000 mg/kg/day of zineb on days 11 or 13 of pregnancy, showed a high incidence of skeletal malformations, as well as defects in the closing of the neural tube, an embryonic tube that eventually develops into the brain and spinal cord. A very high single oral dose of 8000 mg/kg to rats on day 11 of gestation produced numerous deformities in the offspring. Teratogenic effects were also seen when pregnant mice were given intraperitoneal injections of 150 mg/kg. In pregnant rats fed 5.0 mg/kg/day, the lowest dose tested, developmental toxicity was observed in the form of delayed hardening of the skull bones in offspring. Zineb's metabolite, ethylene thiourea (ETU), may cause abnormal fetal development. It has been shown to be teratogenic in hamsters, but not in mice.

Mutagenic effects: Results of mutagenicity assays of zineb and its metabolite, ETU, are inconclusive. The data suggest that zineb may be a weak mutagen.

Carcinogenic effects: Available data clearly show that low doses of zineb are not carcinogenic. Very high doses have caused tumors in some test animals. In two strains of mice, the maximum tolerated lifetime dose of zineb did not cause tumors. Oral doses of 3500 mg/kg/week for 6 weeks caused one of two mice strains tested to develop benign lung tumors after 3 weeks. Two rat feeding studies showed no evidence of tumor formation. Overall, evidence of carcinogenicity in chronic oral feeding studies in rats and mice is inconclusive, although they suggest it is not likely to be carcinogenic in humans.

4

Organ toxicity: Zineb appears to be harmful to the thyroid, liver and muscles. Liver and kidney injury was observed in autopsies done on sheep that died after a 3-week exposure to oral doses of 500 mg/kg/day zineb. Studies of the effects of zineb on test animals have shown rapid reduction in the uptake of iodine and swelling of the thyroid (i.e., goiter).

12. Ecological and Ecotoxicological Information

Effects on birds: Zineb is practically nontoxic to birds. The oral LD50 for zineb in mallards and young pheasants is greater than 2000 mg/kg.

Effects on aquatic organisms: Zineb is moderately toxic to fish. The 96-hour LC50 in perch is 2 mg/L.

Effects on other organisms: Zineb is not toxic to bees . Little or no reduction in the numbers of beneficial predatory and parasitic arthropods was seen when zineb was used in Nova Scotian orchards at recommended dosages. Mites appear to be sensitive to zineb.


Waste Disposal Methods: Disposal must be in accordance with local regulation. 14. Transport Information

Not applicable.


Not applicable.



1

ziram -MATERIAL SAFETY DATA SHEET




Product Name: ziram

Molecular Formula: C6H12N2S4Zn


Structural Formula:

Chemical Name: dimethylaminomethanedithioate; zinc(+2) cation

Form: Power

Colour: white

Odour: odorless

CAS No.: 137-30-4



ziram 137-30-4 90.0



Known Hazards: IRRITANT

2


If swallowed: Rinse mouth. Refer for medical attention.

If in inhalation: Fresh air rest. Refer for medical attention.

If on skin: Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.

If in eyes: First rinse with plenty of water for several minutes (remove contact lenses if easily possible) then take to a doctor.


Extinguishing Media: Carbon dioxide, dry chemical powder, foam, water.

Special Fire Fighting Equipment: Wear a self-contained breathing apparatus and protective clothing.


Personal Precautions: Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.

Spill Clean-up Methods: Provide adequate ventilation. Carefully absorb on vermiculite and transfer to a closed container.


Handing: Use only in a well-ventilated area. Minimize dust generation and accumulation.

Storage: Keep away from food, feed and drinking water. Store in a well-ventilated, dry place away from heat and moisture.

8. Exposure Controls / Personal Protection

Respiratory Protection: Self-contained breathing apparatus or chemical cartridge.

Hand Protection: Chemical-resistant gloves, solvent-resistant gloves.

Eye Protection: Wear safety goggles.

Other Protective Equipment: Protective clothing.

Other Protective Measures: Provide safety showers and eyewash station near workplace.

9. Physical And Chemical Properties

Melting point: 246 ℃

Specific gravity: 1.66 @25℃

Vapor pressure : <1

3

Solubility : in water 0.03mg/L@20℃

In organic solvent : Soluble in chloroform, carbon disulfide, dilute alkali, moderately soluble in acetone,insoluble in ethanol and aether

10. Stability And Reactivity

Chemical stability: Stable

Incompatible with iron, copper, strong oxidizing agents, acids, mercury

Conditions to avoid: Avoid exposure to excessive heat

Hazardous polymerization: Products will not undergo polymerization.


Acute Toxicity:

Oral LD50 (rat): 1400 mg/kg

Dermal LD50 (rat): >6000mg/kg

Inhalation LC50 (rat): not applicable

Skin irritation (rabbit): Moderate

Eye irritation (rabbit): Moderate

Reproductive effects: When female and male rats were given moderate doses of ziram (50 mg/kg/day) for nearly 2 months prior to pregnancy, the rats had marked reductions in fertility and litter size. The rats in this study became largely sterile. A lower dose of 10 mg/kg had no effect on reproduction. Female mice fed moderate doses (50 mg/kg/day) of ziram for 15 days exhibited reduced fertility but no effects on fertility appeared in male mice. Wasting away of the testes has been noted as a toxic effect of ziram. Based on these data, reproductive effects in humans are unlikely at normal levels of exposure.

Teratogenic effects: Pregnant rats administered ziram at doses of 12.5 to 100 mg/kg/day during the organ forming period of pregnancy showed embryotoxic effects at doses of 25 mg/kg/day and greater. The compound also had a slight growth inhibiting effect on the embryos at 100 mg/kg. Maternal toxicity was observed at all test levels. No teratogenic effects were observed.

Mutagenic effects: Numerous tests have established that ziram is mutagenic. For example, there was an increase in the number of chromosome changes in bone marrow cells in mice treated with oral doses of 100 mg/kg/day. Chromosomal changes have also been observed in workers exposed to the compound in industrial settings for 3 to 5 years. The concentration in the air averaged 1.95 mg/L but reached as high as 71.3 mg/L in some of these cases. Thus, there is a risk to humans chronically exposed to ziram at moderate to high concentrations.

4

Carcinogenic effects: A carcinogenicity study was performed on rats and mice exposed to ziram for a 103-week period. Under the conditions of the study, ziram was carcinogenic to male rats, causing an increase in thyroid cancer. There was no increase in carcinogenicity in female rats or in male mice. Female mice showed an increase in lung tumors, but this was complicated by a virus infection making interpretation difficult. Ziram's carcinogenicity is not determinable from current evidence.

Organ toxicity: The primary target organ is the thyroid, as shown in a study of workers who experienced thyroid enlargement after ziram exposure.


Effects on birds: Toxicity of ziram to birds will vary from essentially non-toxic to moderately toxic. Its LD50 is 100 mg/kg in European starlings and red-wing blackbirds. In a 2-year study, the dietary LC50 in quail was 3346 ppm. In chickens, doses of 56 mg/kg were toxic. Ziram has an antifertility action in laying hens. When given to chickens under unspecified conditions, there were adverse effects on body weight and retarded testicular development.

Effects on aquatic organisms: Based on data from only one species, the goldfish, the compound appears to be moderately toxic to fish. The 5-hour LC50 for ziram in goldfish was between 5 and 10 mg/L. Based on its low solubility in water, ziram should have a low bioconcentration potential. Effects on other organisms: No data are currently available.


Dispose of according to the local regulations.


Not applicable.


Not applicable.


All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this

5

product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.

Annexure VI: Public Hearing

" ｾｯ＠ｾ c6ftiCf>H1 ｬｊｔＨＩｾｏＬ＠ｾＧｾｏ＠ＢＴＩｾＱＵＯ＠ｾ＠ ift22, ｾＭＲＬ＠ trn"o:tlo\ftt"ll, ｜ｩｆｦｔｊｇＭｾ＠ｾ＠｣ｴｾＧｫＢＧＱｉＺｴｉｃｦＩＱI ( , !

, q} \iNIG'1i tg ｾ qfr ｾｬｱＧＱＧｩ＠ fctr4 ｜ｩｬｩａｾ＠ｱｾｦｱＧＨｵｦｉＺｱ＠ｾｃｦｬｾ＠ m ｾ q} ｾ \l0"Sl0 ｾ＠

ｐｉｾＢ＿ｉ､ｬ＠ｾ em ｾ 'SRffiCf q} ｾＬＱｬ＠ｾｾｦｱｫｵｬＬ＠ q.:r ｾ＠｜ｩｪｴＢｬｱｬｧｱｾｱｴｦ､ＧＱ＠Ｔ＿ＱｬｴＢＱｾＬ＠ 1ffi(f tI '(Cf> 1'<, '1l flni<;ft ;;m "GIRt ＢｾＢｉＮＢｾｉ＠ｾＱＴｦｦｬ､Ｑ［Ｎｾｴ＠ <f; ｡ｲｪＧｬｬ｡ｾ＠ if ｾＬＬＧｾＬ｜ＬｉＴｬ＠ｾＮｾ ;;m 'I1fi'rn 3TtR fuR;rr ｊｦｒｩＱｾ･Ｌ＠ｾ qfr 31l:4lftdl 1l : 30.12.2017 em ｾ q} ｾ｜ｦｦｩｬｾ､＠ｾｾ ;f0 "4)15

ｾ＠ ift22, ｾＭＲＬ＠ trn"tr'("fut'lt"Il, ｜ｩｆｦｔｊｇＭｾ＠ 'Q'<' ｾｾｾ n'1ql( 'Cf)T <f)142ct11

I lfO ｾｾｾ｣ｰｃＢｦｦ＠ wofuo &m ｾ ;:f0 ｾＭＱＵ＠ｾ＠ｾＭＲＲＬ＠ $;,2, %0 tlut1C"1I, ｾＭｾ＠qx ｣ＣｬｃＺＢＱｉｾｉｃｦＩＧｪ＠ｾ＠ \3t<lIG"1 ｾ \3EWr c#t ｾｾｾｾ＠ qllfq,<u?\ll ｾｱｺｾ＠ Wt{f ｾ c5 fR1:; "\3mm

• ｾ Pill '"?I 01 mi ｾ＠ "W1'a1, >ffiITCf >RWf fcpm lfm ｾ＠ I \3Cftf ｾ &m ｾ >ffiITCf cf; ｾｾ＠

qllfq,<OI, q.:r ｾ＠ \J1C"1C1lg qRClct"l 4?1 1<"1 <1, 11ffii ｾＬｾｾ Gm ｾＬ＠ｾＮ＠ x:T0 "([ff03lT0 1533

ｾ 14 ｦｦｉＨｪｾＧ＼Ｌ＠ 2006 1l ｾＧｭｦ｣ｬｭＧＱｔ＠ｾＢＢ､ｭｬ＠ＢＧ＼Ｂｦｬ｣ｰｾ＠ｾｾＬ＠ｾ IDXT ｾ＠

3m" ｾＴｩｦｇＱｾ･Ｌ＠ｾｾ＠ｾ｡ｦＨＱｔ＠ｾ＠ \JWT ｾ＠ JNfllFcld ｾ l:ffiC rio ｾＭＱＵ＠ｾ＠ｾＭＲＲＬ＠ $n-2,

ｾｯ＠ tl 0s"1<"I I, ｾＭｾ qx ｾ 30.12.2017 em ID(f: ＱＲＮＮＰＰａｾ＠ s<fr I ｾｾ c#t cpl4ql51

ｾｾ｣Ｃｴｾｾｾ｣ＣｴｾＱ＠

1. ｸ］ｲｭｲｾ＠ tlt:llICf> ｾ $1IPiCf> ｾＬ \j0 >f0 ｾ PllI'"?IUI mi Gm fficn ｾ qx ｾｾ＠

ｾｾ＠ｾ CfRT<n lfm fclJ .4l1fCl,!UI, q.:r ｾ＠ \J1<"1C1lg qRqct"l s:i?l 1(>1 <1, ｾ＠ｾ &NT vrRl ｾｾｾＰＳｬｔＰ＠ 1533 ｾ 14 ｦｦｉＨｪｾＬＡＢ＠ 2006 ｾ＠ｾ｣ｂＩｃＢｬｉｾｉｃｦＩＧｪ＠ 'Cf>T \3t<lIG"I 17m)

u:rR ｾｾ '<"flcp ｾ >rf$m cf; 3Rf7nl ＳｬｉｩｕｬｾＨｪ＠ t I '

2. 4l1fCl,!01, q.:r ｾ＠ \i1(>1C1lg qRClct"l 4?1.1 (>1 <1, ｾｾＬ＠ｾ＠ｾ Gm ｾｾｾ＠

"([ffo31TO 1533 ｾ 14 ffI(jRN, 2006 ｾ＠ｾ Wco ｾ cf; ｾｾＬ＠ｾ \j0 >f0 ｾ＠

PllIr:lIUI mi Gm ｾ 29.11.17 ｾ＠ｾ 30.11.2017 "Cf>T ｾ "fflifCR tr3lT ｾＺ＠ｾ＠\i1l l l,<ul ｾ＠ｦＶｾｦｦｩｬＢｬ＠ｾ＠ＡＧｉ｣ｰｬｾｬＨｪ＠ qft TJ<fT ｾ＠Ｂ､Ｂｾ＠Ｓｬｔ｡ＩＭｱＯｾＯＳＱｎｦＦＺ［＠ｾＡＧｉ｣ｰｬｾｈ＠ｾ＠ｾ＠

ｾ＠ 30 ｾ cf; ｾｾｾ .m ｾ I \3Cfn ｾｾ 1f ｾ 3lTaT4 Ｏｾ / 31J11fffi >rfC(j

o:ffiT §'fr t I

3. '<"flcp ｾ qft cpI4C1161 "Cf>T 31PT ｾｾ＠ｾｏ＠ｾＧ＠｣ｂｾｃｦ＾ｃＢｦｦ＠ mofBo &RT l:ffiC ;:fo ｾＭＱＵ＠ｾ＠

ｾＭＲＲＬ＠ $:ir2, %0 tl ut1(>1I, ｜ｗｦｃｦｇＭｾ＠ｾ＠ t!<"IIt:ICf>I'! ｾｏ＠ｾｯｾｯＭｱＫＺｲｯｾｯ＠Ｇ＠ｾｦｃｬ［ｧｬｬｬ＠ mofue ｾｦｃｬ［ｧ＼ＱｉＬ＠ｾ cfi ＡＧｉｾｐｉｾ＠ｾ＠ｬｉｾｉｃｉＢＧ､＠ｾ IDXT"\3CR1 ｾｾ >Rf1lCT ｣ｦ［ｾ＠ｾＳｉｔ＠ tf'

ｾｾ lTm I ｾ &m 3fCllTIl ｾ lTm fclJ "\3CR1 ｾ ffi IFcltl Ｎｾ em l:ffiC ;:fo ｾＭＱＵ＠ｾ＠

ｾＭＲＲＬ＠ｾＭＲＬ＠ %0 ｴｬｕｾ＼ＢｉｉＬ＠ｾＭｾ qx ｾ fcO<l u:rR 'Cf>T >ffiITCf i I \3Cftf ｾ em ｾ fcO<l u:rR ｾ＠ rgR 26930 qrf ｾｾｾ t I ｾ 21344 qrf ｾｾ COl

>r<Wr f.1mur ｾ fcOm \JfRT !'I'«IIFcl(j ｾｾＢ､Ｂｭ＠ 5586 Cllf4k'! ｾ mT ｾＬｾＮ＠ m ｾｾ＠

Rl cp Rt (j . fcPm \ilAT !>I '«II Rl (j t I \rcRf ｾ cr?T 31 jii IPI (j ｾ "<"fTlT(j" 15 ｾ t I

,

4. ｾ 6RT ｾ 1ITR ｾ＠ｾ 1f Oxo(20totylmethylphenyl) acetonitrile ( OTAN), Sulfuric Acid,

Hydrochloric Acid, methanol, 0 methyl hydroxylamine. HeI, 2( chloromethyl) tetrahydrofuran, Sodiurr hydroxide, Dimethyl "formamide, NmethylNnitroguanidine, 1,3Diisopropyl2isothiocyanato5· phenoxybenezene, Tertiay butyl amine, Toluene, Hexane, 1(4phenoxyphenoxy)propoane2ol, 2· chloropyridine,

........2....

ｾＮ＠

'""" ..._,,.... , . . '.. ...,_ｾＭ_.

, ,"

, ' , , I

i ' Potassium hydroxide, Tetramethylthiuramdisulfide, Chlorine; Dichloromethane, Sodium bicarbonate,

Diethyl . amine, Carbon disulfide, Zinc ¢arbonate, Caustic lye, Zinc chloride, Tetrahydrophthalic,

anhydride (THPA), Ammonia, . Phthalimlde cpr ｾｾ＠ｋｲ･ｳｯｸｹｭＭｍｾｴｨｹｬＭＲＵ＠ MTlMonth,

Dinotefuron30 MTlMonth, ｄｩｦ･ｮｴｨｩｵｲｯｮｾ＠ 50 MTlMonth, · Pyriproxyfen50 MTlMonth, ZDCIOO

MTlMonth, ZiramIOO MTIMOI'Ith, Thitam ,lOO MTlMonth, CaptanIOO MTlMonth,FolpetIOO

MTlMonth, Metam Sodium200 MTlMonth, Zineb 50 MTlMbnth & Intermediate Product Pthalide-

100 MTlMonth, NN Oimethyl Carbamoyl C/lloride 50 MTlMonth, NN Demethyl Thi6carbamoyl

Chloride 50 MTlMonth em ｜ＳｾｉｇＱ＠ｾ \;fRf SI'«1I.fc1d t, \Jcftf ct> 3iIflRc/tf ｬｩｊｉＱ｣Ｇｬｾｈ＠ｾＮ＠ c5 ｾ Solid Formulation WDG, WP 1 500 MTlMonth, Liquid Formulation' EC, SL 1000

MTlMonth em \3c=q1 G1 fcnm \Jfl'lT SI'Rl1 f?ld t,

5. fC;jfcl:q;s ｾ 1=fT'R c5 ｾｏ［ｳｉＧ＼ｏｉｾ＠ｾＮｾ 1l ｾｯ［ｳｬＧ＼ﾰｬ＠Ｎｾｾｦ｣ｮｭ｜ｩｦａｔＧＮ＠ｬＧｬﾫｬｉｾｴＱ＠ t ｾｾｾｯｸＺｦｴＧｯｾｯ＠ (32 >rftlmf) ｾ 30 ｾｏ a=rmT c5 02 'fTT, cl?lFkCf) ｾ (48 ｓｬｦ＿ｬｾｬ､Ｉ＠ｾ＠ 30 fcnNTo a=rmT c5 01 'fTT, ｾｾｦｬ｣＾ｱＩｉｬ＿［ｳ＠ｾ＠ 30 fcnBro a=rmT c5 01 'fTT, ｾｾ＠

ｾｾ 20 fcnBro aiImT ct> 01 ｾＬ＠ｾｾｃｦｃＧｬｬＧ＼ｉｾ［ｳ＠ tg ｾ 30 fcnBro a=r:mT ct> 01 'fTT,

ｾｾ＼［［ｗｦｬｾＱ＠ｾ 30 ｾｏ＠ aiImT cf; 01 ｾ -qci CfC'lH)1 ｾ tg 30 fcnc;fro a=r:mT cf; 01 'fTT teD ｾ fqrm \jf'RT ｓｬｦｦｩｬｾ､＠ t, \3Cffl cf; 3iRlRCfd ｦｬＨ＾ｱＩｾｃｦＩ＠ｾ (98 ｓｬｒｬｾｬ､Ｉ＠ＳｩＱｾｦｬｬｓＱＱＴＱｾｃＱ＠ｾｃＢｃｐ｜ｬｩＵｃＱＬ＠ｾＬ［ｳＱｾｃｦｃＧｬＩｉＧ＼ｬｾｾＬ＠･ＧＱｾ＼ｦｉＬ＠ｾＱｾｃＱｱｊｬＧ＼ｩＱｉｩＱｉｾ［ｳ＠ Cf5T ｾ 1l -qci ＳｩｾＱｾｻｬＱ＠ｾ Cf5T

fftc'lO;s,< ｾ＠ '+1 o;sIRd fct;<rr ｾＬ＠ｾｴＱＧｈｉｃｦＩ＠ '<fllll ..ti ct> '+1 0'151'<01, wWr ｾ m ｾ＠ \3"C'G'9

'ffiftt ｾ＠ EJmCr ｾ＠ Cf)1"!1!5I111 ｾｾ＠ｾｾｃｦｦｬｬＨＱＱｒｆＱＬ＠ｾ ctr ｾｾ ct> ｾｾ＠Ｎｾｾ vrrWrr' '

6. tfo ｾｏｾｯｯＯｦｏｾｏ＠ｾｦｕ［ｓｬｬｬ＠ｭｯｾｯ＠ｾｦｕ［ｳｬｬｬＬ＠ｾ ct> ｓｬｒｬｾｾ＠ &NT <:rg '4T 3TCrm ｾ ll<TI fcp

\3Cffl qR4hl'1l ｾ＠ 4 >rCl>'R ct> ｾ m cffr ｾ t , 31. \jf(1' ｾ＠

ｾＮｾｾ＠

'fT. ｾｾ＠

ｇＮｾｾ＠

31. "GRif ｾ : ＮＮＮＮＮＬＮｓｬｦｦｩｯ］ＮＮｐＭｬｾＢ］ｴＱ＠ｾ 1l \jf(1' em ｾｾ 5141\111, cnfijlr, tG III C1'<, ｾｾ 3f)Eilf1'lCf)

ｾｾ＠ W'rN 90 ｦ｣ｐ｣［ｦｴｏＯｾ＠ fcl;m \1fRT ｓｬｦｦｩｬｾ､＠ t, ｾ ctr \3c=qIG1 ｾＬ＠ &:JllIC1'<

€>C11OSI\31, cnfii1T ｾＬ＠ f?lflc'lPlllfl ｾＱｃｦｾｬｬ＠ Cf);:;g'i\9c ｭｾｾＵＶｦ｣ｐ｣［ｦｴｏＯｾ＠ \301C1li5

vrf.1o N7JT I <"IT ｸＺｦｴＧＰＳｬｔｏｾｏ＠ -qci <"IT ｩｔｯｾｯｾｯ＠ｾＮ＠ Cf5T ｾｾｫｾｲ｣＠ＨｾｃｦｃｬｃＱｉＧｾｊ｜ｾＱＱ＠ teD, ｱＩｾｃｦＩｃＱ＠ｾｴｊｾｉＧＱ＠ ten), ftq)o;{) ｾｫｾｲ｣Ｌ＠ｾｾｫｾｲ｣＠ (3lR031TO, ｾｏＭｱｲＰＳｔｒｯＳｉｔｏＩ＠ ct> ｾｾ＠

ｾｉＥｃｩｩｴＱ＠ 'CP'<', ｾｦＥｃｦｬｴＱ＠ 3TR031T0 4xf?l{lc Cf5T ｾ cBT \3c=qIG1 ｾＳＱｔ＠ｾ＠ m CJR ｾ 'GfTWrr m:rr 31N031l'O ｾ em ｯＯｦｏｾｏｾｏ＠ ct> ｾｾ＠ｾｱｬｱｾ･＠ fcnm ｾＬ＠ｾｸＺｦｩＰＳＱｔｏｾｏ＠ｾ＠ｾ＠

ｩｔｯｾｯｾｯ＠ｾ em ｾｾ｣ｾｲ｣Ｌ＠ｾ cfi ｾｾ＠ｾｆ｣Ｆｃｦｬ､＠ 'CP'<' ｯＯｦｯｾｏｾｏ＠ ct> 11lUP'f ｾ＠

ｾｱｬｱｾ｣＠ fcpm "GiJ<Tm, ｾｾ＠ \iff.1TI 3l1ifPlCf) [%te1c'lc, ｯＯｦｏｾｏｾｏ＠ｾ＠ \iff.1TI ｾｾ 'QCf

ｾ cfi ｾｾ＠ｾ 3ilifPlCf) ｛Ｅｴｴｊ｣ＧｬｾＱＱ＠ｾ em ｩｔｯｾｯｾｯｾｏ＠ cfi 11TUP1 ｾ＠ Pl'RlIRC'1 fcnm

ｾ I ｾ ctr ｜ＳｾｉｇＱ＠ 51RP{lI3lT ｾ＠ｾ '4T >remx cpr \301qli5 PlffiIRt1 ｾ＠, ｾfcl?<:rr I

ｾ ct> ti'qIC11 ct> ｾ VTC1' ｾ .. ｾ &IT, ｾｾ＠ｾｾｾ＠ｾ \301qli5

'C1'T111T 4 fcf;c;fro /fG'i' em ｾｴ｣ｮ / ff1 Cf) fC1 e cfi ｾｾ＠ f.1 ffi 1 Rt1 fcpm ｾ ,

)( .............. 3 .......... .

1 '[

!.

. ｦｾＧｔｾｩｾｷ［ｩｴＦｬｾ＠

ｾｾｾ＠Itt&

i1J;

ＨｾＱＦｾ［ｉ＠!

ｾ＠I

! ..

j ｾｾ＠Ｎｾ＠[t& ｾ＠ｾi J 'N 1&

ｾ＠.w; i t i

ｾ＠1J l ｾ＠

Ew;

ｾ＠:

, ii I

. f

1& ｾ＠

. ｾ＠ｾ＠f

ｾ＠J ｾ＠1t&

1J; i &' i§

ｾ＠l

ｾ＠ｾ＠

1J; .'ｾ＠t

t ".

I

.. ' . ｾｬｪｾｩｩｴＧｾｾｾｉｾｾｉｾｾ＠

ｾＧｾｉｾｉ＠ｾｩＧｾｩ［Ｑ＠

I ｾ＠

,w; ｾＢ＠

Ｍｾ＠.

&

1& !

ｾ＠w

ｾ＠ｾ＠

'W ｾ＠

ｾ＠Ｎｾ＠

1& ｾ＠

ｾ＠I

o I Jl: ｾｊ＠

ｾ＠ｾ＠I

ｾ＠i Iｾｾ＠

Ｇｾ＠ｾ＠

15 ｾ＠ｾ＠

ｾ＠ｾ＠

ｾ＠1i i ｾ＠

ｾ＠ｾ＠

ｾ＠-

ｾｾｾＡｧｾＡｾ＠t&<[g

ＺｾＬＮ＠_

.

. ..

ｾＱｊ［＠ｾ＠i t

ｾ＠ｾ＠

ｾ＠ｾj Ji

ｾ＠ｾ＠ｾ＠

ｾｾI (;' ｾ＠

t ｾＡ＠ｾ＠ｾＡ＠

t ｾ＠

rｾｩｾｾ＠

ｩｩ［ｾｴｬ［Ｚｾ＠ｬ＼ﾧｾ＠

ｾＱＦ＠ｦｾ＠

ＱＡＷｾＱＦｴ＠ｾ＠

ｾ＠ｾ＠

..ｾ＠i 7

jli'ii 1J;1 ｾＡ＠

ｾ!! Iｾ!Ｎｾ＠1_ !

i ｾ＠ｾｾ＠1&

ｾ＠

ｾ＠iiｾＢｩI!!1!]i!1 i!ｾ＠

iiiｾＡ1

iiiｾｩi ! t. _.

ｾＮ＠ｴＦｴｩＮｬｬｩｬｩｴﾷ［ｾｉｾ＠

ｊｾｉ＠ｩＤｬｾｩｩ＠

li:!!1 ·i ::

i i ｾ＠ｾ＠ｾi ｾ＠ｾｩｾｾＡＧ＠

I ｾＮ＠'N t&

: : ｾＬｩ＠$

t I!ｾ11 ｾ＠: i

$

.I, .. C) ｾ＠ｾ＠

1& 1Y

ｾ＠Ｌｾ＠t If j

.ｾ＠11\(1 I

ｾ＠ｾ＠

ｾ＠ｾ＠

ｾ＠Iｾ

1

wｾ＠

i! ｾ＠i ｾ＠

Jl: ｾ＠!rl &' ｾｾ＠

f 1·1·

1. ｾ＠

ｾ＠ｾ＠! i ｾ＠

1!' ｾ＠

l rｾ＠

ｾｪ＠ｾ＠

t ｾ＠1&

1& ｾｾ

1J; i ｾ＠

ｾ＠ｾ1

ｾ＠ｾ＠ｾ

<Ili wｾ＠ｉＧｾ＠

ｾ＠'l< ｾ＠

ｾｾ＠ｾｊｬＺｊﾥＧｊｉ＠

[i ｗｾｾ＠ＡｉｾｩＤ＠

ｾＱｊ［ｉｾ＠ｾｬ＠

I:i!tloi ｾ＠'

y

r

i .... ;-;'·-t:f.'.-.

.:.. r, .'";"i:iW

i 'Wt¥i,'"" ,' ,·......'-

..'+"W

"w,M

".y,/,;t "*"",;.,'ＧｈｻＢｩｦｲＧｦ［ｩＧ＠ＧＧ＠ＧＧＧＬＬＬＬＬＬＬＬＬｾ

ＬＬＬＬＬＬＬＬＢＬＬＬＬｾＬＬＬｾｾ

ｾ｟Ｌｾ

ｷ｣ＮＬＬｾｾ｟

Ｎ＠

\I ' ,

I I ,

, II

" . I

" I ,

;

. "

ｾｯ＠ｾｾｃＧＱｐｉＧｬＡＬ＠ＢｇｦｴｯｾｯＬ＠ cBf?lCbRl ＾ｲｲｯｾｯ＠ｾ t(;nc =fa ｾＭＱＵ＠ｾ＠ Efi22, .mrr2, "('f60 ｦｬｕｾ＼＾ｉｉＬ＠ｾＭＢＭ aRT 6!"ffi<IT Tf1:IT ftp 6l1RT ｾ aRT ｜ＺＺｬｾｉｾｃＱ＠

I

Ｈｬ＾ｉＱｾｾｉＧＱ＠ｾｾ $T ｾｾ＠ｾ fclRIT ｾＬ＠ｾ Cf6 t:pC;f, ｾＬ＠ 3ATGr, \J'Jl ｾ＠ｾ｜ＺＺｬｾｉｾｃＱｾＧｾＬｾ＠ . ＬｾｾｾｾＭｧｧｾｦ｣ｰ＼ｲｲｾＱ＠

ｾ＠ｾＬ＠ 1JTl=f \3 SixC1 i<>ft, ＮＬＮＮＮＬＮＮＭＺｾ＠ 6RT ｾＮＱｲｭ＠ ftp ｾ ctr ｾｾ＠ｾｾ tN

ｾ WN<rr ill ;fflT mnT 1 Ｈｾ＠ . , mfr \3SixC1I<'11, fju\iE)<>II) 1

' I I

\RfI'{ ｦｬ＼＾ｬｬｾｉｃ｢ｬｸ＠ lfO ｾｏｃｦ＼ｩｏｾｏｾｏ＠ｾｦｕＧ［ｧｾＱ＠＾ｲｲｯｾｯ＠ｾｦｕ［ｧｾｉＬ＠Ｌｾ cf; ｉｏｬｦ､ｦｙＩｾ＠ｾ＠ｾｾｬｱＢＧｴＱ＠ｾ＠

aRT "6RfTm 1fm fcp ｾ \3 (q I G'1em ｾ ct , ｾｾ＠ q)f?lCb<>l ' c15T ｾ 6Prr ,ｾ＠ｾＯＤｲｮ 3llfG ｾ＠ｾ mrrr ｾ｜ＺＺｬＨｱｉｇＧＱｾＬ＠ｾＬｾ･ｭ＠Ｎｾｾｉ＠

ｾ 3 ｾ＠ｾｾＬ＠ <.:JTff ｃ｢ｾｾｉｓｩ｜ＳＧｩＬ＠ flu\iE)("J1 ｾｾ TTm fcp cBf?lCb<>l ｾｾ＠ｾ mIT ｾ＠ｾＳｉｔ＠ em ｾ jCbflJ'1 ill ｾ mrrr 1 (J>fr ｾｾＬ＠ lJlll ｃ｢ｲ･ｾｉｓｩｉＳＩＬ＠ fluJ'i<>lI) I

fl<>lIt5ICf>lx ltO ｴｯｾｯｾｯｾｯ＠ｾｦｕ｜ｓｾＱ＠＾ｲｲｯｾｯ＠ｾｦｕ｜ｓｾｉＬ＠ｾ ct Ａｏｉｒｬｐｴｾ＠ｾ＠ｾｾｬｱＢＧｴＱ＠ｾ＠

aRT ｾ 1fm fcp \3CRf ct\ c'1l ｾｉ＠ CPl' q)f w:trr ｾ / l<>Il ue; fl tN ｾｐｴｾＺｱ C1 "fl11"(:T \Jf6r

ｾ /$rn 3llfG q)f ｾ mm t \jfl" "fl11"(:T ct\ c'1l ｾｉ＠ CPl em w:trr ｾ / ｾ I0e; fj tN

fcl>m \jffffi t; ｾ＠ｾ＠ fY)Fhm "fl11"(:T ｾ CJ5 ｾＺ＠ｾｃ｢ａＴＧｉ｜ｊＱ＠ mｾｾ＠ "Cfct ｾ >rmcT

3Tf"C!Ctr \if4T;:r tN ｾｾ 3tR ｾｾｾ［ｦｦｬｔＢｩｗｦｴ＠ 1

ｾ 4 ｾ＠ｾＬ m." flot'l<>ll &m ｾ <Tm fcn ｾｾ＠ "\J1'f.1ff xrofi ｾ＠ｾｾ ill ;fflT

"t5llfi 1 Ｈｾ＠ｾＬ "flTB, flot'l<>ll) 1

,

flNIt5ICf>lx ltO ｴｯｾｯｾｯｾｯ＠ｾ＾ｲｲｯｾｯ＠ｾｦｕ｜ｓｾｉＬ＠ｾ * Ａｏｉｦ､ｦｙＩｾ＠ｾ＠ｾｾｬｱＢＧｴＱ＠ｾ＠

am ｾ 1fm fcp ｾｕ｜ｳｾＱ＠ｾ＠ｾ xmr ｾｯ［ｓｦｃｨｃＱ＠ if ｾ mT ｾｾｾ fljRId

PI '«11 '< 01 fcp<rr ｾ I

ｾ 5 ｾ＠ｾ fm", 3TCCIT, fl o\iE) C11 6RT ｾ 7f"m fcp c6fflCbC1 ｾ＠ w:trr ｾ＠ crrr:r WIT <:IT m, ｾ l1ffi ｾ I ＨｾｾｾＬ 3TCCIT, fl0t'l<>ll ) 1

flC1It5lcBlx ltO ｾｯｃｦｬＡｯｾｯｾｏ＠ｾ＾ｲｲｯｾｯ＠ｾｦｕ［ｧｾｉＬ＠ｾ ct SlfdPtftr J>fr ｾｾｉｃｪＢＧｴＱ＠ｾ＠

am 6!ffi<.IT 1fm fcp qttl fll ｾ［ｧ＠ / en", ¢ "11 ｾ ICb ｾｾｾＺｱ C1 1=fT?IT if w:trr fcpm \ilT'1T mm t; ｾ＠

\NICf>T ｾ 1:f>llf mm t , RilflCf>1 ｦｦｓｩｾＯｪｦｬｬＧｬＡ＠ w:ITrr men t;, ｾ＠ｾ＠ｾｾＺｱ｣ｩＺ＠ｾ tN ｾＺ＠

RCf>A4llJl m\1ImT ｾ＠ I' ' II

ｾ 6 ｾ＠ｾｾ｣ｍｦｉｃｊＬ＠ flot'lC1/ Gffi ｾ <Tm fcn FcPfll'""Il en) ｾ 1Jl1'1Cf>/ofl m ?;rrr, ｾ <IT

"fRCbN I Ｈｾ＠ｾｾｱＯＧﾫＱｱＬ＠ fl ot'lC1I) I

....... .... 5 ......... .

i!ii i

il 11&

) iii!

ｾｾｩ＠. ｾｴ＠

ｩＡｩｩｩｾ＠I

.; ｾ＠

fg' t ｾＮ＠

. ｾ＠1&

1!

ｾ＠ｾ＠

ｾ＠I ｾ＠\' ｾ＠

1

1l' i 1l' ｾｾ＠rfJ' ｾ＠

1

: t ｾi ｾＡ＠:ｾ＠

t ｾ＠ｾ＠I :

i liW t! ｬ｟ｩｾ

, !i ｾ＠;1&

i 1

ｾｾｩｾＡ＠i

ｾｾ＠ｾｾ［＠

ｾＬｾｾＡｾＢｩｾ＿＠ＡｾｾｩｾｬＴ＼［ｾＱＦ

ｾ＠ｾ＠

1¥ ｾ＠ｾ＠

ｾ＠

ｾ＠ｾ＠1l'

ｾ＠Wｲｾ＠

11<; ｾ＠

ｾＮ＠re;.

1l' ｾ＠'Ii l

1

ｾＧ＠ｾ＠1& iI

1& t'

; i! i 1&

ｾ＠ｾ＠

%; ｾ＠. ｾｾ

i!il1; i ｾ

1ｾ＠

t 1ｾ＠

Ｇｾ＠1& ｾ＠ｾ＠

I, ｾ＠I ｾ＠ｾ!

ｾ＠;ｾ＠

t i i!1l' iii 1!4.i1&

1& 40

. ｾ＠ｾ＠ｾｾ＠

Ii ｾＡｾｉｉｾｾＡｾｾ＠

ｩｩｾｩＬｾＱＦｩｴｾ＠

ｾ＠ｾ＠:t1 ｾｾｩｾＡ＠

ｾｾ＠ｾｾｩＭ

ｾｾＱＦ＠ｾｾｾＬｉｊｩｾ＠

to'. .

i i 1 ｾＡＡＡ

t i "

)iW '" t

"i' ｾ＠ｾ＠

ｾｾＱｩｾｉｾＧｲＺ＠ＭＭ

ｾＭ'F

'"'

f Ii'

te. ｾ＠ｉｩｾｾ＠

Ｎｾ＠ｾ＠

, Ｎｾ

ＮＱ］＠ｾ＠

ｾ＠!r ｾ＠

!; ｾ.. ｾ＠

-;f\(I

ＲｴｲｾＮ＠f

10. Ff

Ｎｾ＠ｾ＠

1l' "" I>' ｾ＠

c ｾ＠ｾ＠

Ｎｾ＠ｾＺＭ

"'.

" e:

I I

f Ii;i ｾ［［ｾ＠

i ｾ＠ｾ＠i j ! , ｾｾｾｾｾ＠

Ig ｾＡＱＦ＠

ｾｉＬｾ＠ｾ＠

tｾ＠

ｾ＠ｾ＠

t ｾ＠1

tｾ＠ｾ＠

ｾ＠? i ｾ＠

t ｾｾ＠ｾ＠

ｾ＠

1&

;ｾ＠ｾ＠ｾＱＱ＠ｾＡ＠

:; ｾ＠ｾ＠ｾＧｩ［＠

i :; ｾ＠it f;1!i

ｾ＠i !i ｾ［＠iii

ｾ＠ｾ＠ｾ＠t<

§ g ｾ＠ｾ＠

tt, i1 ｾｬ＠ｾ＠

ｾ＠ｾ＠

ｾｾＢＢＧ＠ｬｬＺｾ＠

［［Ｍｾｾ＠ｴｾＱＦＴ＼［ｾ＠

i! ｾ＠

ｾＱＦＱＦ＠Ｇｉ＼ｩｾ＠

! ｾＭｦｧＧ＠'l<i1l'$1&

! ｾＱｗｾＤＱｾ＠ｾ＠

ｾＡＱＱｉｲｩｩｬＢＢＧｩ＠'/ :j

1i!i ｾ＠ｾ＠,15 ｾ＠

." ｾ＠

! ｾ＠

ｾ＠ｾｾ＠

ｗｴｴｾ＠ｾ＠

ｾ＠ｾ＠

ｾ＠ｾ＠

ｾ＠it; i

ｾＱＦ＠$

ｾ＠ｾ＠

I il

';>&

j II

\

\ \

I i I : !

I .

I , /1 i (6)

" I , i

I '

m RlCl?ffttl ｾｉ＠ m ｾｾ＠ｾ :fIT ｾｾ g ｾｾｾ＠ aT?r q ｾｾ＠ :fIT \RITGT

Rlq;ffttl g I 3«1: \JA1lG q ｾｾＳｦＩＧｴｬｬｬａｃｉ＿Ｌ＼ｯｬ＠ 6Pn. ｾ \3"C'PIT t)" N1lT I ｾＧｾ c#t ｾｾ＠ fGrc;rr "CI?T ｾ 6Pn I ｾｾ＠ｾＬ＼ｬ｜ｩｐｉｉＧ＼＠Ｂｾ em ,<lGPII'< ｾ＠ｾｾｾ I ｾ＠

• ＴＬ＼ｾｇｐｉｉＧ＼＠ｾ em ｾｾｾ ill RlCl?ffttl M I ｾ am ｾ P!4?1ol ｾ＠ｾｾ＠

ｾＮ＠ ftAq;1 qllfCl,<ol fcr:frT ｾ＠ c;Wr 31141<:'1'1 '{1f.1flcld ｃｉ＿Ｇ＼ｉｾｬｬＢ＠ I ｾｾｾＺ＠ｾｾｾｃｉ＿＼ＺＧＱ＠ m \ffiT1T ｾＬ＠ｾ \RCllG ｾ q ｾ C11T . ｾＯＬｾｾＮ＠ｾＮＭｧｧ＠ｾ fcmrr \i'ITWn, ｾｾ＠CBT ｾ \=jI;qIG'1 Nrrri ｾｾ＠ｾｾ mn ｾ CfRW ｾｉ＠ .

3Rf q ｾＹ＠ 3l"Rl >ffifG "¥. '<"1glllCl? ｾｾｉｦＮＱｃｦｊ＠ｾＬ \3"0 ｾｯ＠ｾ f.1l1"?l OI ｾ GRT 3l&ia1

ｾｾ＠ｾ WfR ＼ｦｉｃｬ＿ＧｴｬＧＱｱｬｾ＠ W11lR cp'T tWrurr cp'T 7J<fr I 3llN ftR;rr lift1«c ｾＬ＠ｾ＠

ｾ \1A ｾｾ＠ mTi 3TMN ｾ q;ffi ｾｾｾｾ＠ '{i1i14'1 "$T "$rJrr cp'T .mT I

•

, ,

4 . 6t101 C:::h qt?mt SJl\ Z ｾｾ SJ "Yr/W 611 C ｾＶｾ＠ }(/2 <:; • (') d1d"" 1(/)1 n ＭＺＨｦ＿Ｗｾ Wt 4 <:-,.n;;:r 6; ,

__.iL· 2/J1 ｾ＠ ;t:zT;Fr'1 .. \ fL.. • .'d} ｾ 0( f ＮＯｾｾ＠

Ｂ＠ＮＢＺ＠ＮｩＱｾＮ＠＿ＭＱＭ､ｬＭｴＡＺｲｾ＠ＭｬｾＭＮＮ＠Ｎ＠ A"v\.J\',,,i It ｵｾｊ＠..u:, ｾＭｊｾＢ＾ＭｴＷｔ＠

｟ｾ＠ f::c-r.D)T, '

_Ll.' ｉｾ＠l ·<::I· '

V ｾＧＭＧｲＧ＠

ｪｾＮＡ｟ ..;R(rq b( C{1r;(

"E.:.... /lliA ｾＧｬ ( Y 1vq....J

ｾｦ｜ｌｾ＠r'\ ':-

ｪＮＮｾ＠ｾ｡ｾ｜ｉＱ｜ｌ＠ＮＮ＠･ｹＯＱＭＮｏＨｾ＠ｃｬｇｾｊＭＱ＠

ｊＧＭｾＮ＠ 1.1. ｧＮＺＮＭＮｾ＠ＮｾＮ＠ｾｑｾｴｾ＠Ｏｾ｡ｯｐｾＩｾ＠

puhlic hearing reg Swaroop Chemical

" "--- ---,, ------ --- --

Gct1't m M,&qol Ptli?lol ｾ＠

W UTTAR PRADESH POLLUTION CONTROL BOARD

ｾｊｾＯ＠ｾ . . ｾＮＭＯ＾｟Ｌｲｏ. ｾｾｾｾｾ＠ . • .. . ;; Ｏｾrn ........ ........... ｾ＠ 5/ ｾＧｦＱ＠ t .Un7)t<-O ... 18ｾ＠ .............;..

ｯｯｾＬ＠

31fdRCRl ｾｾｾｉｃｦＩ＠

ql1fCl,!UI q;=f "CfCf ｜ｊＱｃＱｃＱｉｾ＠ qRClct'1 1=i?lIC1l1,

11ffif fi '!Cf) I'!

ｾｐｇＧＡｉ＠ Ql1fCl,!OI ｾＬＳＱ｣＾Ｑｐｉ｜ｊＱＬｇＱＧｉＧＡｾｉｾｌ＠ｾ＠

ｾ＠ｾＦ｣ｬｬ＠ 110003

ｾ Ql1fCl,!OI (X#aTDT) ｾＬ＠ 1986 ｾ＠ 31;:tpft1 ｾｾ｣ｂｾｩｦＩｃＧｦＱ＠

mofBo" Ｓｬｾ＠ tlllTl if) aBr, fj O;g)C1I, 5,! ｃｻＧｉｾ＠ am cGt ･ＺＧＱｉｾＱ＠ 4>,' ｾ＠ \3{"q IC{'1

ｾｾ＠ｦｩｒｓｬｾ＠ｑｬＱｨＺｎｏｾｬＱ＠ 31'1IQfffi ｾｾｾＧＱＱｃｦＩ＠ 14.9.2006 ｾ＠

ＳＱＧＢｦＱｾｦｴＱ＠ｾＧＱＱｃｦＩ＠ 30.12.2017 em ｾ＠ｾ＠ＧｴｩＧＱｱｬｾ＠ｾ＠ｃｦＩＱＴｾｃＧ､Ｌ＠

C/l ｾＱｬＱ｜Ｂ lhl cBI xfttr \3 qC1 a:T ｾｾ c# ｾｴｲ＠ｾ＠ I

ｾＬ＠

ｾｾＭＭＭＭｦｪｃｻｾ＠ｾ '7v

QIflfc;tf(l ｾｫｉｾｒＵｬｴＱ＠ em ｘｩｩｬＧＱｬｾ＠ "CfCf ＳＱＱｃＱｾＱＱｩｦＩ＠ Cf)14C116) ｾｾ I

3. ｾ＠Ｍｱｏｾｏ＠ｾｾ｣ｦｴＬ＠ｾｾｾｉｩｦＩＬ＠ｾｾ｣ｂｾｃｦＩｃＱ＠ mofBo, atl€llfrlif) aBr, fjO;g)C1I,

ｾｉ＠4. ｾｾＬ \3'0 ｾｏ＠ Uc&t'lOI f.1ti?lOI mt, \"3"1lq I

it. "fl\. ＱＲｾＮ＠ｾｾ＠ T.C. 12 V, Vlbhutl Khand

ｾＮｾＲＲＶＰＱＰ＠ Gomti Nagar, Lucknow 226010

ｾ 272831. 2720828. 2720691. 2720681 Phone: 2720831,2720828,2720691,2720681

m 05222720764 Fax: 0522 - 2720764 l.q:('l'& [email protected] ｾＺ www.uppcb.com

Documents

$QQH[XUH, …environmentclearance.nic.in/writereaddata/online/EC/...Hardoi, Uttar Pradesh E\ MIs Swarup Chemicals Pvt. Ltd. - Terms of Reference - Reg. Ref. No.: Your Proposal No