Proposed Syllabus for B.Sc.-Chemical Science at GSFC ... Ch.pdf · L T P Theory Practical 1 BSC3CH01 Chemistry - V Core Organic Chemistry – II 3 2 5 100 50 150 2 BSC3CH02 Chemistry

Proposed Syllabus for B.Sc.-Chemical Science at GSFC University

(Chemistry as a principal subject)

Course Structure

B. Sc. (Chemical Science), Semester-I

Sr. No.

Course Code

Course Type of Course

Subject Teaching hours per week

Credit Examination Scheme

Total Marks

L T P Theory Practical

1 BSC1CH01 Chemistry - I Core General Chemistry 3 2 5 100 50 150

2 BSC1CH02 Chemistry - II Core Organic Chemistry-I 3 2 5 100 50 150

3 BSS1PH01 Physics – I Subsidiary Mechanics& Heat And Thermodynamics

4 2 6 100 50 150

4 BSS1MA01 Mathematics - I Subsidiary Linear Algebra 4 1 4 100 100

5 BSF1EN01 Functional English-I Foundation 2 1 2 100 100

6 BSF1IT01 Information and Communication Technology-I

Foundation 2 1 - 2 100 100

Total Contacts hrs. per week: 30 Total Credit: 24 Total Marks: 750

Industrial Internship / Industrial Training Module of 2 Credit (100 Marks) Course will be introduced at the end of an academic session/Term

B. Sc. (Chemical Science), Semester-II

Sr. No

.

Course Code Course Type of Course

Subject Teaching hours per week

Credit Examination Scheme Total Marks


1 BSC2CH01 Chemistry – III Core Inorganic Chemistry-I

3 2 5 100 50 150

2 BSC2CH02 Chemistry – IV Core Physical Chemistry-I 3 2 5 100 50 150

3 BSS2PH01 Physics-II Subsidiary Optics -1 and Electricity & Magnetism

4 2 6 100 50 150

4 BSS2MA01 Mathematics – II Subsidiary Vector Calculus &Ordinary Differential Equations

4 1 0 4 100 100

5 BSF2EN02 Functional English-II

Foundation 2 1 2 100 100

6 BSF2IT02 Information and Communication

Technology-II

Foundation 2 1 - 2 100 100



B. Sc. (Chemical Science), Semester-III

Sr. No

.

Course Code Course Type of Course

Subject Teaching hours per

week


Total Marks


1 BSC3CH01 Chemistry - V Core Organic Chemistry – II 3 2 5 100 50 150

2 BSC3CH02 Chemistry - VI Core Physical Chemistry-II 3 2 5 100 50 150

3 BSE3CH01 Chemistry – VII

Elective Green Chemistry 2 2 50 50

BSE3CH02 Industrial Chemistry

4 BSS3PH01 Physics – III Subsidiary Optics And Electronics 4 2 6 100 50 150

5 BSS3MA01 Mathematics – III

Subsidiary Numerical Analysis Graph Theory

4 1 4 100 100

6 BSF3ES01 Environmental Studies

Foundation 2 1 - 2 100 100



B. Sc. (Chemical Science), Semester-IV

Sr. No

.

Course Code



week


Total Marks


1 BSC4CH01 Chemistry – VIII Core Inorganic Chemistry – II

3 2 5 100 50 150

2 BSC4CH02 Chemistry – IX Core Physical Chemistry-III

3 2 5 100 50 150

3 BSE4CH01 Chemistry-X Elective Polymer Science 2 2 50 50

BSE4CH02 Nano Science

4 BSS4PH01 Physics – IV Subsidiary Modern Physics and Statistical

Physics

4 2 6 100 50 150

5 BSS4MA01 Mathematics - IV

Subsidiary Integral Calculus Linear

Programming Problem

4 1 4 100 100

6 BSF4CA01 Computer Application

Foundation 2 1 2 100 100



B. Sc. (Chemical Science), Semester-V

Sr. No

.

Course Code



week


Total Marks


1 BSC5CH01 Chemistry – XI Core Organic Chemistry – III 3 2 5 100 50 150

2 BSC5CH02 Chemistry – XII

Core Physical Chemistry-IV 3 2 5 100 50 150

3 BSC5CH03 Chemistry- XIII Core Inorganic Chemistry – III 3 2 5 100 50 150

4 BSC5CH04 Chemistry-XIV Core Physical Chemistry-V 3 3 100 100

5 BSC5CH05 Chemistry-XV Core Inorganic Chemistry – IV 3 3 100 100



B. Sc. (Chemical Science), Semester-VI

Sr. No

.

Course code



week


Total Marks


1 BSC6CH01 Chemistry – XVI Core Organic Chemistry – IV

3 2 5 100 50 150

2 BSC6CH02 Chemistry – XVII Core Physical Chemistry-VI 3 2 5 100 50 150

3 BSC6CH03 Chemistry-XVIII Core Inorganic Chemistry – V

3 2 5 100 50 150

4 BSC6CH04 Chemistry- XIX Core Analytical Chemistry 3 3 100 100

5 BSF6CA02 Application of Computer in

Chemistry

Foundation Computer Applications

2 1 2 100 100



Sr. Semester Credits Total Marks

1 Semester – I 24 750

2 Semester – II 24 750

3 Semester – III 24 700

4 Semester – IV 24 700

5 Semester – V 21 650

6 Semester – VI 20 650

7 Industrial Internship 12 600

Total Credits and Marks 149 4800

CourseTitle FunctionalEnglish–I

CourseCode BSF1EN01

CourseCredits L T P Credits

2 1 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I:BASIC

Articles,Prepositions,Degreesofcomparison,Tenses;KindsandUses,ActiveandPassiveVoice,PhrasesClausesandSentences,Kindsofsentences,ReportedSpeech.

(12Lectures)UNIT-II:BASICCOMPOSITION

ParagraphWriting,BusinessCorrespondence,OfficialReports(07Lectures)

UNIT-III:BASICPHONETICS

TheProductionofSpeech,TheSoundsofEnglish,PhoneticTranscription,SyllableandStress,Intonation

(08Lectures)UNIT-IV:BASICCONVERSATION

Englishinuse,Englishforroutinecommunicativefunctions,Speechpractice

(03Lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:

1.MurphyR.,IntermediateEnglishGrammar:ReferenceandPracticeforSouthAsianStudents,CambridgeUniversityPress,2001.2.ThakerP.K.,DesaiS.andPuraniT.J.(eds),DevelopingEnglishSkills:ACompositeCourseforIntermediateStudents,OxfordUniversityPress,1997.3.MohanK.andBanerjiM.,DevelopingCommunicationSkills,Mc.MillanCo.Publication1990.4.KrishnaswamiNandSriram T.,CreativeEnglishforCommunication,Mc.MillanCo.Publication1992.5.BoardofEditors,WrittenandSpokenCommunicationinEnglish,UniversityPressPrivateLimited,

CourseTitle GeneralChemistryCourseCode BSC1CH01


3 0 2 5

Prerequisites Studentsshouldhavebasicknowledgeofchemistryupto10+2level.

Courseobjectives

CourseContents UNIT-I: STRUCTURE OF ATOM, ELECTRONIC STRUCTURE,CHEMICALBONDINGANDSTATESOFMATTER

Chemistry:Thestudyofchange,theatomictheory,structureoftheatom,atomicnumber,massnumber,andIsotopes,periodictable,periodicity,moleculesandIons,atomicmass,Avogadro’snumber,molarmassofanelement,molecularmass,typesofbonds:ionic,covalent,polarandnon-polarcovalentbonds,metallicbonds,non-covalentinteractions;theoriesofbonding:valencebondtheory,hybridization,moleculargeometry,introductiontomolecularorbitaltheory,MOdiagramsofsimplediatomicmolecules;intermolecularforces,gases,liquids,propertiesofsolutions,reactionsinaqueoussolutions.

(20Lectures)

UNIT-II: MACROMOLECULES AND ADVANCES INNANOCHEMISTRY

Methods of polymerization, Characterization by TGA, DTA,Molecularweightanditsdetermination,amorphousandcrystallinepolymers,biopolymers,structure-property relation in polymers.Introduction,Basicstructuralfeaturesandtypesofcarbohydrates,Reactions and conversions, role in biological systems;nanochemistry,smartmaterials,andtheirapplications,

(08Lectures)

UNIT-III:INTRODUCTIONTOORGANICCHEMISTRY

Introduction to organic chemistry,types offunctionalgroups,nomenclatureoforganiccompounds,relationshipbetweenshapesand properties of organic molecules, isomerism andconformationalanalysisofalkanesandcycloalkanes,relativeandabsolute configuration,sequence rules,D and L systems ofnomenclatureandRandSsystemsofnomenclature,Geometricisomerism –determinationofconfigurationofgeometricisomersEandZsystemsofnomenclature,geometricisomersofoximesand alicylic compounds; reactive intermediates-free radical,carbonium ion,carbanion,carbenesandarynes.Electrophilesandnucleophiles.Typesoforganicreactions-Stepwise,ionicandfreeradicalmechanisms,concertedmechanism,addition,substitution,elimination and rearrangement,basic features of pericyclic

reactions.,Enantiomers,molecularchirality,diastereomers,threoand erythro diastereomers,meso compounds,resolution ofenantiomers, retention and racemization. Linear and cyclicconjugation, benzene, aromaticity, properties of conjugatedsystems.Environmentallybenignchemistry,Interfaceofchemicalsciences with otherdisciplines,particularly in technology andmedicalsciencesandengineering.

(17Lectures)

Courseoutcomes

TextandReferences

1.ChawlaS..,“TextBookofEngg.Chemistry”,DhanpatRai&Co.Pvt.Ltd.,Delhi,2003.

2.AdamsonA.W.,“PhysicalChemistryofSurfaces”,3rdEdn.,JohnWiley,1976.

3.MorrisonR.T.andBoydR.N.,“OrganicChemistry”,6thEdn.,PrenticeHall,1992.

4.SolomonsT.W.G.,“FundamentalsofOrganicChemistry”,5thEdn.,JohnWiley,1992.

5.Streitwieser,Jr.A.andHeathcockC.H.,“Introductiontoorganicchemistry”2ndEdn,MacMillan,NewYork,19986.Lee,J.D.ConciseInorganicChemistry,ELBS,1991.

CourseTitle Information&CommunicationTechnology–I

CourseCode BSF1IT01


2 0 0 2

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:LearningEssentialComputerSoftwares:MicrosoftOfficeToolsWord:Creating,Formatting,Savingdocumentsindifferenttypesanddestinations,identifyingandconvertingfiletypeslike.doc,.pdf,.rtfetcPowerPoint:Preparationofpowerpointslides,editing

andformattingslidesandmakingPPTpresentationExcel:PreparingExcelWorkbooksandlearningitsvariousfunctions.

(10Lectures)

UNIT-II:CommunicationTechnologiesE-mail:Writinge-mailstosingleandmultipleusers,Attachingafile,MarkingCCandBCC,Creatingexclusivecommunicationgroups.LCDProjectors:UsingLCDprojectorsformakinganaudio-visualpresentationTele/VideoConferencingBloggingandchattingFaxandMobiles

(10Lectures)

UNIT-III:InternetUsageforE-learningIntroductiontoInternetandWebBrowsersSearchenginestolocateinformation,savingwebpages,downloadingfiles,(pdf,mp3etc)andsoftwareOpenlearningsites-Wikipedia,Wikispaces,Wikieducatoretc.OpenFreewares-HotPotatoes,Audacity,andWida.co.ukAdvancedSocialNetworkingWebpagebuildingwithtailor-madewebsitebuildersprovidedfreebywebsiteslikegoogle.com &webs.com

(10Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.IGCSE, Information and Communication Technology,

G.BrownandD.WatsonHodderEducation2015.

2.Information and Communication Technology,H.F.Cline,

HodderEducation2015.

3.IGCSE, Information and Communication

Technology,D.Spencer,F.Heathcote,Oxford,2015.

CourseTitle Mathematics-ICourseCode BSS1MA01


4 1 0 4

Prerequisites --

Courseobjectives

CourseContents Unit-1:

Trigonometryand itsidentities,inversetrigonometricfunctions,

Conceptofa limitand functions,Continuityand derivative of

elementaryfunctions,Rulesofdifferentiation(withoutproof).

(10lectures)

Unit-2:

Chain rule (withoutproof),differentiation ofimplicitfunctions,

succesivedifferentiation,Indeterminateforms,Indeterminentform

0/0, / ,0 , . L.Hospital’s rules, Applicationsof

Derivatives: maxima and minima,Concavity/ convexity ofa

function.

(18lectures)

Unit3:

Standard integration formulae,Integration by the method of

substitution,Integration byparts,Integrationbythemethodof

partialfractions,definite integration,fundamentaltheorem of

calculusApplicationsofIntegrations:Areaandvolume.

(12lectures)

Unit4:

Functionofseveralvariables,Limitandcontinuityoffunctionof

severalvariables,partialderivativesoffunctionoftwovariables,

Totaldifferential,Chainrule,implicitdifferentiation,Euler’stheorem

forhomogeneousfunction,ApplicationsofPartialDerivatives :

Tangentplane,Normalline,Linearapproximation,Maximum and

minimum valuesbysecondderivativetest,Lagrange’smethodof

multipliers,Taylor’sformulafortwovariables.

(20lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:1.ShantiNarayan,IntegralCalculus,S.Chand&Co.Ltd,1999.

2.V.M.Shah,IntroductoryCalculus,AcharyaBookDepot,1980.

3.ErwinKreyszig,AdvancedEngineeringMathematics,John

WileyandSonsInc,1983.

4.G.B.ThomasJr.andR.L.Finney,CalculusandAnalytic

Geometry,Addison-WesleyPublishers,1999.8.David V.

Widder,AdvancedCalculus,Prentice-HallofIndia,1989.

5.T.M.Apostol, Calculus,Volumes2,WileyEastern.6.LinearAlgebraanditsApplications,DavidC.Lay,PearsonEducation.

CourseTitle OrganicChemistry-ICourseCode BSC1CH02


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:BASICSOFORGANICCHEMISTRY

Organic Compounds: Classification, and Nomenclature,Hybridization,Shapesofmolecules,Influenceofhybridizationonbondproperties.ElectronicDisplacements:Inductive,electromeric,resonance and mesomeric effects,hyperconjugation and theirapplications;Dipolemoment;Organicacidsandbases;theirrelativestrength.HomolyticandHeterolyticfissionwithsuitableexamples.Curlyarrow rules,formalcharges;ElectrophilesandNucleophiles;Nucleophlicityandbasicity;Types,shapeandtheirrelativestabilityof Carbocations, Carbanions, Free radicals and Carbenes.Introductiontotypesoforganicreactionsandtheirmechanism:Addition, Elimination and Substitution reactions.

(13Lectures)UNIT-II:STEREOCHEMISTRY

FischerProjection,NewmannandSawhorseProjectionformulae

andtheirinterconversions;Geometricalisomerism:cis–transand,

syn-antiisomerism E/ZnotationswithC.I.Prules.

Optical Isomerism: Optical Activity, Specific Rotation,Chirality/Asymmetry,Enantiomers,Molecules with two ormorechiral-centres,Distereoisomers,mesostructures,racemicmixtureandresolution.Relativeandabsoluteconfiguration:D/LandR/Sdesignations.

(10Lectures)

UNIT-III:CHEMISTRYOFSATURATEDHYDROCARBONS

Chemistryofalkanes:Formationofalkanes,WurtzReaction,Wurtz-FittigReactions,Freeradicalsubstitutions:Halogenation-relativereactivityandselectivity.Typesofcycloalkanesandtheirrelativestability,Baeyerstraintheory,Conformationanalysisofalkanes:Relativestability:Energydiagramsofcyclohexane:Chair,BoatandTwistboatforms;Relativestabilitywithenergydiagrams.

(10Lectures)

UNIT-IV:CHEMISTRYOFUNSATRUATEDHYDROCARBONSFormation of alkenes and alkynes by elimination reactions,

Mechanism ofE1,E2,E1cb reactions.Saytzeffand Hofmann

eliminations.Reactions ofalkenes:Electrophilic additions their

mechanisms (Markownikoff/ AntiMarkownikoff addition),

mechanism of oxymercuration-demercuration, hydroboration-

oxidation,ozonolysis,reduction(catalyticandchemical),synand

anti-hydroxylation (oxidation).1,2-and 1,4-addition reactions in

conjugateddienesand,Diels-Alderreaction;Allylicandbenzylic

brominationandmechanism,e.g.propene,1-butene,toluene,ethyl

benzene. Reactions of alkynes: Acidity, Electrophilic and

Nucleophilic additions.Hydration to form carbonylcompounds,

Alkylationofterminalalkynes.

(12Lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:1.Morrison,R.N.& Boyd,R.N.OrganicChemistry,Dorling

Kindersley(India)Pvt.Ltd.(PearsonEducation).2.Finar,I.L.OrganicChemistry(Volume1),DorlingKindersley

(India)Pvt.Ltd.(PearsonEducation).3.Finar,I.L.OrganicChemistry(Volume2:Stereochemistry

andtheChemistryofNaturalProducts),DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

4.Eliel,E.L.& Wilen,S.H.Stereochemistry ofOrganicCompounds;Wiley:London,1994.

5.Kalsi,P.S.StereochemistryConformationandMechanism;NewAgeInternational,2005.

CourseTitle Physics–ICourseCode BSS1PH01

CourseCredits

L T P Credits

4 0 2 6

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:MOTIONUNDERCENTRALFORCE:

Motionunderacentralforce,Conservationofangularmomentum,Kepler’slaws,GravitationalFieldandpotentialduetosphericalbodies,GaussandPoisson equations,Gravitationalself-energy,Two-body problem;Reduced mass,scattering byhard spheres,Centre ofmass andlaboratoryreferenceframes,Collisionsin2D&3D,Calculationoffinalvelocitiesofcollidingparticlesandscatteringangle.

(15Lectures) (15Lectures)UNIT-II:MECHANICSOFCONTINUOUSMEDIA:

Elastic constants ofan isotropic solid,Poisson’s ratio,Relationsconnectingtheelasticconstants,DeterminationofYoung’sModulusof a Material,Determination of Poisson’s ratio (σ) of rubber,Dynamicalmethod (Maxwell’s needle) of determination of thecoefficientofrigidity(η)ofawire.Bendingofbeam,BendingMoment,Thecantilever,Determinationof‘Y’ofthematerialofacantilever–casestudy.

(15Lectures)UNITIII:HEAT

Idealgas:Review ofthekinetictheoryofanidealgasmodelofanidealgas;Interpretation oftemperature,equi-partition ofenergy;Atomicityofgasesanditsrelationwithspecificheatsofgases

Realgas:VanderWaalsmodel;Equationofstate,NatureofVanderWaals forces, Critical constants, Mean free path, Transportphenomena,Transportofmomentum (viscosity)ofenergy(thermalconduction)and matter(diffusion),Joule-Thomson and adiabaticcooling;Porousplugexperiment,ConstancyofU+pV,

Liquefactionofgases:Cascadeprocess,Principlesofregenerativecooling,Linde’sprocess

(15Lectures)UNIT-IV:

Otto engine;Otto engine cycle,its efficiency,the second law,Thermodynamicscaleoftemperature,ConceptofEntropy,Entropychangeinreversibleandirreversibleprocesses,Principleofincreaseofentropy,Entropyasathermo-dynamicalbehavior,Maxwell’sthermo-dynamicalequations,itsapplicationtoClausius-Clapeyronequation,Cooling due to adiabatic demagnetization (derivation). Simpleapplications: Black-body radiation: Thermal radiation, Stefan-Boltzmann law,Spectraldistribution,Wien’s displacement law,

Rayleigh-JeansLawandtheultravioletcatastrophe.

(15Lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:1. MechanicsbyD.S.Mathur(SChand&Co.Ltd.,N Delhi,

2006)2.BerkleyPhysicsCourse(Vol.I)AsianStudentEdition3.HeatandThermodynamicsbyBrijlaland

NSubramaniyam (SChand&Co.Ltd,NewDelhi)

4. HeatandThermodynamicsbyA.B. GuptaandH.P.Roy(New

CentralBookAgencyPvt.Ltd.,Kolkata1999)

CourseTitle FunctionalEnglish–II

CourseCode BSF2EN02


2 1 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I:GRAMMARINUSE

TheVerbPhrase;Be,haveanddo;ModalVerbs;InfiniteGerundandParticiples.

(10Lectures)

UNIT-II:CONCEPTSINGRAMMAR

QuestionsandAuxiliaryVerbs;Conditionalsand‘wish’;‘–ing’andtheinfinite;ArticlesandNouns;PronounsandDeterminers;AdjectivesandAdverbs;ConjunctionsandPreposition.

(10Lectures)UNIT-III:ACOURSEINLISTENINGANDSPEAKING

PronunciationandNeutralizationofAccent(10Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:1.Murphy,Raymond,IntermediateEnglishGrammar,2nd

edition,CambridgeUniversityPress,NewDelhi,2007.2.Murthy,J.D.,ContemporaryEnglishGrammar,BookPalace

Publication1998.3.Sasikumar,V.,Dutt,P.K.&Rajeevan,G.,ACoursein

ListeningandSpeaking-I,FoundationBooks,CambridgeUni.PressIndiaPvt.Ltd.,2005.

4.Monippally,M.M,BusinessCommunicationStrategies,TataMcGraw-HillPublishingCom.Ltd.,NewDelhiPublication,2001

5.Eastwood,J.,OxfordGuidetoEnglishGrammar,OxfordUni.Press,NewDelhi,2008.

CourseTitle Information&CommunicationTechnology–II

CourseCode BSF2IT02


2 0 0 2

Prerequisites --

Courseobjectives

CourseContents

UNITI:EffectsofUsingITSoftwarecopyright:IssuesandformalitiesTheproblem ofHackingandpreventivemeasuresComputervirusandAnti-virusEffectofICTonpatternsofemploymentincludingareasofworkwherethereisincreasedunemploymentEffectofmicroprocessor-controlleddevices,inthehomeincludingtheireffectsonleisuretime,socialinteractionetcCapabilityandlimitationofITIssuesrelatedtoinformationfoundonneti.e.unreliability,undesirabilityandthesecurityofdatatransferPotentialhealthproblemsrelatedtoconstantuseofICT,forexample,repetitivestraininjury(RSI),neckandbackproblems,eyeproblemsandsomesimplestrategiesforpreventingtheseproblems.

(18Lectures)

UNITII:GroupProjectStudentsmaybedividedinsmallgroupstoworkonprojectsbasedonthefollowing:APowerPointpresentationbasedonreviewofaWebsiteoftheirchoiceAnexhaustiveblogcreatedonissuesofcurrentsocio-political,cultural,economicrelevanceBuildingawebpageongiventopicswithhyperlinks,jpg,mp3filesetc.

(12Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.IGCSE, Information and Communication Technology,

G.BrownandD.WatsonHodderEducation2015.

2.Information and Communication Technology,H.F.Cline,

HodderEducation2015.

3.IGCSE, Information and Communication

Technology,D.Spencer,F.Heathcote,Oxford,2015.

CourseTitle InorganicChemistry-ICourseCode BSC2CH01


3 0 2 5

Prerequisites --

Courseobjectives

CourseContentsUNIT-I:ATOMICSTRUCTUREANDQUANTUM MECHANICS

Review of:Bohr’stheoryand itslimitations,dualbehaviourofmatterandradiation,deBroglie’srelation,HeisenbergUncertaintyprinciple.Hydrogen atom spectra.Need ofanew approach toAtomicstructure.WhatisQuantum mechanics?TimeindependentSchrodinger equation and meaning of various terms in it.Significanceofψandψ2,Schrödingerequationforhydrogenatom.Radialandangularpartsofthehydogenicwavefunctions(atomicorbitals)andtheirvariationsfor1s,2s,2p,3s,3pand3dorbitals(Onlygraphicalrepresentation).Radialandangularnodesandtheirsignificance.Radialdistributionfunctionsandtheconceptofthemostprobabledistancewithspecialreferenceto1sand2satomicorbitals. Significance of quantum numbers, orbital angularmomentum andquantum numbersmlandms.Shapesofs,panddatomicorbitals,nodalplanes.Discoveryofspin,spin quantumnumber(s)andmagneticspinquantum number(ms).Rulesforfillingelectronsinvariousorbitals,Electronicconfigurationsoftheatoms.Stabilityofhalf-filledandcompletelyfilledorbitals,conceptof exchange energy. Relative energies of atomic orbitals,Anomalouselectronicconfigurations.

(15Lectures)UNIT-II:CHEMICALBONDING

(i)lonicbond:Generalcharacteristics,typesofions,sizeeffects,radiusratioruleanditslimitations.Packingofionsincrystals.Born-LandéequationwithderivationandimportanceofKapustinskiiexpressionforlatticeenergy.Madelungconstant,Born-Habercycleanditsapplication,Solvationenergy.(ii)Covalentbond:Lewisstructure,ValenceBondtheory(Heitler-Londonapproach).Energeticsofhybridization,equivalentandnon-equivalenthybridorbitals.Bent’srule,Resonanceandresonanceenergy,Molecularorbitaltheory.Molecularorbitaldiagrams ofdiatomicandsimplepolyatomicmoleculesN2,O2,C2,B2,F2,CO,NO,and theirions;HCl,BeF2,CO2,(idea ofs-p mixing and orbitalinteractiontobegiven).Formalcharge,Valenceshellelectronpairrepulsiontheory(VSEPR),shapesofsimplemoleculesandionscontaininglonepairsandbondpairsofelectrons,multiplebonding(σandπbondapproach)andbondlengths.Covalentcharacterinioniccompounds,polarizingpowerandpolarizability.Fajan’srulesand consequences ofpolarization.Ionic characterin covalentcompounds:Bondmomentanddipolemoment.Percentageioniccharacterfrom dipolemomentandelectronegativitydifference.(iii)Metallic Bond:Qualitative idea ofvalence bond and band

theories.Semiconductorsandinsulators,defectsinsolids.(iv)Non-CovalentInteractions:van derWaalsforces,ion-dipoleforces,dipole-dipole interactions,induced dipole interactions,Instantaneousdipole-induceddipoleinteractions.Repulsiveforces,Hydrogenbonding(theoriesofhydrogenbonding,valencebondtreatment)Effectsofchemicalforce,meltingandboilingpoints,solubilityenergeticsofdissolutionprocess.

(15Lectures)UNIT-III:GENERALPROPERTIESOFELEMENTSs,p,d,fblockelements,thelongform ofperiodictable.Detaileddiscussion ofthe following properties ofthe elements,withreferencetos&p-block.

(a)Effectivenuclearcharge,shieldingorscreeningeffect,Slaterrules,variationofeffectivenuclearchargeinperiodictable.

(b)Atomicradii(vanderWaals)(c)Ionicandcrystalradii.(d)Covalentradii(octahedralandtetrahedral)(e)Ionization enthalpy,Successive ionization enthalpies and

factors affecting ionization energy. Applications ofionizationenthalpy.

(f)Electrongainenthalpy,trendsofelectrongainenthalpy.(g)Electronegativity,Pauling’s/ Mulliken’s/ Allred Rachow’s/

and Mulliken-Jaffé’selectronegativityscales.Variation ofelectronegativity with bond order, partial charge,hybridization,groupelectronegativity.Sanderson’selectrondensityratio.

(h)Variable valency and oxidation states,redox-potentials,redoxreactions

(15Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Lee,J.D.ConciseInorganicChemistry,ELBS,1991.2.Douglas,B.E.andMcDaniel,D.H.,Concepts&Modelsof

InorganicChemistry,Oxford,19703.Atkins,P.W.&Paula,J.PhysicalChemistry,OxfordPress,

2006.4.Day,M.C.andSelbin,J.TheoreticalInorganicChemistry,

ACSPublications1962

CourseTitle Mathematics-IICourseCode BSS1MA01


4 1 0 4

Prerequisites --

Courseobjectives

CourseContents Unit1:

Introductiontomatrices,differenttypesofmatrices,Elementary

operationsonmatricesandtypesofmatrices,Symmetricandskew

-symmetricmatrices,Hermitianandskew-Hermitianmatrices.rank

ofamatrix.Row ReducedEchelonform ofamatrixandmatrix

inversionusingit.

(15

lectures)

Unit2:

Homogeneous and Non-homogeneous linear equations.

Applicationofmatricesinsolvingasystem ofsimultaneouslinear

equations.Eigen values,Eigen vectors and the characteristic

equationofamatrix.CayleyHamiltontheorem (withoutproof)and

its use in finding inverse of a matrix.

(15lectures)

Unit-3:

OrdinaryDifferentialEquations,Degreeandorderofadifferential

equation,Equationsoffirstorderandfirstdegree,Equationsin

which variables are separable,Homogeneous equations,Linear

equations and equations reducible to the linearform,Exact

differentialequations,Integratingfactors.Applicationsoffirstorder

equations: Mixtureproblem,Orthogonaltrajectories,Decayand

Growthproblems,Temperatureproblem.

(16lectures)

Unit-4:

Linear differential equations of higher order,Homogeneous

equations,Differentialoperators,Methodofsolvinghomogeneous

equations, Non-homogeneous equations, Inverse operators,

Methods ofsolving non-homogeneous equations.Application:

Cardiography(ECG).

(14

lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:1.ShantiNarayan,IntegralCalculus,S.Chand&Co.Ltd,1999.

2.V.M.Shah,IntroductoryCalculus,AcharyaBookDepot,1980.


WileyandSonsInc,1983.

4.G.B.ThomasJr.andR.L.Finney,CalculusandAnalytic



5.T.M.Apostol, Calculus,Volumes2,WileyEastern.6.LinearAlgebraanditsApplications,DavidC.Lay,PearsonEducation.

CourseTitle PhysicalChemistry-ICourseCode BSC2CH02


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:GASEOUSSTATE

Kineticmolecularmodelofagas:postulatesandderivationofthekineticgasequation;collisionfrequency;collisiondiameter;meanfreepathandviscosityofgases,includingtheirtemperatureandpressure dependence,relation between mean free path andcoefficientofviscosity,calculation ofσ from η;variation ofviscositywithtemperatureandpressure.Maxwelldistributionanditsuseinevaluatingmolecularvelocities(average,rootmean square and mostprobable)and averagekineticenergy,law ofequipartitionofenergy,degreesoffreedomandmolecularbasisofheatcapacities.Behaviourofrealgases:Deviations from idealgas behaviour,

compressibility factor,Z,and its variation with pressure for

differentgases.Causesofdeviationfrom idealbehaviour.Vander

Waalsequationofstate,itsderivationandapplicationinexplaining

realgasbehaviour,mentionofotherequationsofstate(Berthelot,

Dietrici);virialequationofstate;vanderWaalsequationexpressed

invirialform andcalculationofBoyletemperature.Isothermsof

realgasesandtheircomparisonwithvanderWaalsisotherms,

continuity of states,critical state,relation between critical

constantsand van derWaalsconstants,law ofcorresponding

states.

(18Lectures)

UNIT-II:LIQUIDSTATE

Qualitativetreatmentofthestructureoftheliquidstate;Radialdistribution function; physical properties of liquids; vapourpressure,surfacetensionandcoefficientofviscosity,andtheirdetermination.Effectofaddition ofvarioussoluteson surfacetension and viscosity. Explanation of cleansing action ofdetergents.Temperature variation ofviscosity ofliquids andcomparisonwiththatofgases.Qualitativediscussionofstructureofwater.

(6Lectures)

UNIT-III:SOLIDSTATE

Natureofthesolidstate,lawofconstancyofinterfacialangles,lawofrationalindices,Millerindices,elementaryideasofsymmetry,

symmetryelementsandsymmetryoperations,qualitativeideaofpointand space groups,seven crystalsystems and fourteenBravaislattices;X-raydiffraction,Bragg’slaw,asimpleaccountofrotatingcrystalmethodandpowderpatternmethod.Analysisofpowderdiffraction patterns ofNaCl,CsCland KCl.Defects incrystals.Glassesandliquidcrystals.

(15Lectures)

UNIT-IV:CHEMICALTHERMODYNAMICS-I

Intensive and extensive variables;state and path functions;

isolated,closedandopensystems;zerothlawofthermodynamics.

Firstlaw:Conceptofheat,q,work,w,internalenergy,U,andstatementoffirstlaw;enthalpy,H,relationbetweenheatcapacities,calculationsofq,w,UandH forreversible,irreversibleandfreeexpansionofgases(idealandvanderWaals)underisothermalandadiabaticconditions.

(6Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS

1.Atkins,P.W.&Paula,J.deAtkin’sPhysicalChemistryEd.,OxfordUniversityPress(2006).

2.Ball,D.W.PhysicalChemistryThomsonPress,India(2007).3.Castellan,G.W.PhysicalChemistry4thEd.Narosa(2004).4.Mortimer,R.G.PhysicalChemistry3rd Ed.Elsevier:NOIDA,

UP(2009).

CourseTitle Physics–II

CourseCode BSS2PH01


4 0 2 6

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:OPTICS

Fermat’sprinciple,Lawsofreflectionandrefractionfrom Fermat’sprinciple,principlesofreversibility,Refractionatsphericalsurface,Matrixmethodinparaxialoptics,coordinatesofaRay,Translationmatrix,RefractionMatrix.Aberration:Aberration ofa thin lens,longitudinaland lateralchromaticaberration,Achromatism oflenses:achromatism oftwolenses in contact,achromatism oftwo lenses separated byadistance,Sphericalaberration,sphericalaberrationduetosphericalsurface,minimizationofsphericalaberration.

(15Lectures)

UNIT-II:WaveMotioninaMedium

Characteristicofprogressivewave,mathematicalrepresentationofa plane progressive wave,differentialwave equation in onedimension,velocityofpropagationofplanelongitudinalwavesinanelasticfluid,velocityofsound in gasesand liquids,velocityoflongitudinalwavesinasolidbar,propertiesofthedifferentialwaveequation,solutionofthesimpleharmonicwaveequation,energydensity ofplane progressive wave,phase velocity and groupvelocity.

(15Lectures)

UNIT-III:VECTORANALYSIS

Review ofvectoralgebra (Scalarand Vectorproduct),gradient,

divergence,Curlandtheirsignificance,VectorIntegration,Vectors

AnalysisIntegrals(line,surfaceandvolume),Physicalsignificance

ofGradient,Divergenceandcurl,statementofGauss’sandStoke’s

theorems.

(6Lectures)

UNIT–IV:ELECTROSTATICS

Gradientofscalarfieldandcurlofavectorfield,irrotational&rotationalvectorfields,Gauss’s Law (divE = ρ/0),EnergyassociatedwithEfield,Poisson’sequation,Laplace’sequationandUniquenesstheorems.Conductor in electric field ,Electric dipole,dipole moment,polarizationandchargedensity,EandD fields,polarizabilityandsusceptibility,Gauss’slawindielectrics,Staticboundaryconditionsindielectric,energyoffieldsinthepresenceofdielectrics.

(12Lectures)

UNIT-V:MAGNETICFIELD

MagneticfieldB(throughLorentzforce)onamovingcharge,unitforB,torqueonacurrentloopinBfield,magneticdipolesinatomsandmolecules,gyromagneticratio.

HYSTERISIS LOOP:Magnetizing Current,vector,H and B fields,Magneticpermeability,susceptibility,Retentivty,coercivety andHysterisisloss,BoundaryconditionsforBandH.Measurementofsusceptibility(Gouy’sMethod/Quincke’sMethod).

(12Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS

1.TextbookofopticsbyN.Subrahmanyam,BrijLalandM.N.Avadhamulu(S.ChandandCo.Ltd.,N Delhi,2006)

2.Vibrations,wavesandacousticsbyD.ChattopadhyayandP.C.Rakshit(NewCentralbookagencyPvt.India)

3.TexbookofVibrationsandwaves(Revisededition)byS.P.Puri(MacmilanIndiaLtd.2004).

4.Electricityandmagnetism,Berkleyphysicscourse,Vol.II,Mcgrawbookscompany.

5.Electromagnetism byB.B.Laud2ndEdition,Wileyeasternlimited.

6.Electricity&Magnetism withElectronicsbyK.K.Tiwari(S.Chand&CompanyLtd.2007)

CourseTitle EnvironmentalStudies

CourseCode BSF3ES01


2 1 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I: INTRODUCTION OF ENVIRONMENT, ECOLOGY ANDECOSYSTEMSEcology-ObjectivesandClassificationConceptsofanecosystem-structure&functionofecosystem componentsofecosystem,Hydrologicalcycle,carbon cycle,oxygen cycle,Nitrogen cycle,Sulphur cycle,Ecological Pyramids major ecosystems:ForestEcosystem,Grassland Ecosystem,DesertEcosystem,Aquaticecosystem,EstuarineEcosystem

(8Lectures)

UNIT-II:AIRPOLLUTIONANDITSCONTROLIntroduction,Classificationofairpollutants,airpollutantsandtheireffects,acidrain,photochemicalsmog,particulates.Characteristicsandbiochemicaleffectsofsomeimportantairpollutants,Effectofairpollutantsonmanandenvironment,Airqualitystandard,airmonitoringandcontrolofairpollution.

(7Lectures)

UNIT-III:WATERPOLLUTIONANDITSCONTROLIntroduction,Classificationofwaterpollutants,physical,chemicaland biologicalcharacteristics of waste water,waste watertreatment: Primary treatment- Sedimentation, coagulation,equalization,neutralization,secondarytreatment-aerobictreatment-aeratedlagoons,tricklingfilter,activatedsludgeprocess,oxidationditch process,oxidation pond,anaerobic treatment-anaerobicsludge digestion,sludge treatmentand disposaland tertiarytreatment-evaporation, ion exchange, adsorption, chemicalprecipitation,Electrodialysis,reverseosmosis.

(8Lectures)

UNIT-IV: SOLID AND HAZARDOUS WASTE: POLLUTION,TREATMENTANDDISPOSALIntroduction,Classification and origin,characteristics ofsolidwastes,objectivesandconsiderationsinsolidwastemanagement,methodsofsolidwastetreatmentanddisposal-composting,landfilling,thermalprocesses-incineration,pyrolysis,recycling andreuseofsolidwaste-co-disposal,bioconversion.

(7Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Bharucha E.,Textbook of EnvironmentalStudies,UGCuniversitiesPress2005.

2.Mishra, D.D., Fundamental concepts in EnvironmentalStudies,S.Chand&CoLtd.2010

3.R.Rajagopalan,EnvironmentalStudies,Oxford UniversityPress.

CourseTitle GREENCHEMISTRYCourseCode

BSE3CH01

CourseCredits

L T P Credits

2 0 0 2

Prerequisites

--

Courseobjectives

CourseContents

UNIT-I:INTRODUCTIONTOGREENCHEMISTRY

WhatisGreenChemistry?NeedforGreenChemistry.GoalsofGreenChemistry.Limitations/ObstaclesinthepursuitofthegoalsofGreenChemistry.

(4Lectures)

UNIT-II:PRINCIPLES OF GREEN CHEMISTRY AND DESIGNING ACHEMICALSYNTHESIS

Twelve principles ofGreen Chemistry with theirexplanations andexamples;Designing a Green Synthesis using these principles;Prevention ofWaste/ byproducts;maximum incorporation ofthematerialsusedintheprocessintothefinalproducts(Atom Economy);prevention/minimizationofhazardous/toxicproducts;designingsaferchemicals – different basic approaches to do so;selection ofappropriateauxiliarysubstances(solvents,separationagents),greensolvents,solventlessprocesses,immobilizedsolventsandionicliquids;

UNIT-III:

Energyrequirements forreactions -use ofmicrowaves,ultrasonicenergy;selection ofstarting materials;avoidance ofunnecessaryderivatization – carefuluse ofblocking/protecting groups;use ofcatalyticreagents(whereverpossible)inpreferencetostoichiometricreagents;designingofbiodegradableproducts;preventionofchemicalaccidents;strengthening/ developmentofanalyticaltechniques topreventand minimize the generation ofhazardous substances inchemicalprocesses.

(20Lectures)

UNIT-IV:FUTURETRENDSINGREENCHEMISTRY

Oxidationreagentsandcatalysts;Biomimetic,multifunctionalreagents;Combinatorialgreenchemistry;Proliferationofsolventlessreactions;oncovalentderivatization;Greenchemistryinsustainabledevelopment

(6Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.V.K.Ahluwalia&M.R.Kidwai:NewTrendsinGreenChemistry,2.AnamalayaPublishers(2005).3.P.T.Anastas&J.K.Warner:OxfordGreenChemistry-Theoryand

Practical,UniversityPress(1998).4.A.S.Matlack:IntroductiontoGreenChemistry,MarcelDekker

(2001).5.M.C.Cann&M.E.Connely:Real-WorldcasesinGreenChemistry,

AmericanChemicalSociety,Washington(2000).6.M.A.Ryan & M.Tinnesand,Introduction to Green Chemistry,

AmericanChemicalSociety,Washington(2002).

CourseTitle INDUSTRIALCHEMISTRY

CourseCode BSE3CH02


2 0 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I:INDUSTRIALGASESANDINORGANICCHEMICALSIndustrialGases:Large scale production,uses,storage andhazardsinhandlingofthefollowinggases:oxygen,nitrogen,argon,neon,helium,hydrogen,acetylene,carbon monoxide,chlorine,fluorine,sulphurdioxideandphosgene.Inorganic Chemicals: Manufacture, application, analysis andhazardsinhandlingthefollowingchemicals:hydrochloricacid,nitricacid,sulphuricacid,causticsoda,commonsalt,borax,bleachingpowder,sodium thiosulphate,hydrogen peroxide,potash alum,chrome alum, potassium dichromate and potassiumpermanganate.

(8Lectures)

UNIT-II:MASSANDENERGYBALANCECALCULATIONSElementaryconceptsofunitoperationsandunitprocesses,flowsheetpreparation,conceptofmassbalanceandtypeofmassbalance problems, strategy and guide for mass balancecalculationsfornon‐reactiveandreactivesystem,recycleoperationandpurgeoperationbypassoperation,energybalanceforbatchandcontinuousprocesses.

(7Lectures)

UNIT-III:FLUIDFLOWPumps:Definition,Classification ofPumps,Centrifugalpumps,Construction/componentpartsofCentrifugalpumps,workingofacentrifugalpump,advantages and disadvantages ofcentrifugalpumps, air binding and priming, Reciprocating pumps:Construction/componentsofareciprocatingpumps,workingandtypes ofreciprocating pumps,Piston pumps,Plungerpumps,Diaphragm pumps,Gearpumps,ComparisonofCentrifugalpumpwithReciprocatingpump.Heattransferequipment,Heatexchangers:ShellandTubetypeheatexchanger,Double type heatexchanger,finned tube heatexchanger,Plate‐typeheatexchanger.

(8Lectures)

UNIT-IV:INDUSTRIALINSTRUMENTATION

Expansion thermometers: Introduction, Temperature scale,Constant‐volumegasthermometer,Mercuryinglassthermometer,Bimetallic thermometer, Pressure‐Spring thermometer;

Thermocouples:Industrialthermocouples,Thermocouple leadwires, Thermal Wells; Resistance thermometers: Null‐BridgeResistancethermometers,DeflectionalResistancethermometer,Pyrometers:RadiationandOpticalpyrometer,MeasuringelementsforGaugepressureandvacuum.

(7Lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:

1.E.Stocchi:IndustrialChemistry,Vol-I,EllisHorwoodLtd.UK.2.R.M.Felder,R.W.Rousseau:Elementary Principles of

ChemicalProcesses,WileyPublishers,NewDelhi.3.J.A.Kent:Riegel’sHandbookofIndustrialChemistry,CBS

Publishers,NewDelhi.4.S.S.Dara:A Textbook ofEngineering Chemistry,S.

Chand&CompanyLtd.NewDelhi.

CourseTitle Mathematics-III

CourseCode BSS3MA01


4 1 0 4

Prerequisites --

Courseobjectives

CourseContents Unit-1:SolutionofequationsinonevariablebyBisectionmethod,

RegulaFalsimethod,Newton-Raphson’smethod,Secantmethod.

Solution ofsystem oflinearequations by Gauss elimination

method,Gauss-Seideliterative method,Gauss-Jecobimethod,

Newton’sforwardandbackwardinterpolationformulas,Lagrange’s

interpolationformula

(18lectures)

Unit-2:NumericalIntegration:Trapezoidalrule,Simpson’s1/3rd

rule,Simpson’s 3/8th rule,Numericalsolution of differential

equations by TaylorSeries method,Euler’s Method,Modified

Euler’s Method,Second,third and fourth order Runge-Kutta

methods.

(12lectures)

Unit-1: Definition and elementary properties of graphs,Isomorphism ofgraphs,Subgraphs Walks,Paths and circuits,Connectedgraphs,Eulergraphs,Operationsongraphs,Hamiltoniancircuits,Definitionandpropertiesoftree,Centersinatree,RootedandBinarytree.

(15lectures)Unit-2:Spanning trees,fundamentalcircuits,Cutsetand itsproperties, Planar graphs and Kuratowski’s two graphs,Representation ofplanargraphs,Geometric and combinatorialduals,Chromaticnumber,Chromaticpolynomial,Matchings.

(15lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.1.G.ShankarRao,NumericalAnalysis,NewAge

InternationalPvt.Ltd,2006.

2.2.S.S.Sastry,IntroductorymethodsofNumericalAnalysis,

Prentice-HallofIndia,2006.

3.3.RalpG.Stanton,Numericalmethodsforscienceand

Engineering,Prentice-HallofIndia,1967.

4.4.P.C.Biswal,NumericalAnalysis,Prentice-HallofIndia,

2008.

5.NarsinghDeo,GraphtheorywithapplicationstoEngineeringandComputerScience,Prentice-HallofIndia,1993.

6.J.P.TrembleyandR.Manohar,DiscreteMathematicalStructurewithapplicationstoComputerScience,McGrawHillBookCompany,2001.

CourseTitle OrganicChemistry–IICourseCode BSC3CH01


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:AKLYLHALIDES,NUCLEOPHILICSUBSTITUTIONANDELIMINATIONREACTIONSAlkylhalides:Methodsofpreparation,nucleophilicsubstitutionreactions–SN1,SN2andSNimechanismswithstereochemicalaspectsandeffectofsolventetc.;nucleophilicsubstitutionvs.elimination,relativereactivityofhalideleavinggroups,carbocationstabilityandtherateofsubstitutionbytheSN1reaction,carbocationrearrangement.

(10Lectures)

UNIT-II:AROMATICANDPOLYNUCLEARHYDROCARBONS

Aromaticity:Hückel’s rule,aromatic characterofarenes,cycliccarbocations/carbanions and heterocyclic compounds withsuitable examples. Electrophilic aromatic substitution:halogenation, nitration, sulphonation and Friedel-Craft’salkylation/acylationwiththeirmechanism.Directingeffectsofthegroups.Arylhalides:Preparation,including preparation fromdiazonium salts.nucleophilicaromaticsubstitution;SNAr,Benzynemechanism.Relativereactivityofalkyl,allyl/benzyl,vinylandarylhalides towards nucleophilic substitution reactions.Polynuclearhydrocarbons: Reactions of naphthalene phenanthrene andanthraceneStructure,Preparation and structureelucidation andimportantderivativesofnaphthaleneandanthracene;Polynuclearhydrocarbons.

(15Lectures)

UNIT-III:ORGANICSPECTROSCOPYMass spectroscopy and its applications General principles

Introduction to absorption and emission spectroscopy. UVSpectroscopy:Typesofelectronictransitions,λmax,Chromophoresand Auxochromes, Bathochromic and Hypsochromic shifts,Intensity of absorption;Application of Woodward Rules forcalculationofλmaxforthefollowingsystems:α,β unsaturatedaldehydes,ketones,carboxylicacidsandesters;Conjugateddienes:alicyclic,homoannularand heteroannular;Extended conjugatedsystems(aldehydes,ketonesanddienes);distinctionbetweencisand trans isomers.IR Spectroscopy:Fundamentaland non-fundamentalmolecularvibrations;IRabsorptionpositionsofO,Nand S containing functional groups; Effect of H-bonding,conjugation,resonanceandringsizeonIRabsorptions;Fingerprintregionanditssignificance;applicationinfunctionalgroupanalysis.NMR Spectroscopy: Basic principles of Proton Magnetic

Resonance,chemicalshiftandfactorsinfluencingit;Spin–Spincoupling and coupling constant;Anisotropic effects in alkene,alkyne,aldehydesandaromatics,InterpetationofNMRspectraofsimple compounds. Applications of IR, UV and NMR foridentificationofsimpleorganicmolecules.

(20Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1. Morrison,R.T.&Boyd,R.N.OrganicChemistry,DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

2. Finar,I.L.OrganicChemistry(Volume1),DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

3. Graham Solomons,T.W.OrganicChemistry,JohnWiley&Sons,Inc.

4. Finar,I.L.OrganicChemistry(Volume2:StereochemistryandtheChemistryofNaturalProducts),DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

5.Eliel,E.L.&Wilen,S.H.Stereochemistry of OrganicCompounds;Wiley:London,1994.

6.Kalsi,P.S.StereochemistryConformationandMechanism;NewAgeInternational,2005.

CourseTitle PhysicalChemistry–IICourseCode BSC3CH02


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:CHEMICALTHERMODYNAMICS-II

Thermochemistry:Heatsofreactions:standardstates;enthalpyofformationofmoleculesandionsandenthalpyofcombustionandits applications;calculation ofbond energy,bond dissociationenergyandresonanceenergyfrom thermochemicaldata,effectoftemperature(Kirchhoff’sequations)andpressureonenthalpyofreactions.Adiabaticflametemperature,explosiontemperature.UNIT-II:Second Law: Concept of entropy;thermodynamic scale oftemperature,statementofthe second law ofthermodynamics;molecularandstatisticalinterpretationofentropy.Calculationofentropychangeforreversibleandirreversibleprocesses.ThirdLaw:Statementofthirdlaw,conceptofresidualentropy,

calculationofabsoluteentropyofmolecules.

FreeEnergyFunctions:GibbsandHelmholtzenergy;variationofS,G,A withT,V,P;Freeenergychangeandspontaneity.Relationbetween Joule-Thomson coefficientand otherthermodynamicparameters;inversion temperature;Gibbs-Helmholtz equation;Maxwellrelations;thermodynamicequationofstate.

(27Lectures)UNIT-III:CHEMICALEQUILIBRIUM

Criteriaofthermodynamicequilibrium,degreeofadvancementofreaction,chemicalequilibriainidealgases,conceptoffugacity.ThermodynamicderivationofrelationbetweenGibbsfreeenergyofreactionandreactionquotient.Couplingofexoergicandendoergicreactions.Equilibrium constantsandtheirquantitativedependenceontemperature,pressureandconcentration.Freeenergyofmixingandspontaneity;thermodynamicderivationofrelationsbetweenthe various equilibrium constants Kp ,Kc and Kx.Le Chatelierprinciple(quantitativetreatment);equilibrium betweenidealgasesandapurecondensedphase.

(10Lectures)

UNIT-IV:SYSTEMSOFVARIABLECOMPOSITION

Partialmolarquantities,dependenceofthermodynamicparametersoncomposition;Gibbs-Duhem equation,chemicalpotentialofidealmixtures,changeinthermodynamicfunctionsinmixingofidealgases.

(8Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS

• Peter,A.&Paula,J.de.PhysicalChemistry9thEd.,OxfordUniversityPress(2011).1.Castellan,G.W.PhysicalChemistry4thEd.,Narosa(2004).

2.Engel,T.&Reid,P.PhysicalChemistry3rdEd.,Prentice-Hall(2012).

3.McQuarrie,D.A.&Simon,J.D.MolecularThermodynamicsVivaBooksPvt.Ltd.:NewDelhi(2004).

4.Assael,M.J.;Goodwin,A.R.H.;Stamatoudis,M.;Wakeham,W. A. & Will, S.Commonly Asked Questions inThermodynamics.CRCPress:NY(2011).

5.Levine,I.N.PhysicalChemistry6th Ed.,TataMcGraw Hill(2010).

6.Metz,C.R.2000 solved problems in chemistry,SchaumSeries(2006)

CourseTitle Physics–III

CourseCode BSS3PH01

CourseCredits

L T P Credits

4 0 2 6

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:

Conditionforsustainedinterference,classificationofinterference,Divisionofwavefront:Biprism,Divisionofamplitude:Newton’srings.

InterferenceinThinFilms:Interferenceduetoreflectedlightandtransmitted light, Variable thickness of film, Michelson’sinterferometer,Fabry-Perotinterferometer(etalon),Applicationsofinterferometers.

Diffraction:Fresnel’sassumption,rectilinearpropagationoflight,zoneplate,FresnelandFraunhoferdiffraction,Diffractionduetoastraightedge,Fraunhoferdiffractionduetoasingleslit,FraunhoferdiffractionatNslits,

DiffractionGrating:planediffractiongrating,Dispersivepowerofagrating,prism andgratingspectra.

Polarization:PolarizationbyscatteringandbyselectiveAbsorptionDoublerefraction,Huygen’stheoryofdoublerefraction,Nicol’sprism,Productionanddetectionofplane,ellipticallyandcircularlypolarizedlights,Analysis ofPolarized lights (experimentalaspects only),Identification of Polarization, Quarter wave plate, Babinetcompensator.

(20Lectures)

UNIT-II:

Lasers:Attenuationoflightinanopticalmedium,Thermalequilibrium,Interactionoflightwithmatter,Absorption,Spontaneousemission,Einstein’sprediction,Stimulated emission,Einsteinrelations,Lightamplification, condition for stimulated emission to dominatespontaneousemissionandabsorption,populationinversion,activemedium,pumpingmethods,meta-stablestates,principleofpumpingschemes-threeandfourlevelscheme,opticalresonantcavity,lasingaction,He-NeLaser,P-NJunctionLaser,applications,introductiontoopticalfibre,acceptanceangle,numericalaperture,andapplications.

(10Lectures)

UNIT–III:SEMICONDUCTORDIODES

Reviewofp-njunctiondiodeandcharacteristics,Rectifiersequation,Loadlineofadiode,DiodeasaHalfwaveandfullwaverectifier;efficiencyofrectifier,ripplefactor,filtercircuit;Landπtypefilterwithefficiencyandripplefactors.Zenerdiode,useasaregulator.

TransistorBiasing:Base bias,voltage divider,Transistoraction;Relationofαandβ,Loadlines,operatingpointstability(incommonemitteronly).Transistorasafourterminal,hybridparameter(model)in common emitterconfiguration (briefdiscussion only)with h-parametersequivalentcircuit,commonemitteramplifierwithemitterresistance and voltage divider.RC coupled amplifierfrequencyresponseinmid-,low-andhighfrequencyranges.

(15Lectures)

UNIT-IV:

Feedback conceptin amplification,closed and open loop gains,negativefeedbackamplifier,Seriesandshuntfeedback,Advantagesof negative feedback on band width,gain stability,frequencyresponse,inputandoutputimpedanceanddistortion.Oscillators:Oscillatory circuit,undamped oscillations from tankcircuit,Positivefeed-back,Barkhausencriterion,RC oscillatortankcircuitresonance;Tunedcollectoroscillator,Hartleyoscillator,Colpittoscillator,Phaseshiftoscillator(Noderivation),limitationsofRC&LCoscillator.Semiconducting Devices:ZenerDiode,LED,Photo Diode,TunnelDiods,VaractorlaserDiode,Photo voltaic and voltage dependentResistororvaristors.

(15Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS

1.Text book of optics by Nsubrahmanyam,Brijlaland M NAvadhamulu(SChandandCo.Ltd.,N.Delhi,2006).

2.Principles of Electronics by V.K.MehtaandRohitMehta(SChandandCo.,NDelhi,2007)

3.ElementsofElectronicsbyM KBagdeandSP Singh(SChandandCo.,NDelhi)

CourseTitle ComputerApplication

CourseCode BSF4CA01


2 1 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I:BASICOFCOMPUTER

Constants,variables,bits,bytes,binary and ASCII formats,

arithmeticexpressions,hierarchyofoperations,inbuiltfunctions.

ElementsoftheBASIClanguage.BASICkeywordsandcommands.

(15Lectures)

UNIT-II:INTRODUCTIONTOCOMPUTERAPPLICATION

Logicaland relativeoperators.Stringsand graphics.Compiled

versusinterpretedlanguages.Debugging.Simpleprogramsusing

these concepts.Matrix addition and multiplication.Statistical

analysis.

(15Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Harris,D.C.QuantitativeChemicalAnalysis.6th

Ed.,Freeman(2007)Chapters3-5.

2.Levie,R.de,How to useExcelinanalyticalchemistryand ingeneralscientificdataanalysis,CambridgeUniv.Press(2001)487pages.

3.Noggle,J.H.PhysicalchemistryonaMicrocomputer.LittleBrown&Co.(1985).

4.Venit,S.M. Programming in BASIC: Problem solving withstructureandstyle.

JaicoPublishingHouse:Delhi(1996).

CourseTitle InorganicChemistry–IICourseCode BSC4CH01


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:CHEMISTRYOFSANDPBLOCKELEMENTS

Trends in s and p-block elements,diagonalrelationship and

anomalousbehaviouroffirstmemberofeachgroup,allotropyand

catenation,relativestabilityofdifferentoxidationstates,hydrides

and theirclassification ionic,covalentand interstitial.Basic

beryllium acetateandnitrate.Studyofthefollowingcompounds

withemphasisonstructure,bonding,preparation,propertiesand

uses. Boric acid and borates,boron nitrides,borohydrides

(diborane)carboranesandgraphiticcompounds,silanes,Oxides

andoxoacidsofnitrogen,Phosphorusandchlorine.Peroxoacids

of sulphur, interhalogen compounds, polyhalide ions,

pseudohalogensandbasicpropertiesofhalogens.

Inertpaireffect,relativisticeffects,complexformationtendencyofsandpblockelements.

(30Lectures)UNIT-II:INORGANICPOLYMERSTypesofinorganicpolymers,comparisonwithorganicpolymers,synthesis,structuralaspects and applications ofsilicones andsiloxanes. Borazines, silicates and phosphazenes, andpolysulphates.

(5Lectures)

UNIT-III:GENERALPRINCIPLESOFMETALLURGY

Chiefmodesofoccurrenceofmetalsbasedonstandardelectrodepotentials.Ellingham diagramsforreductionofmetaloxidesusingcarbon and carbon monoxide as reducing agent.ElectrolyticReduction,Hydrometallurgy.Methods ofpurification ofmetals:Electrolytic Krollprocess,Parting process,van Arkel-de BoerprocessandMond’sprocess,Zonerefining.

(10Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Lee,J.D.ConciseInorganicChemistry,ELBS,1991.2.Douglas,B.E;McDaniel,D.H.&Alexander,J.J.Concepts

& Models ofInorganic Chemistry3rd Ed.,John WileySons,N.Y.1994.

3.Greenwood,N.N.&Earnshaw.ChemistryoftheElements,Butterworth-Heinemann.1997.

4.Cotton, F.A. & Wilkinson, G. Advanced InorganicChemistry,Wiley,VCH,1999.

5.Miessler,G.L.&Donald,A.Tarr.InorganicChemistry4thEd.,Pearson,2010.

6.Shriver&Atkins,InorganicChemistry5thEd.

CourseTitle Mathematics-IV

CourseCode BSS4MA01


4 1 0 4

Prerequisites --

Courseobjectives

CourseContents Unit-1:Iteratedintegralsanddoubleintegral,Changeoforder,

Double Integrals in Polar Coordinates,Evaluation by using

transformations,Applicationstoareaandvolume,TripleIntegrals.

(15

lectures)

Unit-2:Lineintegrals,Pathindependenceoflineintegrals,Green’s

theorem (withoutproof).Tripleintegrals,Surfaceintegrals,Stokes’s

theorem (withoutproof)and its applications,Gauss’theorem

(withoutproof)anditsapplications.

(15

lectures)

Unit-3:Linear programming problems and their illustrations,Graphicalmethodofsolvingtwovariableproblem,Convexsetsandtheirproperties,Feasiblesolution,optimum solution,SlackandSurplusvariables,L.P.P.inastandardform,Propertiesofasolution(withoutproof),Simplexmethodanditscomputationalprocedure,Artificialbasistechnique.

(15

lectures)

Unit-4:Transportationproblem,Methodsforfindinginitialbasicfeasiblesolution:Northwestcornerrule,Matrixminimamethod,Vogel’sapproximation method,optimalsolution:MODIMethod.Assignmentproblem:HungarianMethod.

(15

lectures)

CourseoutcomesTextandReferences

REFERENCEBOOKS:


WileyandSonsInc.,1983.

2. LouisLeithold,TheCalculuswithAnalyticGeometry,Harper-

CollinsPublishers,1981.

3. ShantiNarayan,DifferentialCalculus,S.Chand&Co.Ltd.,

2005.

4. G.B.ThomasJr.andR.L.Finney,CalculusandAnalytic



5.S.I.Gass,Linearprogramming,McGrawHillBookCompany,

1985.

6. KantiSwaroop,Man Mohan and P.K.Gupta,Operations

Research,SultanChandandSons,2005.

7.Hamdy A.Taha,Operations Research:An Introduction,

McMillanPublishingCompany,2007.

CourseTitle NANOSCIENCE

CourseCode BSE4CH02


2 0 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I:

Nanoscaleanditssignificance,Surfacetovolumeratio,surface

effects on nanomaterials, quantum size effects, electron

confinement. Introduction and preparation Introduction to

Nanomaterials,Optical,magnetic and chemicalproperties of

Nanometrials.

(08Lectures)

UNIT-II:

Nanomaterials and nano-science,properties ofnanomaterials.

Preparation ofNanoparticles:ChemicalApproaches:Chemical

reduction; Sonochemical Synthesis; Sol-Gel Synthesis; Self-

assembly.PhysicalApproaches:Aerosolspray;gasCondensation;

LaservaporizationandVapourdeposition;Sputtering.Particlesize

Analyzer(Laserscattering),OpticalMicroscopy:ScanningElectron

Microscopy.

(10Lectures)

UNIT-III:

Synthesis of nanomaterials:top-down and bottom approach,

classificationofnanomaterials,carbonbasednano-materials.

(05Lectures)

UNIT-IV:

Characterization techniques forNanomaterials Applications of

nano-materialsApplication ofNanomaterials,Applications Solar

energy conversion and catalysis, Polymers with a special,

architecture,Liquid crystallinesystems,Applicationsin displays

andotherdevices,Advancedorganicmaterialsfordatastorage,

Photonics,Chemicaland biosensors,Nano medicineand Nano

biotechnology.

(07Lectures)

Courseoutcomes

TextandReferences

1.HandBookofNanoscienceandNanotechnologyby Jayanta

Barman

2.Nanotechnology:AnIntroductiontoSynthesis,Properties

andApplicationsofNanomaterialsbyThomasVarghese&

K.M.Balakrishna

3. IntroductiontoNanosciencebyGaborL.Hornyak,Joydeep

Dutta,H.F.Tibbals,AnilRao

CourseTitle PhysicalChemistry–III

CourseCode BSC4CH02


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:IONICEQUILIBRIA

Strong,moderate and weak electrolytes,degree ofionization,factorsaffectingdegreeofionization,ionizationconstantandionicproductofwater.Ionizationofweakacidsandbases,pH scale,common ion effect;dissociation constants of mono-,di-andtriprotic acids (exact treatment).Salt hydrolysis-calculation ofhydrolysisconstant,degreeofhydrolysisandpHfordifferentsalts.Buffer solutions;derivation of Henderson equation and itsapplications;buffer capacity,buffer range,buffer action andapplications ofbuffers in analyticalchemistryand biochemicalprocessesinthehumanbody.Solubilityandsolubilityproductofsparinglysolublesalts–applicationsofsolubilityproductprinciple.Qualitativetreatmentofacid–basetitrationcurves(calculationofpHatvariousstages).Theoryofacid–baseindicators;selectionofindicators and their limitations.Multistage equilibria inpolyelectrolytesystems;hydrolysisandhydrolysisconstants.

(15Lectures)

UNIT-II:SolutionsandColligativeProperties:

Dilutesolutions;loweringofvapourpressure,Raoult’sandHenry’s

Laws and their applications. Excess thermodynamic

functions.Thermodynamicderivation using chemicalpotentialto

deriverelationsbetweenthefourcolligativeproperties[(i)relative

lowering ofvapourpressure,(ii)elevation ofboiling point,(iii)

Depressionoffreezingpoint,(iv)osmoticpressure]andamountof

solute.Applications in calculating molar masses of normal,

dissociatedandassociatedsolutesinsolution.

(10Lectures)

UNIT-III:CHEMICALKINETICS

Orderandmolecularityofareaction,ratelawsintermsoftheadvancementofareaction,differentialandintegratedform ofrateexpressionsuptosecondorderreactions,experimentalmethodsofthe determination ofrate laws,kinetics ofcomplex reactions(integratedrateexpressionsuptofirstorderonly):(i)Opposingreactions(ii)parallelreactionsand(iii)consecutivereactionsandtheirdifferentialrate equations (steady-state approximation inreaction mechanisms) (iv) chain reactions. Temperaturedependence of reaction rates;Arrhenius equation;activationenergy.Collisiontheoryofreactionrates,Lindemannmechanism,

qualitativetreatmentofthetheoryofabsolutereactionrates.

(20Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.PeterAtkins& Julio DePaula,PhysicalChemistry9thEd.,OxfordUniversityPress(2010).

2.Castellan,G.W.PhysicalChemistry,4thEd.,Narosa(2004).3.McQuarrie,D.A.&Simon,J.D.,MolecularThermodynamics,

VivaBooksPvt.Ltd.:NewDelhi(2004).4.Engel,T.&Reid,P.PhysicalChemistry3rdEd.,Prentice-Hall

(2012).5.Assael,M.J.;Goodwin,A.R.H.;Stamatoudis,M.;Wakeham,

W. A. & Will, S.Commonly Asked Questions inThermodynamics.CRCPress:NY(2011).

6.Zundhal,S.S.ChemistryconceptsandapplicationsCengageIndia(2011).

7.Ball,D.W.PhysicalChemistryCengageIndia(2012).8.Mortimer,R.G.PhysicalChemistry3rdEd.,Elsevier:NOIDA,

UP(2009).9.Levine,I.N.PhysicalChemistry6thEd.,Tata McGraw-Hill

(2011).10.Metz,C.R.PhysicalChemistry2ndEd.,Tata McGraw-Hill

(2009).

CourseTitle Physics–IV

CourseCode BSS4PH01


4 0 2 6

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:ModernPhysics

Millikan'soildropexperimentforelectroniccharge,Determinationofq/m ofpositiverays,Astonmassspectrograph.X Rays production,origin and properties,diffraction ofX rays,Bragg’slaw,Moseley’slaw.Wavebehaviourofparticles;DeBrogliewavelengthwavepacketsand particles;Heinsenberg'suncertaintyrelation;Wavefunction;Physical interpretation of trapped particles and Probabilitydensities.

(15Lectures)

UNIT-II:

α and β decay,radioactive dating,nuclearreactions,particleinteraction(Basicforces)andfamiliesofelementaryparticles.Particleaccelerators:LinearAccelerators,Van-de-graphgenerator,Cyclotron,betatron(Briefintroduction).Detectors:IntroductiontoGasfilleddetectors,ScintillationCounterandsemiconductordetector.

(15Lectures)

UNIT-III:SpecialTheoryofRelativity

InertialFramesofReference,Galileantransformation,InvarianceofNewton’slaw.TheMichelson-MorleyExperiment,Expression forFringe shift,Nullecperimentand its consequences,Einstein’sPostulates,LorentzTransformation,Lorentz-Fitzerald,Contraction,LengthcontractionandTimeDilation,RelativisticVelocity.Transformation Equations,RelativisticmassVariation,Einstein’sMass-Energy Relation, Momentum and Energy Relationship,Particleswithzerorestmass.

(15Lectures)

UNIT-IV:StatisticalMechanics

BasicconceptsofStatisticalmechanics,Densityofstates,Maxwell– Boltzmann (MB)statistics,Thermodynamic probabilityin MBstatisticsanddistributionfunction,ApplicationsofMB-statistics,Equationofstate,Maxwell’senergyandvelocitydistributionlaw,limitationsofMB-statistics.IntroductiontoQuantum Statistics,Bose-Einstein(BE)Statistics,Thermodynamicprobability,BEdistributionfunction,ApplicationofBE-statistics,Planck’sradiationlaw,Bosecondensate,Fermi-Dirac(FD) statistics, FD-distribution function, Applications of FD-

statistics,Electronicspecificheatofmetals,ComparisonofMB,BEandFD-Statistics.

(15Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.ModernphysicsbyGAruldhasandPRajgopal2.ModernphysicsbyDSehgal,KChopraandNSehgal

(SChandandCo,NewDelhi)3.FundamentalsofmodernphysicsbyJPAgrawaland

AAgrawalPragatiPrakashan(Meerut)4.ConceptsofModernPhysicsbyBieser(TataMcGraw-

Hill).ModernphysicsbyGAruldhasandPRajgopal5.ConceptofModernphysicsbyABeiser(TataMcgraw

Hill,6thedition)6.ModernphysicsbyDSehgal,KChopraandNSehgal

(SChandandCo,NewDelhi)7.Quantum MechanicsbyV.Devanathan(NarosaPub.-

2006).

CourseTitle POLYMERSCIENCE

CourseCode BSE4CH01


2 0 0 2

Prerequisites --

Courseobjectives

CourseContents UNIT-I:INTRODUCTIONANDHISTORYOFPOLYMERICMATERIALS

Differentschemesofclassificationofpolymers,Polymer

nomenclature,Molecularforcesandchemicalbondinginpolymers,

TextureofPolymers.

(5Lectures)UNIT-II:FUNCTIONALITYANDITSIMPORTANCE

Criteria for synthetic polymer formation, classification ofpolymerization processes,Relationships between functionality,extentofreaction and degree ofpolymerization.Bi-functionalsystems,Poly-functionalsystems.KineticsofPolymerization:Mechanism andkineticsofstepgrowth,radicalchaingrowth,ionicchain(bothcationicandanionic)andcoordinationpolymerizations,Mechanism and kinetics of copolymerization,polymerizationtechniques.

(10lectures)

UNIT-III:CRYSTALLIZATIONANDCRYSTALLINITY

Determination of crystalline melting point and degree of

crystallinity,Morphologyofcrystallinepolymers,Factorsaffecting

crystallinemeltingpoint.

Natureandstructureofpolymers-StructurePropertyrelationships.Glasstransitiontemperature(Tg)anddeterminationofTg,Freevolumetheory,WLFequation,Factorsaffectingglasstransitiontemperature(Tg).

Determinationofmolecularweightofpolymers(Mn,Mw,etc)byend group analysis,viscometry,lightscattering and osmoticpressure methods. Molecular weight distribution and itssignificance.

(5Lectures)

UNIT-IV:PROPERTIESOFPOLYMERS

Brief introduction to preparation, structure, properties andapplicationofthefollowingpolymers:polyolefins,polystyreneandstyrene copolymers,poly(vinylchloride) and relatedpolymers,poly(vinylacetate)andrelatedpolymers,acrylicpolymers,fluoropolymers,polyamidesandrelatedpolymers.Phenolformaldehyde

resins (Bakelite, Novalac), polyurethanes, silicone polymers,polydienes,Polycarbonates,ConductingPolymers,[polyacetylene,polyaniline,poly(p-phenylenesulphidepolypyrrole,polythiophene)].

(10Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Seymour’sPolymerChemistry,MarcelDekker,Inc.2.G.Odian:PrinciplesofPolymerization,JohnWiley.3.F.W.Billmeyer:TextBookofPolymerScience,JohnWiley.4.P.Ghosh:PolymerScience&Technology,TataMcgraw-Hill.5.R.W.Lenz:OrganicChemistryofSyntheticHighPolymers.

CourseTitle InorganicChemistry–IV

CourseCode BSC6CH05


3 0 0 3

Prerequisites --

Courseobjectives

CourseContents UNIT-I:THEORETICALPRINCIPLESINQUALITATIVEANALYSIS(H2SSCHEME)Basicprinciplesinvolvedinanalysisofcationsandanionsandsolubility products,common ion effect.Principles involved inseparationofcationsintogroupsandchoiceofgroupreagents.Interfering anions(fluoride,borate,oxalateand phosphate)andneedtoremovethem afterGroupII.

(10Lectures)UNIT-II:ORGANOMETALLICCOMPOUNDSDefinitionandclassificationoforganometalliccompoundsonthebasisofbondtype.Conceptofhapticityoforganicligands.Metalcarbonyls:18 electron rule,electron count of mononuclear,polynuclearandsubstitutedmetalcarbonylsof3dseries.Generalmethods of preparation (direct combination, reductivecarbonylation,thermalandphotochemicaldecomposition)ofmonoandbinuclearcarbonylsof3dseries.StructuresofmononuclearandbinuclearcarbonylsofCr,Mn,Fe,CoandNiusingVBT.π-acceptorbehaviourofCO (MO diagram ofCO tobediscussed),synergic effectand use ofIR data to explain extentofbackbonding.Zeise’s salt:Preparation and structure,evidences ofsynergiceffectand comparison ofsynergiceffectwith thatincarbonyls.

(13Lectures)

UNIT-III:MetalAlkyls:Importantstructuralfeatures of methyllithium(tetramer)andtrialkylaluminium (dimer),conceptofmulticentrebonding in these compounds. Role of triethylaluminium inpolymerisation of ethene (Ziegler– Natta Catalyst).SpeciespresentinethersolutionofGrignardreagentandtheirstructures,Schlenkequilibrium.Ferrocene: Preparation and reactions (acetylation, alkylation,metallation,Mannich Condensation).Structure and aromaticity.Comparisonofaromaticityandreactivitywiththatofbenzene.

(12Lectures)

UNIT-IV:CATALYSISBYORGANOMETALLICCOMPOUNDSStudyofthefollowingindustrialprocessesandtheirmechanism:

1.Alkenehydrogenation(WilkinsonsCatalyst)2.Hydroformylation(Cosalts)3.WackerProcess

4.Syntheticgasoline(FischerTropschreaction)5.Synthesisgasbymetalcarbonylcomplexes

(10Lectures)Courseoutcomes

TextandReferences

1.Sharpe,A.G.InorganicChemistry,4thIndianReprint(PearsonEducation)2005

2.Lee,J.D.ConciseInorganicChemistry5thEd.,JohnWileyandsons2008.

3.Shriver,D.D.&P.Atkins,InorganicChemistry2ndEd.,OxfordUniversityPress,1994.

4.Basolo,F.&Person,R.MechanismsofInorganicReactions:StudyofMetalComplexesinSolution2ndEd.,JohnWiley&SonsInc;NY.

5.Miessler,G.L.&Donald,A.Tarr,InorganicChemistry4thEd.,Pearson,2010.

6.Crabtree,RobertH.TheOrganometallicChemistryoftheTransitionMetals.NewYork,NY:JohnWiley,2000.

CourseTitle INORGANICCHEMISTRY-III

CourseCode BSC5CH03


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:ACIDSANDBASE

Brönsted-Lowryconceptofacid-basereactions,solvatedproton,relativestrengthofacids,typesofacid-basereactions,levellingsolvents,Lewisacid-baseconcept,ClassificationofLewisacids,Hard and SoftAcids and Bases (HSAB)Application ofHSABprinciple,pKa,Henderson–Hasselbachequation,pHofweakacidsandbases,buffersolutions.

(5Lectures)

UNIT-II:COORDINATIONCHEMISTRYIUPAC nomenclature ofcoordination compounds,isomerism incoordinationcompounds.Stereochemistryofcomplexeswith4and6 coordination numbers.Chelateeffect,polynuclearcomplexes,Labileandinertcomplexes.Werner’stheory,valencebondtheory(innerandouterorbitalcomplexes),electroneutralityprincipleandbackbonding.Crystalfieldtheory,measurementof10Dq(o),CFSEinweakandstrongfields,pairingenergies,factorsaffectingthemagnitudeof10Dq(o,t).Octahedralvs.tetrahedralcoordination,tetragonal distortions from octahedral geometry Jahn-Tellertheorem,squareplanargeometry.QualitativeaspectofLigandfieldandMOTheory.

(20Lectures)

UNIT-III:TRANSITIONELEMENTSGeneral group trends with special reference to electronic

configuration,colour,variable valency,magnetic and catalytic

properties,abilitytoform complexes.Stabilityofvariousoxidation

states and e.m.f.(Latimer & Bsworth diagrams).Difference

betweenthefirst,secondandthirdtransitionseries.Chemistryof

Ti,V,CrMn,FeandCoinvariousoxidationstates(excludingtheir

metallurgy)

(20Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS

1. Huheey,J.E.;Keiter,E.A.& Keiter,R.L.InorganicChemistry,Principles ofStructure and Reactivity 4th Ed.,HarperCollins1993,Pearson,2006.

2. Sharpe,A.G.Inorganic Chemistry,4th Indian Reprint(PearsonEducation)2005

3. Lee,J.D.ConciseInorganicChemistry5thEd.,JohnWileyandsons2008.

4. Shriver,D.D.& P.Atkins,Inorganic Chemistry2ndEd.,OxfordUniversityPress,1994.

5. Basolo,F.& Person,R.Mechanisms of InorganicReactions:StudyofMetalComplexes in Solution 2nd Ed.,JohnWiley&SonsInc;NY.

6. Miessler,G.L.& Donald,A.Tarr,InorganicChemistry4thEd.,Pearson,2010.

7. Collman,JamesP.etal.PrinciplesandApplicationsofOrganotransitionMetalChemistry.MillValley,CA:UniversityScienceBooks,1987.

8. Crabtree,RobertH.TheOrganometallicChemistryoftheTransitionMetals.jNewYork,NY:JohnWiley,2000.

CourseTitle OrganicChemistry–III

CourseCode BSC5CH01


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:ALCOHOLS,PHENOLS,ETHERS,EPOXIDES,THIOLS ANDTHIOETHERS

Alcohols:preparation,propertiesandrelativereactivityof1°,2°,3°alcohols,Bouvaelt-BlancReduction;Preparationandpropertiesofglycols:Oxidationbyperiodicacidandleadtetraacetate,Pinacol-Pinacolone rearrangement;Phenols:Preparation and properties;Acidity and factors effecting it,Ring substitution reactions,Reimer–TiemannandKolbe’s–SchmidtReactions,FriesandClaisenrearrangementswithmechanism;EthersandEpoxides:Preparationand reactions with acids.Reactions ofepoxides with alcohols,ammoniaderivativesandLiAlH4.Preparationandreactionsofthiols,thioethersandsulphonicacids.

(15Lectures)

UNIT-II:CARBONYLCOMPOUNDS

Structure, reactivity and preparation;Nucleophilic additions,Nucleophilic addition-elimination reactions with ammoniaderivativeswith mechanism;MechanismsofAldoland Benzoincondensation,Knoevenagelcondensation,Claisan-Schmidt,Perkin,CannizzaroandWittigreaction,BeckmannandBenzil-Benzilicacidrearrangements,haloform reactionandBaeyerVilligeroxidation,α-substitution reactions,oxidations and reductions (Clemmensen,Wolff-Kishner, LiAlH4, NaBH4, MPV, PDC and PGC);Additionreactions of unsaturated carbonyl compounds: Michaeladdition.Active methylene compounds:Keto-enoltautomerism.Preparationandsyntheticapplicationsofdiethylmalonateandethylacetoacetate.

(15Lectures)

UNIT-III:CARBOXYLICACIDSANDTHEIRDERIVATIVES

Preparation,physicalpropertiesandreactionsofmonocarboxylicacids:Typicalreactionsofdicarboxylicacids,hydroxyacidsandunsaturated acids:succinic/phthalic,lactic,malic,tartaric,citric,maleic and fumaric acids;Preparation and reactions of acidchlorides,anhydrides,estersand amides;Comparativestudyofnucleophilicsustitutionatacylgroup-Mechanism ofacidicandalkalinehydrolysisofesters,Claisencondensation,DieckmannandReformatsky reactions, Hofmann-bromamide degradation andCurtiusrearrangement.

(10Lectures)

UNIT-IV:NITROGENCONTAININGFUNCTIONALGROUPS

Preparation and importantreactions ofnitro and compounds,nitrilesandisonitrilesAmines:Effectofsubstituentandsolventonbasicity;Preparationandproperties:Gabrielphthalimidesynthesis,Carbylaminereaction,Mannichreaction,Hoffmann’sexhaustivemethylation,Hofmann-eliminationreaction;Distinctionbetween1°,2°and3°amineswithHinsbergreagentandnitrousacid.Diazonium Salts:Preparationandtheirsyntheticapplications.

(5Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Morrison,R.T.&Boyd,R.N.OrganicChemistry,DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

2.Finar,I. L. Organic Chemistry (Volume 1),DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

3.Finar,I.L.OrganicChemistry(Volume2:StereochemistryandtheChemistryofNaturalProducts),DorlingKindersley(India)Pvt.Ltd.(PearsonEducation).

4.Acheson, R.M. Introduction to the Chemistry ofHeterocycliccompounds,JohnWelly&Sons(1976).

CourseTitle PhysicalChemistry–IV

CourseCode BSC5CH02


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:PHASEEQUILIBRIA

Concept of phases,components and degrees of freedom,derivation ofGibbs Phase Rule fornonreactive and reactivesystems;Clausius-Clapeyronequationanditsapplicationstosolid-liquid,liquid-vapourandsolid-vapourequilibria,phasediagram forone componentsystems,with applications.Phase diagrams forsystemsofsolid-liquidequilibriainvolvingeutectic,congruentandincongruent melting points,solid solutions.Three componentsystems,water-chloroform-aceticacidsystem,triangularplots.

(20Lectures)

UNIT-II:Binarysolutions:Gibbs-Duhem-Margules equation,its derivationandapplicationstofractionaldistillationofbinarymiscibleliquids(idealandnonideal),azeotropes,leverrule,partialmiscibilityofliquids,CST,misciblepairs,steam distillation.Nernstdistributionlaw:itsderivationandapplications.

(10Lectures)

UNIT-III:SURFACECHEMISTRY

Physicaladsorption,chemisorption,adsorptionisotherms.natureofadsorbedstate.Typesofadsorption,adsorptionisotherms-FreundlichandLangmuir;Colloidsandcolloidsstate,applicationofcolloids,surfactants,micelles,criticalmicelleconcentration,BasicsofsurfacecharacterizationbyX-RayandDLS.

(10Lectures)

UNIT-IV:CATALYSIS

Types ofcatalyst,specificity and selectivity,mechanisms ofcatalyzedreactionsatsolidsurfaces;effectofparticlesizeandefficiency of nanoparticles as catalysts. Enzyme catalysis,Michaelis-Mentenmechanism,acid-basecatalysis.

(5Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Atkins,P.W &Paula,J.D.PhysicalChemistry,9th Ed.,OxfordUniversityPress(2011).

2.Castellan,G.W.PhysicalChemistry4thEd.,Narosa(2004).3.Mortimer,R.G.PhysicalChemistry3rdEd.,Elsevier:NOIDA,

UP(2009).4.Barrow,G.M.,PhysicalChemistry5thEd.,TataMcGraw Hill:

NewDelhi(2006).5.Engel,T.&Reid,P.PhysicalChemistry3rdEd.,Prentice-Hall

(2012).6.Rogers,D.W.ConcisePhysicalChemistryWiley(2010).

CourseTitle PhysicalChemistry–V

CourseCode BSC5CH04


3 0 0 3

Prerequisites --

Courseobjectives

CourseContentsUNIT-I:CONDUCTANCEArrheniustheoryofelectrolyticdissociation.Conductivity,

equivalentandmolarconductivityandtheirvariationwithdilution

forweakandstrongelectrolytes.Molarconductivityatinfinite

dilution.Kohlrauschlawofindependentmigrationofions.Debye-

Hückel-Onsagerequation,Wieneffect,Debye-Falkenhageneffect,

Walden’srules.

(10Lectures)

UNIT-II:TRANSPORTSTUDIESOFIONS

Ionicvelocities,mobilitiesandtheirdeterminations,transferencenumbersand theirrelationto ionicmobilities,determinationoftransferencenumbersusingHittorfandMovingBoundarymethods.Applications of conductance measurement: (i) degree ofdissociationofweakelectrolytes,(ii)ionicproductofwater(iii)solubility and solubility productofsparingly soluble salts,(iv)conductometrictitrations,and(v)hydrolysisconstantsofsalts.

(10Lectures)UNIT-III:ELECTROCHEMISTRYQuantitative aspectsofFaraday’slawsofelectrolysis,rulesof

oxidation/reductionofionsbasedonhalf-cellpotentials,

Chemicalcells,reversible and irreversible cells with examples.Electromotiveforceofacellanditsmeasurement,Nernstequation;Standard electrode (reduction)potentialand its application todifferentkindsofhalf-cells.ApplicationofEMFmeasurementsindetermining(i)freeenergy,enthalpyandentropyofacellreaction,(ii)equilibrium constants,and (iii)pH values,using hydrogen,quinone-hydroquinone, glass and SbO/Sb2O3 electrodes.Concentrationcellswithandwithouttransference,liquidjunctionpotential;determinationofactivitycoefficientsandtransferencenumbers.Qualitativediscussionofpotentiometrictitrations(acid-base,redox,precipitation).

(15Lectures)

UNIT-IV:APPLICATION OF ELECTROCHEMISTRY:CORROSIONSCIENCECorrosion principle, electrochemical aspects, environmental

effects,metallurgicalaspects,eightformsofcorrosion:Galvanic,

crevice,pitting,intergranular,selectiveleaching,erosion-corrosion,

stress corrosion,and hydrogen damage.Basics ofcorrosion

prevention:materialselection,alterationofenvironment,design,

cathodicandanodicprotectionandcoatings.

(10Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1.Banwell,C.N.&McCash,E.M.FundamentalsofMolecularSpectroscopy4thEd.TataMcGraw-Hill:NewDelhi(2006).

2.Chandra,A. K. Introductory Quantum Chemistry TataMcGraw-Hill(2001).

3.House,J.E.FundamentalsofQuantum Chemistry2nd Ed.Elsevier:USA(2004).

4.Lowe,J.P.&Peterson,K.Quantum Chemistry,AcademicPress(2005).

5.Kakkar,R.Atomic& MolecularSpectroscopy,CambridgeUniversityPress(2015).

CourseTitle ANALYTICALCHEMISTRY

CourseCode BSC6CH04


3 0 0 3

Prerequisites --

Courseobjectives

CourseContents

UNIT-I:QUALITATIVEANDQUANTITATIVEASPECTSOFANALYSIS

Sampling,evaluation of analyticaldata,errors,accuracy andprecision,methodsoftheirexpression,normallawofdistributionifindeterminateerrors,statisticaltestofdata;F,Qandttest,rejectionofdata,andconfidenceintervals.

Flame Atomic Absorption and Emission Spectrometry:Basicprinciplesofinstrumentation(choiceofsource,monochromator,detector,choice offlame and Burnerdesigns.Techniques ofatomization and sample introduction;Method of backgroundcorrection,sourcesofchemicalinterferencesandtheirmethodofremoval.

(15Lectures)

UNIT-II:THERMALMETHODSOFANALYSIS&SEPARATIONTECHNIQUES

Theoryofthermogravimetry(TG),basicprincipleofinstrumentation.TechniquesforquantitativeestimationofCaandMgfrom theirmixture.Solventextraction:Classification,principleand efficiencyofthetechnique.Mechanism ofextraction:extractionbysolvationandchelation.Techniqueofextraction:batch,continuousandcountercurrentextractions.Qualitativeandquantitativeaspectsofsolventextraction: extraction of metal ions from aqueous solution,extractionoforganicspeciesfrom theaqueousandnonaqueousmedia.

(10Lectures)

UNIT-III:CHROMATOGRAPHY

Chromatography:Classification,principle and efficiency ofthetechnique.Mechanism ofseparation:adsorption,partition & ionexchange.Developmentof chromatograms:frontal,elution anddisplacement methods.Qualitative and quantitative aspects ofchromatographicmethodsofanalysis:IC,GLC,GPC,TLCandHPLC.Stereoisomericseparationandanalysis:Measurementofopticalrotation,calculationofEnantiomericexcess(ee)/diastereomericexcess(de)ratiosanddeterminationofenantiomericcompositionusing NMR,Chiralsolvents and chiralshift reagents.Chiralchromatographictechniquesusingchiralcolumns(GCandHPLC).


TextandReferences

ReferenceBooks:

1.Vogel,ArthurI:A TestbookofQuantitativeInorganic

Analysis(Rev.byG.H.Jefferyandothers)5th

Ed.TheEnglishLanguageBookSocietyofLongman.

2.Willard,Hobert H.et al.:InstrumentalMethods ofAnalysis, 7

thEd. Wardsworth Publishing Company,

Belmont,California,USA,1988.

3.Christian,GaryD;AnalyticalChemistry,6th

Ed.JohnWiley&Sons,NewYork,2004.

4.Harris,DanielC:ExploringChemicalAnalysis,Ed.NewYork,W.H.Freeman,2001.

5.Khopkar,S.M.BasicConceptsofAnalyticalChemistry.NewAge,InternationalPublisher,2009.

6.Skoog,D.A.HollerF.J.andNieman,T.A.PrinciplesofInstrumentalAnalysis,ThomsonAsiaPvt.Ltd.Singapore.

7.Mikes,O.& Chalmes,R.A.LaboratoryHand Book ofChromatographic& AlliedMethods,EllesHarwoodLtd.London.

8.Ditts,R.V.AnalyticalChemistry–Methodsofseparation.

CourseTitle ApplicationsofComputersinChemistry

CourseCode BSF6CA02


2 1 0 2

Prerequisites --

Courseobjectives

CourseContentsUNIT-I:NUMERICALMETHODS-IISimultaneousequations:Matrixmanipulation:addition,multiplication.Gauss-Siedalmethod.Interpolation,extrapolationandcurvefitting:Handlingofexperimentaldata.

(20Lectures)UNIT-II:

Conceptualbackgroundofmolecularmodelling:Potentialenergysurfaces.ElementaryideasofmolecularmechanicsandpracticalMOmethods.

(10Lectures)

Courseoutcomes

TextandReferences

ReferenceBooks:

1.Harris,D.C.Quantitative ChemicalAnalysis.6th

Ed.,Freeman(2007)Chapters3-5.

2.Levie,R.de,How to useExcelin analyticalchemistryand ingeneralscientificdataanalysis,CambridgeUniv.Press(2001)487pages.

3.Noggle,J.H.PhysicalchemistryonaMicrocomputer.LittleBrown&Co.(1985).

4.Venit, S.M. Programming in BASIC: Problem solving with

structureandstyle.JaicoPublishingHouse:Delhi(1996).

CourseTitle InorganicChemistry–V

CourseCode BSC6CH03


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:LANTHANOIDSANDACTINOIDSElectronic configuration,oxidation states,colour,spectralandmagnetic properties, lanthanide contraction, separation oflanthanides(ion-exchangemethodonly).

(7Lectures)

UNIT-II:NOBLEGASESOccurrenceanduses,rationalizationofinertnessofnoblegases,Clathrates;preparation and properties ofXeF2,XeF4 and XeF6;Nature of bonding in noble gas compounds (Valence bondtreatmentandMOtreatmentforXeF2).Molecularshapesofnoblegascompounds(VSEPRtheory).

(8Lectures)

UNIT-III:BIOINORGANICCHEMISTRYMetalionspresentinbiologicalsystems,classificationofelementsaccordingtotheiractioninbiologicalsystem.Geochemicaleffectonthedistributionofmetals.Sodium /K-pump,carbonicanhydraseand carboxypeptidase.Excess and deficiency ofsome tracemetals.Toxicityofmetalions(Hg,Pb,CdandAs),reasonsfortoxicity,Use of chelating agents in medicine.Iron and itsapplicationinbio-systems,Haemoglobin;Storageandtransferofiron.

(15Lectures)UNIT-IV:REACTIONKINETICSANDMECHANISMIntroduction to inorganic reaction mechanisms. Substitutionreactionsinsquareplanarcomplexes,Trans-effect,theoriesoftrans effect,Mechanism ofnucleophilic substitution in squareplanarcomplexes,ThermodynamicandKineticstability,Kineticsofoctahedralsubstitution,Ligand field effectsand reaction rates,Mechanism ofsubstitutioninoctahedralcomplexes.

(15Lectures)

Courseoutcomes

TextandReferences

1. Huheey,J.E.;Keiter,E.A.&Keiter,R.L.InorganicChemistry,PrinciplesofStructureandReactivity4thEd.,HarperCollins1993,Pearson,2006.

2. Sharpe,A.G.InorganicChemistry,4thIndianReprint(PearsonEducation)2005

3. Lee,J.D.ConciseInorganicChemistry5thEd.,JohnWileyandsons2008.

4. Shriver,D.D.&P.Atkins,InorganicChemistry2ndEd.,OxfordUniversityPress,1994.

5. Basolo,F.&Person,R.MechanismsofInorganicReactions:StudyofMetalComplexesinSolution2ndEd.,JohnWiley&SonsInc;NY.

6. Miessler,G.L.&Donald,A.Tarr,InorganicChemistry4thEd.,Pearson,2010.

7. Crabtree,RobertH.TheOrganometallicChemistryoftheTransitionMetals.NewYork,NY:JohnWiley,2000.

CourseTitle OrganicChemistry–IV

CourseCode BSC6CH01


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:CARBOHYDRATESOccurrence,classificationandtheirbiologicalimportance.Monosaccharides:Constitution and absolute configuration ofglucose and fructose, epimers and anomers, mutarotation,determination ofring size ofglucose and fructose,Haworthprojections and conformationalstructures;Interconversions ofaldoses and ketoses; Killiani-Fischer synthesis and Ruffdegradation; Disaccharides, Polysaccharides – Elementarytreatmentofstarch,celluloseandglycogen.

(10Lectures)

UNIT-II:AMINOACIDS,PEPTIDES,AND PROTEINSAND NUCLEICACIDSClassificationofaminoacids,stereochemistryofaminoacids,acid-base behavior of amino acids,electrophoresis,synthesis ofaminoacids,reactionsofaminoacids,peptides,peptidestructuredetermination: Amino acid analysis; peptide structuredetermination:sequence analysis,end-group analysis,selectivehydrolysisofpeptides,peptidesynthesis,aminogroupprotection,carboxylgroup protection,peptide bond formation,solid-phasepeptidesynthesis,secondarystructureofpeptidesandproteins,tertiarystructure ofpeptides and proteins,coenzymes,proteinquaternarystructure:Hemoglobin.

(10Lectures)UNIT-III:POLYMERSIntroduction and classification including di-block,tri-block andamphiphilicpolymers;Numberaveragemolecularweight,Weightaveragemolecularweight,Degreeofpolymerization,PolydispersityIndex.Polymerisation reactions -Addition and condensation -Mechanism of cationic, anionic and free radical additionpolymerization;Metallocene-basedZiegler-Nattapolymerisationofalkenes;Preparationandapplicationsofplastics–thermosetting(phenol-formaldehyde,Polyurethanes)andthermosoftening(PVC,polythene);Fabrics – naturaland synthetic (acrylic,polyamido,polyester);Rubbers – natural and synthetic: Buna-S,Chloroprene andNeoprene;Vulcanization;Polymeradditives;Introductiontoliquidcrystalpolymers;Biodegradable and conducting polymers withexamples.

(10Lectures)

UNIT-IV:BIOLOGICALLYCOMPOUNDS:PHARMACEUTICALSANDALKALOIDSClassification,structure and therapeutic uses of antipyretics:Paracetamol (with synthesis), Analgesics: Ibuprofen (withsynthesis), Antimalarials: Chloroquine (with synthesis). Anelementary treatment of Antibiotics and detailed study ofchloramphenicol,Medicinalvaluesofcurcumin(haldi),azadirachtin(neem),vitamin C and antacid (ranitidine).Alkaloids:Naturaloccurrence, General structural features, Isolation and theirphysiologicalaction.Hoffmann’sexhaustivemethylation,Emde’smodification,StructureelucidationandsynthesisofHygrineandNicotine.Medicinalimportance of Nicotine,Hygrine,Quinine,Morphine,Cocaine,andReserpine.


TextandReferences

REFERENCEBOOKS:

1. Berg,J.M.,Tymoczko,J.L.and Stryer,L.(2006)Biochemistry.VIthEdition.W.H.FreemanandCo.

2. Nelson,D.L.,Cox,M.M.and Lehninger,A.L.(2009)Principles ofBiochemistry.IVEdition.W.H.FreemanandCo.

3. Murray,R.K.,Granner,D.K.,Mayes,P.A.and Rodwell,V.W.(2009)Harper’sIllustratedBiochemistry.XXVIIIedition.LangeMedicalBooks/McGraw-Hill

CourseTitle PhysicalChemistry–VI

CourseCode BSC6CH02


3 0 2 5

Prerequisites --

Courseobjectives

CourseContents UNIT-I:ELECTRICAL&MAGNETICPROPERTIESOFATOMSANDMOLECULESBasicideasofelectrostatics,Electrostaticsofdielectricmedia,Clausius-Mosotti equation, Lorenz-Laurentz equation, Dipolemomentandmolecularpolarizabilitiesandtheirmeasurements.Diamagnetism,paramagnetism,magnetic susceptibility and itsmeasurement,molecularinterpretation.

(10Lectures)UNIT-II:MOLECULARSPECTROSCOPY-IInteractionofelectromagneticradiationwithmoleculesandvarious

typesofspectra;Born-Oppenheimerapproximation.

Rotationspectroscopy:Selectionrules,intensitiesofspectrallines,

determinationofbond lengthsofdiatomicand lineartriatomic

molecules,isotopicsubstitution.

Vibrational spectroscopy: Classical equation of vibration,computationofforceconstant,amplitudeofdiatomicmolecularvibrations,anharmonicity,Morsepotential,dissociationenergies,fundamental frequencies,overtones,hot bands,degrees offreedom forpolyatomicmolecules,modesofvibration,conceptofgroup frequencies. Vibration-rotation spectroscopy: diatomicvibratingrotator,P,Q,Rbranches.

(10Lectures)UNIT-III:MOLECULARSPECTROSCOPY-IIRamanspectroscopy:QualitativetreatmentofRotationalRamaneffect;Effectofnuclearspin,VibrationalRamanspectra,Stokesand anti-Stokes lines;theirintensitydifference,rule ofmutualexclusion.Electronic spectroscopy: Franck-Condon principle, electronictransitions, singlet and triplet states, fluorescence andphosphorescence,dissociationandpredissociation,calculationofelectronictransitionsofpolyenesusingfreeelectronmodel.NuclearMagneticResonance(NMR)spectroscopy:PrinciplesofNMR spectroscopy,Larmorprecession,chemicalshiftand lowresolutionspectra,differentscales,spin-spincouplingandhighresolution spectra,interpretation of PMR spectra of organicmolecules.Electron Spin Resonance (ESR) spectroscopy: Its principle,

hyperfinestructure,ESRofsimpleradicals.

(15Lectures)

UNIT-IV:PHOTOCHEMISTRYCharacteristicsofelectromagneticradiation,Lambert-Beer’slawanditslimitations,physicalsignificanceofabsorptioncoefficients.Laws,ofphotochemistry,quantum yield,actinometry,examplesoflow andhighquantum yields,photochemicalequilibrium andthedifferential rate of photochemical reactions,photosensitisedreactions, quenching. Role of photochemicalreactions inbiochemical processes, photostationary states,chemiluminescence.

(10Lectures)

Courseoutcomes

TextandReferences

REFERENCEBOOKS:

1. Banwell,C.N.&McCash,E.M.FundamentalsofMolecularSpectroscopy4thEd.TataMcGraw-Hill:NewDelhi(2006).

2. Chandra,A.K.IntroductoryQuantum ChemistryTataMcGraw-Hill(2001).

3. House,J.E.FundamentalsofQuantum Chemistry2nd Ed.Elsevier:USA(2004).

4. Lowe,J.P.& Peterson,K.Quantum Chemistry,AcademicPress(2005).

5. Kakkar,R.Atomic & MolecularSpectroscopy,CambridgeUniversityPress(2015).

Documents

Proposed Syllabus for B.Sc.-Chemical Science at GSFC ... Ch.pdf · L T P Theory Practical 1 BSC3CH01 Chemistry - V Core Organic Chemistry – II 3 2 5 100 50 150 2 BSC3CH02 Chemistry