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PROSPEKTING BIOMASSA
improving, adding and finding further value of biomass
Kontrak PerkuliahanDosen:Masruri, S.Si., M.Si., PhDSiti Mariyah Ulfa, S.Si., M.Sc., D.Sc.
Syllabus description:• This course will explore potential natural resources especially
carbohydrate, protein, oil and lipids as sources for fine chemical or other functional material. This will include understanding on recent methods for chemical and catalytic transformation, and method for analysis.
• The ourse requires 14 weeks class session and 2-session writtingexamination (UTS, UAS)
Assessment:• Student task-1 (Presentation and Review/Writing Essay) = 20%• Student task-2 (Presentation and Review/Writing Essay) = 20%• Mid-term test = 30%• End-term test = 30%
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Kontrak PerkuliahanMaterial:• Introduction (natural resources from forest, plants, grass, etc)• Biomass contains carbohydrate• Biomass contains protein• Biomass contain oils, lipids• Biomass separation and application• Transformation of carbohydrate into fine chemical source• Transformation of protein into fine chemical and material• Transformation of oil and lipid into fine chemical and material• Analysis of carbohydrate and its transformation products• Analysis of protein and its transformation products• Analysis of oil and lipids and its transformation products
References:• Avelino Corma,* Sara Iborra, and Alexandra Velty, Chemical Routes
for the Transformation of Biomass into Chemicals, Chemicals Review, 2007, 107, 2411-2502
• Beberapa jurnal
DEFINISI
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STRATEGI
Gallezot, P., Conversion of biomass to selected chemical products, Chemical Society Review, 2011, DOI: 10.1039/c1cs15147a
Conversion via Platform Molecule
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Conversion via Platform Molecule
J. J. Bozell and G. R. Petersen, Green Chem., 2010, 12, 539.
Conversion via Platform Molecule
Chemo-catalytic process: efficiency, selectivity
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Conversion via Platform Molecule
Chemo-catalytic process: efficiency, selectivity
Conversion via Platform Molecule
Chemo-catalytic process: efficiency, selectivity
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Conversion via Platform Molecule
Gallezot, P., Conversion of biomass to selected chemical products, Chemical Society Review, 2011, DOI: 10.1039/c1cs15147a
STRATEGI
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Conversion Biomass to End Products
Conversion Biomass to End Products
Epoxidation of fatty ester and oxiran ring opening (a) with alcohols; (b) with acids
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Conversion Biomass to End Products
Plasticisers obtained by methanolysis, epoxidationand acylation of vegetable oils
G. Fogassy, P. Ke, F. Figueras, P. Cassagnau, S. Rouzeau, V. Courault, G. Gelbard and C. Pinel, Appl. Catal., A, 2011, 393, 1.
Conversion Biomass to End Products
4.1 Conversion of triglyceride to oleochemicals
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Conversion Biomass to End Products
Conversion Biomass to End Products
Many others left for the next prospecting
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Biomass further perspective
Brehmer, Chemical biorefinery perspective, PhD thesis, Wageningen University, Netherland, 2008