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PROCESSING OF THERMOMECHANICAL ROLLED STEEL
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 1
Processing of thermomechanical rolled steel
Jürgen Schütz, EWEWelding Laboratory, Dillinger Hütte
with respect of welding and cutting
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Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 3
Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 4
Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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Oxygen cutting, plasmacutting, laser cutting
no preheat requiredno scale on thesurface
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flame cutting
material is combusted with oxygen and oxides are blown out
plasma-cutting
material is melted by ionized gas and blown outby gas jet (oxygen / nitrogen)
laser-cutting
material is vaporized (minor thickness) or combusted with oxygen
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material suiteable for gas cutting :
ignition temperature lower than melting temperature
melting temperature of oxides lower than melt temperature of base material
positive energy balance to keep material above ignition temperature
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liquidus-temperature
ignition-temperature
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Combustion of the plate ?
1. combustion of gas (acetylene, propane, 0.5 bar)
2. heating of subsurface to ignition temperature
3. combustion of iron within the oxygen (7 bar) jet, oxides are blown out inthe jet, (exothermic process ,autogenous)
1. nozzle
2. gas -oxygen (heating)
3. oxygen -jet (cutting)
4. plate to be cut
5. heating flame
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 11
In brief
Oxy acetylene flame preheats the metal to the ignition point at the place to be cut. It also provides a protective shield between the cutting oxygen stream and the atmosphere.
Cutting oxygen combines with iron to form iron oxide.
Cutting oxygen jet blows away molten iron and iron oxide thereby cutting anarrow slit or kerf in the metal object.
Datum und Veranstaltung eintragen 12
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too fast o.k too slow
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Oxy-cutting
rapid heating and cooling at the flame cut edge
martensitique microstructure :
maximum hardness is only a function of carbon content
Hv = f(C) ; 800*C(%) +294
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90° section, 50 mm plate thickness 15° section, for hardness measurement
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 19
Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 20
straining of outer surface :
ε = t / (2r + t)
r : mandrel (bending) radiust : plate thickness
approximate value : 2r >> t
ε = t/2r or….. ε = thickness / diameter
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0,0
0,5
1,0
1,5
2,0
2,5
3,0
3,5
4,0
grinded edge
grinded edge
grinded edge
non grinded edge
non grinded edge
non grinded edge
Influence of edge preparation for technical bending specimen
bending (180°) without cracking crack initiation at subsurface crack initiation at edge
S460N0.18%C
S460N0.15%C
S460N0.13%C
S460M0.10%C
S460M0.11%C
r/t te
chni
cal b
endi
ng s
peci
men
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Hot forming
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Hot forming
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increase of yield strength
higher yield to tensile ratio
reduction of residual elongation
shift of transition from brittle - ductile
Effect of cold forming on steel properties
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 28test temperaturetest temperature
impact impact energyenergy
initialinitial
after 5% after 5% strainstrain
ΔΔTTstrainstrain
staining staining + ageing+ ageing
ΔΔTTageingageing
Cold forming
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 29test temperaturetest temperature
impact impact energyenergy
staining staining + ageing+ ageing
S + A +S + A +PWHTPWHTinitialinitial
Cold forming
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-100 -80 -60 -40 -20 00
25
50
75
100
125
150
S420M - 40mm (CMnNb)influence of straining, ageing and tempering on TT (1/4 thickness)
delivery condition 10 % strain 10 % strain + aged (250°/30min) 10 % strain + 580°C/30min
impa
ct e
nerg
y, a
vera
ge [j
oule
s]
test temperature [°C]
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 31
Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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Consumables for welding TM-rolled steels :
Consunables have to be selected in a way that they fulfill the requiredmechanical properties ( i.e yield, tensile, toughness)
Welding position may be respected
Any subsequent PWHT has to be taken into account
But no difference to normalized steel
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 33
DIN EN 499
electrode
460 MPa Reh
TT 47 J, -60°C
0.6-1.2 % Ni
E 24646 1Ni H5B
basic covered
DC –current, >105% efficiency
all welding positions
5 ml H2 /100g
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 34
Welding
HAZ hardness
Hydrogen induced cracking - preheating
Toughness in the HAZ
Working range
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 35
melt
A1-line
A3 -line
temperature
% C
CGWEZ
fine grained WEZ
partly aust. WEZ
0.15 %
temp. WEZ
1200
1600
1400
Base material
WEZ
Weld metal
200
400
fusion line
austenite
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 36
S420M 100mm HAZ hardness as a function of distance from fusion line
-4 -2 2 4150
175
200
225
250
275
S420M - 100mmSAW 5.0 kJ/mm
hardness HV 10
upper lower
distance from fusion line [mm]-4 -2 2 4
150
175
200
225
250
275
S420M - 100mmSAW 0,7 kJ/mm
hardness HV 10
upper lower
distance from fusion line [mm]
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1 10 205cooling time t8/5 s
HAZ hardness tests on bead on plate welds
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200
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Tmax (fusion line) 1350°C
40s
10s
tem
pera
ture
[°C]
time [sec]
20s
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50 100 150 200 2500
1
2
3
4
5
3-dimensional heat flow
40 s
30 s
10 s
20 s
heat input [kJ/mm]
interpass temperature [°C]
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 42
1 10 100150
200
250
300
350
400
450WEZ-Härte
C,Si,Mn,Cr,Mo,Ni,Cu,B
C,Si,Mn,Cr,Mo,Ni,Cu,V,Nb
Ti
C,Si,Mn,Cr,Mo,Ni,B
C
t8/5 Zeit
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 43
1 10
200
300
400
500
205
S 460 M
S 460 N
HAZ
har
dnes
s (H
V10)
cooling time t8/5 s
HAZ hardness tests on bead on plate welds
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Hydrogen induced crackparallel to fusione linein the CG-HAZ
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Hydrogen induced crackIn the HAZ of a multi-pass weld
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Calculation of minimum preheating temperature (EN 1011)
CET = C + (Mn + Mo)/10 + (Cr + Cu)/20 + Ni/40
To = 700 CET + 160 tanh (t/35) + 62 HD exp 0.35 + (53 CET - 32) Q - 330
t = Blechdicke (mm)HD = Wasserstoff-Eintrag (ml/100 g - DIN 8572)Q = Wärmeeinbringen ( kJ/cm)
Tekken Test :
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0255075
100125150175200
0 25 50 75 100plate thickness (mm)
Tp (°
C)
0255075
100125150175200
0 1 2 3 4 5welding heat input (kJ/mm)
Tp (°
C)
0255075
100125150175200
0,2 0,25 0,3 0,35 0,4 0,45 0,5CET = C + (Mn+Mo)/10 + (Cu+Cr)/20 + Ni/40 (%)
Tp (°
C) C Mn Mo Cr Cu Ni
0,07 1,55 0 0,03 0,2 0,20,12 1,55 0 0,03 0,2 0,250,18 1,45 0 0,03 0,05 0,05
CET 0,24 % 0,29 % 0,33 %Q 1,5 1,5 1,5d 50 50 50
HD 5 5 5
0255075
100125150175200
0 5 10 15hydrogen ml/100g deposit metal
Tp(°
C)
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0 20 40 60 80 100
25
50
75
100
125
150Heat input hydrogen
GSMAW 1.0 kJ/mm 2 ml/100g DMSMAW 2.2 kJ/mm 4 ml/100g DMSAW 3.3 kJ/mm 7 ml/100g DM
S460M
S460N
plate thickness
S500M
S355J2G3 (N)
S355G8+N Offshore
S355G8+M
S460 (N)heat input hydrogenGMAW 0.7 kJ/mm 2 ml/100gSMAW 2.0 kJ/mm 4 ml/100gSAW 3.3 kJ/mm 7 ml/100g
Preheating temperature EN1011
S420G2+M
plate thickness
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-80 -60 -40 -20 0 20 400
50
100
150
200
250
300
350 S355M (Nb) 0,08% C, 0,001% S S355N Offshore 0,12% C, 0.001% S S355N standard 0,20% C, 0,003% S S355N old 0,20% C, 0,028% S
impa
ct e
nerg
y [jo
ules
]
temperature [°C]
HAZ toughness of S355N and S355M
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 53
TM High toughness / High safety
-120 -100 -80 -60 -40 -20 0 200
50
100
150
200
250
300
350 S355J2+N S460ML S690QL
Cha
rpy-
V [J
]
Temperature [°C]
Welding leads to
toughness
reduction
High toughnessin the base
material reducesthe risk of brittle
fracture and gives saftey!
Advantages of TM-steel - Processing
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Impact testing of thick welds for the approval of offshore steels
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0 1 2 3 4 50
50
100
150
200
250
300
GRD 450 TMCP plate thickness 60-100mm
FL FL+2mm FL+5mmmea
n im
pact
ene
rgy
at -4
0°C
[J]
heat input [kJ/mm]
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Temperature [°C]
max. interpass temp.
higher heat input
1 2 3 4 550
100
150
200
250
S355J2G370 mm
S355M - 100mm
min. preheat andinterpass temp.
Heat input [kJ/mm]
Working range
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Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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The flame straightening of a plate is based in principle on a local heating of the areato be shortened in combination with the hindrance of thermal expansion by the coldvicinity. This causes a bulging of the heated zone. When cooling down to ambient temperature the resulting tensile stresses willlead to the required deformation.
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The efficiency of the process depends on :
thermal fieldwall thicknessheating ratevery narrow located heatingrestraint and stiffness of the construction
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Lower limit of applicable temperature
At peak temperature the area to be straightened must undergo plastic deformation.During subsequent cooling the compressive stresses turn into tensile stresses.The final tensile stresses are producing the effect on geometry.Thus the temperature must be increased above the temperature wheresufficiently high compression stress are built up so that the yielding occurs
The yield strength at elevated temperature is lowered to such an extent that thecompressive stress will lead to sufficient bulging of the area to be straightened.
For S355 / 420M steel both conditions are fulfilled for temperaturesexceeding approximately 450°C.So any lower temperatures are ineffective for shaping.
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Upper limit of applicable temperature
The upper limit of the temperature range is shall not be exceededin order to regain the mechanical properties of the plate after subsequent cooling.
Two different flame straightening procedures have to be distinguishedbecause they require different temperature limits.
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In the first case the plate is only superficially heated. The heat input relatedto the plate thickness is small. Due to the steep temperature gradients in thethrough thickness direction cooling is very fast. Cooling speed is in the rangeof high heat input welding. Due to the fast transformation again a fine grainedmicrostructure is achieved which is very similar to the initial microstructure. Soare the mechanical properties.
Temperatures above 925°C shall not be permitted to avoid grain growth.(examples: line heating)
Surface heatingrapid coolingpeak temperaturemax. 900-950°C
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 64
In the second case the entire cross section of the plate is heated. The heatinput related to the plate thickness is high. The heated area cools down slowerthan in the first case. The larger the heated area the slower the cooling. Aircooling represents the very extreme of such procedure.To avoid softening of the steel temperatures exceeding 600°C are notpermitted. For a short period 650°C may still be acceptable, but clearly below700°C so that a partial transformation to austenite can be excluded.
(examples: wedge heating, triangular heating)
Full section heatingrather slow coolingpeak temperaturemax. 600-650°C
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 65
Zusammenstellung der Glühfarben beim Flammrichten
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 66
Different delivery conditions of fine grained steel
Processing of thermo-mechanical rolled steel
Flame cutting
Forming
Welding
Flame straightening
Post weld heat treatment
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Response of tensile properties on PWHT (S420 M)
16,8 17,0 17,2 17,4 17,6 17,8 18,0 18,2 18,4 18,6 18,8380
400
420
440
20mm 25mm 50mm
yield strength MPa
Hollomon Parameter16,8 17,0 17,2 17,4 17,6 17,8 18,0 18,2 18,4 18,6 18,8
480
500
520
540
560
20mm 25mm 50mm
tensile strength MPa
Hollomon Parameter
Holdingtemperature
Holding time HP-Factor
600°C 60 min 17,00600°C 240 min 17,53600°C 480 min 18,05630°C 60 min 18,15630°C 240 min 18,25
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 68
For post weld heat treatment
recommended parameters
530°C - 580°C
1-2 hours
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 69
No hot forming allowedNo hot forming allowed
No heat treatment above ~600°CNo heat treatment above ~600°CProcessing temperatures up to ~600°C are acceptableProcessing temperatures up to ~600°C are acceptable“warm”“warm”--forming, PWHT,forming, PWHT,
Good initial toughness allows considerable cold deformationGood initial toughness allows considerable cold deformation
Excellent weldability as a result of the optimised chemical Excellent weldability as a result of the optimised chemical composition, benefits:composition, benefits:
the omission of preheating, the omission of preheating, the application of higher weld deposition ratesthe application of higher weld deposition ratesomission of post weld heat treatmentomission of post weld heat treatment
Weight reduction in the construction without a drawback for Weight reduction in the construction without a drawback for processingprocessing
Summary and conclusion
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• Distortion caused by residual stress :
• Yield strength will lower with increasing temperature
• Tensile stress occurs when material shrinks
• Transformation constituents (martensite/perlite) have higher volume thanaustenite, this creates compressive stress
• Expanding material will be plastically deformed due to colder vincinity(flame straightening)
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12.01.2010 ADVANCED STEEL FOR THE FUTURE 71
tensile
compressive
temperature900700500300
300
300
ferrite / bainiteformation
martensit formation
thermal shrinkage austenite
Yield point = f(T)
Entstehung von Schrumpf- und Umwandlungsspannungen