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L. Di Felice * , J. Meyer Institute for Energy Technology (IFE), Department of Environmental Industrial process, P.O. Box 40, 2027 Kjeller, Norway * Corresponding author's e-mail address: [email protected] SORPTION-ENHANCED REFORMING - SER CONSORTIUM CCT: Catalytic cracking of tars from an indirectly heated gasifier to below green C 8 maximizing the BTX productivity. Sorption Enhanced Reforming (SER): by integrating a high temperature CO 2 sorbent in the reforming step, SER allows to efficiently convert the syngas into H 2 while separating CO 2 . Target: An EHC system that extracts and compresses H 2 at >99.5% purity to 50 bar in a single step and at a primary energy consumption down to 12 MJ/kg H 2 . By incorporating a membrane into the methanol reactor, the selective removal of methanol and water boosts the driving force for methanol synthesis. Target: Validate the Enhanced Membrane Methanol synthesis with single pass conversion > 33% reducing the size of the methanol reactor. Electrochemical Hydrogen Compression (EHC) Target: The adoption of Sorption Enhanced Reforming will reduce the energy intensity of the H 2 production and CO 2 separation from 2 MJ/kg CO2 (current technologies) down to 1.2 MJ/kg CO2 . Recovery of BTX (Benzene, Toluene, Xylene): BTX represent valuable components in the product gas TNO has developed a BTX scrubbing technology based on a proprietary liquid, suitable for any producer gas Valuable bio-BTX improve process economy Mini pilot unit able to process 5 Nm 3 /h dry product gas with a BTX removal > 95 vol% and quantitative removal of higher aromatic compounds Conventional Membrane assisted Target: The syngas treatment process will guarantee a carbon/hydrogen purity above 99% which is 5% higher than current technologies, allowing 17% larger overall carbon usage. The CONVERGE project will validate an innovative process which will increase the biodiesel production by 12% per secondary biomass unit used and reduce the capital investment cost by 10%. The CONVERGE technologies will be validated for more than 2000 cumulated hours taking these from the discovery stage (TRL3) to development stage (TRL5). 2 universities Politecnico di Milano, University of Babes Bolyai 3 research organizations TNO, IFE, Kemijski Institut 2 SMEs BioRecro, HyET 2 large companies Enviral, Campa Iberia 1 professional association Care for Engineering PROJECT OBJECTIVES VALIDATION OF THE SER-EHC INTEGRATION AT THE IFE-HYNOR HYDROGEN TECHNOLOGY CENTER Dual Bubbling Fluidized Bed SER reactor prototype with indirect heat transfer H 2 production capacity 13 Nm 3 /h Solids inventory: ca. 170 kg Solids circulation rate: 75 kg/h PROCESS AND TECHNOLOGY DEVELOPMENT The CONVERGE project has received funding from the European Union’s Horizon 2020 research and innovation programme under Grant Agreement N° 818135 Website: www.converge-h2020.eu Researchgate: CONVERGE: CarbON Valorisation in Energy-efficient Green fuels Linkedin: showcase/converge-horizon2020

PROCESS AND TECHNOLOGY DEVELOPMENT

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Page 1: PROCESS AND TECHNOLOGY DEVELOPMENT

L. Di Felice*, J. Meyer Institute for Energy Technology (IFE), Department of Environmental

Industrial process, P.O. Box 40, 2027 Kjeller, Norway* Corresponding author's e-mail address: [email protected]

SORPTION-ENHANCED REFORMING - SER

CONSORTIUM

CCT: Catalytic cracking of tars from an indirectly

heated gasifier to below green C8 maximizing

the BTX productivity.

Sorption Enhanced Reforming (SER): by integrating a high temperature CO2 sorbent in the reforming step, SER allows to efficiently convert the syngas into H2 while separating CO2.

Target: An EHC system that extracts and compresses H2 at >99.5% purity to 50 bar in a single step and at a primary energy consumption down to 12 MJ/kg H2.

By incorporating a membrane into the methanol reactor, the selective removal of methanol and water boosts the driving force for methanol synthesis.

Target: Validate the Enhanced Membrane Methanol synthesis with single pass conversion > 33% reducing the size of the methanol reactor.

Electrochemical Hydrogen Compression (EHC)

Target: The adoption of Sorption Enhanced Reforming will reduce the energy intensity of the H2 production and CO2 separation from 2 MJ/kgCO2 (current technologies) down to 1.2 MJ/kgCO2.

Recovery of BTX (Benzene, Toluene, Xylene):• BTX represent valuable components in the product gas• TNO has developed a BTX scrubbing technology based on a

proprietary liquid, suitable for any producer gas• Valuable bio-BTX improve process economy• Mini pilot unit able to process 5 Nm3/h dry product gas with a

BTX removal > 95 vol% and quantitative removal of higher aromatic compounds

Conventional

Membrane assisted

Target: The syngas

treatment process will

guarantee a

carbon/hydrogen purity

above 99% which is 5%

higher than current

technologies, allowing 17%

larger overall carbon usage.

The CONVERGE project will validate an innovative process which will increase the biodiesel production by 12% per secondary biomass unit used and reduce the capital investment cost by 10%.

The CONVERGE technologies will be validated for more than 2000cumulated hours taking these from the discovery stage (TRL3) to development stage (TRL5).

2 universitiesPolitecnico di Milano, University of Babes Bolyai3 research organizationsTNO, IFE, Kemijski Institut2 SMEsBioRecro, HyET2 large companiesEnviral, Campa Iberia1 professional associationCare for Engineering

PROJECT OBJECTIVES

VALIDATION OF THE SER-EHC INTEGRATION AT THE IFE-HYNOR

HYDROGEN TECHNOLOGY CENTER

Dual Bubbling Fluidized Bed SER reactor prototype with indirect heat transfer

• H2 production capacity 13 Nm3/h• Solids inventory: ca. 170 kg• Solids circulation rate: 75 kg/h

PROCESS AND TECHNOLOGY DEVELOPMENT

The CONVERGE project has received funding from the European Union’s Horizon 2020 research and innovation programme under

Grant Agreement N° 818135

Website: www.converge-h2020.euResearchgate: CONVERGE: CarbON Valorisation in Energy-efficient Green fuels

Linkedin: showcase/converge-horizon2020