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The Hamiltonian for the positronium atom in the 1S state in a magnetic field B is, to a good
approximation,
,
where 1 labels the electron and 2 the positron. Here S1 and S2 are the spin operators for the
two particles and A is a constant.
(a) Choose the z-axis along B. Which of the following are constants of motion?
1. S12 and S2
2
2. S1z and S2z
3. S2
4. S=S1+S2
5. Sz=S1z+S2z
(b) Find the energy eigenvalues of H in terms of the constants A and .
Solution:
(a) The positronium atom consists of two spin ½ particles. We neglect the spatial
motion of the particles and consider only spin interactions. The first term in the
Hamiltonian is the spin-spin interaction, and the second term is the interaction of the
spins with an external magnetic field.
.
In the { |S,Sz> } basis the matrix of S1×S2 is diagonal, while the matrix of is
diagonal in the {|++>,|+->,|-+>,|-->} basis. Let us work in the {|++>,|+->,|-+>,|-->}
basis.
Then the matrix of S1×S2 is
,
and the matrix of S1z - S2z is
.
The matrix of H therefore is
Problems http://electron6.phys.utk.edu/qm1/modules/m10/problems3.htm
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,
where .
To find out if an observable is a constant of motion, we have to find out if it commutes
with the Hamiltonian H. If it commutes, it is a constant of motion.
1. .
2. The matrix of S1z is .
The matrix of S2z is .
S1z, S2z, and H do not have a set of common eigenvectors. Therefore
.
3. The matrix of S2 is . .
4. The matrix of S1x +S2x is .
The matrix of S1y +S2y is .
The matrix of S1z +S2z is .
.
S1+S2 is not a constant of motion.
5. Sz=S1z+S2z is a constant of motion.
Problems http://electron6.phys.utk.edu/qm1/modules/m10/problems3.htm
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(b) The eigenvalue of H are found from E=C or from
(-C+D-E)(-C-D-E)-4C2 =0.
The value E=C is twofold degenerate.
E2+2CE+C2-D2-4C2=0.
.
An electron (charge -e, and magnetic moment m) moves through a magnetic field.
(a) Write the Hamiltonian for this particle (assume non-relativistic kinematics). Give m for
the electron in Bohr magnetons.
(b) Now ignore the charge and spatial motion of the particle. Assume a constant magnetic
field B0 in the y-direction. Write the Schroedinger equation for the spin state vector,
explicitly giving the Hamiltonian. At time t=0 the spin state is . By solving
the time-dependent Schroedinger equation in which one defines show that the state
at time t1 such that is .
(c) Suppose that a neutron in this spin state passes between the two poles of a magnet. If B
is inhomogeneous and in the x-direction, find the probability that the neutron will be found in
the spin down state (in the x-direction) after passing the gap between the poles of the
magnet.
Solution:
(a) The intrinsic magnetic moment of a particle is .
For an electron , where is the Bohr magneton in Gaussian
units.
In SI units the Hamiltonian of the particle is
,
where
, , .
(b) .
The matrix of H is .
Problems http://electron6.phys.utk.edu/qm1/modules/m10/problems3.htm
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The energy eigenvalues are found from .
Let .
Let .
.
.
.
(c) A neutron is in the state
.
It is passed through the analyzer, which measures the Sx component. The probability
that the neutron will be found in the spin down state is
.
An atom with L=0 and S=½ is initially in its ground state with Sz =-½ . A field is turned
on at t=0 so that the effective Hamiltonian may be taken to be
,
where H0 is the atomic Hamiltonian with H1 = 0. Thus both Sz=½ and Sz=-½ states have the
same eigenvalue of H0 in the ground state.
(a) What is the probability P, to lowest order in H1, that the atom remains in the state
|S=½,Sz=-½ > at time t?
Here , e is the magnitude of the electron charge, me is the electron mass,
and c is the velocity of light in the vacuum.
(b) Under what conditions on t will P=0?
Solution:
Problems http://electron6.phys.utk.edu/qm1/modules/m10/problems3.htm
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(a) Assume that the energy of the twofold degenerate ground state is much lower than
the energy of any excited state, and approximate the system by a two-level system.
Denote the two levels by |+> and |->. H0|+>=E0|+>, H0|->=E0|->, the system is
degenerate.
{|+>,|->} are the eigenstates of Sz. .
At t=0 the system is in the state |->, but the Hamiltonian is H0+W=H, with
.
In the {|+>,|->} the matrix of W is
.
The matrix of H is
.
The eigenvalues of H are , and the corresponding eigenfunctions are
.
In this problem .
.
.
.
If then .
(b) If with n an odd integer, then .
The Hamiltonian of a system of two spin ½ particles may be written as
,
where S1 and S2 are the spin matrices for particle 1 and 2 respectively.
Problems http://electron6.phys.utk.edu/qm1/modules/m10/problems3.htm
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(a) Show that H commutes with the square of the total spin operator and the z-component of
the total spin.
(b) Find the eigenspinors and eigenenergies of this Hamiltonian.
Solution
(a) The first term (A) is the part of the Hamiltonian that does not depend on spin, the
second term is the spin-spin interaction, and the third term is the interaction of the
spins with an external magnetic field. In the {|S,Sz>} basis the matrices of
are diagonal.
,
.
, .
The matrix of H is therefore diagonal and the matrix of S2 is diagonal.
, .
Since all these matrices are diagonal, they all commute with each other.
(b) The eigenvalues of H are the diagonal matrix elements. The eigenvectors are the
corresponding basis vectors,
and .
Problems http://electron6.phys.utk.edu/qm1/modules/m10/problems3.htm
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