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Sunlight-Induced Self-Healing of a Microcapsule-Type Protective Coating

Young-Kyu Song , Ye-Hyun Jo , Ye-Ji Lim , Sung-

Youl Cho , Hwan-Chul Yu , Byung-Cheol Ryu ,

Sang-In Lee , and Chan-Moon Chung *Department of Chemistry, Yonsei University, Wonju,

Gangwon-do 220-710, KoreaKorea Conformity Laboratory, 1276 Jisa-dong,

Kangseo-ku, Busan, 618-230, Korea

ACS Appl. Mater. Interfaces, 2013, 5(4), pp 13781384

DOI: 10.1021/am302728m

Publication Date (Web): February 1, 2013

Copyright 2013 American Chemical Society

*E-mail: [email protected] .

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Photopolymerization behavior of a methacryloxypropyl-terminated polydimethylsiloxane

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Published In I ssue

February 27, 2013

Article ASAPFebruary 13, 2013

Just Accepted Manuscript

February 01, 2013

Received: November 16, 2012

Accepted: February 01, 2013

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ICP10201100-36 | Copyright 2013 American Chemical Society

PDMS. It was confirmed by optical microscopy and SEM that, when the self-healing coating is

damaged, the healing agent is released from ruptured microcapsules and fills the damaged

region. The self-healing coating was evaluated as protective coating for mortar, and it was

demonstrated by water permeability and chloride ion penetration tests that our system has

sunlight-induced self-healing capability. Our self-healing coating is the first example of

capsule-type photoinduced self-healing system, and offers the advantages of catalyst-free,

environmentally friendly, inexpensive, practical healing.

Keywords: photoinduced self-healing; capsule type ; protective coating for concrete ;

microencapsulation

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