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September 16 2011 Herlenius Nils for Ergon Europe MEA Inc. Slide No. 1 This Material is Copy write protected. CC BT-NC-ND Premium Transformer Oil Processing and its impacts on Transformer Oil Lifetime By Nils Herlenius

Premium Transformer Oil Processing and its impacts on ... ERGON 2011_0.pdf · Premium Transformer Oil ... Transformer, since oil change / regeneration is not frequent as for a Car

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September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 1This Material is Copy write protected. CC BT-NC-ND

Premium Transformer Oil Processing and its impacts on Transformer Oil Lifetime

By Nils Herlenius

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 2This Material is Copy write protected. CC BT-NC-ND

Presentation Topics

• Manufacturing Premium Transformer OilNaphthenic versus Paraffinic OilTransformer Oil StandardsInhibited or un-inhibited oilCorrosive Sulphur

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 3This Material is Copy write protected. CC BT-NC-ND

Crude Oil

Distillation “Cleaning” BlendingCrude Selection

Transformer Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 4This Material is Copy write protected. CC BT-NC-ND

Transformer Oil• Electrical Properties• Cooling Properties• Health & Safety• Oxidation Stability = Long Life• Free from Corrosive Sulphur

Requested Standard

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 5This Material is Copy write protected. CC BT-NC-ND

Crude Oil

Distillation “Cleaning” BlendingCrude Selection

Transformer Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 6This Material is Copy write protected. CC BT-NC-ND

Naphthenic or Paraffinic?

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 7This Material is Copy write protected. CC BT-NC-ND

Theoretical Molecule in Crude Oil

Aromatic Naphthenic

Paraffinic

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 8This Material is Copy write protected. CC BT-NC-ND

Theoretical Molecule in Crude Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 9This Material is Copy write protected. CC BT-NC-ND

Definition: Naphthenic / Paraffinic Oil

Cp below 50% Naphthenic oilCp 50 – 60% Intermediate oilCp 60%< Paraffinic oil

Cp = Paraffinic Carbon Type

Cn = Naphthenic Carbon TypeCn Above 40% Naphthenic oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 10This Material is Copy write protected. CC BT-NC-ND

Naphthenic or Paraffinic?

• Low Viscosity Index

• High Solubility

• Low Pour Point Cooling Properties

Long Life

Specific characteristics of Naphthenic crude oils, makes it more suitable for Transformer Oil than paraffinic type:

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 11This Material is Copy write protected. CC BT-NC-ND

Naphthenic or Paraffinic?

• Low Viscosity Index Yes!No!

Temperature

Visc

osity

Temperature

Visc

osity• Ideal Viscosity Index

High Viscosity Index

Low Viscosity Index

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 12This Material is Copy write protected. CC BT-NC-ND

Naphthenic or Paraffinic?

High Solubility Low Solubility

The Solubility of the oil is more important for a Transformer, since oil change / regeneration is not frequent as for a Car

= Naphthenic Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 13This Material is Copy write protected. CC BT-NC-ND

Crude Oil

Distillation “Cleaning” BlendingCrude Selection

Transformer Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 14This Material is Copy write protected. CC BT-NC-ND

Distillation

Source of Picture: http://www.absoluteastronomy.com/topics/Oil_refinery

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 15This Material is Copy write protected. CC BT-NC-ND

Distillation

Fractionation allows a refiner to separate crude into different

temperature range blocks each with different molecular weight, viscosity, chemistry and sulfur levels. These serve as Feed

Stocks (FS) for other processes.

Gasoline40°C to 220°C

Gas & LPGBelow Ambient

to 40°C

Light Gasoil or Diesel

220°C to 370°C

Heavy Gasoilor Lubricants

370°C to 565°C

Extra Heavy Gasoil or Brightstock

565°C to 700°C

Asphalt or Pitch Bottoms

> 700°C

TypicalTransformer Oil

300 - 370°C

A good Pricing trend for transformer oil is the

VGO Notations

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 16This Material is Copy write protected. CC BT-NC-ND

Crude Oil

Distillation “Cleaning” BlendingCrude Selection

Transformer Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 17This Material is Copy write protected. CC BT-NC-ND

• Transformer Oil Standard(s)• Inhibited or un-inhibited oil• Special Customer Request

Cleaning ProcessThe Purpose of the Cleaning Process is to Meet or Exceed Targeted Transformer Oil Standards. Before you start, you need to decide upon:

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 18This Material is Copy write protected. CC BT-NC-ND

Hydrotreating

H2H2S, H2O, NH3

>300°CCatalyst, Pressure,

Contact Time

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 19This Material is Copy write protected. CC BT-NC-ND

Severity of Refining “Cleaning of the oil”

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 20This Material is Copy write protected. CC BT-NC-ND

For Sulfur to be Corrosive, it needs to be Reactive

As such, its easy to remove in the refining process!

Transformer OilProperties

Good

Poor

Severity of Refining “Cleaning of the oil”

Response to Inhibitor

Electrical Properties

Oxidation Stability

CORROSIVE!

Elimination of Corrosive Sulfur

Gas Absorption

= Premium un-inhibited Transformer Oil

= Poorly Refined Corrosive Transformer Oil= Premium inhibited Transformer Oil

Health & Safety

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 21This Material is Copy write protected. CC BT-NC-ND

Degree of Oxidation

Life Time of Oil

InhibitedPoorly Refined Oil

Un-inhibitedHighly Refined Transformer Oil

Inhibited Highly Refined Transformer Oil

Un-inhibited Poorly Refined Oil

Critical Level

Good!

Bad!

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 22This Material is Copy write protected. CC BT-NC-ND

Crude Oil

Distillation “Cleaning” BlendingCrude Selection

Transformer Oil

September 16 2011Herlenius Nils for

Ergon Europe MEA Inc. Slide No. 23This Material is Copy write protected. CC BT-NC-ND

Discussions & Questions…