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Air Pollution Meteorology
Atmospheric thermodynamics
Atmospheric stability
Boundary layer development
Effect of meteorology on plume dispersion
Atmosphere
Pollution cloud is interpreted by the chemical composition and physical characteristics of the atmosphere
Concentration of gases in the atmosphere varies from trace levels to very high levels
Nitrogen and oxygen are the main constituents. Some constituents such as water vapor vary in space and time.
Four major layers of earth’s atmosphere are:
Troposphere
Stratosphere
Mesosphere
Thermosphere
Atmospheric Thermodynamics
A parcel of air is defined using the state variables
Three important state variables are density, pressure and temperature
The units and dimensions for the state variables are
Density (mass/volume)
gm/cm3 ML-3
Pressure (Force/Area) N/m2 ( Pa ) ML-1T-2
Temperature o F, o R, o C, o K
T
Humidity is the fourth important variable that gives the amount of water vapor present in a sample of moist air
Equation of State
Relationship between the three state variables may be written as: f ( P, ρ ,T) = 0
For a perfect gas: P = ρ .R .T
R is Specific gas constant
R for dry air = 0.287 Joules / gm /oK
R for water vapor = 0.461 Joules / gm /oK
R for wet air is not constant and depend on mixing ratio
Processes in the Atmosphere
An air parcel follows several different paths when it moves from one point to another point in the atmosphere. These are:
Isobaric change – constant pressure
Isosteric change – constant volume
Isothermal change – constant temperature
Isentropic change – constant entropy (E)
Adiabatic Process – δQ = 0 (no heat is added or
removed )
The adiabatic law is P. αγ = constant E = T
Q
Statics of the Atmosphere
Vertical variation of the parameters = ?
Hydrostatic Equation: Pressure variation in a "motionless" atmosphere
Pressure variation in an atmosphere:
Relationship between pressure and elevation using gas law:
gz
porg
z
p
1.
2
21
dt
zd
z
pg
TR
g
z
p
p d
1
Statics of the Atmosphere
Integration of the above equation gives
Using the initial condition Z=0, P = P0
The above equation indicates that the variation of pressure depends on vertical profile of temperature.
For iso-thermal atmosphere
Therefore, pressure decreases exponentially with height at a ratio of 12.24 mb per 100m.
zTR
g
p
po
do
.exp 1
z
do
dzTR
g
p
p
0
1.ln
Lapse Rate: Lapse rate is the rate of change of temperature with
height
Lapse rate is defined as Γ = -δT δz
Value of Γ varies throughout the atmosphere
Potential Temperature: Concept of potential temperature is useful in comparing two air
parcels at same temperatures and different pressures.
Atmosphere Stability The ability of the atmosphere to enhance or to resist
atmospheric motions
Influences the vertical movement of air.
If the air parcels tend to sink back to their initial level after the lifting exerted on them stops, the atmosphere is stable.
If the air parcels tend to rise vertically on their own, even when the lifting exerted on them stops, the atmosphere is unstable.
If the air parcels tend to remain where they are after
lifting stops, the atmosphere is neutral.
Atmospheric Stability
The stability depends on the ratio of suppression to generation of turbulence
The stability at any given time will depend upon static stability ( related to change in temperature with height ), thermal turbulence ( caused by solar heating ), and mechanical turbulence (a function of wind speed and surface roughness).
Atmospheric Stability
Atmospheric stability can be determined using adiabatic lapse rate.
Γ > Γd Unstable
Γ = Γd Neutral
Γ < Γd Stable
Γ is environmental lapse rate
Γd is dry adiabatic lapse rate (10c/100m) and dT/dZ = -10c /100 m
Atmospheric Stability Classification
Schemes to define atmospheric stability are: P- G Method
P-G / NWS Method
The STAR Method
BNL Scheme
Sigma Phi Method
Sigma Omega Method
Modified Sigma Theta Method
NRC Temperature Difference Method
Wind Speed ratio (UR) Method
Radiation Index Method
AERMOD Method (Stable and Convective cases)
Pasquill-gifford Stability Categories
Surface Wind
Speed (m/s)
Daytime Insolation Nighttime cloud cover
Strong Moderate Slight Thinly overcast or
4/8 low cloud 3/8
< 2 A A - B B - -
2 - 3 A - B B C E F
3 - 5 B B - C C D E
5 - 6 C C - D D D D
> 6 C D D D D
Source: Met Monitoring Guide – Table 6.3
Sigma Theta stability classification
CATEGORY PASQUILL CLASS SIGMA THETA (ST)
EXTREME UNSTABLE A ST>=22.5
MODERATE UNSTABLE B 22.5>ST>=17.5
SLIGHTLY UNSTABLE C 17.5>ST>=12.5
NEUTRAL D 12.5>ST>=7.5
SLIGHTLY STABLE E 7.5>ST>= 3.8
MODERATE STABLE F 3.8>ST>=2.1
EXTREMELY STABLE G 2.1>ST
Source: Atmospheric Stability – Methods & Measurements (NUMUG - Oct 2003)
Temperature Difference (∆T)
Source: Regulatory guide; office of nuclear regulatory research- Table 1
Turbulence
Fluctuations in wind flow which have a frequency of more than 2 cycles/ hr
Types of Turbulence Mechanical Turbulence
Convective Turbulence
Clear Air Turbulence
Wake Turbulence
Boundary Layer Development
Thermal boundary Layer (TBL) development depends on two factors: Convectively produced turbulence
Mechanically produced turbulence
Development of TBL can be predicted by two distinct approaches: Theoretical approach
Experimental studies
Boundary Layer Development
Theoretical approach may be classified into three groups: Empirical formulae
Analytical solutions
Numerical models
One layer models
Higher order closure models
Effects of Meteorology on Plume Dispersion
Dispersion of emission into atmosphere depends on various meteorological factors.
Height of thermal boundary layer is one of the important factors responsible for high ground level concentrations
At 9 AM pollutants are pulled to the ground by convective eddies
Spread of plume is restricted in vertical due to thermal boundary height at this time
Wind Velocity
A power law profile is used to describe the variation of wind speed with height in the surface boundary layer
U = U1 (Z/Z1)p Where,
U1 is the velocity at Z1 (usually 10 m)
U is the velocity at height Z.
The values of p are given in the following table.
Stability Class Rural p Urban p
Very Unstable 0.07 0.15
Neutral 0.15 0.25
Very Stable 0.55 0.30
Beaufort Scale
This scale is helpful in getting an idea on the magnitude of wind speed from real life observations
Atmospheric condition Wind speed Comments
Calm < 1mph Smoke rises vertically
Light breeze 5 mph Wind felt on face
Gentle breeze 10 mph Leaves in constant motion
Strong 25 mph Large branches in motion
Violent storm 60 mph Wide spread damage
Wind Rose Diagram (WRD)
WRD provides the graphical summary of the
frequency distribution of wind direction and wind
speed over a period of time
Steps to develop a wind rose diagram from hourly observations
are:
Analysis for wind direction
Determination of frequency of wind in a given wind
direction
Analysis for mean wind speed
Preparation of polar diagram
Calculations for Wind Rose
% Frequency =
Number of observations * 100/Total Number of
Observations
Direction: N, NNE, ------------------------,NNW, Calm
Wind speed: Calm, 1-3, 4-6, 7-10, -----------
Determination of Maximum Mixing Height
Steps to determine the maximum mixing height for a day are:
Plot the temperature profile, if needed
Plot the maximum surface temperature for the day
on the graph for morning temperature profile
Draw dry adiabatic line from a point of maximum
surface temperature to a point where it intersects
the morning temperature profile
Read the corresponding height above ground at the
point of intersection obtained. This is the maximum
mixing height for the day