polymer

S E C T I O N I I I

P H Y S I C A L P R O P E R T I E S O F

M O N O M E R S A N D S O L V E N T S

P h y s i c a l P r o p e r t i e s o f M o n o m e r s

D a n i e l R. BlochLakeshore Research, 5536 W. Branch Trail, Racine, Wl 53402, USA

A. IntroductionB. Tables of Physical Properties

Table 1. AcetylenesTable 2. Acid DichloridesTable 3. AcroleinsTable 4. Acrylamides/Methacrylamides

4.1. Acrylamides4.2. Methacrylamide

Table 5. Acrylates/Methacrylates5.1. Acrylate, Acids/Esters5.2. Methacrylate, Acids/Esters

Table 6. Alcohols6.1. Alkanediols6.2. Ether Diols

Table 7. AIIyI FunctionalTable 8. Amines, DifunctionalTable 9. Anhydrides

9.1. Monoanhydrides9.2. Dianhydrides

Table 10. Butadienes10.1. 1,2-Butadienes10.2. 1,3-Butadienes

Table 11. Butenes11.1. 1-Butenes11.2. 2-Butenes

Table 12. Epoxides12.1. Monoepoxides12.2. Diepoxides

Table 13. Ethylene HalidesTable 14. Fumaric, Acids/EstersTable 15. lsocyanatesTable 16. LactamsTable 17. LactonesTable 18. Maleic, Acids/EstersTable 19. PropenesTable 20. StyrenesTable 21. Vinyl Functional

21.1. Aryl21.2. Esters21.3. Ethers

111-1ill-4III-4III-4III-4III-4III-4III-6III-8III-8

111-12111-16111-16111-18111-18III-20III-20III-20III-24III-24III-24III-24III-26III-26III-26III-26III-26III-28III-28III-30III-30III-32IM-32III-32III-32III-34III-36III-36III-36III-38

21.4. /V-substituted III-3821.5. Sulfonates III-40

A. INTRODUCTION

This chapter contains some of the principal properties of themore common monomers. The monomers are arrangedalphabetically, in groups, with derivatives listed alphabeti-cally within the groups. Compounds are listed under theirmost commonly used names in polymer chemistry. There-fore, some names are not in agreement with the nomencla-ture rules of the International Union of Pure and AppliedChemistry.

Data are taken from a variety of published literature,including the 3rd edition of the "Polymer Handbook","The Brandon Worldwide Monomer Reference Guide andSourcebook", the "Aldrich Catalog Handbook of FineChemicals", and "Polysciences Monomers/Polymers,Scientific Polymer Products", "TCI America", "Lancasterand Janssen Chemica" catalogs. Where a range is reportedin the literature, the average value is used here for meltingpoints and boiling points. No attempt was made to verifythe reported values experimentally.

Linear structures are given for most monomers. Mole-cular formulas are provided when linear structures cannotbe unambiguously drawn.

Molecular weight is calculated based on the InternationalAtomic Weight values.Boiling point is given in degrees Celsius (0C), at760mmHg, unless indicated otherwise by the value inmmHg following a slash (/).Melting point is given in degrees Celsius (0C), at760 mmHg, unless indicated otherwise by the value inmmHg following a slash (/).Refractive index is given at 200C, unless indicatedotherwise by the temperature in Celsius following a slash(/).Density is relative to water at 4°C and measured at 200C,unless otherwise indicated by the value following a slash(/).Flash point was determined by the closed-cup method,using a Setaflash apparatus.

RTECS# is the reference to the Registry of Toxic Effectsof Chemical Substances.

R&S is the reference found in the "Sigma-AldrichLibrary of Regulatory & Safety Data", available fromAldrich Chemical Company.

FT-NMR is the reference to spectra in the "AldrichLibrary of 13C and 1H FT-NMR Spectra", available fromthe Aldrich Chemical Company.

FT-IR is the reference to spectra in the "Aldrich Libraryof FT-IR Spectra", available from the Aldrich ChemicalCompany.

Merck Index is the reference to "The Merck Index",Merck & Co., Inc., Whitehouse Station, NJ.

Beilstein is the reference to "Beilsteins Handbuchder Organischen Chemie", Springer-Verlag, New York,NY.

Fieser is the reference to L. F. Fieser and M. Fieser,"Reagents for Organic Synthesis", John Wiley, New York,NY.

Abbreviations: (d) decomposes; (s) sublimes; (aq)aqueous.

B. TABLES OF PHYSICAL PROPERTIESTABLE 1. ACETYLENES

Formula RC = CR' CASRegistry Boiling Melting

Name R R' Number MoL wt. point (0C) point (0C)

Acetylene -H -H 74-86-2 26.04 - 8 2 - 84(s)- , Chloro -Cl -H 60.48 - 3 2 -126- , Dichloro- -Cl -Cl 94.93 - 6 6- , Diphenyl- -C6H5 -C6H5 501-65-5 178.23 60 170/19- , Phenyl- -C6H5 -H 102.14 143

TABLE 2. ACID DICHLORIDES

Formula ClC(O)RC(O)Cl CASRegistry Boiling Melting

Name R Number MoI. wt. point (0C) point (0C)

Adipoyl -(CH2)4- 111-50-2 183.03 106/2Azelaoyl -(CH2)7- 123-98-8 255.12 166/18Diethylmanoyl -C(CH2CH3)2- 54505-72-5 197.06 198Dodecanedioyl -(CH2) 1 0- 4834-98-4 267.20 140/0.5Glutaryl -(CH2)3- 2873-74-7 169.01 217Isophthaloyl -C 6 H 4 - 99-63-8 203.02 276 43Malonyl -CH 2 - 1663-67-8 140.95 54/19Methylpimeloyl -(CH2)2CH(CH3)(CH2)2- 44987-62-4 197.06 118/10Oxalyl -CO-CO- 79-37-8 126.93 61 - 8Phthaloyl -C 6 H 4 - 88-95-9 203.02 270 12Pimeloyl -(CH2)5- 142-79-0 197.06 113/5Sebacoyl -(CH2)8- 111-19-3 239.14 168/12 -2.5Suberoyl -(CH2)6- 10027-07-3 211.09 162/15Succinyl -(CH2)2- 543-20-4 154.98 190 16Terephthaloyl -C 6 H 4 - 100-20-9 203.02 266 80Thionyl ClC(S)Cl 7719-09-7 118.97 79 -105

TABLE 3. ACROLEINS

Formula HC(O)CR = CHR' CASRegistry Boiling Melting

Name R R' Number MoI. wt. point (0C) point (0C)

Acrolein -H -H 107-02-8 56.06 53 - 8 7- , 2-Chloro- -Cl -H 90.51 40/30- , 2-Methyl- -CH3 -H 78-85-3 70.09 68 - 8 1- , 3-Methyl-,

fra/w-(Crotonaldehyde) -H -CH3 123-73-9 70.09 104- , 2-Chloro-3-methyl- -Cl -CH3 104.54 148

TABLE 4. ACRYLAMIDES/METHACRYLAMIDES

CAS Registry Boiling MeltingName R R' Number MoI. wt. point (C) point (0C)

4.1. ACRYLAMIDES H2C=CHC(O)NRR'Acrylamide -H -H 79-06-1 71.08 125/25- , Acetyl-, N- -C(O)CH3 -H 1432-45-7 113.12 129- , Adamantyl-, N- -Ci0H5 -H 19026-83-6 205.30 155-,AlIyI-, N- -CH2CH=CH2 -H 2555-13-7 111.14 120/19- , Benzyl-, N- -CH2C6H5 -H 13304-62-6 161.20 70- , Butoxymethyl-, N- -CH2O(CH2)3CH3 -H 1852-16-0 157.21 125/0.3 - 9- , terf-Butyl-, N- -C(CH3)3 -H 107-58-4 127.19 128- , Cyclohexyl-, N- -C6Hn -H 3066-72-6 153.23 113- , Cystamine-bis-, NJf'- -CH2CH2SSCH2CH2- -H 60984-57-8 260.38 123- , Diacetone-, N- -C(CH3)2CH2C(O)CH3 -H 2873-97-4 169.23 93/0.1 55- , Diallyl-, N,N- -CH2CH=CH2 -CH2CH=CH2 3085-68-5 151.21 108/3- , Di-n-butyl-, N9N- -(CH2)3CH3 -(CH2)3CH3 2274-13-7 183.29 97/1

Density Refractive Flash RTECS(at 200C) index (at 200C) point (°C) Number R and S FT-NMR FT-IR Merck Beilstein Fieser

1.000 AO9600000 1,11

0.990 1(2),2711I 1(3), 533A 1(2),946B 11,9428 5,656 1,3350.929 1.548

Density Refractive Flash RTECS(at 200C) index (at 200C) point (0C) Number R and S FT-NMR FT-IR Merck Beilstein Fieser

1.259 1.4700 >110 1(1), 867J 1(1),741A 2,6531.143 1.4680 >110 1(1),869C 2,7091.145 1.4590 74 1(1),867G 1(1),1211B l(l),740B 2,6871.069 1.4680 >110 1(1),869E 1(1)1212C 2(4),21271.324 1.4720 107 1(1),867I 1(1),1212A l(l),740D 2,634

180 NT2625000 1(2),1981H 1(2),352A 9,8341.449 1.4650 47 1(1),867F 1(1),1211A l(l),740A 2(1),252 12,2911.217 1.4720 >110 1(1),867K 1(1),1212B 1(1),741B1.455 1.4290 None KI2950000 1(1),867D 1(1),739C 11,6867 2,542 17,2411.409 1.5684 >110 1(2),1981G 1(2),351D 11,7439 9,805 14,2631.205 1.4690 >110 1(1),869A 1(1),741C 2,6711.121 1.4680 >110 1(1),869D 1(1),742B 2,7191.172 1.4680 >110 1(1),869B 1(1),741D 2,6941.407 1.4680 77 WN4900000 1(1),867H 1(1),1211C l(l),740C 11,8844 2,613

180 WZ1797000 1(2),1981I 1(2),352B 9,8441.631 1.5190 None XM515OOOO 1(2),3197F 1(2),1227B 11,9278 13,297


0.839 1.4025 - 1 9 AS105000 1(1),515A 1(1),733B l(l),470D 11,122 1,725 10,21.199 1.4630.847 1.4160 - 1 6 OZ2625000 1(1),515B 1(1),733C 1(1),471A 1(3),2981

0.846 1.4365 9 GP9625000 1(1),515G 1(1),472C 11,2599 1,7281.478


1.122 AS3325000 1(1),877K 1(1),1221A 1(1),749B 11,123 2,400

0.9790 1.4620 > 110 AS3450000AS3460000 4(4),664

>110 AS3475000 1(1),887I 1(1),1236A l(l),750C 11,2943

TABLE 4. cont'd

Name

- , Diethyl-, N9N-- , 1,2-Dihydroxyethylene-

bis-,N,N'- , Diisopropyl-, N,N-- , 4,4-Dimethoxybutyl-, N-- , Dimethyl-, N9N-- , 3-(Dimethylamino)-

propyl-, N--, l,l-Dimethyl-2-

sulfoethyl-, N-(AMPS)- , Diphenylmethyl-,7V-- , Ethylenebis-,WV'-- , Ethylhexyl-,iV-

- , 2-Glycolic acid, N-- , 2-Glycolic acid

methyl ester, N-- , Hexamethylenebis-, -

N,Nf

- , tert-Hexyl-, N-- , Hydroxymethyl-,

N- (solution)- , Isobornyl-, N--, Isobutoxymethyl-, N--, Isopropyl-, N--, Isopropylidenebis-,

N9N1-

- , 3-Methoxypropyl-, N-- , Methyl-, N-- , Methylenebis-, N,Nf-- , (1-Methoxy)- , (Methoxy)-

acetoxymethyl-, N-- , Morpholinoethyl-, N-- , 1-Naphthyl-, N-- , Octadecyl-, N-- , Octamethylenebis-,

NJ*'-- , tert-Octyl-, N-- , Phthalamidomethyl-, N-- , 2,2,2-Trichloro-l-

hydroxyethyl-, N-- , Tri(hydroxymethyl)-

methyl-, N-, 1,1,3-Trimethylbutyl-, N-- , Trimethylenebis-, N,N'-- , Triphenylmethyl-, N-

R

-CH2CH3

-CH(OH)CH(OH)-

-CH(CHs)2

-(CH2)3CH(OCH3)2

-CH 3

-(CH2)3N(CH3)2

-C(CH3)2CH2SO3H

-CH(C6H5),-CH 2 CH 2 --CH2CH(CH2CH3)

(CH2)3CH3

-CH(OH)C(O)OH-CH(OH)C(O)OCH3

- (CH 2 ) 6 -

-CH2CH2C(CH3),-CH2OH

- C H)H 17-CH2OCH2CH(CH3)2

-CH(CH3),-C(CH 3 ) 2 -

-(CH2)3OCH3

-CH 3

- C H 2 -

-C(OCH3)C(O)OCH3

-CH2CH2NC4H8O-Ci 0 H 7

-(CH2) 17CH3

- (CH 2 ) 8 -

-(CH2)4C(CH3)3

-CH2NC8H4O2

-CH(OH)CCl3

-C(CH2OH)3

-C(CH3)2CH2CH(CH3)2

- ( C H 2 ) , --C(C6H5) ,

4.2. METHACRYLAMIDES H2C=C(CH3)C(O)NRR'

Methacrylamide- , Acetyl-, N-- , Acetylphenyl-, N-- , AlIyI-, N-- , 3-Aminopropyl-, N-,

hydrochloride- , Benzyl-, N--, Bis(diethylaminoethyl)-,

N9N-- , Butoxymethyl-, N-

-, ^rr-Butyl-, N-- , 2-Cyanoethyl-, N-- , 2-Cyanoethyl-, N-,

methyl-, N

- H-C(O)CH3

-C6H4C(O)CH3

-CH2CH=CH2

-(CH2)3NH2HC1

-CH2C6H5

-CH2CH2N(CH2CH3)2

-CH2O(CH2)3CH3

-C(CH3),-CH2CH2CN-CH2CH2CN

R ;

-CH2CH3

- H

-CH(CH3),- H-CH 3

- H

- H

- H- H- H

- H- H

- H

- H- H

- H- H- H- H

- H- H- H

- H

- H- H- H- H

- H- H- H

- H

- H- H- H

- H- H- H- H- H

- H-CH2CH2N-

(CH2CH3),- H

- H- H-CH3

CAS RegistryNumber

2675-94-7868-63-3

44975-46-438486-53-2

2680-03-73845-76-9

15214-89-8

10254-08-72956-58-3

91625-16-0

6737-24-277402-03-0

7150-41-6

51330-07-5924-42-5

17159-04-516669-59-32210-25-5

107374-86-71187-59-3

110-26-9

77402-03-0

5117-12-422302-62-1

1506-54-32945-02-0

4223-03-480500-94-3

13880-05-2

25269-93-64887-13-2

102548-89-0

79-39-044810-87-958813-69-7

2186-33-672607-53-5

3219-55-476392-05-7

5153-77-528384-61-4

6554-73-024854-94-2

MoI. wt.

127.19200.19

155.24187.2499.13

156.23

207.25

237.30168.20183.30

163.13173.17

224.28

155.24101.11

207.31157.21113.16182.22

143.1985.11

154.17

173.17

141.17197.24323.56252.35

183.29230.22218.47

175.18

169.27182.22313.40

85.11127.14203.24125.17178.66

175.23183.28

171.24

142.20138.17152.20

Boilingpoint (0C)

93/19

54/0.4135/0.782/21117/2

178

123/0.5

95

10890/2

99/0.3106/4

158/50

125/25

21576/1.2

90/2.2

122/0.4

105/0.3

163

113/1

Meltingpoint (0C)

156(d)

18

195(d)

140

74

135

100

135

61210

>300

73

>11013875

138

58190170

139

55112204

109138138

124

82

604646

Density(at 200C)

0.9620.949

1.074

0.970

1.122

1.10

0.96

Refractiveindex (at 200C)

1.47301.4820

1.4130

1.4610

1.5120

1.4702

1.46

1.4755

Flashpoint (0C)

71> 110

160

None

79

> 110

122

RTECSNumber

AU3230000

AI8967330

AS3600000

AS3630000AS3675000

AS3678000

AI8967330

UC6475000

R and S

1(1),885K

1(1),893I

l(l),1065K

1(1),883K

1(1),915E1(1),913D

1(1),885J

1(1),883J

1(1),913D

1(1),883M

1(1),877L

FT-NMR

1(1),1233C

1(1),1244C

1(1),1438C

1(1),1276B1(1),1272B

l(l),1230C

1(1),1272B

1(1),1231B

1(1),1221B

FT-IR Merck

1(3),784B

1(1),781A

l(l),750A

1(1),749D

1(1),749C

Beilstein

4(3),1304(4), 1268

4(3),526

2(4), 1472

4(4),517

27(4),278

2(2),399

Fieser

TABLE 4. cont'd

Name

- , Cyclohexyl-, N-- , Diallyl-, N,N-- , Dibenzyl-, N,N-- , Dibutyl-, NJf-- , 3-Di(butyl)aminopropyl-, N--, Diethyl-, NJf-- , 3-(Diethylamino)propyl-, N-- , Diisopropyl-, NJf--, 2,2-Dimethoxyethyl-, N-- , Dimethyl-, NJf-- , 2-(Dimethylamino)ethyl-, N-- , 3-(Dimethylamino)propyl-,

N-- , Dodecyl-, N-- , Ethylenebis-, NJf'-- , 2-Ethylhexyl-, N--, 2-Hydroxyethyl-, N-- , Hydroxymethyl-, N-- , 4-Hydroxyphenyl-, N-- , Isobutoxymethyl-, Af-- , Isopropyl-, N--, Methoxymethyl-, N-- , Methyl-, N-- , Methylenebis-, NJf'-- , Methyl-, N-, Phenyl-, N--, Methyl-, N-, 2,2-dimethoxy-

ethyl-, N-- , 3-(Af-morpholino)propyl-, A -- , 2-(2-Oxo-l-imidazolidinyl)-

ethyl-, N-- , Phenyl-, N-- , Phenyl-, N-, Phenylethyl-, N--, 3-(Trifluoromethyl)phenyl-,

A-- , 3-(Trimethylammonium)-

propyl-, chloride,N- (eq. solution)

R

-C6Hn-CH2CH=CH2

-CH2C6H5

-(CH2)3CH3

-(CH2)3N((CH2)3CH3)2

-CH2CH3

-(CH2)3N(CH2CH3)2

-CH(CH3)2

-CH2CH(OCH3)2

-CH3

-CH2CH2N(CH3)2

-(CH2)3N(CH3)2

-(CH2)nCH3

-CH2CH2--CH2CH(CH2CH3)(CH2)3CH3

-CH2CH2OH-CH2OH-C6H4OH-CH2OCH(CH3)2

-CH(CH3),-CH2OCH3

-CH3

-CH 2 --CH3

-CH3

-(CH2)3NC4H4O-CH2CH2C3H5N2O

-C6H5

-C6H5

-C6H4CF3

-(CH2)3N(CH3)3HC1

TABLE 5. ACRYLATES/METHACRYLATES

Name

5.1. ACRYLATE, ACIDS/ESI

AcidAllyl esterAnhydrideBenzyl ester4-Biphenylyl esterBisphenol A ethoxylate diesterBisphenol A diglycidyl

ether diester2-Bromo-3-Bromo-, cis-2-Bromo-, ethyl ester2-Bromoethyl ester2-Bromomethyl-2-Bromomethyl-, ethyl ester2-Bromomethyl-, methyl ester1,3-Butylene diester1,4-Butylene diester2-Butylene-l,4 diester

R'

-H-CH2CH=CH2

-CH2C6H5

-(CH2)3CH3

-H-CH2CH3

-H-CH(CH3)2

-H-CH3

-H-H

-H-H-H-H-H-H-H-H-H-H-H-C6H5

-CH2CH(OCH3)2

-H-H

-H-CH2CH2C6H5

-H

-H

R

PERS H2C = CHC(O)OR

-H-CH2CH=CH2

-C(O)CH=CH2

-CH2C6H5

-C6H4C6H5

(-(CH2CH2OC6H4)2C(CH3)2

(-CH2CH(OH)CH2OC6H4)2C(CH3)2

H2C=CBrC(O)OHBrCH=CHC(O)OHH2C=CBrC(O)OCH2CH3

-CH2CH2BrH2C=C(CH2Br)C(O)OHH2C=C(CH2Br)C(O)OCH2CH3

H2C=C(CH2Br)C(O)OCH3

-CH2CH2CH(CH3)--(CH2)4--CH2CH=CHCH2-

CAS RegistryNumber

2918-67-413169-99-857625-30-622240-86-476392-03-55441-99-6

51745-62-195984-11-56976-91-6

13081-44-25205-93-6

1191-39-56117-25-5

5238-56-2923-02-4

19243-95-94548-27-0

13749-61-63644-12-03887-02-32359-15-12918-73-2

95984-81-9

55937-58-13089-19-8

1611-83-276392-02-4

783-05-1

51410-72-1

CAS RegistryNumber

79-10-7999-55-3

2051-76-52495-35-4

13026-23-864401-02-14687-94-9

10443-65-91609-92-34519-46-44823-47-6

72707-66-517435-72-24224-69-5

19485-03-11070-70-8

MoL wt.

167.25197.32265.36197.32253.41141.21197.30169.27173.21113.16156.34170.26

253.43196.25197.32129.16115.13177.20171.24127.19129.1699.13

182.22238.31187.24

212.30197.24

161.20266.37229.20

220.74

MoL wt.

72.06112.13126.11162.19226.27424484.55

150.97150.96164.99179.03164.99193.05179.02198.22198.22127.16

Boilingpoint (0C)

50/1.1

81/0.8125/0.1382/7

134/10

66/1087/1.8

134/2

145/0.08

110/0.3147/1.2

ca. 100127/5

112/11580.03

88/3.5

88/272/2

150/0.08100

Boilingpoint (0C)

139123

97/35110/8

72/7852/5

86/2036/1.373/0.183/0.3

60/23

Meltingpoint (°C)

102

41

4727

170

- 3 7154

90

16450

846395

-22.5

Meltingpoint (0C)

13

224

6363

70

Density(at 200C)

0.940

1.100

0.97

0.97

1.110

1.053

Density(at 200C)

1.0510.880

1.0573

1.1461.180

1.4774

1.3881.4891.0301.0510.9344


1.4731

1.46001.47441.4790

1.5002

1.4300

1.46

1.47071.4740

1.4560

1.427

Refractiveindex (at 20°C)

1.42021.43201.44871.5143

1.54501.5570

1.4770

1.4781.4901.45001.45601.4422

Flashpoint (0C)

140

>110

107

>110

Flashpoint (0C)

548

101

> 110> 110

7893

>110

RTECSNumber

UC6380000

SI1225000

RTECSNumber

AS4375000

AS4900000AS5250000UD3130000

R and S

R and S

1(1),547A

1(1),563H1(1),563I

1(1),563K

1(1),745J

FT-NMR

FT-NMR

1(1),776A

l(l),806C

l(l),1031C

FT-IR

FT-IR

1(1),498B

1(1),516C

1(3),696D

Merck

Merck

11,1242,400

Beilstein

4(3),276

Beilstein

2,397

2,4022(4), 1486

2(4), 170

Fieser

Fieser

TABLE 5. cont'd

Name

2-(2-Butoxyethoxy)ethyl ester2-Butoxyethyl esterw-Butyl esters-Butyl esterf-Butyl ester2-Chloro-2-Chloro-, butyl ester2-Chloro-, ethyl ester2-Chloro-, methyl ester3-Chloro-, cis-3-Chloro-, trans-2-Chloroethyl esterCinnamyl esterCrotyl ester2-Cyano-, butyl ester2-Cyano-, ethyl ester2-Cyano, isobutyl ester2-Cyanoethyl esterCyclohexyl esterCyclopentyl esterrc-Decyl ester2,3-Dibromopropyl ester2,3-Dichloropropyl esterDicyclopentenyl esterDicyclopentenyloxyethyl ester2-(Diethylamino)ethyl ester3-(Diethylamino)propyl esterDi(ethylene glycol) diesterDihydrodicyclopentadienyl estei2,3-Dihydroxypropyl ester2-(Dimethylamino) ethyl ester3-(Dimethylamino) neopentyl -

ester3-(Dimethylamino) propyl esterDipentaerythritol pentaesterDi(propylene glycol) diesterDi(trimethylolpropane) tetraesteDodecyl ester1H,1H,1 lH-Eicosafluoro-

undecylester2-(2-Ethoxyethoxy)ethyl ester2-Ethoxyethyl esterEthyl esterEthylene diester2-Ethylhexyl esterFurfuryl esterGlycidyl esterGlycerol propoxylate triester1H,1H,2H,2H-Heptadecafluoro-

decyl ester1H, 1 H-Heptafluorobutyl esterHeptyl esterHexadecyl ester2,2,3,4,4,4-Hexafluorobutyl este:lH-Hexafluoroisoporpyl esterHexanediol diestern-Hexyl ester4-Hydroxybutyl ester2-Hydroxyethyl ester2-Hydroxy-3-phenoxypropyl

ester2-Hydroxypropyl esterIsobornyl esterIsobutyl ester

R

-CH2CH2OCH2CH2O(CH2)3CH3-CH2CH2O(CH2)SCH3

-(CH2)3CH3

-CH(CH3)CH2CH3

-C(CH3)3

H2C=CClC(O)OHH2C=CC1(O)O(CH2)3CH3

H2C=CClC(O)OCH2CH3

H2C=CClC(O)OCH3

ClCH=CHC(O)OHClCH=CHC(O)OH-CH2CH2Cl-CH2CH=CHC6H5

-CH2CH=CHCH3

H2C=C(CN)C(O)O(CH2)3CH3

H2C=C(CN)C(O)OCH2CH3

H2C=C(CN)C(O)OCH2CH(CH3)2

-CH2CH2CN-C6H11

-C5H9

-(CH2)9CH3

-CH2CHBrCH2Br-CH2CHCICH2Cl-C1OH13

-CH2CH2OC 10H 13

-CH2CH2N(CH2CH3)2

-(CH2)3N(CH2CH3)2

-CH2CH2OCH2CH2--C1OH15

-CH2CH(OH)CH2OH-CH2CH2N(CH3)2

CH2C(CH3)2CH2N(CH3)2

-(CH2)3N(CH3)2

(-CH2)3CCH2OCH2C(CH2OH)(CH2-)2

- C H 2 C H ( C H 3 ) O C H 2 C H ( C H 3 ) -r ((-CH2)2C(CH2CH3)CH2)2O

-(CH2)nCH3

-CH2(CF2)9CHF2

-(CH2CH2O)2CH2CH3

-CH2CH2OCH2CH3

-CH2CH3

-CH2CH2--CH2CH(CH2CH3)(CH2)3CH3

-CH2C4H3O-CH2CH(-O-)CH2

-CH(CH3)CH2OCH(CH2OCH2CH(CH3)-)2

-CH2CH2(CF2)7CF3

-CH2CF2CF2CF3

-(CH2)6CH3

-(CH2) 15CH3

r -CH2CF2CHFCF3

-CH(CF3),-(CHa)6--(CH2)5CH3

-(CH2)4OH-CH2CH2OH-CH2CH(OH)CH2OC6H5

-CH2CH(OH)CH3

-C10H18

-CH2CH(CH3)2

CAS RegistryNumber

7251-90-3141-32-2

2998-08-51663-39-4

26952-44-313401-85-9

687-46-780-63-7

1609-93-42345-61-12206-89-5

23916-33-86606-65-17085-85-01069-55-2106-71-8

3066-71-516868-13-62156-96-9

19660-16-324910-84-733791-58-165983-31-52426-54-2

4074-88-812542-30-210095-20-22439-35-2

20166-73-8

18526-07-360506-81-285136-76-194108-97-12156-97-04998-38-3

7328-17-8106-74-1140-88-5

2274-11-5103-11-7

10525-17-4106-90-1

52408-84-127905-45-9

424-64-62499-58-3

13402-02-354052-90-32160-89-6

13048-33-42499-95-82478-10-6818-61-1

16969-10-1

999-61-15888-33-5

106-63-8

MoI. wt.

232.28172.22128.17128.17128.17106.51162.62134.56120.54106.51106.51134.57188.23126.16153.18125.13153.18125.13154.21282.38212.34271.94183.04202.25248.32171.27185.27214.22204.27146.15143.19181.24

157.22524.53242.27466.53240.39586.17

188.23144.17100.12170.16184.28152.15128.13428518.10

254.11170.25296.50236.11222.09226.28156.23144.17116.11222.24

130.15208.30128.19

Boilingpoint (0C)

103/2363/2

14559/2530/25176(d)

100/4241/2052/50

64/20105/238/1092/690/581/4

103/8183

145/0.08185/50105/658/0.5

105/4100/0.5

171.2744/0.1

162119/5115/0.164/1253/1.4

167

95/0.5

120/1115/1

25065/16

9967/2217

92/16115/78

100/4

121/74356/1

170/1548/12

84295190

95/0.190/12

77/15275132

Meltingpoint (0C)

- 6 4

60

6184

- 1 7

- 1 7

<-60

-40

<-60

49

-72

-90

-45

-101

-92-15-61

Density(at 200C)

0.98210.94970.8940.81140.8850

1.14041.189

1.14041.0495

0.9861.069

1.06900.975

0.87811.78031.2603

1.0850.92500.91801.1181.08

0.9430.90

0.9281.1915

1.1010.884

1.0160.98190.9241.0900.88591.11251.0991.064

1.4180.88460.86201.3981.3301.0100.88821.0391.0111.160

1.050.9860.8896


1.43941.43231.41801.41401.4108

1.43841.4420

1.43841.5660

1.4420

1.44331.4673

1.4401.55201.4765

1.50101.4431.4411.46301.509

1.43801.439

1.4400

1.44881.47901.4450

1.43901.42821.40601.46101.43601.48001.44901.46101.3380

1.33011.43111.44701.3521.31901.45621.42801.45201.45021.5280

1.44481.47601.4140

Flashpoint (0C)

9039

17

33

99108

12429

227

9968

> 110

5875

68115

> 110> 110

1026515

10079

76

31

5910

> 11068

> 1109889

659333

RTECSNumber

UD3150000

AS5960000

AT1500000AS7350000

AS8225000

AS9450000

AS8578000

AS9800000AT0700000AT0350000AT0855000

AS9275000

AT1430000AT1450000

AT1750000

AT2100000

R and S

1(1),719E

1(1),719F

1(1),563F1(1),563G

1(1),771G

1(1),719D1(1),727M1(1),719G

1(1),745C1(1),729E

1(1),753L1(1),753J

1(1),719H

FT-NMR

1(1),974A

1(1),974B

l(l),805Cl(l),806A

l(l),1073C

1(1),973C

1(1),974C

1(1),1O88C

l(l),1029B

l(l),1044Cl(l),1044A

FT-IR

1(1),642A

1(3),674D

1(1),516A1(1),516B

1(3),734A

1(1),638C1(3),675B1(3),675A

1(1),639B

l(3),720Cl(3),720B

Merck

11,1539

11,3715

Beilstein

2(2),388

2(3),1228

2,4002,400

3(3),543

4(3),649

2(3), 1230

2(3),12322(3), 12322,3992(4), 14962(3),1229

17(3), 1005

2(4), 1464

2(3), 12282(4), 14702(4), 1496

2(3),1227

Fieser

6,251

TABLE 5. cont'd

Name R

Isodecyl ester -(CH2)7CH(CH3)2

Isooctyl ester -(CH2)5CH(CH3)2Isopropoxyethyl ester -CH2CH2OCH(CH3)SIsopropyl ester -CH(CH3)2

Methallyl ester -CH2C(CH3)=CH2

2-(2-Methoxyethoxy) ethyl ester - C H 2 C H 2 O C H 2 C H 2 O C H 3

2-Methoxyethyl ester -CH2CH2OCH3

Methyl ester -CH 3

2-Methylbutyl ester -CH2CH(CH3)CH2CH3

2-(A^Morpholino)ethyl ester -CH2CH2NC4H8O1-Naphthyl ester -C i 0 H 7

2-Naphthyl ester -C i 0 H 7

Neopentyl ester -CH2C(CH3)3

Neopentyl glycol diester -CH 2C(CH 3 ) 2CH 2 -Nonyl ester -(CH2)8CH3

Octadecyl ester -(CH2) I7CH3

1H,1H,5H-Octafluoropentyl ester -CH2(CF2)3CF2Hrc-Octyl ester -(CH2)7CH3

1H,1H-Pentadecafluorooctyl ester-CH2(CF2)6CF3

Pentaerythritol tetraester (-CH2)4CPenterythritol triester (-CH2)3CCH2OHPentaerythritol stearate diester (-CH2)2C(CH2OH)CH2OC(O)(CH2)I6CH3

2,2,3,3,3-Pentafluoropropyl e s t e r -CH2CF2CF3

1,5-Pentanediol diester - ( C H 2 ) 5 -w-Pentyl ester -(CH2)4CH3

2-Phenoxyethyl ester -CH2CH2OC6H5

Phenyl ester - C 6 H 5

1,4-Phenylene diester - C 6 H 4 -1,4-Phenylene di(acrylic acid) C6H4(CH=CHC(O)OH)2

2-Phenylethyl ester -CH 2CH 2C 6H 5

Trimethyl 2-phosphonoacrylate (CH3O)2P(O)C(C(O)OCH3)=CH2

Propargyl ester -CH 2 C = CHw-Propyl ester -CH2CH2CH3

1,2-Propylene glycol diester -CH2CH(CH3)-1,3-Propylene glycol diester - ( C H 2 ) 3 -Tetradecyl ester -(CH2)I3CH3

Tetra(ethylene glycol) diester -(CH2CH2O)3CH2CH2-2,2,3,3-Tetrafluoropropyl ester -CH2CF2CF2HTetrahydrofurfuryl ester - C 5 H ^S,S'-Thiodi-l,4-phenylene dithiol -SC 6 H 4 SSC 6 H 4 S-

diester2,3,3-Trichloro- ClCH2 =CC1C(O)OHTridecyl ester -(CH2) I2CH3

Tri(ethylene glycol) diester -(CH2CH2O)2CH2CH2-2,2,2-Trifluoroethyl ester -CH 2 CF 3

l,l,l-Tri(2-hydroxyethoxy- (-CH2CH2OCH2)3CCH2CH3

methyl)propane triesterTri(2-hydroxyethyl) isocyanurate (-CH2CH2)3C3N3O3

triester3,5,5-Trimethylcyclohexyl ester -C 6H 8(CH 3) 3

3,5,5-Trimethylhexyl ester -(CH2)2CH(CH3)CH2C(CH3)3

Trimethylolpropane triester (-CH2)3CCH2CH3

Trimethylolpropane ethoxylate ((-CH2CH2O)XCH2)3CCH2CH3

triesterTri(propylene glycol) diester ( - C H 2 ( C H 3 ) C H 2 O ) 2 C H 2 C H ( C H 3 ) -Vinyl ester -CH=CH2

5.2. METHACRYLATE, ACIDS/ESTERS (H2C=C(CH3)C(O)OR)

Acid - H2-(Acetoacetoxy)ethyl ester -CH2CH2C(O)OCH2C(O)CH3

AUyI ester -CH2CH=CH2

Anhydride -C(O)C(CH3)=CH2

2-(l-Aziridinyl)ethyl ester -CH 2CH(-NH-)CH 2

CAS RegistryNumber

1330-61-629590-42-9

689-12-3818-67-7

7328-18-93121-61-7

96-33-3

19727-38-920069-66-352684-34-14513-36-42223-82-7

4813-57-4376-84-1

2499-59-4307-98-2

4986-89-43524-68-3

92092-01-8356-86-5

36840-85-42998-23-4

48145-04-6937-41-7

6729-79-916323-43-63530-36-7

55168-74-610477-47-1

925-60-0

25151-33-121643-42-517831-71-97383-71-32399-48-6

129283-82-5

2257-35-43076-04-81680-21-3407-47-6

28961-43-5

40220-08-4

86178-38-32664-55-3

15625-89-528961-43-5

42978-66-52177-18-6

79-41-421282-97-3

96-05-9760-93-0

6498-81-3

MoI. wt.

212.34184.25159.21114.14126.16174.20130.1486.09

142.20185.2198.22198.22142.24212.25198.31324.55286.12184.28454.13352.34298.30510.72204.10212.25142.20192.21148.16218.21218.21176.22194.13110.11114.14184.19184.19268.44302.33186.11156.18386.56

175.40254.41258.30154.09428.48

423.38

196.29198.31296.32

ca. 428

30098.10

86.09214.22126.16154.17155.20

Boilingpoint (0C)

121/10125/2082/19

51/10370/5086/4.6

56/1280

63/2767/0.2

212/1138/0.431/3

105/576/0.2

160/388/4157/0.0565/5

>315

50/10094/0.347/7

103/0.687/12

104/591/0.1

43/4063/0.3

122/0.5138/0.4

>120/0.3132

87/9

150/10125/0.2

92157

40/0.158/0.8316157

>120/l91

163274

60/43200190

Meltingpoint (0C)

- 1 0 0

- 7 5

32

181530

88>300

138

<-6064

72

97

-34

<-20

16

-20

Density(at 200C)

0.8750.8800.95490.89320.92851.04211.0120.9560.88831.0711

0.8591.0300.8750.800

0.88101.631.1901.1801.0181.32

0.89201.104

1.249

0.9078

0.87001.1101.3171.063

1.0991.2161.110

0.92920.8751.1001.110

1.0300.942

1.0151.1220.9341.035


1.44201.43701.42581.40601.43721.43921.42721.40201.48001.4728

1.45301.4375

1.34671.43501.32791.48701.4840

1.33631.45511.42401.5180

1.4540

1.41301.44701.45291.44681.46381.36291.4580

1.46091.35061.4710

1.4551.43701.47361.4720

1.45001.4320

1.4321.45601.43601.454

Flashpoint (0C)

10680

607

>37123

19070

170> 110

> 110

105

>11045

>110

6312

>110

8889

>11086

2

761063483

RTECSNumber

AT2190000UD3391000

KL6000000AT2800000

AS8925000

UD3370000

KM0700000

AS8100000

KM2890000

UD3643625AT4810000KM2890000

AT4690000

OZ2975000

UD3483000OZ5700000

R and S

1(1),719C

1(1),753I

1(2),1775F

l(l),1109B

1(1),759E1(1),745A

1(1),743M

1(1),729F

1(1),729A

1(1),547B1(1),791E1(1),721E1(1),831C

FT-NMR

1(1),973B

1(2), 1050A

1(1),1489B

l(l),1053B

l(l),1028C1(1),999C

1(1),999C

1(1),776Bl(l),1107C1(1),977Al(l),1170C

FT-IR

1(1),638B

1(1),639C

1(2),179B

1(1),639A

1(3),696C

l(l),640A

1(1),638D

1(1),499C

1(1),641B

Merck

11,5935

11,5849

Beilstein

2(3),12323,638B

2(4), 1468

6(3),572

9,914

4(4),3638

17(3),110417(3),1104

2(4), 1462

2(3),1230

2,421

2(3), 12902(3),12936(3),1481

Fieser

17,183

TABLE 5. cont'd

Name

Benzyl esterBisphenol A diesterBisphenol A tetraethoxylate

diester2-Bromoethyl ester1,3-Butylene diester1,4-Butylene diester2-Butoxyethyl ester«-Butyl esters-Butyl estertert-Butyl ester7V-te/?-Butyl-2-aminoethyl ester2-Chloro-2-hydroxypropyl ester2-Chloroethyl esterChloromethyl esterCinnamyl esterChloride2-Cyanoethyl ester1,4-Cyclohexanediol diesterCyclohexyl esterDecanediol diesterDecyl ester2,3-Dibromopropyl ester2-(Dibutylamino)ethyl esterDicyclopentenyl esterDicyclopentenyloxyethyl ester2-(Diethylamino) ethyl ester3-(Dimethylamino) propyl esterDi(ethylene glycol) diester3,4-Dihydroxybutyl ester2,3-Dihydroxypropyl ester2-(Dimethylamino) ethyl esterDiurethane diester (isomers)IH, 1H,7H-Dodecafluoroheptyl

esterDodecanediol diesterDodecyl ester2,3-Epithiopropyl ester2,3-Epoxybutyl ester3,4-Epoxybutyl ester2,3-Epoxyopropyl ester4-Ethoxybutyl ester2-Ethoxyethyl esterEthyl esterEthyl 2-bromomethyl- ester2-Ethylbutyl ester1,2-Ethylene diester2-Ethylhexyl ester2-(Ethylthio)ethyl esterEthyl 2-(trimethoxysilylmethyl-)

esterFurfuryl esterGlycerol diesterGlycerol triesterGlycidyl ester1H,1H,2H,2H-Heptadeca-

fluorodecyl ester1H, 1 H-Heptafluorobutyl esterHeptyl ester1,6-Hexanediol diester2,2,3,4,4,4-Hexafluorobutyl esterlH-Hexafluoroisopropyl esterHexyl ester

R

-CH 2 C 6 H 5

—C6H4C(CH3)2C6H4 —((-CH2CH2O)2C6H4)SC(CHs)2

-CH2CH2Br-CH2CH2CH(CH3)-- (CHz) 4 --CH2CH2O(CH2)3CH3

-(CH2)3CH3

-CH(CH3)CH2CH3

-C(CH3)3

-CH2CH2NHC(CH3)3

-CH2C(OH)ClCH3

-CH2CH2Cl-CH2Cl-CH2CH=CHC6H5

CH2=C(CH3)C(O)Cl-CH2CH2CN-C 6 HiO--C6Hn

-(CH2)IO--(CH2)9CH3

-CH2CHBrCH2Br-(CH2)2N(CH2CH2CH2CH3)2

-C10H13- C 1 2 H n O-(CH2)2N(CH2CH3)2

-(CH2)3N(CH3)2

-CH 2CH 2OCH 2CH 2 -- C H 2 C H 2 C H ( O H ) C H 2 O H

-CH2CH(OH)CH2OH-CH2CH2N(CH3)2

C2 3H3 8N2O8

-CH2(CF2)5CF2H

-(CHz) 1 2 --(CH2)IiCH3

-CH 2 CH(-S-)CH 2

-CH2CH(-O-)CHCH3

-CH 2CH 2CH(-O-)CH 2

-CH 2 CH(-O-)CH 2

-(CH2)4OCH2CH3

-CH2CH2OCH2CH3

-CH 2CH 3

CH2=C(CH2Br)C(O)OCH2CH3

- C H 2 C H ( C H 2 C H 3 ) C H 2 C H 3

- C H 2 C H 2 --CH2CH(CH2CH3)(CH2)3CH3

-CH2CH2SCH2CH3

CH2=C(CH2Si(OCH3)3)C(O)OCH2CH3

-CH 2C 4H 3O-CH2CH(OH)CH2--CH(CH 2 - ) ,-CH(-O-)CH 2

-(CH2)2(CF2)7CF3

-CH2(CF2)2CF3

-(CH2)6CH3

- ( C H 2 ) 6 --CH2CF2CHFCF3

-CH(CF3) ,-(CH2)5CH3

CAS RegistryNumber

2495-37-63253-39-2

41637-38-1

4513-56-81189-08-82082-81-7

13532-94-097-88-1

2998-18-7585-07-9

3775-90-413159-52-9

1888-94-427550-73-831736-34-2

920-46-74513-53-5

38479-34-4101-43-9

6701-13-93179-47-33066-70-42397-75-3

31621-69-968586-19-6

105-16-817577-32-12358-84-1

62180-57-85919.74.4

2867-47-272869-86-4

2261-99-6

72829-09-5142-90-5

3139-91-168212-07-755750-22-6

106-91-276392-24-0

2370-63-097-63-2

17435-72-25138-86-3

97-90-5688-84-6

14216-25-274976-84-4

3454-28-21830-78-0

52408-84-1106-91-2

1996-88-9

13695-31-35459-37-06606-59-3

36405-47-73063-94-3

142-09-6

MoI. wt.

176.22364.44452.55

193.05226.28226.28186.25142.20142.20142.20185.27178.62148.60146.57202.25104.54139.16252.31168.24310.44226.36285.96241.38218.30262.35185.28199.30242.27174.20160.17157.22470.57400.17

338.49252.42158.22156.18156.18142.16186.25158.20114.15193.05170.25198.22198.31174.26186.33

166.18228.25296.3142.16532.20

268.13184.28254.33250.14236.11170.25

Boilingpoint (0C)

232

ca. 540

47/2.7290

133/490/3

161146132

100/1295/259/7.5

54/20141/3

9599/2

69/4170/2

32772/0.03

100/1137/13150/1080/10105/1.5134/2110/0.25140/0.6

187200

107/23

142/459/1.445/0.2555/0.8

18985/2392/35

11838/0.8

74/16240218

102/1571/10

81/5120/1150/0.1

189120/4

134104/14

>31515899

88/14

Meltingpoint (0C)

73

50

- 4 4

<-60

-30

0.95- 7

<-75

-40

<-18

Density

(at 200C)

1.040

1.120

1.0101.0230.9390.894

0.8750.9141.190

1.070

0.9626

0.875

1.0501.0640.922

1.082

0.9331.110

1.460.868

1.0381.042

0.9640.9171.398

1.0510.885

0.897

1.0781.120

1.042

1.345

0.9951.3481.3020.885


1.5120

1.5320

1.45201.45651.43351.42301.41951.41501.44201.4750

1.4434

1.44201.4459

1.4591.45771.443

1.44741.49901.49701.4442

1.4580

1.44001.485

1.4450

1.44221.44721.44901.42231.42901.41301.4790

1.45401.4380

1.4380

1.48201.4720

1.4490

1.3410

1.45801.36101.33101.432

Flashpoint (0C)

107

> 110

1301139350

5071

150

3

8282

101

>110> 110

85

66

70>150

>110

76

711587

8692

59

90> 115

76

37

150571463

RTECSNumber

OZ3675000

OZ3675500OZ3500000

OZ5791000

OZ4200000

OZ4300000

OZ4375000

OZ4550000

OZ4400000OZ4630000

OZ4375000

R and S

1(2),1931F

1(1),729D

1(1),721A

1(1),857B

1(1),771H

1(1),721D

1(1),781F

1(1),759C1(1),719J

1(1),729B1(1),721C

1(2),2985A

1(1),781F

1(1),745F1(1),745E

FT-NMR

1(2),1296C

1(1),999A

1(1),975C

l(l),1074A

1(1),976C

l(l),1089A

l(l),1052C1(1),975B

1(1),998B1(1),976B

1(3),686B

l(l),1089A

l(l),1030Bl(l),1030A

FT-IR Merck

1(2),316B

1(1),639D

1(1),641A

1(1),732C

1(1),675C

1(3),678B

1(1),668D

1(3),723Cl(l),640D

1(1),642D

1(1),668D

Beilstein

2(4),15342(3),12922(3),1286

2(4),15824(4),15092(4),1533

2(3), 1293

6(3),25

6(3), 1942

4(3),676

2(3),1292

4(3),649

2(3), 1290

2(3),12912,423

2(3), 12922(3),1289

17(3), 1248

Fieser

TABLE 5. cont'd

Name

4-Hydroxybutyl ester2-Hydroxyethyl ester3-(5-Hydroxypentyloxy)-

3-oxopropyl ester3-Hydroxypropyl esterIsobornyl esterIsobutyl ester2-Isocyanatoethyl esterIsodecyl esterIsopropyl esterMethallyl ester2-(2-Methoxyethoxy) ethyl ester2-Methoxyethyl esterMethyl ester2-Methyl-2-nitropropyl ester2-(Methylthio) ethyl esterMethyl 2-bromomethyl esterMethyl 2-(l-hydroxyethyl-)ester2-Af-Morpholinoethyl esterNeopentylglycol diesterNona(ethylene glycol) diesterNona(propylene glycol) diesterNonyl ester4-Nonylphenyl esterOctadecyl ester«-Octyl esterPentabromophenyl esterPentachlorophenyl ester1H, 1 H-Pentafluorooctyl esterPentaerythritol tetraester2,2,3,3,3-Pentafloropropyl esterPentyl ester2-Phenoxyethyl esterPhenyl ester2-Phenylethyl esterrc-Propyl ester1,2-Propylene diester1,3-Propylene diester2-Sulfoethyl ester3-Sulfopropyl ester, potassium

saltTetra(ethylene glycol) diester2,2,3,3-Tetrafluoropropyl esterTrimethylsilyl ester2-(Trimethylsilyloxy)ethyl ester3-(Trimethylsilyloxy)propyl ester3-(Tris(trimethylsiryloxy)silyl)

propyl esterVinyl ester

TABLE 6. ALCOHOLS

Name

6.1. ALKANEDIOLS

1,2-Butane1,3-Butane1,4-Butane1,10-Decane1,12-Dodecane1,2-Ethylene

R

-(CH2)4OH-CH2CH2OH-CH2CH2C(O)O(CH2)5OH

-(CH2)3OH-CioHg-CH2CH(CHs)2

-CH2CH2NCO-(CH2)7CH(CH3)2

-CH(CHs)2

-CH2C(CH3)=CH2

-(CH2CH2O)2CH3

-CH2CH2OCH3

-CH 3

-CH2C(CH3)(NO2)CH3

-CH2CH2SCH3

CH2 =C(CH2Br)C(O)OCH3

CH2=C(CH(OH)CH3)C(O)OCH3

-CH2CH2NC4H8O-CH 2C(CH 3 ) 2CH 2 --(CH2CH2O)8CH2CH2-- ( C H ( C H 3 ) C H 2 O ) 8 C H ( C H 3 ) C H 2 -

-(CH2)8CH3

-C6H4(CH2)8CH3

-(CH2) 17CH3

-(CH2)7CH3

-C 6 Br 5

-C 6 Cl 5

-CH2(CF2)6CF3

C(CH 2 - ) ,-CH2CF2CF3

-(CH2)4CH3

-CH2CH2OC6H5

- C 6 H 5

-CH 2CH 2C 6H 5

-CH2CH2CH3

-CH2CH(CH3)-- ( C H 2 ) , --CH2CH2SO3H-(CH2)3SO3K

-CH2CH2(OCH2CH2)3--CH2CF2CF2H-Si(CH3) ,-CH2CH2OSi(CHs)3

-(CH2)3OSi(CH3)3

-(CH2)3Si(OSi(CH3)3)3

-CH=CH2

Formula HOROH

R

-CH(C 2H 5 )CH 2 --CH(CH3)CH2CH2-- ( C H 2 ) , -- (CHa) 1 0 -- (CH 2 ) I 2 -- ( C H 2 ) 2 -

CAS RegistryNumber

997-46-6868-77-9

85099-10-1

276-09-37534-94-3

97-86-930674-80-729964-84-94655-34-9

816-74-045103-58-0

6976-93-880-62-6

2177-42-614216-23-04224-69-5

18020-65-02997-88-81985-51-9

25852-47-525852-49-7

2696-43-776391-98-532360-05-7

2157-01-918967-31-216184-61-53934-23-43253-41-6

45115-53-52849-98-1

10595-06-92177-70-03683-12-32210-28-81188-09-6

10595-80-931098-21-2

109-17-145102-52-113688-56-717407-09-92530-85-0

17096-07-0

4245-37-8

CASRegistryNumber

584-03-2107-88-0110-63-4112-47-0

5675-51-4107-21-1

MoI. wt.

158.20130.14244.29

144.17222.33142.20155.17226.36128.17140.18188.22144.17100.12187.20160.24179.02130.14199.25240.30550560212.33288.43338.58198.31556.69334.41468.16408.45218.12156.23206.24162.19190.24128.17212.25212.25194.21246.33

300.37200.14158.28202.33248.35422.82

112.13

MoI. wt.

90.1290.1290.12

174.28202.3462.07

Boilingpoint (0C)

105/0.01250

90/9245155211

126/10125157

67/166/16

100102/438/0.0636/1.3

91/2080/0.08

112/1.2

>200/l

125/0.03195/6105/4

67/5

55/11073/17

183115/10119/11

14068/168/1

(d)

220124

51/2065/0.9

190113/0.2

111

Boilingpoint (0C)

191/747203230

170/8189/12

197

Meltingpoint (0C)

- 1 2- 4 8

- 5 1

- 4 5- 4 1

- 4 8

19

13287

66

295(d)

Meltingpoint (0C)

167382

- 1 3

Density(at 200C)

1.0731.080

1.0660.98300.8861.0960.8780.8847

1.0200.9930.9361.0871.0401.4891.071

1.0031.0991.0101.099

0.864

1.5732

1.0687

0.980.9022

1.3245

1.0801.2500.8900.9281.0450.918

0.933

Density(at 2O0C)

1.0061.0051.017

1.113


1.45201.4360

1.44701.47701.420

1.44301.4122

1.43971.43101.41401.4501.48001.49001.4520

1.45301.46601.45201.46601.50201.45101.4373

1.3482

1.51301.51841.5081.44501.4450

1.4772

1.46301.37301.41471.42801.43101.4190

1.4360


1.43801.44001.4450

1.4310

Flashpoint (0C)

97>110

961074197

>110

> 1106510

> 110887843

117>110>110> 110> 110

196

96>100

6

100

122

8250327692

> 110

13

Flashpoint (0C)

93121

>110

>110

RTECSNumber

OZ4725000

OZ4900000

OZ5000000

OZ5075000

AS4900000

OZ4000000

UC0230000

RTECSNumber

EK0380000EK0440000EK0525000HD8433713

KW2975000

Rand S

1(1),753M

1(1),721B

1(1),719I

1(1),745J

l(l),1065F

1(1),745B1(2),2985B1(2),2985C1(2),2985D

R and S

1(1),141A1(1),139L1(1),139K1(1),143N1(1),145A1(1),139A

FT-NMR

l(l),1045A

1(1),976A

1(1),975A

l(l),1031C

1(1),1438B

l(l),1029A1(3),686C1(3),687A1(3),687B

FT-NMR

1(1),196C1(1),195C1(1),195Bl(l),205Cl(l),206B

FT-IR

1(1),665B

1(3),677C

1(1),64OC

l(l),890D

1(2),1116C

FT-IR

1(1), 130B1(1), 130Dl(l),130A1(1),136D1(1),137A1(1),127D

Merck

11,5849

Merck

11,1566

11,2842

11,3755

Beilstein

2(3),1287

2(2),3982(3),1288

2(4),1535

2(3),1290

2(4),1531

2(3),1290

Beilstein

1,4771,4771,478l(2),5601(2),5621,465

Fieser

Fieser

15,156

TABLE 6. cont'd

Name

1,7-Heptane1,16-Hexadiene1,6-Hexane1,7-Heptane1,16-Hexadiene1,9-Nonane1,8-Octane1,5-Pentane1,2-Propane1,3-Propane1,14-Tetradecane

6.2. ETHERDIOLS

Di(ethylene glycol)Di(propylene glycol)Hexa(ethylene glycol)Penta(ethylene glycol)Tetra(ethylene glycol)Tri(ethylene glycol)Tri(propylene glycol)

Formula HOROH

R

- (CHa) 7 -- (CH 2 ) I 6 -- ( C H 2 ) 6 -- ( C H a ) 7 --(CH2) 1 6 -- ( C H 2 ) 9 -- (CH 2 )S-- (CH 2 )S--CH(CH3)CH2-- (CH 2 )S--(CH2) 1 4 --CH2CH2OCH2CH2-- C H ( C H 3 ) C H 2 O C H ( C H 3 ) C H 2 -

-CH2CH2(OCH2CH2)S--CH 2CH 2(OCH 2CH 2) 4-

-CH2CH2(OCH2CH2)3-

-CH 2CH 2(OCH 2CH 2) 2-

-CH(CH3)CH2(OCH(CH3)CH2)2-

TABLE 7. ALLYL FUNCTIONAL

Name

Acetate-Acetic acidAcetoacetateAlcohol- , 2-Bromo-- , 2-Chloro-- , 3-Methyl(crotyl alcohol;-Amine-AT-Aniline-4-Anisole-BenzeneBenzyl etherBromideButyl etherButyrateChlorideChloroacetateChloroformateCyanideCyanoacetateDiallyl amine2,3-Dibromide2,3-DichlorideEtherEthyl etherFluorideFormateGlycidyl etherIodideIsocyanateIsopropyl ether4-(2-Methoxyphenol)Methyl ether-2-Phenol

Formula CH2=CHCH2R

R

-OC(O)CH3

-CH2C(O)OH-OC(O)CH2C(O)CH3

-OHH2C=CBrCH2OHH2C=CClCH2OH

) CH3CH=CHCH2OH-NH 2

-NC 6 H 5

-C 6H 4OCH 3

- C 6 H 5

-OCH2C6H5

-Br-O(CH2)3CH3

-OC(O)CH2CH2CH3

-Cl-OC(O)CH2Cl-OC(O)Cl-CN-OC(O)CH2CN- N H -H2=CBrCH2BrH2C=CClCH2Cl- O --OCH2CH3

- F-OC(O)H-O-CH 2 CH(-O-)CH 2

- I-NCO-OCH(CH3)2

-C6H4(OCH3)OH-OCH 3

-C 6H 4OH

CASRegistryNumber

629-30-123079-20-1

629-11-8629-30-1

23079-20-13937-56-2

629-41-4111-29-557-55-6

504-63-219812-64-7

111-46-6110-98-5

2615-15-84792-15-8

112-60-7112-27-6

24800-44-0

CASRegistryNumber

591-87-7591-80-0

1118-84-9107-18-6

5976-47-66117-91-5

107-11-9589-09-3140-67-0300-57-2

14593-43-2106-95-6

3739-64-82051-78-7

107-05-12916-14-52937-50-0

109-75-113361-32-5

124-02-7513-31-5

557-40-4557-31-3818-92-8

106-92-3556-569

1476-23-9

97-53-0627-40-7

1745-81-9

MoL wt.

132.20258.45118.18132.20258.45160.26146.23104.1576.1076.10

230.39

106.12134.18282.34238.28194.23150.17192.26

MoL wt.

100.12100.12142.1658.08

136.9892.5372.1257.10

133.19148.21118.18148.21120.98114.19128.1776.09

134.56120.5467.09

125.1397.16

199.88110.9798.1586.1360.0786.09

114.14167.9883.09

100.16164.2072.11

134.18

Boilingpoint (0C)

259198/3

250259

198/3177/15172/20

242187214

245

217/4184/2

314285273

Boilingpoint (0C)

10484/12

194/73797

15213412253

219215156204

70

44/1545

164/265109118

110/20112141949566

- 1 084

1541038884

15446

220

Meltingpoint (0C)

18924218924860

- 6 0- 2 7

88

- 1 0

6

- 6- 7

Meltingpoint (0C)

- 2 2

- 1 2 9

- 8 8

- 1 1 9

- 1 3 4

- 8 8

- 1 1

Density(at 200C)

0.951

0.951

0.9941.0361.053

1.1181.0231.1271.1261.1251.1251.021

Density(at 200C)

0.9280.9811.0370.8541.61.1620.8450.7610.9820.9650.8920.9591.3980.7830.9020.9391.1591.1360.8341.0650.7871.9341.2110.8030.760

0.94600.9621.8370.9400.77641.0660.9781.028


1.4550

1.4550

1.45001.43201.4400

1.44601.44101.46401.46201.45901.45501.4440


1.40401.42831.43901.41201.51.45901.42701.42051.56301.52101.51001.50701.46901.40601.41401.41351.44601.42201.40501.44301.44051.54701.46031.41601.3880

1.43301.55401.41701.39461.54101.52001.5450

Flashpoint (0C)

>110

102> 110

>110

12910779

143138

>110>110

177166

>110

Flashpoint (0C)

7897522

5437

- 2 989813376

- 21441

- 2 9613123

>1101681

- 7- 2 1

571843

>1106388

RTECSNumber

MI9804000

MO2100000MI9804000

SA0480000TY2000000TY2010000

ID5950000UB8785000MM3670000RZ2670000XC2100000YE4550000YK6825000

RTECSNumber

AFl760000SB2800000

BA5075000

UD4725000EM9275000BA5425000

BZ8225000CY2275000

UC7090000

ES5775000UC7350000

LQ5775000EM8050000AG3690000UC6650000UC8200000

KN7525000

RR0875000VD0450000NQ8175000

SJ4375000

SJ3850000

R and S

1(1),143J1(1),145E1(1),143D1(1),143J1(1),145E1(1),143M1(1),143K1(1),141I1(1),139C1(1),139B1(1),145C

1(1),225D1(1),225E1(1),229B1(1),227K1(1),227H1(1),227D1(1),227F

Rand S

1(1),715C1(1),547H1(1),787A1(1),147A

1(1),183D1(1),147C1(1),347A1(1),1383K1(1),1243C1(1),1139E

1(1),95I1(1),219G1(1),717N1(1),95E

1(1),863B1(1),991Fl(l),1013F1(1),347Kl(l),101K

1(1),219H1(1),219E

1(1),251C1(1),95Jl(l),1023E

1(1),1283E

1(1),1265H

FT-NMR

l(l),204B

l(l),202Bl(l),204B

l(l),205Bl(l),204C1(1),199A1(1),192C1(1),192Bl(l),207A

1(1),341B1(1),341C1(1),347A1(1),346B1(1),346A1(1),345A1(1),345B

FT-NMR

1(1),963C1(1),778A1(1),687Cl(l),207B

l(l),208A1(1),518C1(2),454Bl(2),208B1(2),24B

1(1),135A1(1),333Bl(l),970B1(1),133C

l(l),1206B1(1),1358C1(1),1391Bl(l),520A

1(1),333C1(1),332C

1(1),374A

l(l),1404A

1(2),278A

1(2),245B

FT-IR

1(1),135C1(1),137D1(1),134B1(1),135C1(1),137D1(1),136B1(1),135D

1(1),132B1(1),128B1(1),128A

1(1),223B1(1),226A1(1),227A1(1),226D1(1),226C1(1),226B

FT-IR

1(1),633B1(1),499Bl(l),1098A1(1),138B

1(1),138C1(1),322B1(1),1191Al(l),1053B1(1),946B

1(1),93D

1(1),637B1(1),93C

1(1),737A1(1),843A

1(1),322C1(1),99C

1(1),212D1(1),212C

1(1),233D1(1),94A1(1),872A

l(l),1091A

l(l),1070D

Merck

11,4610

11,707311,786811,96291(2),564

11,3109

11,9585

Merck

1(1),687C11,284

11,260411,285

11,3657

11,286

11,287

11,288

11,295111,3009

11,29011,291

11,292

11,3855

Beilstein

1,489

1,4841,4891,4891,4931,4901,4811,4721,475

1,4681(2),5371,4681,4681,4681,468

Beilstein

2,1362,42519(3), 12031,436

1,4391,4424,20512,1706,7515,4846(3),14591,2011(3),18822,2721,1982,1983,122,408

4,2081,201

1,4381,438

1,202

4,214

6,961

6,572

Fieser

Fieser

13,2

TABLE 7. cont'd

Formula CH2=CHCH2R

Name R

Phenyl ether4-Chloro-2,4,6-Tribromo-

Phenyl sulfonePropyl-Succinic anhydrideSulfide2-Tolyl ether3-Tolyl ether4-Tolyl ether-Urea

-OC 6 H 5

-OC6H4Cl-OC6H2Br3

-S(O)(O)C6H5

-CH2CH2CH3

- C 4 H 3 O 3

- S --OC 6H 4CH 3

-OC 6H 4CH 3

-OC 6H 4CH 3

-NHC(O)NH2

TABLE 8. AMINES, DIFUNCTIONAL

Formula H2NRNH2

Name R

Butane -Decane-Dodecane-Ethylene-Heptane-Hexane-Nonane-Octane-Pentane-1,2-Phenylene-1,3-Phenylene-1,4-Phenylene-Propane-

TABLE 9. ANHYDRIDES

- (CHz) 4 -- (CHz) 1 0 -- (CHz) 1 2 -- (CHz) 2 -- (CHz) 7 -- (CHz) 6 -- (CHz) 9 -- (CHz) 8 -- (CH 2 )S-- C 6 H 4 -- C 6 H 4 -- C 6 H 4 -- (CHz) 3 -

Name Formula

9.1. MONOANHYDRIDES

Acetoxysuccinic5-AcetylmercaptosuccinicAconitic, cis-Acrylic (see Acrylates)Allylsuccinic4-Amino-1,8-naphthalic1,2,4-Benzenetricarboxylic

(trimellitic)Bicyclo[2.2.2.]oct-5-ene-

2,3-dicarboxylic, endo-Bromomaleic4-Bromo, 1,8-naphthalic3-(tert-Butyldimethylsilyloxy)-

glutaric4-tert-ButylphthalicN-Carboxybenzyloxy-L-asparticCantharidin5-Chloroisotoic4-Chloro-1,8-naphthalicCitraconicCyclohexane-1,2-dicarboxylic,

cis-

C6H6O5

C6H6O4SC6H4O5

C7H8O3

C12H7NO3

C9H4O5

C10H10O3

C4HBrO3

C12H5BrO3

C11H20O4Si

C12H12O3

C12H11NO5

C10H12O4

C8H4ClNO3

C12H5ClO3

C5H4O3

C8H1 0O3

CASRegistryNumber

1746-13-0

3278-89-516212-05-8

1471-03-07539-12-0

592-88-1

557-11-9

CASRegistryNumber

110-60-1646-25-3

2783-17-7107-15-3646-19-5124-09-4646-24-2373-44-4462-94-2

95-54-5108-45-2106-50-3109-76-2

CAS RegistryNumber

79814-40-76953-60-26318-55-4

7539-12-06492-86-0

552-30-7

24327-08-0

5926-51-221563-29-191424-40-7

32703-79-04515-23-5

56-25-74743-17-34053-08-1

616-02-413149-00-3

MoL wt.

134.18168.63370.88182.24100.16140.1114.21148.21148.21148.21100.12

MoL wt.

88.15172.32200.37

60.10130.24116.21158.29144.26102.18108.14108.14108.1474.13

MoL wt.

158.11174.18156.10

140.1213.20192.13

178.19

176.96277.08244.37

204.23249.23196.20197.58232.63112.08154.17

Boilingpoint (0C)

192107/12

111/0.591

260138

81/2213

91/10

BoilingPoint(°C)

159140/12

118224204

258/756225179257283267140

Boilingpoint (0C)

260

215

213158/17

Meltingpoint (0C)

75

6

85

MeltingPoint(°C)

276270

8.528433751

10465

144- 1 2

Meltingpoint (0C)

568375

6

167

145

21880

73123216

300(d)208

733

Density(at 200C)

0.978

1.1890.767

0.8870.9500.95640.970

Density(at 200C)

0.877

0.899

0.873

0.888

Density(at 200C)

1.163

1.905

1.247


1.52001.5348

1.54801.3990

1.48891.51791.51791.5168

RefractiveIndex*At 200C)

1.4569

1.4565

1.4582

1.4565


1.4710

Flashpoint (0C)

63

>110_ 5

46

FlashPoint(°C)

52

155348881

>11016563

>110

34

Flashpoint (0C)

>110

101>110

RTECSNumber

DA8575000

WR2400000

BC4900000

YR7875000

RTECSNumber

EJ6800000HD7175000JR2200000KH8575000

MOl 180000

RG8841500SA0200000SS7875000SS7700000SS8050000TX6825000

RTECSNumber

DC2050000

RN8575000

QL6127295GE6825000

R and S

1(1),1241M

1(2),2185B1(1),219F

1(1),287J

1(1),939M

Rand S

l(l),309G1(1)31111(1),31Ul(l),309A1(1),3HE1(1),311B1(1),3HH1(1),3HFl(l,309K1(1),1429A1(1),1431C1(1),1433Dl(l),309D

R and S

1(1),837E1(1),837D

1(2),1961B1(2),1959G

1(1),835N

1(1),839A1(2),1961A1(2),2987F

1(2),1957H1(2),1959N1(1),837J1(1),835G

FT-NMR

l(2),207A

1(2), 1580A1(1),333A

1(1),432C

l(l),1308B

FT-NMR

1(1),465A1(1),469B1(1),469C1(1),463B1(1),468A1(1),467A1(1),469A

1(1),468B

1(2),536B1(2),539A1(2),542C1(1),464A

FT-NMR

1(1),1179B

1(2),1329C

1(1),1178B

1(1),1182B1(2), 133OB1(3),692A

1(1),1181A1(1),1175C

FT-IR

l(l),1052B

l(3),2780

1(1),269C

l(l),800D

FT-IR

1(1),291D1(1),293D1(1),294A1(1),289C1(1),293A1(1),292C1(1),293C1(1),293B1(1,292B1(1),1235C1(1),1239A1(1),1242Bl(l),290A

FT-IR

1QV715C

1(2),336A

1,(2),334A

1(1),717D

1(1),719C

1(2),332C1(2),335D1(1),718D1(1),715D

Merck

6,144

11,295

11,296

Merck

11,7964

11,3752

11,4614

11,160811,725511,725411,7256

Merck

11,9617

Beilstein

11,14

6,2056,2991,438

1,440

4,209

Beilstein

4,2644,2734,2734,2304,2714,2694,2724,2714,26613,63,3313,614,261

Beilstein

18(2), 1128

18,463

18(2),46918,468

17,43517,523

19,16127,26517,52217,440

Fieser

Fieser

4,231

8,393

Fieser

TABLE 9. cont'd

Name

Cyclohexane-1,2-dicarboxylic,trans-

Diacetyl-L-tartaric3,5-Diacetyltetrahydropyran-

2,4,6-trioneDichloromaleic3,6-Dichlorophthalic4,5-Dichlorophthalic3,6-DifluorophthalicDiglycolic2,2-Dimethylglutaric3,3-Dimethylglutaric2,3-Dimethylmaleic2,2-DimethylsuccinicDiphenic2,3-Diphenylmaleic2-Dodecen-1 -ylsuccinic3,6-Epoxy-l,2,3,6-tetra-

hydrophthalic, exo-3-Ethyl-3-methylglutaric3-Fluorophthalic4-Fluorophthalic2-ForaiamidosuccinicGlutaricl,4,5,6,7,7-Hexachloro-5-

norbornene-2,3-dicarboxylic

HexafluoroglutaricHexahydro-4-methylphthalicHomophthalic3 -Hy droxy phthalicIsatoicIsobutenylsuccinicItaconicMaleic3-MethylglutaricAf-MethylisatoicMethyl-5-norbornene-

2,3-dicarboxylic4-MethylphthalicMethylsuccinic1,8-Naphthalic3-Nitro-1,8-naphthalic4-Nitro-1,8-naphthalic3-Nitrophthalic4-Nitrophthalic5 -Norbornene- endo-

2,3-dicarboxylic,

CJS-

Octadecylsuccinic2-Octen-1 -ylsuccinic3-Oxabicyclo[3.1.0] hexane-

2,4-dione2,5-Oxazolidenedione2-PhenylglutaricPhenylmaleic1 -Phenyl-2,3-naphthalene-

dicarboxylicPhenylsuccinicPhthalicN-Phthaloylglutamic1 -PropenyloxymethylmaleicPyrazinedicarboxylic

Formula

C8H1 0O3

C8H8O7

C9H8O6

C4Cl2O3

C8H2Cl2O3

C8H2Cl2O3

C8H2F2O3

C4H4O4CVHK)O 3

C7H1 0O3

C6H6O3

C6H8O3

Ci4H8O3

C1 6Hi0O3

C16H26O3

C8H6O4

C8H1 2O3

C8H3FO3

C8H3FO3

C5H5NO4

C5H6C3

C9H2Cl6O3

C5F6O3

C9H1 2O3

C9H6O3

C8H4O4

C8H5NO3

C8H10O3

C5H4O3

C4H2O3

C6H8O3

C9H7NO3

C10H10O3

C9H6O3

C5H6O3

Ci2H6O3

Ci2H5NO5

C12H5NO5

C8H3NO5

C8H3NO5

C9H8O3

C22H38O3

C12H18O3

C5H4O3

C3H3NO3

C11H10O3

C1 0H6O3

C18H10O3

C10H8O3

C8H4O3

C13H9NO5

C7H1 0O4

C6H2N2O3

CAS RegistryNumber

14166-21-3

6283-74-533524-89-9

1122-17-44466-59-5

942-06-3652-40-4

4480-83-52938-48-94160-82-1

766-39-217347-61-46050-13-14808-48-4

19780-11-16118-51-0

6970-57-6652-39-1319-03-9

33605-73-1108-55-4115-27-5

376-68-119438-60-9

703-59-337418-88-5

118-48-918908-20-82170-03-8

108-31-64166-53-4

10328-92-425134-21-8

19438-61-04100-80-5

81-84-53027-38-1

34087-02-0641-70-3

5466-84-2129-64-6

26680-54-65617-74-3

2185-00-42959-96-8

36122-35-71985-37-1

1131-15-385-44-9

3343-28-0130221-78-2

4744-5O-7

MoI. wt.

154.17

216.15212.16

166.95217.01217.01184.10116.07142.16142.16126.11128.13224.22250.26266.38166.13

156.18166.11116.11143.10114.10370.83

222.04168.19162.14164.12163.13157.17112.0998.06

128.13117.16178.19

162.14114.10198.18243.17343.17193.11193.11164.16

350.55210.27112.08

101.06190.20176.16247.28

176.17148.12259.22158.16150.09

Boilingpoint (0C)

240175/60181/25

223219

180/5

185/20

72

146/14114/12

202181/25

295239

251/4168/10

100/5

218/13

191/12284

251

Meltingpoint (0C)

146

131154

188186219

9236

1249430

22516042

118(d)

15979

14556

237

141200

233(d)64715245

9134

268248(d)

228164118166

621060

120(d)97

121259

54132199

210(d)

Density(at 200C)

1.135

1.6541.162

1.232

1.220

1.0551.000

1.100

Refractiveindex (at 2O0C)

1.32401.4770

1.5060

1.4694

1.4610

Flashpoint (0C)

108

177

>110

None>110

103>110

>110

>110

>110

>110

RTECSNumber

ON4025000

MA3850000RB9080000

TI3300000DM3100000

ON3675000

DM3140000

RB9100000

QK5350000QK5370000

TI3328000DT5600000

TI3150000MA3900000

Rand S

1(1),835H

1(1),837F1(1),839L

1(1),839B1(2),1959B1(2),1959C1(2),1959A1(1),841C1(1),839G1(1),839H1(1),837K1(1),835C1(2),1959L1(2),1957C1(1),835K1(1),837B

1(1),839I

1(1),839E1(1),839C

1(1),839K1(1),835I1(2),1957E1(2),1959F1(2),1957F1(1),835E1(1),835J1(1),837I1(1),839F1(2),1957Gl(l),835O

1(2),1957M1(1),835B1(2),1959M1(2),1961C1(2),1961D1(2),1959H1(2),1959I1(1),835M

1(1),835F

l(l),907M1(2),1957D

1(2), 1957 Jl(2),2017M

FT-NMR

1(1),1176A

1(1),1179C1(1),1174A

1(2),1328B1(2),1328C1(2),1328A

1(1),1183C1(1),1184A1(1),1181B1(1),1175A

1(1),1177A1(1),1179A

1(1),1184B

1(1),1183A1(1),1182C

1(1),1184C1(1),1176B

1(2),1329B

1(1),1175B1(1),1176Cl(l),1180C1(1),1183B

1(1),1178C

1(2),1327B1(1),1174C

1(2), 1330C

l(2),1330A1(1),1177C

1(2),1327A1(2)1391A

FT-IR

1(1),716A

1(1),457D

1(1),719D

1(1),722Al(l),720D1(1),721A1(1),719A

1(2),335B

1(1),717A

1(1),721B

l(l),720Bl(l),720A

1(1),716B

1(2),331D

1(2),332A

1(1),716D1(1),718Cl(l),720C1(2),332B1(1),718C

1(1),715B1(2),335C

1(2),334B1(2),334C1(1),717C

1(2),331C

1(2),332D

Merck

11,2084

11,5586

11,1801

11,7346

Beilstein

17,452

18,16217(4),6841

17,43417,48317,48317(5), 11,25919,15317,41817,41917,44517,41717,52617,532

19(2),181

17(1),231

17(5),11,25918(11),5,54817,411

17(4),5814

17,48918,9427,26417(4),592717,44217,43217,41527,26517(2),461

17,49217,41417,52117,52317,52417,48617,48617(2),461

17,442

27,24517,49417,510

17,49217,46921(3),5370

27,681

Fieser

5,195

11,254

5,422

1,713

1,882

TABLE 9. cont'd

Name Formula

2,3-Pyridenedicarboxylic3,4-PyridinedicarboxylicSuccinic4-Sulfo-1,8-naphthalicTetrabromophthalicTetrachlorophthalicTetrafluorophthalic1,2,3,6-Tetrahydrophthalic, cis-3,4,5,6-Tetrahydrophthalic3,3-Tetramethy leneglutaricTetrapropenylsuccinic (isomers)Trimellitic2-(Triphenylphosphoranylidene)-

succinic

9.2. DIANHYDRIDES

Benzene-1,2,4,5-tetracarboxylicBenzophenone-

3 3 ',4,4'-tetracarboxylicBicyclo[2.2.2.]oct-7-ene-

2,3,5,6-tetracarboxylicBiphenylene-3,3',4,4'-

tetracarboxylicCyclobutanetetracarboxylicCyclopentane-1,2,3,4-

tetracarboxylic, cis,cis-DiethylenetriaminepentaaceticEthylenediaminetetraacetic4,4'-(HeXaSuOrOiSOPrOPyUdBnC)

diphthalicNaphthalene-1,4,5,8-tetra-

carboxylicPery lene-3,4,9,10-tetracarboxylicTetrahydrofuran-2,3,4,5-tetra-

carboxylic

TABLE 10. BUTADIENES

C7H3NO3

C7H3NO3

C4H4O3

C12H6O6SC8Br4O3

C8Cl4O3

C8F4O3

C8H8O3

C8H8O3

C9H1 2O3

C16H26O3

C9H3ClO4

C22H17O3P

C1 0H2O6

C1 7H6O7

C1 2H8O6

C1 6H6O6

C8H4O6

C9H6O6

C1 4H1 9N3O8

C1 0H1 2N2O6

C1 9H6F6O6

C1 4H4O6

C2 4H8O6

C8H4O7

Name Formula

10.1. 1,2-BUTADIENES

1,2-Butadiene- , 4-Bromo-- , 4-Chloro-- , 4-Hydroxy-- , 4-Iodo-- , 3-Methyl-

10.2. 1,3-BUTADIENES

1,3-Butadiene- , 2-Bromo-- , 1-Chloro-- , l-Chloro-2-methyl-- , l-Chloro-3-Methyl-- , 2-Chloro-- , 2-Chloro-3-methyl-- , 1,2-Dichloro-- , 2,3-Dichloro-

H2C=C=CHCH3

H2C=C=CHCH2BrH2C=C=CHCH2ClH2C=C=CHCH2OHH2C=C=CHCH2IH2C=C=C(CH3),

H2C=CHCH=CH2

H2C=CBrCH=CH2

HCCl=CHCH=CH2

HCCl=C(CH3)CH=CH2

HCC1=CHC(CH3)=CH2

H2C=CClCH=CH2

H2C=CC1C(CH3)=CH2

H C C I = C C I C H = C H 2

H2C=CClCCl = CH2

CAS RegistryNumber

699-98-94664-08-8

108-30-571501-16-1

632-79-1117-08-8652-12-0935-79-5

2426-02-05662-95-3

26544-38-71204-28-0906-65-0

89-32-72421-28-5

1719-83-1

2420-87-3

4415-87-66053-68-5

23911-26-423911-25-3

1107-00-2

81-30-1

128-69-825774-69-0

CAS RegistryNumber

590-19-2

598-25-4

106-99-0

126-99-8

MoI. wt.

149.11149.11100.07316.34463.72285.90220.08152.15152.15168.19266.38210.57360.35

218.12

322.23

248.19

294.22

196.11210.14

357.32256.22444.25

268.18

392.32212.11

MoI. wt.

54.09133.0088.5470.09

179.9968.12

54.09133.0088.54

102.57102.5788.54

102.57122.98122.98

Boilingpoint (0C)

126

371

186/15150/3

397

Boilingpoint (0C)

1111088

12713041

- 442/165

681071005993

63/10598

Meltingpoint (0C)

13876

119

275256

95987265

67167(d)

283220

>300

300

>300225(d)

183190(d)

244

>300

>300223

Meltingpoint (0C)

- 1 3 6

- 1 4 8

- 1 0 9

Density(at 2O0C)

1.005

Density(at 2O0C)

0.6521.42550.98910.91641.71290.694

0.650/- 61.3970.9610.97100.95430.95830.95931.19911.1829


1.4790


1.4205/1.31.52481.47751.47591.57091.4190

1.4292/ - 2 51.49881.47091.47921.47191.45831.46861.49601.4890

Flashpoint (0C)

>110

162

Flashpoint (0C)

- 2 3

RTECSNumber

WN0875000

TI3350000TI3450000

GW5775000

WN1300000

DB9300000

QK3695000

RTECSNumber

EI9275000

EI9625000

R and S

1(2),2547K1(2),2547L1(1),835Al(2),2203F1(2),1959E1(2),1959D

1(1),835L1(1),837M1(1),839J

1(2),1981E

1(2),1959K1(21),1957L

1(1),837H

1(1),837G

1(1),841B1(1),841A1(2),1957N

1(2),1961F

1(2),1961G

Rand S

1(1),27B

1(1),27D

FT-NMR

1(3),336A1(3),336B1(1),1174B

1(2),1329A1(1),1177B1(1),1182A

1(2),1353Bl(2),1680C

l(l),1180B

l(l),1180A

1(1),1185A1(2),1327C

FT-NMR

1(1),35C

1(1),36B

FT-IR

1(2),795B

1(1),715Al(2),501D1(2),333D1(2),333C

1(1),717B1(1),719B1(1),721C

1(2),351Bl(2),550D

1(2),335A1(2),333B

1(1),716C

1(2),336B

1(2),336C

FT-IR

l(l),30C

Merck

11,8841

Merck

11,1500

Beilstein

27,26127,261

17,407

17,48517,48417(5),ll,26017,46217,46117,23717(5),ll,105

19,196

19,196

Beilstein

1(4),975

1,252

1,249

Fieser

4,468

15,300

Fieser

TABLE 10. cont'd

Name Formula

- , 2,3-Dimethyl-- , 2-Fluoro-- , Hexachloro-- , Hexafluoro-- , 2-Iodo-- , 2-Methyl-

TABLE 11. BUTENES

H2C=C(CH3)C(CHs)=CH2

H2C=CFCH=CH2

C C I 2 = C C I C C I = C C I 2

CF2=CFCF=CF2

H2C=CICH=CH2

H2C=C(CH3)CH=CH2

Name Formula

11.1. 1-BUTENES

1-Butene- , 4-Bromo-- , 2,3-Dimethyl-- , 3,3-Dimethyl-- , 2-Methyl-- , 3-Methyl-

11.2. 2-BUTENES

2-Butene, cis-2-Butene, trans-1,4-Dihydroxy-, cis-2,3-Dimethyl-2-Methyl-

TABLE 12. EPOXIDES

H2C=CHCH2CH3

H2C=CHCH2CH2BrH2C=C(CH3)CH(CH3),H2C=CHC(CH3)2CH3

H2C=C(CH3)CH2CH3

H2C=CHCH2(CH3)2

CH3CH=CHCH3

CH3CH=CHCH3

H2C(OH)CH = CHCH2(OH)(CH3)2C = C(CH3)2

(CH3)2C=CHCH3

Name Formula

12.1. MONOEPOXIDES CH2(-O-)CHR

Allylglycidyl ether2-Biphenylyl glycidyl ethern-Butyl glycidyl etherr-Butyl glycidyl ether4-f-Butylphenyl glycidyl ether4-Chlorophenyl glycidyl etherCyclohexene oxideCyclooctene oxideCyclopentene oxideEpibromohydrinEpichlorohydrinEpifluorohydrin1,2-Epoxybutane, trans-1,2-Epoxydecane1,2-Epoxydodecane1,2-Epoxyhexadecane1,2-Epoxyhexane2,3-Epoxynorbornane, exo-1,2-Epoxyoctadecane2,3-Epoxypropyl benzeneiV-(2,3-Epoxypropyl)phthalimide1,2-EpoxytetradecaneEthylene oxide2-Ethylhexyl glycidyl etherFurfuryl glycidyl etherGlycidol

-CH2OCH2CH=CH2

-CH 2OC 6H 4C 6H 5

-CH2O(CH2)3CH3

-CH2OC(CH3)3

-CH2OC6H4C(CHs)3

-CH2OC6H4ClC6H10OC8H14OC5H8O-CH2Br-CH2Cl-CH 2 FCH3CH(-O-)CHCH3

-(CH2)7CH3

-(CH2)9CH3

-(CH2) 13CH3

-(CH2)3CH3

C7H10O-(CH2)1 5CH3

-CH 2 C 6 H 5

-CH 2NC 8H 4O 2

-(CH2)nCH3

- H-CH2OCH2CH(CH2CH3)(CH2)3CH3

-CH2OCH2C4H3O-CH2OH

CAS RegistryNumber

513-81-5

87-68-3685-63-2

78-79-5

CAS RegistryNumber

106-98-95162-44-7

563-78-0558-37-2563-46-2563-45-1

590-18-1624-64-6

6117-80-2563-79-1513-35-9

CAS RegistryNumber

106-92-37144-65-22426-08-67665-72-73101-60-82212-05-7

286-20-4286-62-4285-67-6

3132-64-7106-89-8503-09-3

21490-63-12404-44-62855-19-87320-37-81436-34-63146-39-27390-81-04436-24-25455-98-13234-28-4

75-21-82461-15-65380-87-0

556-52-5

MoI. wt.

82.1572.08

260.76162.03179.9968.12

MoI. wt.

56.11135.0184.1684.1670.1470.14

56.1156.1188.1184.1670.14

MoL wt.

114.14266.28130.19130.19206.29184.6298.15

126.2084.12

136.9892.5376.0772.11

156.27184.32240.43100.16110.16268.49134.18203.20212.38

44.05186.30154.1774.08

Boilingpoint (0C)

6812

2157

11234

Boilingpoint (0C)

- 69956413120

41

131/127336

Boilingpoint (0C)

154120/0.1

165151

166/4

12955/5

1021351168554

94/15124/15176/12

119

137/0.599/17

95/10.410.7

61/0.3103/1161/15

Meltingpoint (0C)

- 7 6

- 2 0- 1 3 2

- 1 4 6

Meltingpoint (°C)

- 1 8 5

- 1 5 8- 1 1 5- 1 3 7- 1 6 8

- 1 3 9- 1 0 5

7- 7 5

- 1 3 4

Meltingpoint (0C)

31

32

54

- 4 0- 5 7

21

12334

99

- 1 1 1

Density(at 200C)

0.7260.8431.6651.553/-20

1.4220

Density(at 200C)

1.3300.6840.6530.6500.627/0

1.0700.7080.662

Density(at 20°C)

0.962

0.9100.9171.038

0.970

0.9641.6011.1831.0670.8040.8400.8440.8460.831

1.020

0.8450.891/40.8911.1221.117


1.43901.4001.55501.378/-201.56161.4220


1.39621.46251.38901.37601.37801.3640

1.3931/-251.3848/-251.47801.41201.3870


1.4330

1.41901.41701.51501.54501.4520

1.43401.48201.43801.36801.37301.42901.43601.44601.4060

1.5230

1.44081.3597/71.43401.48101.4330

Flashpoint (0C)

- 2 2

None

- 5 4

Flashpoint (0C)

9- 1 8- 2 9

< - 3 5- 5 7

37

126- 1 7- 4 6

Flashpoint (0C)

57

5643

10210727561056344

- 2 778

105931610

>11082

>110

9710281

RTECSNumber

EJ0700000

NT4037000

RTECSNumber

EM4970000

RTECSNumber

RR0875000

TX4200000RR0475000TX4250000TX5600000RN7175000

RN8935000TX4115000TX4900000TZ3325000EK3855000

JR2450000ML9450000MO3630000RB7176000

DA0178000TI4950000

KX2450000TZ33OOOOOLU1423000UB4375000

R and S

1(1),27F

l(l),105H

1(1),27E

Rand S

1(1),15C1(1),97E1(1),23I1(1),23B1(1),23G1(1),23A

1(1),19A1(1),19B1(1),153A1(1),25H1(1),25D

Rand S

1(1),251C1(1),1253D1(1),249K1(1),251A1(1),1253A1(1),1253B1(1),251L1(1),251M1(1),251K1(1),247L1(1),247I1(1),247H1(1),245F1(1),245J1(1),245K1(1),247A1(1),245H1(1),253D1(1),247B1(1),1251Dl(2),2083B1(1),245L1(1),245A1(1), 251B1 (2),2319J1(1),249B

FT-NMR

1(1),37A

l(l),150A

1(1),36C

FT-NMR

1(1),136C1(1),31B1(1),29Bl(l),30C1(1),29A

1(1),221A1(1),35B1(1),34A

FT-NMR

1(1),374A1(2),225A1(1),373A1(1),373B1(2),224A1(2),224B1(1),376C1(1),377A1(1),376Bl(l),370B1(1),369B1(1),369A1(1),364C1(1),365C1(1),366A1(1),366C

1(1),378B1(1),367Al(2),220C1(2),1461C1(1),366B

1(1),373C1(3),17Cl(l),370C

FT-IR

1(1),32A

l(l),102A

l(l),30D

FT-IR

1(1),94B1(1),22A1(1),25B1(1),21B1(1),21C

1(1),146C1(1),25A1(1),21D'

FT-IR

1(1),233Dl(l),1065C

1(1),232Cl(l),1065Bl(l),1064E1(1),235A1(1),235B1(1),234D1(1),232A1(1),231D1(1),231C1(1),229Bl(l),230Al(l),230Bl(l),230D1(1),229A1(1),235D1(1),231B

l(2),408Al(2),230C

1(1),232D

1(1),232B

Merck

11,3228

11,5087

Merck

11,1513

11,64411,644

Merck

)

11,3563

11,3758

11,4385

Beilstein

1(3),991

1,250

1,252

Beilstein

1,2031(D,841(3),8161,2171,2111,213

11,151411,15141(2),5671,2181,211

Beilstein

17(3),98817(3),988

17,21

17,2117,2117,6

17(3),4917,1817(3),13617,2017,86

17(3), 14017,51

17(3), 13917,4

17(5),34717,104

Fieser

1,276

10,195

Fieser

1,2051,205

Fieser

5,290

8,150

TABLE 12. cont'd

Name Formula

3-Glycidoxypropyl trimethoxy- -CH2O(CH2)SSi(OCHs)3

silane(R)-(-)-Glycidyl Butyrate -CH2OC(O)CH2CH2CH3

Glycidyl isopropyl ether -CH2OCH(CH3)2

Glycidyl methacrylate (see Methacrylates)GIy cidy ltrimethy lammonium -CH2N(CH3)3C1

chloride, (70% aq. solution)Hexafluoropropylene oxide F2C(-O-)CFCF3

4-Methoxyphenyl glycidyl ether -CH2OC6H4OCH3

a-Pinene oxide CioH^OPropylene oxide -CH 3

Styrene oxide -C 6HsTetracyanoethylene oxide (NC)2C(-O-)C(CN)2

1,1,2,2-Tetrafluoroethyl glycidyl -CH2OCF2CHF2

etherVinylethylene oxide -CH=CH2

12.2. DIEPOXIDES CH2(-O-)CHRCH(-O-)CH2

Bis(3,4-epoxycyclohexylmethyl) C6H9(-O-)CH2OC(O)(CH2)4C(O)OCH2C6H9(-O-)adipate

1,3-Butadiene diepoxide CH 2(-O-)CHCH(-O-)CH 2

1,4-Butanediol diglycidol ether -CH2O(CH2)4OCH2-1,2,5,6-Diepoxycyclooctane CgHi2O2

1,2,7,8-Diepoxyoctane - ( C H 2 ) 4 -3,4-Epoxycyclohexylmethyl C6H9(-O-)CH2OC(O)C6H9(-O-)

3,4-epoxycyclohexane-carboxylate

Ethylene glycol digycidyl ether -CH2O(CH2)2OCH2-

TABLE 13. ETHYLENE HALIDES

Name Formula

Ethylene H2C=CH2

- , Bromo- (vinyl bromide) BrCH=CH2

- , Chloro- (vinyl chloride) ClCH=CH2

- , 1-Chloro-1-fluoro- ClCF=CH2

- , Chlorotrifluoro- ClCF=CF2

- , 1,1-Dibromo- (vinylidene Br2C=CH2

bromide)- , 1,2-Dibromo-, cis- BrCH=CHBr1,2-Dibromo-, trans- BrCH=CHBr- , 1,1-Dichloro- (vinylidene Cl2C=CH2

chloride)- , 1,2-Dichloro-, cis- ClCH=CHCl- , 1,2-Dichloro-, trans- ClCH=CHCl- , Tetrabromo- Br2C=CBr2

- , Tetrachloro- Cl2C=CCl2

- , Tetrafluoro- F2C=CF2

- , Tetraiodo- I2C=CI2

- , Tribromo- Br2C=CHBr- , Trichloro- Cl2C=CHCl

CAS RegistryNumber

2530-83-8

60456-26-04016-14-2

3033-77-0

428-59-12211-94-11686-14-2

75-56-996-09-3

3189-43-385567-21-1

930-22-3

3130-19-6

1464-53-52425-79-8

27035-39-82426-07-52386-87-0

2224-15-9

CAS RegistryNumber

74-85-1593-60-2

75-01-4

79-38-9

75-35-4

156-59-2156-60-5

127-18-4116-14-3513-92-8

79-01-6

MoI. wt.

236.34

144.17116.16

151.54

166.02180.20152.2458.08

120.15144.09174.10

70.09

366.46

86.09202.25140.18142.20252.31

174.20

MoI. wt.

28.05106.9662.5084.48

116.47185.86

185.86185.8696.94

96.9496.94

343.66165.83100.02531.64264.76131.39

Boilingpoint (0C)

120/2

90/19131

- 4 2

102/5034

194

143

65

57/25158/11

70/0.4240

112/4.5

Boilingpoint (0C)

- 1 0 416/750

-13 .4- 2 4- 2 9

92

11210831

6048

226121

- 7 6

16387

Meltingpoint (0C)

46

- 1 1 2- 3 7

3

- 3 7

Meltingpoint (0C)

- 1 6 9- 1 3 9- 1 5 4- 1 6 9- 1 5 7

- 5 3- 6

- 1 2 2

- 8 0- 5 0

56- 2 2

- 1 4 2192

- 8 5

Density(at 200C)

1.070

1.0180.924

1.129

0.9640.8301.054

1.380

0.870

1.149

1.1131.1001.1380.9971.170

1.118

Density(at 200C)

1.5170.911

2.178

2.24642.23081.213

1.2841.257

1.6231.1507/-2.9832.7081.463


1.4290

1.42801.4100

1.4780

1.46901.36601.5350

1.3490

1.4170

1.4930

1.43401.46101.46901.44501.4980

1.4630


1.43501.3700

1.54281.5501.4254

1.44811.4456

1.506040

1.6045/161.4760

Flashpoint (0C)

>110

8533

> 110

>11066

- 3 579

51

- 5 0

> 110

46>110

10598

118

> 110

Flashpoint (0C)

None- 61

- 9

66

None

None

RTECSNumber

VV4025000

TZ35OOOOO

BQ3480000

TZ3400000DA0176000TK4565000TZ2975000CZ9625000

EM7350000

MO 1880550

EJ8400000EJ5100000GX9627000RG9450000RN7750000

KH5780000

RTECSNumber

KU5340000KU8400000KU9625000

KV0525000

KV9275000

KV9420000KV9400000

KX3850000

KX4125000

KX4550000

Rand S

1(2),2973B

1(1),781E1(1),249J

1(1),249A1(1),1253C1(1),253B1(1),245B1(1),1251Al(l),1003F

1(1),247D

1(1),251E1(1),251I1(1),253E1(1),251F

1(1),251G

R a n d S

1(1),15A1(1),95B1(1),95A

l(l),103I

l(l),101B

l(l),101Dl(l),101E

l(l),103J

l(l),103K

l(l),103G

FT-NMR

1(3),667C

l(l),1088B1(1),372C

1(1),616B

1(2),224C1(1),377C1(1),363B1(2),219C1(1),1376C

1(1),367C

1(1),374B1(1),375C1(1),378C1(1),374C

1(1),375A

FT-NMR

1(3),17C1(1),133A

1(1),142B

1(1),143A1(1),134B

1(1),147C

FT-IR

1(2),1113D

l(3),306A

l(l),1065A1(1),237A1(1),228Bl(l),1063C

1(1),233A

1(1),234A1(1),234C1(1),235C1(1),234B

FT-IR

1(1),93A

1(1),98B

1(1),98A1(1),79D

l(l),101C

l(l),101B

Merck

11,7869

18(5),7,215

11,3621

Merck

11,3748

11,9898

11,9900

11,8611,86

11,9126

11,9151

11,9552

Beilstein

17(5),3,3417(3),988

18,583

17(3),20

5,15217,617,49

17(1),13

19,14

17(3),997

Beilstein

1,1801,1881,186

1(3),646

1,186

1,1881,188

1,187

1,195

1,187

Fieser

4,53

Fieser

1,1274

14,12712,175

11,552

TABLE 14. FUMARATE ACIDS/ESTERS

Formula ROC(O)CH=CHC(O)OR

Name R

Acid - H2-Bromo- HOC(O)CBr=CHC(O)OH2-Chloro- HOC(O)CCl=CHC(O)OH2-Chloro-, diethyl ester C H 3 C H 2 O C ( O ) C C I = C H C ( O ) O C H 2 C H 3

2-Chloro-, dimethyl ester C H 3 O C ( O ) C C I = C H C ( O ) O C H 3

Di-n-amyl ester -(CH2)4CH3

Diethyl ester -CH2CH3

Diisoamyl ester -CH2CH2CH(CH3)2

Diisobutyl ester -CH2CH(CH3)2

Diisopropyl ester -CH(CH3)2

2,3-Dimethyl- HOC(O)C(CH3)=C(CH3)C(O)OHDimethyl ester -CH3

Dinitrile- (fumaronitrile) NCCH=CHCNDiphenyl ester -C6H5Di-/z-propyl ester -CH2CH2CH3

2-Methyl- (mesaconic acid) HOC(O)C(CH3) = CHC(O)OH2-Methyl-, diethyl ester CH3CH2OC(O)C(CH3)=CHC(O)CH2CH3

2-Methyl-, dimethyl ester CH3OC(O)C(CH3)=CHC(O)OCH3

TABLE 15. ISOCYANATES

Formula OCNRNCO

Name R

1,3-Benzene diisocyanate - C 6 H 4 -1,4-Benzene diisocyanate - C 6 H 4 -1,3-Bis(isopropyl)benzene -C(CH3)2C6H4C(CH3)2-

a,oc'-diisocyanate1,4-Bis(isopropyl)benzene -C(CH3)2C6H4C(CH3)2-

a,a'-diisocyanate1,4-Butene diisocyanate - (CH 2 ) 4 -a-Chlorotoluene -C6H3(CH2Cl)-

2,4-diisocyanate1,4-Cyclohexylene diisocyanate, - C 6 H 1 0 -

trans-1,12-Dodecane diisocyanate -(CH2) 1 2 -1,6-Hexane diisocyanate -(CH2) 6 -Isopherone diisocyanate -C1 0H1S-

(isomers)4,4/-Methylenebis(cyclohexyl -(C6H10)CH2(C6H10)-

isocyanate) (isomers)4,4'-Methylenebis(2,6-di- -C6H2(CH2CH3)2CH2C6H2(CH2CH3)2-

ethylphenylisocyanate)

4,4/-Methylenebis(phenyliso- -C 6H 4CH 2C 6H 4 -cyanate)

2-Methylpentane 1,5-diisocyanate-CH2CH(CH3)(CH2)3 -1,8-Octane diisocyanate -(CH2)g-2,4-Toluene diisocyanate -C6H3(CH3)-

CAS RegistryNumber

110-17-8

623-91-6

624-49-7764-42-1

498-24-8

CASRegistryNumber

123-61-5104-49-4

2778-42-9

2778-41-8

4538-37-851979-57-8

7517-76-2

13879-35-1822-06-0

4098-71-9

5124-30-1

105442-35-1

101-68-8

34813-62-210124-86-4

584-84-9

MoI. wt.

116.07194.98150.52206.63178.57256.33172.18256.33228.29200.24144.13144.1378.07

268.27200.24130.10

MoI. wt.

160.13160.13244.30

244.30

140.14208.60

166.18

252.36168.20222.29

262.35

362.48

250.26

168.20196.25174.16

Boilingpoint (0C)

200(d)

136/19224

162/7217

166/11170/160

226

192186

219/14110/5205(d)

186.21

158.16

Boilingpoint (0C)

121/25260

157/10

150/3

102/14153/11

168/3255

158/15

200/5

156/15120/10

Meltingpoint (0C)

299(s)186193

2

24110396

162

204229

204

Meltingpoint (0C)

5098

- 1 0

72

60

56

43

21

Density(at 200C)

1.18801.2900.96811.0520.96550.9760

0.9416

1.01291.466


1.4571

1.44961.44101.44791.4432

1.4349

1.4439

1.0453

1.0914

Flashpoint (0C)

94

1.4488

1.4512

RTECSNumber

LS9625000

EM5950000

EM6125000LT2300000

OX5075000

R and S

1(1),553A

1(1),725M

1(1),725L1(1),993A

1(1),553C

FT-NMR

1(1),787B

1(1),993C

1(1),993Bl(l),1360B

1(1),788A

FT-IR

l(l),502D

1(1),645A

1(1),644D1(1),844A

l(l),503B

Merck

11,4200

11,5806

Beilstein

2,737

2,742

2,7412(l),302

2,763

Fieser

5,319

Density(at 200C)

1.05

1.1051.362

0.9401.0401.049

1.066

1.180

1.0491.0071.214


1.5960

1.45901.45201.4840

1.4970

1.45501.45501.5680

Flashpoint (0C)

>110>110

153

>93

106>110

>110140

>110

>110

>110

>110> 110> 110

RTECSNumber

NR0150000CZ6150000CY8480000

GU9642500

MO1740000NQ9370000

NQ9250000

NQ9350000

CZ630000

Rand S

1(2),2165G1(2),2165H

l(l),1023F1(2),2169H

l(l),1025A

l(l),1023Hl(l),1023Gl(l),1023J

l(l),1025B

1(2),2169K

1(2),2163D

l(l),1023I

1(2),2169F

FT-NMR

l(l),1404B1(2),1572A

l(l),1406A

l(l),1405Al(l),1404Cl(l),1405C

1(2),1572C

l(l),1405B

FT-IR

1(3),1432D

1(1),871A

1(2),478B

Merck

11,9456

Beilstein

13,5013,105

4(3),57813(4),245

13(3),12

4(3),6244(2),711

13(4),33

13(3),461

4(3),61413,138

Fieser

1,117

TABLE 16. LACTAMS

Name Formula

y-Butyrolactam (2-pyrrolidinone) -C(O)(CH2)3NH-s-Caprolactam -C(O)(CH2)5NH-12-Dodecanolactam -C(O)(CH2) n NH-7-Heptanolactam -C(O)(CH2)6NH-P-Propiolactam -C(O)CH2CH2NH-5-Valerolactam -C(O)(CH2)4NH-

TABLE 17. LACTONES

Name Formula

y-Butyrolactone -C(O)(CH2)^O-8-Caprolactone -C(O)(CH2)5O-p-Propiolactone -C(O)(CH2)2O-5-Valerolactone -C(O)(CH2)4O-

TABLE 18. MALEATE ACIDS/ESTERS

Formula ROC(O)CH=CHC(O)OR

Name R

Acid -H2-Chloro- HOC(O)CCl=CHC(O)OH2-Chloro-, diethyl ester C H 3 C H 2 O C ( O ) C C I = C H C ( O ) O C H 2 C H 3

2-Chloro-, dimethyl ester C H 3 O C ( O ) C C I = C H C ( O ) O C H 3

Diallyl ester -CH2CH=CH2

Di-n-amyl ester -(CH2)4CH3

Di-«-butyl ester -(CH2)3CH3

2,3-Dichloro- HOC(O)CC1=CC1C(O)OHDiethyl ester -CH2CH3

2,3-Dihydroxy- HOC(O)C(OH)=C(OH)C(O)OHDiisoamyl ester -CH2CH2CH(CH3)2

Dimethyl ester -CH3

Diphenyl ester -C6H5Di-n-propyl ester -CH2CH2CH3

2-Methyl-, cis- (citraconic acid) HOC(O)C(CH3 )=CHC(O)OH2-Methyl-, diethyl ester, cis- CH3CH2OC(O)C(CH3)=CHC(O)OCH2CH3

2-Methyl-, dimethyl ester, cis- CH3OC(O)C(CH3)=CHC(O)OCH3

TABLE 19. PROPENES

Name Formula

Propene H2C=CHCH3

- , 1-Bromo-, cis- BrCH=CHCH3

- , 1-Bromo-, trans- BrCH=CHCH3

- , 2-Bromo- H2C=CBrCH3

- , 1-Chloro-, cis- ClCH=CHCH3

- , 1-Chloro-, trans- ClCH=CHCH3

- , 2-Chloro- H2C=CClCH3

- , l-Chloro-2-methyl- C1CH=C(CH3)2

(isocrotyl chloride)- , 3-Chloro-2-methyl- H2C=C(CH3)CH2Cl

(methallyl chloride)- , 1,1-Dichloro- Cl2C=CHCH3

CAS RegistryNumber

616-45-5105-60-2947-04-6673-66-5930-21-2675-20-7

CAS RegistryNumber

96-48-0502-44-357-57-8

542-28-9

CASRegistryNumber

110-16-7

999-21-3

105-76-0

141-05-9

624-48-6

498-23-7

CAS RegistryNumber

115-07-1590-13-6590-15-8557-93-7

557-98-2513-37-1

563-47-3

563-58-6

MoI. wt.

85.11113.16197.32127.1971.0899.13

MoI. wt.

86.09114.1472.06

100.12

MoI. wt.

116.07150.52206.63178.57196.20256.33228.29184.97172.18148.07156.33144.13268.27200.24130.10186.21

MoI. wt.

42.08120.98120.98120.9876.5376.5376.5390.55

90.55

110.97

Boilingpoint (0C)

245137/10

149/10106/15

256

Boilingpoint (0C)

20497/15

16259/0.5

Boilingpoint (°C)

235107

110/4161/10

281

225

157/13204

226/15126/12

230158.16

Boilingpoint (0C)

- 4 8586448333722.568

71

76

Meltingpoint (0C)

2469

151367539

Meltingpoint (0C)

- 4 5

- 3 3

Meltingpoint (0C)

141110

- 4 7

120- 1 0155

93

90

211

Meltingpoint (0C)

- 1 8 5

-125-135- 9 9

- 1 3 9

- 8 0

Density(at 2O0C)

1.120

Density(at 200C)

1.1201.0301.1461.079

Density(at 200C)

1.590

1.17411.2771.0730.97410.988

1.064

0.97141.152

1.0245

1.0491

Density(at 2O0C)

1.4231.4081.3620.93470.93510.8990.920

0.917

1.169


1.4870


1.43601.46301.41201.4580


1.46901.44751.4452

1.4410

1.44591.4410

1.4433

1.44681.9491


1.45451.45301.4361.40551.40541.39391.4225

1.4278

1.4450

Flashpoint (0C)

>110

>110

> 110

Flashpoint (0C)

9810970

100

Flashpoint (0C)

>110

>110

93

91

1.4473

Flashpoint (0C)

- 3 4- 1 5

4

- 3 4- 1

- 1 2

0

RTECSNumber

UY5715000CM3675000CL6940000CN4810000

TO0110000

RTECSNumber

LU3500000MO8400000RQ7350000

RTECSNumber

OM9625000

ON0700000

ON0875000

ON1225000

EM6300000

GE6650000

RTECSNumber

UC6740000

UC7085000

UC7200000UC8045000

UC8050000

UC8290000

Rand S

1(1),923B1(1),927G1(1),929A1(1),927M1(1),923A1(1),927E

Rand S

l(l),803J1(1),819El(l),803A1(1),815A

Rand S

l(l),5510

1(1),725K

1(1),725J

1(1),725I

1(1),725H

1(1),553B

R and S

1(1),15B1(1),95F1(1),95C1(1),95H

1(1),95D1(1),97I

1(1),97J

l(l),101G

FT-NMR

1(1),1285B1(1),1293B1(1),1296A1(1),1295B1(1),1285A1(1),1292C

FT-NMR

1(1),1127A1(1),1161C

1(1),1152A

FT-NMR

1(1),787A

1(1),993A

1(1),992C

1(1),992B

1(1),992A

1(1),787C

FT-NMR

1(1),134A

1(1),134C

1(1),133B1(1),137C

1(1),138A

1(1),144A

FT-IR

1(1),788D1(1),792B1(1),794A1(1),793C

1(1),791D

FT-IR

1(1),697D1(1),699B

l(l),704D

FT-IR

l(l),503A

1(1),644C

1(1),644B

l(l),503C

FT-IR

1(1),96B

1(1),96A1(1),97A

1(1),96D

1(3),138D

Merck

11,802711,1762

Merck

11,1596

11,7832

Merck

11,5585

11,3113

11,2323

Merck

11,7862

11,2147

11,2148

Beilstein

21,23621(2),216

21,24221(3),314121,238

Beilstein

17,23417(2),29017(l),13017,235

Beilstein

2,748

2(3), 1926

2(3),1925

2,751

2,751

2,768

Beilstein

1,196l(3),7101(4),7541,200

1,1981,209

1,209

1,199

Fieser

Fieser

1,101

1,957

Fieser

Fieser

4,236

TABLE 19. cont'd

Name

- , 1,2-Dichloro-- , Hexafluoro-- , 2-Methyl- (isobutylene)- , 1,1,2-Trichloro-- , 1,1,3-Trichloro-- , 1,2,3-Trichloro-- , 3,3,3-Trichloro-

TABLE 20. STYRENES

Name

Styrene- , 4-Acetoxy-- , 2-Amino-- , 4-Amino-- , 4-Benzyloxy-3-methoxy-- , 3,5-Bis(trifluoromethyl)-a-Bromo-p-Bromo-- , 2-Bromo-- , 3-Bromo-- , 4-Bromo-- , 4-terf-Butyl-- , 4-Carboxy-a-Chloro-(3-Chloro-- , 2-Chloro-- , 3-Chloro- , 3-Chloromethyl

(3-vinylbenzyl chloride)- , 4-Chloro-- , 4-Chloromethyl-- , 4-Chloro-a-Methyl-- , 2-Cyano-- , 3-Cyano- , 4-Cyano-- , 2,5-Dichloro-- , 2,6-Dichloro-- , 3,4-Dichloro-- , a,p-Difluoro-- , 1,2-Difluoro-- , 2,6-Difluoro-- , 1,3-Diisopropenyl benzene- , 3,4-Dimethoxy-- , a,2-dimethyl-- , 2,4-Dimethyl-- , 2,5-Dimethyl-- , Divinyl-, (isomers)- , 4-Ethoxy-- , 2-Ethyl-- , 4-Ethyl-- , 3-Iodo-- , 2-Fluoro-- , 3-Fluoro-- , 4-Fluoro-- , 2-Hydroxy-- , 3-Hydroxy-- , 4-Hydroxy-- , 4-Isopropyl-

Formula

CICH=CClCH3

F2C=CFCF3

H2C=C(CH3)2

Cl2C=CClCH3

Cl2C=CHCH2ClC I C H = C C I C H 2 C I

H2C=CHCCl3

Formula CH2=CHR

R

- C 6 H 5

-C6H4OC(O)CH3

-C 6 H 4 NH 2

-C 6 H 4 NH 2

-C6H3(OCH3)OCH2C6H5

-C 6H 4(CF 3) 2

H2C=CBrC6H5

HCBr=CHC6H5

-C 6H 4Br-C 6H 4Br-C 6H 4Br-C 6H 4C(CH 3) ,-C 6H 4CO 2HH2C=CClC6H5

HCCl=CHC6H5

-C6H4Cl-C 6H 4Cl-C6H4CH2Cl

-C 6H 4Cl-C6H4CH2ClH2C=C(CH3)C6H4Cl-C 6 H 4 CN-C 6H 4CN-C 6H 4CN-C 6 H 3 Cl 2

-C 6 H 3 Cl 2

-C 6 H 3 Cl 2

HCF=CFC6H5

-C 6 H 3 F 2

- C 6 H 3 F 2

C6H4(C(CH3)=CH2)2

-C 6H 3 (OCH 3 ) ,H2C=C(CH3)C6H4CH3

-C 6 H 3 (CH 3 ) ,-C 6 H 3 (CH 3 ) ,C6H4(CH=CH2)2

-C6H4OCH2CH3

-C 6H 4CH 2CH 3

-C6H4CH2CH3

-C 6 H 4 I-C 6 H 4 F-C 6 H 4 F-C 6 H 4 F-C 6H 4OH-C 6H 4OH-C 6H 4OH-C6H4CH(CH3) ,

CAS RegistryNumber

116-15-4115-11-7

CASRegistryNumber

100-42-52628-16-23867-18-31520-21-4

55708-65-1349-59-7

98-81-7103-64-0

2039-88-52039-86-32039-82-91746-23-21075-49-6

2039-87-42039-85-2

57458-41-0

1073-67-21592-20-71712-70-5

5338-96-53435-51-61123-84-8

28469-92-32039-83-0

366-37-0

3748-13-86380-23-0

26444-18-82234-20-02039-89-61321-74-05459-40-57564-63-83454-07-7

394-46-7350-51-6405-99-2

2055-40-5

MoI. wt.

110.97150.0256.11

145.42145.42145.42145.42

MoI. wt.

104.15162.19119.18119.18240.30240.15183.05183.05183.05183.05183.05160.26148.16138.60138.60138.60138.60152.62

138.60152.62152.62129.16129.16129.16173.04173.04173.04140.03140.03140.03158.25164.20132.21132.21132.21130.19148.21132.21132.21233.05122.14122.14122.14120.15120.15120.15146.22

Boilingpoint (0C)

77- 2 8

- 7118131142114

Boilingpoint (0C)

145260

104/8249

5160/20

69/4111/20

21074/3

212219

199199188

62/6229

192229

53/0.1583/2.692/374/388/876/3

88/6090/4559/51

231120/1054/1170/1171/10

59/1191193

67/1530/4

30/14108/15

115

204

Meltingpoint (0C)

- 1 5 3- 1 4 0

Meltingpoint (0C)

- 3 07

23

7- 4 4

7- 5 3

4.5- 3 7143

- 2 3

- 6 3

- 1 6

- 1 5

- 6 4- 3 5

- 1 2 7- 5 0

73

29

73.5- 4 5

Density(at 200C)

1.1818

1.3821.4031.4141.369

Density(at 200C)

0.90591.0601.6081.014

1.3341.4101.4271.4601.4061.4000.875

1.1016/181.1095/151.0801.0901.074

1.1551.0831.065

1.083

1.267

1.1300.9251.1090.8940.9060.9040.9140.9900.89550.8925

1.0251.0251.0241.0609/181.0468/35

0.885


1.4471

1.48271.49501.50201.4827


1.54701.5380

1.6267

1.42501.58801.60701.59271.58911.59401.5260

1.56121.56481.56481.5613

1.56621.57401.55501.57561.56301.575

1.5740

1.5061

1.49901.55701.57101.51501.53901.53911.54701.54981.53511.53761.63901.52001.51751.51561.5783/271.5804/31

1.5289

Flashpoint (0C)

48

FlashPQint (0C)

3187

>11012287

10285677580

5862

105

6010474

104

71

3091

>1104360636487

352926

RTECSNumber

UD0350000UD0890000

UD1928500

RTECSNumber

WL3675000SL3784000

WL3840000WL385OOOO

WL4160000

CY8535OOO

WL4450000WL4460000CZ9370000

R and S

l(l),105A1(1),23F

l(l),103H

R and S

1(1),1139A1(2),1927F

1(1),1237M1(1),1213Al(l),1203Fl(l),1203Hl(l),1203Ll(l),1205Dl(l),1205H

1(2),1789D

l(l),1203Kl(l),1205C

l(l),1205F

l(l),1205G

l(l),1205J

1(1X120511(1),1139L1(1),1243D

1(1),1141D1(1),1141E1(1),1141B1(1), 1243 A

l(l),1203Jl(l),1205Bl(l),1205E

FT-NMR

1(1),148A

FT-NMR

1(2),23A1(2),1287C

1(2),197C1(2),155A

1(2),136C1(2),138A1(2),139C1(2),141A

l(2),1076A

1(2),137C1(2),139B

1(2), 140B

1(2), 140C

1(2),141C

1(2),141B1(2),26Bl(2),208C

1(2),27C1(2),28A

1(2),137B1(2), 139 A1(2), 140A

FT-IR

1(3),143C1(3),28B

1(3),142A

FT-IR

1(1),945B

l(l),1053A

l(l),1017Bl(l),1018A1(3),195Bl(l),1019C

1(2),194D

l(l),1017Dl(l),1018C

l(l),1019B

l(l),1018D

l(l),1019D

1(1),947Cl(l),1053D

1(3),984B

l(l),1081Bl(l),1019A

Merck

11,5024

Merck

11,8830

Beilstein

1(3),6971,207

l(3),707

Beilstein

5,4746(3),2387

12,1187

5(4), 13865,4775,4775(3X11765(3),11765(2),3675(3X12549(3),2755

5(2),367

6,954

5,4915,491

6,561

5(3),11715(3),1171

Fieser

Fieser

TABLE 20. cont'd

Name

- , 2-Methoxy-- , 3-Methoxy-- , 4-Methoxy-- , 2-Methoxy-4-hydroxy-a-Methyl-- , 2-Methyl-- , 3-Methyl-- , 4-Methyl-- , P-Nitro-- , 2-Nitro-- , 3-Nitro-- , 4-Nitro-- , Pentabromo-- , Pentafluoro-- , 4-Phenoxy-- , 4-Phenyl-- , 4-Sulfonic acid, sodium salt- , 2-Trifluoromethyl-- , 3-Trifluoromethyl-- , 4-Trifluoromethyl-- , 2,4,6-Trimethyl-

Formula CH2=CHR

R

-C 6H 4OCH 3

-C 6H 4OCH 3

-C 6H 4OCH 3

-C6H3OCH3(OH)H2C=C(CH3)C6H5

-C 6 H 4 CH 3

-C 6 H 4 CH 3

-C 6 H 4 CH 3

HC(NO2)=CHC6H5

-C 6 H 4 NO 2

-C 6 H 4 NO 2

-C 6 H 4 NO 2

-C 6Br 5

- C 6 F 5

-C 6 H 4 OC 6 H 5

-C 6 H 4 C 6 H 5

-C6H4SO3Na-C 6 H 4 CF 3

-C 6 H 4 CF 3

-C 6 H 4 CF 3

-C 6 H 2 (CH 3 ) ,

TABLE 21. VINYLFUNCTIONAL

Name

21.1. ARYLH2C=CHR

9-AnthraceneBenzene (see Styrene)2-Naphthalene2-Pyridine3-Pyridine4-Pyridine2-Quinoline

Formula

- C I 4 H Q

-C 1 0 H 7

-C 5 H 4 N-C 5 H 4 N-C 5 H 4 N-C 9 H 6 N

21.2. ESTERS H2C=CHOC(O)R

AcetateAcrylate (see Acrylates)AUyI adipateBenzoateBromoacetate4-tert-Buty\ benzoateButyrateCarbonateChloroacetate2-ChlorobenzoateChloroformateCinnamateCrotonateDecanoateDodecanoate2-EthylhexanoateFormate2-FuroateHexadecanoate (palmitate)Hexanoate (caproate)Maleate

-CH 3

-(CH2)4C(O)OCH2CH=CH2

- C 6 H 5

-CH2Br-C6H4C(CH3)3

-(CH2)2CH3

-OCH=CH2

-CH2Cl-C6H4Cl-Cl-CH=CHC6H5

-CH2CH=CHCH3

-(CH2)8CH3

-(CH2) K)CH3

-CH(CH2CH3)(CH2)3CH3

- H-C 4 H 3 O-(CH2) 14CH3

-(CH2)4CH3

-CH=CHC(O)OCH=CH2

CASRegistryNumber

612-15-7626-20-0637-69-4

7786-61-098-83-9

611-15-4100-80-1622-97-9

586-39-0100-13-0

53097-59-9653-34-9

4973-29-92350-89-22695-37-6

395-45-9402-24-4402-50-6769-25-5

CAS RegistryNumber

2444-68-0

827-54-3100-69-6

1121-55-7100-43-6772-03-2

108-05-4

56860-96-9769-78-8

5309-70-615484-80-7

123-20-6872-36-6

2549-51-115721-27-45130-24-53098-92-8

14861-06-44704-31-82146-71-6

94-04-2692-45-5

1917-10-8693-38-9

3050-69-9

MoI. wt.

134.18134.18134.18150.18118.18118.18118.18118.18149.15149.15149.15149.15498.66194.10196.25180.25206.20172.15172.15172.15146.24

MoI. wt.

204.27

154.21105.14105.14105.14155.20

86.09

212.25148.16165.0204.27114.1486.05

120.54182.61106.51174.20112.13198.31226.36170.2572.06

138.12282.47142.20168.15

Boilingpoint (0C)

61.3144/2

204224167171170172250

90/3.5120/10

139

61/4055/1265/40

209

Boilingpoint (0C)

62/10

80/2968/1563/1571/0.5

72

135/9203

50/10111/2

116162134

68/735125/7

133146/50140/10128/20

46182/10165/2

160/1094/10

Meltingpoint (0C)

29

- 2 4- 6 9- 8 2- 3 4

5813

- 525

188

71120225

Meltingpoint (0C)

65

61

- 9 3

22

- 9 0

1424

Density(at 200C)

1.00490.99990.9941.1100.9090.9170.8900.897

1.070

1.406

1.1751.1611.1650.906

Density(at 200C)

0.975

0.9751.340

0.934

1.070

0.9990.90221.3551.191.221.2531.070.9400.8860.86390.8750.9651

0.86020.8837


1.53881.55401.56201.58201.53801.5441.54081.5412

1.58401.6016

1.4455

1.47001.46551.46601.5320


1.54901.55301.5500

1.3950

1.5290

1.51801.4111.42101.4440

1.4100

1.44801.43501.43871.42561.4757

1.44441.4159

Flashpoint (0C)

72>110

45585245

107

34

42

75

Flashpoint (0C)

47

52128

- 6

82

>1102072

- 4

2710413665

RTECSNumber

SL8205000WL5075300WL5075900WL5075800WL5076000

WL5470000

RTECSNumber

UU1040000

UU1045000

AK0875000

DI1050000

FG3325000

GQ5850000

MO7875000LR0525000

R and S

l(l),1241O

1(1),1139B1(1),1139K1(1),1139M1(1),1139N

1(1),1555D

l(l),1205Nl(l),1205K

1(1),1145Gl(2),2207Il(l),1207Cl(l),1207Kl(l),1209F1(1),1141G

R and S

1(1),1153I

1(1),1151G1(2),2495G

1(2),2499B

1(1),715A

l(2),1903L

1(1),697E

1(1),863A

1(1),721H

1(1),719A

FT-NMR

l(2),207C

1(2),2437C

1(2),26C

1(2),27A

1(2),687C

1(2),142A

1(2),35B1(2),1598C1(2), 143 A1(2),138C1(2),148A

FT-NMR

1(2),51A

1(2),46A1(3),242C

1(3),248B

1(1),963A

1(2),1248C

1(1),933A

l(l),1206A

1(1),978C

1(1),793Al(l),1206A

FT-IR

l(l),1052C

1(1),945C1(1),947A1(3),869B1(1),947B

1(1),1334D

l(l),1020Bl(l),1020A

1(1),951D

1(3),871A

FT-IR

1(1),963B

1(1),959C1(2),734A

1(2),738D1(2),853D

1(1),632D

1(1),644A

1(1),736D

1(1),642B

1(1),637C1(1),736C

Merck

Merck

11,9896

Beilstein

6,5616(3),49815,4845(1),2335,4855,485

5,478

5(4), 13675(3),11975(4), 13695,500

Beilstein

20,256

20(2),17020,425

2(1),63

9(1),65

9(4), 18852(4),792

3(3),28

2(3),12632(3),843

2(4), 10053(3),28

Fieser

Fieser

12,565

13,342

8,530

8,530

TABLE 21. cont'd

Name Formula

Maleate, monoester -CH=CHC(O)OHMethacrylate (see Methacrylates)Neodecanoate -C9H19Nonate -(CH2)7CH3

Octadecanoate (stearate) -(CH2) i 6CH3

9-Octadecenoate (oleate) -(CH2)7CH=CH(CH2)7CH3Octanoate -(CH2)6CH3

Pentafluoropropionate -CF 2CF 3

Pentanoate -(CH2)3CH3

Pivalate -C(CH3)3

Propionate -CH 2CH 3

Sebacate -(CH2)8C(O)OCH=CH2

Succinate -CH2CH2C(O)OCH=CH2

Tetradecanoate (myristate) -(CH2) I2CH3

Thioacetate H2C=CHSC(O)CH3

Trichloroacetate -CCl 3Trifluoroacetate - C F 3

1-Trifluoromethyl acetate H2C=C(CF3)OC(O)CH3

Trithiocarbonate H2C=CHSC(S)SCH=CH2

Undecanoate -(CH2)9CH3

Versatate -C(CH3)2(CH2)5CH3

21.3. ETHERS H2C=CHOR

Allyl -CH2CH=CH2

Butoxyethyl -CH2CH2O(CH2)3CH3

/i-Butyl -(CH2)3CH3

2-Butyl -CH(CH2CH3)CH3

tert-Butyl -C(CH3)3

1 -Chloroethyl -CHClCH3

2-Chloroethyl -CH2CH2ClCyclohexyl - C 6 H n1,2-Dichloroethyl -CHClCH2ClDi(ethylene glycol) -CH2CH2OCH2CH2OHDivinyl -CH=CH2

Dodecyl -(CH2) 11CH3

Ethyl -CH 2CH 3

2-Ethylhexyl -CH2CH(CH2CH3)(CH2)3CH3

Glycidyl -CH 2 CH(-O-)CH 2

Hexachlorodivinyl (Cl2C=CCl)2OHexadecyl -(CH2)I5CH3

4-Hydroxybutyl -(CH2)4OH2-Hydroxyethyl -CH2CH2OHIsoamyl -CH2CH2CH(CH3)2

Isobutyl -CH2CH(CH3)2

Isooctyl -(CH2)5CH(CH3)2

Isopropyl -CH(CH3)2

2-(2-Methoxyethoxy)ethyl -(CH2CH2O)2CH3

2-Methoxyethyl -CH2CH2OCH3

Methyl -CH 3

Octadecyl -(CH2)I7CH3

Perfluoropropyl F2C=CFOCF2CF2CF3

Phenyl - C 6 H 5

1-Phenylethyl -CH(C6H5)CH3

Propyl -CH2CH2CH3

21.4. ^-SUBSTITUTED H2C=CHR

-Caprolactam -NC6H10O-Carbazole -NCi 2 H 8

-Formamide -NHC(O)H-Phthalimide -NC 8 H 4 O 2

-Pyrolidone -NC 4H 6O-N-Methylacetamide -N(CH3)C(O)CH3

CAS RegistryNumber

19896-47-0

51000-52-36280-03-1

111-63-73896-58-0

818-44-0

5873-43-83377-92-2

105-38-410355-50-713416-90-55809-91-6

10340-63-37062-87-5433-28-3

2247-91-8930-35-8

49863-74-3

3917-15-54223-11-4

111-34-24181-12-8

926-02-3110-75-8110-75-8

2182-55-0

929-37-3109-93-3765-14-0109-92-2103-44-6

3678-15-7

822-28-617832-28-9

764-48-7

109-53-537769-62-3

926-65-826256-87-1

1663-35-0107-25-5930-02-9

1623-05-8766-94-9

6230-62-2764-47-6

2235-00-91484-13-5

13162-05-53485-84-5

88-12-03195-78-6

MoI. wt.

142.11

198.31184.28310.51308.49170.25190.08128.17128.17100.12254.33170.16254.41102.15189.43140.06154.09134.24212.33198.31

84.12144.21100.16100.16100.16106.55106.55126.20141.00132.1670.09

212.3872.11

156.27100.12276.76268.47116.1688.11

114.19100.16156.2786.13

190.24102.1358.08

296.54266.04120.15148.2186.13

139.20193.2571.08

173.171-11.1499.10

Boilingpoint (0C)

80/1

216133/50

181/2145

79/758/560

13211295

142/350/3

152/3115

38/54286

125/860/1

6770/20

948775

10910914712819628

11833

177139210

173/518914311282

17583

242108

5178/5

36154211

65

128/21154/3

210

166

Meltingpoint (0C)

3236

- 8 1

15

48

- 9 2

- 7 0- 1 0 9

- 1 0 1- 1 2

- 1 1 6- 8 5

16- 3 3

- 1 1 2

- 1 4 0

- 8 3- 1 2 3

27

- 5 0

3665

- 1 685

- 3 6

Density(at 200C)

0.8820.86890.904

0.8719

0.8660.9173

0.87

1.2031.212

0.80.8660.774

0.7621.0481.0480.8911.1970.9860.7730.8170.7540.8161.0061.654

0.9390.9820.78260.7645

0.75340.9900.89670.7511/00.8211.53

1.029

1.014

1.0400.9600


1.43601.4291

1.4256

1.40501.4030

1.31701.3410

1.41091.42201.4101.45581.39801.43801.43801.45401.4558/171.44801.39891.43821.37701.42801.4326

1.44401.43601.40721.3950

1.38401.43901.40721.3730/01.440

1.5226

1.3908

1.4940

1.51201.4835

Flashpoint (0C)

83

>110

>110

106

- 3 12

> 110

<2046

- 9

- 1 7161635

83- 3 0>110- 4 5

5235

8548

- 1 3

- 3 2

17- 5 6177

- 2 6

101

102

9460

RTECSNumber

UF8575000

KH7175000KN5950000

KN6300000KN6300000

KM5495500

KO0710000KO0175000

KM5495000

KO1300000

KO2300000RG0300000

FE6350000

UY6107000AC6475000

R and S

1(1),719B

1(1),745G

1(1),697F

1(1),219C

1(1),221C1(1),221C

1(1),219B

1(1),219D

1(1),219A

1(2),2425E

1(1),923K1(1),891K

FT-NMR

l(l),1030C

1(1),933B

1(1),332B

1(1),336A1(1),336A

1(1),332A

1(3),161C

1(1),1288A1(1),1242C

FT-IR Merck

l(3),704B

1(1),213D

1(1),213B 11,21391(1),213B 11,2139

1(1),212B

1(3),278A

1(3),277C

l(l),790B1(1),759C

Beilstein

2(3),12902(4),1045

2(3),532

2(4),466

19(3),1598

1(4),2387

1(3), 18631(2),4731(2),4736(3), 181(4),23981(4),2398

1,4331(3),186417(5),8,12

1(4),2518l(2),520

1(3),1862

1(3), 1857l(4),2057

1(3),1859

2(3),320720(2),282

21(1),363

4(3),442

Fieser

11,235

1,697

TABLE 21. cont'd

Name Formula

21.5. SULFONATES H2C=CHSO3R

Ethylene sulfonic acid - Hn-Amy\ ester -(CH2)4CH3

n-Butyl ester -(CH2)3CH3

Ethyl ester -CH 2CH 3

n-Hexyl ester -(CH2)5CH3

Isoamyl ester -(CH2)2CH(CH3)2

Isobutyl ester -CH2CH(CH3)2

Isopropyl ester -CH(CH3)2

Methyl ester -CH 3

Phenyl ester -C6H5rc-Propyl ester -CH2CH2CH3

CAS RegistryNumber

1562-34-1

MoL wt.

108.10178.23164.21136.16192.26178.23164.21152.20122.13184.21152.20

Boilingpoint (0C)

100/0.5131/17117/15

76/5146/15124/15

78/570/4

91/1545/2

110/18

Meltingpoint (0C)

Density(at 200C)

1.40031.0871.1221.1831.0501.0821.1901.1321.2481.1651.156


1.44931.44121.44161.4311.44301.44151.4261.43211.43161.4261.4368

Flashpoint (0C)

>110

RTECSNumber Rand S

1(2),2219A

FT-NMR

l(2),1605A

FT-IR

1(3),1437A

Merck Beilstein

6(3),651

Fieser

13,241

Documents

polymer