PRUETT-SCHAFFER CHEMICAL COMPANY - Calbond€¦ · PRUETT-SCHAFFER CHEMICAL COMPANY Page 2 of 14 2. HAZARDS IDENTIFICATION – cont. GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910

PRUETT-SCHAFFER CHEMICAL COMPANY

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SAFETYDATASHEET1.PRODUCTandCOMPANYIDENTIFICATION

PRODUCTNAME: PVCTOUCHUPCOMPOUNDEXTERIORGRAY PRINTDATE:January26,2016 PRODUCTCODE: 45-1-1

RECOMMENDEDUSE: IndustrialPaint USESADVISEDAGAINST:

MANUFACTURER: Pruett-SchafferChemicalCompany 3327StaffordStreet Pittsburgh,PA15204 Phone:412-771-2000Fax:412-771-2205

EMERGENCYPHONE 1-800-633-8253(PERS)

2.HAZARDSIDENTIFICATIONGHSCLASSIFICATIONINACCORDANCEWITH29CFR1910(OSHAHCS):

• HighlyFlammableLiquidandVapor(Category2),H225(chapter2.6)• HealthHazards:

Acutetoxicity- Category4 H302+H312+H332Oral (chap.3.1)Dermal (chap.3.1)Inhalation (chap.3.1)

• Specifictargetorgantoxicity–repeatedexposure Category2 H373

• Eyedamage/irritation- (chap.3.3) Category2B H320

• Aspirationhazard- (chap.3.10) Category1 H304

• Chronicaquatictoxicity- (chap.4.1) Category3 H412

GHSLABELELEMENTS,INCLUDINGPRECAUTIONARYSTATEMENTS:• PICTOGRAMS:

• SIGNALWORD:DANGER

• HAZARDSTATEMENT(S):H225 Highlyflammableliquidandvapor.H304 Maybefatalifswallowedandentersairways.H332 Harmfulifinhaled.H373 Maycausedamagetoorgansthroughprolongedorrepeatedexposure.H412 Harmfultoaquaticlifewithlonglastingeffects.

• PRECAUTIONARYSTATEMENTS:GENERALHAZARDS:P101/P103 Ifmedicaladviceisneeded,haveproductcontainerorlabelathand. Readlabelbeforeuse.


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2.HAZARDSIDENTIFICATION–cont.GHSCLASSIFICATIONINACCORDANCEWITH29CFR1910–cont.

• PRECAUTIONARYSTATEMENTS–cont.:PHYSICALHAZARDS:P210 Keepawayfromheat,sparks,openflamesandhotsurfaces.–NOSMOKING.P211 Donotsprayonanopenflameorotherignitionsource.P233 Keepcontainertightlyclosed.P240 Ground/bondcontainerandreceivingequipment.P241 Useexplosion-proofelectricalequipment/lighting/ventilationequipment.P242 Useonlynon-sparkingtools.P260 Donotbreathdust/fume/gas/mist/spray/vapors.P262 Donotgetineyes,onskin,oronclothing.P264 Washface,handsandanyexposedskinthoroughlyafterhandling.P270 Donoteat,drinkorsmokewhenusingthisproduct.P273 Avoidreleasetotheenvironment.P280 Wearfaceprotection,protectivegloves,protectiveclothing.P284 Wearrespiratoryprotection.

HEALTHHAZARDS:P308/P313 Ifexposedorconcerned:Getmedicaladvice.P342/P311 Ifexperiencingrespiratorysymptoms:CallaPOISONCENTERordoctor.

P305/P351/P338 IFINEYES:Rinsecautiouslywithwaterfor15minutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.P337/P313 Ifeyeirritationpersists:Getmedicalattention.

P304/P340 IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.

P303/P361/P353 IFONSKIN(ORHAIR):TakeoffimmediatelyallcontaminatedclothingRinseskinwithsoapandwater.

P333/P313 Ifskinirritationorrashoccurs:Getmedicalattention.

P301/P310 IFSWALLOWED:DONOTINDUCEVOMITING.ImmediatelycallaPOISONCENTERordoctor.

P363 Washcontaminatedclothingbeforereuse.

ENVIRONMENTALHAZARDS:P391/P502 Collectspillage.Refertomanufacturerforinformationonrecovery.

INHALATIONHEALTHRISKSANDSYMPTOMSOFEXPOSURE:• Maycauseheadache,dizziness,nausea,irritationofthenose,throat,andrespiratorytract,

andlossofcoordination.• Severeoverexposuremayproduceanesthesiaorunconsciousness.

SKINANDEYECONTACTHEALTHRISKSANDSYMPTOMSOFEXPOSURE:

• Eyecontactmaycauseirritation,redness,andtearing,andblurredvision.• Skincontactmaycauseirritationandredness.• Longtermskinexposuremaydryanddefattheskin,causingcracking,andinseverecases,

dermatitis.


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2.HAZARDSIDENTIFICATION–cont.GHSCLASSIFICATIONINACCORDANCEWITH29CFR1910–cont.

INGESTIONHEALTHRISKSANDSYMPTOMSOFEXPOSURE:• Ingestioncancausegastrointestinalirritation,vomiting,nausea,anddiarrhea.

HEALTHHAZARDS(ACUTEANDCHRONIC):

• Breathinghighconcentrationsofaerosolsormistsofthismaterialmaycausenauseaandirritationofthenose,throat,andrespiratorytract.

• Acuteoverexposuretosolventfumesduringairdryingofthisproductmaycauseheadache,dizziness,nausea,andlossofcoordination.

• Chronicoverexposuretosolventfumesmaycausecentralnervoussystemdamage.

SIGNIFICANTDATAONMIBKWITHPOSSIBLERELEVANCETOHUMANS Intestswithlaboratoryanimals,methylisobutylketone(MIBK)producedevidenceof embryofetaltoxicityatexposurelevelswhichweretoxictomothers,butnoevidence wasobtainedforteratogenicity,orforembryofetaltoxicity,atlevelswhichdidnot affectthemothers.Resultsfromfivemutagenicityassayswithdifferentgeneticend- pointsindicatethatMIBKdoesnotproduceactivitytypicalofthatofchemicalmutagens. AdditionalstudieshaveshownthatMIBKistoxicifaspirated.Itisknowntoenhancethe

neurotoxicityoflinear6carbonsolvents.

CARCINOGENICITY:• NTP:No IARCMONOGRAPHS:Yes OSHAREGULATED:No

CHRONICEFFECTSOFCARBONBLACKOVEREXPOSURE

• ThecarbonblackcomponentofthisformulaisanIARClistedGroup2Bsubstance,consideredbyIARCtobea"Possiblehumancarcinogen".CarbonblackisnotdesignatedasacarcinogenbytheU.S.NationalToxicologyProgram(NTP)ortheU.S.OccupationalSafetyandHealthAdministration(OSHA).TheAmericanConferenceofGovernmentalIndustrialHygienists(ACGIH)classifiescarbonblackasA4,"Notclassifiableasahumancarcinogen".CarbonblackisnotpresentlylistedbyCaliforniaProposition65,buttheCaliforniaOfficeofEnvironmentalHealthHazardAssessment(OEHHA)publishedonOctober29,1999aNoticeofIntenttoList"CarbonBlack(airborneparticlesofrespirablesize)"asa"substanceknowntotheStatetocausecancer".

SIGNIFICANTDATAWITHPOSSIBLERELEVANCETOHUMANS Thisproductmaycontaintraceamountsofresidualvinylacetate.Vinylacetatehasbeen identifiedbyIARCasapotentialhumancarcinogen.Lifetimeexposuretohighvapor

concentrations(600ppm)ofvinylacetatecausedmalignantandbenigntumorsoftherespiratorytractofrats,butnotofmice;thisresponsepossiblybeingassociatedwiththeirritanteffect.Vinylacetatehasbeentestedforcarcinogenicpotentialinratsintwoseparatedrinkingwaterstudies.Inonestudyinwhichanimalswereexposedtoconcentrationsupto0.5%inwater,therewasnoevidenceofcarcinogenicity.Inthesecondstudy,conductedathigherconcentrations(upto1%inwater),evidenceofcancerinthestomachandoralcavitieswasobserved.Thereisnoevidencethatvinylacetatehascausedcancerinhumans.Thereshouldbeminimalriskwhenusedwithventilationadequatetokeeptheatmosphericconcentrationofvinylacetatebelowtherecommendedexposurelimit.


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2.HAZARDSIDENTIFICATION–cont.SIGNIFICANTDATAWITHPOSSIBLERELEVANCETOHUMANS–cont.

Maleratsreceivingvinylacetateathighconcentrationsindrinkingwater(0.5%)fortwoGenerationspossibledemonstratedadecreasedabilitytoproduceoffspring.

MEDICALCONDITIONSGENERALLYAGGRAVATEDBYEXPOSURE:

• Overexposuretosolventfumesmayaggravateanesthesia,respiratorytractdiseaseorpre-existinglungdisorders,nausea,andvomiting.

3.COMPOSITION/INFORMATIONONINGREDIENTSReportable VaporPressure @Temp WeightComponents CASNo. mmHg DegreeF. Percent*MethylIsobutylKetone,4-Methyl-2-pentanone 108-0-11 15 68 33.87ACGIHTWA8TLV:50ppmor205mg/m3,75ppmSTEL.OSHATWA8PEL100ppmmg/m3.OSHA:50ppmTWA8,205mg/m3TWA8,75ppmSTEL,300mg/m3STEL.*Toluol(methylbenzene) 108-88-3 26 77 25.18ACGIHTWATLV:50ppm.OSHAPEL:200ppmTWA,150ppmSTEL.VinylChloride-VinylAcetate-MaleicAcidPolymer 9003-22-9 0 0 22.25DIISODECYLPHTHALATE 68515-49-1 0 0 5.79Mica,inertfiller 12001-26-2 0 0 3.99 ACGIHTLV:3mg/m3,OSHAPEL:20MppcfTitaniumDioxide,inertpigment 13463-67-7 0 0 2.31ACGIHTLV:10mg/m3,OSHAPEL:15mg/m3,OtherTLV:10mgTWAAmorphousfusedsilica 68909-20-6 0 0 2.03OSHAPEL&ACGIH:20MppcfCarbonBlackPigment 1333-86-4 0 0 1.74ACGIHTLV:3.5mg/m3TWA,OSHAPEL:3.5mg/m3TWAOrganoclay 68911-87-5 1.50YellowIronOxide,inertpigment 51274-00-1 0 0 0.34ACGIHTLV:5mg/m3,OSHAPEL:10mg/m3RedIronOxide,inertpigment 1309-37-1 0 0 0.17ACGIHTLV:5mg/m3,OSHAPEL:10mg/m3Acetone 67-64-1 157 68 0.11ACGIHTLV:500ppmTWA,750ppmSTEL(C),OSHAPEL:1000ppmTWA.VinylAcetate(Asanimpurityinrawmaterial) 108-05-4 0 0 0.02ACGIH:10ppmTWA8,15ppmSTEL.OSHA:10ppmTWA8,20ppmSTEL.


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3.COMPOSITION/INFORMATIONONINGREDIENTS–cont.

* Indicates toxic chemical (s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.

Legend: C CeilingLimit MppcfMillionParticlesperCubicFoot S SkinLimit TWA 8HRTimeWeightedAverage STEL ShortTermExposureLimit4.FIRST-AIDMEASURES

Inhalation Movevictimtofreshair.Giveartificialrespirationifvictimisnotbreathingandseekimmediatemedicalattention.NOTE:Usesupplied-airrespiratorforrescueinenclosedareas.Ifsymptomspersist,callaphysician.

Skin Washskinimmediatelywithsoapandplentyofwater.Removeallcontaminatedclothesandshoes.Avoidrepeatedcontactwithsubstance.Ifskinirritationoccurs,callaphysician.

EyesFlushwithlargeamountsoftepidwaterforatleast15minutes,andseekmedicaladvice.

Callaphysicianimmediately.

IngestionDoNOTinducevomiting.Ifaspirated,materialcancausechemicalpneumonitisorpulmonaryedema.Callaphysicianorpoisoncenterimmediately.Ifpersonisdrowsyorunconsciousandvomiting,placeontheleftsidewithheaddown,andseekimmediatemedicalattention.

5.FIRE-FIGHTINGMEASURESNFPA: Health:2 Flammability:3 Instability:1

FLASHPOINT:-4˚F METHODUSED:TCC FLAMMABLELIMITSINAIRBYVOLUME:LOWER:1.2 UPPER:12.8

SuitableExtinguishingMedia: UseCO2ordrychemicalforsmallfires.Usealcoholtypeaqueousfilmformingfoamforlargefires.

SpecialExposureHazardsArisingfromtheSubstanceorMixture:Underconditionsgivingincompletecombustion,hazardousgasesproducedmayconsistofcarbonmonoxide.Vaporsareheavierthanairandmayspreadalongfloors.Oxidizingchemicalsmayacceleratetheburningrateinafiresituation.IfpotentialforexposuretovaporsorProductsofcombustionexists,wearfullfire-fightingturnoutgearandNIOSHapprovedself-containedbreathingapparatus.

UnusualFireandExplosionHazards:• Pressuremaybuildupintightlyclosedcontainersexposedtofirewhichmay

resultinrupture.• Vaporsmaytravelaconsiderabledistancetoasourceofignitionorcollectinlowareas.


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5.FIRE-FIGHTINGMEASURES–cont.EnvironmentalPrecautions: Dikeandcollectwaterusedtofightfire.

AdviceforFirefighters:• Wearself-containedbreathingapparatus.• Wearfullchemicalprotectiveclothing.• Wearpositivepressureself-containedbreathingapparatus(SCBA).• Keeponlookersaway.• Dikerunofftoprevententryintosewers,stormdrainsandwatercourses.• USECAUTIONAFTERFIREISEXTINGUISHED,VAPORSORLIQUIDMAYREIGNITE.• Usewaterspraytocoolcontainersexposedtofire.• NotifyappropriateStateandLocalAgencies.

6.ACCIDENTALRELEASEMEASURES PersonalPrecautions

• Wearappropriateprotectiveclothingincludinggloves.• Userespirator.• Provideventilation.• Onlytouchdamagedcontainersorspilledmaterialwhenwearingappropriateprotective

clothingandgloves.

EmergencyProcedures• ELIMINATEallignitionsources(nosmoking,flares,sparksorflamesinimmediatearea).• Recoverfreeliquidbyshovelingintocontainerusingnon-sparkingtoolsoraddabsorbent

suchassandorearthtospillandsweepup.

EnvironmentalPrecautions:• Diketoprevententryintosewersorsurfacewaters.• Notifyproperauthoritiesifspillcontaminateslandorwaterways.

Cleanup• Storesoakedragsorabsorbentmaterialinairtightcontainerstopreventspontaneous

combustionofmaterial.• Absorbentmaterialsmayemitflammablevapors.• DisposeofinchemicallandfillorincinerateassuringconformitytoallapplicableFederal,

StateandLocalgoverningregulations.

7.HANDLINGandSTORAGEHandling

• Keepcontainersawayfromflame,heatandotherignitionsources–NoSmoking.• Usenon-sparkingalloytoolsandexplosion-proofequipmentforhandling.• BondandgroundequipmentinaccordancewithOSHA29,CFR1910.106andNFPA77,

whentransferringfromonevesseltoanother.• Donotinhalevaporsormists.• UsewithadequateventilationANDweararespirator.


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7.HANDLINGandSTORAGE–cont.

OtherHandlingPrecautions• Emptycontainersretainproductresidueandmaybedangerous.• Donotpressurize,cut,weld,braze,solder,drillorgrindonornearcontainers

whetherfullorempty.• Donotreusecontainerswithoutprofessionalreconditioningandtesting.

Storage• Storeawayfromflame,heat,sparksorothersourcesofignition.• Storeinsideawayfromextremetemperaturevariations.• Protectcontainersfromphysicaldamage.• Keepcontainerstightlyclosedwhennotinuse.• Storeinawell-ventilatedplace.• Donotremovewarninglabelsfromcontainers.

Incompatiblematerialsorignitionsources• Keepawayfromincompatiblematerials,especiallyfoodoranimalfeed.• Keepawayfromflame,heat,sparksorothersourcesofignition.

8.EXPOSURECONTROLS/PERSONALPROTECTION

EngineeringMeasures/Controls:• Usegoodgeneralmechanicalventilationandlocalexhaustadequatetoreducethe

concentrationofvaporsormistsofthelistedhazardousmaterialstobelowtheThresholdLimitValue(s)andtheLowerExplosionLimit.

• Ventilationequipmentmustbeexplosion-proof.

PersonalProtectiveEquipment: Pictograms

Respiratory

• Incaseofinsufficientventilation,wearsuitablerespiratoryequipment;MineSafetyAppliance#475217pressure/demandair-suppliedrespiratororequivalent.

• FollowtheOSHArespiratorregulationsfoundin29CFR1910.134.• UseMineSafetyAppliancerespirator#448849withorganicvaporcartridgeandmist

filter,orequivalent,ifairmonitoringdemonstratesthattheconcentrationoflistedhazardousmaterialsexceedstherecommendedTLV’s.

Eye/Face • Wearsafetygogglesorfullfaceshields,asnecessary.

Hands

• Wearprotectivegloves–chemicallyresistanttype.Skin/Body

• Useimperviousapronorcoverallstopreventcontaminatingstreetclotheswhichmayresultinprolongedexposure.Theuseofheadcapsorhelmetsisrecommended.


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8.EXPOSURECONTROLS/PERSONALPROTECTION–cont.GeneralIndustrialHygieneConsiderations:

• Handleinaccordancewithgoodindustrialhygieneandsafetypractice.• Washthoroughlywithsoapandwaterafterhandlingandbeforeeating,drinking,

orusingtobacco.• Safetyshowerandeyewashshouldbeavailableclosetoworkareas.• Removesaturatedclothingorshoesatonce;launderallusedclothingbeforereuse.

EnvironmentalExposureControls:• Followbestpracticeforsitemanagementanddisposalofwaste.Avoidreleasetothe

environment.

9.PHYSICALANDCHEMICALPROPERTIES

BOILINGRANGE: 134˚F-241˚F SPECIFICGRAVITY: 1.00 VAPORDENSITY: Heavierthanair EVAPORATIONRATE: Slowerthanether. COATINGVOC: 4.94lb/gal MATERIALVOC: 4.94lb/gal

ORGANICSOLVENT,PERCENTBYWEIGHT: 59.05 ORGANICSOLVENT,PERCENTBYVOLUME: 71.69

COATINGDENSITY,LB/GAL: 8.4 SOLUBILITYINWATER: Insoluble APPEARANCEandODOR: Viscous,opaqueliquidwithapaintthinner-likeodor.10.STABILITYANDREACTIVITY

Reactivity:• Nodangerousreactionknownunderconditionsofnormaluse.

ChemicalStability:• Stableundernormaltemperaturesandpressures.

PossibilityofHazardousReactions:• Hazardouspolymerizationwillnotoccur.

ConditionstoAvoid:• Sourcesofignition.• Poorventilation• Corrosiveatmosphere• Liquidswhichmaydamagecontainers.

IncompatibleMaterialstoAvoid:• Oxidizingagents,strongacidsandbases.

HazardousDecompositionorBy-Products:• Incaseoffire,carbondioxide,carbonmonoxideandothertoxicgasesmaybeproduced.

11.TOXICOLOGICALINFORMATION

TargetOrgans: CentralNervousSystem(CNS)

RoutesofEntryExposure: Inhalation,Skin,Eye,Ingestion


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11.TOXICOLOGICALINFORMATION–cont.

Carcinogenicity: NTP:NoIARCMONOGRAPHS:YesOSHAREGULATED:No

SubstancesClassifiedbyIARC(InternationalAgencyforResearchonCancer): CAS#9003-22-9PolyvinylChloride-PolyvinylAcetateCopolymer:3

PotentialHealthEffects:Inhalation

Acute(Immediate) Breathinghighconcentrationsofaerosolsormistsofthismaterialmaycausenauseaandirritationofthenose,throat,andrespiratorytract.Acuteoverexposuretosolventfumesduringairdryingofthisproductmaycauseheadache,dizziness,nausea,andlossofcoordination.Severeoverexposuremayproduceanesthesiaorunconsciousness.

Chronic(Delayed)Chronicoverexposuretosolventfumesmaycausecentralnervoussystemdamage.

Skin Acute(Immediate) Skincontactmaycauseskinirritationandredness. Chronic(Delayed) Longtermskinexposuremaydryanddefattheskincausingcracking,andinsevere casesdermatitis.

Eye Acute(Immediate) Eyecontactmaycauseirritation,redness,tearingandblurredvision. Chronic(Delayed) Nodataavailable.

Ingestion Acute(Immediate) Ingestioncancausegastrointestinalirritation,vomiting,nausea,anddiarrhea. Chronic(Delayed) Nodataavailable.MedicalConditionsGenerallyaggravatedbyexposure: Overexposuretosolventfumesmayaggravateanesthesia,respiratorytract

diseaseorpre-existinglungdisorders,nauseaandvomiting.

12.ECOLOGICALINFORMATION(1)MIBK–CAS#108-10-1: Toxicitytofish: LC50(Daniorerio(zebrafish))96hours:>100mg/l;statictest. (literaturevalue)

Toxicitytoaquatic EC50(Daphniamagna(Waterflea))48hours:>100mg/l;statictest. Invertebrates: (literaturevalue)

Toxicitytoalgae: Nodataavailable.

Chronictoxicityto NOEC(Daphniamagna(Waterflea))21d:>10–100mg/l;semi-statictest; Aquatic OECDTestGuideline211.Invertebrates: (literaturevalue)

Biodegradation: Readilybiodegradable. OECDTestGuideline301F(28d):>60%. (literaturevalue)

Bioaccumulation: Nobioaccumulationistobeexpected(LogPOW<=4).


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12.ECOLOGICALINFORMATION–cont.

(1)MIBK–CAS#108-10-1–cont.: Mobilityinsoil: Nodataavailable.

Otheradverseeffects: Thissubstanceisnotconsideredtobepersistent,bioaccumulatingnortoxic(PBT).(2)Toluol–CAS#108-88-3:

ChroniceffectCarcinogenicity:

ACGIH: A4-NotclassifiableasaHumanCarcinogen.OSHA: Possibleselectcarcinogen.IARC: Group3carcinogen.Epidemiology: Notavailable.Teratogenicity: Teratogeniceffectshaveoccurredinexperimentalanimals.ReproductiveEffects:Adversereproductiveeffectshaveoccurredinexperimentalanimals.Neurotoxicity: Notavailable.Mutagenicity: Notavailable.Ecotoxicity: LC50(96hr.).Fish: 7.3～22.8mg/lEC50(48hr.).Waterflea: Bioconcentrationfactor(BCF):1.67～380.

(3)VINYLCHLORIDE–VINYLACETATE–MALEICACIDPOLYMER–CAS#9003-22-9:

• Persistence and Degradability: No data available. • Bioaccumulative Potential: No data available.

13.DISPOSALCONSIDERATIONS

√STOREsoakedragsorabsorbentmaterialinairtightcontainerstopreventspontaneouscombustionofmaterial.

√Absorbentmaterialsmayemitflammablevapors.Disposeofinchemicallandfillorincinerateassuringconformitytoallapplicablelocal,StateandFederalgoverningregulations.

14.TRANSPORTINFORMATIONAdditionalHazardousMaterialInformation:

SHIPPINGINFORMATION: UN/NAIDNo.: UN1263 DOTHazardClass: 3(FlammableLiquid) PackingGroup: II DOTHazardousMaterialProperShippingName: FlammableLiquid,Paint

15.REGULATORYINFORMATIONShownherearethestatutesandregulationsthatcoverallofthecomponentsshownunderSection3ofthisSDSwithanasterisk.

I.UNITEDSTATESEPASARATitleIII:HazardousComponents

TheEmergencyPlanningandCommunityRight-to-Know(EPCRA)of1986,alsoknownasSARATitleIII,establishesemergencyplanningandreportingforindustryandgovernment,andgivescommunitiesthenecessarytoolsforplanningandrespondingtothepotentialreleaseofhazardouswaste.


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15.REGULATORYINFORMATION–cont.

Definitionofterms:

SARA SuperfundAmendmentsandReauthorizationActof1986TitleIII(EmergencyPlanningandCommunityRight-to-KnowActof1986)passedOctober17,1986.SARAamendstheCERCLA,orSuperfund.

CERCLA ComprehensiveEnvironmentalResponse,CompensationandLiabilityActpassedbytheU.S.Congressin1980tohelpsolvetheproblemsofhazardouswastesites.

SARA §302–ExtremelyHazardousSubstances(EHS)withthresholdplanningquantity(TPQ)listedinpounds. *indicates10000LBTPQifnotvolatile.

Components CAS# ComponentEHS ComponentTPQ

MethylIsobutylKetone- 108-10-1 Nochemicalsinthismaterialaresubjecttothe MIBK reportingrequirementsofSARA§302SARA §304–CERCLAReportable+§302withReportableQuantity(RQ).

**indicatesstatutoryRQ.

Components CAS# TypicalValue ComponentRQ

MethylIsobutylKetone- 108-10-1 5,000Lb. 100% MIBKSARA §110-SuperfundSitePriorityContaminantList

NoneoftheingredientsinourSec.3arelistedfor§110.

II.U.S.EPASARATitleIIIHazardCategories§311/312:HazardCategories

ThematerialmeetstheEPA‘HazardCategories’definedforSARATitleIIISections311/312 asindicated:

ChemicalName CASNo.MethylIsobutylKetone- 108-10-1 [X]Yes[]No Acute(immediate)HealthHazardMIBK [X]Yes[]No Chronic(delayed)HealthHazard

[X]Yes[]No FireHazard[]Yes[X]No ReactiveHazard[]Yes[X]No SuddenReleaseofPressureHazard

Toluol 108-88-3 Notlistedfor§311/312.

VinylChloride-VinylAcetate- 9003-22-9 Notlistedfor§311/312.MaleicAcidPolymer

SARA §313–ToxicReleaseInventory(TRI):-Catindicatesamemberofachemicalcategory. Components CAS# TypicalValue

MethylIsobutylKetone-MIBK 108-10-1 <=100.0%

Toluol 108-88-3 Notlistedfor§313.

VinylChloride-VinylAcetate- 9003-22-9 Notlistedfor§313.MaleicAcidPolymer

SARA §355–ExtremelyHazardousSubstances. Components CAS# TypicalValue NoingredientsinSec.3listedfor§355.


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15.REGULATORYINFORMATION–cont.III.U.S.EPATOXICSUBSTANCESCONTROLACTof1976(TSCA):

Components CAS# TypicalValue MethylIsobutylKetone 108-10-1 Notlisted.

Toluol 108-88-3 Notlisted.

VinylChloride-VinylAcetate- 9003-22-9 SubstanceislistedforTSCA.MaleicAcidPolymer

IV.COMPREHENSIVEENVIRONMENTALRESPONSE,COMPENSATIONandLIABILITYACT(CERCLA)passedbyU.S.Congress

in1980:Components CAS# TypicalValue ComponentRQ

NoingredientsinSec.3listedV.OSHAHAZARDCOMMUNICATIONSTANDARD,29CFR1910.1200: Components CAS# Listed NoingredientsinSec.3listed VI.CARCINOGENICCATEGORIES,EPA,,TLV(ThresholdLimitValueestablishedbyACGIH),NIOSH-Ca,OSHA-Ca: Components CAS# Listed NoingredientsinSec.3listedVII.U.S.STATEREGULATIONS: ChemicalsassociatedwiththeproductwhicharesubjecttothestateRight-To-KnowRegulations,listedwiththe applicablestate(s): ---------ListedonStateRight-To-Know---------- Component CASNo. PA NY NJ IL MA MN RI FL

MethylIsobutylKetone108-10-1 YES

Toluol 108-88-3 YES NO YES NO YES YES NO YES(methylbenzene)

VIII.CALIFORNIAPROPOSITION65(SafeDrinkingWaterandToxicEnforcementActof1986):

ChemicalName CASNo. ListedMIBK 108-10-1 NowarningshownonMIBKSDS.

Toluol 108-88-3 WARNING:ThisproductcontainsToluene,achemicalknowntothestateofCaliforniatocausebirthdefectsorotherreproductiveharm.

VinylChloride-Vinyl 9003-22-9 PVCresincontainsminoramounts(<1ppmonaverage;0.0001%)ofAcetate-MaleicAcid residualvinylchloridemonomer.Vinylchloride,CAS#75-01-4,islistedPolymer asacarcinogenunderProposition65.

CarbonBlackpigment 1333-86-4 WARNING!ThisproductcontainsachemicalknowntotheStateof Californiatocausecancer.


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15.REGULATORYINFORMATION–cont.VIX.INTERNATIONALREGULATIONS:

A.Chemicalsassociatedwiththeproductarelistedonthechemicalinventoriesofthefollowingcountriesorqualifies asanexemption:

-------------------------------------Components----------------------------------------- MIBK TOLUOL VINYLCHLORIDE- VINYLACETATE- MALEICACIDPOLYMER CAS# CAS# CAS# 108-10-1 108-88-3 9003-22-9

Australia InventoryofChemicalSubstances(AICS) YES Japan InventoryofExistingand NewChemicalSubstances(ENCS) YES Japan IndustrialSafety&HealthLaw(ISHL)Inventory YESCanada DomesticSubstancesList (DSL)Inventory YES YES YES Canada Non-DomesticSubstance Listing(NDSL) NO YES NOEuropean InventoryofExisting CommercialChemical Substances(EINECS) YES PhilippinesInventoryofChemicals/ ChemicalSubstances(PICCS) YES Korea ExistingChemicalsInventory (KECI) YES B.WHMISClassification: Components CAS# Listed MIBK 108-10-1 ClassB,Division2:FlammableLiquid ClassD,Division2,SubdivisionA:Verytoxicmaterial ClassD,Division2,SubdivisionB:Toxicmaterial

Toluol 108-88-3:

EuropeanLabelinginAccordancewithECDirectives

HazardSymbols:XNF

RiskPhrases:R10Flammable.

R20Harmfulbyinhalation.

SafetyPhrases:S9Keepcontainerinawell-ventilatedplace.S16Keepawayfromsourcesofignition-Nosmoking.S25Avoidcontactwitheyes.S29Donotemptyintodrains.S33Takeprecautionarymeasuresagainststaticdischarges.


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15.REGULATORYINFORMATION–cont.B.WHMISClassification–cont.: Components CAS# ListedToluol–cont. 108-88-3:

WGK(WaterDanger/Protection)CAS#108-88-3:2

UnitedKingdomOccupationalExposureLimitsCAS#108-88-3:OES-UnitedKingdom,TWA50ppmTWA;191mg/m3TWA.CAS#108-88-3:OES-UnitedKingdom,STEL150ppmSTEL;574mg/m3STEL.

CANADACAS#100-42-5islistedonCanada’sDSL/NDSLlist.ThisproducthasaWHMISclassificationofB2,D2A(99%)/B3,D2A(100%).CAS#105-05-5isnotlistedonCanada’sIngredientDisclosureList.

16.OTHERINFORMATIONHMISIIIrating:

Health:2Flammability:3Reactivity:0PhysicalHazard:C&HHMISIIIusesanumberingscalerangingfrom0to4toindicatethedegreeofhazard.Avalueof0meansthatthesubstancepossessesessentiallynohazard;aratingof4indicatesextremedanger.TheHMISIIIsystemwasdesignedtocommunicateworkplacehazardinformationtoemployeeswhohandlehazardouschemicals.

SDSPreparedBy: Pruett-SchafferChemicalCorporation

LastRevisionDate: December31,2015PreparationDate:December31,2015

Disclaimer/StatementofLiability

●Theinformationandrecommendationscontainedhereinarepresentedingoodfaithandbelievedtobeaccurate.Itisprovidedforyourguidanceonly.NOWARRANTIESOFANYKIND,EITHEREXPRESSEDORIMPLIED,AREMADEREGARDINGPRODUCTSDESCRIBED,DATAORINFORMATIONPRESENTED,ORTHATTHEPRODUCTS,DATAORINFORMATIONMAYBEUSEDWITHOUTINFRINGINGONTHEINTELLECTUALPROPERTYRIGHTSOFOTHERS.Pruett-SchafferChemicalCorporationmakesnowarrantyconcerningtheaccuracyoftheinformationcontainedhereinandwillnotbeheldliableforclaimsrelatingtoanyparty’suseoforrelianceoninformationcontainedherein.Dataandcalculationsarebasedoninformationfurnishedbythemanufactureroftheproductandmanufacturersofthecomponentsoftheproduct.Usersareadvisedtoconfirminadvanceofneedthatinformationiscurrent,applicableandsuitedtothecircumstanceofuse.Vendorassumesnoresponsibilityforinjurytovendeeorthirdpersonsproximatelycausedbythematerialifreasonablesafetyproceduresarenotadheredtoasstipulatedinthedatasheet.Furthermore,Pruett-SchafferChemicalCorporationassumesnoresponsibilityforinjurycausedbyabnormaluseofthismaterialevenifreasonablesafetyproceduresarefollowed.AnyquestionsregardingthisproductshouldbedirectedtothemanufactureroftheproductasdescribedinSection1.

KeytoabbreviationsNDA=Nodataavailable.

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PRUETT-SCHAFFER CHEMICAL COMPANY - Calbond€¦ · PRUETT-SCHAFFER CHEMICAL COMPANY Page 2 of 14 2. HAZARDS IDENTIFICATION – cont. GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910