Product WATER BASED HIGHLINGT INK Date:03-15-2008 · MATERIAL SAFETY DATA SHEET According to European 91/155/EEC 1 Product WATER BASED HIGHLINGT INK Date:03-15-2008 Revision Date:03-15-2008

MATERIALMATERIALMATERIALMATERIALSAFETYSAFETYSAFETYSAFETYDATADATADATADATA SHEETSHEETSHEETSHEETAccordingAccordingAccordingAccording totototo EuropeanEuropeanEuropeanEuropean 91/155/EEC91/155/EEC91/155/EEC91/155/EEC

1

ProductProductProductProduct WATERWATERWATERWATER BASEDBASEDBASEDBASED HIGHLINGTHIGHLINGTHIGHLINGTHIGHLINGT INKINKINKINK Date:03-15-2008Revision Date:03-15-2008

Part# FT-48-O-02(4#)

1111 CHEMICALCHEMICALCHEMICALCHEMICALPRODUCTPRODUCTPRODUCTPRODUCTANDANDANDAND COMPANYCOMPANYCOMPANYCOMPANY IDENTIFICATIONIDENTIFICATIONIDENTIFICATIONIDENTIFICATIONPRODUCT NAME: WATER BASED HIGHLINGT INKSUPPLIER:Name: SHANGHAI UNIVERSITY SCIENCE &

TECHNOLOGY PARK SPECIAL INK R&DDEPARTMENT

Address: No.788 GUANGZHONG RD.SHANGHAI CITY 200072

Telephone number: 008621-56331532Recommended use: Ink

2222 COMPOSITION/INFORMATIONCOMPOSITION/INFORMATIONCOMPOSITION/INFORMATIONCOMPOSITION/INFORMATION ONONONON INGREDIENTINGREDIENTINGREDIENTINGREDIENTPREPARATION:

CHEMICAL NAME CAS No. PERCENTAGEWATER 7732-18-5 50%GLYCOL 56-81-5 25%SF-3014 28556-33-0

3068-38-1277-459-0

25%

3333 HAZARDSHAZARDSHAZARDSHAZARDS IDENTIFICATIONIDENTIFICATIONIDENTIFICATIONIDENTIFICATIONMOST IMPORTANT HAZARDS:Adverse human health effects:Environmental effects: Contains hazardous substances(s) for the

EnvironmentPhysical and chemical hazards:-Fire or explosion: Unflammable liquidClassification of the product: According to European regulations,this product

is classified as:None

Further information: In a usual writing situation,will not causeadverse effects on the user’s health.

4444 FIRSTFIRSTFIRSTFIRSTAIDAIDAIDAIDMEASURESMEASURESMEASURESMEASURESInhalation: No specific intervention is indicated as the

compound is not likely to be hazardous byinhalation.

Skin contact: Immediately wash and with plenty of waterEye contact: Rinse immediately and thoroughly, pulling

the eyelids well away from the eye(15 min.minimum) Always refer to an eye specialist,even if there are no immediate symptoms.


2

Ingestion: Never attempt to induce vomitingCall a doctor immediately

5555 FIREFIREFIREFIRE FIFHTINGFIFHTINGFIFHTINGFIFHTINGMEASURESMEASURESMEASURESMEASURESSuitable extinguishing media: Not needNot suitable extingushing meia: Not needSpecific hazards: Not needSpecific fire fighting methods: Not needProtection of fighters Not need

6666 ACCIDENTALACCIDENTALACCIDENTALACCIDENTALRELEASERELEASERELEASERELEASEMEASURESMEASURESMEASURESMEASURESPersonal precautions: Avoid with eyesEnvironmental precautions: Do not discharge into drains and riversMethods for cleaning up:-Neutrlization: Absorb spillage with:

-inert abosrbent material-sand

-Cleaing/decontamination: Wash non-recoverable remainder withplenty of water

-Disposal: Dispose of containated materials inaccordance with current regulations

7777 HANDLINGHANDLINGHANDLINGHANDLINGANDANDANDAND STORAGESTORAGESTORAGESTORAGEHANDLINGTechnical mesure: Not needPrecaution: Avoid any direct contact with the productSTORAGETechnical measures: Not needStorage conditions:-Recommended: Store:

-in a cool, well-ventilated area-the container tightly closed

Incompatiable materials: NonePackaging materials:-Not suitable: Certain mental materials

8888 EXPOSUREEXPOSUREEXPOSUREEXPOSURE CONTROLS/PERSONALCONTROLS/PERSONALCONTROLS/PERSONALCONTROLS/PERSONALPROTECTIONPROTECTIONPROTECTIONPROTECTIONEngineering measures: Ensure good ventiliation of the work stationOccupational exposure limits:-France: NonePersonal protective equipment:-Respiratory protection: Not need-Hand protection: Gloves-Eye protection: Safety spectacles-Skin and body protection: Suitable clothingCollective emergency equipment: Eye fountain

Safety shower


3

Hygiene measures: Do not drink, eat or smoke in the workplace

9999 PHYSICALPHYSICALPHYSICALPHYSICALANDANDANDAND CHEMICALCHEMICALCHEMICALCHEMICALPROPERTIESPROPERTIESPROPERTIESPROPERTIESPhysical state: LiquidColour: VariableOdour: OdourlessPH: 4—9Flammability characteristics:-Flash point: >85℃-Auto-ignition temperature:Explosive limits in air:-Lower:-Upper:Vapour density(air=1_:Solubility:-In water: Miscible(in all proportions)-In organic solvents:-Common organic solvents

10101010 PHYSICALPHYSICALPHYSICALPHYSICALANDANDANDAND CHEMICALCHEMICALCHEMICALCHEMICALPROPERTIESPROPERTIESPROPERTIESPROPERTIESStability: Stable at ambient temperture and un

-der normal conditions of usHazardous reactions:-Conditions to avoid:-Materials to avoid: On hot condition-Hazardous decompositionproducts:

11111111 TOXICOLOGICALTOXICOLOGICALTOXICOLOGICALTOXICOLOGICAL INFORMATIONINFORMATIONINFORMATIONINFORMATIONAcute toxicity: NoAcute symptoms: NoLocal effects: NoFurther information: Above information is for the ink.The

Ink will be contained in the fibrousReservoir of a small capacityfine-liner maker

12121212 ECOLOGICALECOLOGICALECOLOGICALECOLOGICAL INFORMATIONINFORMATIONINFORMATIONINFORMATIONProduct as is: Avoid discharge of the product as is

into the environmentECOTOXICITY:Effects on the aquatic environment: Ethanol

May cause adverse effects to theaquatic environment

13131313 DISPOSALDISPOSALDISPOSALDISPOSALCONSIDERATIONSCONSIDERATIONSCONSIDERATIONSCONSIDERATIONSWASTE FROM PRODUCT:Destruction/Disposal: Dispose of in accordance with


4

Relevant local regulationsCONTAMINATED PACKAGING:Destruction/disposal: Destory at an authorized siteNOTE: The user’s attention is drawn to the

possible existence of specific Europ-ean,national or local regulationsregarding disposal

14141414 TRANSPORTTRANSPORTTRANSPORTTRANSPORT INFORMATIONINFORMATIONINFORMATIONINFORMATIONINTERNATIONAL REGULATIONS:Land transportation: UN Number:-Rail/road(RID?ADR): Class:

Classification code:Packaging group:Labeling:

-Sea(IMO/IMDG): UN Number:Class:Classification code:Packaging group:Labeling:

-Air(ICAO-IATA): UN Number:Class:Classification code:Packaging group:Labeling:

Further information:NOTE: The above regulatory prescriptions

are those valid on the date ofpublication of this sheet. In casethe prescent sheet is dating back tomore than 1 year ago, it would beadvisable to check their validitywith your commercial agency

15151515 REGULATORYREGULATORYREGULATORYREGULATORY INFORMATIONINFORMATIONINFORMATIONINFORMATIONEC LABELING: Marker: not applicable

Ink: not needSymbols and indications of danger: --R phrases: R21: Harmful in contact by skin

R22: Harmful if swallowedR36: Irritating to eyeR38: Irritating to skinR41: Risk of serious damage to eyes

-S phrases: S7: Keep container tightly closedS24: Avoid contact with skin


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S25: Avoid contact with eyes

S26: In case of contact with eyes, rinseImmediately with plenty of water and seekmedical adviceS36: Wear suitable protective clothingS39: Wear eye protection

FURTHER REGULATIONS:National prescriptions:France:NOTE: The regulatory information given above only

indicate the principal regulations specificallyapplicable to the product described in theMSDSThe cited basic community texts are beingupdated and transcribed in national lawRefer to all applicable international, nationaland local regulations or provisionsThe user’s attention is drawn to the possibleexistence of additional provisions whichcomplete these regulations

16 OTHER INFORMATIONRestricitions on use: This product must not be used for other

applications than mentioned in § 1Safety data sheet established by: Howard Young, Technical Director

This sheet completes the technical sheets but it does not replace them. The information given isbased on our knowledge of this product, at the time of publication. It is given in good faith.The attention of the user is drawn to the risks possibly incurred by using the product for any otherpurpose than that for which it was intented.This does not in any way excuse the user from knowing and applying all the regulations governinghis activity. It is the sole responsibility of the user to take all precautions required in handing theproduct.The mandatory regulations mentioned are only intended to help the user to fullfill his obligationsregarding the use the products.This listing must not be considered exhaustive. It does not exonerate the user from ensureing thatother legal obligations than those mentioned do not exist, relating to the use and storage of theproduct for which he solely is responsible.Note: The supplying of a material safety data sheet is not mandatory for manufactured articleswhich contain dangerous substances or preparations, when these latter’s are packaged so that theydo not present any danger for the user.

Page 1/4

Printing date 10/05/2005Reviewed on 10/05/2005

Material Safety Data Sheetacc. to ISO/DIS 11014

DR

1 Identification of substance

· Product details

· Trade name: CF 5873 red- violet / rotviolett

· Manufacturer/Supplier:DOKUMENTAL GmbH & Co KG SchreibfarbenWoellnerstraße 26D-67065 LudwigshafenPhone + 49 (0) 6 21 /54 02 - 227Fax + 49 (0) 6 21 /54 02 394www. dokumental.de

· Information department:Technical Service, Dr. B. PolzinTel.: +49-621-5402322Mobile +49-1726204412

· Emergency information:Product Safety, Dr. Polzin+49-621-5402322+49-172-6204412

2 Composition/Data on components

· Chemical characterizationMixture of the following substances, containing non-hazardous substances and colouring agents.

· Description: Mixture of the substances listed below with nonhazardous additions.

· Dangerous components: Void· Additional information: For the wording of the listed risk phrases refer to section 16.

3 Hazards identification

· Hazard description: Not applicable.· Information pertaining to particular dangers for man and environment:

The product does not have to be labelled due to the calculation procedure of the "GeneralClassification guideline for preparations of the EU" in the latest valid version.

· Classification system:The classification was made according to the latest editions of international substances lists, andexpanded upon from company and literature data.

· NFPA ratings (scale 0 - 4)

00

0Health = 0Fire = 0Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

0

0

0

Health = 0Fire = 0Reactivity = 0

4 First aid measures

· General information: No special measures required.· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.

5 Fire fighting measures

· Suitable extinguishing agents:CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistantfoam.

· Protective equipment: No special measures required.

6 Accidental release measures

· Person-related safety precautions: Not required.· Measures for environmental protection:

Dilute with plenty of water.Do not allow to enter sewers/ surface or ground water.

(Contd. on page 2) USA

Page 2/4



Trade name: CF 5873 red- violet / rotviolett

(Contd. of page 1)

DR

· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

· Additional information: No dangerous substances are released.

7 Handling and storage

· Handling:· Information for safe handling: No special measures required.· Information about protection against explosions and fires: No special measures required.

· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: None.

8 Exposure controls and personal protection

· Additional information about design of technical systems: No further data; see item 7.

· Components with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have tobe monitored at the workplace.

· Additional information: The lists that were valid during the creation were used as basis.

· Personal protective equipment:· General protective and hygienic measures:

The usual precautionary measures for handling chemicals should be followed.· Breathing equipment: Not required.· Protection of hands:

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has thereforeto be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and hasto be observed.

· Eye protection: Goggles recommended during refilling.

9 Physical and chemical properties

· General Information

Form: FluidColor: According to product specificationOdor: Characteristic

Important information on protection of healthand environment, and on safety. Not applicable

Not applicable

· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 100°C (212°F)

· Flash point: Not applicable.

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Vapor pressure at 20°C (68°F): 23.0 hPa (17 mm Hg)

· Density: Not determined.

· Solubility in / Miscibility withWater: Fully miscible.

· pH-value at 20°C (68°F): 5.8

· Viscosity:Dynamic at 20°C (68°F): 3 mPas

· Solvent content:Organic solvents: 0.0 %

(Contd. on page 3) USA

Page 3/4




(Contd. of page 2)

DR

Water: 79.6 %

· Solids content: 19.9 %

10 Stability and reactivity

· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Dangerous reactions No dangerous reactions known.· Dangerous products of decomposition: No dangerous decomposition products known.

11 Toxicological information

· Acute toxicity:· Primary irritant effect:· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product is not subject to classification according to internally approved calculation methodsfor preparations:When used and handled according to specifications, the product does not have any harmful effectsaccording to our experience and the information provided to us.

12 Ecological information

· General notes:Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course orsewage system.

13 Disposal considerations

· Product:· Recommendation: Smaller quantities can be disposed of with household waste.

· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.· Recommended cleansing agent: Water, if necessary with cleansing agents.

14 Transport information

· DOT regulations:· Hazard class: -

· Land transport ADR/RID (cross-border):· ADR/RID class: -

· Maritime transport IMDG:· IMDG Class: - · Marine pollutant: No

· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: - · Packaging group: Not applicable

15 Regulations

· Sara

· Section 355 (extremely hazardous substances):

None of the ingredient is listed.

· Section 313 (Specific toxic chemical listings):

81-88-9 9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride

· TSCA (Toxic Substances Control Act):

7732-18-5 water, distilled, conductivity or of similar purity

118-71-8 3-hydroxy-2-methyl-4-pyrone

81-88-9 9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride(Contd. on page 4)

USA

Page 4/4




(Contd. of page 3)

DR

· Proposition 65

· Chemicals known to cause cancer:

81-88-9 9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride

· Chemicals known to cause reproductive toxicity:

None of the ingredients is listed.

· Cancerogenity categories

· EPA (Environmental Protection Agency)


· IARC (International Agency for Research on Cancer)

81-88-9 9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride 3

· NTP (National Toxicology Program)


· TLV (Threshold Limit Value established by ACGIH)


· MAK (German Maximum Workplace Concentration)


· NIOSH-Ca (National Institute for Occupational Safety and Health)


· OSHA-Ca (Occupational Safety & Health Administration)


· Product related hazard informations:Observe the general safety regulations when handling chemicals.The product is not subject to identification regulations according to directives on hazardousmaterials.

· National regulations:

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guaranteefor any specific product features and shall not establish a legally valid contractual relationship.

USA


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Part# FT-BLE-P






CHEMICAL NAME CAS No. PERCENTAGEWATER 7732-18-5 50%GLYCOL 56-81-5 25%SF-3038 55840-82-8 25%











2










Safety showerHygiene measures: Do not drink, eat or smoke in the workplace

9999 PHYSICALPHYSICALPHYSICALPHYSICALANDANDANDAND CHEMICALCHEMICALCHEMICALCHEMICALPROPERTIESPROPERTIESPROPERTIESPROPERTIES


3

Physical state: LiquidColour: VariableOdour: OdourlessPH: 4—9Flammability characteristics:-Flash point: >85℃-Auto-ignition temperature:Explosive limits in air:-Lower:-Upper:Vapour density(air=1_:Solubility:-In water: Miscible(in all proportions)-In organic solvents:-Common organic solvents









Relevant local regulationsCONTAMINATED PACKAGING:


4

Destruction/disposal: Destory at an authorized siteNOTE: The user’s attention is drawn to the














5








1


Part# FT-G-P







28556-33-055840-82-8

25%










2











Safety shower


3

Hygiene measures: Do not drink, eat or smoke in the workplace











4

Relevant local regulationsCONTAMINATED PACKAGING:Destruction/disposal: Destory at an authorized siteNOTE: The user’s attention is drawn to the













5









1


Part# FT-P-P







277-459-025%









Ingestion: Never attempt to induce vomiting


2

Call a doctor immediately












3










Relevant local regulations


4

CONTAMINATED PACKAGING:Destruction/disposal: Destory at an authorized siteNOTE: The user’s attention is drawn to the














5








1


Part# FT-Y-P







28556-33-025%









Ingestion: Never attempt to induce vomiting


2

Call a doctor immediately












3










Relevant local regulations


4

CONTAMINATED PACKAGING:Destruction/disposal: Destory at an authorized siteNOTE: The user’s attention is drawn to the














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Documents

Product WATER BASED HIGHLINGT INK Date:03-15-2008 · MATERIAL SAFETY DATA SHEET According to European 91/155/EEC 1 Product WATER BASED HIGHLINGT INK Date:03-15-2008 Revision Date:03-15-2008