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PROBLEMAS AMBIENTALES DE LOS CREMATORIOS Fernando Palacios Correo electrónico: [email protected] Ispaster 6 marzo 2018

PROBLEMAS AMBIENTALES DE LOS CREMATORIOS · DE LA VIDA SUSTANCIAS ... Water H2O % ... deposits and may bio-accumulate in the food chain after methylation by microbiota

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PROBLEMAS

AMBIENTALES

DE LOS

CREMATORIOS

Fernando Palacios

Correo electrónico: [email protected]

Ispaster 6 marzo 2018

¿QUÉ SE INCINERA

EN UN

CREMATORIO?

SE INCINERAN

CADÁVERES QUE HAN

ACUMULADO A LO LARGO

DE LA VIDA SUSTANCIAS

PELIGROSAS COMO

METALES PESADOS

DIOXINAS, PBDEs, ETC

Toxicological Overview

Summary of Health Effects

Dioxin is a term used to describe a group of closely related compounds with similar chemical

structures but which vary greatly in their toxicity. These include 75 polychlorinated dibenzo- p-

dioxins and 135 polychlorinated dibenzo-p-furans, the most toxic being 2,3,7,8-

tetrachlorodibenzo- p -dioxin (TCDD). TCDD is the most extensively studied of the dioxins and

most of the data in this document refer to TCDD.

Dioxins are well absorbed following oral exposure and undergo extensive distribution throughout

body tissues, with particular accumulation in the liver and adipose tissues [1]. Dioxins are also

expected to be well absorbed following inhalation and dermal exposure. Dioxins are not rapidly

eliminated and are extremely persistent, the half-life of TCDD in humans is considered to

approximately 7 to 12 years [2]. Due to the extensive distribution and persistence of absorbed

dioxins there is a high potential for accumulation following repeated exposure.

LAS DIOXINAS SON BIEN ABSORBIDAS POR EXPOSICIÓN ORAL Y ADQUIEREN UNA EXTENSA

DISTRIBUCIÓN EN TODOS LOS TEJIDOS DEL CUERPO, CON ACUMULACIÓN PARTICULAR EN EL

HÍGADO Y EN TEJIDOS ADIPOSOS. LAS DIOXINAS TAMBIÉN SON BIEN ABSORBIDAS POR

INHALACIÓN Y EXPOSICIÓN DÉRMICA. LAS DIOXINAS NO SON ELIMINADAS RÁPIDAMENTE Y

SON EXTREMADAMENTE PERSISTENTES, LA VIDA MEDIA DE LAS TCDD EN PERSONAS SE

CONSIDERA APROXIMADAMENTE DE 7 A 12 AÑOS. DEBIDO A LA EXTENSA DISTRIBUCIÓN Y

PERSISTENCIA DE LAS DIOXINAS ABSORBIDAS EXISTE UN ALTO POTENCIAL ACUMULATIVO

SIGUIENDO A UNA EXPOSICIÓN REPETITIVA.

TAMBIÉN SE INCINERAN:

Materiales que comúmente se encuentran en los

cadáveres (empastes, dentaduras, prótesis, siliconas,

material ortopédico, marcapasos, desfibriladores)

Medicamentos utilizados para tratamientos de la salud

Sustancias químicas del embalsamamiento

Ataúdes (maderas tratadas, barnices,

embellecimientos, herrajes, juntas)

Prendas de ropa natural y sintética

REVIEW ARTICLE Human body preservation – old and new techniques Erich

Brenner

Division for Clinical and Functional Anatomy, Department of Anatomy, Histology

and Embryology, Innsbruck Medical University, Innsbruck, Austria .J. Anat.

(2014) 224, pp316—344

Embalming fluids

Preservatives or fixatives

Aldehydes

Formaldehyde

Glutaraldehyde

Glyoxal

Tetrakis(hydroxymethyl)phosphonium chloride

1-Methyl-3-octyloxymethylimidazolium tetrafluoroborate

Alcohols

Methanol

Ethanol

Isopropanol

Phenoxyethanol

Sodium Nitrate

Boric acid/sodium borate CONT.

PRODUCTOS DE EMBALSAMAMIENTO

Disinfectants

Phenol

Phenolic derivates

Salicylic acid

Sodium pentachlorophenate

Thymol

4-Chloro-3-methylphenol (parol;4-

chloro-m-cresol,PCMC)

1,4-Dichlorobenzene

Chinosol/oxyquinolin

Quaternary ammonium compounds

Benzalkonium chloride

Tetradecylamine

Polyhexamethylene guanidine

hydrochloride

Modifying agents

Softener

Anticoagulants

Salts

Green or natural embalming fluids

TOXICIDAD PRODUCTOS EMBALSAMAMIENTO

A PESAR DEL RIESGO PARA LA SALUD, LOS EMBALSAMADORES CONTINÚAN

UTILIZANDO SUSTANCIAS CANCERÍGENAS COMO EL FORMOL.

ESTUDIO SOBRE LOS EFECTOS TÓXICOS DE LOS FLUIDOS DE EMBALSAMAMIENTO

PARA LOS ESTUDIANTES Y LOS PROFESIONALES

The guide asks for a copy of temperature recording and stack emission analysis for:

Carbon Dioxide CO2 %

Carbon Monoxide CO %

Oxygen O2 %

Nitrogen N2 %

Water H2O %

Particulate emission

The major public health concern for the people living in the vicinity of crematoria is probably not

mercury but other pollutants such as particulate matter and pollutants from incomplete combustion.

(LA MAYOR PREOCUPACIÓN SOBRE SALUD PÚBLICA EN LAS PERSONAS QUE VIVEN CERCA DE

UN CREMATORIO NO ES PROBABLEMENTE EL MERCURIO SINO OTRAS SUSTANCIAS COMO LAS

PARTÍCULAS Y LOS CONTAMINANTES DE LA COMBUSTIÓN INCOMPLETA).

Mercury is of concern because of long-range transport. Most Mercury is volatilized as elemental

mercury, some is oxidized and a small fraction is bound to particulate matter. Volatilized Mercury re-

deposits and may bio-accumulate in the food chain after methylation by microbiota.

The best option would be to remove amalgam fillings before cremation, but in practice this might be

difficult to achieve for practical and cultural reasons. This option is worth to explore with the

crematorium operator.

CONT.

Public Health Impact of Crematoria (report by Chief Medical Officer of

British Columbia)

EMISIONES DE LA CREMACIÓN

Mercury:

Estimates of average mercury release per cremation of a human body vary considerably:

o 5 to 3.41g in Sweden and Finland[5]: Similar to the 3g in finding from studies from Mills in

UK[6] and Kunzler and Andree[7] in Switzerland.

o Emissions from crematoria were estimated to be the third highest emission source of Mercury

in Sweden[8]. (LAS EMISIONES DE CREMATORIOS FUERON LA TERCERA FUENTE DE

EMISIÓN DE MERCURIO MÁS ALTA DE SUECIA)

o 1.5 g to 4.5 g in the UK (National Atmospheric Emissions Inventory or NAEI ):.

o NAEI estimates that in 1998, crematoria accounted for 11% of the United Kingdom’s total

atmospheric mercury emissions. Between 0.4 to 1.23 tonnes mercury (for 446,000

cremations)[9]

o 0.94 x 10-3 g in US. Results of the testing for uncontrolled mercury emissions of a propane-

fired incinerator at a crematorium inCalifornia ranged from 3.84 x 10-8 to 1.46 x 10-6 kg/body

burned; the average mercury emission factor was 0.94 x 10-3 g/body burned. The test results

were obtained from a confidential test report to the Califonia Air Resource Board (FIRE,

1995).[10]

o EPA estimated that all US crematories, together, would have produced a total of 108 kg of

mercury emissions in 1999 (598,721 cremations).

A US flow model estimates cremation as the third largest source of air emissions of mercury from

products at 2436 kg a year in 2005 (3.4 g per cremation and approximate 709,000 cremations)[11] (EN

ESTADOS UNIDOS SE HA ESTIMADO QUE LA CREMACIÓN ES LA TERCERA FUENTE DE EMISIONES

AÉREAS DE MERCURIO PRODUCIENDO 2436 kg EN 2005 A UNA MEDIA DE 3.4 g DE MERCURIO POR

CREMACIÓN SOBRE UN TOTAL DE 709.000 CREMACIONES).

CONT.

In Canada, amalgam continues to be used for tooth

restorations due to its durability and low cost. The use of

amalgam for new fillings in dentist office is declining and

may eventually even become phased out. Maybe this

problem resolves itself spontaneously in the future. In the

immediate future though emissions from mercury will

probably increase since there is an increase in the number

of cremations and more people retain their heavily restored

teeth into old age.

EN CANADA EN EL FUTURO INMEDIATO LAS EMISIONES

DE MERCURIO PROBABLEMENTE SE INCREMENTARÁN

DEBIDO AL AUMENTO DEL NÚMERO DE CREMACIONES Y

A QUE MUCHAS PERSONAS RETIENEN LOS DIENTES

RESTAURADOS HASTA LA VEJEZ

CONT.

Amalgan contains approximately 50% mercury. It is considered special waste through application of

the BC Special Waste Regulation (BCSWR) under the BC Waste Management Act.[12]

Canada-wide Standard (CWS) on Mercury for Dental Amalgam Waste was endorsed by the Canadian

Council of Ministers of the Environment (CCME) in 2001.[13]

The release from crematoria is not considered in the CWS for Dental amalgam waste.

Dentists have a legal requirement to use a mercury separator in their office.

According to environment Canada Approximately 1.3 T/yr of mercury in new filling material is placed

each year in the mouths of Canadians and approximately 2 Tonnes/yr of mercury in amalgam waste

is generated from the removal of old fillings and from the placing of new fillings.[14]

Of the 215,742 deaths in Canada in 2004, 120,714 bodies have been cremated.[15].

This gives an estimate of 109 kg to 411.6 kg mercury emissions from cremations for the year 2004 (If

we use the estimates of 0.9 to 3.41 g mercury emissions per cremation).

(DE 215.742 MUERTES EN CANADÁ EN 2004, HAN SIDO INCINERADOS 120.714 CADÁVERES,

ESTOS SUPONEN UNA ESTIMACIÓN DE 109 A 411.6 KG DE EMISIONES DE MERCURIO

PROCEDENTES DE CREMACIONES EN 2004, A RAZÓN DE 0.9 A 3.41 GRAMOS DE EMISIONES DE

MERCURIO POR CREMACIÓN).

The total mercury emission for Canada in 2000 was estimated as 8,025 kg.[16]

The OSPAR Convention for the Protection of the Marine Environment of the North-East Atlantic calls

for Application of Best Available Techniques (BAT) to prevent the dispersal into the environment of

mercury from crematoria[17].National emission standards that require gas cleaning to remove

mercury vapor at new or large crematoria are in place in several European countries (Austria,

Belgium, Germany, Great Britain, The Netherlands, Norway Sweden and Switzerland).

CONT.

John Reindl, Retired P.E. Retired from Dane County Department of Public Works

Madison, Wisconsin Current email [email protected]

Summary of References on Mercury Emissions from Crematoria September 25,

2012

CONT.

MERCURIO EN EL CABELLO DE TRABAJADORES DE CREMATORIOS: TODOS

LOS EMPLEADOS TIENEN VALORES MEDIOS POR ENCIMA DEL CONTROL

Mercury has been found to be significantly elevated in the

hair of crematorium workers especially in administrators

who work in closed environment with limited air

ventilation. Of the 97 crematoria workers, 3% had

concentrations higher than 6 ppm which is considered as

the maximum tolerable level. Mean mercury concentrations

were 1.96 ppm for administrative personnel and 1.47 ppm

for ground personnel compared to 0.97 ppm for controls.

The number of amalgam fillings was taken into

consideration. A limiting factor of the study is that there is

no information on possible diet exposure to mercury. The

authors argue that fish is only a minor part in the diet in

the UK. The authors conclude that this study contributes to

the evidence that emission monitoring and control is

warranted. [18]

CONT.

Dioxins and furans:

Since cremation is a combustion process of organic matter

dioxin and furans may be formed during the process due to

incomplete combustion or new formation in the stack induced

by high temperatures.

In the USA the emission of dioxins and furans measured at a

crematorium with new technology was 0.5 µg TEQ per cremated

body.

European test data found higher values: 4.9 µg TEQ per body at

two Dutch crematoria and 70–80 µg TEQ in a British

crematorium with older technology. Reviewers of the EPA dioxin

emission inventory report recommend to use the Dutch Data as

reference.[20]

(LOS DATOS SOBRE EMISIONES DE DIOXINAS Y FURANOS AL

INCINERAR CADÁVERES EN CREMATORIOS SON MÁS ALTOS

EN EUROPA QUE EN ESTADOS UNIDOS)

CONT.

A Japanese study, Takeda et al (2001) found an average of 3.9 µg and a median of 1.8

µg TEQ/body with a maximum of 24 µg TEQ/ body. The operational condition of the

crematorium, mainly the temperature control, influenced to a large extent the

emission of dioxins and furans. Takeda found in a study in Japan 1998

measurements ranging from 9.9pg to 6500 pg TEQ/m3 and in a second study in 2001

measurements between 64 pg TEQ/m3 and 24000 pg TEQ/m 3. [21]

The authors concluded that it is necessary to take measures immediately to reduce

emissions given the high volume of cremations.

A recent stack test conducted by Environment Canada at a crematorium located in

Mainland, Ontario detected a dioxins and furans concentration of 227 picograms

ITEQ/m3 resulting in an estimated annual emission rate of .079 milligrams/year.

Higher individual test run results have been noted in testing performed by a

commercial source testing firm on a similar new facility in Windsor, Ontario.[22]

Canada-wide standards have been developed for waste incineration, burning salt

laden wood in coastal pulp and paper boilers, iron sintering, electric arc furnace

steel manufacturing, and conical municipal waste combustion, crematoria are

exempt.

Municipal waste incineration 80pg I-TEQ/m 3

Medical waste incineration 80pg I-TEQ/m 3

Hazardous waste incineration 80pg I-TEQ/m 3

Sewage sludge incineration 80pg I-TEQ/m 3 CONT.

Conclusion and recommendations:

Crematoria have the potential to have a negative impact on public health.

There is a lack of emission data of existing facilities in Canada and North

America. The few emission studies that have been done are on new facilities.

Internationally there is clearly a concern around the polluting capacity of

crematoria. Crematoria emissions are strictly regulated in most European

countries, Japan, and Hongkong. In Canada and the USA, emissions of

crematoria are ‘assumed’ to have only a small impact on public health.

Crematoria should use the best available technology economically achievable

to reduce air pollutant emissions and should operate at an optimal level with

strict temperature control to obtain complete combustion.

Minimum operating temperatures, minimum oxygen levels, maximum carbon

monoxide levels, maximum opacity measures, maximum PM levels should be

established based on work in other jurisdictions.

A crematorium should not be sited [sic] close to a neighborhood (UN

CREMATORIO NO SE DEBERÍA SITUAR EN LA PROXIMIDAD DE UNA ZONA

URBANIZADA)

Stack emissions and ambient air quality should be monitored before and after a

crematorium starts functioning.

Golden Gate University Environmental Law Journal Volume 2 Issue 1Symposium

Edition - the West's Aging Dams: Retain or Remove?

Article 7 August 2008 Dust in the Wind? The Bell Tolls for Crematory Mercury

Philip Donald Batchelder

2. MERCURY EMISSIONS FROM CREMATORIA

The origin of mercury emissions from crematoria comes mainly from mercury amalgam

fillings in human remains and potentially from metallic ornamental pieces on caskets

(France). Research in the Netherlands indicates that the number of fillings in Dutch

human remains will decrease from 5,4 to 4,9 over the 1995-2020 period. However, due

to differences in the number of fillings in people of different age groups, the average

amount of fillings will increase from 3,2 to 5,1. This trend means that mercury

emissions in the Netherlands will double between now and 2020 unless abatement

measures are introduced. Cremations in France are increasing (from 2% of deceased

persons in the 1970s to 16% in 2000). The number of ovens has increased in the last

two years by 20, resulting in 110 ovens in 80 crematoria.

Information provided on the estimated amount of mercury emitted from crematoria, the

number of crematoria per country and the number of cremations per year are given in

Table 1. This confirms that mercury from crematoria represent a significant source of

mercury (approximately 1 tonne per annum just for the 8 Contracting Parties reporting).

However, differences in the emissions factors for calculating releases mean that it is

not possible to compare the results. Several Contracting Parties (Netherlands and

Norway) report that emissions will increase in the next few years due to the increasing

number of mercury amalgam fillings per corpse. Sweden reports that emissions of

mercury from crematoria are now the most important point source. France has reported

that mercury is concentrated principally in the dust. CONT.

CONT.

CANTIDADES DE MERCURIO EMITIDAS A LA ATMÓSFERA ANUALMENTE

EN DISTINTOS PAÍSES

5 Note: In general, information was not supplied regarding how

the mercury emissions were calculated, and whether the quoted

figures were based on actual measurements or estimates from

mercury per corpse. 6 Netherlands point out that "the tendency is

an increase of the mercury emissions by crematoria from 80 to

160 kg per year in the next years if there are no measures". 7

Based on measurement of mercury emissions arising from

cremations. 8 Note: This figure is based on the year 2000 and

looks low compared with other countries. The emission is on

average 103,7 mg hg per cremation. 9 Belgium reports that

cremations are increasing by 10% per year. 10 The Icelandic

crematorium operates once a week, if required. 11 No information

available yet; a monitoring programme is under development. 12

Crematoria in Lisbon (2), Oporto (all operated continuously) and

Ferreira do Alentejo (discontinuous operation). Type of

installations: Shelton (two burners on propane gas, temperature

of last chamber 1200ºC). CONT.

Permitting review of an air pollution construction permit for a crematory (Spring Hill

Crematory) to Spring Hill Memorial Park and Funeral Home, LLC at Spring Hill,

Tennessee The Tennessee Division of Air Pollution Control issued a construction

permit to the Spring Hill Crematory

Alternatives Suggestions by the some of the participants indicated other alternatives

for crematories should be addressed. Those included removal of teeth with mercury

amalgams prior to cremation, installing air pollution control equipment such scrubbers

or filters, and moving the crematory site to a more remote location. Regarding

removal of teeth with mercury amalgams prior to cremation is not a prescribed

practice and disdained by the funeral home industry as well as families of the

deceased. The installation of scrubber or filter controls was not needed due to the

extent of the emissions and the cremator design by the manufacturer that is built and

equipped to operate to comply with state standards. Regarding the location of a

crematory, the location of any air pollution source such as a crematory is subject to

approval by local zoning and city and county commissions and is not the prerogative

of the Division of Air Pollution Control. The three main choices for disposition of the

deceased human remains continue to be burials, entombment in vaults, and

cremation. Although some state funeral boards may allow other processes such

alkaline hydrolysis, this alternative is not currently approved by the Tennessee Board

of Funeral Directors and Embalmers/Burial Services. Accordingly, it appears more

crematories will apply for air permits as the demand for cremation continues to

increase. The funeral home business intends to provide that service at a local level

with cremation taking place either at the funeral home property or at some other

location.

CONT.

CONT.

EMISIONES DE UN CREMATORIO EN ITALIA

CONT.

CONT.

CONT.

CONT.

EMISIONES DE UN CREMATORIO EN ITALIA: LOS PARÁMETROS PAHs Y

DIOXINAS Y FURANOS TOTALES (PCDD + PCDF) SON 170 VECES Y 11

VECES MAYORES, RESPECTIVAMENTE, QUE LOS LÍMITES STANDARD.

TAMBIÉN SE SUPERA EL VALOR LÍMITE DEL MERCURIO.

ALTERNATIVAS ECOLÓGICAS

A LOS CREMATORIOS

MÉTODO PROMESSA

http://www.promessa.se/

MÉTODO DE HIDRÓLISIS ALCALINA

http://resomation.com/

Conclusiones sobre los crematorios

Los crematorios incineran cadáveres humanos que contienen

sustancias orgánicas persistentes y acumulativas y una variedad de

materiales que han incorporado las personas durante su vida como

empastes, dentaduras, prótesis, silicona, aparatos electrónicos, etc,

así como los féretros y las sustancias de embalsamamiento.

Los crematorios son una fuente importante de emisiones de

mercurio, metales pesados, dioxinas, bifenilospoliclorados,

hidrocarburos aromáticos policíclicos y otras sustancias peligrosas

que son cancerígenas, mutágenas o que afectan a la reproducción.

Las emisiones de los crematorios superan los valores standard de

emisión establecidos por las agencias reguladoras.

No está recomendado ubicar los crematorios cerca de zonas

urbanizadas.

Hoy en día los crematorios deben ser sustituidos por instalaciones

ecológicas de secado en frío (método Promessa) o de licuefacción o

disolución del cuerpo (método de hidrólisis alcalina).