POLYSOFT BINDER - PART B - aquasealllc.com · Inhalation of vapors or aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful. The

POLYSOFT BINDER - PART B

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Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMEPOLYSOFT BINDER - PART B

STATEMENT OF HAZARDOUS NATURECONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.CONSIDERED A DANGEROUS MIXTURE ACCORDING TO DIRECTIVE 1999/45/EC AND ITS AMENDMENTS.HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.

NFPA

FLAMMABILITY1HEALTH HAZARD3 INSTABILITY0

PRODUCT USEPolyurethane curative

Section 2 - HAZARDS IDENTIFICATION

CANADIAN WHMIS SYMBOLS

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SUPPLIERCompany: PolySoft Pty Ltd Address:2/71 Prince William Drive,Seven Hills, NSW 2147, Australia

Telephone: +61 2 4322 1453 Emergency Tel:1300 308 037 (AUS) Fax: +61 2 4325 3541Email: [email protected]

Hazard Alert Code: EXTREME Material Safety Data Sheet (REVIEW)Jun-29-2012 9-36874B293L Version No:1


Page 2 of 17Section 2 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

RISKCauses severe burns.Risk of serious damage to eyes.May cause SENSITIZATION by skin contact.Possible risk of irreversible effects.Toxic: danger of serious damage to health by prolonged exposure if swallowed.Harmful by inhalation, in contact with skin and if swallowed.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED■ Toxic effects may result from the accidental ingestion of the material; animal experiments indicate thatingestion of less than 40 gram may be fatal or may produce serious damage to the health of the individual.■ Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations and swellings of themucous membranes, profuse saliva production, with an inability to speak or swallow. Both the esophagus andstomach may experience burning pain; vomiting and diarrhea may follow. Epiglottal swelling may result inrespiratory distress and asphyxia; shock can occur. Narrowing of the esophagus, stomach or stomach valve mayoccur immediately or after a long delay (weeks to years). Severe exposure can perforate the esophagus orstomach leading to infections of the chest or abdominal cavity, with low chest pain, abdominal stiffness andfever. All of the above can cause death.

EYE■ If applied to the eyes, this material causes severe eye damage.■ Direct eye contact with corrosive bases can cause pain and burns. There may be swelling, epitheliumdestruction, clouding of the cornea and inflammation of the iris. Mild cases often resolve; severe cases canbe prolonged with complications such as persistent swelling, scarring, permanent cloudiness, bulging of theeye, cataracts, eyelids glued to the eyeball and blindness.

SKIN■ Skin contact with the material may be harmful; systemic effects may resultfollowing absorption.■ The material can produce severe chemical burns following direct contactwith the skin.■ Skin contact with alkaline corrosives may produce severe pain and burns; brownish stains may develop. Thecorroded area may be soft, gelatinous and necrotic; tissue destruction may be deep.■ Open cuts, abraded or irritated skin should not be exposed to this material.■ Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injurywith harmful effects. Examine the skin prior to the use of the material and ensure that any external damageis suitably protected.

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Page 3 of 17Section 2 - HAZARDS IDENTIFICATION

INHALED■ Inhalation of vapors or aerosols (mists, fumes), generated by the material during the course of normalhandling, may be harmful.■ The material can cause respiratory irritation in some persons. The body's response to such irritation cancause further lung damage.■ Inhaling corrosive bases may irritate the respiratory tract. Symptoms include cough, choking, pain anddamage to the mucous membrane. In severe cases, lung swelling may develop, sometimes after a delay of hoursto days. There may be low blood pressure, a weak and rapid pulse, and crackling sounds.■ Inhalation of quantities of liquid mist may be extremely hazardous, even lethal due to spasm, extremeirritation of larynx and bronchi, chemical pneumonitis and pulmonary edema.

CHRONIC HEALTH EFFECTSToxic: danger of serious damage to health by prolonged exposure if swallowed.This material can cause serious damage if one is exposed to it for long periods. It can be assumed that itcontains a substance which can produce severe defects. This has been demonstrated via both short- and long-term experimentation.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Section 4 - FIRST AID MEASURES

SWALLOWED• For advice, contact a Poisons Information Center or a doctor at once.• Urgent hospital treatment is likely to be needed.• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.• Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.• Transport to hospital or doctor without delay.

EYE■ If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.• Continue flushing until advised to stop by the Poisons Information Center or a doctor, or for at least 15 minutes.• Transport to hospital or doctor without delay.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

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NAME CAS RN %Polyol Blend >60bis(2- dimethylaminoethyl)ether 3033-62-3 10-30dibutyltin dilaurate 77-58-7 10-30



Page 4 of 17Section 4 - FIRST AID MEASURES

SKIN■ If skin or hair contact occurs:• Immediately flush body and clothes with large amounts of water, using safety shower if available.• Quickly remove all contaminated clothing, including footwear.• Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Center.• Transport to hospital, or doctor.

INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.• Transport to hospital, or doctor, without delay.Inhalation of vapors or aerosols (mists, fumes) may cause lung edema. Corrosive substances may cause lung damage (e.g. lung edema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorized by him/her. (ICSC13719).

NOTES TO PHYSICIANFor acute or short term repeated exposures to organic tin compounds:• Severe exposure results in tinnitus, deafness, memory loss, psychosis, coma, disorientation and respiratory

depression after a latent period of 1-3 days.• Permanent neurologic sequelae include extrapyramidal hyperkinesia.• The material produces erythmetous skin lesions• Management is primarily supportive.• British Anti-Lewisite and d-penacillamine are not effective as chelators. [Ellenhorn and Barceloux:

Medical Toxicology].Treat symptomatically.For acute or short-term repeated exposures to highly alkaline materials:• Respiratory stress is uncommon but present occasionally because of soft tissue edema.• Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy

may be necessary.• Oxygen is given as indicated.• The presence of shock suggests perforation and mandates an intravenous line and fluid administration.• Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and

solubilization of proteins allow deep penetration into the tissue.Alkalis continue to cause damage after exposure.INGESTION:• Milk and water are the preferred diluentsNo more than 2 glasses of water should be given to an adult.• Neutralizing agents should never be given since exothermic heat reaction may compound injury.* Catharsis and emesis are absolutely contra-indicated.* Activated charcoal does not absorb alkali.* Gastric lavage should not be used.Supportive care involves the following:• Withhold oral feedings initially.• If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.• Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.• Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing

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Page 5 of 17Section 4 - FIRST AID MEASURES

(dysphagia).SKIN AND EYE:• Injury should be irrigated for 20-30 minutes.• Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology].Scanty animal data indicate that BAL may be useful against dialkyl but not trialkyl organotin compounds. D-penicillamine is thought to be inactive. GOSSELIN, SMITH HODGE: Clinical Toxicology of Commercial Products,5th Ed Dimercaprol is suggested to be an effective antidote for dialkyltin poisoning and has been reported toprevent the accumulation of alpha-keto acids produced by dialkyltin compounds. It does not however appear toprotect rats from the general toxic effects of triethyltin compounds. This may be due to the fact thatdialkyltin compounds, at least up to dihexyl derivatives, react readily with sulfhydryl groups andtrialkyltin compounds do not. Surgical decompression was considered to be the only treatment that offered anybenefit in human cases of cerebral edema caused by trialkyl compounds. Tin and Organotin Compounds: APreliminary Review. ENVIRONMENTAL HEALTH CRITERIA: World Health Organization Geneva 1980.Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of lung edemaoften do not manifest until a few hours have passed and they are aggravated by physical effort. Rest andmedical observation is therefore essential. Immediate administration of an appropriate spray, by a doctor ora person authorized by him/her should be considered. (ICSC24419/24421.

Section 5 - FIRE FIGHTING MEASURES

Vapour Pressure (mmHg): Not AvailableUpper Explosive Limit (%): Not AvailableSpecific Gravity (water=1): 1.1Lower Explosive Limit (%): Not Available

EXTINGUISHING MEDIA• Foam.• Dry chemical powder.• BCF (where regulations permit).• Carbon dioxide.• Water spray or fog - Large fires only.

FIRE FIGHTING• Alert Emergency Responders and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Use fire fighting procedures suitable for surrounding area.• DO NOT approach containers suspected to be hot.• Cool fire exposed containers with water spray from a protected location.• If safe to do so, remove containers from path of fire.• Equipment should be thoroughly decontaminated after use.When any large container (including road and rail tankers) is involved in a fire,consider evacuation by2625 feet in all directions.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS• Combustible.• Slight fire hazard when exposed to heat or flame.• Heating may cause expansion or decomposition leading to violent rupture of containers.• On combustion, may emit toxic fumes of carbon monoxide (CO).• May emit acrid smoke.• Mists containing combustible materials may be explosive.May emit corrosive fumes.

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Page 6 of 17Section 5 - FIRE FIGHTING MEASURES

FIRE INCOMPATIBILITY■ Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorineetc. as ignition may result.

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapors and contact with skin and eyes.• Control personal contact by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.• Wipe up.• Place in a suitable labeled container for waste disposal.

MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Emergency Responders and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Consider evacuation.• Stop leak if safe to do so.• Contain spill with sand, earth or vermiculite.• Collect recoverable product into labeled containers for recycling.• Neutralize/decontaminate residue.• Collect solid residues and seal in labeled drums for disposal.• Wash area and prevent runoff into drains.• After clean up operations, decontaminate and launder all protective clothing and equipment before storing

and re-using.• If contamination of drains or waterways occurs, advise emergency services.

PROTECTIVE ACTIONS FOR SPILL

From IERG (Canada/Australia)Isolation Distance 25 metersDownwind Protection Distance 250 meters

FOOTNOTES1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone

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Page 7 of 17Section 6 - ACCIDENTAL RELEASE MEASURES

assumes that random changes in wind direction confines the vapor plume to an area within 30 degrees on eitherside of the predominant wind direction, resulting in a crosswind protective action distance equal to thedownwind protective action distance.2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spilland working away from the site in the downwind direction. Within the protective action zone a level of vaporconcentration may exist resulting in nearly all unprotected persons becoming incapacitated and unable to takeprotective action and/or incurring serious or irreversible health effects.3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a highprobability of localized wind reversal may expose nearly all persons without appropriate protection to life-threatening concentrations of the material.4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican orbox with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from asmall cylinder are also considered "small spills".LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as acargo tank, portable tank or a "one-tonne" compressed gas cylinder.5 Guide 154 is taken from the US DOT emergency response guide book.6 IERG information is derived from CANUTEC - Transport Canada.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.• Avoid smoking, naked lights or ignition sources.• Avoid contact with incompatible materials.• When handling, DO NOT eat, drink or smoke.• Keep containers securely sealed when not in use.• Avoid physical damage to containers.• Always wash hands with soap and water after handling.• Work clothes should be laundered separately.• Launder contaminated clothing before re-use.• Use good occupational work practice.• Observe manufacturer's storing and handling recommendations.• Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.

RECOMMENDED STORAGE METHODS• Lined metal can, Lined metal pail/drum• Plastic pail• Polyliner drum• Packing as recommended by manufacturer.• Check all containers are clearly labeled and free from leaks.For low viscosity materials• Drums and jerricans must be of the non-removable head type.• Where a can is to be used as an inner package, the can must have a screwed enclosure.For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids (between 15 C deg. and 40 deg C.):• Removable head packaging;• Cans with friction closures and

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Page 8 of 17Section 7 - HANDLING AND STORAGE

• low pressure tubes and cartridges may be used.- Where combination packages are used, and the inner packages are of glass, porcelain or stoneware, there must be sufficient inert cushioning material in contact with inner and outer packages unless the outer packaging is a close fitting molded plastic box and the substances are not incompatible with the plastic.

STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.• Protect containers against physical damage and check regularly for leaks.• Observe manufacturer's storing and handling recommendations.DO NOT store near acids, or oxidizing agents.

_____________________________________________________

SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS

X X + X X +_____________________________________________________+: May be stored togetherO: May be stored together with specific preventionsX: Must not be stored together

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSSource Material TWA TWA STEL STEL Peak Peak TWA Notes

ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC__________ __________ ______ ______ ______ ______ ______ ______ ______ ______US ACGIH bis(2- 0.05 0.15 TLV® Basis: URT,Threshold Limit dimethylaminoeth eye, & skin irrValues (TLV) yl)ether (bis(2-

Dimethylaminoethyl)ether(DMAEE))

US ACGIH dibutyltin 0.1 0.2 TLV® Basis: EyeThreshold Limit dilaurate (Tin , & URT irr;Values (TLV) as Sn Organic headache;

compounds) nausea; CNS &immune eff

EMERGENCY EXPOSURE LIMITSMaterial Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)dibutyltin dilaurate|22577 25

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Page 9 of 17Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

MATERIAL DATADIBUTYLTIN DILAURATE:POLYSOFT BINDER - PART B:

Exposure limits with "skin" notation indicate that vapor and liquid may be absorbed through intact skin.Absorption by skin may readily exceed vapor inhalation exposure. Symptoms for skin absorption are the same asfor inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may alsoinvalidate the exposure standard.The no/lowest-observed-adverse-effect levels (NOAELs or LOAELs) ininhalation studies involving tri-n-butyltin chloride and bromide are 0.3-0.4 ppm (2-4 mg/m3) based on changesin the lungs, heart, liver, kidneys, nervous system and reproductive system in rodents. Oral administrationof organotin compounds has induced toxicity in a number of differing organ systems, organs and lungs. TheLOAEL for triethyltin bromide was 0.4 mg triethyltin/kg/day as 5 ppm in drinking water. The LOAELs for themost critical organ sites in rats (i.e. the cellular immune response and CNS effects) are 0.15 and 0.23mg/tin/kg body weight/day. Experience with ingested tri- and diethyltins in the treatment of staphylococcalinfections, osteomyelitis, anthrax and acne suggests that humans react in a manner similar to rodents, butthat the human is more sensitive to absorbed organic tin. The recommended TLV-TWA is thought to minimize thepotential for adverse effects on immune function and the central nervous system. A STEL is also recommendedto minimize acute symptoms such as eye and respiratory tract irritation, headaches and/or nausea. Based on anexposure to 0.1 mg/m3, a 70-kg worker breathing 10 m3 of air/8hr workday and assuming complete retention ofthe inhaled dose, would receive a daily exposure of 14.3 ug tin/kg body weight of an organotin compound. Askin notation was recommended based on animal data and the potential danger of enhanced absorption due todamaged skin present in many exposed workers.

BIS(2-DIMETHYLAMINOETHYL)ETHER:DIBUTYLTIN DILAURATE:

Exposure limits with "skin" notation indicate that vapor and liquid may be absorbed through intact skin.Absorption by skin may readily exceed vapor inhalation exposure. Symptoms for skin absorption are the same asfor inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may alsoinvalidate the exposure standard.

POLYOL BLEND:Not available

PERSONAL PROTECTION

EYE• Chemical goggles.• Full face shield.• Contact lenses pose a special hazard; soft contact lenses may absorb irritants and all lenses concentrate

them.

HANDS/FEET■ Elbow length PVC gloves.NOTE: The material may produce skin sensitization in predisposed individuals. Care must be taken, whenremoving gloves and other protective equipment, to avoid all possible skin contact.

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Page 10 of 17Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

OTHER• Overalls.• PVC Apron.• PVC protective suit may be required if exposure severe.• Eyewash unit.• Ensure there is ready access to a safety shower.

RESPIRATOR•Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or nationalequivalent)

The local concentration of material, quantity and conditions of use determine the type of personal protectiveequipment required.Use appropriate NIOSH-certified respirator based on informed professionaljudgement. In conditions where no reasonable estimate of exposure can bemade, assume the exposure is in a concentration IDLH and use NIOSH-certifiedfull face pressure demand SCBA with a minimum service life of 30 minutes, ora combination full facepiece pressure demand SAR with auxiliary self-containedair supply. Respirators provided only for escape from IDLH atmospheres shall beNIOSH-certified for escape from the atmosphere in which they will be used.

ENGINEERING CONTROLS■ Local exhaust ventilation usually required. If risk of overexposure exists, wear an approved respirator.Correct fit is essential to obtain adequate protection an approved self contained breathing apparatus (SCBA)may be required in some situations. Provide adequate ventilation in warehouse or closed storage area.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL PROPERTIESLiquid.Corrosive.Alkaline.

State Liquid Molecular Weight Not AvailableMelting Range (°F) Not Available Viscosity Not AvailableBoiling Range (°F) Not Available Solubility in water (g/L) Not AvailableFlash Point (°F) Not Available pH (1% solution) Not AvailableDecomposition Temp (°F) Not Available pH (as supplied) Not AvailableAutoignition Temp (°F) Not Available Vapour Pressure (mmHg) Not AvailableUpper Explosive Limit (%) Not Available Specific Gravity (water=1) 1.1Lower Explosive Limit (%) Not Available Relative Vapor Density Not Available

(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not Available

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Page 11 of 17Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCEYellow Colour

Section 10 - CHEMICAL STABILITY

CONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY■ Avoid reaction with oxidizing agents.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION


TOXICITY AND IRRITATION

BIS(2-DIMETHYLAMINOETHYL)ETHER:POLYSOFT BINDER - PART B:■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'sedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of thedelayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions. The significance of the contact allergen is not simply determined by its sensitization potential:the distribution of the substance and the opportunities for contact with it are equally important. A weaklysensitizing substance which is widely distributed can be a more important allergen than one with strongersensitizing potential with which few individuals come into contact. From a clinical point of view, substancesare noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.

POLYSOFT BINDER - PART B:~OTHER

POLYOL BLEND:■ None assigned. Refer to individual constituents.

BIS(2-DIMETHYLAMINOETHYL)ETHER:TOXICITY IRRITATIONOral (rat) LD50: 609 mg/kg * Skin (rabbit): Corrosive *Oral (rat) LD50: 1070 mg/kg Skin (rabbit): 5 mg/24h - SEVEREInhalation (rat) LC50: 4 mg/l/4h Skin (rabbit): 100 mg/24h- SEVEREInhalation (rat) LC50: 117 ppm/6h Eye (rabbit): 0.25 mg - SEVEREDermal (rabbit) LD50: 280 ul/kg Eye (rabbit): 1 mg - SEVEREOral (Rat) LD50: 571 mg/kgDermal (rabbit) LD50: 238 mg/kg (calc)Dermal (Rabbit) LD50: <2000 mg/kg **

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Page 12 of 17Section 11 - TOXICOLOGICAL INFORMATION

Dermal (Rabbit) LD50: >4000 mg/kg **■ The material may produce severe irritation to the eye causing pronounced inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contactskin redness, swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposuresmay produce severe ulceration.

(aerosol)*** BASF CanadaCorneal damage, respiratory tract changes, gastrointestinal tract changes, changes in bladder weight, ptosis,changes in kidney tubules, dermatitis after systemic exposure, foetotoxicity, specific developmentalabnormalities (musculoskeletal system) recorded.

DIBUTYLTIN DILAURATE:TOXICITY IRRITATIONOral (rat) LD50: 175 mg/kg Skin (rabbit): 500 mg/24h - Mild

Eye (rabbit): 100 mg/24h - Moderate

CARCINOGENTin , as Sn Organic US ACGIH Threshold Carcinogen Category A4compounds Limit Values (TLV) -

Carcinogensdibutyltin dilaurate US - Rhode Island IARC

Hazardous SubstanceList

dibutyltin dilaurate Canada - Prince Edward NotesIsland OccupationalExposure Limits -Carcinogens

SKINbis(2- US ACGIH Threshold Limit Values (TLV) - Skin Designation Yesdimethylaminoethyl)et Skinherbis(2- Canada - British Columbia Occupational Notation Skindimethylaminoethyl)et Exposure Limits - Skinherbis(2- US - California Permissible Exposure Limits Skin Sdimethylaminoethyl)et for Chemical Contaminants - Skinherbis(2- Canada - Alberta Occupational Exposure Substance Interaction 1dimethylaminoethyl)et Limits - Skinherdibutyltin dilaurate US - Washington Permissible exposure limits Skin X

of air contaminants - Skindibutyltin dilaurate US - Tennessee Occupational Exposure Limits Skin Designation X

- Limits For Air Contaminants - Skindibutyltin dilaurate Canada - British Columbia Occupational Notation Skin

Exposure Limits - Skindibutyltin dilaurate US - Minnesota Permissible Exposure Limits Skin Designation X

(PELs) - Skindibutyltin dilaurate US - Hawaii Air Contaminant Limits - Skin Skin Designation X

Designation

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Page 13 of 17Section 11 - TOXICOLOGICAL INFORMATION

dibutyltin dilaurate US - California Permissible Exposure Limits Skin Sfor Chemical Contaminants - Skin

dibutyltin dilaurate Canada - Alberta Occupational Exposure Substance Interaction 1Limits - Skin

Section 12 - ECOLOGICAL INFORMATION

DIBUTYLTIN DILAURATE:BIS(2-DIMETHYLAMINOETHYL)ETHER:DO NOT discharge into sewer or waterways.

BIS(2-DIMETHYLAMINOETHYL)ETHER:Marine Pollutant YesMay cause long-term adverse effects in the aquatic environment.May cause long-term adverse effects in the aquatic environment.Prevent, by any means available, spillage from entering drains or watercourses.For bis(2-dimethylaminoethyl)etherEcotoxicity:Fish LC50 (96 h): zebra fish 124 mg/lGreen algae EC50 (72 h): 23 mg/lActivated sludge EC50 (30 m): > 72 mg/lBiodegradability:COD: 670 mg/lBOD5: 2 mg/l<20% DOC Reduction OECD 302BEcotoxicology:Fish LC50 (96 h): Brachydanio rerio 100-215 mg/lNo inhibition of bacteria in effluent if properly introduced into acclimated biological treatment facility;toxic limit concentration: 1440 mg/l

DIBUTYLTIN DILAURATE:Marine Pollutant YesVery toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Fish: LC50 (48 h): 58 mg/LBioaccumulation: not sig

EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/SoilPolyol Blend No Data No Data

Available Availablebis(2- dimethylaminoethyl)ether HIGH No Data LOW HIGH

Availabledibutyltin dilaurate HIGH No Data LOW LOW

Available

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Section 13 - DISPOSAL CONSIDERATIONS

US EPA Waste Number & DescriptionsA. General Product Information

Corrosivity characteristic: use EPA hazardous waste number D002 (waste code C)

Disposal InstructionsAll waste must be handled in accordance with local, state and federal regulations.¦ Puncture containers to prevent re-use and bury at an authorized landfill.• Recycle wherever possible.• Consult manufacturer for recycling options or consult Waste Management Authority for disposal if no suitable treatment or disposal facility can be identified.• Treat and neutralize at an approved treatment plant.• Treatment should involve: Neutralization with suitable dilute acid followed by: Burial in a licensed landfill or Incineration in a licensed apparatus (after admixture with suitable combustible material).• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

DOT:Symbols: None Hazard class or Division: 8Identification Numbers: UN2922 PG: IILabel Codes: 8, 6.1 Special provisions: B3, IB2,

T7, TP2Packaging: Exceptions: 154 Packaging: Non- bulk: 202Packaging: Exceptions: 154 Quantity limitations: 1 L

Passenger aircraft/rail:Quantity Limitations: Cargo 30 L Vessel stowage: Location: Baircraft only:Vessel stowage: Other: 40Hazardous materials descriptions and proper shipping names:Corrosive liquids, toxic, n.o.s.

Air Transport IATA:ICAO/IATA Class: 8 ICAO/IATA Subrisk: 6.1UN/ID Number: 2922 Packing Group: IISpecial provisions: A3A803Cargo OnlyPacking Instructions: 855 Maximum Qty/Pack: 30 LPassenger and Cargo Passenger and CargoPacking Instructions: 851 Maximum Qty/Pack: 1 LPassenger and Cargo Limited Quantity Passenger and Cargo Limited Quantity

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Page 15 of 17Section 14 - TRANSPORTATION INFORMATION

Packing Instructions: Y840 Maximum Qty/Pack: 0.5 L

Shipping name:CORROSIVE LIQUID, TOXIC, N.O.S.(contains bis(2-dimethylaminoethyl)ether and dibutyltindilaurate )

Maritime Transport IMDG:IMDG Class: 8 IMDG Subrisk: 6.1UN Number: 2922 Packing Group: IIEMS Number: F-A,S-B Special provisions: 274Limited Quantities: 1 L Marine Pollutant: YesShipping name:CORROSIVE LIQUID, TOXIC, N.O.S.(contains bis(2-dimethylaminoethyl)ether and dibutyltindilaurate )

Section 15 - REGULATORY INFORMATION

REGULATIONS

Regulations for ingredients

bis(2-dimethylaminoethyl)ether (CAS: 3033-62-3, 59948-21-9, 112326-78-0, 357920-72-0) is found on the following regulatory lists;"Canada - Alberta Occupational Exposure Limits", "Canada - British Columbia Occupational Exposure Limits", "Canada - Nova Scotia Occupational Exposure Limits", "Canada - Prince Edward Island Occupational Exposure Limits", "Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination Limits", "Canada Controlled Drugs and Substances Act Schedule VI", "Canada Domestic Substances List (DSL)", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals", "United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II", "United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control (Red List) - Table II", "US - California Permissible Exposure Limits for Chemical Contaminants", "US - New Jersey Right to Know Hazardous Substances (English)", "US - North Dakota Air Pollutants - Guideline Concentrations", "US - Wisconsin Control of Hazardous Pollutants - Emission Thresholds, Standards and Control Requirements (Hazardous Air Contaminants)", "US ACGIH Threshold Limit Values (TLV)", "US EPA High Production Volume Program Chemical List", "US NIOSH Recommended Exposure Limits (RELs)", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

dibutyltin dilaurate (CAS: 77-58-7) is found on the following regulatory lists;"Canada - Alberta Occupational Exposure Limits", "Canada - British Columbia Occupational Exposure Limits", "Canada - Northwest Territories Occupational Exposure Limits (English)", "Canada - Nova Scotia Occupational Exposure Limits", "Canada - Ontario Occupational Exposure Limits", "Canada - Prince Edward Island Occupational Exposure Limits", "Canada - Prince Edward Island Occupational Exposure Limits - Carcinogens", "Canada - Quebec Permissible Exposure Values for Airborne Contaminants (English)", "Canada - Saskatchewan

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Page 16 of 17Section 15 - REGULATORY INFORMATION

Occupational Health and Safety Regulations - Contamination Limits", "Canada - Yukon Permissible Concentrations for Airborne Contaminant Substances", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that are Inherently Toxic to the Environment (English)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that are Inherently Toxic to the Environment (French)", "Canada Domestic Substances List (DSL)", "Canada Ingredient Disclosure List (SOR/88-64)", "Canada Toxicological Index Service - Workplace Hazardous Materials Information System - WHMIS (English)", "International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR List of Chemicals for Priority Action", "US - Alaska Limits for Air Contaminants", "US - California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous Substances List", "US - California Permissible Exposure Limits for Chemical Contaminants", "US - Connecticut Hazardous Air Pollutants", "US - Hawaii Air Contaminant Limits", "US - Idaho - Limits for Air Contaminants", "US - Minnesota Hazardous Substance List", "US - Minnesota Permissible Exposure Limits (PELs)", "US - North Dakota Air Pollutants - Guideline Concentrations", "US - Oregon Permissible Exposure Limits (Z-1)", "US - Rhode Island Hazardous Substance List", "US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants","US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air Contaminants", "US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air Contaminants", "US - Washington Permissible exposure limits of air contaminants", "US - Wisconsin Control of Hazardous Pollutants - Emission Thresholds, Standards and Control Requirements (Hazardous Air Contaminants)", "US - Wisconsin Control of Hazardous Pollutants - Substances of Concern for Sources of Incidental Emissions of Hazardous Air Contaminants", "US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants", "US ACGIH Threshold Limit Values (TLV)", "US ACGIH Threshold Limit Values (TLV) - Carcinogens", "US American Apparel & Footwear Association (AAFA) Restricted Substance List (RSL)", "US Department of Transportation (DOT) Marine Pollutants - Appendix B", "US EPA High Production Volume Chemicals Additional List", "US FDA Indirect Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives - Adhesives", "US FDA List of ""Indirect"" Additives Used in Food Contact Substances", "US OSHA Permissible Exposure Levels (PELs) - Table Z1", "US RCRA (Resource Conservation & Recovery Act) - Appendix IX to Part 264 Ground-Water Monitoring List 1", "US RCRA (Resource Conservation & Recovery Act) - List of Hazardous Inorganic and Organic Constituents 1", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory", "US TSCA Section 8 (d) - Health and Safety Data Reporting"

Section 16 - OTHER INFORMATION

Denmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesbis(2- dimethylaminoethyl)ether 3033- 62- 3 Xn; R22 R43 Xi;

R38 R52/53

INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient Name CASbis(2-dimethylaminoethyl)ether 3033-62-3, 59948-21-9, 112326-78-0, 357920-72-0

■ Classification of the preparation and its individual components has drawn on official and authoritative sources using available literature references.

■ For detailed advice on Personal Protective Equipment, refer to the following U.S. Regulations and Standards:OSHA Standards - 29 CFR:

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No data for POLYSOFT BINDER - PART B (CW: 9-36874)No data for Polyol Blend (CAS: , )



Page 17 of 17Section 16 - OTHER INFORMATION

1910.132 - Personal Protective Equipment - General requirements1910.133 - Eye and face protection1910.134 - Respiratory Protection1910.136 - Occupational foot protection1910.138 - Hand ProtectionEye and face protection - ANSI Z87.1Foot protection - ANSI Z41Respirators must be NIOSH approved.

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Issue Date: Jun-29-2012Print Date: Jun-29-2012


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POLYSOFT BINDER - PART B - aquasealllc.com · Inhalation of vapors or aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful. The