Curriculum Vitae

THOMAS JAMES MCCARTHY

Professor

Polymer Science and Engineering University of Massachusetts

Amherst, Massachusetts 01003

Education

Massachusetts Institute of Technology, Cambridge, MA 02139 Ph.D. in Organic Chemistry, June 1982 Advisor: George M. Whitesides

Thesis: Surface Chemistry of Platinum and Polyethylene

University of Massachusetts, Amherst, MA 01003 B.S. (summa cum laude) in Chemistry, June 1978 Advisor: C. Peter Lillya Thesis: Metal-Carbon Bonding in Small Ring Organometallic Complexes

Positions

Assistant Professor, University of Massachusetts, Amherst September 1982 - August 1986

Associate Professor, University of Massachusetts, Amherst September 1986 - August 1991

Professor, University of Massachusetts, Amherst September 1991- June 2000, November 2003 - present

Head, Polymer Science and Engineering July 2000 - October 2003

Guest Professor, Changchun Institute of Applied Chemistry July 2006 - present

Awards and Honors

Univ of Mass "Centennial Award - Outstanding Faculty Member" 2008 Univ of Mass "Outstanding Accomplishments in Research and Creative Activity" 2008

Univ of Mass "Milestone Award" (5th patent issued) 2006 ACS Colloids and Surfaces Division Langmuir Lecture 2006

Univ of Mass "Conti Faculty Fellowship" 2000 Univ of Mass “125 Alumni-to-Watch” 1998

Arthur K. Doolittle Award 1996 NSF Presidential Young Investigator Award 1986-1991

Office of Naval Research Young Investigator Award 1985-1987 3M Young Faculty Award 1982-1985

IBM Faculty Development Award 1983, 1984 National Science Foundation Graduate Fellow 1978-1981

Professional Activities

Co-Chairman, International Symposium on Polymer Chemistry Director, UMASS Institute for Interface Science

Editorial Advisory Board, Heteroatom Chemistry Editorial Advisory Board, Journal of Applied Polymer Science

Editorial Advisory Board, Langmuir (currently active) Editorial Advisory Board, Macromolecules

Editorial Advisory Board, Chinese Journal of Applied Chemistry (currently active) International Advisory Board, ACS Polymer Surfaces and Interfaces Series

Science Advisory Boards: Henkel, ShockingTechnologies Previous Coworkers Present Employer

Ilke Anac (Ph.D.) Gebze Institute of Technology Kelyn A. Arora (Ph.D.) Procter and Gamble Prof. Ricardo Baumhardt UFRGS Porto Allegre, Brasil Timothy G. Bee (Ph.D.) International Specialty Products Robert C. Bening (Ph.D.) Kraton Polymers James A. Bonafini (M.S.) Consultant Joan V. Brennan (Ph.D.) 3M Ebru Cataltarla (Ph.D.) Alvimedica Xue Cai (M.S.) University of Massachusetts Chuntao Cao (Ph.D.) 3M Terrence C. Caskey (Ph.D.) Invensas Dalton Cheng (Ph.D.) AIST Nagoya Catherine G. Coleman (Ph.D.) NASA Christine A. Costello (Ph.D.) ExxonMobil Wei Chen (Ph.D.) Mt. Holyoke College Elisa M. Cross (Ph.D.) 3M Dhamodharan R (Ph.D.) IIT, Madras Anthony J. Dias (Ph.D.) ExxonMobil Zerlina Dubois (M.S.) Procter and Gamble Scott Eastman (Ph.D.) NIST Dr. Alexander Fadeev Seton Hall University Dr. Jianxin Feng Shamrock Technologies Robert J. Fleming (Ph.D.) ShockingTechnologies Nicole L. Franchina (Ph.D.) 3M (retired) Dr. Lichao Gao Procter and Gamble Heather J. Hayes (Ph.D.) Milliken Corporation Meng C. Hsieh (Ph.D.) Atotech Margarita Herrera-Alonso (Ph.D.) Johns Hopkins University Voravee Hoven (Vipavee) (Ph.D.) Chulalungkorn University Jayaraman K (Ph.D.) Dow Chemical Xinqiao Jia (Ph.D.) University of Delaware Dr. Yasuhiko Iwasaki Kansei University Anthony Karandinos (Ph.D.) Megaplast Takahisa Kato Mitsubishi Paper Mills Eric W. Kendall (Ph.D.) WilsonArt Bokyung Kim (Ph.D.) MIT Gene Kim (Ph.D.) Cookson Electronics Taehyung Kim (Ph.D.) UC Riverside Brant U. Kolb (Ph.D.) 3M Mikhail Kozlov (Ph.D.) Millipore Corporation

Edward Kung (Ph.D.) Sabic Richard Larson (Ph.D.) Markem Imaje Dr. Jung Ah Lee Sabic Dr. Kang-Wook Lee IBM Dr. Maria Lerum Mt. Holyoke College Juha-Matti Leväsalmi (Ph.D.) Sabic Zhixiang Lu (Ph.D.) Henkel Dr. Troy Milliken Jackson State University Dr. Sung In Moon Entegris Katherine G. Nelson (M.S.) Eksigent Richard L. Norton (Ph.D.) QLT Didem Öner (Ph.D.) Dow Chemical Penelope A. Patton (Ph.D.) Tate & Lyle Voravee Hoven (Ph.D.) Chulalungkorn University Dr. Padma Rajgopalan Virginia Tech Prof. Sung Hun Ryu Kyunghee University Dr. Xiaoxing Shan BASF Molly S. Shoichet (Ph.D.) University of Toronto Christopher Stafford (Ph.D.) NIST Jan M. Stouffer (Ph.D.) Dupont Zhaohui Su (Ph.D.) Changchun Inst. of Appl. Chem. Katrina R. Viviano (Ph.D.) University of Wisconsin Raul deVincenzi (M.S.) deceased David A. Waldman (Ph.D.) Dow Corning Dr. Susan Walker ? James J. Watkins (Ph.D.) University of Massachusetts Kevin Wier (Ph.D.) Dow Corning Joonsung Yoon (Ph.D.) Axel Plastics Jeffrey P. Youngblood (Ph.D.) Purdue University Yufeng Zhang (M.S) Epsilon Corporation Current Group Year of Study

Joseph Krumpfer (Ph.D.) (5) Peiwen Zheng (Ph.D.) (5) Yan Wang (Ph.D.) (2) Minchao Zhang (Ph.D.) (1) Dr. Liming Wang postdoctoral Dr. Pei Bian postdoctoral Dr. Atsushi Hozumi visiting professor Jacob Hirsch technical specialist

Publications

1. Synth. Commun. 1978, 8, 379 (with W.F. Connor and S.M. Rosenfeld)

"Stereospecific Addition of Dimethylsulfonium Methylide to 9,10-Anthraquinone"

2. J. Am. Chem. Soc. 1981, 103, 1676 (with R.G. Nuzzo and G.M. Whitesides) "Apparent Fluxionality in Diethyl(triethylphosphine)platinum(II), A Coordinately

Unsaturated Intermediate"

3. J. Am. Chem. Soc. 1981, 103, 3396 (with R.G. Nuzzo and G.M. Whitesides) "Mechanisms of the Thermal Decomposition of Diethylbis(triethylphoshine)platinum(II)"

4. J. Am. Chem. Soc. 1981, 103, 3404 (with R.G. Nuzzo and G.M. Whitesides) "Thermal Decomposition of Dicycloalkylbis(triethylphosphine)platinum(II) Complexes"

5. Inorg. Chem. 1981, 20, 1312 (with R.G. Nuzzo and G.M. Whitesides) "Preparation of Tertiary Phosphine-Olefin Complexes of Platinum(II)"

6. Proc. Natl. Acad. Sci. 1981, 78, 4649 (with Y.S. Shih and G.M. Whitesides) "Heterogeneous Platinum-Catalyzed Hydrogenation of Dialkyl(diolefin) Complexes: A New Route to Platinum Surface Alkyls"

7. Ann. N.Y. Acad. Sci. 1983, 415, 56 (with G.M. Whitesides, R.H. Reamey, R.L. Brainard and A.N. Izumi) "Organometallic Reactions of Platinum Involving Platinum Hydrides"

8. Macromolecules 1984, 17, 2529 (with A.J. Dias) "Synthesis of a Two-Dimensional Array of Organic Functional Groups"

9. Macromolecules 1984, 17, 2939 (with P.A. Patton) "Ring Strain is Not an Important Factor Contributing to the Rate of Olefin Metathesis Polymerization:

10. Macromolecules 1984, 17, 2940 (with C.A. Costello) "Surface Modification of Poly(tetrafluoroethylene) with Benzoin Dianion"

11. J. Appl. Polym. Sci. 1984, 29, 4335 (with D.R. Gagnon) "Polymer Surface Reconstruction by Diffusion of Organic Functional Groups from and to the Surface"

12. J. Polym. Sci. Polym. Lett. Ed. 1985, 23, 33 (with J.A. Bonafini, A.J. Dias and Z.A. Guzdar) "Gravimetric Analysis of Polymer Surface Chemistry: A Sensitive Technique for Monitoring Reactions at Polymer Surfaces"

13. J. Polym. Sci. Polym. Chem. Ed. 1985, 23, 1057 (with A.J. Dias) "Dehydrofluorination of Poly(vinylidene fluoride) in Dimethylformamide Solution: Synthesis of an Operationally Soluble Semiconducting Polymer"

14. Macromolecules 1985, 18, 869 (with A.J. Dias) "Poly(acetylene-co-ethylene) via Isomerization of Poly(1,3-butadiene)"

15. Macromolecules 1985, 18, 1826 (with A.J. Dias) "Surface Modification of Poly(chlorotrifluoroethylene) with Methyllithium"

16. Macromolecules 1985, 18, 2087 (with C.A. Costello) "Electronic Conductivity of Benzoin Dianion-Reduced Poly(tetrafluoroethylene)"

17. Langmuir 1985, 1, 725 (with S.R. Holmes-Farley, R.H. Reamey, J. Deutch and G.M. Whitesides) "Acid-Base Behavior of Carboxylic Acid Groups Covalently Attached at the Surface of Polyethylene: The Usefulness of Contact Angle in Following the Ionization of Surface Functionality"

18. Macromolecules 1986, 19, 1266 (with P.A. Patton and C.P. Lillya) "Olefin Metathesis of Cyclohexene"

19. Macromolecules 1987, 20, 778 (with P.A. Patton) "Factors Influencing the Rate of Tungsten Hexachloride/Tetramethyltin-

Catalyzed Olefin Metathesis Polymerization"

20. Macromolecules 1987, 20, 1437 (with K.-W. Lee) "Poly(chlorotrifluoroethylene) Containing Surface-Confined Hydroxyl Groups:

A Chemically Versatile Model Hydroxylated Surface"

21. CHEMTECH 1987, 17 (July), 442 (with P.A. Patton) "Running the Impossible Reaction: Metathesis of Cyclohexene"

22. Macromolecules 1987, 20, 2068 (with A.J. Dias) "Introduction of Carboxylic Acid, Aldehyde and Alcohol Functional Groups onto

the Surface of Poly(chlorotrifluoroethylene)"

23. Langmuir 1987, 3, 799 (with S.R. Holmes-Farley, R.H. Reamey, R.G. Nuzzo and G.M. Whitesides) "Reconstruction of the Interface of Oxidatively Functionalized Polyethylene and Derivatives on Heating"

24. Macromolecules 1987, 20, 2819 (with C.A. Costello) "Surface-Selective Introduction of Specific Functionalities onto

Poly(tetrafluoroethylene)"

25. Langmuir 1987, 3, 932 (with J.D. Swalen, D.L. Allara, J.D. Andrade, E.A. Chandross, S. Garoff, J. Israelachvili, R. Murray, R.F. Pease, J.F. Rabolt, K.J. Wynne and H.Yu)

"Molecular Monolayers and Films"

26. J. Am. Chem. Soc. 1988, 110, 3156 (with T.M. Miller and G.M. Whitesides) "Deuterium Labeling Experiments Relevant to the Mechanism of Platinum-Catalyzed Hydrogenation of (Diolefin)dialkylplatinum(II) Complexes: Evidence for Isotopic Exchange via Platinum Surface Hydrogen. The Stereochemistry of Reduction"

27. Macromolecules 1988, 21, 309 (with K.-W. Lee) "Surface-Selective Hydroxylation of Polypropylene"

28. Macromolecules 1988, 21, 1204 (with J.M. Stouffer) "Polymer Monolayers Prepared by the Spontaneous Adsorption of Sulfur-

Functionalized Polystyrene on Gold Surfaces"

29. Macromolecules 1988, 21, 2318 (with K.-W. Lee) "Chemistry of Surface-Hydroxylated Poly(chlorotrifluoroethylene)"

30. Macromolecules 1988, 21, 3353 (with K.-W. Lee) "Synthesis of a Polymer Surface Containing Covalently Attached Triethoxysilane

Functionality: Adhesion to Glass"

31. Macromolecules 1989, 22, 1022 (with R.L. Norton) "ω-Norbornenyl Polystyrene: An Olefin Metathesis Polymerizable

Macromonomer"

32. Encyclopedia of Polymer Science and Engineering John Wiley & Sons, Inc., New York: 1989, Supplement Volume, 674 (with W.J. Ward)

"Surface Modification"

33. Macromolecules 1990, 23, 366 (with B.U. Kolb and P.A. Patton) "Reactions of Polystyryl Anions with Poly(chlorotrifluoroethylene) Film at the

Solution-Solid Interface"

34. Macromolecules 1990, 23, 2648 (with R.C. Bening) "Surface Modification of Poly(tetrafluoroethylene-co-hexafluoropropylene).

Introduction of Alcohol Functionality"

35. Concise Encyclopedia of Polymer Science and Engineering Kroschwitz, J.I., Ed., John Wiley & Sons, Inc., New York: 1990, 1152 (with W.J. Ward)

"Surface Modification"

36. J. Chem. Phys. 1990, 92, 6970 (with P. Frantz, S. Granick and D.R. Iyengar) "End Group Effect in Polymer Adsorption: Competitive adsorption of Carboxylic

Acid-Terminated and Unfunctionalized Polystyrene"

37. Macromolecules 1990, 23, 3916 (with E.M. Cross) "Thermal Reconstruction of Surface-Functionalized

Poly(chlorotrifluoroethylene)"

38. Chimia 1990, 44, 11 "Organic Chemistry at Chemically Resistant Polymer Surfaces: Modification of

Surface Reactivity and Surface Properties"

39. Macromolecules 1990, 23, 4344 (with D.R. Iyengar) "Trends in Adsorption of End-Functionalized Polystyrenes by Thin-Layer

Chromatography"

40. Macromolecules 1991, 24, 982 (with M.S. Shoichet) "Convenient Syntheses of Carboxylic Acid Functionalized Fluoropolymer

Surfaces"

41. Macromolecules 1991, 24, 1441 (with M.S. Shoichet) "Surface Modification of Poly(tetrafluoroethylene-co-hexafluoropropylene) by

Adsorption of Poly(L-lysine) from Aqueous Solution"

42. Macromolecules 1991, 24, 3045 (with N.L. Franchina) "Surface Modifications of Poly(ether ether ketone)"

43. Macromolecules 1991, 24, 5886 (with D.R. Iyengar and J.V. Brennan) "Spontaneous Adsorption of Polystyrene from Solution to the Cyclohexane -

Poly(vinylidene fluoride) Interface"

44. Materials Synthesis Based on Biological Processes (M. Alper, P.C. Rieke, R. Frankel, P.D. Calvert and D.T. Tirrell, Eds.), Materials Research Society, 1991 (with M.S. Shoichet)

"Poly(L-lysine) Adsorption to Fluoropolymer Films"

45. Chemically Modified Surfaces (H.A. Mottola and J.R. Steinmetz, Eds.) Elsevier, 1992 (with N.L. Franchina)

"Poly(ether ether ketone) Surface Chemistry"

46. Macromolecules 1992, 25, 2093 (with T.G. Bee) "Surface Modification of Poly(chlorotrifluoroethylene): Introduction of Reactive

Carboxylic Acid Functionality"

47. Macromolecules 1992, 25, 2603 (with E.M. Cross) "Radical Chlorination of Polyethylene Film: Control of Surface Selectivity"

48. J. Adhesion Sci. Technol. 1992, 6, 719 (with T.G. Bee, E.M. Cross, A.J. Dias, K.-W. Lee, M.S. Shoichet)

"Control of Wettability of Polymers Using Organic Surface Chemistry"

49. J. Appl. Electrochem. 1993, 23, 86 (with T.A. Zawodzinski Jr., S. Gottesfeld, M.S. Shoichet)

"The Contact Angle between Water and the Surface of Perfluorosulfonic Acid Membranes"

50. Contact Angle, Wettability and Adhesion (K.L. Mittal, Ed.) VSP, 1993 (with T.G. Bee, E.M. Cross, A.J. Dias, K.-W. Lee, M.S. Shoichet)

"Control of Wettability of Polymers Using Organic Surface Chemistry"

51. Macromolecules 1994, 27, 4845 (with J.J. Watkins) “Polymerization in Supercritical Fluid Swollen Polymers: A New Route to Polymer Blends”

52. Macromolecules 1995, 28, 358 (with Y. Ren, M.S. Shoichet, H.D. Stidham and S.L. Hsu) “Spectroscopic Characterization of Polymer Adsorption at the Air-Solution Interface”

53. Macromolecules 1995, 28, 492 (with T.L. Mansfield, D.R. Iyengar, G. Beaucage and R.S. Stein)

“Neutron Reflectivity Studies of End-Grafted Polymers”

54. Macromolecules 1995, 28, 1733 (with J.-M. Leväsalmi) “Gas Permeability of Surface-Selectively Chlorinated Poly(4-methyl-1-pentene)”

55. Macromolecules 1995, 28, 4067 (with J.J. Watkins) “Polymerization of Styrene in Supercritical CO2-Swollen Poly(chlorotrifluoroethylene)”

56. Organic Thin Films and Surfaces: Directions for the Nineties (Thin Films, vol. 20; A. Ulman, Ed.) Academic Press, 1995 (with T.G. Bee, J.V. Brennan, E.M. Cross, A.J. Dias, N.L. Franchina, K.-W. Lee, M.S. Shoichet)

“Polymer Surface Modification”

57. Chem. Mat. 1995, 7, 1991 (with J.J. Watkins) “Polymer/Metal Nanocomposite Synthesis in Supercritical CO2”

58. Step-Growth Polymers for High-Performance Materials (ACS Symposium Series No. 624); J. Hedrick and J. Labadie, Eds.) American Chemical Society, 1996 (with T. Ho et al.)

59. Macromolecules 1997, 30, 78 (with W. Chen) “Layer-by-Layer Deposition: A Tool for Polymer Surface Modification”

60. Macromolecules 1997, 30, 840 (with Z. Su, D. Wu, S.L. Hsu) “Adsorption of End-Functionalized Poly(ethylene oxide)s to the Poly(ethylene oxide)-Air Interface”

61. Macromolecules 1997, 30, 1752 (with J.-M. Leväsalmi) “Poly(4-methyl-1-pentene)-Supported Polyelectrolyte Multilayer Films: Preparation and Gas Permeability”

62. Macromolecules 1997, 30, 8453 (with M.C. Hsieh and R.J. Farris) “Surface “Priming” for Layer-by-Layer Deposition: Polyelectrolyte Multilayer Formation on Allylamine Plasma - Modified Poly(tetrafluoroethylene)”

63. Naval Research Reviews 1997, 49, 19 (with J.A. Gardella, Jr., K.J. Wynne, J.F. Rabolt and G.Belfort)

“New Technologies for Surface Analysis to Assess Biofouling Resistance”

64. Macromolecules 1998, 31, 1906 (with V. Phuvanartnuruks) “Stepwise Polymer Surface Modification: Chemistry - Layer-by-Layer Deposition”

65. Macromolecules 1998, 31, 3648 (with W. Chen) “Chemical Surface Modification of Poly(ethylene terephthalate)”

66. Macromolecules 1998, 31, 4160 (with E. Kung and A.J. Lesser) “The Morphology and Mechanical Performance of Polystyrene/Polyethylene Composites Prepared using Supercritical Carbon Dioxide Processing”

67. Polymer 1998, 39, 4655 (with Z. Su, S.L. Hsu, H.D. Stidham, Z. Fan and D. Wu) “Surface Activity of Perfluorodecanoyl End-Capped Poly(ethylene oxide) and Associated Adsorption Behavior at the Air-Water Interface”

68. Macromolecules 1998, 31, 4614 (with K.A. Arora and A.J. Lesser)

“Preparation and Characterization of Microcellular Polystyrene Foams Processed in Supercritical Carbon Dioxide”

69. Macromolecules 1998, 31, 4791 (with P. Rajagopalan) “Two-Step Surface Modification of Chemically Resistant Polymers: Blend Formation and Subsequent Chemistry”

70. Macromolecules 1998, 31, 4813 (with H.J. Hayes) “Maleation of Poly(4-methyl-1-pentene) Using Supercritical Carbon Dioxide”

71. Langmuir 1998, 14, 5586 (with A. Y. Fadeev) “Surface Modification of Poly(ethylene terephthalate) to Prepare Surfaces with Silica-Like Reactivity”

72. Polym. Eng. Sci. 1998, 38, 2055 (with K.A. Arora and A.J. Lesser) “Compressive Behavior of Microcellular Polystyrene Foams Processed in Supercritical Carbon Dioxide”

73. Chem. Mat. 1999, 11, 213 (with J.J. Watkins and J.M. Blackburn) “Chemical Fluid Deposition: Reactive Deposition of Platinum Metal from Carbon Dioxide Solution”

74. Macromolecules 1999, 32, 2342 (with W. Chen) “Adsorption/Migration of a Perfluorohexylated Fullerene from the Bulk to the Polymer/Air surface”

75. Macromolecules 1999, 32, 2562 (with K.A. Arora and A.J. Lesser) “Synthesis, Characterization, and Expansion of Poly(tetrafluoroethylene-co-hexafluoropropylene)/Polystyrene Blends Processed) in Supercritical Carbon Dioxide”

76. Langmuir 1999, 15, 3395 (with W. Chen, A.Y. Fadeev, M.C. Hsieh, D. Öner, J. Youngblood)

“Ultrahydrophobic and Ultralyophobic Surfaces: Some Comments and Examples”

77. Langmuir 1999, 15, 3759 (with A.Y. Fadeev) “Trialkylsilane Monolayers Covalently Attached to Silicon Surfaces: Wettability Studies Indicating that Molecular Topography Contributes to Contact Angle Hysteresis”

78. Macromolecules 1999, 32, 4106 (with R. Dhamodharan) “Adsorption of Alginic Acid and Chondroitin Sulfate-A to Amine Functionality Introduced on Poly(chlorotrifluoroethylene) and Glass Surfaces”

79. Macromolecules 1999, 32, 6800 (with J.P. Youngblood) “Ultrahydrophobic Polymer Surfaces Prepared by Simultaneous Ablation of Polypropylene and Sputtering of Poly(tetrafluoroethylene) Using Radio Frequency Plasma”

80. Langmuir 1999, 15, 7238 (with A.Y. Fadeev)

“Binary Monolayer Mixtures: Modification of Nanopores in Silicon-Supported Tris(trimethylsiloxy)silyl Monolayers”

81. Macromolecules 1999, 32, 7610 (with C.M. Stafford and T.P. Russell) “Expansion of Polystyrene Using Supercritical Carbon Dioxide: Effects of Molecular Weight, Polydispersity and Low Molecular Weight Components”

82. J. Am. Chem. Soc. 1999, 121, 12184 (with A.Y. Fadeev) “A New Route to Covalently Attached Monolayers: Reaction of Hydridosilanes with Titanium and Other Metal Surfaces”

83. Langmuir 2000, 16, 7268 (with A.Y. Fadeev) “Self-Assembly is Not the Only Reaction possible between Alkyltrichlorosilanes and Surfaces: Monomolecular and Oligomeric Covalently Attached Layers of Dichloro- and Trichlorosilanes on Silicon”

84. Langmuir 2000, 16, 7777 (with D. Öner) “Ultrahydrophobic Surfaces. Effects of Topography Length Scales on Wettability”

85. Macromolecules 2000, 33, 8192 (with E. Kung and A.J. Lesser) “Composites Prepared by the Anionic Polymerization of Ethyl 2-Cyanoacrylate with Supercritical Carbon Dioxide - Swollen Poly(tetrafluoroethylene-co-hexafluoropropylene”

86. "Ultrahydrophobic Polymeric Surfaces Prepared Using Plasma Chemistry" In Polymer Surface Modification: Relevance to Adhesion; Mittal, K. L., Ed.; VSP: Amsterdam, 2000; Vol 2, p 77. (with M.C. Hsieh, J.P. Youngblood, and W. Chen)

87. Langmuir 2001, 17, 757 (with C. Cao and A.Y. Fadeev) “Reactions of Organosilanes with Silica Surfaces in Carbon Dioxide”

88. Thin Solid Films 2001, 382, 95 (with J.P. Youngblood) “Plasma Polymerization Using Solid Phase Polymer Reactants (Non-Classical Sputtering of Polymers)”

89. Langmuir 2001, 17, 3368 (with R. Dhamodharan, A. Nisha and K.Pushkala) “Investigation of the Mercat Reaction as a Tool for the Introduction of Nitrogen Functionality on Linear Low-Density Polyethylene and Polypropylene”

90. Adv. Mater. 2001, 13, 795 (with X. Jia, C.M. Stafford, D.H. Kim, M. Tuominen, C.J. Hawker and T.P. Russell)

“A Route to Nanoscopic SiO2 Posts via Block Copolymer Templates”

91. Polymer Eng. Sci. 2001, 41, 301 (with S.H Cho, G. Kim and R. J. Farris) “Orthotropic Elastic Constants for Polyimide Film”

92. Langmuir 2001, 17, 6547 (with C.M. Stafford, A.Y. Fadeev and T.P. Russell) “Controlled Adsorption of End-Functionalized Polystyrene to Silicon-Supported Tris(trimethylsiloxy)silyl Monolayers”

93. Polym. Eng. Sci. 2001, 41, 2259 (with T.C. Caskey and A.J. Lesser) “Supercritical CO2 Welding of Laminated Linear Low Density Polyethylene Films”

94. Langmuir 2002, 18, 683 (with X. Jia) “Buried Interface Modification Using Supercritical Carbon Dioxide”

95. J. Appl. Polym. Sci. 2003, 88, 1600 (with T.C. Caskey and A.J. Lesser) “In situ polymerization and nano-templating phenomenon in nylon fiber/PMMA composite laminates”

96. Langmuir 2003, 19, 2449 (with X. Jia) “Controlled growth of silicon dioxide from "nanoholes" in silicon-supported tris(trimethylsiloxy)silyl monolayers: Rational control of surface roughness at the nanometer length scale”

97. Macromolecules 2003, 36, 4253 (with S.I. Moon) “Template Synthesis and Self-Assembly of Nanoscopic Polymer “Pencils”

98. Macromolecules 2003, 36, 6054 (with M. Kozlov, M. Quarmyne and W. Chen) “Adsorption of Poly(Vinyl Alcohol) onto Hydrophobic Substrates. A General Approach for Hydrophilizing and Chemically Activating Surfaces”

99. Green Chemistry Using Liquid and Supercritical Carbon Dioxide (DeSimone, J.M.; Tumas, W. Eds.), Oxford Uniersity Press, 2003, p164 (with E. Kung and A.J. Lesser) "Preparation and Studies of Polymer/Polymer Composites Prepared Using Supercritical Carbon Dioxide"

100. Polymer Composites 2003, 24, 545 (with T.C. Caskey and A.J. Lesser) “Evaluating the Mechanical Performance of Supercritical CO2 Fabricated Polyamide 6,6/PMMA, Fiber Reinforced Composites”

101. Macromolecules 2004, 37, 5660 (with H. Xiang, K. Shin, T. Kim, S. I. Moon and T. P. Russell)

“Block Copolymers under Cylindrical Confinement”

102. Langmuir 2004, 20, 9170 (with M. Kozlov) “Adsorption of Poly(vinyl alcohol from Water to a Hydrophobic Surface: Effects of Molecular Weight, Degree of Hydrolysis, Salt, and Temperature”

103. Langmuir 2004, 20, 9184 (with M. Herrera-Alonso) “Chemical Surface Modification of Poly(p-xylylene) Thin Films”

104. Science 2004, 306, 76. (with K. Shin, H. Xiang, T. Kim, S. I. Moon and T. P. Russell)

"Curving and Frustrating Flatland"

105. Macromolecules 2005, 38, 1055 (with H. Xiang, K. Shin, T. Kim, S. I. Moon and T. P. Russell

“From Cylinders to Helices upon Confinement”

106. J. Polym. Sci. Part B-Polym. Phys. 2005, 43, 3377 (with H. Xiang, K. Shin, T. Kim, S. I. Moon and T. P. Russell) “The Influence Of Confinement And Curvature On The Morphology Of Block Copolymers”

107. Langmuir 2006, 22, 1646 (with M. Herrera-Alonso and X. Jia) “Nylon Surface Modification 2: Nylon-Supported Composite Films”

108. Langmuir 2006, 22, 2433 (with K.A. Wier)

“Condensation On Ultrahydrophobic Surfaces and Its Effect On Droplet Mobility: Ultrahydrophobic Surfaces Are Not Always Water Repellant”

109. Langmuir 2006, 22, 2966 (with L. Gao) “The Lotus Effect Explained: Two Reasons Why Two Length Scales of Topography are Important”

110. Langmuir 2006, 22, 4914 (with K.A. Wier and L. Gao) “Two-Dimensional Fluidics Based on Differential Lyophobicity and Gravity”

111. Langmuir 2006, 22, 5998 (with L. Gao) “Artificial Lotus Leaf' Prepared Using a 1945 Patent and a Commercial Textile”

112. Langmuir 2006, 22, 6234 (with L. Gao) “Contact Angle Hysteresis Explained”

113. J. Am. Chem. Soc. 2006, 128, 9052 (with L. Gao) “A Perfectly Hydrophobic Surface: θA/ θR = 180°/180°”

114. Polymer 2006, 47, 4916 (with X. Jia and M. Herrera-Alonso) Nylon Surface Modification. Part 1. Targeting the Amide Groups for

Selective Introduction of Reactive Functionalities”

115. Langmuir 2007, 23, 3260 (with Jayaraman K. and S. L. Hsu) “Versatile Multilayer Thin Film Preparation Using Hydrophobic Interactions, Crystallization, and Chemical Modification of Poly(vinyl alcohol)”

116. Langmuir 2007, 23, 3762 (with L. Gao) “How Wenzel and Cassie Were Wrong”

117. J. Am. Chem. Soc. 2007, 129, 3804 (with L. Gao) “Ionic Liquids Are Useful Contact Angle Probe Fluids”

118. Macromolecules 2007, 40, 3965 (with J. A. Lee) “Polymer Surface Modification: Topography Effects Leading to Extreme Wettability Behavior”

119. Langmuir 2007, 23, 9125 (with L. Gao) “A Commercially Available Perfectly Hydrophobic Material. θA/θR = 180°/180°”

120. Langmuir 2007, 23, 10445 (with L. Gao) “Ionic Liquid Marbles”

121. Small 2007, 3, 1869 (with B. Kim, S. Park and T. P. Russell) “Fabrication of Ordered Anodic Aluminum Oxide Using a Solvent-Induced Array of Block-Copolymer Micelles”

122. Langmuir 2007, 23, 13243 (with L. Gao) “Reply to Comment on How Wenzel and Cassie Were Wrong by Gao and McCarthy”

123. Langmuir 2008, 24, 362 (with L. Gao) “(CH3)3SiCl/SiCl4 Azeotrope Grows Superhydrophobic Nanofilaments”

124. Langmuir 2008, 24, 1391 (with E. J. De Souza, L. Gao, E. Arzt, and A. J. Crosby) “Effect of Contact Angle Hysteresis on the Measurement of Capillary Forces”

125. Langmuir 2008, 24, 5740 (with I. Anac and V. P. Hoven) “Poly(trifluoroethylene) Adsorption and Heterogeneous Photochlorination Reactions”

126. J. Appl. Polym. Sci. 2008, 109, 3961 (with S. A. Eastman and A. J. Lesser) “Bamboo is a Suitable Template for Polymerizations”

127. MRS Bulletin 2008, 33, 747 (with L. Gao and A. Y. Fadeev) “Superhydrophobicity and Contact Line Issues”

128. Langmuir 2008, 24, 9183 (with L. Gao) “Teflon is Hydrophilic. Comments on Definitions of Hydrophobic, Shear versus Tensile Hydrophobicity and Wettability Characterization”

129. J. Coll. Interfac. Sci. 2009, 331, 138 (with I. Anac) “Chemical Modification of Chromium Oxide Surfaces using Organosilanes”

130. Surf. Finish. Soc. Jpn. 2009, 60, 16 (with A. Hozumi) "Hydrophobization of Metal/Metal Oxide Surfaces Using Monolayer Films" 131. J. Mater. Sci. 2009, 44, 1275 (with S. A. Eastman and A. J. Lesser) “Supercritical CO2-Assisted, Silicone-Modified Wood for Enhanced Fire

Resistance”

132. Langmuir 2009, 25, 2875 (with A. Hozumi and B. Kim) “Vapor-Phase Formation of Alkyl Isocyanate-Derived Self-Assembled Monolayers on Titanium Dioxide”

133. Langmuir 2009, 25, 6834 (with A. Hozumi and B. Kim) “Hydrophobicity of Perfluoroalkyl Isocyanate Monolayers on Oxidized Aluminum Surfaces”

134. Langmuir 2009, 25, 7249 (with L. Gao) “An Attempt to Correct the Faulty Intuition Perpetuated by the Wenzel and Cassie ‘Laws’”

135. J. Appl. Polym. Sci. 2009, 113, 3564 (with J. Yoon and A. J. Lesser) "Self-Reinforcing Isotactic Polypropylene Prepared Using Crystallizable Solvents"

136. Macromolecules 2009, 42, 8827 (with J. Yoon and A. J. Lesser) "Locally Anisotropic Porous Materials from Polyethylene and Crystallizable Diluents"

137. Composite Interfaces 2009, 16, 825 (with S. A. Eastman and A. J. Lesser) “A New Approach to Fabricating Cellulosic-Polymer Composites ”

138. Langmuir 2009, 25, 14100 (with L. Gao and X. Zhang) “Wetting and Superhydrophobicity”

139. Langmuir 2009, 25, 14105 (with L. Gao) “Wetting 101°”

140. Langmuir 2010, 26, 2567 (with A. Hozumi) “Ultralyophobic Oxidized Aluminum Surfaces Exhibiting Negligible Contact Angle Hysteresis”

141. Biomacromolecules 2010, 11, 2567 (with X. Zan, M. Kozlov and Z. Su) “Covalently Attached, Silver-Doped Poly(vinyl alcohol) Hydrogel Films on Poly(L-lactic acid)”

142. J. Am. Chem. Soc. 2010, 132, 5602 (with A. Hozumi and P. Bian) “Ionic Liquids: Nondestructive, Nonvolatile Imaging Fluids for Submicrometer- Scale Monolayer Patterns”

143. Langmuir 2010, 26, 2567 (with P. Bian) “Polymerization of Monomer-Based Ferrofluids”

144. Macromolecules 2010, 43, 4584 (with S. A. Eastman and A. J. Lesser) “Quantitative Poly(vinyl alcohol) Modification in Ionic Liquids: Esterification and Urethanation with Low Surface Tension Producing Reagents”

145. Faraday Discussions 2010, 146, 103 (with J. W. Krumpfer) “Contact angle hysteresis: a different view and a trivial recipe for low hysteresis hydrophobic surfaces”

146. Langmuir 2010, 26, 18585 (with P. Zheng) “Rediscovering Silicones. Molecularly Smooth, Low Surface Energy, Unfilled, UV/vis-Transparent, Extremely Crosslinked, Thermally Stable, Hard and Elastic PDMS”

147. Langmuir 2011, 27, 2166 (with J. W. Krumpfer, Pei Bian, P. Zhang and L. Gao) “Contact Angle Hysteresis on Superhydrophobic Surfaces: An Ionic Liquid Probe Fluid Offers Mechanistic Insight”

148. Langmuir 2011, 27, 3693 (with D. F. Cheng) "Using the Fact that Wetting Is Contact Line Dependent"

149. J. Am. Chem. Soc. 2011, 133, 5764 (with J. W. Krumpfer) "Dip-Coating Crystallization on a Superhydrophobic Surface: A Million Mounted Crystals in a 1 cm2 Array"

150. Langmuir 2011, 27, 7976 (with P. Zheng) "D4H/D4V Silicone: A Replica Material with Several Advantages for Nanoimprint Lithography and Capillary Force Lithography"

151. Langmuir 2011, 27, 11514 (with J. W. Krumpfer) "Rediscovering Silicones: "Unreactive" Silicones React with Inorganic Surfaces"

152. J. Am. Chem. Soc. 2012, 134, 2024 (with P. Zheng) "A Surprise from 1954: Siloxane Equilibration is a Simple, Robust and Obvious Polymer Self-Healing Mechanism "

Patents

1. U.S. Patent 5,789,027 Aug 4, 1998 (with J. J. Watkins) “Method of Chemically Depositing Material onto a Substrate”

2. U.S. Patent 5,965,470 Oct 12, 1999 (with R.C. Bening) “Composites Containing Surface Treated Carbon Microfibers”

3. U.S. Patent 6,203,814 Mar 20, 2001 (with A. Fisher, R. Hoch, D. Moy, C. Niu, N. Ogata, H. Tennent)

“Method of Making Functionalized Nanotubes”

4. U.S. Patent 6,331,329 Dec 18, 2001 (with A.Y. Fadeev) “Surface Modification using Hydridosilanes to Prepare Monolayers”

5. U.S. Patent 6,524,655 Feb 25, 2003 (with A.Y. Fadeev) “Surface Modification using Hydridosilanes to Prepare Monolayers”

6. U.S. Patent 6,673,459 Jan 6, 2004 (with A.Y. Fadeev) “Surface Modification using Hydridosilanes to Prepare Monolayers”

7. U.S. Patent 7,410,628 Aug 12, 2008 (with R.C. Bening) “Surface Treatment of Carbon Microfibers”

8. U.S. Patent 7,862,794, Jan 4, 2011 (with R.C. Bening) “Surface Treatment of Carbon Microfibers”

9. U.S. Patent 8,067,065, Nov 29, 2011 (with L. Gao) “Fibrillar, Nanostructured Coating and Method for its Manufacture”

10. U.S. Patent Application US 2008/0268239, Oct 30, 2008 (with J. Yoon, O. S. Yordem and A. J. Lesser) "Reinforced Polymeric Materials, Methods of Manufacture Thereof and Articles Comprising the Same"